Pub Date : 2026-04-01Epub Date: 2026-01-30DOI: 10.1016/j.epsl.2026.119885
Guy Libourel , Marc Portail , Vincent Guigoz , Virginie Brändli , Cyrille Collin , Nathalie Vigier , Tomoki Nakamura , Hikaru Yabuta , Shogo Tachibana , Cecile Engrand
Secondary mineral prevalence in Ryugu samples, similar to primitive carbonaceous-Ivuna type (CI) chondrites, suggests that aqueous alteration was a key factor in its formation. However, this general consensus masks our limited understanding of the specific mechanisms and environmental conditions involved in water-rock interactions on primitive asteroids. High-resolution cathodoluminescence (CL) analysis of the ubiquitous dolomite crystals in Ryugu samples reveals concentric epitaxial overgrowths with varying levels of Mn2+-activated luminescence. CL panchromatic images and spectral deconvolution provide compelling evidence for the evolution of aqueous fluids toward highly saturated brines. Given the close association of dolomite with widespread intergrowths of serpentine and saponite in the matrix, we propose that brine formation occurs as a byproduct of serpentinization. Unlike large-scale evaporation or freezing, this process can locally cause the hydrothermal fluid to dry out, significantly increasing its salinity over time. This leads to the sporadic precipitation of an evaporite mineral sequence, with dolomite forming at an early stage. This serpentinization-driven brine formation model offers a convincing alternative to a purely prograde alteration history for Ryugu. It may also provide a better explanation for the alteration processes of Bennu and other CI chondrite parent bodies.
{"title":"Low temperature brine formation by serpentinization on asteroid (162,173) Ryugu","authors":"Guy Libourel , Marc Portail , Vincent Guigoz , Virginie Brändli , Cyrille Collin , Nathalie Vigier , Tomoki Nakamura , Hikaru Yabuta , Shogo Tachibana , Cecile Engrand","doi":"10.1016/j.epsl.2026.119885","DOIUrl":"10.1016/j.epsl.2026.119885","url":null,"abstract":"<div><div>Secondary mineral prevalence in Ryugu samples, similar to primitive carbonaceous-Ivuna type (CI) chondrites, suggests that aqueous alteration was a key factor in its formation. However, this general consensus masks our limited understanding of the specific mechanisms and environmental conditions involved in water-rock interactions on primitive asteroids. High-resolution cathodoluminescence (CL) analysis of the ubiquitous dolomite crystals in Ryugu samples reveals concentric epitaxial overgrowths with varying levels of Mn<sup>2+</sup>-activated luminescence. CL panchromatic images and spectral deconvolution provide compelling evidence for the evolution of aqueous fluids toward highly saturated brines. Given the close association of dolomite with widespread intergrowths of serpentine and saponite in the matrix, we propose that brine formation occurs as a byproduct of serpentinization. Unlike large-scale evaporation or freezing, this process can locally cause the hydrothermal fluid to dry out, significantly increasing its salinity over time. This leads to the sporadic precipitation of an evaporite mineral sequence, with dolomite forming at an early stage. This serpentinization-driven brine formation model offers a convincing alternative to a purely prograde alteration history for Ryugu. It may also provide a better explanation for the alteration processes of Bennu and other CI chondrite parent bodies.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"679 ","pages":"Article 119885"},"PeriodicalIF":4.8,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-04-01Epub Date: 2026-02-04DOI: 10.1016/j.epsl.2026.119891
Chloe Griffin , Thomas M. Gernon , Minmin Fu , Elias J. Rugen , Anthony M. Spencer , Geoffrey Warrington , Thea K. Hincks
During the two Cryogenian snowball Earth glaciations, the Sturtian (ca. 717–658 Ma) and Marinoan (ca. 639–635 Ma), ice persisted in the tropics for millions of years. Previous analyses of varves deposited before and after these glaciations have revealed climate variability linked to solar, oceanic, and atmospheric dynamics. However, to our knowledge, no evidence of sub-Milankovitch scale climatic variability has been documented during the glaciations themselves. The proposition of reduced solar luminosity in the Cryogenian, an attenuated hydrological cycle, and an expected hiatus in atmosphere-ocean interactions due to ocean freezing, raises questions regarding whether solar-ocean-atmospheric interactions continued during these glaciations. We analyze a unit of 2,640 laminites within the Sturtian Port Askaig Formation on the Garvellach Islands, Scotland, to better understand climate variability during a discrete interval of the Sturtian. Our study indicates the laminites most likely represent annual varves, reflecting seasonal freeze-thaw cycles in a deep, quiescent waterbody. Spectral analysis of laminae thickness reveals decadal and centennial periodicities consistent with present-day Schwabe and Gleissberg solar cycles, alongside interannual periodicities, likely tied to ocean-atmospheric climate modes, resembling the modern El-Niño Southern Oscillation. Our coupled Cryogenian climate simulations under varying degrees of ice coverage produce similar interannual periodicities in surface temperatures near the paleo-coordinates of the Garvellach Islands and in the tropics. This evidence reveals that solar-ocean-atmospheric interactions generated a wider range of climatic variability than expected during snowball Earth and hints at the possibility of transient unfrozen tropical waters during the Sturtian, or other yet unexplored modes of internal climate variability.
在两次冰冻期雪球地球冰期,斯图亚特期(约717-658 Ma)和马里诺期(约639-635 Ma),冰在热带地区持续存在了数百万年。先前对这些冰期前后沉积的碎屑的分析表明,气候变化与太阳、海洋和大气动力学有关。然而,据我们所知,在冰期期间没有记录亚米兰科维奇尺度气候变化的证据。低温期太阳亮度降低、水文循环减弱以及由于海洋冻结而导致大气-海洋相互作用预期中断的主张,提出了在这些冰期期间太阳-海洋-大气相互作用是否继续的问题。我们分析了苏格兰Garvellach群岛上的Sturtian Port Askaig组内的2640个层叠岩单元,以更好地了解Sturtian离散间隔期间的气候变化。我们的研究表明,纹层岩最有可能代表年度变化,反映了一个深的、静止的水体中的季节性冻融循环。层叠厚度的光谱分析显示,年代际和百年周期与当今的Schwabe和Gleissberg太阳周期一致,年际周期可能与海洋-大气气候模式有关,类似于现代El-Niño南方涛动。我们在不同冰覆盖程度下的低温期气候耦合模拟,在Garvellach群岛古坐标附近和热带地区产生了类似的年际周期性地表温度。这一证据表明,太阳-海洋-大气相互作用在雪球地球期间产生的气候变化范围比预期的要大,并暗示在斯图蒂亚时期可能存在短暂的未冻结的热带水域,或者其他尚未探索的内部气候变化模式。
{"title":"Interannual to multidecadal climate oscillations occurred during Cryogenian glaciation","authors":"Chloe Griffin , Thomas M. Gernon , Minmin Fu , Elias J. Rugen , Anthony M. Spencer , Geoffrey Warrington , Thea K. Hincks","doi":"10.1016/j.epsl.2026.119891","DOIUrl":"10.1016/j.epsl.2026.119891","url":null,"abstract":"<div><div>During the two Cryogenian snowball Earth glaciations, the Sturtian (ca. 717–658 Ma) and Marinoan (ca. 639–635 Ma), ice persisted in the tropics for millions of years. Previous analyses of varves deposited before and after these glaciations have revealed climate variability linked to solar, oceanic, and atmospheric dynamics. However, to our knowledge, no evidence of sub-Milankovitch scale climatic variability has been documented during the glaciations themselves. The proposition of reduced solar luminosity in the Cryogenian, an attenuated hydrological cycle, and an expected hiatus in atmosphere-ocean interactions due to ocean freezing, raises questions regarding whether solar-ocean-atmospheric interactions continued during these glaciations. We analyze a unit of 2,640 laminites within the Sturtian Port Askaig Formation on the Garvellach Islands, Scotland, to better understand climate variability during a discrete interval of the Sturtian. Our study indicates the laminites most likely represent annual varves, reflecting seasonal freeze-thaw cycles in a deep, quiescent waterbody. Spectral analysis of laminae thickness reveals decadal and centennial periodicities consistent with present-day Schwabe and Gleissberg solar cycles, alongside interannual periodicities, likely tied to ocean-atmospheric climate modes, resembling the modern El-Niño Southern Oscillation. Our coupled Cryogenian climate simulations under varying degrees of ice coverage produce similar interannual periodicities in surface temperatures near the paleo-coordinates of the Garvellach Islands and in the tropics. This evidence reveals that solar-ocean-atmospheric interactions generated a wider range of climatic variability than expected during snowball Earth and hints at the possibility of transient unfrozen tropical waters during the Sturtian, or other yet unexplored modes of internal climate variability.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"679 ","pages":"Article 119891"},"PeriodicalIF":4.8,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-04-01Epub Date: 2026-02-06DOI: 10.1016/j.epsl.2026.119894
Zhuang Jiang , Tao Zhou , Zhongyi Zhang , Zeqian Liu , Lei Geng
The oxygen isotope anomaly (or mass-independent fractionation signal, Δ17O) in atmospheric nitrate has been widely used to investigate NOx oxidation chemistry and serves as a proxy to probe atmospheric oxidation capacity. However, interpretations of Δ17O(NO3-) measurements have heavily relied on several key assumptions that are not fully constrained nor verified by observations. With recent advances in reported Δ17O(NO2) observations, we revisit the conventional method for computing atmospheric Δ17O(NO3-) using detailed oxygen isotope box model simulations, focusing on Δ17O transfer during nighttime NOx oxidation. Our model results indicate that the assumptions of photochemical steady state and unidirectional Δ17O transfer during NO2 oxidation in previous studies are insufficient to predict nighttime Δ17O(NO3-). Importantly, the rapid thermal decomposition of N2O5 facilitates oxygen isotope exchange between NO2 and NO3, bringing Δ17O close to equilibrium under typical atmosphere boundary layer conditions, which contrasts with the widely hypothesized unidirectional transfer of Δ17O from NO2 to NO3 and N2O5. The variations in Δ17O(NO2) are instead controlled by multiple processes that can be categorized into two classes: (i) NOx emissions and oxidation processes that lower Δ17O(NO2), and (ii) the NO2-NO3-N2O5 thermal cycles that elevate it. Neglecting these factors can lead to severe overestimations of Δ17O in the produced nitrate. In our specific simulation under typical urban winter nighttime conditions, the simplification resulted in an overestimation of up to 11.6 ‰ in Δ17O of surface Δ17O(NO3-). The deviation of daytime result was smaller but still notable at 2.5 ‰. Predicting nighttime Δ17O(NO3-) is further complicated by stratification in the nocturnal boundary layer, which produces different Δ17O(NO3-) between the near-surface and residual layers. Our results highlight the importance of detailed Δ17O transfer modeling for explaining atmospheric Δ17O(NO3-) measurements, and future studies are expected to incorporate transport and turbulent mixing processes into Δ17O modeling.
{"title":"Revisiting oxygen isotope anomalies in NO2 and nitrate in the nocturnal atmosphere: a modeling approach","authors":"Zhuang Jiang , Tao Zhou , Zhongyi Zhang , Zeqian Liu , Lei Geng","doi":"10.1016/j.epsl.2026.119894","DOIUrl":"10.1016/j.epsl.2026.119894","url":null,"abstract":"<div><div>The oxygen isotope anomaly (or mass-independent fractionation signal, Δ<sup>17</sup>O) in atmospheric nitrate has been widely used to investigate NO<sub>x</sub> oxidation chemistry and serves as a proxy to probe atmospheric oxidation capacity. However, interpretations of Δ<sup>17</sup>O(NO<sub>3</sub><sup>-</sup>) measurements have heavily relied on several key assumptions that are not fully constrained nor verified by observations. With recent advances in reported Δ<sup>17</sup>O(NO<sub>2</sub>) observations, we revisit the conventional method for computing atmospheric Δ<sup>17</sup>O(NO<sub>3</sub><sup>-</sup>) using detailed oxygen isotope box model simulations, focusing on Δ<sup>17</sup>O transfer during nighttime NO<sub>x</sub> oxidation. Our model results indicate that the assumptions of photochemical steady state and unidirectional Δ<sup>17</sup>O transfer during NO<sub>2</sub> oxidation in previous studies are insufficient to predict nighttime Δ<sup>17</sup>O(NO<sub>3</sub><sup>-</sup>). Importantly, the rapid thermal decomposition of N<sub>2</sub>O<sub>5</sub> facilitates oxygen isotope exchange between NO<sub>2</sub> and NO<sub>3</sub>, bringing Δ<sup>17</sup>O close to equilibrium under typical atmosphere boundary layer conditions, which contrasts with the widely hypothesized unidirectional transfer of Δ<sup>17</sup>O from NO<sub>2</sub> to NO<sub>3</sub> and N<sub>2</sub>O<sub>5</sub>. The variations in Δ<sup>17</sup>O(NO<sub>2</sub>) are instead controlled by multiple processes that can be categorized into two classes: (i) NO<sub>x</sub> emissions and oxidation processes that lower Δ<sup>17</sup>O(NO<sub>2</sub>), and (ii) the NO<sub>2</sub>-NO<sub>3</sub>-N<sub>2</sub>O<sub>5</sub> thermal cycles that elevate it. Neglecting these factors can lead to severe overestimations of Δ<sup>17</sup>O in the produced nitrate. In our specific simulation under typical urban winter nighttime conditions, the simplification resulted in an overestimation of up to 11.6 ‰ in Δ<sup>17</sup>O of surface Δ<sup>17</sup>O(NO<sub>3</sub><sup>-</sup>). The deviation of daytime result was smaller but still notable at 2.5 ‰. Predicting nighttime Δ<sup>17</sup>O(NO<sub>3</sub><sup>-</sup>) is further complicated by stratification in the nocturnal boundary layer, which produces different Δ<sup>17</sup>O(NO<sub>3</sub><sup>-</sup>) between the near-surface and residual layers. Our results highlight the importance of detailed Δ<sup>17</sup>O transfer modeling for explaining atmospheric Δ<sup>17</sup>O(NO<sub>3</sub><sup>-</sup>) measurements, and future studies are expected to incorporate transport and turbulent mixing processes into Δ<sup>17</sup>O modeling.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"679 ","pages":"Article 119894"},"PeriodicalIF":4.8,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-04-01Epub Date: 2026-01-27DOI: 10.1016/j.epsl.2026.119826
Connor A. Diaz , Rebecca M. Flowers , Carolyn A. Crow , James R. Metcalf , Rita Economos
Understanding the shock conditions of shergottites during their ejection from the Martian surface is important for deconvolving the pre-ejection thermal and geological history from the ejection overprint in Martian meteorite samples. Here, we investigate Martian meteorite Northwest Africa (NWA) 12241 to better quantify absolute temperatures and local variability in shock-induced thermal events and implications for deciphering the Martian meteorite record. NWA 12241 is classified petrologically as low-shock based on its limited shock features. However, new Raman identification of tuite, a high-pressure phosphate polymorph, demonstrates that minimum temperatures of 1100 °C were achieved in some regions of the sample during ejection. (U-Th)/He dating of merrillite yields a wide range of dates from 2.0 ± 0.3 Ma to 191.7 ± 2.7 Ma, interpreted as the ejection and crystallization ages of NWA 12241, respectively. Thermal history modeling suggests that heterogeneous shock heating is required to explain the merrillite data distribution, with local shock temperatures of ≤570 °C necessary to account for preservation of the older dates. Together, the tuite occurrence and (U-Th)/He data support at least 530 °C (and up to 1730 °C) of variability in the peak shock temperature across this small (7.21 g, ∼4 cm) sample. These findings highlight intense thermal heterogeneity and localized high-temperature microenvironments in an otherwise low-shock meteorite, illustrating the value of (U-Th)/He thermochronology for refining interpretations of localized shock effects in Martian meteorites.
{"title":"Heterogeneous ejection temperatures recorded in a “low-shock” Martian meteorite by (U-Th)/He thermochronology and a high-pressure phosphate polymorph","authors":"Connor A. Diaz , Rebecca M. Flowers , Carolyn A. Crow , James R. Metcalf , Rita Economos","doi":"10.1016/j.epsl.2026.119826","DOIUrl":"10.1016/j.epsl.2026.119826","url":null,"abstract":"<div><div>Understanding the shock conditions of shergottites during their ejection from the Martian surface is important for deconvolving the pre-ejection thermal and geological history from the ejection overprint in Martian meteorite samples. Here, we investigate Martian meteorite Northwest Africa (NWA) 12241 to better quantify absolute temperatures and local variability in shock-induced thermal events and implications for deciphering the Martian meteorite record. NWA 12241 is classified petrologically as low-shock based on its limited shock features. However, new Raman identification of tuite, a high-pressure phosphate polymorph, demonstrates that minimum temperatures of 1100 °C were achieved in some regions of the sample during ejection. (U-Th)/He dating of merrillite yields a wide range of dates from 2.0 ± 0.3 Ma to 191.7 ± 2.7 Ma, interpreted as the ejection and crystallization ages of NWA 12241, respectively. Thermal history modeling suggests that heterogeneous shock heating is required to explain the merrillite data distribution, with local shock temperatures of ≤570 °C necessary to account for preservation of the older dates. Together, the tuite occurrence and (U-Th)/He data support at least 530 °C (and up to 1730 °C) of variability in the peak shock temperature across this small (7.21 g, ∼4 cm) sample. These findings highlight intense thermal heterogeneity and localized high-temperature microenvironments in an otherwise low-shock meteorite, illustrating the value of (U-Th)/He thermochronology for refining interpretations of localized shock effects in Martian meteorites.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"679 ","pages":"Article 119826"},"PeriodicalIF":4.8,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-04-01Epub Date: 2026-02-06DOI: 10.1016/j.epsl.2026.119890
Fawn S.M. Holland , Eva E. Stüeken , Wei Dan , Wenxiang Zhang , Yu Zhu , Sami Mikhail
Strongly Peraluminous Granites (SPGs) are mostly formed by the partial melting of Al-rich sedimentary rocks and can reflect the chemical properties of their sedimentary protoliths. Recent work suggests that the nitrogen content ([N]) of SPGs preserve changes in biomass burial over time (Mikhail et al., 2024). This mechanism occurs because in unaltered samples, SPGs with elevated [N] are thought to reflect the elevated [N] of their sedimentary protolith, and this additional nitrogen would come from sediment-hosted biomass. This archive reveals an increase in biomass burial by a factor of 5- to 8-fold between 1.4–0.5 Ga. In this study, we analysed the nitrogen abundances and isotopic values of SPG samples from 1.0 to 0.7 Ga to better resolve the period when biomass burial increased. We find that SPG [N] increases 2.4-fold across the Mesoproterozoic-Neoproterozoic boundary at 1.0 Ga and 2.8-fold across the Neoproterozoic-Phanerozoic boundary at 0.5 Ga. Therefore, with consideration of the time lag from biomass burial to SPG formation, we suggest that biomass burial first began to increase in the late Mesoproterozoic. Biomass burial removes organic carbon, a reductant, from Earth’s surface, causing a net production of O2. Therefore, these data permit us to calculate an increase in O2 production from biomass burial starting in the Mesoproterozoic, yielding an additional 6.3 × 1020 to 30 × 1020 moles of O2 throughout the Neoproterozoic, possibly contributing to the Neoproterozoic Oxygenation Event and to the chain of events which resulted in an environment capable of supporting animal life in the Cambrian.
强过铝花岗岩多由富铝沉积岩部分熔融形成,能反映其沉积原岩的化学性质。最近的研究表明,SPGs的氮含量([N])随着时间的推移保持了生物量埋藏的变化(Mikhail et al., 2024)。这一机制的发生是因为在未改变的样品中,[N]升高的spg被认为反映了沉积原岩中[N]的升高,而这些额外的氮可能来自沉积物承载的生物量。该档案显示,在1.4-0.5 Ga之间,生物质埋藏增加了5- 8倍。本研究分析了1.0 ~ 0.7 Ga SPG样品的氮丰度和同位素值,以更好地确定生物量埋藏增加的时期。在1.0 Ga时,SPG [N]在中元古代-新元古代边界上增加2.4倍,在0.5 Ga时,在新元古代-显生宙边界上增加2.8倍。因此,考虑到生物埋藏到SPG形成的时间滞后,我们认为生物埋藏在中元古代晚期开始增加。生物质掩埋将有机碳(一种还原剂)从地球表面移走,导致氧气的净产量。因此,这些数据使我们能够计算出从中元古代开始的生物质埋藏产生的氧气增加,在整个新元古代产生了6.3 × 1020至30 × 1020摩尔的氧气,这可能有助于新元古代的氧化事件和一系列事件,这些事件导致了寒武纪能够支持动物生命的环境。
{"title":"Nitrogen in strongly peraluminous granites reveals a significant increase in biomass burial and O2 production prior to the Neoproterozoic Oxygenation Event","authors":"Fawn S.M. Holland , Eva E. Stüeken , Wei Dan , Wenxiang Zhang , Yu Zhu , Sami Mikhail","doi":"10.1016/j.epsl.2026.119890","DOIUrl":"10.1016/j.epsl.2026.119890","url":null,"abstract":"<div><div>Strongly Peraluminous Granites (SPGs) are mostly formed by the partial melting of Al-rich sedimentary rocks and can reflect the chemical properties of their sedimentary protoliths. Recent work suggests that the nitrogen content ([N]) of SPGs preserve changes in biomass burial over time (Mikhail et al., 2024). This mechanism occurs because in unaltered samples, SPGs with elevated [N] are thought to reflect the elevated [N] of their sedimentary protolith, and this additional nitrogen would come from sediment-hosted biomass. This archive reveals an increase in biomass burial by a factor of 5- to 8-fold between 1.4–0.5 Ga. In this study, we analysed the nitrogen abundances and isotopic values of SPG samples from 1.0 to 0.7 Ga to better resolve the period when biomass burial increased. We find that SPG [N] increases 2.4-fold across the Mesoproterozoic-Neoproterozoic boundary at 1.0 Ga and 2.8-fold across the Neoproterozoic-Phanerozoic boundary at 0.5 Ga. Therefore, with consideration of the time lag from biomass burial to SPG formation, we suggest that biomass burial first began to increase in the late Mesoproterozoic. Biomass burial removes organic carbon, a reductant, from Earth’s surface, causing a net production of O<sub>2</sub>. Therefore, these data permit us to calculate an increase in O<sub>2</sub> production from biomass burial starting in the Mesoproterozoic, yielding an additional 6.3 × 10<sup>20</sup> to 30 × 10<sup>20</sup> moles of O<sub>2</sub> throughout the Neoproterozoic, possibly contributing to the Neoproterozoic Oxygenation Event and to the chain of events which resulted in an environment capable of supporting animal life in the Cambrian.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"679 ","pages":"Article 119890"},"PeriodicalIF":4.8,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-04-01Epub Date: 2026-02-01DOI: 10.1016/j.epsl.2026.119884
Anne-Sophie Bouvier , Martin Guitreau , Clémence Le Lay , Muriel Laubier , Estelle F. Rose-Koga
This study reports the first high-precision silicon isotope (δ30Si) measurements of olivine-hosted melt inclusions (OHMIs) and their host olivine crystals using laser ablation multi-collector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS). We analyzed samples from two contrasting tectonic settings: three mid-ocean ridge basalts (MORB) and four island arc volcanic rocks. Our results reveal systematic differences in silicon isotope compositions between these two environments. MORB samples show internally consistent δ30Si values in both melt inclusions and host olivine crystals, with isotopic fractionation between phases suggesting equilibrium crystallization processes in MORB magmas. In contrast, arc samples display greater heterogeneity and systematically lower δ30Si values that deviate from equilibrium fractionation factors between olivine and melt. The absence of a correlation with the degree of polymerization of the silicate melt (NBO/T) indicates that these isotopic signatures are not controlled by melt structure. The coupling of low δ30Si and high δ18O values suggests significant contributions from subducted sedimentary materials, particularly siliceous components, to the arc magma source. Our results demonstrate that OHMIs preserve small-scale Si isotope heterogeneities which are invisible at the bulk rock scale. This work highlights the potential of in situ silicon isotope analysis of melt inclusions and their host crystals to trace magmatic processes and source contributions in different tectonic environments, hence providing new insights into the geochemical evolution of arc magmas and the role of subducted materials in mantle heterogeneity.
{"title":"Low δ30Si values in olivine-hosted melt inclusions trace sediment contributions to subduction zone melts","authors":"Anne-Sophie Bouvier , Martin Guitreau , Clémence Le Lay , Muriel Laubier , Estelle F. Rose-Koga","doi":"10.1016/j.epsl.2026.119884","DOIUrl":"10.1016/j.epsl.2026.119884","url":null,"abstract":"<div><div>This study reports the first high-precision silicon isotope (δ<sup>30</sup>Si) measurements of olivine-hosted melt inclusions (OHMIs) and their host olivine crystals using laser ablation multi-collector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS). We analyzed samples from two contrasting tectonic settings: three mid-ocean ridge basalts (MORB) and four island arc volcanic rocks. Our results reveal systematic differences in silicon isotope compositions between these two environments. MORB samples show internally consistent δ<sup>30</sup>Si values in both melt inclusions and host olivine crystals, with isotopic fractionation between phases suggesting equilibrium crystallization processes in MORB magmas. In contrast, arc samples display greater heterogeneity and systematically lower δ<sup>30</sup>Si values that deviate from equilibrium fractionation factors between olivine and melt. The absence of a correlation with the degree of polymerization of the silicate melt (NBO/T) indicates that these isotopic signatures are not controlled by melt structure. The coupling of low δ<sup>30</sup>Si and high δ<sup>18</sup>O values suggests significant contributions from subducted sedimentary materials, particularly siliceous components, to the arc magma source. Our results demonstrate that OHMIs preserve small-scale Si isotope heterogeneities which are invisible at the bulk rock scale. This work highlights the potential of <em>in situ</em> silicon isotope analysis of melt inclusions and their host crystals to trace magmatic processes and source contributions in different tectonic environments, hence providing new insights into the geochemical evolution of arc magmas and the role of subducted materials in mantle heterogeneity.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"679 ","pages":"Article 119884"},"PeriodicalIF":4.8,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-04-01Epub Date: 2026-02-06DOI: 10.1016/j.epsl.2026.119896
Krzysztof Gaidzik , María-Teresa Ramírez-Herrera
The complex interactions among erosion, tectonic uplift, and climate are fundamental to understanding the mechanisms that drive landscape evolution and govern the recycling of crustal materials. In this study, we used basin-averaged erosion rates based on 10Be concentrations in river sediments from eight medium- to large-sized drainage basins across the Guerrero forearc to investigate the interplay between lithology, climatic conditions, and tectonic factors in shaping the topography above the flat-slab subduction zone. The calculated erosion rates range from <0.5 to >0.8 mm/yr and show an apparent eastward increase. This spatial pattern appears to be primarily controlled by the tectonic processes associated with the subduction of the Cocos Plate beneath the North American Plate, particularly the seismogenic activity of crustal faults, with climate variability exerting a secondary influence and limited lithology impact. The eastward increase in erosion rates across the Guerrero forearc appears to correspond to the activity of trench-parallel, W-striking crustal faults, most notably the La Venta Fault, and aligns with observed patterns of exhumation rates, increasing convergence rate, and roughness of the subducting Cocos Plate. The relatively low erosion rates may be attributed to the flat-slab subduction observed in the Guerrero sector of the Mexican subduction zone, consistent with global observations that associate forearc regions above flat slabs with reduced erosion rates. A secondary climatic influence on erosion patterns is indicated by correlations with mean annual discharge and the potential impact of extreme precipitation events at the individual basin scale.
{"title":"Coupled tectonic and surface processes in the Guerrero forearc, Mexico: Insights from the basin-averaged erosion rates","authors":"Krzysztof Gaidzik , María-Teresa Ramírez-Herrera","doi":"10.1016/j.epsl.2026.119896","DOIUrl":"10.1016/j.epsl.2026.119896","url":null,"abstract":"<div><div>The complex interactions among erosion, tectonic uplift, and climate are fundamental to understanding the mechanisms that drive landscape evolution and govern the recycling of crustal materials. In this study, we used basin-averaged erosion rates based on <sup>10</sup>Be concentrations in river sediments from eight medium- to large-sized drainage basins across the Guerrero forearc to investigate the interplay between lithology, climatic conditions, and tectonic factors in shaping the topography above the flat-slab subduction zone. The calculated erosion rates range from <0.5 to >0.8 mm/yr and show an apparent eastward increase. This spatial pattern appears to be primarily controlled by the tectonic processes associated with the subduction of the Cocos Plate beneath the North American Plate, particularly the seismogenic activity of crustal faults, with climate variability exerting a secondary influence and limited lithology impact. The eastward increase in erosion rates across the Guerrero forearc appears to correspond to the activity of trench-parallel, W-striking crustal faults, most notably the La Venta Fault, and aligns with observed patterns of exhumation rates, increasing convergence rate, and roughness of the subducting Cocos Plate. The relatively low erosion rates may be attributed to the flat-slab subduction observed in the Guerrero sector of the Mexican subduction zone, consistent with global observations that associate forearc regions above flat slabs with reduced erosion rates. A secondary climatic influence on erosion patterns is indicated by correlations with mean annual discharge and the potential impact of extreme precipitation events at the individual basin scale.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"679 ","pages":"Article 119896"},"PeriodicalIF":4.8,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185655","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-04-01Epub Date: 2026-01-21DOI: 10.1016/j.epsl.2026.119849
Gordon D.Z. Williams , Julien Barre , Pascale Louvat , Sylvain Bérail , Romain Millot , Avner Vengosh
Sustainable lithium mining is critical to the renewable energy transition. Closed-basin brines are a major source of lithium yet the processes governing lithium enrichment remain poorly understood. In the Lithium Triangle (LT) of South America, hypersaline brines display anomalously high lithium concentrations including at the Salar de Uyuni (SDU) in Bolivia. Using new geochemical and isotopic data from the SDU, Bolivia, we update the accepted conceptual model of evaporative concentration and sequential mineral precipitation based on the formation of calcite, gypsum, and halite. Here we identify ulexite (Na-Ca-borate) precipitation as a previously overlooked but key process in the evaporative evolution of inflow waters that fundamentally alters brine chemistry prior to halite saturation. Additionally, we reveal that surficial brines are largely disconnected from the major lithium inflow, and instead their chemistries are controlled by cyclic halite dissolution-precipitation, leading to the conservative enrichment of solutes like lithium, boron, and magnesium. We suggest that deep brines exploited for lithium extraction are fossil and reflect different stages of evaporation, while modern processes make little contribution to the solute and lithium balance. This new conceptual model revises the classic geochemical pathway and has broad implications for lithium brines and resource sustainability across the LT.
可持续锂开采对可再生能源转型至关重要。闭盆盐水是锂的主要来源,但控制锂富集的过程仍然知之甚少。在南美洲的锂三角(LT),包括玻利维亚的乌尤尼盐湖(SDU)在内的高盐盐水显示出异常高的锂浓度。利用来自玻利维亚SDU的新的地球化学和同位素数据,我们更新了基于方解石、石膏和岩盐形成的蒸发浓度和顺序矿物降水的公认概念模型。在这里,我们确定了无溶解石(na - ca -硼酸盐)沉淀是一个以前被忽视的关键过程,但在流入水的蒸发演化中,它从根本上改变了盐岩饱和之前的卤水化学。此外,我们发现地表盐水与主要的锂流入基本断开,相反,它们的化学成分由循环岩盐溶解-沉淀控制,导致锂、硼和镁等溶质的保守富集。我们认为,用于提取锂的深层盐水是化石的,反映了不同的蒸发阶段,而现代过程对溶质和锂的平衡贡献不大。这个新的概念模型修正了经典的地球化学途径,对整个LT的锂盐和资源可持续性具有广泛的影响。
{"title":"Geochemical controls on the formation of lithium brines in closed-basins of the Lithium Triangle","authors":"Gordon D.Z. Williams , Julien Barre , Pascale Louvat , Sylvain Bérail , Romain Millot , Avner Vengosh","doi":"10.1016/j.epsl.2026.119849","DOIUrl":"10.1016/j.epsl.2026.119849","url":null,"abstract":"<div><div>Sustainable lithium mining is critical to the renewable energy transition. Closed-basin brines are a major source of lithium yet the processes governing lithium enrichment remain poorly understood. In the Lithium Triangle (LT) of South America, hypersaline brines display anomalously high lithium concentrations including at the Salar de Uyuni (SDU) in Bolivia. Using new geochemical and isotopic data from the SDU, Bolivia, we update the accepted conceptual model of evaporative concentration and sequential mineral precipitation based on the formation of calcite, gypsum, and halite. Here we identify ulexite (Na-Ca-borate) precipitation as a previously overlooked but key process in the evaporative evolution of inflow waters that fundamentally alters brine chemistry prior to halite saturation. Additionally, we reveal that surficial brines are largely disconnected from the major lithium inflow, and instead their chemistries are controlled by cyclic halite dissolution-precipitation, leading to the conservative enrichment of solutes like lithium, boron, and magnesium. We suggest that deep brines exploited for lithium extraction are fossil and reflect different stages of evaporation, while modern processes make little contribution to the solute and lithium balance. This new conceptual model revises the classic geochemical pathway and has broad implications for lithium brines and resource sustainability across the LT.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"679 ","pages":"Article 119849"},"PeriodicalIF":4.8,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146001768","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-04-01Epub Date: 2026-01-29DOI: 10.1016/j.epsl.2026.119886
Jiangyang Zhang , Robert J. Stern , Fan Zhang , Jian Lin , Hongfeng Yang
The Challenger Deep in the southernmost Mariana Trench is the deepest area on Earth, yet the physical cause of its exceptional depth remains debated. Here, we quantify the mechanical factors that produce this extreme trench relief and explain why it occurs there. Bathymetric analysis shows that this segment exhibits a steeper outer-trench slope and tighter plate curvature than both the northern Mariana and other global trenches. Applying a buoyancy-loaded elastic plate bending model constrained by bathymetry and deep slab geometry, we isolate two key controls on trench depth through forward and inversion tests: a reduced near-trench elastic thickness and a moderate slab–mantle density contrast. Additional two-dimensional flexure experiments demonstrate that narrower slab segments experience greater deflection under the same load, implying that limited along-strike width mechanically enhances local bending. This effect is realized in nature by a slab tear near 144°30′ E, which isolates a narrow, weakly anchored slab tip and thereby concentrates curvature at the Challenger Deep. Our results suggest that the extreme depth of the Challenger Deep arises from the combined effects of slab negative buoyancy, lithospheric weakening, and slab segmentation, which together localize flexure to produce the deepest trench on Earth.
{"title":"Unusually tight bending of subducting pacific plate causes the extreme depth of challenger deep","authors":"Jiangyang Zhang , Robert J. Stern , Fan Zhang , Jian Lin , Hongfeng Yang","doi":"10.1016/j.epsl.2026.119886","DOIUrl":"10.1016/j.epsl.2026.119886","url":null,"abstract":"<div><div>The Challenger Deep in the southernmost Mariana Trench is the deepest area on Earth, yet the physical cause of its exceptional depth remains debated. Here, we quantify the mechanical factors that produce this extreme trench relief and explain why it occurs there. Bathymetric analysis shows that this segment exhibits a steeper outer-trench slope and tighter plate curvature than both the northern Mariana and other global trenches. Applying a buoyancy-loaded elastic plate bending model constrained by bathymetry and deep slab geometry, we isolate two key controls on trench depth through forward and inversion tests: a reduced near-trench elastic thickness and a moderate slab–mantle density contrast. Additional two-dimensional flexure experiments demonstrate that narrower slab segments experience greater deflection under the same load, implying that limited along-strike width mechanically enhances local bending. This effect is realized in nature by a slab tear near 144°30′ E, which isolates a narrow, weakly anchored slab tip and thereby concentrates curvature at the Challenger Deep. Our results suggest that the extreme depth of the Challenger Deep arises from the combined effects of slab negative buoyancy, lithospheric weakening, and slab segmentation, which together localize flexure to produce the deepest trench on Earth.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"679 ","pages":"Article 119886"},"PeriodicalIF":4.8,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-03-15Epub Date: 2026-01-16DOI: 10.1016/j.epsl.2026.119846
D. Delle Donne , G. Lacanna , A. Aiuppa , M. Bitetto , G. Ulivieri , F. Biagioli , G. Lo Bue Trisciuzzi , M. Ripepe
Volcanic degassing is a key manifestation of volcanic activity, and offers crucial insights into the subtle changes in volcano behavior during unrest and prior to eruption. However, accurately assessing gas emission rates remains difficult, and the implementation of gas flux sensing techniques is one of the most pressing challenges in modern volcanology. Here, we present two years of continuous measurements (April 2017–March 2019) of the SO2 flux and infrasound associated with volcanic degassing at Stromboli volcano (Italy). We show that degassing can be tracked in space and time following changes in infrasonic activity during persistent Strombolian activity. By modeling gas expansion within the conduit, we convert ∼10 million infrasonic signals into equivalent gas fluxes associated with puffing and spattering activity. Our results and calculations from both methodologies indicate a total magmatic gas emission rate ranging between 10 and 100 m³/s. We find this volumetric rate to be almost entirely accounted for by the acoustically-derived gas flux, both in terms of total volume released and the spatial distribution of the degassing sources. Our results open new avenues to interpreting passive degassing at open-vent volcanoes, and demonstrate the potential of infrasound as a valuable tool for quantifying gas emissions in such systems.
{"title":"The beating sound of passive degassing at an open-vent volcano captured by combined infrasonic and SO2 flux observations","authors":"D. Delle Donne , G. Lacanna , A. Aiuppa , M. Bitetto , G. Ulivieri , F. Biagioli , G. Lo Bue Trisciuzzi , M. Ripepe","doi":"10.1016/j.epsl.2026.119846","DOIUrl":"10.1016/j.epsl.2026.119846","url":null,"abstract":"<div><div>Volcanic degassing is a key manifestation of volcanic activity, and offers crucial insights into the subtle changes in volcano behavior during unrest and prior to eruption. However, accurately assessing gas emission rates remains difficult, and the implementation of gas flux sensing techniques is one of the most pressing challenges in modern volcanology. Here, we present two years of continuous measurements (April 2017–March 2019) of the SO<sub>2</sub> flux and infrasound associated with volcanic degassing at Stromboli volcano (Italy). We show that degassing can be tracked in space and time following changes in infrasonic activity during persistent Strombolian activity. By modeling gas expansion within the conduit, we convert ∼10 million infrasonic signals into equivalent gas fluxes associated with puffing and spattering activity. Our results and calculations from both methodologies indicate a total magmatic gas emission rate ranging between 10 and 100 m³/s. We find this volumetric rate to be almost entirely accounted for by the acoustically-derived gas flux, both in terms of total volume released and the spatial distribution of the degassing sources. Our results open new avenues to interpreting passive degassing at open-vent volcanoes, and demonstrate the potential of infrasound as a valuable tool for quantifying gas emissions in such systems.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"678 ","pages":"Article 119846"},"PeriodicalIF":4.8,"publicationDate":"2026-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145975722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}