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Pristine or altered, what can early diagenesis tell us in shallow-water carbonates? 无论是原始的还是经过改造的,浅水碳酸盐的早期成岩作用能告诉我们什么?
IF 5.3 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-06-03 DOI: 10.1016/j.epsl.2024.118806
Guang-Yi Wei, Feifei Zhang

Early marine and meteoric diagenesis is commonly proposed to alter the primary geochemical signals of shallow-marine carbonates, hindering their use as a reliable archive for ancient seawater chemistry. However, there are still uncertainties on the extent and controlling factors of early diagenetic alteration for shallow-marine carbonates. In this study, we compile and compare radiogenic Sr, Li, and U isotope data of carbonate island reefs and platforms from the South China Sea and the Bahamas to better constrain the early diagenetic effects on geochemical signals in carbonates. Multiple diagenetic zones are identified in carbonate drillcores from the South China Sea, and temporally correlated with similar zones in the Bahamas. The radiogenic Sr, Li and U isotope records from shallow-marine carbonates in these two geographically distant regions are affected by multiple factors, including compositions of diagenetic fluids, local depositional environments, fluid advection/diffusion rates, and carbonate recrystallization rates. These factors ultimately determined the diagenetic extents and regimes (fluid-buffered or sediment-buffered) of shallow-marine carbonates, which vary across different isotopic systems. A full understanding of early diagenetic history and its effects on different isotopic proxies will validate the use of shallow-marine carbonate as an archive for ancient seawater information, and contribute to tracking the temporal changes in paleo-climate and -environment.

人们普遍认为,早期海洋和陨石成岩作用改变了浅海碳酸盐的初级地球化学信号,阻碍了它们作为古海水化学可靠档案的使用。然而,浅海碳酸盐早期成岩蚀变的程度和控制因素仍存在不确定性。在本研究中,我们汇编并比较了南海和巴哈马群岛碳酸盐岛礁和平台的放射性 Sr、Li 和 U 同位素数据,以更好地确定早期成岩作用对碳酸盐地球化学信号的影响。在中国南海的碳酸盐岩钻屑中发现了多个成岩带,并与巴哈马群岛的类似成岩带在时间上相互关联。这两个地理位置遥远地区浅海碳酸盐的放射性 Sr、Li 和 U 同位素记录受到多种因素的影响,包括成岩流体成分、当地沉积环境、流体平流/扩散速率以及碳酸盐再结晶速率。这些因素最终决定了浅海碳酸盐岩的成岩范围和机制(流体缓冲或沉积物缓冲),不同同位素系统的成岩范围和机制各不相同。充分了解早期成岩历史及其对不同同位素代用指标的影响,将验证将浅海碳酸盐作为古海水信息档案的有效性,并有助于追踪古气候和古环境的时间变化。
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引用次数: 0
Mantle serpentinization of subducting plate are controlled by combined effect of plate age and bending curvature 俯冲板块的地幔蛇化受板块年龄和弯曲曲率的共同作用控制
IF 5.3 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-06-01 DOI: 10.1016/j.epsl.2024.118799
Jiangyang Zhang , Fan Zhang , Jian Lin , Xiang Gao , Chen Cai , Zhiyuan Zhou

A primary pathway for surface water to enter the Earth's interior is through faulting of oceanic plates. Mantle hydration of subducting plate is considered to play an important role on the water flux of subduction zone. Previous studies have found that the mantle hydration was related to plate bending and faulting, however the controlling mechanism of plate bending on mantle hydration at subduction zone is still highly unclear. In this study, we use the latest obtained reduction in uppermost mantle P-wave velocity (Vp) profiles beneath the subduction zone outer rise region, which is thought to be the result of mantle serpentinization, to examine the degrees of mantle serpentinization at several subduction zones and analyzed their relationship to plate age, bending curvature, and the sediment thickness near the trench. Results of analysis revealed that the average degree of the estimated mantle serpentinization increases with both the plate age and bending curvature, while it is hampered by sedimentation. The thick sediment can almost entirely prevent water from entering the mantle. Importantly, we found a good linear correlation between the reduction of uppermost mantle Vp and the theoretical brittle extensional strain determined by plate age and curvature. Based on this, a mechanism is proposed to illustrate the governing mechanism of the combined effect of the plate age and bending curvature in controlling the mantle serpentinization degree for global subduction zones.

地表水进入地球内部的一个主要途径是通过大洋板块的断层。俯冲板块的地幔水化被认为对俯冲带的水通量起着重要作用。以往的研究发现,地幔水化与板块弯曲和断层有关,但板块弯曲对俯冲带地幔水化的控制机制仍然非常不清楚。在本研究中,我们利用最新获得的俯冲带外隆起区下最上层地幔P波速度(Vp)剖面的减小(认为是地幔蛇化的结果),研究了几个俯冲带的地幔蛇化程度,并分析了它们与板块年龄、弯曲曲率和海沟附近沉积厚度的关系。分析结果表明,估算的地幔蛇绿化平均程度随板块年龄和弯曲曲率的增加而增加,但受到沉积作用的阻碍。厚厚的沉积物几乎可以完全阻止水进入地幔。重要的是,我们发现最上地幔 Vp 的减少与由板块年龄和曲率确定的理论脆性伸展应变之间存在良好的线性相关。在此基础上,我们提出了一个机制,以说明板块年龄和弯曲曲率共同作用控制全球俯冲带地幔蛇化程度的支配机制。
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引用次数: 0
Importance of grain boundary processes for plasticity in the quartz-dominated crust: Implications for flow laws 晶界过程对石英为主的地壳塑性的重要性:对流动规律的影响
IF 5.3 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-06-01 DOI: 10.1016/j.epsl.2024.118767
Subhajit Ghosh , Holger Stünitz , Hugues Raimbourg , Jacques Précigout , Ida Di Carlo , Renée Heilbronner , Laurette Piani

When H2O is present along grain boundaries, the deformation processes responsible for plasticity in silicate mineral aggregates can deviate from what may be conventionally expected. Although a necessary component of understanding crustal deformation processes, there is no theoretical framework that incorporates grain boundary processes into polycrystalline quartz rheology. To address this issue, we carried out high-pressure and high-temperature deformation experiments on fine-grained quartz aggregates. Our study illustrates that grain boundary migration (GBM) through dissolution-precipitation (in the presence of an aqueous fluid) and grain boundary sliding (GBS) may act as accommodation mechanisms to prevent hardening from dislocation glide. GBM and GBS can relax incompatibilities resulting from an inadequate number of independent slip systems, plastic anisotropy between neighbouring grains, and non-planar grain boundaries together with grain boundary junctions. As demonstrated earlier in the literature, GBM may act as a recrystallization mechanism counteracting hardening, but also is a potential mechanism that allow H2O to enter in the quartz crystal (hydrolization) at the experimental time-scale. The above serial processes occur over a range of more than two orders of magnitude in grain size (∼3 to 200 μm) and explain a grain-size-insensitive stress exponent (n = 2) and low activation energy (Q = 110 kJ/mol). In the absence of a switch to grain size sensitive deformation mechanisms induced by grain size reduction, our results imply that only a modest weakening (∼5 times the strength of the protolith) is needed (or possible) to localize shear zones in the Earth's crust.

当 H2O 沿晶界存在时,硅酸盐矿物聚集体中负责塑性的变形过程可能会偏离常规预期。虽然晶界过程是了解地壳变形过程的必要组成部分,但目前还没有一个理论框架将晶界过程纳入多晶石英流变学。为了解决这个问题,我们对细粒石英集合体进行了高压和高温变形实验。我们的研究表明,通过溶解-沉淀(在有水性流体存在的情况下)进行的晶界迁移(GBM)和晶界滑动(GBS)可作为一种调适机制,防止位错滑行引起的硬化。GBM 和 GBS 可放松因独立滑移系统数量不足、相邻晶粒之间的塑性各向异性以及非平面晶界和晶界交界而产生的不相容性。正如之前的文献所证明的那样,GBM 可能是一种抵消硬化的再结晶机制,同时也是一种在实验时间尺度上允许 H2O 进入石英晶体(水化)的潜在机制。上述系列过程发生在两个数量级以上的晶粒尺寸范围内(∼3 至 200 μm),并解释了晶粒尺寸不敏感应力指数(n = 2)和低活化能(Q = 110 kJ/mol)的原因。在没有晶粒尺寸减小引起的对晶粒尺寸敏感的变形机制转换的情况下,我们的结果表明,只需要(或可能)适度的削弱(原岩强度的5倍)就可以在地壳中形成局部剪切带。
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引用次数: 0
A phlogopite-bearing lithospheric mantle source for Europe's largest REE-HFSE belt: Gardar Rift, SW Greenland 欧洲最大的 REE-HFSE 带的岩石圈地幔源:格陵兰西南部的加达尔裂谷
IF 5.3 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-05-31 DOI: 10.1016/j.epsl.2024.118780
Charles D. Beard , Adrian A. Finch , Anouk M. Borst , Kathryn M. Goodenough , William Hutchison , Ian L. Millar , Tom Andersen , Helen M. Williams , Owen M. Weller

Alkaline-silicate complexes host some of the world's largest resources of rare-earth elements and high-field-strength elements (REE & HFSE) and represent the most fractionated magmatic systems on our planet. Geochemical evidence indicates that they are mantle melts, but while various studies highlight a role for lithospheric mantle, we do not know the precise origin of their contained REE and HFSE, and whether enrichment of the mantle source for these magmas can be attributed to specific geodynamic processes or events.

We present new Nd-Hf isotope measurements (

/
&
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) made by LA-MC-ICP-MS, as well as a compilation of existing isotopic data for a suite of alkaline igneous rocks from the Gardar Province, a Mesoproterozoic continental rift in southern Greenland. Neodymium and hafnium isotopes are unaffected by crystal fractionation and can directly fingerprint the source of REE and HFSE. The dataset covers both phases of Gardar magmatism (1325–1261 and 1184–1140 Ma) and incorporates mafic dyke swarms and km-scale intrusive complexes, including Ilimmaasaq (Ilímaussaq) and Motzfeldt, which host some of the world's largest REE and HFSE deposits. The majority of Gardar complexes have a narrow range of positive median initial εNd (0 to +3.3) and εHf values (+0.2 to +6.0). Only two granite intrusions and the Eriksfjord basaltic lavas have crustally contaminated Nd-Hf isotope compositions, with the vast majority of Gardar igneous rocks preserving the isotope signature of their mantle source. Considering the diversity of rock types in the Gardar Province, initial εNd -εHf compositions are remarkably homogeneous, indicating a derivation of the Gardar's REE and HFSE from a laterally-extensive mantle melt source.

Several Gardar systems have low initial εHf for a given εNd (

εHf to -9.7), a distinctive signature as few geological processes decouple the Nd and Hf isotope systems. The decoupled Nd-Hf isotope signatures are consistent with contributions from isotopically-matured phlogopite-bearing metasomatic veins (commonly known as PIC: phlogopite-ilmenite-clinopyroxene) in the lithospheric mantle. The metasomatising fluids that formed these source rocks were introduced via Palaeoproterozoic subduction, but the Gardar isotopic signatures indicate that REE and HFSE enrichment of these metasomes was not derived from subducted sediment; instead it is likely that metals were scavenged from the mantle wedge overlying the ancient subduction zone. The Gardar Nd-Hf isotope evolution trends overlap with a global compilation of kimberlites through time and allow us to tie the origin of the PIC metasomes to the regional geodynamic history of South Greenland. We identify PIC metasomes as a key metal s
碱性硅酸盐复合体蕴藏着世界上最大的稀土元素和高场强元素(REE & HFSE)资源,是地球上分馏程度最高的岩浆系统。地球化学证据表明它们是地幔熔体,但尽管各种研究都强调了岩石圈地幔的作用,我们却不知道它们所含稀土元素和高场强元素的确切来源,也不知道这些岩浆的地幔源富集是否可归因于特定的地球动力学过程或事件。我们介绍了利用 LA-MC-ICP-MS 进行的新的钕铪同位素测量(/ & / ),以及对格陵兰南部中新生代大陆裂谷加达尔省的一套碱性火成岩的现有同位素数据的汇编。钕和铪同位素不受晶体分馏的影响,可以直接确定 REE 和 HFSE 的来源。该数据集涵盖了加达尔岩浆活动的两个阶段(1325-1261 Ma 和 1184-1140 Ma),包括岩浆岩堤群和千米规模的侵入复合体,其中包括伊利玛萨克(Ilimmaasaq)和莫茨费尔特(Motzfeldt),它们拥有一些世界上最大的 REE 和 HFSE 矿床。大多数加达尔复合体的初始εNd(0 至 +3.3)和εHf 值(+0.2 至 +6.0)的中值范围较窄,均为正值。只有两个花岗岩侵入体和埃里克斯峡湾玄武岩熔岩的 Nd-Hf 同位素组成受到地壳污染,绝大多数加达尔火成岩保留了其地幔源的同位素特征。考虑到加尔达省岩石类型的多样性,初始εNd -εHf成分非常均匀,这表明加尔达省的REE和HFSE来源于一个横向扩展的地幔熔体源。在给定的εNd条件下,几个加尔达系的初始εHf较低(εHf至-9.7),这是一个独特的特征,因为很少有地质过程使Nd和Hf同位素系统脱钩。脱钩的 Nd-Hf 同位素特征与岩石圈地幔中同位素成熟的含辉绿岩的变质岩脉(通常称为 PIC:辉绿岩-钛铁矿-辉铜矿)的贡献是一致的。形成这些源岩的变质流体是通过古新生代俯冲作用引入的,但加尔达同位素特征表明,这些变质岩的 REE 和 HFSE 富集并非来自俯冲沉积物;相反,金属很可能是从古俯冲带上覆的地幔楔中清除的。Gardar Nd-Hf 同位素演变趋势与全球金伯利岩的时间汇编相重叠,使我们能够将 PIC metasomes 的起源与南格陵兰的区域地球动力学历史联系起来。我们确定 PIC 变质岩是加达尔地区的一个关键金属源,进而可能是全球其他 REE 矿化火成岩区的一个关键金属源。
{"title":"A phlogopite-bearing lithospheric mantle source for Europe's largest REE-HFSE belt: Gardar Rift, SW Greenland","authors":"Charles D. Beard ,&nbsp;Adrian A. Finch ,&nbsp;Anouk M. Borst ,&nbsp;Kathryn M. Goodenough ,&nbsp;William Hutchison ,&nbsp;Ian L. Millar ,&nbsp;Tom Andersen ,&nbsp;Helen M. Williams ,&nbsp;Owen M. Weller","doi":"10.1016/j.epsl.2024.118780","DOIUrl":"https://doi.org/10.1016/j.epsl.2024.118780","url":null,"abstract":"<div><p>Alkaline-silicate complexes host some of the world's largest resources of rare-earth elements and high-field-strength elements (REE &amp; HFSE) and represent the most fractionated magmatic systems on our planet. Geochemical evidence indicates that they are mantle melts, but while various studies highlight a role for lithospheric mantle, we do not know the precise origin of their contained REE and HFSE, and whether enrichment of the mantle source for these magmas can be attributed to specific geodynamic processes or events.</p><p>We present new Nd-Hf isotope measurements (<figure><img></figure>/<figure><img></figure> &amp; <figure><img></figure>/<figure><img></figure> ) made by LA-MC-ICP-MS, as well as a compilation of existing isotopic data for a suite of alkaline igneous rocks from the Gardar Province, a Mesoproterozoic continental rift in southern Greenland. Neodymium and hafnium isotopes are unaffected by crystal fractionation and can directly fingerprint the source of REE and HFSE. The dataset covers both phases of Gardar magmatism (1325–1261 and 1184–1140 Ma) and incorporates mafic dyke swarms and km-scale intrusive complexes, including Ilimmaasaq (Ilímaussaq) and Motzfeldt, which host some of the world's largest REE and HFSE deposits. The majority of Gardar complexes have a narrow range of positive median initial <em>ε</em><sub>Nd</sub> (0 to +3.3) and <em>ε</em><sub>Hf</sub> values (+0.2 to +6.0). Only two granite intrusions and the Eriksfjord basaltic lavas have crustally contaminated Nd-Hf isotope compositions, with the vast majority of Gardar igneous rocks preserving the isotope signature of their mantle source. Considering the diversity of rock types in the Gardar Province, initial <em>ε</em><sub>Nd</sub> -<em>ε</em><sub>Hf</sub> compositions are remarkably homogeneous, indicating a derivation of the Gardar's REE and HFSE from a laterally-extensive mantle melt source.</p><p>Several Gardar systems have low initial <em>ε</em><sub>Hf</sub> for a given <em>ε</em><sub>Nd</sub> (<figure><img></figure><em>ε</em><sub>Hf</sub> to -9.7), a distinctive signature as few geological processes decouple the Nd and Hf isotope systems. The decoupled Nd-Hf isotope signatures are consistent with contributions from isotopically-matured phlogopite-bearing metasomatic veins (commonly known as PIC: phlogopite-ilmenite-clinopyroxene) in the lithospheric mantle. The metasomatising fluids that formed these source rocks were introduced via Palaeoproterozoic subduction, but the Gardar isotopic signatures indicate that REE and HFSE enrichment of these metasomes was not derived from subducted sediment; instead it is likely that metals were scavenged from the mantle wedge overlying the ancient subduction zone. The Gardar Nd-Hf isotope evolution trends overlap with a global compilation of kimberlites through time and allow us to tie the origin of the PIC metasomes to the regional geodynamic history of South Greenland. We identify PIC metasomes as a key metal s","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0012821X24002139/pdfft?md5=ff5d376be64564e07f6cecbb0a301879&pid=1-s2.0-S0012821X24002139-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141244462","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evolution of tungsten isotope systematics in the Mauna Kea volcano provides new constraints on anomalous µ182W and high 3He/4He in the mantle 莫纳克亚火山中钨同位素系统学的演变为地幔中的异常µ182W和高3He/4He提供了新的制约因素
IF 5.3 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-05-31 DOI: 10.1016/j.epsl.2024.118795
Lori N Willhite, Valerie A Finlayson, Richard J Walker

Highly siderophile element abundances and 182W/184W and 187Os/188Os were determined for a suite of Mauna Kea lavas from the Hawaiian Scientific Drilling Project phase 2 drill core. The new analyses, combined with previous measurements, compose the largest database for µ182W (the parts-per-million deviation of 182W/184W from a terrestrial standard) for a single volcano (n = 16). Although most lavas analyzed are characterized by negative µ182W values, lavas with values similar to the modern bulk silicate Earth are found throughout the entire stratigraphic column. This suggests that components with normal µ182W are collocated with components that host µ182W deficits in the plume. Negative µ182W values are associated with elevated 3He/4He, as well as elevated Ti and Nb. These correlations may link µ182W anomalies to ancient deep mantle crystal-liquid fractionation processes. Consistent with previously measured 3He/4He (R/RA) in the drill core, the magnitude of negative µ182W values was greatest when Mauna Kea was close to the plume axis then generally decreased over the ∼400 kyr captured by the stratigraphic section. The component with anomalous µ182W was either concentrated near the plume axis, or was more effectively sampled by melting near the plume axis where the temperature excess was greatest, suggesting it was less fusible than the dominant plume components. The process leading to the generation of a mantle component with a negative µ182W anomaly could either be related to some form of core-mantle isotopic equilibration, or early-Earth fractionation within the silicate Earth. At present each possibility remains viable.

从夏威夷科学钻探项目第二阶段钻探岩芯中测定了一组莫纳凯亚火山岩的高嗜硒元素丰度、182W/184W和187Os/188Os。新的分析结果与之前的测量结果相结合,构成了单座火山(n = 16)最大的 µ182W(182W/184W 与陆地标准的百万分之一偏差)数据库。虽然分析的大多数熔岩的µ182W值为负值,但在整个地层柱中都发现了与现代大块硅酸盐地球值相似的熔岩。这表明,µ182W 值正常的成分与羽流中µ182W 值不足的成分位于同一地点。负 µ182W 值与升高的 3He/4He 以及升高的 Ti 和 Nb 有关。这些相关性可能将µ182W异常与古老的深地幔晶体-液体分馏过程联系起来。与之前在钻芯中测得的 3He/4He (R/RA) 值一致,当莫纳凯亚火山靠近羽流轴线时,µ182W 负值的幅度最大,然后在地层剖面捕获的 400 千年内普遍下降。µ182W异常的成分要么集中在羽流轴附近,要么在温度过剩最大的羽流轴附近更有效地通过熔化取样,这表明它比主要羽流成分更不容易熔化。导致产生负 µ182W 异常的地幔成分的过程可能与某种形式的地核-地幔同位素平衡有关,或者与硅酸盐地球内部的早期地球分馏有关。目前,每一种可能性都是可行的。
{"title":"Evolution of tungsten isotope systematics in the Mauna Kea volcano provides new constraints on anomalous µ182W and high 3He/4He in the mantle","authors":"Lori N Willhite,&nbsp;Valerie A Finlayson,&nbsp;Richard J Walker","doi":"10.1016/j.epsl.2024.118795","DOIUrl":"https://doi.org/10.1016/j.epsl.2024.118795","url":null,"abstract":"<div><p>Highly siderophile element abundances and <sup>182</sup>W/<sup>184</sup>W and <sup>187</sup>Os/<sup>188</sup>Os were determined for a suite of Mauna Kea lavas from the Hawaiian Scientific Drilling Project phase 2 drill core. The new analyses, combined with previous measurements, compose the largest database for µ<sup>182</sup>W (the parts-per-million deviation of <sup>182</sup>W/<sup>184</sup>W from a terrestrial standard) for a single volcano (<em>n</em> <em>=</em> 16). Although most lavas analyzed are characterized by negative µ<sup>182</sup>W values, lavas with values similar to the modern bulk silicate Earth are found throughout the entire stratigraphic column. This suggests that components with normal µ<sup>182</sup>W are collocated with components that host µ<sup>182</sup>W deficits in the plume. Negative µ<sup>182</sup>W values are associated with elevated <sup>3</sup>He/<sup>4</sup>He, as well as elevated Ti and Nb. These correlations may link µ<sup>182</sup>W anomalies to ancient deep mantle crystal-liquid fractionation processes. Consistent with previously measured <sup>3</sup>He/<sup>4</sup>He (R/R<sub>A</sub>) in the drill core, the magnitude of negative µ<sup>182</sup>W values was greatest when Mauna Kea was close to the plume axis then generally decreased over the ∼400 kyr captured by the stratigraphic section. The component with anomalous µ<sup>182</sup>W was either concentrated near the plume axis, or was more effectively sampled by melting near the plume axis where the temperature excess was greatest, suggesting it was less fusible than the dominant plume components. The process leading to the generation of a mantle component with a negative µ<sup>182</sup>W anomaly could either be related to some form of core-mantle isotopic equilibration, or early-Earth fractionation within the silicate Earth. At present each possibility remains viable.</p></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141244463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simulated radiocarbon cycle revisited by considering the bipolar seesaw and benthic 14C data 通过考虑双极跷跷板和海底 14C 数据,重新审视模拟的放射性碳循环
IF 5.3 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-05-31 DOI: 10.1016/j.epsl.2024.118801
Peter Köhler , Luke C. Skinner , Florian Adolphi

Carbon cycle models used to calculate the marine reservoir age of the non-polar surface ocean (called Marine20) out of IntCal20, the compilation of atmospheric Δ14C, have so far neglected a key aspect of the millennial-scale variability connected with the thermal bipolar seesaw: changes in the strength of the Atlantic meridional overturning circulation (AMOC) related to Dansgaard/Oeschger and Heinrich events. Here we implement such AMOC changes in the carbon cycle box model BICYCLE-SE to investigate how model performance over the last 55 kyr is affected, in particular with respect to available 14C and CO2 data. Constraints from deep ocean 14C data suggest that the AMOC in the model during Heinrich stadial 1 needs to be highly reduced or even completely shutdown. Ocean circulation and sea ice coverage combined are the processes that almost completely explain the simulated changes in deep ocean 14C age, and these are also responsible for a glacial drawdown of ∼60 ppm of atmospheric CO2. We find that the implementation of abrupt reductions in AMOC during Greenland stadials in the model setup that was previously used for the calculation of Marine20 leads to differences of less than ±100 14C yrs. The representation of AMOC changes therefore appears to be of minor importance for deriving non-polar mean ocean radiocarbon calibration products such as Marine20, where atmospheric carbon cycle variables are forced by reconstructions. However, simulated atmospheric CO2 exhibits minima during AMOC reductions in Heinrich stadials, in disagreement with ice core data. This mismatch supports previous suggestions that millennial-scale changes in CO2 were probably not driven directly by the AMOC, but rather by biological and physical processes in the Southern Ocean and by contributions from variable land carbon storage.

根据大气Δ14C 汇编 IntCal20 计算非极地表层海洋储层年龄(称为 Marine20)的碳循环模式,迄今为止忽略了与热双极跷跷板有关的千年尺度变率的一个关键方面:与 Dansgaard/Oeschger 和 Heinrich 事件有关的大西洋经向翻转环流(AMOC)强度的变化。在此,我们在碳循环箱模型 BICYCLE-SE 中实现了这种 AMOC 变化,以研究过去 55 千年的模型性能如何受到影响,特别是与可用的 14C 和 CO2 数据有关的影响。深海 14C 数据的约束表明,模型中海因里希期 1 的 AMOC 需要大幅减少甚至完全关闭。海洋环流和海冰覆盖是几乎可以完全解释深海 14C 年龄模拟变化的过程,这些过程也是冰川期大气 CO2 减少 60 ppm 的原因。我们发现,在以前用于计算 Marine20 的模型设置中,格陵兰岛间歇期 AMOC 的突然减少导致的 14C 年龄差异小于 ±100 年。因此,AMOC 变化的表示对于得出 Marine20 等非极地平均海洋放射性碳校准产品似乎并不重要,因为大气碳循环变量是由重建强迫产生的。然而,模拟大气中的二氧化碳在海因里希海平面下降期间呈现出最小值,这与冰芯数据不符。这种不匹配支持了之前的建议,即千年尺度的二氧化碳变化很可能不是由 AMOC 直接驱动的,而是由南大洋的生物和物理过程以及可变陆地碳储量贡献的。
{"title":"Simulated radiocarbon cycle revisited by considering the bipolar seesaw and benthic 14C data","authors":"Peter Köhler ,&nbsp;Luke C. Skinner ,&nbsp;Florian Adolphi","doi":"10.1016/j.epsl.2024.118801","DOIUrl":"https://doi.org/10.1016/j.epsl.2024.118801","url":null,"abstract":"<div><p>Carbon cycle models used to calculate the marine reservoir age of the non-polar surface ocean (called Marine20) out of IntCal20, the compilation of atmospheric <span><math><msup><mrow><mi>Δ</mi></mrow><mrow><mn>14</mn></mrow></msup></math></span>C, have so far neglected a key aspect of the millennial-scale variability connected with the thermal bipolar seesaw: changes in the strength of the Atlantic meridional overturning circulation (AMOC) related to Dansgaard/Oeschger and Heinrich events. Here we implement such AMOC changes in the carbon cycle box model BICYCLE-SE to investigate how model performance over the last 55 kyr is affected, in particular with respect to available <sup>14</sup>C and CO<sub>2</sub> data. Constraints from deep ocean <sup>14</sup>C data suggest that the AMOC in the model during Heinrich stadial 1 needs to be highly reduced or even completely shutdown. Ocean circulation and sea ice coverage combined are the processes that almost completely explain the simulated changes in deep ocean <sup>14</sup>C age, and these are also responsible for a glacial drawdown of ∼60 ppm of atmospheric CO<sub>2</sub>. We find that the implementation of abrupt reductions in AMOC during Greenland stadials in the model setup that was previously used for the calculation of Marine20 leads to differences of less than ±100 <sup>14</sup>C yrs. The representation of AMOC changes therefore appears to be of minor importance for deriving non-polar mean ocean radiocarbon calibration products such as Marine20, where atmospheric carbon cycle variables are forced by reconstructions. However, simulated atmospheric CO<sub>2</sub> exhibits minima during AMOC reductions in Heinrich stadials, in disagreement with ice core data. This mismatch supports previous suggestions that millennial-scale changes in CO<sub>2</sub> were probably not driven directly by the AMOC, but rather by biological and physical processes in the Southern Ocean and by contributions from variable land carbon storage.</p></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0012821X24002346/pdfft?md5=02e7f6decab49d3433b42b2126685fb7&pid=1-s2.0-S0012821X24002346-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141244461","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-resolution mapping of the mantle transition zone and its interaction with subducted slabs in the Ibero-Maghrebian region 伊比利亚-马格里布地区地幔过渡带及其与俯冲板块相互作用的高分辨率绘图
IF 5.3 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-05-30 DOI: 10.1016/j.epsl.2024.118798
J.A. Parera-Portell , F.d.L. Mancilla , J. Morales , J. Díaz

The mantle transition zone (MTZ) beneath Iberia and NW Maghreb has been precisely mapped using more than 56000 high-quality P-wave receiver functions calculated from the data collected by permanent seismic networks and multiple temporary deployments in the region. Three-dimensional depth migration using both regional and global tomographic models has allowed us to obtain robust and continuous measurements of the MTZ thickness and the depth of the 410 and 660 discontinuities. We found the MTZ thickened by as much as

in the Mediterranean coast due to the effect of the cold Gibraltar-Alboran and Alpine-Tethys slabs. Coinciding with expected water-enriched MTZ areas near the subducted slabs there is evidence for partial melting atop the 410 in at least three low-velocity layers (LVL). Partial melting is also likely in a LVL in the uppermost lower mantle under the Alpine-Tethys slab, while we attribute other intra-MTZ LVL to increased mineralogical heterogeneity. We link a thinning of the MTZ at the rear of the Gibraltar-Alboran slab to mantle upwelling, and a band of depressed 410 along its southern boundary as an area of hot toroidal flow. A discontinuous region of depressed 410 following the Atlas Mountains also supports mantle upwelling beneath this range. Areas with LVL atop a depressed 410 discontinuity correlate well with active intraplate volcanism, suggesting a possible MTZ source. We also found that deep-focus seismicity occurs where the 660 discontinuity starts to deepen at the westernmost edge of the Gibraltar-Alboran slab.

伊比利亚和西北马格里布地下的地幔过渡带(MTZ)是利用该地区永久性地震网络和多个临时部署收集的数据计算出的 56000 多个高质量 P 波接收函数精确绘制的。利用区域和全球层析模型进行的三维深度迁移使我们能够获得 MTZ 厚度以及 410 和 660 不连续面深度的可靠、连续测量结果。我们发现,由于寒冷的直布罗陀-阿尔伯拉斯板块和阿尔卑斯-特提斯板块的影响,MTZ 的厚度与地中海沿岸一样厚。与俯冲板块附近预期的富水MTZ区域相吻合的是,至少有三个低速层(LVL)的410顶部存在部分熔融的证据。在阿尔卑斯-特提斯板块下最上层下地幔的低速层中也可能存在部分熔融现象,而我们将其他板块内的低速层归因于矿物异质性的增加。我们将直布罗陀-阿尔伯兰板块后部的MTZ变薄与地幔上涌联系起来,并将其南部边界的410凹陷带作为热环流区域。沿阿特拉斯山脉的不连续 410 凹陷区域也支持该山脉下的地幔上升流。在凹陷的 410 不连续区域顶部的低纬度层与板内活跃的火山活动密切相关,这表明可能存在 MTZ 来源。我们还发现,在直布罗陀-阿尔博兰板块最西边的 660 不连续面开始加深的地方,出现了深焦距地震。
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引用次数: 0
Garnet fracturing reveals ancient unstable slip events hosted in plate interface metasediments 石榴石断裂揭示了板块界面基岩中蕴藏的古代不稳定滑动事件
IF 5.3 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-05-29 DOI: 10.1016/j.epsl.2024.118794
Samuel Angiboust , Paraskevi Io Ioannidi , Iskander Muldashev

A paradox exists between the great number of intermediate-depth earthquakes occurring along active subduction interfaces worldwide and the extreme scarcity of paleo-seismic events recorded in exhumed metasediments from ancient subducted slabs. Recrystallization associated with exhumation-related overprinting generally contributes to the nearly-complete erasing of markers of unstable slip events in metamorphic rocks. We herein focus on a sample from an ancient deep thrust from a Cretaceous High-Pressure paleo-accretionary complex in Chilean Patagonia. A representative, moderately foliated micaschist exhibits broken garnet crystals that host a dense network of healed micro-fractures. While garnet fragments appear thoroughly disaggregated along the main foliation, the rock matrix that completely recrystallized has lost the record of brittle deformation. We employ a 2D visco-elasto-plastic numerical modelling approach in order to investigate the mechanical conditions that enable the fracturing of isolated garnet grains in a relatively weak matrix. The rupture of these stiff grains is achieved in our models at strain rates faster than 10−10 /s to 10−12 /s for elevated pore fluid pressures (80 to 99 % of the lithostatic value, respectively). Since high pore fluid pressures prevail in deep subduction interface settings, it is suggested that the rupture of these garnet crystals occurred through cataclastic deformation via (transient) slip rate acceleration, perhaps as a consequence of localized slip associated with slow to conventional earthquakes. Upon slip rate deceleration, viscous disaggregation of the broken garnet clasts occurred along with the erasing of the matrix cataclastic fabric.

在全球范围内,沿着活跃的俯冲界面发生了大量的中深层地震,而在从古代俯冲板块中掘出的变质岩中所记录的古地震事件却极为稀少,这两者之间存在着矛盾。变质岩中不稳定滑动事件的标志物几乎被完全抹去,这通常是与掘出相关的叠加作用有关的再结晶作用造成的。在此,我们重点研究了来自智利巴塔哥尼亚白垩纪高压古沉积复合体的一个古老深冲的样品。一个具有代表性的中度叶理微岩表现出破碎的石榴石晶体,其上有密集的愈合微裂隙网络。虽然石榴石碎片沿着主折线彻底解离,但完全重结晶的岩石基质已经失去了脆性变形的记录。我们采用二维粘弹性数值建模方法,研究在相对较弱的基质中,使孤立的石榴石颗粒发生断裂的力学条件。在我们的模型中,当孔隙流体压力升高(分别为岩性值的 80% 至 99%)时,这些坚硬颗粒的断裂是在应变速率快于 10-10 /s 至 10-12 /s 的条件下实现的。由于在深俯冲界面环境中普遍存在高孔隙流体压力,因此这些石榴石晶体的破裂是通过(瞬时)滑动速率加速的弹塑性变形发生的,这可能是与缓慢至常规地震相关的局部滑动的结果。滑动速度减慢后,破碎的石榴石碎屑发生粘性解离,同时基质弹塑性结构也被抹去。
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引用次数: 0
New U-Pb zircon tuff ages and revised stratigraphic correlations in the Superior craton during the Great Oxidation Episode 大氧化作用期间苏必利尔克拉通的新U-Pb锆凝灰岩年龄和修订的地层相关性
IF 5.3 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-05-29 DOI: 10.1016/j.epsl.2024.118779
Birger Rasmussen , Jian-wei Zi , Andrey Bekker

Major environmental changes during the Great Oxidation Episode are recorded in 2.5–2.0 Ga sedimentary successions across the world. In North America, the Huronian Supergroup is the most complete succession, preserving three glacial intervals with possible equivalents in the Lake Superior region. The third and youngest glacial unit (Gowganda Formation, Cobalt Group) of the Huronian Supergroup has been correlated with glacial deposits of the Chocolay Group in the Lake Superior region. Here we present the results of in situ SHRIMP U-Pb geochronology of zircon in thin tuff layers from the basal Wewe Slate, Chocolay Group, from drill-core in the Marquette Range area, upper Michigan. Zircon U-Pb data from two intervals ∼16 m apart yielded weighted mean 207Pb/206Pb ages of 2174 ± 9 Ma and 2172 ± 6 Ma, which define the depositional ages of the Wewe Slate and the conformably underlying Kona Dolomite. In the Huronian Supergroup, SHRIMP U-Pb dating of zircon in a tuff bed from the Gordon Lake Formation, Cobalt Group, yielded a weighted mean 207Pb/206Pb age of 2318 ± 8 Ma, interpreted to be the age of deposition. Re-examination of previously published U-Pb zircon data from the Gordon Lake Formation (Rasmussen et al., 2013) yields a slightly older weighted mean 207Pb/206Pb age of 2310 ± 5 Ma. Our results show that the Wewe Slate, and probably the Kona Dolomite, are ∼150 million years younger than the ∼2.32 Ga Gordon Lake Formation, with which they were previously correlated. Our results suggest that the glacial deposits in the Lake Superior region represent a fourth Paleoproterozoic glaciation in North America, whose age range corresponds to that of the fourth and final early Paleoproterozoic glaciation in southern Africa. We propose that the Chocolay Group was deposited after the Huronian Supergroup and is broadly coeval with the rift-passive margin succession (Cycle 1 of the Kaniapiskau Supergroup) in the New Québec Orogen, Canada, whose deposition has been linked to rifting and breakup along the eastern margin of the Superior craton at ∼2.22 Ga.

世界各地的 2.5-2.0 Ga 沉积演替记录了大氧化期的主要环境变化。在北美洲,休伦超群是最完整的演替,保留了三个冰川期,苏必利尔湖地区可能也有类似的冰川期。休伦超群的第三个也是最年轻的冰川单元(高干达层,科博尔特组)已与苏必利尔湖地区的乔克雷组冰川沉积物相关联。在此,我们介绍了对密歇根州上马奎特山脉地区钻芯中的 Chocolay 组基底 Wewe 板岩薄凝灰岩层中的锆石进行原位 SHRIMP U-Pb 地质年代测定的结果。相距 16 米的两个区间的锆石 U-Pb 数据得出的加权平均 Pb/Pb 年龄分别为 2174 ± 9 Ma 和 2172 ± 6 Ma,从而确定了 Wewe 板岩和下伏科纳白云岩的沉积年龄。在休伦超群中,对来自戈登湖地层、钴群的凝灰岩床中的锆石进行了 SHRIMP U-Pb 测定,得出的加权平均 Pb/Pb 年龄为 2318 ± 8 Ma,被解释为沉积年龄。-对以前发表的戈登湖地层的 U-Pb 锆石数据(Rasmussen 等人,2013 年)进行检验,得出的加权平均 Pb/Pb 年龄为 2310 ± 5 Ma,略早于此年龄。我们的研究结果表明,Wewe板岩以及科纳白云岩可能比之前与之相关的2.32 Ga的戈登湖地层年轻1.5亿年。我们的研究结果表明,苏必利尔湖地区的冰川沉积代表了北美洲古生代的第四次冰川作用,其年龄范围与非洲南部古生代早期第四次也是最后一次冰川作用的年龄范围一致。我们认为 Chocolay 组沉积于休伦超群之后,与加拿大新魁北克造山带的裂谷-被动边缘演替(Kaniapiskau 超群的第 1 周期)大致同时期,其沉积与 2.22 Ga ∼ 2.22 Ga 时苏必利尔陨石坑东缘的裂谷和断裂有关。
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引用次数: 0
Thermodynamic modelling and chronometric dating of melting and refertilization in the subcontinental lithospheric mantle 次大陆岩石圈地幔熔化和再肥化的热力学模型和年代测定法
IF 5.3 1区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2024-05-29 DOI: 10.1016/j.epsl.2024.118793
Yujian Wang, Jingao Liu

Geochemically distinguishing the products of melt depletion from refertilization and constraining the timing of such mantle-melt interactions in the subcontinental lithosphere (SCLM) remain outstanding research issues. Here we utilize alphaMELTS thermodynamic modeling of both partial melting and refertilization to revisit the origins of the Lherz mantle rocks from the Pyrenean orogenic mantle massifs. Thermodynamic modeling reveals subtle but critical differences between refertilization (i.e., elevated TiO2/Al2O3 and higher HREE in both whole rocks and clinopyroxenes) and partial melting processes. Harzburgites from the Lherz massif comprise predominantly pristine residues of partial melting and subordinately refertilized products with low melt/rock ratios. The Lherz lherzolites that show close spatial associations with olivine websterite layers represent secondary rocks, derived from refertilization involving the pristine, refractory harzburgites and upwelling N-MORB-like melts. Lherzolites with no intimate spatial association to olivine websterites are open to an additional origin, i.e., via stationary cooling at the base of lithosphere after moderate adiabatic upwelling of asthenospheric mantle. The Re-depletion model ages (TRD) of refractory harzburgites yield a systematic peak melting age of 2.0 Ga. We have developed a novel solution for constraining the relatively ancient age of refertilization (∼ 1.5 – 2.0 Ga) through the approach of an adapted percolation model to assess the behavior of Re-Os and Lu-Hf isotopic systems. Together with a comprehensive dataset of global on- and off-cratonic SCLM, this study has successfully distinguished silicate-melt induced refertilization from partial melting on elemental level, demonstrated the contribution of different melting mechanisms to the distinctive SCLM compositional evolution in the history, and highlighted how profound a role that refertilization has played on the variations of geochemical buoyancy and mechanical robustness and eventually on the stability and longevity of the ancient SCLM.

从地球化学角度区分熔体耗竭和再充填的产物,并确定次大陆岩石圈(SCLM)中这种地幔-熔体相互作用的时间,仍然是悬而未决的研究课题。在这里,我们利用 alphaMELTS 对部分熔融和再肥化的热力学建模,重新审视了比利牛斯造山地幔丘陵的勒尔兹地幔岩的起源。热力学建模揭示了再富集(即整块岩石和clinopyroxenes中的TiO2/Al2O3和HREE含量升高)和部分熔融过程之间微妙而关键的差异。来自勒尔茨山丘的哈兹博格岩主要由部分熔融的原始残留物和熔体/岩石比率较低的次级再肥化产物组成。与橄榄石菱锰矿层在空间上有密切联系的勒尔兹沸石是次生岩石,由原始的难熔哈兹堡垒岩和上涌的 N-MORB 类熔体再充填而成。与橄榄石网状岩没有密切空间联系的海尔兹堡岩有可能是另一种起源,即通过岩石圈底部的静止冷却,在天体层地幔适度绝热上涌之后形成的。难熔哈兹堡垒岩的再损耗模型年龄(TRD)得出的系统峰值熔融年龄为 2.0 Ga。我们开发了一种新的解决方案,通过评估Re-Os和Lu-Hf同位素系统的行为,采用一种经过调整的渗滤模型来制约相对较早的再增殖年龄(∼ 1.5 - 2.0 Ga)。该研究结合全球弧上和弧下SCLM的综合数据集,成功地区分了硅酸盐熔融诱导的再热化和元素层面的部分熔融,证明了不同熔融机制对历史上SCLM成分演化的独特贡献,并强调了再热化对地球化学浮力和力学稳健性的变化,以及最终对古SCLM的稳定性和寿命所起的深远作用。
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引用次数: 0
期刊
Earth and Planetary Science Letters
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