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Rubidium isotopes reveal dehydration and melting of the subducting slab beneath the Mariana arc 铷同位素揭示了马里亚纳弧下俯冲板块的脱水和熔化过程
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-17 DOI: 10.1016/j.epsl.2024.118978
<div><p>Rubidium (Rb) is a strongly incompatible and highly fluid-mobile element and Rb isotopes have the potential to track subducted material recycling to the mantle source of arc magmas. However, the behavior of Rb isotopes during slab subduction and associated processes remains unconstrained. This study for the first time presents Rb isotope data for the altered oceanic crust (AOC) from IODP Site U1365, subducted sediments, and lavas from the Southern Mariana arc. The δ<sup>87</sup>Rb of the AOC varies between –0.16 ± 0.03 ‰ to 0.07 ± 0.02 ‰ with a weighted average of –0.02 ± 0.06 ‰, which is higher than that of fresh mid-ocean ridge basalts (MORB; –0.12 ± 0.08 ‰). Such Rb isotope fractionation may be attributed to the preferential loss of <sup>85</sup>Rb into seawater during the dissolution of primary phases and the preferential structural incorporation of <sup>87</sup>Rb into secondary phases and preferential <sup>87</sup>Rb adsorption by clays. The δ<sup>87</sup>Rb of the sediments varies from –0.20 ± 0.07 ‰ to –0.03 ± 0.02 ‰ with an average of –0.11 ± 0.12 ‰, identical to that of the upper continental crust (UCC; –0.14 ± 0.08 ‰). The correlations observed between δ<sup>87</sup>Rb and sediment depth (and loss on ignition; LOI) suggest that hydrodynamic sorting of sediments which enriches the upper stratigraphic intervals in clays, exerts a first-order control on the Rb isotope fractionation in subducted sediments. The formation of authigenic clays, which act as a sink of <sup>85</sup>Rb from seawater, could partially account for the elevated δ<sup>87</sup>Rb of seawater (0.14 ± 0.12 ‰) relative to the Bulk Silicate Earth (BSE; –0.12 ± 0.06 ‰). For the Mariana lavas, the δ<sup>87</sup>Rb decreases from fore-arc lavas (–0.03 ± 0.04 ‰ to 0.09 ± 0.02 ‰) to frontal arc lavas (–0.12 ± 0.04 ‰ to –0.01 ± 0.03 ‰), which are all higher than the average δ<sup>87</sup>Rb of fresh MORB (–0.12 ± 0.08 ‰). The elevated δ<sup>87</sup>Rb of the lavas reflects the addition of AOC-derived aqueous fluids with a high δ<sup>87</sup>Rb (∼0.08 ‰) to the magma source, which is higher than the average δ<sup>87</sup>Rb (–0.02 ± 0.18 ‰) of the Site-1365 AOC. The variation of δ<sup>87</sup>Rb with <sup>143</sup>Nd/<sup>144</sup>Nd<sub>i</sub> values of the lavas indicates that AOC-derived aqueous fluids are increasingly mixed with a component with a low δ<sup>87</sup>Rb that most likely represents sediment melts. The estimated δ<sup>87</sup>Rb of sediment melts is about –0.27 ‰, lower than the average δ<sup>87</sup>Rb (–0.11 ± 0.12 ‰) of the Mariana sediments. Thus, our study suggests that Rb isotopes can be fractionated during AOC dehydration and sediment partial melting. Overall, the across-arc Rb isotope variation reflects slab dehydration and melting at different subduction depths. Our findings demonstrate that Rb isotopes are a powerful novel tool for probing deep recycling of subducted slabs. Furthermore, they can distinguish contributions from AOC-derived fluids
铷(Rb)是一种强烈不相容和高度流体流动的元素,铷同位素具有追踪俯冲物质循环到弧岩浆地幔源的潜力。然而,Rb同位素在板块俯冲和相关过程中的行为仍未受到制约。本研究首次展示了来自IODP U1365站点的蚀变洋壳(AOC)、俯冲沉积物和南马里亚纳弧的熔岩的铷同位素数据。AOC的δ87Rb介于-0.16 ± 0.03 ‰至0.07 ± 0.02 ‰之间,加权平均值为-0.02 ± 0.06 ‰,高于新鲜洋中脊玄武岩(MORB;-0.12 ± 0.08 ‰)的δ87Rb。这种 Rb 同位素分馏可能是由于 85Rb 在原生相溶解过程中优先流失到海水中,87Rb 在结构上优先融入次生相,以及 87Rb 优先被粘土吸附。沉积物的δ87Rb在-0.20±0.07‰到-0.03±0.02‰之间变化,平均为-0.11±0.12‰,与上大陆地壳(UCC;-0.14±0.08‰)的δ87Rb相同。观察到的δ87Rb与沉积深度(和点火损失率;LOI)之间的相关性表明,沉积物的水动力分选使上部地层间富含粘土,对俯冲沉积物中的Rb同位素分馏产生了一阶控制作用。自生粘土的形成是海水中 85Rb 的吸收汇,可以部分解释海水δ87Rb(0.14 ± 0.12 ‰)相对于块状硅酸盐土(BSE;-0.12 ± 0.06 ‰)的升高。就马里亚纳熔岩而言,δ87Rb从前弧熔岩(-0.03 ± 0.04 ‰到 0.09 ± 0.02 ‰)到前弧熔岩(-0.12 ± 0.04 ‰到-0.01 ± 0.03 ‰)都在下降,均高于新鲜MORB的平均δ87Rb(-0.12 ± 0.08 ‰)。熔岩δ87Rb的升高反映了岩浆源中加入了δ87Rb较高(∼0.08 ‰)的AOC衍生水流,高于Site-1365 AOC的平均δ87Rb(-0.02 ± 0.18 ‰)。δ87Rb与熔岩的143Nd/144Ndi值的变化表明,AOC衍生的水流体越来越多地与低δ87Rb的成分混合在一起,而后者很可能是沉积熔融物。据估计,沉积熔融物的δ87Rb约为-0.27‰,低于马里亚纳沉积物的平均δ87Rb(-0.11 ± 0.12‰)。因此,我们的研究表明,Rb同位素可在AOC脱水和沉积物部分融化过程中分馏。总体而言,跨弧Rb同位素的变化反映了不同俯冲深度的板块脱水和熔融。我们的研究结果表明,Rb同位素是探测俯冲板块深部循环的一个强大的新工具。此外,它们还可以区分弧长岩浆来源于弧长岩浆流体还是沉积物来源于弧长岩浆熔体。
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引用次数: 0
The very late-stage crystallization of the lunar magma ocean and the composition of immiscible urKREEP 月球岩浆海洋的极晚期结晶和不溶性铀矿石的成分
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-16 DOI: 10.1016/j.epsl.2024.118989

The latest stages of the lunar magma ocean (LMO) crystallization led to the formation of ilmenite-bearing cumulates and urKREEP, residual melts enriched in K, rare earth elements (REEs), P, and other incompatible elements. Those highly evolved lithologies had major impacts on the petrogenesis of lunar volcanic rocks and the compositional diversity of post-LMO magmatism resulting from mantle remelting. Here, we present new experimental results constraining the composition of the very last liquids produced during LMO crystallization. To test the potential role of silicate liquid immiscibility in the formation of urKREEP, synthetic samples representative of residual melts of bulk Moon compositions were placed in double platinum-graphite capsules at 1020–980 °C and 0.08–0.10 GPa in an internally-heated pressure vessel. The produced silicate liquids are multiply saturated with plagioclase, augite, silica phases, and ilmenite (± fayalitic olivine ± pigeonite). Our experiments show that the liquid line of descent reaches a two-liquid field at 1000 °C and >97% crystallization for a range of whole-Moon compositions. Under these conditions, a small proportion of silica-rich melt (70.0–71.4 wt.% SiO2, 6.4–7.3 wt.% FeO, 5.4–6.1 wt.% K2O, 0.2–0.3 wt.% P2O5) coexists within an abundant Fe-rich melt (42.6–44.1 wt.% SiO2, 27.6–28.8 wt.% FeO, 0.9–1.0 wt.% K2O, 2.8–3.2 wt.% P2O5) with sharp two-liquid interfaces. Our experimental results also constrain the relative onset of ilmenite crystallization compared to the development of immiscibility and indicate that an ilmenite-bearing layer formed in the lunar interior before immiscibility was attained. Using a self-consistent physicochemical LMO model, we constrain the thickness and depth of the ilmenite-bearing layer during LMO differentiation. The immiscible K-Si-rich and P-Fe-rich melts together also produced an immiscible urKREEP layer ∼2–6 km thick and ∼30–50 km deep depending on the trapped liquid fraction in the cumulate column (≤10%) and the thickness of the buoyant anorthosite crust (30–50 km). We provide constraints on the relationship between the compositions of immiscible urKREEP melts and those of KREEPy rocks. By modeling the mixing of KREEP-poor basalt and the immiscible melt pairs, we reproduce the K and P enrichments and apparent decoupling of K from P in KREEPy rocks. Our results highlight that processes such as the assimilation of evolved heterogeneous mantle lithologies may be involved in hybridization during post-LMO magmatism. The immiscible K-Si-rich lithology may also have contributed to lunar silicic magmatism.

月球岩浆洋(LMO)结晶的最后阶段形成了含钛铁矿的积岩和富含钾、稀土元素(REEs)、钾和其他不相容元素的残余熔体(urKREEP)。这些高度演化的岩性对月球火山岩的岩石成因以及地幔重熔产生的后LMO岩浆活动的成分多样性产生了重大影响。在这里,我们展示了新的实验结果,对LMO结晶过程中产生的最后一种液体的成分进行了约束。为了测试硅酸盐液体不溶性在urKREEP形成过程中的潜在作用,我们将代表月球主体成分的残余熔体的合成样品置于双铂-石墨胶囊中,在1020-980 °C和0.08-0.10 GPa条件下置于内部加热的压力容器中。生成的硅酸盐液体中含有多重饱和斜长石、辉石、硅石相和钛铁矿(± 辉橄榄石± 白榴石)。我们的实验表明,对于一系列全月成分,液态下降线在 1000 °C 和 97% 的结晶度时达到双液态场。在这些条件下,一小部分富含二氧化硅的熔体(70.0-71.4 wt.% SiO2、6.4-7.3 wt.% FeO、5.4-6.1 wt.% K2O、0.2-0.3 wt.%的 P2O5)共存于丰富的富铁熔体(42.6-44.1 wt.% SiO2、27.6-28.8 wt.% FeO、0.9-1.0 wt.% K2O、2.8-3.2 wt.% P2O5)中,具有尖锐的双液界面。我们的实验结果还确定了钛铁矿结晶的相对起始时间与不溶性的发展时间,并表明月球内部在达到不溶性之前形成了含钛铁矿层。利用自洽的物理化学 LMO 模型,我们确定了 LMO 分化过程中含钛铁矿层的厚度和深度。富含K-Si和P-Fe的不互溶熔体还产生了一个厚度为2-6千米、深度为30-50千米的不互溶urKREEP层,其厚度和深度取决于积液柱中的截留液比例(≤10%)和浮力正长岩壳的厚度(30-50千米)。我们提供了不相溶的 urKREEP 熔体成分与 KREEPy 岩石成分之间关系的约束条件。通过模拟贫KREEP玄武岩与不互溶熔体对的混合,我们再现了KREEPy岩石中K和P的富集以及K与P的明显脱钩。我们的研究结果突出表明,在后LMO岩浆作用过程中,同化演化的异质地幔岩性等过程可能参与了杂化作用。富含K-Si的不互溶岩性也可能促成了月球硅质岩浆活动。
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引用次数: 0
Insights into the last 100 ky of geomagnetic field variability using numerical dynamo simulations 利用数值动力模拟洞察地磁场最近 100 千年的变化
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-16 DOI: 10.1016/j.epsl.2024.119011

Recent observational models of the paleomagnetic field have revealed new details about geomagnetic field variability, which have yet to be adequately explored in numerical dynamo simulations. Here we present results from a new suite of dynamo simulations with computationally accessible rotating rates and diffusivities, an Earth-like magnetic Reynolds number, and a force balance that is consistent with the expected regime of the geodynamo, allowing comparison of simulated data and observational models. We find that such simulations are able to simultaneously reproduce the observed extreme rates of change in intensity and direction as well as the general amplitude of field variability over the last 100 ky, if the mean dipolarity is in the range 0.4-0.5. We use the paleosecular variation (PSV) index to identify a broad spectrum of polarity excursions and show that the PSV index is closely linked to the dipolarity of the simulation. Simulated excursional events are mostly associated with a decrease in the axial dipole moment with generally modest changes in dipole tilt. The excursions range from global events characterised by a reduction in the field contribution from solely the axial dipole component and a decrease in mean VDM in the manner of the Laschamp excursion, to localised events with anomalous activity in small regions reminiscent of the Mono Lake/Auckland excursion. Global events are generally longer than regional excursions, and reflect a drop in the total magnetic energy of the dynamo.

最近的古磁场观测模型揭示了地磁场变异性的新细节,而这些细节尚未在动力学数值模拟中得到充分探索。在这里,我们展示了一套新的动力模拟结果,它具有可计算的旋转率和扩散率、类似地球的磁雷诺数,以及与预期地球动力机制相一致的力平衡,从而可以对模拟数据和观测模型进行比较。我们发现,如果平均偶极性在 0.4-0.5 范围内,这种模拟能够同时再现观测到的强度和方向的极端变化率,以及过去 100 ky 内磁场变化的总体振幅。我们利用古地球变异指数(PSV)来确定极性偏移的广泛范围,并表明 PSV 指数与模拟的偶极性密切相关。模拟的极性偏移事件大多与轴向偶极矩的减小有关,偶极倾角的变化一般不大。偏移的范围很广,既有全球性事件,其特点是轴向偶极子分量的场贡献减少,平均 VDM 下降,与拉斯汉普偏移类似;也有局部事件,其特点是小区域异常活动,与莫诺湖/奥克兰偏移类似。全球性事件一般比区域性偏移持续时间长,反映了动力总磁能的下降。
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引用次数: 0
Rise of mantle oxidation by Neoarchean subduction in the North China Craton 华北克拉通新元古代俯冲造成的地幔氧化作用的兴起
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-14 DOI: 10.1016/j.epsl.2024.119006

The Archean mantle redox state played an important role in degassing of the Earth's interior and thus influenced atmospheric oxygen levels of the early Earth. But it is unclear if any parts of the uppermost mantle were significantly oxidized by a certain point in the Archean. Here, we investigate oxygen fugacity (fO2) of Archean (> 2535–2517 Ma) peridotites in the North China Craton. Petrology and geochemistry reveal that they experienced strong Neoarchean subduction-related metasomatism. These Neoarchean subduction-metasomatized peridotites record fO2 of ΔFMQ +1.3 ± 0.4 (SD) [relative to the fayalite-magnetite-quartz (FMQ) buffer], which are more oxidized than the Archean ambient mantle, but similar to the modern sub-arc mantle. We propose that this Neoarchean rise of mantle oxidation in the North China Craton was induced by plate subduction, during which the Neoarchean sub-arc mantle in the North China Craton could have been metasomatized and oxidized, and its oxygen fugacity was increased. This process may have had connections with the Great Oxidation Event in the Early Proterozoic.

阿基坦地幔氧化还原状态在地球内部脱气过程中发挥了重要作用,从而影响了早期地球大气中的氧含量。但是,目前还不清楚最上层地幔是否有任何部分在阿基坦时期的某一时刻被严重氧化。在此,我们研究了华北克拉通地区阿寒纪(> 2535-2517 Ma)橄榄岩的氧富集度(fO2)。岩石学和地球化学揭示了它们经历了强烈的新元古代俯冲变质作用。这些新元古代俯冲变质橄榄岩记录的fO2为ΔFMQ +1.3±0.4(标度)[相对于辉绿岩-磁铁矿-石英(FMQ)缓冲区],其氧化程度高于Archean环境地幔,但与现代弧下地幔相似。我们认为,华北克拉通新元古代地幔氧化程度的上升是由板块俯冲引起的,在这一过程中,华北克拉通新元古代弧下地幔可能发生了变质和氧化,其氧富集度有所增加。这一过程可能与早新生代的大氧化事件有关。
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引用次数: 0
Eoarchean granulite-facies metamorphism in the Itsaq Gneiss Complex, southwest Greenland 格陵兰西南部伊萨格片麻岩群的始新世花岗岩层变质作用
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-14 DOI: 10.1016/j.epsl.2024.118977

Using petrography, in situ garnet Lu–Hf geochronology, garnet rare-earth element (REE) analysis, zircon U–Pb geochronology and phase equilibrium modelling, we provide unambiguous evidence for Eoarchean granulite-facies metamorphism in the northern Itsaq Gneiss Complex (IGC), southwest Greenland. In situ garnet Lu–Hf geochronology from two samples of variably migmatitic metabasic rocks least affected by subsequent (Neoarchean) reworking yield Lu–Hf isochron ages of 3641 ± 62 Ma (MSWD = 1.7, n = 45/67; all age uncertainties at 2σ level) and 3652 ± 69 Ma (MSWD = 1.8, n = 83/84) from garnet with REE patterns typical of single-stage prograde growth. From the same two samples, zircon grains with textures consistent with metamorphic growth give weighted-mean 207Pb/206Pb ages of 3620 ± 8 Ma (MSWD = 1.2, n = 45) and 3630 ± 8 Ma (MSWD = 0.6, n = 44), respectively. Phase equilibrium modelling constrains peak P–T conditions of Eoarchean (3640–3630 Ma) metamorphism to 8.3–9.0 kbar and 730–820 °C. The thermobaric ratios (T/P) of 800–1000 °C/GPa recorded by the investigated samples are considerably higher (warmer) than previously proposed for granulite-facies metamorphism in the northern IGC, and broadly similar to Archean metamorphic P–T data globally, with no evidence for the bimodality in T/P that characterizes younger metamorphism. Either subduction-driven metamorphism (and plate tectonics) did not operate in the Eoarchean, or the Eoarchean lithosphere had a rheology that prohibited exhumation of subducted rocks.

利用岩相学、原位石榴石lu-hf地质年代学、石榴石稀土元素(REE)分析、锆石U-Pb地质年代学和相平衡建模,我们为格陵兰西南部Itsaq片麻岩群(IGC)北部的新元古代花岗岩变质作用提供了明确的证据。从两个受后续(新元古代)再加工影响最小的变质玄武岩样品中提取的原位石榴石lu-hf地质年代为3641 ± 62 Ma(MSWD = 1.7,n = 45/67;所有年龄不确定性均为2σ级)和3652 ± 69 Ma(MSWD = 1.8,n = 83/84),石榴石的lu-hf等时线年龄具有典型的单级顺行生长的REE模式。在同样的两个样品中,质地与变质生长一致的锆石颗粒的加权平均 207Pb/206Pb 年龄分别为 3620 ± 8 Ma(MSWD = 1.2,n = 45)和 3630 ± 8 Ma(MSWD = 0.6,n = 44)。相平衡模型将新元古代(3640-3630 Ma)变质作用的峰值P-T条件约束为8.3-9.0 kbar和730-820 °C。调查样本记录的热压比(T/P)为800-1000 °C/GPa,比之前提出的北IGC地区花岗岩成因变质作用的热压比要高(更热)得多,与全球范围内的阿新世变质作用P-T数据大体相似,没有证据表明年轻变质作用的T/P具有双峰性。要么是俯冲驱动的变质作用(和板块构造作用)在始新世并不发生,要么是始新世岩石圈的流变性禁止了俯冲岩石的吐出。
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引用次数: 0
Low-velocity middle-and-lower crustal materials blocked by the red river fault in the SE margin of the Tibetan plateau 青藏高原东南缘红河断层阻挡的低速中下地壳物质
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-14 DOI: 10.1016/j.epsl.2024.118988

The ongoing collision between the Indian and Eurasian plates propels the eastward movement of the Tibetan plateau (TP), leading to substantial crustal deformation around the southern Sichuan-Yunnan block (SYB). Using ambient noise data from multiple temporary seismic arrays and permanent stations, we construct a high-resolution regional crustal azimuthally anisotropic Vs model in the SYB. Our new model reveals two significant low-velocity anomalies with strong azimuthal anisotropy near the block boundary faults in the middle-and-lower crust. The extensive low-velocity anomalies around the middle-south segment of the Xiaojiang Fault (XJF) possibly result from partial melting due to spontaneous deformation caused by crustal thickening and increased felsic components, as well as the superimposition of shear heating faults and local upwelling asthenosphere. The N‒S trending low-velocity anomaly at the northwest end of the Red River Fault (RRF) may be associated with weak material migration from the TP, potentially serving as a conduit for mantle upwelling. The azimuthal anisotropy along the block boundary faults exhibits spatial variations linked to segmented distortion resulting from southeastward crustal movement and various geological activities. A key finding is that the crustal channelized low-velocity along the XJF is clearly blocked by the RRF, instead of going through. Notably, the azimuthal anisotropy in the E‒W direction, observed above the Moho and at depths deeper than 30 km in the intersection end, implies the potential intrusion of localized mantle materials into the lower crust. Therefore, lithospheric deformation is significantly affected by block boundary faults and the properties of the crust and mantle.

印度板块和欧亚板块之间的持续碰撞推动了青藏高原(TP)的东移,导致四川-云南南部地块(SYB)地壳发生巨大变形。利用多个临时地震阵列和永久台站的环境噪声数据,我们构建了四川云南块体南部高分辨率区域地壳方位各向异性 Vs 模型。我们的新模型揭示了中下地壳块体边界断层附近两个具有强烈方位各向异性的重要低速异常。小江断层(XJF)中南段附近的大范围低速异常可能是由于地壳增厚和长英岩成分增加引起的自发变形导致的部分熔融,以及剪切加热断层和局部上涌的星体层叠加造成的。红河断层(RRF)西北端的N-S向低速异常可能与TP的弱物质迁移有关,有可能成为地幔上涌的通道。块体边界断层沿线的方位各向异性表现出空间变化,这与地壳向东南运动和各种地质活动造成的分段变形有关。一个重要发现是,沿XJF的地壳通道化低速明显受到RRF的阻挡,而不是穿过RRF。值得注意的是,在莫霍面以上和交汇端深度超过30公里处观察到的东西向方位各向异性,意味着局部地幔物质可能侵入下地壳。因此,岩石圈变形受到块体边界断层以及地壳和地幔性质的重大影响。
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引用次数: 0
Metasedimentary “carbon filter” and its implication for subduction zone carbon recycling 沉积岩 "碳过滤器 "及其对俯冲带碳循环的影响
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-13 DOI: 10.1016/j.epsl.2024.119007

The movement of carbon in subduction zones plays a crucial role in regulating the global carbon cycle, controlling Earth's climate, and maintaining its habitability. Recent work suggests that only a fraction of the carbon released from subducting slabs at sub-arc depths is ultimately released from volcanic arcs, necessitating the existence of hidden carbon reservoirs within the slab-to-arc pathways. However, the precise location of these reservoirs remains enigmatic. Slab fluid serves as the primary medium for carbon transport in subduction zones; thus, a comprehensive understanding of fluid-rock interaction during slab fluid migration is essential for reconciling the carbon flux imbalance between the slab and the arc. In this study, we explore rock carbonation along a fluid conduit in the Southwestern Tianshan HP metamorphic belt in northwest China. Field evidence and petrologic observation reveal significant carbonation of a siliciclastic metasediment at its contact with a high-pressure garnet-bearing calcite (formerly aragonite) vein. We find that rock carbonation (by progressive Fe-bearing magnesite, dolomite, then aragonite precipitation) occurred when slab-derived carbonic fluids migrated through the metasedimentary sequence at approximately 80 km depth. Furthermore, modeling demonstrates that the metasedimentary layer atop the slab has the capacity to sequester 20%–50% of the fluid carbon from the ascending slab devolatilization flux. We propose that the metasedimentary veneer at the plate interface functions as a “carbon filter”, hindering the transfer of carbon from the slab to the arc and helping to reconcile the carbon flux imbalance between the amount released by the slab and that emitted by the arc. This study also provides insights into decarbonation efficiency and mechanisms, carbon-transfer pathways, and temporal aspects of the subduction zone carbon cycle.

俯冲带的碳运动在调节全球碳循环、控制地球气候和维持地球宜居性方面起着至关重要的作用。最近的研究表明,从亚弧深俯冲板块释放的碳中只有一部分最终从火山弧释放出来,因此板块到火山弧的路径中必然存在隐藏的碳库。然而,这些储层的确切位置仍然是个谜。板块流体是俯冲带碳迁移的主要介质;因此,全面了解板块流体迁移过程中流体与岩石之间的相互作用对于协调板块与弧之间的碳通量失衡至关重要。在本研究中,我们探讨了中国西北部天山西南HP变质带流体通道沿线的岩石碳化现象。现场证据和岩石学观察显示,在硅质碎屑岩基岩与高压含石榴石的方解石(原文石)矿脉接触处,发生了显著的碳化现象。我们发现,岩石碳化(通过含铁菱镁矿、白云石,然后是文石的逐步沉淀)发生在板块衍生的碳酸流体流经大约 80 千米深的变质岩序列时。此外,建模表明,板坯顶部的变质岩层有能力封存来自上升板坯脱碳通量的20%-50%的流体碳。我们认为,板块界面上的沉积岩饰面具有 "碳过滤器 "的功能,它阻碍了碳从板块向弧的转移,并有助于调和板块释放量与弧释放量之间的碳通量失衡。这项研究还为俯冲带碳循环的脱碳效率和机制、碳转移途径和时间方面提供了见解。
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引用次数: 0
New weak fault model that does not require high pore pressure 无需高孔隙压力的新弱断层模型
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-13 DOI: 10.1016/j.epsl.2024.119003

We propose a new weak fault model in which isolated viscoelastic regions are distributed along the fault. Numerical simulations using the finite element method show that the viscoelastic regions relax and the shear stress supported by them is applied to surrounding elastic regions after a time sufficiently longer than their relaxation time, while the normal stress continues to be supported by the viscoelastic regions, and then the normal stress in the elastic regions remain unchanged. Since the shear stress is amplified but the normal stress remains unchanged in the elastic regions, a macroscopic weakening of the fault occurs even under a constant coefficient of friction. The fault can be weakened without assuming high pore pressure. As a result of examining the effect of the geometry of the viscoelastic regions on the fault strength by changing their shape and spatial distribution in various ways, we found that the fault strength decreases as the ratio of the area of the elastic regions remaining unrelaxed to the total area of the fault decreases. It is known that faults can be weakened by fault rocks such as clay minerals, but the frictional properties of these fault rocks are basically velocity strengthening, making it difficult to weaken seismic faults. The fault model in this study is a model for deformation characteristics of the host rock around a fault, which does not place any constraints on the frictional properties of the fault, and thus can weaken a seismic fault.

我们提出了一种新的弱断层模型,其中沿断层分布着孤立的粘弹性区域。利用有限元法进行的数值模拟表明,粘弹性区域会发生松弛,在松弛时间足够长之后,粘弹性区域支撑的剪应力会施加到周围的弹性区域,而法向应力则继续由粘弹性区域支撑,然后弹性区域的法向应力保持不变。由于剪应力被放大,但弹性区域的法向应力保持不变,因此即使在摩擦系数不变的情况下,断层也会发生宏观削弱。在不假设高孔隙压力的情况下,断层也会被削弱。我们通过改变粘弹性区域的形状和空间分布,研究了这些区域的几何形状对断层强度的影响,结果发现,随着未松弛的弹性区域面积与断层总面积之比减小,断层强度也随之减弱。众所周知,断层岩(如粘土矿物)可以削弱断层,但这些断层岩的摩擦特性基本上是速度强化,因此很难削弱地震断层。本研究中的断层模型是断层周围主岩变形特性的模型,对断层的摩擦特性没有任何约束,因此可以削弱地震断层。
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引用次数: 0
Seismicity zoning at Coso geothermal field and stress changes from fluid production and migration 科索地热田的地震区划以及流体生产和迁移引起的应力变化
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-13 DOI: 10.1016/j.epsl.2024.119000

The Coso geothermal field is a major geothermal power production site in the western United States. It has been observed that low-magnitude seismic events (M < 3.71) are unevenly distributed in three distinct zones, namely, nearfield (<3 km), midfield (3–6 km), and farfield (> 6 km) from the Coso geothermal plant. These zones exhibit distinct changes in earthquake location before and during geothermal production episodes that began in 1986. After 1986, the midfield region of the main flank experiences a significantly lower seismicity rate than the surrounding areas before production episodes. During 2014–2019, the farfield earthquakes cluster in the eastern and western parts of the greater Coso area, which is discernably different from how those pre-production earthquake events were distributed along the conjugate NW-SE and SW-NW trending structures across the main flank. Here, we analyze the stage of stress with finite-element-based poroelastic simulations to illustrate how the spatiotemporal evolution of the seismicity is associated with the pattern of stress perturbations caused by fluid migration amid the operations of geothermal power plants. Generally, ∼70% of co-production seismicity is found in zones of increased Coulomb stress between 2014 and 2019 at >99% confidence. Meanwhile, the midfield zone of seismic paucity overlaps with the zone of decreasing pore-fluid pressure. Overall, the results provide a physical explanation of how decadal geothermal operations at Coso have perturbed stress-field changes and contributed to the evolving characteristic seismic pattern, shedding insights into assessing the seismic hazard in other geothermal settings.

科索地热田是美国西部的一个主要地热发电站。据观察,低震级地震事件(M <3.71)不均匀地分布在三个不同的区域,即距离科索地热发电厂的近场(<3 千米)、中场(3-6 千米)和远场(>6 千米)。在 1986 年开始的地热生产活动之前和期间,这些区域的地震位置发生了明显变化。1986 年之后,主侧翼中场地区的地震率明显低于生产事件之前的周边地区。在 2014-2019 年期间,远场地震集中在大科索地区的东部和西部,这与生产前地震事件沿主翼 NW-SE 和 SW-NW 共轭结构的分布明显不同。在此,我们通过基于有限元的孔弹性模拟分析了应力阶段,以说明地震的时空演变如何与地热发电厂运行过程中流体迁移引起的应力扰动模式相关联。一般来说,在置信度为 99% 的情况下,2014 年至 2019 年期间,70% 的共产地震发生在库仑应力增加区。同时,中场地震贫乏区与孔隙流体压力下降区重叠。总之,研究结果提供了一个物理解释,说明了科索地热的十年运行如何扰动了应力场的变化,并促成了特征地震模式的演变,为评估其他地热环境中的地震危害提供了启示。
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引用次数: 0
Anomalously high relief on Denali, Alaska, caused by tectonic, lithologic, and climatic drivers 由构造、岩性和气候驱动因素造成的阿拉斯加德纳利异常高地势
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-13 DOI: 10.1016/j.epsl.2024.118999

We assess the growth of anomalously high relief on Denali, located in the Alaska Range, Alaska, and the tallest mountain in North America (6190 masl). Denali is 3000 m taller than most surrounding peaks. It lies inside a 19° restraining bend in the active Denali fault system that is moving at about 7 mm/yr, providing a tectonic and structural driver for ongoing rock uplift. High relief around Denali is also due, in part, to its granitic rock type and low fracture density relative to adjacent metasediments. Here we show that unique climatic conditions at high elevations also contribute to the growth of relief. We examine 10Be concentrations in 1) three new gravel samples between 3500 and 5200 m elevation from sites unaffected by recent glacial erosion, 2) previously published samples from a sidewall of the Kahiltna Glacier from 2400 to 2800 masl, 3) previously published data for samples collected from medial moraines along the length of the Kahiltna Glacier from ∼500 to 1400 masl, and 4) previously published data for alluvial samples collected along the Kahiltna River at an elevation of ∼200 masl. These samples constitute a transect extending >5000 vertical meters, and the data establish that erosion rates decrease with elevation and contribute to the growth of relief. Erosion rates for the three new high-elevation samples are calculated to 4.6 ± 0.6 mm/ka at 5200 masl, 28.6 ± 3.7 mm/ka at 4000 masl, and 38±5 mm/ka at 3500 masl. Erosion rates at intermediate elevations, on the sidewall of the Kahiltna Glacier, range between 160 and 327 mm/ka. Along the medial moraines inferred erosion rates range between 140 and 537 mm/ka, and basin-wide erosion rates calculated from sediments in the river below the glacier range between 450 and 896 mm/ka. These differences in erosion rates can create relief of 3 km within 1–10 Ma, well within the estimated period of increase in rock uplift and exhumation on Denali over the last ∼6 Ma. Meteorological data from 2130 to 5550 masl at 5 sites show temperatures rarely exceed freezing above 4000 masl elevation, indicating that frost weathering currently plays a diminished role in erosion at high elevations. The immediate implication of this temperature and erosional correlation is an increase in relief. This is the first study to directly measure a significant decrease in erosion rates at high elevations in the relative absence of frost weathering. The results highlight the combined influence of rock type, glacial erosion, and permanent sub-zero temperatures on erosion rates. In combination with active faulting, the data explain the resultant increase in relief along the southern side of the Alaska Range over the past 100 ka.

我们对位于阿拉斯加州阿拉斯加山脉、北美最高山峰(海拔 6190 米)德纳利峰的异常高地势增长进行了评估。迪纳利峰比周围大多数山峰高出 3000 米。它位于活跃的迪纳利断层系统中一个 19° 的限制性弯曲内,该断层系统以大约 7 毫米/年的速度移动,为持续的岩石隆起提供了构造和结构驱动力。迪纳利周围的高地势部分也是由于其花岗岩岩石类型和相对于邻近的玄武岩较低的断裂密度。在这里,我们展示了高海拔地区独特的气候条件也有助于地貌的增长。我们研究了以下样本中的 10Be 浓度:1)海拔 3500 米至 5200 米之间、未受近期冰川侵蚀影响的三个新的砾石样本;2)之前发表的、来自卡希尔特纳冰川侧壁 2400 米至 2800 米处的样本;3)之前发表的、来自卡希尔特纳冰川侧壁 2400 米至 2800 米处的样本、3) 此前公布的从卡希尔特纳冰川沿线海拔 500 至 1400 米的内侧冰碛采集的样本数据;以及 4) 此前公布的从卡希尔特纳河沿线海拔 200 米的冲积层采集的样本数据。这些样本构成了一个垂直延伸达 5000 米的横断面,这些数据证实了侵蚀率随着海拔的升高而降低,并促进了地形的增长。根据计算,三个新的高海拔样本的侵蚀速率分别为:5200 海拔 4.6 ± 0.6 毫米/千卡,4000 海拔 28.6 ± 3.7 毫米/千卡,3500 海拔 38±5 毫米/千卡。卡希尔特纳冰川侧壁中等海拔地区的侵蚀率介于 160 至 327 毫米/千卡之间。沿中间冰碛推断的侵蚀率介于 140 至 537 毫米/千卡之间,而根据冰川下方河流中的沉积物计算出的全流域侵蚀率介于 450 至 896 毫米/千卡之间。这些侵蚀速率的差异可在 1-10 Ma 内造成 3 km 的地形起伏,完全符合德纳利在过去 ∼6 Ma 岩石隆起和掘起的估计增长期。从 2130 到 5550 masl 的 5 个地点的气象数据显示,海拔 4000 masl 以上的温度很少超过冰点,这表明霜冻风化目前在高海拔地区的侵蚀作用已经减弱。这种温度与侵蚀相关性的直接影响就是地势的上升。这是第一项直接测量高海拔地区在相对没有霜冻风化的情况下侵蚀率显著下降的研究。研究结果凸显了岩石类型、冰川侵蚀和永久性零下温度对侵蚀率的综合影响。这些数据与活动断层相结合,解释了阿拉斯加山脉南侧在过去 100 ka 年间地势上升的原因。
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引用次数: 0
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Earth and Planetary Science Letters
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