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Low temperature brine formation by serpentinization on asteroid (162,173) Ryugu 小行星(162173)Ryugu的蛇纹岩作用形成低温卤水
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-04-01 Epub Date: 2026-01-30 DOI: 10.1016/j.epsl.2026.119885
Guy Libourel , Marc Portail , Vincent Guigoz , Virginie Brändli , Cyrille Collin , Nathalie Vigier , Tomoki Nakamura , Hikaru Yabuta , Shogo Tachibana , Cecile Engrand
Secondary mineral prevalence in Ryugu samples, similar to primitive carbonaceous-Ivuna type (CI) chondrites, suggests that aqueous alteration was a key factor in its formation. However, this general consensus masks our limited understanding of the specific mechanisms and environmental conditions involved in water-rock interactions on primitive asteroids. High-resolution cathodoluminescence (CL) analysis of the ubiquitous dolomite crystals in Ryugu samples reveals concentric epitaxial overgrowths with varying levels of Mn2+-activated luminescence. CL panchromatic images and spectral deconvolution provide compelling evidence for the evolution of aqueous fluids toward highly saturated brines. Given the close association of dolomite with widespread intergrowths of serpentine and saponite in the matrix, we propose that brine formation occurs as a byproduct of serpentinization. Unlike large-scale evaporation or freezing, this process can locally cause the hydrothermal fluid to dry out, significantly increasing its salinity over time. This leads to the sporadic precipitation of an evaporite mineral sequence, with dolomite forming at an early stage. This serpentinization-driven brine formation model offers a convincing alternative to a purely prograde alteration history for Ryugu. It may also provide a better explanation for the alteration processes of Bennu and other CI chondrite parent bodies.
与原始碳-伊武那型(CI)球粒陨石相似,Ryugu样品中的次生矿物普遍存在,表明水蚀变是其形成的关键因素。然而,这种普遍共识掩盖了我们对原始小行星上水岩相互作用的具体机制和环境条件的有限理解。高分辨率阴极发光(CL)分析了龙谷样品中普遍存在的白云石晶体,发现了不同水平的Mn2+活化发光的同心外延过度生长。CL全色图像和光谱反褶积为含水流体向高饱和盐水的演化提供了令人信服的证据。鉴于白云岩与基质中广泛的蛇纹石和皂石共生关系密切,我们认为卤水形成是蛇纹石化的副产物。与大规模蒸发或冻结不同,这一过程会局部导致热液变干,随着时间的推移,其盐度会显著增加。这导致蒸发岩矿物序列的零星沉淀,白云岩形成于早期阶段。这种蛇纹岩驱动的盐水地层模型为Ryugu提供了一种令人信服的替代方案,而不是纯粹的递进蚀变历史。这也可能为贝努和其他CI球粒陨石母体的蚀变过程提供更好的解释。
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引用次数: 0
Interannual to multidecadal climate oscillations occurred during Cryogenian glaciation 在冰川期发生了年际到多年代际气候振荡
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-04-01 Epub Date: 2026-02-04 DOI: 10.1016/j.epsl.2026.119891
Chloe Griffin , Thomas M. Gernon , Minmin Fu , Elias J. Rugen , Anthony M. Spencer , Geoffrey Warrington , Thea K. Hincks
During the two Cryogenian snowball Earth glaciations, the Sturtian (ca. 717–658 Ma) and Marinoan (ca. 639–635 Ma), ice persisted in the tropics for millions of years. Previous analyses of varves deposited before and after these glaciations have revealed climate variability linked to solar, oceanic, and atmospheric dynamics. However, to our knowledge, no evidence of sub-Milankovitch scale climatic variability has been documented during the glaciations themselves. The proposition of reduced solar luminosity in the Cryogenian, an attenuated hydrological cycle, and an expected hiatus in atmosphere-ocean interactions due to ocean freezing, raises questions regarding whether solar-ocean-atmospheric interactions continued during these glaciations. We analyze a unit of 2,640 laminites within the Sturtian Port Askaig Formation on the Garvellach Islands, Scotland, to better understand climate variability during a discrete interval of the Sturtian. Our study indicates the laminites most likely represent annual varves, reflecting seasonal freeze-thaw cycles in a deep, quiescent waterbody. Spectral analysis of laminae thickness reveals decadal and centennial periodicities consistent with present-day Schwabe and Gleissberg solar cycles, alongside interannual periodicities, likely tied to ocean-atmospheric climate modes, resembling the modern El-Niño Southern Oscillation. Our coupled Cryogenian climate simulations under varying degrees of ice coverage produce similar interannual periodicities in surface temperatures near the paleo-coordinates of the Garvellach Islands and in the tropics. This evidence reveals that solar-ocean-atmospheric interactions generated a wider range of climatic variability than expected during snowball Earth and hints at the possibility of transient unfrozen tropical waters during the Sturtian, or other yet unexplored modes of internal climate variability.
在两次冰冻期雪球地球冰期,斯图亚特期(约717-658 Ma)和马里诺期(约639-635 Ma),冰在热带地区持续存在了数百万年。先前对这些冰期前后沉积的碎屑的分析表明,气候变化与太阳、海洋和大气动力学有关。然而,据我们所知,在冰期期间没有记录亚米兰科维奇尺度气候变化的证据。低温期太阳亮度降低、水文循环减弱以及由于海洋冻结而导致大气-海洋相互作用预期中断的主张,提出了在这些冰期期间太阳-海洋-大气相互作用是否继续的问题。我们分析了苏格兰Garvellach群岛上的Sturtian Port Askaig组内的2640个层叠岩单元,以更好地了解Sturtian离散间隔期间的气候变化。我们的研究表明,纹层岩最有可能代表年度变化,反映了一个深的、静止的水体中的季节性冻融循环。层叠厚度的光谱分析显示,年代际和百年周期与当今的Schwabe和Gleissberg太阳周期一致,年际周期可能与海洋-大气气候模式有关,类似于现代El-Niño南方涛动。我们在不同冰覆盖程度下的低温期气候耦合模拟,在Garvellach群岛古坐标附近和热带地区产生了类似的年际周期性地表温度。这一证据表明,太阳-海洋-大气相互作用在雪球地球期间产生的气候变化范围比预期的要大,并暗示在斯图蒂亚时期可能存在短暂的未冻结的热带水域,或者其他尚未探索的内部气候变化模式。
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引用次数: 0
Revisiting oxygen isotope anomalies in NO2 and nitrate in the nocturnal atmosphere: a modeling approach 重新审视夜间大气中NO2和硝酸盐的氧同位素异常:建模方法
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-04-01 Epub Date: 2026-02-06 DOI: 10.1016/j.epsl.2026.119894
Zhuang Jiang , Tao Zhou , Zhongyi Zhang , Zeqian Liu , Lei Geng
The oxygen isotope anomaly (or mass-independent fractionation signal, Δ17O) in atmospheric nitrate has been widely used to investigate NOx oxidation chemistry and serves as a proxy to probe atmospheric oxidation capacity. However, interpretations of Δ17O(NO3-) measurements have heavily relied on several key assumptions that are not fully constrained nor verified by observations. With recent advances in reported Δ17O(NO2) observations, we revisit the conventional method for computing atmospheric Δ17O(NO3-) using detailed oxygen isotope box model simulations, focusing on Δ17O transfer during nighttime NOx oxidation. Our model results indicate that the assumptions of photochemical steady state and unidirectional Δ17O transfer during NO2 oxidation in previous studies are insufficient to predict nighttime Δ17O(NO3-). Importantly, the rapid thermal decomposition of N2O5 facilitates oxygen isotope exchange between NO2 and NO3, bringing Δ17O close to equilibrium under typical atmosphere boundary layer conditions, which contrasts with the widely hypothesized unidirectional transfer of Δ17O from NO2 to NO3 and N2O5. The variations in Δ17O(NO2) are instead controlled by multiple processes that can be categorized into two classes: (i) NOx emissions and oxidation processes that lower Δ17O(NO2), and (ii) the NO2-NO3-N2O5 thermal cycles that elevate it. Neglecting these factors can lead to severe overestimations of Δ17O in the produced nitrate. In our specific simulation under typical urban winter nighttime conditions, the simplification resulted in an overestimation of up to 11.6 ‰ in Δ17O of surface Δ17O(NO3-). The deviation of daytime result was smaller but still notable at 2.5 ‰. Predicting nighttime Δ17O(NO3-) is further complicated by stratification in the nocturnal boundary layer, which produces different Δ17O(NO3-) between the near-surface and residual layers. Our results highlight the importance of detailed Δ17O transfer modeling for explaining atmospheric Δ17O(NO3-) measurements, and future studies are expected to incorporate transport and turbulent mixing processes into Δ17O modeling.
大气硝酸盐中氧同位素异常(或质量无关分异信号,Δ17O)已被广泛用于研究NOx氧化化学,并作为探测大气氧化能力的替代指标。然而,对Δ17O(NO3-)测量值的解释在很大程度上依赖于几个关键假设,这些假设没有得到观测的完全约束和验证。随着Δ17O(NO2)观测报告的最新进展,我们重新审视了使用详细的氧同位素箱模型模拟计算大气Δ17O(NO3-)的传统方法,重点关注夜间NOx氧化期间的Δ17O转移。我们的模型结果表明,以往研究中对NO2氧化过程中光化学稳态和单向Δ17O转移的假设不足以预测夜间Δ17O(NO3-)。重要的是,N2O5的快速热分解促进了NO2和NO3之间的氧同位素交换,使Δ17O在典型的大气边界层条件下接近平衡,这与广泛假设的Δ17O从NO2向NO3和N2O5的单向转移形成对比。相反,Δ17O(NO2)的变化由多个过程控制,这些过程可分为两类:(i)降低Δ17O(NO2)的氮氧化物排放和氧化过程,以及(ii)提高它的NO2- no3 - n2o5热循环。忽略这些因素会导致严重高估所产生的硝酸盐中Δ17O的含量。在典型城市冬季夜间条件下的具体模拟中,简化导致地表Δ17O(NO3-) Δ17O的高估高达11.6‰。日间结果偏差较小,但仍显著,为2.5‰。夜间边界层的分层使夜间Δ17O(NO3-)的预测变得更加复杂,夜间边界层在近地表和剩余层之间产生不同的Δ17O(NO3-)。我们的研究结果强调了详细的Δ17O传输模型对于解释大气Δ17O(NO3-)测量的重要性,未来的研究有望将输送和湍流混合过程纳入Δ17O模型。
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引用次数: 0
Heterogeneous ejection temperatures recorded in a “low-shock” Martian meteorite by (U-Th)/He thermochronology and a high-pressure phosphate polymorph 通过(U-Th)/He热年代学和高压磷酸盐多晶体记录了“低冲击”火星陨石的非均匀喷射温度
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-04-01 Epub Date: 2026-01-27 DOI: 10.1016/j.epsl.2026.119826
Connor A. Diaz , Rebecca M. Flowers , Carolyn A. Crow , James R. Metcalf , Rita Economos
Understanding the shock conditions of shergottites during their ejection from the Martian surface is important for deconvolving the pre-ejection thermal and geological history from the ejection overprint in Martian meteorite samples. Here, we investigate Martian meteorite Northwest Africa (NWA) 12241 to better quantify absolute temperatures and local variability in shock-induced thermal events and implications for deciphering the Martian meteorite record. NWA 12241 is classified petrologically as low-shock based on its limited shock features. However, new Raman identification of tuite, a high-pressure phosphate polymorph, demonstrates that minimum temperatures of 1100 °C were achieved in some regions of the sample during ejection. (U-Th)/He dating of merrillite yields a wide range of dates from 2.0 ± 0.3 Ma to 191.7 ± 2.7 Ma, interpreted as the ejection and crystallization ages of NWA 12241, respectively. Thermal history modeling suggests that heterogeneous shock heating is required to explain the merrillite data distribution, with local shock temperatures of ≤570 °C necessary to account for preservation of the older dates. Together, the tuite occurrence and (U-Th)/He data support at least 530 °C (and up to 1730 °C) of variability in the peak shock temperature across this small (7.21 g, ∼4 cm) sample. These findings highlight intense thermal heterogeneity and localized high-temperature microenvironments in an otherwise low-shock meteorite, illustrating the value of (U-Th)/He thermochronology for refining interpretations of localized shock effects in Martian meteorites.
了解火星表面抛射时的冲击条件,对于从火星陨石样品的抛射叠印中解褶化抛射前的热历史和地质历史具有重要意义。在这里,我们研究了火星陨石西北非洲(NWA) 12241,以更好地量化绝对温度和局部变化在冲击引起的热事件和破译火星陨石记录的意义。NWA 12241在岩石学上被归类为低冲击,基于其有限的冲击特征。然而,高压磷酸盐多晶白石的新拉曼鉴定表明,在喷射过程中,样品的某些区域达到了1100°C的最低温度。(U-Th)/He定年得到2.0±0.3 Ma ~ 191.7±2.7 Ma的宽范围时间,分别解释为NWA 12241的喷射年龄和结晶年龄。热历史模型表明,需要非均匀冲击加热来解释merrillite数据的分布,局部冲击温度≤570°C是解释较旧日期保存的必要条件。总的来说,白钨的出现和(U-Th)/He数据支持在这个小(7.21 g, ~ 4 cm)样品中,峰值冲击温度的变化至少为530°C(最高为1730°C)。这些发现强调了在低激波陨石中强烈的热非均质性和局部高温微环境,说明了(U-Th)/He热年代学在改进火星陨石局部激波效应解释方面的价值。
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引用次数: 0
Nitrogen in strongly peraluminous granites reveals a significant increase in biomass burial and O2 production prior to the Neoproterozoic Oxygenation Event 在新元古代氧化事件之前,强过铝花岗岩中的氮显示出生物质埋藏和氧气生产的显著增加
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-04-01 Epub Date: 2026-02-06 DOI: 10.1016/j.epsl.2026.119890
Fawn S.M. Holland , Eva E. Stüeken , Wei Dan , Wenxiang Zhang , Yu Zhu , Sami Mikhail
Strongly Peraluminous Granites (SPGs) are mostly formed by the partial melting of Al-rich sedimentary rocks and can reflect the chemical properties of their sedimentary protoliths. Recent work suggests that the nitrogen content ([N]) of SPGs preserve changes in biomass burial over time (Mikhail et al., 2024). This mechanism occurs because in unaltered samples, SPGs with elevated [N] are thought to reflect the elevated [N] of their sedimentary protolith, and this additional nitrogen would come from sediment-hosted biomass. This archive reveals an increase in biomass burial by a factor of 5- to 8-fold between 1.4–0.5 Ga. In this study, we analysed the nitrogen abundances and isotopic values of SPG samples from 1.0 to 0.7 Ga to better resolve the period when biomass burial increased. We find that SPG [N] increases 2.4-fold across the Mesoproterozoic-Neoproterozoic boundary at 1.0 Ga and 2.8-fold across the Neoproterozoic-Phanerozoic boundary at 0.5 Ga. Therefore, with consideration of the time lag from biomass burial to SPG formation, we suggest that biomass burial first began to increase in the late Mesoproterozoic. Biomass burial removes organic carbon, a reductant, from Earth’s surface, causing a net production of O2. Therefore, these data permit us to calculate an increase in O2 production from biomass burial starting in the Mesoproterozoic, yielding an additional 6.3 × 1020 to 30 × 1020 moles of O2 throughout the Neoproterozoic, possibly contributing to the Neoproterozoic Oxygenation Event and to the chain of events which resulted in an environment capable of supporting animal life in the Cambrian.
强过铝花岗岩多由富铝沉积岩部分熔融形成,能反映其沉积原岩的化学性质。最近的研究表明,SPGs的氮含量([N])随着时间的推移保持了生物量埋藏的变化(Mikhail et al., 2024)。这一机制的发生是因为在未改变的样品中,[N]升高的spg被认为反映了沉积原岩中[N]的升高,而这些额外的氮可能来自沉积物承载的生物量。该档案显示,在1.4-0.5 Ga之间,生物质埋藏增加了5- 8倍。本研究分析了1.0 ~ 0.7 Ga SPG样品的氮丰度和同位素值,以更好地确定生物量埋藏增加的时期。在1.0 Ga时,SPG [N]在中元古代-新元古代边界上增加2.4倍,在0.5 Ga时,在新元古代-显生宙边界上增加2.8倍。因此,考虑到生物埋藏到SPG形成的时间滞后,我们认为生物埋藏在中元古代晚期开始增加。生物质掩埋将有机碳(一种还原剂)从地球表面移走,导致氧气的净产量。因此,这些数据使我们能够计算出从中元古代开始的生物质埋藏产生的氧气增加,在整个新元古代产生了6.3 × 1020至30 × 1020摩尔的氧气,这可能有助于新元古代的氧化事件和一系列事件,这些事件导致了寒武纪能够支持动物生命的环境。
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引用次数: 0
Low δ30Si values in olivine-hosted melt inclusions trace sediment contributions to subduction zone melts 含橄榄石的熔体包裹体δ30Si值低,微量沉积物对俯冲带熔体有贡献
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-04-01 Epub Date: 2026-02-01 DOI: 10.1016/j.epsl.2026.119884
Anne-Sophie Bouvier , Martin Guitreau , Clémence Le Lay , Muriel Laubier , Estelle F. Rose-Koga
This study reports the first high-precision silicon isotope (δ30Si) measurements of olivine-hosted melt inclusions (OHMIs) and their host olivine crystals using laser ablation multi-collector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS). We analyzed samples from two contrasting tectonic settings: three mid-ocean ridge basalts (MORB) and four island arc volcanic rocks. Our results reveal systematic differences in silicon isotope compositions between these two environments. MORB samples show internally consistent δ30Si values in both melt inclusions and host olivine crystals, with isotopic fractionation between phases suggesting equilibrium crystallization processes in MORB magmas. In contrast, arc samples display greater heterogeneity and systematically lower δ30Si values that deviate from equilibrium fractionation factors between olivine and melt. The absence of a correlation with the degree of polymerization of the silicate melt (NBO/T) indicates that these isotopic signatures are not controlled by melt structure. The coupling of low δ30Si and high δ18O values suggests significant contributions from subducted sedimentary materials, particularly siliceous components, to the arc magma source. Our results demonstrate that OHMIs preserve small-scale Si isotope heterogeneities which are invisible at the bulk rock scale. This work highlights the potential of in situ silicon isotope analysis of melt inclusions and their host crystals to trace magmatic processes and source contributions in different tectonic environments, hence providing new insights into the geochemical evolution of arc magmas and the role of subducted materials in mantle heterogeneity.
本研究首次利用激光烧蚀多集电极电感耦合等离子体质谱(LA-MC-ICP-MS)对橄榄石包裹体(OHMIs)及其宿主橄榄石晶体进行了高精度硅同位素(δ30Si)测量。我们分析了两种不同构造背景的样品:三种洋中脊玄武岩(MORB)和四种岛弧火山岩。我们的研究结果揭示了这两种环境中硅同位素组成的系统性差异。MORB样品中熔体包裹体和寄主橄榄石晶体的δ30Si值内部一致,相间同位素分馏表明MORB岩浆中存在平衡结晶过程。相比之下,电弧样品表现出更大的非均质性,δ30Si值偏离橄榄石和熔体之间的平衡分馏因子。与硅酸盐熔体聚合度(NBO/T)没有相关性表明这些同位素特征不受熔体结构的控制。低δ30Si值和高δ18O值的耦合表明,俯冲沉积物质,特别是硅质成分对弧岩浆源有重要贡献。我们的研究结果表明,OHMIs保留了在大块岩石尺度上不可见的小尺度Si同位素非均质性。本工作强调了熔融包裹体及其寄主晶体原位硅同位素分析在不同构造环境下追踪岩浆过程和来源贡献的潜力,从而为弧岩浆的地球化学演化和俯冲物质在地幔非均质性中的作用提供了新的见解。
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引用次数: 0
Coupled tectonic and surface processes in the Guerrero forearc, Mexico: Insights from the basin-averaged erosion rates 墨西哥Guerrero前弧的耦合构造和地表过程:来自盆地平均侵蚀速率的见解
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-04-01 Epub Date: 2026-02-06 DOI: 10.1016/j.epsl.2026.119896
Krzysztof Gaidzik , María-Teresa Ramírez-Herrera
The complex interactions among erosion, tectonic uplift, and climate are fundamental to understanding the mechanisms that drive landscape evolution and govern the recycling of crustal materials. In this study, we used basin-averaged erosion rates based on 10Be concentrations in river sediments from eight medium- to large-sized drainage basins across the Guerrero forearc to investigate the interplay between lithology, climatic conditions, and tectonic factors in shaping the topography above the flat-slab subduction zone. The calculated erosion rates range from <0.5 to >0.8 mm/yr and show an apparent eastward increase. This spatial pattern appears to be primarily controlled by the tectonic processes associated with the subduction of the Cocos Plate beneath the North American Plate, particularly the seismogenic activity of crustal faults, with climate variability exerting a secondary influence and limited lithology impact. The eastward increase in erosion rates across the Guerrero forearc appears to correspond to the activity of trench-parallel, W-striking crustal faults, most notably the La Venta Fault, and aligns with observed patterns of exhumation rates, increasing convergence rate, and roughness of the subducting Cocos Plate. The relatively low erosion rates may be attributed to the flat-slab subduction observed in the Guerrero sector of the Mexican subduction zone, consistent with global observations that associate forearc regions above flat slabs with reduced erosion rates. A secondary climatic influence on erosion patterns is indicated by correlations with mean annual discharge and the potential impact of extreme precipitation events at the individual basin scale.
侵蚀、构造隆起和气候之间复杂的相互作用是理解驱动景观演化和控制地壳物质循环的机制的基础。在这项研究中,我们使用了基于格雷罗前弧8个大中型流域河流沉积物中10Be浓度的盆地平均侵蚀速率,来研究岩性、气候条件和构造因素在塑造平板俯冲带上方地形方面的相互作用。计算得到的侵蚀速率在0.5 ~ 0.8 mm/年之间,呈明显的向东增加趋势。这种空间格局似乎主要受与科科斯板块俯冲到北美板块之下有关的构造过程控制,特别是地壳断层的发震活动,气候变化起次要影响,岩性影响有限。东侵格雷罗前弧的侵蚀速率增加似乎与沟平行的w向地壳断层(最显著的是La Venta断层)的活动相对应,并与观测到的挖掘速率、不断增加的收敛速率和俯冲的Cocos板块的粗糙度模式一致。相对较低的侵蚀速率可能归因于在墨西哥俯冲带的Guerrero板块观测到的平板俯冲作用,这与全球观测结果一致,即平板上方的弧前区域侵蚀速率较低。在单个流域尺度上,气候对侵蚀模式的次生影响与年平均流量和极端降水事件的潜在影响相关。
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引用次数: 0
Geochemical controls on the formation of lithium brines in closed-basins of the Lithium Triangle 锂三角封闭盆地锂盐形成的地球化学控制
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-04-01 Epub Date: 2026-01-21 DOI: 10.1016/j.epsl.2026.119849
Gordon D.Z. Williams , Julien Barre , Pascale Louvat , Sylvain Bérail , Romain Millot , Avner Vengosh
Sustainable lithium mining is critical to the renewable energy transition. Closed-basin brines are a major source of lithium yet the processes governing lithium enrichment remain poorly understood. In the Lithium Triangle (LT) of South America, hypersaline brines display anomalously high lithium concentrations including at the Salar de Uyuni (SDU) in Bolivia. Using new geochemical and isotopic data from the SDU, Bolivia, we update the accepted conceptual model of evaporative concentration and sequential mineral precipitation based on the formation of calcite, gypsum, and halite. Here we identify ulexite (Na-Ca-borate) precipitation as a previously overlooked but key process in the evaporative evolution of inflow waters that fundamentally alters brine chemistry prior to halite saturation. Additionally, we reveal that surficial brines are largely disconnected from the major lithium inflow, and instead their chemistries are controlled by cyclic halite dissolution-precipitation, leading to the conservative enrichment of solutes like lithium, boron, and magnesium. We suggest that deep brines exploited for lithium extraction are fossil and reflect different stages of evaporation, while modern processes make little contribution to the solute and lithium balance. This new conceptual model revises the classic geochemical pathway and has broad implications for lithium brines and resource sustainability across the LT.
可持续锂开采对可再生能源转型至关重要。闭盆盐水是锂的主要来源,但控制锂富集的过程仍然知之甚少。在南美洲的锂三角(LT),包括玻利维亚的乌尤尼盐湖(SDU)在内的高盐盐水显示出异常高的锂浓度。利用来自玻利维亚SDU的新的地球化学和同位素数据,我们更新了基于方解石、石膏和岩盐形成的蒸发浓度和顺序矿物降水的公认概念模型。在这里,我们确定了无溶解石(na - ca -硼酸盐)沉淀是一个以前被忽视的关键过程,但在流入水的蒸发演化中,它从根本上改变了盐岩饱和之前的卤水化学。此外,我们发现地表盐水与主要的锂流入基本断开,相反,它们的化学成分由循环岩盐溶解-沉淀控制,导致锂、硼和镁等溶质的保守富集。我们认为,用于提取锂的深层盐水是化石的,反映了不同的蒸发阶段,而现代过程对溶质和锂的平衡贡献不大。这个新的概念模型修正了经典的地球化学途径,对整个LT的锂盐和资源可持续性具有广泛的影响。
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引用次数: 0
Unusually tight bending of subducting pacific plate causes the extreme depth of challenger deep 俯冲的太平洋板块异常紧密的弯曲导致了挑战者深处的极端深度
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-04-01 Epub Date: 2026-01-29 DOI: 10.1016/j.epsl.2026.119886
Jiangyang Zhang , Robert J. Stern , Fan Zhang , Jian Lin , Hongfeng Yang
The Challenger Deep in the southernmost Mariana Trench is the deepest area on Earth, yet the physical cause of its exceptional depth remains debated. Here, we quantify the mechanical factors that produce this extreme trench relief and explain why it occurs there. Bathymetric analysis shows that this segment exhibits a steeper outer-trench slope and tighter plate curvature than both the northern Mariana and other global trenches. Applying a buoyancy-loaded elastic plate bending model constrained by bathymetry and deep slab geometry, we isolate two key controls on trench depth through forward and inversion tests: a reduced near-trench elastic thickness and a moderate slab–mantle density contrast. Additional two-dimensional flexure experiments demonstrate that narrower slab segments experience greater deflection under the same load, implying that limited along-strike width mechanically enhances local bending. This effect is realized in nature by a slab tear near 144°30′ E, which isolates a narrow, weakly anchored slab tip and thereby concentrates curvature at the Challenger Deep. Our results suggest that the extreme depth of the Challenger Deep arises from the combined effects of slab negative buoyancy, lithospheric weakening, and slab segmentation, which together localize flexure to produce the deepest trench on Earth.
位于马里亚纳海沟最南端的挑战者深渊是地球上最深的区域,但其异常深度的物理原因仍然存在争议。在这里,我们量化了产生这种极端海沟起伏的机械因素,并解释了它为什么会发生在那里。水深分析表明,与北马里亚纳海沟和其他全球海沟相比,这一段海沟外坡度更陡,板块曲率更窄。应用受测深和深板块几何约束的浮力载荷弹性板块弯曲模型,我们通过正演和反演测试分离出影响海沟深度的两个关键控制因素:减小的海沟附近弹性厚度和适度的板块-地幔密度对比。另外的二维弯曲实验表明,在相同的荷载下,较窄的板段经历了更大的挠曲,这意味着有限的沿走向宽度在机械上增强了局部弯曲。这种效果在自然界中是通过靠近东经144°30 '的板块撕裂实现的,它隔离了狭窄的、弱锚定的板块尖端,从而集中了挑战者深渊的曲率。我们的研究结果表明,挑战者深的极端深度是板块负浮力、岩石圈减弱和板块分割共同作用的结果,这些共同作用使板块弯曲局部化,形成了地球上最深的海沟。
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引用次数: 0
The beating sound of passive degassing at an open-vent volcano captured by combined infrasonic and SO2 flux observations 利用次声和SO2通量联合观测捕获的露天火山被动脱气的跳动声
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2026-03-15 Epub Date: 2026-01-16 DOI: 10.1016/j.epsl.2026.119846
D. Delle Donne , G. Lacanna , A. Aiuppa , M. Bitetto , G. Ulivieri , F. Biagioli , G. Lo Bue Trisciuzzi , M. Ripepe
Volcanic degassing is a key manifestation of volcanic activity, and offers crucial insights into the subtle changes in volcano behavior during unrest and prior to eruption. However, accurately assessing gas emission rates remains difficult, and the implementation of gas flux sensing techniques is one of the most pressing challenges in modern volcanology. Here, we present two years of continuous measurements (April 2017–March 2019) of the SO2 flux and infrasound associated with volcanic degassing at Stromboli volcano (Italy). We show that degassing can be tracked in space and time following changes in infrasonic activity during persistent Strombolian activity. By modeling gas expansion within the conduit, we convert ∼10 million infrasonic signals into equivalent gas fluxes associated with puffing and spattering activity. Our results and calculations from both methodologies indicate a total magmatic gas emission rate ranging between 10 and 100 m³/s. We find this volumetric rate to be almost entirely accounted for by the acoustically-derived gas flux, both in terms of total volume released and the spatial distribution of the degassing sources. Our results open new avenues to interpreting passive degassing at open-vent volcanoes, and demonstrate the potential of infrasound as a valuable tool for quantifying gas emissions in such systems.
火山脱气是火山活动的一个重要表现,它为火山在动荡和喷发前的细微变化提供了重要的见解。然而,准确评估气体排放率仍然很困难,气体通量传感技术的实施是现代火山学中最紧迫的挑战之一。在这里,我们提供了两年(2017年4月至2019年3月)连续测量的SO2通量和次声与斯特隆博利火山(意大利)的火山脱气有关。我们表明,在持续的斯特隆波活动期间,随着次声活动的变化,脱气可以在空间和时间上进行跟踪。通过模拟管道内的气体膨胀,我们将约1000万个次声信号转换为与膨化和飞溅活动相关的等效气体通量。我们的结果和两种方法的计算表明,岩浆气体的总排放速率在10到100 m³/s之间。我们发现,无论从释放的总体积还是从脱气源的空间分布来看,这个体积率几乎完全由声衍生的气体通量来解释。我们的研究结果为解释开放式火山的被动脱气开辟了新的途径,并证明了次声作为量化此类系统中气体排放的有价值工具的潜力。
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Earth and Planetary Science Letters
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