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Linking clean energy consumption to environmental sustainability in Africa: Puzzling evidence from new artificial intelligence methods 将非洲的清洁能源消费与环境可持续性联系起来:来自新的人工智能方法的令人困惑的证据
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-19 DOI: 10.1002/ep.70117
Solomon Prince Nathaniel, Dimitrios Dimitriou, Süleyman Bolat, Aviral Kumar Tiwari

The literature is inundated with studies emphasizing the importance of renewable energy consumption (REN) and sustainable resource management as a panacea to the threats of climate change, which include loss of species, food insecurity, extreme weather, sea level rise, and security risks. The current study examines the dynamic relationships in spatial and time domains between REC, natural resource rents (NR), and ecological footprint (EF) from 1990 to 2022, using the novel spatiotemporal intelligent regression models, specifically the Geographically Neural Network Weighted Regression (GNNWR) model for sub-Saharan Africa (SSA) countries. This novel method introduced by Yin et al. (2024) integrates a spatiotemporal weighting framework with neural network architectures. The GNNWR results suggest that REN, NR, and urbanization are significant supportive elements of ecological sustainability in SSA. Conversely, non-renewable energy consumption (NRE), economic growth, and globalization hurt the environment by upsurging the EF. The causality results display a bidirectional causality between REN and EF, NRE and EF, and economic growth and EF. However, unidirectional causality flows from NR and globalization to EF. In line with the results, policymakers in SSA will need to redefine their energy consumption portfolio. Efforts must be made to encourage energy transition by raising adequate awareness of the availability and benefits of consuming clean energies such as solar, tidal, geothermal, wind, and hydropower.

文献中充斥着强调可再生能源消费(REN)和可持续资源管理作为应对气候变化威胁的灵丹妙药的重要性的研究,包括物种丧失、粮食不安全、极端天气、海平面上升和安全风险。本研究利用新颖的时空智能回归模型,特别是撒哈拉以南非洲(SSA)国家的地理神经网络加权回归(GNNWR)模型,研究了1990 - 2022年生态足迹(REC)、自然资源租金(NR)和生态足迹(EF)在时空上的动态关系。Yin等人(2024)提出的这种新方法将时空加权框架与神经网络架构相结合。GNNWR结果表明,REN、NR和城市化是SSA生态可持续性的重要支持因素。相反,不可再生能源消费(NRE)、经济增长和全球化通过提高EF而损害环境。因果关系结果表明,经济增长与经济增长、经济增长与经济增长之间存在双向因果关系。然而,单向因果关系从NR和全球化流向EF。根据研究结果,SSA的政策制定者需要重新定义他们的能源消费组合。必须作出努力,通过提高对诸如太阳能、潮汐能、地热能、风能和水力等清洁能源的可得性和效益的充分认识,鼓励能源转型。
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引用次数: 0
Issue Information - Cover and Table of Contents 发行资料-封面及目录
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-17 DOI: 10.1002/ep.14408
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引用次数: 0
Issue Information - Info for Authors 发行信息-作者信息
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-17 DOI: 10.1002/ep.14430
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引用次数: 0
The removal of organic and pharmaceutical contaminants from aquatic solutions using the Fe/Ni dual-doping TiO2 nano photocatalytic method Fe/Ni双掺杂TiO2纳米光催化法去除水中的有机和药物污染物
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-16 DOI: 10.1002/ep.70102
Aya Talal Sami, Selma M. H. Al-Jawad, Natheer Jamal Imran, Karrer Alghazali

Globally, water contamination has become a major issue, and many individuals are deprived of potable clean water resources. Titanium dioxide (TiO2) has recently attracted considerable scholarly interest for its potential application in water treatment processes due to its non-toxic nature and elevated catalytic activity. The hydrothermal technique has been utilized to prepare pure TiO2 and Fe/Ni dual-doped TiO2 to improve the photocatalytic efficacy for breaking down organic and pharmaceutical contaminants in wastewater using simple materials. x-Ray diffraction, Fourier transform infrared spectroscopy, UV–visible spectrophotometer, zeta potential, and field emission scanning electron microscopy (FE-SEM) were used to characterize the produced samples. The XRD pattern indicates that pure and Fe/Ni dual-doped TiO2 samples have a tetragonal structure and anatase phase. Doping TiO2 with metal ions can prevent the crystal formation of the particles. An FE-SEM image displays a spherical shape and uniform morphology. Utilizing a UV–Vis spectrophotometer, the absorbance spectra were measured. The outcomes demonstrated that the Fe/Ni dual-doped TiO2 had good visible light absorption. As demonstrated by several methods like HPLC and gas chromatography (GC), the TiO2 and Fe/Ni-doped TiO2 system is very effective at promoting the breakdown of pharmaceutical and organic contaminants in wastewater. The Fe/Ni (3%,3%) dual-doped TiO2 had the strongest photocatalytic efficacy against the breakdown of pharmaceutical and organic pollutants, and catalysts may eliminate amoxicillin up to 100%. All specimens have high photocatalytic activity. Additionally, our research has demonstrated that the dual-doped TiO2 catalyst is a potential and successful water treatment technique.

在全球范围内,水污染已成为一个重大问题,许多人被剥夺了清洁的饮用水资源。二氧化钛(TiO2)由于其无毒特性和高催化活性而在水处理工艺中具有潜在的应用前景,近年来引起了相当大的学术兴趣。利用水热技术制备了纯TiO2和Fe/Ni双掺杂TiO2,以提高光催化效率,利用简单的材料降解废水中的有机和药物污染物。采用x射线衍射、傅里叶变换红外光谱、紫外可见分光光度计、zeta电位和场发射扫描电镜(FE-SEM)对样品进行表征。XRD谱图表明,纯和Fe/Ni双掺杂TiO2样品具有四方结构和锐钛矿相。在TiO2中掺杂金属离子可以防止颗粒的结晶。FE-SEM图像显示为球形,形貌均匀。利用紫外可见分光光度计测定了吸光度。结果表明,Fe/Ni双掺杂TiO2具有良好的可见光吸收性能。通过HPLC和气相色谱(GC)等多种方法证明,TiO2和Fe/ ni掺杂TiO2体系在促进废水中药物和有机污染物的分解方面非常有效。Fe/Ni(3%,3%)双掺杂TiO2对药物和有机污染物的降解具有最强的光催化效果,催化剂对阿莫西林的去除率可达100%。所有样品均具有较高的光催化活性。此外,我们的研究表明,双掺杂TiO2催化剂是一种潜在的和成功的水处理技术。
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引用次数: 0
Preparation and selective adsorption properties of Cu2+ imprinted chitosan membranes Cu2+印迹壳聚糖膜的制备及其选择性吸附性能
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-15 DOI: 10.1002/ep.70114
Feng Ying, Jing Rui, Xie Yuju, Wang Zhuo, Wang Zixin, Zhang Jianwei, Dong Xin

In order to improve the selective adsorption capacity of the adsorbent and achieve efficient separation of target ions from solution, a novel ion imprinted chitosan composite membrane PVDF-(CTS-Cu/CMC)3 was developed in this paper. The preparation of the imprinted membrane combined molecular imprinting technology with layer-by-layer self-assembly method, which could achieve selective separation of copper ions. The effects of polyelectrolyte assembly layers, assembly time, and crosslinking on the properties of the membrane were systematically investigated, and the membrane characteristics were characterized membrane characteristics by SEM, XRD, and FTIR. The experimental results indicate that under optimized preparation conditions (3 assembly layers, 0.25% crosslinker concentration, 45 min crosslinking time, 55°C crosslinking temperature) and adsorption conditions (pH 5, adsorption temperature 25°C, adsorption time 120 min), the maximum adsorption capacity of the imprinted membrane for Cu2+ was 98.18 mg/g. On this basis, the selective adsorption capacity for Cu2+ and other characteristics of the membrane were analyzed. In the multi-component system composed of Cu2+, Zn2+ and Fe2+, the selectivity coefficient of the imprinted membrane to Cu2+ reached 18, exhibiting good adsorption selectivity. In addition, the imprinted membrane had reusability, and the adsorption capacity was still as high as 60 mg/g after three adsorption–desorption cycles. This study provided a reference for improving the selectivity of chitosan-based membrane materials to copper ions.

为了提高吸附剂的选择性吸附能力,实现对溶液中目标离子的高效分离,研制了一种新型离子印迹壳聚糖复合膜PVDF-(CTS-Cu/CMC)3。印迹膜的制备将分子印迹技术与逐层自组装方法相结合,实现了铜离子的选择性分离。系统研究了聚电解质组装层数、组装时间、交联对膜性能的影响,并通过SEM、XRD、FTIR等手段对膜的特性进行表征。实验结果表明,在最佳制备条件(3层组装层,交联剂浓度0.25%,交联时间45 min,交联温度55℃)和吸附条件(pH 5,吸附温度25℃,吸附时间120 min)下,印迹膜对Cu2+的最大吸附量为98.18 mg/g。在此基础上,分析了膜对Cu2+的选择性吸附能力等特性。在由Cu2+、Zn2+和Fe2+组成的多组分体系中,印迹膜对Cu2+的选择性系数达到18,表现出良好的吸附选择性。此外,印迹膜具有可重复使用性,经过3次吸附-解吸循环后,其吸附量仍高达60 mg/g。本研究为提高壳聚糖基膜材料对铜离子的选择性提供了参考。
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引用次数: 0
Energy benchmarking of industrial wastewater treatment plants: A case study of activated sludge systems in Isfahan, Iran 工业废水处理厂的能源基准:伊朗伊斯法罕活性污泥系统的案例研究
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-15 DOI: 10.1002/ep.70091
Hamidreza Orumiyeh, Mahsa Bakhtiar, Masoud Taheriyoun

Wastewater treatment plants (WWTPs) using the activated sludge process are widely recognized as significant energy consumers within the water cycle. As a result, it is essential to assess energy consumption and implement solutions for reducing and optimizing it. Energy benchmarking (EB) is a method used to compare and evaluate the energy efficiency of a system to identify opportunities for improvement and enhance energy efficiency. This study aims to evaluate the energy consumption of selected 10 activated sludge operating industrial WWTPs in Isfahan province, Iran. EB of the WWTPs was done using various methods, including normalization, multiple logistic regression, and ordinary least squares. The plants were ranked based on the aggregated scores from different methods using weighted averaging. The results showed that the IWW8, IWW1, and IWW6 plants had the best energy performance. Also, it was found that the aeration unit and effluent pump station accounted for the largest share of energy usage with an average of 68% and 13%, respectively. A positive correlation was found between key performance indices (KPIs) and factors like plant age, design capacity deficiency, and blower power to flow rate ratio that validate the ranking results. Finally, energy saving measures were introduced and prioritized for each of the studied WWTPs based on the BM results and detailed site visits, with a focus on enhancing the aeration system efficiency.

使用活性污泥工艺的污水处理厂(WWTPs)被广泛认为是水循环中重要的能源消耗者。因此,评估能源消耗并实施减少和优化能源消耗的解决方案至关重要。能源基准是一种比较和评估系统能源效率的方法,以确定改进和提高能源效率的机会。本研究旨在评估伊朗伊斯法罕省选定的10个活性污泥运行工业污水处理厂的能耗。采用归一化、多元逻辑回归和普通最小二乘等方法对污水处理厂进行了EB分析。根据不同方法的综合得分,采用加权平均法对植物进行排名。结果表明,IWW8、IWW1和IWW6三个品种的能源性能最好。此外,还发现曝气装置和污水泵站所占的能源使用量最大,平均分别为68%和13%。关键绩效指标(kpi)与植物年龄、设计能力不足和风机功率流量比等因素之间存在正相关关系,从而验证了排名结果。最后,根据BM结果和详细的实地考察,介绍了每个污水处理厂的节能措施,并对其进行了优先级排序,重点是提高曝气系统的效率。
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引用次数: 0
Is geothermal and biomass energy a better alternative for seven renewable energy courteous countries: Evidence from Fourier ARDL, Fourier Bootstrap Toda-Yamamoto and wavelet coherence 地热和生物质能是七个可再生能源文明国家的更好选择:来自傅立叶ARDL、傅立叶Bootstrap Toda-Yamamoto和小波相干性的证据
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-12 DOI: 10.1002/ep.70090
Shweta Kumari, Akanksha Singh, Shiv Lal, Magdalena Radulescu

This study examines geothermal and biomass energy as cleaner alternatives in seven renewable-focused countries in the context of sustainable development and global carbon-neutrality objectives. Geothermal power provides significant emission reductions, with facilities around 99% less CO2 and 97% less SO2 compared to equivalent fossil-fuel plants. Biomass energy is regarded as carbon-neutral in CO2 assessments; however, it still emits SO2 and NOx. We utilize a Fourier-augmented bootstrap ARDL model to examine long-term energy-emissions relationships, a Fourier-augmented Toda-Yamamoto causality test, and wavelet coherence for time-frequency co-movements. Research indicates validation of the Environmental Kuznets Curve in certain economies (USA, Italy), but not in others (France, Portugal, New Zealand, Turkey, Australia). France has no Environmental Kuznets Curve impact. Data from the EEA for Italy indicate the possible advantages; geothermal expansion from 2005 to 2018 averted approximately 2 Mt of CO2 and reduced around 0.9 kt of NOx and 0.7 kt of SO2. Current business-as-usual predictions significantly exceed net-zero objectives, with existing commitments anticipated to result in around 22 Gt CO2 emissions by 2050. Conversely, IEA models anticipate over 90% renewable electricity by 2050, emphasizing the benefits of geothermal and biomass optimization. Essential policy recommendations for parallel economies encompass tripling clean energy investments by 2030, implementing robust carbon pricing and renewable mandates, and enhancing international collaboration on technology and finance. These actions would capitalize on geothermal and biomass potential to reduce emissions by the middle of the century. Renewable energy sources help reduce pollutant emissions, enhancing air quality and providing public health benefits.

本研究在可持续发展和全球碳中和目标的背景下,考察了七个以可再生能源为重点的国家将地热能和生物质能作为更清洁的替代品。地热发电提供了显著的减排,与同等的化石燃料发电厂相比,地热发电厂的二氧化碳排放量减少了99%,二氧化硫排放量减少了97%。在二氧化碳评估中,生物质能被视为碳中性能源;然而,它仍然会排放二氧化硫和氮氧化物。我们利用傅里叶增强自举ARDL模型来检验长期能量排放关系,傅里叶增强Toda-Yamamoto因果检验,以及时频共运动的小波相干性。研究表明,环境库兹涅茨曲线在某些经济体(美国、意大利)得到证实,但在其他经济体(法国、葡萄牙、新西兰、土耳其、澳大利亚)没有得到证实。法国没有环境库兹涅茨曲线影响。欧洲经济区对意大利的数据表明了可能的优势;2005年至2018年的地热扩张减少了约200万吨的二氧化碳排放,减少了约0.9万吨的氮氧化物和0.7万吨的二氧化硫。目前一切照旧的预测大大超过了净零目标,现有承诺预计到2050年将产生约220亿吨二氧化碳排放量。相反,国际能源署的模型预测到2050年可再生电力将超过90%,强调地热和生物质优化的好处。针对平行经济体的基本政策建议包括,到2030年将清洁能源投资增加两倍,实施强有力的碳定价和可再生能源授权,以及加强技术和金融方面的国际合作。这些行动将利用地热和生物质的潜力,到本世纪中叶减少排放。可再生能源有助于减少污染物排放,改善空气质量,并为公众健康带来益处。
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引用次数: 0
Advancement in metal organic frameworks@metal oxides composites for energy and environmental applications 金属有机frameworks@metal氧化物复合材料在能源和环境中的应用进展
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-12 DOI: 10.1002/ep.70104
Muhammad Dilawar Hussain, Sami Ullah, Muhammad Arshad, Lala Gurbanova, Mostafa A. Ismail, Md Razaul Karim, Syed Shoaib Ahmad Shah, Muhammad Altaf Nazir

The integration of metal–organic frameworks (MOFs) into Metal Oxides has garnered significant interest due to their unique combined synergistic effects, morphological features, and outstanding performance across various high-tech applications ranging from sustainable solutions to environmental and energy sector problems. This article comprehensively covers every aspect of pristine MOF and MOF@MO composite materials, spanning synthesis methodologies, morphological features, synergistic effects, and their extensive applications in the environmental and energy sectors. The article begins by detailing the synthesis methods for pristine MOFs and MOF@MO composites. It systematically illustrates the combined synergistic effects of MOF@MO composite materials, highlighting their enhanced properties and morphological characteristics in a schematic manner. Subsequently, the article delves into the applications of these composite materials in environmental and energy sectors, including wastewater treatment, energy storage and conversion, supercapacitors, and wastewater treatment technologies. Moreover, this study highlights the underlying mechanisms involved during these applications and discusses their key findings. Furthermore, the article consolidates recent research and integrated studies up to the present, providing a comprehensive overview of advancements in the field. It concludes with a precise and concise conclusion, offering insights into future prospects and inviting new researchers and professionals to explore emerging opportunities in this promising area of study.

金属有机框架(mof)与金属氧化物的集成由于其独特的组合协同效应、形态特征以及在从可持续解决方案到环境和能源部门问题的各种高科技应用中的卓越性能而引起了人们的极大兴趣。本文全面介绍了原始MOF和MOF@MO复合材料的各个方面,包括合成方法、形态特征、协同效应以及它们在环境和能源领域的广泛应用。本文首先详细介绍了原始MOFs和MOF@MO复合材料的合成方法。系统地说明了MOF@MO复合材料的综合协同效应,以示意图的方式突出了它们的增强性能和形态特征。随后,文章深入探讨了这些复合材料在环境和能源领域的应用,包括废水处理、储能和转换、超级电容器和废水处理技术。此外,本研究强调了这些应用过程中涉及的潜在机制,并讨论了他们的主要发现。此外,文章整合了最近的研究和综合研究到目前为止,提供了一个全面的概述,在该领域的进展。它以一个精确而简洁的结论结束,提供了对未来前景的见解,并邀请新的研究人员和专业人士探索这个有前途的研究领域的新兴机会。
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引用次数: 0
Comparative techno-economic and environmental study of hybrid and pure adsorption for carbon capture in blue hydrogen 混合吸附和纯吸附蓝氢捕集碳的技术经济和环境比较研究
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-11 DOI: 10.1002/ep.70100
Mohammad Sajjadi, Michael Fabrik, Hussameldin Ibrahim

Blue hydrogen offers a promising solution for mitigating global warming. Accordingly, improving carbon capture in blue H2 plant designs becomes crucial. This study assesses and compares the viability of technologies for 100 and 400 tonnes-per-day plants, considering technical, environmental, and economic aspects using Aspen HYSYS and ReCiPe methodology for process simulation and life cycle assessment respectively. The hybrid absorption/adsorption system demonstrated superior long-term profitability and higher net present value, despite its higher capital costs. In contrast, the adsorption-only system resulted in a shorter payback period and lower equivalent emissions. The cost of hydrogen production was $2.20/kg for the former and $1.80/kg for the latter, with a slight difference in rate of return. Additionally, sensitivity analysis revealed the impact of natural gas costs, H2 and CO2 selling prices, and zeolite costs on profitability. Also, scale-up showed that a plant with a larger capacity is more profitable.

蓝色氢为缓解全球变暖提供了一个很有希望的解决方案。因此,改善蓝色H2工厂设计中的碳捕获变得至关重要。本研究分别使用Aspen HYSYS和ReCiPe方法进行过程模拟和生命周期评估,从技术、环境和经济方面考虑,评估和比较了100和400吨/天工厂的技术可行性。混合吸收/吸附系统显示出优越的长期盈利能力和更高的净现值,尽管其资本成本较高。相比之下,仅吸附系统的投资回收期更短,当量排放量更低。前者的制氢成本为2.20美元/公斤,后者为1.80美元/公斤,回报率略有差异。此外,敏感性分析还揭示了天然气成本、H2和CO2销售价格以及沸石成本对盈利能力的影响。此外,规模扩大表明,产能越大的工厂利润越高。
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引用次数: 0
Enhancing solar power generation with eco-friendly surfaces to promote clean energy, reduce emissions, and Foster sustainable resource use 加强表面环保的太阳能发电,推广清洁能源,减少排放,促进资源的可持续利用
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-09-11 DOI: 10.1002/ep.70094
Ganesan Rathinavel Pandian, Gurukarthik Babu Balachandran, Prince Winston David, Santhiya R

A comprehensive assessment is carried out on bifacial solar photovoltaic (bPV) systems, focusing on two surface types— proposed Freshwater Surface (PFWS) and Conventional White Surface (CWS)—to compare their performance outcomes. Optimal operating parameters—such as a 6 cm water depth, 100 cm panel elevation, and a 90° tilt angle—were determined through experimental trials combined with statistical optimization using Central Composite Design (CCD) within the Response Surface Methodology (RSM) framework. The PFWS configuration consistently demonstrated superior performance, achieving power output gains ranging from 3.05% to 4.86% over CWS. Although energy and exergy efficiencies between the two configurations were closely matched, PFWS yielded a slightly higher average output, confirming its improved energy capture capability. From an economic standpoint, PFWS showed a clear advantage, with higher Net Present Value (NPV) figures across all evaluated timeframes—ranging from $309.05 to $335.95—compared to CWS, which ranged from $288.42 to $330.96. In terms of sustainability, PFWS also achieved better environmental performance, with increased Gross Carbon Reduction (GCR) values (891.884 to 892.873 tCO2) and a reduced Levelized Cost of Energy (LCOE), demonstrating enhanced cost-effectiveness and carbon mitigation potential. PFWS proves more sustainable and scalable for solar energy, ideal in sunny, land-limited regions.

本文对双面太阳能光伏(bPV)系统进行了全面的评估,重点关注两种表面类型——拟议的淡水表面(PFWS)和传统的白色表面(CWS)——以比较它们的性能结果。最佳操作参数-如6厘米水深,100厘米面板高度和90°倾斜角-通过实验试验确定,并在响应面方法(RSM)框架内使用中心复合设计(CCD)进行统计优化。PFWS配置始终表现出优异的性能,与CWS相比,功率输出增益在3.05%至4.86%之间。虽然两种配置之间的能量和火用效率非常接近,但PFWS的平均输出略高,这证实了其改进的能量捕获能力。从经济角度来看,PFWS表现出明显的优势,与CWS相比,PFWS的净现值(NPV)在所有评估时间范围内(从309.05美元到335.95美元)都更高,而CWS的净现值(NPV)在288.42美元到330.96美元之间。在可持续性方面,PFWS还取得了更好的环境绩效,其总碳减量(GCR)值(891.884至892.873 tCO2)有所增加,平准化能源成本(LCOE)有所降低,显示出更高的成本效益和碳减排潜力。事实证明,PFWS在太阳能方面更具可持续性和可扩展性,是阳光充足、土地有限地区的理想选择。
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引用次数: 0
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