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Seasonal upper ocean temperatures from coccolith clumped isotopes and a proxy-model comparison for the late Early Eocene Climatic Optimum 球岩块团同位素的季节性上层海洋温度与早始新世晚期气候最佳的代用模式比较
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-24 DOI: 10.1016/j.epsl.2026.119863
Alexander J. Clark , Xiaoqing Liu , Madalina Jaggi , Stefano M. Bernasconi , Victoria E. Taylor , A. Nele Meckler , Heather M. Stoll
The Early Eocene Climatic Optimum (EECO) is a time interval of great interest to the paleoclimate community due to the overall hot temperatures and polar amplification reconstructed by multiple temperature proxies. However, these conditions have been hard to reproduce in climate models and temperature estimates from different proxy carriers for the same regions can differ by 10 °C. Coccolith clumped isotopes—with a robust calibration recently established from laboratory cultures and sediment traps—represent an as-yet untested temperature proxy for this interval. Coccoliths are produced by coccolithophores with well-constrained depth and ecological preferences and therefore provide a clear depth and seasonal target for a proxy-model comparison for the late EECO (∼51.0–50.3 Ma).
We measured coccolith clumped isotopes in 15 globally distributed sites and find a 10 °C upper ocean meridional temperature gradient, similar to previous studies using different proxy systems and carriers such as Mg/Ca and δ18O in foraminifera. We compare our coccolith clumped isotope-derived temperatures to the DeepMIP model compilation, using the known modern ecological constraints of coccolithophores, and divide the model simulations into groups sorted by the difference in global mean surface temperature relative to preindustrial levels (ΔGMST). The best fitting model simulations have ΔGMST between 9.0–13.0 °C. Proxy-model temperature differences up to ±6 °C reveal a hemispheric asymmetry, with warmer proxy/colder model temperatures in the Southern Ocean and cooler proxy/warmer model temperatures in the northern mid-latitudes, highlighting the need for improved model constraints to more accurately simulate ocean circulation and heat transport phenomena.
早始新世气候最适期(EECO)是古气候界非常感兴趣的一个时间间隔,它是由多个温度指标重建的整体高温和极性放大。然而,这些条件很难在气候模式中重现,同一地区不同代用载体的温度估计可能相差10°C。球砾石块状同位素——最近通过实验室培养和沉积物圈闭建立了可靠的校准——代表了该层段尚未测试的温度代表。球粒岩是由深度和生态偏好受良好约束的球粒石藻产生的,因此为EECO晚期(~ 51.0-50.3 Ma)的代理模型比较提供了明确的深度和季节目标。我们在全球分布的15个地点测量了球砾石的团块同位素,发现了10°C的海洋上层经向温度梯度,与之前使用不同的代理系统和载体(如有孔虫中的Mg/Ca和δ18O)的研究相似。我们使用已知的现代生态约束条件,将我们的球石团块同位素衍生温度与DeepMIP模型编译进行了比较,并根据全球平均地表温度相对于工业化前水平的差异将模型模拟分为几组(ΔGMST)。最佳拟合模型模拟结果为ΔGMST在9.0 ~ 13.0°C之间。代理模式之间高达±6°C的温差显示出半球不对称,南大洋代理模式温度较暖/较冷,中纬度北部代理模式温度较冷/较暖,这突出表明需要改进模式约束,以更准确地模拟海洋环流和热输送现象。
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引用次数: 0
Accumulation of remineralised carbon and nutrients in the mid-depth Atlantic during Heinrich Stadial 1 and the Younger Dryas 海因里希第1期和新仙女木期大西洋中深度再矿化碳和营养物的积累
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-24 DOI: 10.1016/j.epsl.2026.119866
Joseph A. Stewart , Laura F. Robinson , James W.B. Rae , Naomi Pratt , Tianyu Chen , Maria Luiza de Carvalho Ferreira , Andrea Burke , Tao Li , Tina van de Flierdt
Atmospheric CO2 and the temperature of the interior Atlantic Ocean both increased in 2-steps during the last deglaciation, particularly during Heinrich Stadial 1 (HS1; ∼16 ka) and the Younger Dryas (YD; ∼12 ka). However, what drove these punctuated rises remains a long-standing question. The role of deep-ocean carbon storage, release, and redistribution continues to be debated. To establish the role of ocean circulation in deglacial carbon and nutrient cycling, we present new multi-proxy data in sub-fossil corals from mid-depths in the Equatorial Atlantic, including boron isotopes (δ11B; seawater pH), Ba/Ca (seawater [Ba] and refractory nutrients), and neodymium isotopes (εNd; provenance of seawater signal). Corals are dated to a precise radiometric age scale and combined with previously published radiocarbon and temperature proxy measurements on the same samples. Our data reveal abrupt intervals (∼500 years) of notably low pH, Ba-rich, and radiocarbon-depleted (old) waters at 15.4 and 12.0 ka during HS1 and the YD at depths of ∼1700 m. However, very low εNd (unradiogenic) values suggest that these corals were bathed in northern-sourced Atlantic waters throughout the deglaciation. These results imply that these (old) carbon- and nutrient-rich intermediate waters were not sourced from the carbon- and nutrient-rich Southern Ocean via Antarctic Intermediate Water (AAIW). Instead, carbon and nutrient accumulation at mid-depths in the tropical Atlantic was likely the result of remineralisation of organic matter at times of Atlantic Meridional Overturning Circulation (AMOC) slowdown. The Atlantic Ocean interior was therefore accumulating heat and carbon during these times when deepwater flushing was minimal, thus acting to partially dampen atmospheric CO2 rise and warming caused by ventilation of the Southern and Pacific Oceans.
在末次冰期,大气CO2和大西洋内部温度均呈2级上升,特别是在Heinrich Stadial 1 (HS1; ~ 16 ka)和Younger Dryas (YD; ~ 12 ka)期间。然而,是什么推动了这些断断续续的上涨,仍然是一个长期存在的问题。深海碳储存、释放和再分配的作用仍在争论中。为了确定海洋环流在去冰碳和营养物循环中的作用,本文利用赤道大西洋中深海亚化石珊瑚的硼同位素(δ11B;海水pH)、Ba/Ca(海水[Ba]和难熔营养物)和钕同位素(εNd;海水信号来源)等新数据,研究了海洋环流在去冰碳和营养物循环中的作用。珊瑚的年代是精确的辐射年龄尺度,并结合先前发表的放射性碳和温度代理测量相同的样本。我们的数据揭示了HS1期间15.4 ka和12.0 ka的显著低pH、富ba和放射性碳枯竭(旧)水的突变间隔(~ 500年)和YD在深度~ 1700 m。然而,极低的εNd(非放射性成因)值表明,这些珊瑚在整个消冰期沐浴在北源的大西洋水域。这些结果表明,这些(古老的)富含碳和营养的中间水不是通过南极中间水(AAIW)来自富含碳和营养的南大洋。相反,热带大西洋中深度的碳和养分积累可能是大西洋经向翻转环流(AMOC)减缓时有机质再矿化的结果。因此,在深水冲刷最小的时期,大西洋内部积累了热量和碳,从而部分地抑制了大气中二氧化碳的上升和由南太平洋和太平洋的通风引起的变暖。
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引用次数: 0
Induced seismicity in the southern Sichuan basin regulated by heterogeneous folding 四川盆地南部受非均质褶皱控制的诱发地震活动
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-23 DOI: 10.1016/j.epsl.2026.119860
Bingfeng Zhang , Xuewei Bao , Mengfan Jiang , Kecheng Zhou
The potential for strong induced earthquakes in industrial production fields is largely controlled by the spatial arrangement of pre-existing faults shaped by regional tectonics. The 2021 Ms 6.0 Luxian earthquake in the southern Sichuan basin is an unusual case in which the seismogenic fault geometry deviates from the prevailing regional stress field and geological framework. To date, the seismogenic environment and the tectonic processes responsible for this destructive event remain poorly understood. In this study, we present a sedimentary shear-wave velocity model and eleven moment tensor solutions across the Luxian shale gas field, derived using data collected by our newly deployed seismic network. Our results reveal previously unrecognized, nearly reversed lateral variations in the amplitudes of synclinal low-velocity anomalies between terrestrial and marine strata, in addition to a first-order velocity contrast that correlates with the regional anticline–syncline architecture. The central Yujiasi syncline exhibits weaker low-velocity anomalies in the shallow terrestrial strata than areas to the north and south, reflecting lower strain intensity likely influenced by shallower décollement layers. Detected seismicity and anomalous reverse-faulting events with fold-parallel P-axes (including the Ms 6.0 earthquake) cluster mainly within two strain transition zones of the Yujiasi syncline, where stress is expected to concentrate and form fold-normal fault planes. These observations provide direct evidence that heterogeneous folding regulates the spatial distribution of induced seismicity in the southern Sichuan basin. They also help identify areas susceptible to induced seismic hazards and provide guidance for planning hydraulic fracturing operations in the region.
工业生产领域发生强震的可能性在很大程度上受区域构造形成的既存断层的空间排列控制。2021年四川盆地南部陆县6.0级地震是一个不寻常的例子,其中发震断层的几何形状偏离了主要的区域应力场和地质框架。迄今为止,人们对这次破坏性事件的发震环境和构造过程仍然知之甚少。在这项研究中,我们利用新部署的地震台网收集的数据,建立了一个横跨芦县页岩气田的沉积横波速度模型和11个矩张量解。我们的研究结果揭示了以前未被认识到的,在陆相和海相地层之间的向斜低速异常振幅中几乎反向的横向变化,以及与区域背斜-向斜结构相关的一级速度对比。渝家泗向斜中部浅层陆相低速异常弱于南北地区,反映出可能受浅层结层影响的应变强度较低。以褶皱平行p轴(包括6.0级地震)探测到的地震活动性和异常逆断层事件主要集中在余家寺向斜的两个应变过渡带内,预计应力将集中形成褶皱正断层面。这些观测结果为非均质褶皱调节川南地区诱发地震活动的空间分布提供了直接证据。它们还有助于识别易受诱发地震危害的区域,并为该地区的水力压裂作业规划提供指导。
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引用次数: 0
Continued continental weathering during snowball earth mitigated greenhouse gas buildup and prolonged global glaciation 雪球地球期间持续的大陆风化减缓了温室气体的积聚,延长了全球冰川作用
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-22 DOI: 10.1016/j.epsl.2026.119837
Shintaro Kadoya , Mohit Melwani Daswani
Global glaciations, also known as snowball events, represent some of Earth’s most significant climate changes. The Neoproterozoic Sturtian glaciation lasted 4–15 times longer than the subsequent Marinoan glaciation, but the causes of this dramatic difference remain unclear. The standard theory attributes the termination of such events to a pause in silicate weathering due to the absence of liquid water on continents. However, recent evidence of syn-glacial dolomite precipitation suggests the possibility of continental weathering during global glaciation. We numerically investigate water-rock reactions under limited water and fresh rock supplies to identify the key factors controlling subglacial weathering and to evaluate their impact on the carbon cycle during global glaciation. The compositions of the discharge fluid and mineral assemblage reach their steady state over a timescale determined by the rate of fresh rock supply. These steady-state compositions are identical when the ratio of the meltwater production rate (Fw) to the fresh rock supply rate (Fr) is constant (Fw/Fr=k). Furthermore, the maximum estimated CO2 consumption could match Earth’s volcanic CO2 emission, assuming present-day Antarctic conditions for meltwater production and fresh rock supply. This finding contradicts the standard assumption that silicate weathering ceases during global glaciation and suggests a mechanism for the prolonged duration of the Sturtian glaciation. These results demonstrate that subglacial weathering represents a previously unrecognized feedback mechanism that could account for the dramatically different durations of Neoproterozoic snowball Earth events.
全球冰川,也被称为雪球事件,代表了地球上一些最重大的气候变化。新元古代的斯图特冰期比随后的马里诺冰期持续了4-15倍,但造成这种巨大差异的原因尚不清楚。标准理论将这些事件的终止归结为由于大陆上缺乏液态水而导致的硅酸盐风化暂停。然而,最近同冰期白云岩降水的证据表明,在全球冰期期间可能存在大陆风化作用。我们通过数值研究在有限的水和新鲜岩石供应条件下的水岩反应,以确定控制冰下风化的关键因素,并评估其对全球冰川时期碳循环的影响。排出流体和矿物组合的成分在一个由新鲜岩石供应速率决定的时间尺度内达到稳定状态。当融水产生速率(Fw)与新鲜岩石供应速率(Fr)之比恒定(Fw/Fr=k)时,这些稳态组成是相同的。此外,假设目前南极的融水生产和新鲜岩石供应条件,估计的最大二氧化碳消耗量可以与地球的火山二氧化碳排放量相匹配。这一发现与硅酸盐风化在全球冰期停止的标准假设相矛盾,并提出了一种延长斯图亚特冰期持续时间的机制。这些结果表明,冰下风化代表了一种以前未被认识到的反馈机制,可以解释新元古代雪球地球事件持续时间的巨大差异。
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引用次数: 0
Experimental determination of equilibrium fractionation of triple oxygen isotopes between dissolved sulfite species and water 溶解亚硫酸盐与水之间三氧同位素平衡分馏的实验测定
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-22 DOI: 10.1016/j.epsl.2026.119862
Yu Wei , Hao Yan , Yan Fang
<div><div>Sulfite, a key intermediate sulfoxyanion in both the reductive and oxidative sulfur cycles, rapidly exchanges oxygen isotopes with ambient water under circumneutral to acidic conditions. Equilibrium oxygen isotope fractionation factors (<sup>18</sup><em>α</em> and <sup>17</sup><em>α</em>) between sulfite and water are therefore critical for interpreting the triple oxygen isotope composition of sulfate and for constraining sulfur cycling. However, equilibrium <sup>18</sup><em>α</em> values remain poorly constrained, with significant discrepancies among experimental and theoretical estimates, largely due to experimental challenges in determining sulfite oxygen isotope compositions and uncertainties in theoretical calibrations. Moreover, equilibrium <sup>17</sup><em>α</em> values have previously been derived only through theoretical calculation. In this study, we applied a pH-shifting technique to eliminate kinetic isotope effects during sulfite precipitation. We also employed a recently developed high-temperature reduction–discharge–CO<sub>2</sub>/O<sub>2</sub> isotope exchange technique to minimize the influence of sulfite hygroscopicity and precisely measured the triple oxygen isotope composition of sulfite equilibrated with water across a pH range of 4.60 to 8.89 and temperature range of 12 to 55 °C. Our results show a consistent, monotonic dependence of oxygen isotope fractionation between bulk sulfite (encompassing all S(IV)-oxyanions, including SO<sub>3</sub><sup>2–</sup> and the bisulfite isomers (HS)O<sub>3</sub><sup>–</sup> and SO<sub>2</sub>(OH)<sup>–</sup>) and water on both pH and temperature. We attribute the former to pH-controlled speciation of dissolved sulfite. From our data, we derived equilibrium fractionation factors for oxygen isotopes between bisulfite and water, and between sulfite (SO<sub>3</sub><sup>2–</sup>) and water:</div><div>1000ln<sup>18</sup><em>α</em><sub>bisulfite–H2O</sub> = (7.06 ± 1.06) × 10<sup>3</sup>/T – 8.80 ± 3.49</div><div>1000ln<sup>18</sup><em>α</em><sub>sulfite–H2O</sub> = (6.59 ± 1.32) × 10<sup>3</sup>/T – 12.56 ± 4.34</div><div>The associated mass-dependent fractionation exponents (<em>θ</em> = ln<sup>17</sup><em>α</em>/ln<sup>18</sup><em>α</em>) are temperature-independent within our studied range, with values of 0.5202 ± 0.0003 for bisulfite and 0.5155 ± 0.0008 for sulfite. These imply that the Δ′<sup>17</sup>O values of bisulfite and sulfite are offset by -0.152‰ and −0.143‰, respectively, from that of ambient water (assuming a reference slope of 0.5305) at 25 °C. Our findings offer new insights into the isotope fractionations associated with microbial sulfate reduction and pyrite oxidation. The observed pH-dependent variations in sulfate δ<sup>18</sup>O signatures during abiotic aerobic pyrite weathering may reflect oxidation of distinct sulfite species under variable pH conditions. Furthermore, the isotope fractionation observed between residual sulfate and water during microbial sulfat
亚硫酸盐是还原和氧化硫循环中一个关键的中间亚砜阴离子,在环中性到酸性条件下与周围水快速交换氧同位素。因此,亚硫酸盐和水之间的平衡氧同位素分馏因子(18α和17α)对于解释硫酸盐的三重氧同位素组成和限制硫循环至关重要。然而,平衡18α值的约束仍然很差,实验和理论估计之间存在显着差异,这主要是由于确定亚硫酸盐氧同位素组成的实验挑战和理论校准的不确定性。此外,平衡17α值以前仅通过理论计算得出。在这项研究中,我们应用了ph转移技术来消除亚硫酸盐沉淀过程中的动力学同位素效应。我们还采用了最近开发的高温还原-排放- co2 /O2同位素交换技术,以最大限度地减少亚硫酸盐吸湿性的影响,并精确测量了亚硫酸盐在pH范围为4.60至8.89,温度范围为12至55°C的情况下与水平衡的三氧同位素组成。我们的研究结果表明,体积亚硫酸盐(包括所有S(IV)-氧阴离子,包括SO32 -和亚硫酸盐异构体(HS)O3 -和SO2(OH) -)与水之间的氧同位素分馏对pH和温度具有一致的单调依赖性。我们将前者归因于溶解亚硫酸盐在ph控制下的形成。根据我们的数据,我们推导出亚硫酸氢盐与水、亚硫酸盐(SO32 -)与水之间的氧同位素平衡分馏因子:1000ln18α亚硫酸氢盐- h2o =(7.06±1.06)× 103/T - 8.80±3.491000ln18α亚硫酸氢盐- h2o =(6.59±1.32)× 103/T - 12.56±4.34。在我们的研究范围内,相关的质量依赖分馏指数(θ = ln17α/ln18α)与温度无关,亚硫酸氢盐的分馏指数为0.5202±0.0003,亚硫酸盐的分馏指数为0.5155±0.0008。这意味着亚硫酸盐和亚硫酸盐的Δ ' 17O值在25°C时分别比环境水(假设参考斜率为0.5305)偏移-0.152‰和- 0.143‰。我们的发现为与微生物硫酸盐还原和黄铁矿氧化相关的同位素分馏提供了新的见解。观察到的非生物好氧黄铁矿风化过程中硫酸盐δ18O特征的pH依赖性变化可能反映了不同亚硫酸盐在不同pH条件下的氧化。此外,在微生物硫酸盐还原过程中观察到的残留硫酸盐和水之间的同位素分馏表明(HS)O3 -优先再氧化为硫酸盐。
{"title":"Experimental determination of equilibrium fractionation of triple oxygen isotopes between dissolved sulfite species and water","authors":"Yu Wei ,&nbsp;Hao Yan ,&nbsp;Yan Fang","doi":"10.1016/j.epsl.2026.119862","DOIUrl":"10.1016/j.epsl.2026.119862","url":null,"abstract":"&lt;div&gt;&lt;div&gt;Sulfite, a key intermediate sulfoxyanion in both the reductive and oxidative sulfur cycles, rapidly exchanges oxygen isotopes with ambient water under circumneutral to acidic conditions. Equilibrium oxygen isotope fractionation factors (&lt;sup&gt;18&lt;/sup&gt;&lt;em&gt;α&lt;/em&gt; and &lt;sup&gt;17&lt;/sup&gt;&lt;em&gt;α&lt;/em&gt;) between sulfite and water are therefore critical for interpreting the triple oxygen isotope composition of sulfate and for constraining sulfur cycling. However, equilibrium &lt;sup&gt;18&lt;/sup&gt;&lt;em&gt;α&lt;/em&gt; values remain poorly constrained, with significant discrepancies among experimental and theoretical estimates, largely due to experimental challenges in determining sulfite oxygen isotope compositions and uncertainties in theoretical calibrations. Moreover, equilibrium &lt;sup&gt;17&lt;/sup&gt;&lt;em&gt;α&lt;/em&gt; values have previously been derived only through theoretical calculation. In this study, we applied a pH-shifting technique to eliminate kinetic isotope effects during sulfite precipitation. We also employed a recently developed high-temperature reduction–discharge–CO&lt;sub&gt;2&lt;/sub&gt;/O&lt;sub&gt;2&lt;/sub&gt; isotope exchange technique to minimize the influence of sulfite hygroscopicity and precisely measured the triple oxygen isotope composition of sulfite equilibrated with water across a pH range of 4.60 to 8.89 and temperature range of 12 to 55 °C. Our results show a consistent, monotonic dependence of oxygen isotope fractionation between bulk sulfite (encompassing all S(IV)-oxyanions, including SO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;2–&lt;/sup&gt; and the bisulfite isomers (HS)O&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;–&lt;/sup&gt; and SO&lt;sub&gt;2&lt;/sub&gt;(OH)&lt;sup&gt;–&lt;/sup&gt;) and water on both pH and temperature. We attribute the former to pH-controlled speciation of dissolved sulfite. From our data, we derived equilibrium fractionation factors for oxygen isotopes between bisulfite and water, and between sulfite (SO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;2–&lt;/sup&gt;) and water:&lt;/div&gt;&lt;div&gt;1000ln&lt;sup&gt;18&lt;/sup&gt;&lt;em&gt;α&lt;/em&gt;&lt;sub&gt;bisulfite–H2O&lt;/sub&gt; = (7.06 ± 1.06) × 10&lt;sup&gt;3&lt;/sup&gt;/T – 8.80 ± 3.49&lt;/div&gt;&lt;div&gt;1000ln&lt;sup&gt;18&lt;/sup&gt;&lt;em&gt;α&lt;/em&gt;&lt;sub&gt;sulfite–H2O&lt;/sub&gt; = (6.59 ± 1.32) × 10&lt;sup&gt;3&lt;/sup&gt;/T – 12.56 ± 4.34&lt;/div&gt;&lt;div&gt;The associated mass-dependent fractionation exponents (&lt;em&gt;θ&lt;/em&gt; = ln&lt;sup&gt;17&lt;/sup&gt;&lt;em&gt;α&lt;/em&gt;/ln&lt;sup&gt;18&lt;/sup&gt;&lt;em&gt;α&lt;/em&gt;) are temperature-independent within our studied range, with values of 0.5202 ± 0.0003 for bisulfite and 0.5155 ± 0.0008 for sulfite. These imply that the Δ′&lt;sup&gt;17&lt;/sup&gt;O values of bisulfite and sulfite are offset by -0.152‰ and −0.143‰, respectively, from that of ambient water (assuming a reference slope of 0.5305) at 25 °C. Our findings offer new insights into the isotope fractionations associated with microbial sulfate reduction and pyrite oxidation. The observed pH-dependent variations in sulfate δ&lt;sup&gt;18&lt;/sup&gt;O signatures during abiotic aerobic pyrite weathering may reflect oxidation of distinct sulfite species under variable pH conditions. Furthermore, the isotope fractionation observed between residual sulfate and water during microbial sulfat","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"679 ","pages":"Article 119862"},"PeriodicalIF":4.8,"publicationDate":"2026-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146036697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comment on: Evolution of iron formation to ore during Ediacaran to early Paleozoic tectonic stability, by Fuentes et al. (2025) 评:埃迪卡拉纪到早古生代构造稳定时期铁形成到矿石的演化,Fuentes et al. (2025)
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-22 DOI: 10.1016/j.epsl.2026.119864
B. Rasmussen , J-W. Zi , J.R. Muhling , I.R. Fletcher
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引用次数: 0
Zircon deformation features reveal sequence of transient high stress, tension and shearing during seismic faulting: A case study from the Ivrea-Verbano Zone, Italy 锆石变形特征揭示了地震断裂过程中瞬态高应力-张拉-剪切序列——以意大利Ivrea-Verbano带为例
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-22 DOI: 10.1016/j.epsl.2026.119858
Sandra Piazolo , Antonio Langone
The mechanisms associated with the propagation of fault ruptures remain debated in terms of sequence of events, processes and magnitude of stresses involved. Microstructures of zircon grains located within and in the immediate vicinity of pseudotachylyte veins reveal a sequence of events transient in time and space and allow recognition of different processes during rupture. The dynamic rupture causes, at its propagating tip, a damage zone of several centimetres thickness. In this damage zone, zircon grains exhibit crystal-plastic deformation signatures ranging from crystal lattice bending continuous throughout whole grains, to distinct planar deformation bands and {112} twin lamellae. Presence of planar deformation bands and {112} twin lamellae suggest locally high stresses, based on similar features reported from meteorite impacts. Absence of well-developed subgrains indicate dominance of low temperature plasticity at the rupture tip. Subsequently, those grains with highest dislocation densities undergo in-situ grain fragmentation. The observed correlation of grains with very high dislocation densities and in-situ grain fragmentation suggests that the effective tensile strength of these grains is sufficiently decreased by the high stored elastic energy to cause their fragmentation when subject to tensile stresses in the wake of the propagating rupture tip. Subsequent displacement along connected damage zone fracture surfaces results in pseudotachylytes formation.
Our data shows that dynamic rupture initiation and propagation results in stresses heterogeneously distributed in space, magnitude and sign causing both ductile and brittle deformation. Our study highlights the value of the accessory mineral zircon in deciphering the nature of rupture zone dynamics.
与断层破裂传播相关的机制在事件顺序、过程和所涉及的应力大小方面仍然存在争议。锆石颗粒的微观结构显示了一系列在时间和空间上短暂的事件,并允许识别破裂过程中的不同过程。动态破裂在其传播尖端造成数厘米厚的损伤区。在该损伤带中,锆石颗粒表现出晶体塑性变形特征,从整个颗粒的晶格连续弯曲到明显的平面变形带和{112}孪晶片。平面变形带和{112}孪晶片的存在表明,根据陨石撞击报道的类似特征,局部存在高应力。缺乏发育良好的亚晶表明在断裂尖端以低温塑性为主。随后,位错密度最高的晶粒发生原位破碎。观察到的具有极高位错密度的晶粒与原位晶粒破碎的相关性表明,当在扩展的破裂尖端受到拉伸应力时,这些晶粒的有效抗拉强度因储存的高弹性能而充分降低,从而导致其破碎。随后沿着连接的损伤区裂缝表面进行位移,形成假羟基地层。我们的数据表明,动态破裂的开始和扩展导致应力在空间、大小和符号上的非均匀分布,导致韧性和脆性变形。我们的研究强调了伴生矿物锆石在解释破裂带动力学性质方面的价值。
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引用次数: 0
Reply to the comment on “The influence of cementation on fault stability” 回复“胶结对断层稳定性的影响”评论
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-21 DOI: 10.1016/j.epsl.2026.119867
G. Volpe , R. Affinito , L. Calzolari , G. Pozzi , C. Marone , C. Collettini
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引用次数: 0
Geochemical controls on the formation of lithium brines in closed-basins of the Lithium Triangle 锂三角封闭盆地锂盐形成的地球化学控制
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-21 DOI: 10.1016/j.epsl.2026.119849
Gordon D.Z. Williams , Julien Barre , Pascale Louvat , Sylvain Bérail , Romain Millot , Avner Vengosh
Sustainable lithium mining is critical to the renewable energy transition. Closed-basin brines are a major source of lithium yet the processes governing lithium enrichment remain poorly understood. In the Lithium Triangle (LT) of South America, hypersaline brines display anomalously high lithium concentrations including at the Salar de Uyuni (SDU) in Bolivia. Using new geochemical and isotopic data from the SDU, Bolivia, we update the accepted conceptual model of evaporative concentration and sequential mineral precipitation based on the formation of calcite, gypsum, and halite. Here we identify ulexite (Na-Ca-borate) precipitation as a previously overlooked but key process in the evaporative evolution of inflow waters that fundamentally alters brine chemistry prior to halite saturation. Additionally, we reveal that surficial brines are largely disconnected from the major lithium inflow, and instead their chemistries are controlled by cyclic halite dissolution-precipitation, leading to the conservative enrichment of solutes like lithium, boron, and magnesium. We suggest that deep brines exploited for lithium extraction are fossil and reflect different stages of evaporation, while modern processes make little contribution to the solute and lithium balance. This new conceptual model revises the classic geochemical pathway and has broad implications for lithium brines and resource sustainability across the LT.
可持续锂开采对可再生能源转型至关重要。闭盆盐水是锂的主要来源,但控制锂富集的过程仍然知之甚少。在南美洲的锂三角(LT),包括玻利维亚的乌尤尼盐湖(SDU)在内的高盐盐水显示出异常高的锂浓度。利用来自玻利维亚SDU的新的地球化学和同位素数据,我们更新了基于方解石、石膏和岩盐形成的蒸发浓度和顺序矿物降水的公认概念模型。在这里,我们确定了无溶解石(na - ca -硼酸盐)沉淀是一个以前被忽视的关键过程,但在流入水的蒸发演化中,它从根本上改变了盐岩饱和之前的卤水化学。此外,我们发现地表盐水与主要的锂流入基本断开,相反,它们的化学成分由循环岩盐溶解-沉淀控制,导致锂、硼和镁等溶质的保守富集。我们认为,用于提取锂的深层盐水是化石的,反映了不同的蒸发阶段,而现代过程对溶质和锂的平衡贡献不大。这个新的概念模型修正了经典的地球化学途径,对整个LT的锂盐和资源可持续性具有广泛的影响。
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引用次数: 0
Inheritance of depleted mantle 186Os signatures in Tibetan ophiolitic chromitites 西藏蛇绿质铬铁矿衰竭地幔1860o特征的遗传
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-01-20 DOI: 10.1016/j.epsl.2026.119855
Yong Xu , Qing Xiong , Bin Qin , Ruohan Gao , Xiaohan Gong , Degao Zhai , D. Graham Pearson , Jingao Liu
The strongly compatible 190Pt-187Re-186, 187Os systematics are relatively resistant to post-magmatic alteration and potentially preserve snapshots of deep mantle processes, making them valuable for tracing the origins of ultramafic-mafic rocks. To compare high-Cr and low-Cr podiform chromitites within ophiolite suites and uncover their formation mechanisms and related mantle evolution, we conducted the first combined high-precision 186Os-187Os and platinum group elemental (PGE: Os, Ir, Ru, Pt, and Pd) investigation of the Luobusa (mean Cr#=78) and Zedang (mean Cr#= 61) ophiolitic chromitites from south Tibet, China. The contrasting 187Os/188Os ratios between the Luobusa high-Cr (0.1271 ± 0.0002) and Zedang low-Cr (0.1292 ± 0.0004) chromitites correlate with their different degrees of fractionation between palladium-group (PPGE) and iridium-group (IPGE) PGE. This relationship follows a global trend and largely reflects the distinct natures of their parental magmas (boninitic vs. MORB-like). Importantly, both chromitites exhibit relatively homogeneous unradiogenic 186Os/188Os ratios (Luobusa: 0.1198359±0.0000026; Zedang: 0.1198355±0.0000005), which are independent of indices of magmatic differentiation such as Cr# and PGE fractionation. These values are comparable, within analytical uncertainties, to the averages of global abyssal peridotites and Phanerozoic Os-rich alloys, and are slightly lower than the primitive mantle and H ordinary chondrites. The 186Os similarity between the Luobusa chromitites and abyssal peridotites is consistent with their known 187Os similarity that features an unradiogenic 187Os/188Os peak at ∼0.126. The combined unradiogenic 186Os-187Os systematics also show no resolvable genetic linkage to plume-related magmatism or recycled crustal materials. Instead, their parental magmas appear to originate from a depleted mantle source.
强相容的190Pt-187Re-186、187Os系统相对不受岩浆后蚀变的影响,并可能保存深部地幔过程的快照,使其对追踪超基性-基性岩石的起源具有价值。为了比较蛇绿岩组中高铬和低铬脚状铬铁矿,揭示其形成机制和相关的地幔演化,我们首次对藏南罗布沙(平均Cr#=78)和泽当(平均Cr#= 61)蛇绿岩铬铁矿进行了高精度186Os-187Os和铂族元素(PGE: Os, Ir, Ru, Pt和Pd)的组合研究。罗布萨高铬(0.1271±0.0002)和泽当低铬(0.1292±0.0004)铬铁矿的187Os/188Os比值差异与钯基(PPGE)和铱基(IPGE)的PGE分馏程度不同有关。这种关系遵循全球趋势,并在很大程度上反映了它们的母岩浆的不同性质(博尼岩型与morb型)。重要的是,两种铬铁矿均表现出相对均匀的非放射性成因的186Os/188Os比值(罗布萨∶0.1198359±0.0000026;泽当∶0.1198355±0.0000005),与Cr#和PGE分选等岩浆分异指标无关。在分析不确定度范围内,这些值与全球深海橄榄岩和显生宙富os合金的平均值相当,略低于原始地幔和H普通球粒陨石。罗布萨铬铁矿与深海橄榄岩之间的186Os相似性与已知的187Os相似性一致,其中187Os/188Os峰值为~ 0.126。1860s - 1870s的非放射性成因系统也显示出与羽状岩浆活动或再循环地壳物质没有可解决的遗传联系。相反,它们的母岩浆似乎来自枯竭的地幔源。
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Earth and Planetary Science Letters
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