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Evaluation of Trace Metal Contamination in Ise Bay, Mie Prefecture, Central Japan, Based on Geochemical Analysis of Tidal Flat Sediments 基于潮滩沉积物地球化学分析的日本中部三重县伊势湾痕量金属污染评价
Pub Date : 2016-04-28 DOI: 10.5539/EP.V5N1P92
I. Diallo, H. Ishiga
Geochemical analysis of tidal flat sediments was conducted to evaluate the environment of Ise Bay, Mie, central Japan. The sediment samples were analyzed using XRF to determine the geochemical compositions of sediments in the Ise and Matsusaka estuaries and their foreshores. Enrichment Factor (EF) and the Anthropogenic Contribution (AC) parameters were used to examine the potential effect of human activity. Furthermore, the Coastal Ocean Sediment Database, lowest and severe effect levels and Canadian Sediment Quality Guidelines were applied as benchmarks to assess the sediment quality. The results show that the highest average concentrations of metals occur in the Ise estuary, mainly due to the presence of higher proportions of silt and clay in samples at that site. The EFs of Pb in the Matsusaka foreshore, and that of As in the Ise foreshore reflect minimal pollution. The average AC ranged from 1 to 30%, implying that the lithology is the primary control of any enrichment in trace metals within the bay. The sediment quality guidelines indicate that the metal levels in the study areas do not constitute a major threat to biota.
对日本中部三重伊势湾的潮滩沉积物进行了地球化学分析,以评价其环境。利用XRF分析了伊势河口和松坂河口及其前滩沉积物的地球化学成分。利用富集因子(EF)和人为贡献(AC)参数考察了人类活动的潜在影响。此外,沿海海洋沉积物数据库、最低和严重影响水平以及加拿大沉积物质量准则被用作评估沉积物质量的基准。结果表明,伊势河口的平均金属浓度最高,主要是由于该地点的样品中存在较高比例的淤泥和粘土。松坂前滩Pb和伊势前滩As的电场值反映出污染最小。平均交流系数在1 ~ 30%之间,表明岩性是海湾内微量金属富集的主要控制因素。沉积物质量指南表明,研究区域的金属水平不会对生物群构成重大威胁。
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引用次数: 2
Elemental Contents of Spinach and Lettuce from Irrigated Gardens in Kano, Nigeria 尼日利亚卡诺灌溉花园菠菜和生菜的元素含量
Pub Date : 2016-04-28 DOI: 10.5539/EP.V5N1P73
Dike N. I., A. Odunze
One way analysis (ANOVA) was used to analyze a large dataset of elemental levels of two vegetables – spinach ( Amaranthus cruentus ) and lettuce ( Lactuca sativa ) grown around River Jakara in Kano, Nigeria using data generated during 12 months of monitoring Ca, K, Mg, Na, (essential bulk elements) Cu, Zn, Cd, Ni, Cr, Co, Pb and Fe (trace/heavy elements) concentrations collected at three designated sites. The concentrations of the elements showed insignificant differences between sites but significant differences between some months. The soil was implicated as the major source of the elements. The concentrations of the trace/heavy metals exceeded those of the international permissible limits which pointed to the contamination of the vegetables. The mean concentrations of the elements occurred in the magnitude of Ca > Mg > K > Na > Fe > Zn > Pb > Co > Cr > Cu > Ni > Cd and Ca > Na > K >Mg > Fe > Zn > Pb > Cr > Co > Cu > Ni > Cd in the spinach and lettuce respectively. The continued consumption of these vegetables by the inhabitants of Kano and its environs present a public health risk with regards to their concentrations with heavy metals. It is therefore recommended that the relevant organ of government should find an alternative farmland for the farmers within the catchment area of River Jakara where unpolluted soil can be utilized for the production of the vegetables.
采用单向分析(ANOVA)分析了尼日利亚卡诺贾卡拉河附近种植的两种蔬菜——菠菜(Amaranthus cruentus)和生菜(Lactuca sativa)的元素水平的大型数据集,使用了在三个指定地点收集的12个月监测Ca, K, Mg, Na,(必需散装元素)Cu, Zn, Cd, Ni, Cr, Co, Pb和Fe(微量/重元素)浓度的数据。这些元素的浓度在不同地点之间差异不显著,但在某些月份之间差异显著。土壤被认为是这些元素的主要来源。微量/重金属的浓度超过了国际允许的限度,这表明蔬菜受到了污染。菠菜和生菜中各元素的平均浓度分别为Ca >Mg > K > Na > Fe > Zn > Pb > Co > Cr > Cu > Ni > Cd和Ca > Na > K >Mg > Fe > Zn > Pb > Cr > Co > Cu > Ni > Cd。卡诺及其周边地区的居民继续食用这些蔬菜,由于其重金属含量过高,对公众健康构成威胁。因此,建议政府有关机关在贾卡拉河流域内为农民寻找可用于生产蔬菜的未受污染土壤的替代农田。
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引用次数: 2
Synthetic Pyrethroids Pesticide Residues in Soils and Drinking Water Sources from Cocoa Farms in Ghana 合成拟除虫菊酯在加纳可可农场土壤和饮用水源中的农药残留
Pub Date : 2016-04-21 DOI: 10.5539/EP.V5N1P60
B. Fosu-Mensah, E. Okoffo, M. Mensah
The contamination of pesticides in 32 soils and 64 drinking water samples was investigated from cocoa farms in the Dormaa West District of Ghana to assess pollution status. A total of nine synthetic pyrethroids pesticides were measured with a high resolution Varian CP-3800 Gas Chromatograph equipped with 63 Ni electron capture detector (ECD). Eight synthetic pyrethroid residues namely fenvalerate, deltamethrin, cypermethrin, bifenthrin, permethrin, lambda-cyhalothrin, allethrin and cyfluthrin were detected with lambda-cyhalothrin and allethrin occurring most frequently in soil and water respectively. The concentrations of synthetic pyrethroids residues in the soil samples were in the ranges of; 0.02-0.03 mg/kg for lambda-cyhalothrin, 0.010-0.02 mg/kg for allethrin, 0.010-0.04 mg/kg for cyfluthrin, 16-30m>above 30m). All synthetic pyrethroids pesticide residues recorded in the water samples were below and within their respective WHO MRLs for drinking water except for deltamethrin, which exceeded the WHO MRL at Kwakuanya (S4) at distance 0-15m from a cocoa farm. The presence of synthetic pyrethroids residues in the soil and water samples analysed is an indication of the use of the pesticide by cocoa farmers in the study area. The routine monitoring of pesticide residues in the study area is necessary for the control and reduction of environmental pollution.
对来自加纳Dormaa西区可可农场的32个土壤和64个饮用水样本中的农药污染进行了调查,以评估污染状况。采用配备63 Ni电子捕获检测器(ECD)的高分辨率Varian CP-3800气相色谱仪对9种合成拟除虫菊酯农药进行了测定。在土壤和水中分别检测到氰菊酯、溴氰菊酯、氯氰菊酯、联苯菊酯、氯氰菊酯、高效氯氰菊酯和氟氯菊酯等8种合成拟除虫菊酯残留,其中高效氯氰菊酯和高效氯氰菊酯分别在土壤和水中最常见。土壤样品中人工拟除虫菊酯残留量在;高效氯氟氰菊酯0.02 ~ 0.03 mg/kg,丙烯氰菊酯0.010 ~ 0.02 mg/kg,氟氯菊酯0.010 ~ 0.04 mg/kg, 16 ~ 30m> 30m以上)。水样中记录的所有合成拟除虫菊酯农药残留均低于并在其各自的世卫组织饮用水最大残留限量范围内,但溴氰菊酯超出了世卫组织在Kwakuanya (S4)距离可可农场0-15米的最大残留限量。所分析的土壤和水样中存在合成拟除虫菊酯残留物,表明研究地区的可可农民使用了这种杀虫剂。研究区农药残留的常规监测是控制和减少环境污染的必要条件。
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引用次数: 20
Quality Assessment of Soil Pollution Monitoring: Focus on Representativeness 土壤污染监测质量评价:注重代表性
Pub Date : 2016-02-26 DOI: 10.5539/EP.V5N1P51
A. Desaules
Soil monitoring data can be no better than the quality of the monitoring system they stem from. Quality assessment (QA) of soil monitoring requires reliable and comprehensive quality assessment and quality control (QA/QC) schemes including (1) the selection of parameters and measurement quality related to (2) space and (3) time. It can be presented by a synoptic diagram with three axes based on a table with quality criteria. The two major quality parameters are the degrees of resolution (precision) and representativeness (bias), whereas the latter does not yet include parameter selection and soil sampling. As a result the quality of soil monitoring is usually greatly overestimated. This finding is supported by examples and practical recommendations are given. Since full representativeness for the three aspects of soil monitoring is a fiction in practice, their biases have to be quantified completely, continuously and reliably. The most important challenges are to quantitatively assess and control the representativeness of primary soil sampling and to improve it.
土壤监测数据不可能比监测系统的质量更好。土壤监测质量评价(QA)需要可靠、全面的质量评价和质量控制(QA/QC)方案,包括(1)与(2)空间和(3)时间相关的参数选择和测量质量。它可以用一个带有质量标准的表的三轴天气图来表示。两个主要的质量参数是分辨率(精度)和代表性(偏差),而后者尚未包括参数选择和土壤采样。因此,土壤监测的质量通常被大大高估。这一发现得到了实例的支持,并给出了实用的建议。由于在实践中,土壤监测的三个方面都具有充分的代表性是不现实的,因此必须对它们的偏差进行完整、连续和可靠的量化。最重要的挑战是定量评价和控制原始土壤采样的代表性,并改进它。
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引用次数: 0
Distribution and Adsorption Characteristics of Phosphorus at A Headwater Wetland in Ichikawa City, Chiba Prefecture, Japan 日本千叶县市川市水源湿地中磷的分布及吸附特征
Pub Date : 2016-02-15 DOI: 10.5539/EP.V5N1P31
J. Piao, C. Tang, Toma Matsumaru, Z. Han, H. Sakaguchi, S. Satake
The distribution and adsorption characteristics of phosphorus were investigated in a typical headwater wetland in Ichikawa City, Chiba Prefecture, Japan. Total dissolved phosphorus (TDP) was the main phosphorus fraction in the waters, ranging from limit of quantification (0.002 mg/L) to 0.059 mg/L in spring water, from limit of quantification to 0.128 mg/L in groundwater and from 0.012 to 0.048 mg/L in river water. TDP in 33% water samples were higher than the environmental quality standard for eutrophication (0.020 mg/L). Next, phosphorus adsorption experiment was conducted to study phosphorus distribution in the aquifer where the equilibrium phosphorus concentration (C EPC ) is the key to access the phosphorus in the waters. In addition, the amount of TDP releasing from the wetland through river was 20.9 g/day.
对日本千叶县市川市典型水源湿地中磷的分布及吸附特性进行了研究。水体中总溶解磷(TDP)为主要磷组分,泉水定量限为0.002 ~ 0.059 mg/L,地下水定量限为0.128 mg/L,河水定量限为0.012 ~ 0.048 mg/L。33%水样TDP高于富营养化环境质量标准(0.020 mg/L)。其次,进行了磷吸附实验,研究了磷在含水层中的分布,其中平衡磷浓度(C EPC)是获取水体中磷的关键。此外,湿地经河流释放的TDP量为20.9 g/d。
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引用次数: 2
Effects of Parental and Direct Methylmercury Exposure on Flight Activity in Young Homing Pigeons (Columba livia) 亲本接触和直接接触甲基汞对幼雏信鸽飞行活动的影响
Pub Date : 2016-02-15 DOI: 10.5539/EP.V5N1P23
J. K. Moye, C. R. Perez, C. Pritsos
Mercury is one of the most common metals found in contaminated ecosystems. It occurs naturally, but high levels found in contaminated areas derive from human use practices. Among the most vulnerable species to exposure are birds that live, nest, or feed in or near these contaminated ecosystems. Because of the known neurological effects of mercury on birds, it is hypothesized that effects upon migratory ability would be evident after exposure to low levels of this metal, and effects may be exacerbated in young birds. Difficulties in following mercury exposed birds once they migrate away from contaminated areas have left investigators with insufficient data to establish exposure levels causing injury of migratory species due to migration disruption. Breeding pigeons were exposed to ~1.0 mg/kg/day methylmercury via the drinking water, and first round offspring were trained to home after fledging, while also continually exposed to methylmercury. The young pigeons were released individually for three flights, and flight times were assessed and compared to control young pigeon flight times from 3.5, 9, 21, 53, 65, and 98 air miles as well as two individual flights at ~50 air miles from multiple directions. Results indicate that methylmercury exposed birds exhibit slower flight times than controls during the initial flight, and generally improve on successive flights at each distance and direction. This may suggest orientation impairment and allude to migration disruption in migratory species.
汞是污染生态系统中最常见的金属之一。它是天然存在的,但在污染地区发现的高水平是由于人类使用的做法。最易受到污染的物种是在这些受污染的生态系统或其附近生活、筑巢或进食的鸟类。由于已知的汞对鸟类的神经系统影响,假设在接触低水平的汞后,对迁徙能力的影响将是明显的,并且对雏鸟的影响可能会加剧。一旦接触汞的鸟类从受污染地区迁出,就很难对其进行跟踪,这使得调查人员没有足够的数据来确定由于迁徙中断而对候鸟造成伤害的接触水平。饲养鸽通过饮水暴露于~1.0 mg/kg/d的甲基汞环境中,第一轮雏鸽羽化后训练回家,同时持续暴露于甲基汞环境中。雏鸽分别放飞3次,并与对照雏鸽分别放飞3.5、9、21、53、65、98空英里的飞行时间和两次50空英里左右的单次飞行时间进行比较。结果表明,甲基汞暴露的鸟类在初始飞行中表现出比对照组更慢的飞行时间,并且在每个距离和方向的后续飞行中普遍有所改善。这可能表明定向障碍,并暗示迁移物种的迁移中断。
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引用次数: 14
Perceived Health Hazards of Low-Quality Irrigation Water in Vegetable Production in Morogoro, Tanzania 坦桑尼亚莫罗戈罗蔬菜生产中劣质灌溉水对健康的危害
Pub Date : 2015-12-25 DOI: 10.5539/EP.V5N1P1
Winfrida Mayilla, F. Magayane, B. Keraita, H. Ngowi
This study assessed the perceptions of vegetable farmers, traders, consumers and key informants on the health hazards of using low-quality water in irrigation vegetable production in Morogoro, Tanzania. Methods used to collect data were a survey involving all farmers in Changarawe village and Fungafunga area using low-quality water for irrigation vegetable production (n=60), consumers of low-quality water irrigated vegetables (n=70) and vegetable traders selling low-quality water irrigated vegetables (n=60), focus group discussions (n=7) and key informant interviews (n=25). The study employed cross sectional research design. Descriptive statistics were used to calculate mean, frequencies and percentages while Mann-Whitney U-test and Kruskal-Wallis H-test assessed the association between social-demographic variables and respondents score on the health hazard perception scale of using low-quality water in vegetable production. Results showed skin itching, fungal diseases, bilharzias and worm infestation as among the perceived health hazards in using low-quality irrigation water. Health hazard perception differed among groups of farmers, consumers and vegetable traders (p<0.001). The mean ranks of the groups indicated that farmers perceive less health hazards in using low-quality water (mean rank = 147.98) compared to consumers (mean rank = 72.68) and vegetable traders (mean rank 69.64). More health hazards were perceived by Fungafunga farmers compared to farmers from the Changarawe village (p<0.001) while female farmers perceived less hazards in using low-quality water than male farmers (p < 0.05). Consumers with formal education perceived more health hazards than consumers with no formal education (p < 0.001) while vegetable traders from Fungafunga area perceived more health hazards in selling low-quality water irrigated vegetable than vegetable traders from the Changarawe village (p<0.001). These findings demonstrate the need to design health hazards minimization interventions for specific target group.
本研究评估了坦桑尼亚莫罗戈罗的菜农、贸易商、消费者和主要线人对在灌溉蔬菜生产中使用劣质水的健康危害的看法。收集数据的方法是对昌加拉维村和丰加丰加地区所有使用劣质水灌溉蔬菜生产的农民(n=60)、劣质水灌溉蔬菜的消费者(n=70)和销售劣质水灌溉蔬菜的蔬菜贸易商(n=60)进行调查、焦点小组讨论(n=7)和关键信息提供人访谈(n=25)。本研究采用横断面研究设计。采用描述性统计方法计算平均值、频率和百分比,Mann-Whitney u检验和Kruskal-Wallis h检验评估社会人口统计学变量与受访者在蔬菜生产中使用劣质水的健康危害感知量表得分之间的关系。结果表明,使用劣质灌溉水对健康的危害包括皮肤瘙痒、真菌病、血吸虫病和寄生虫病。农民、消费者和蔬菜贸易商群体对健康危害的认知存在差异(p<0.001)。各群体的平均排名表明,与消费者(平均排名为72.68)和蔬菜贸易商(平均排名为69.64)相比,农民认为使用劣质水对健康的危害较小(平均排名为147.98)。与Changarawe村的农民相比,Fungafunga村的农民认为存在更多的健康危害(p<0.001),而女性农民认为使用劣质水的危害比男性农民小(p< 0.05)。受过正规教育的消费者比没有受过正规教育的消费者认为健康危害更大(p<0.001),而来自Fungafunga地区的蔬菜贸易商比来自Changarawe村的蔬菜贸易商认为销售劣质水灌溉蔬菜对健康危害更大(p<0.001)。这些发现表明,有必要针对特定目标群体设计最小化健康危害的干预措施。
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引用次数: 5
Evaluating Alternate Post-Mining Land-Uses: A Review 评价采矿后土地的备选利用:综述
Pub Date : 2015-12-25 DOI: 10.5539/EP.V5N1P14
C. Mborah, K. J. Bansah, M. K. Boateng
The ultimate objective of post-mine land-use and reclamation planning is to identify appropriate alternate land uses to which mined land could be put. This will ensure that land-use and morphology of the location will be capable of supporting either the prior land-use or pre-mining environment. The main challenge is usually, the choice of variables that must be considered in deciding a particular post-mining land-use. Literature reviews were conducted to identify the major factors needed to be considered in the selection of a post-mining land-use. This paper also looks at the most commonly practiced and accepted post-mining land-use techniques. Factors identified as important in the selection process include land resources (e.g. physical, biological and cultural characteristics), ownership, type of mining activity, legal requirements, location, needs of the community, economic, environmental, technical and social factors. In a broad categorization, all post-mining land-uses could be placed under one of the following land-use: agriculture, forestry, lake or pool, intensive recreational land-use, non-intensive recreational land-use, conservation and pit backfilling. However, the objective of any particular post-mining land use should be achieving economic and sustainable outcomes which meet human wants and needs, and protect life and the environment.
地雷后土地使用和复垦规划的最终目标是确定可以放置地雷的适当替代土地用途。这将确保该地点的土地使用和形态能够支持以前的土地使用或采矿前的环境。主要的挑战通常是在决定某一特定采矿后土地使用时必须考虑的变数的选择。进行了文献审查,以确定在选择采矿后土地使用时需要考虑的主要因素。本文还探讨了最常用和公认的采矿后土地利用技术。在选择过程中被确定为重要的因素包括土地资源(如物理、生物和文化特征)、所有权、采矿活动类型、法律要求、地点、社区需求、经济、环境、技术和社会因素。在一个广泛的分类中,所有采矿后的土地用途可归为下列土地用途之一:农业、林业、湖泊或池塘、集约娱乐用地、非集约娱乐用地、养护和坑回填。但是,任何特定的采矿后土地使用的目标应该是取得经济和可持续的成果,满足人类的需要和需要,并保护生命和环境。
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引用次数: 42
Emission of Fine Particles and Ageing Behavior of PTFE Finished Filter Media during Industrial Pollution Control 工业污染治理中聚四氟乙烯成品滤料的细颗粒排放与老化行为
Pub Date : 2015-09-28 DOI: 10.5539/EP.V4N4P58
A. Mukhopadhyay, Harshad S. Bawane
Present study embodies the effect of two different filter media viz. polyester filter fabric treated with PTFE finish and polyester fabric filter without finish, and two different dust concentration (50 and 150 g/m 3 ) on industrial pulse-jet filtration process performance. The fabrics were tested based on ISO - 11057 Standard, while conducting 200 pulsing cycles at measuring phase. Emission in terms of mass concentration (PM 2.5 , PM 10 ) and number particle concentration are substantially lower while using PTFE finished filter media in comparison to media without finish. Outgoing particle number largely reduced while using PTFE treated fabrics particularly at higher dust concentration. The particle size distribution in the downstream side reflects that use of PTFE finish filter is particularly more beneficial for capturing very fine particle. PTFE finish fabric also exhibit lower residual pressure drop as compared to unfinished fabric during measuring phase of filtration operation. Further it was also evident that the trend of residual pressure drop with time is quite stable for PTFE finished fabrics. The said fabric get stable (age) earlier than without finish, hence expected to provide more consistent filtration behaviour for longer time.
本文研究了两种不同的过滤介质,即经过PTFE整理的聚酯滤布和未经整理的聚酯滤布,以及两种不同的粉尘浓度(50和150 g/m 3)对工业脉冲射流过滤过程性能的影响。织物按照ISO - 11057标准进行测试,在测量阶段进行200次脉冲循环。在质量浓度(PM 2.5, PM 10)和粒子数浓度方面,使用PTFE完成的过滤介质与未完成的过滤介质相比,排放量大大降低。在使用聚四氟乙烯处理的织物时,特别是在较高的粉尘浓度下,外向颗粒数大大减少。下游侧的粒径分布反映了PTFE精加工过滤器尤其有利于捕获极细颗粒。在过滤操作的测量阶段,与未完成的织物相比,PTFE整理织物也表现出更低的残余压降。此外,PTFE经整理织物的残余压降随时间的变化趋势也很稳定。上述织物比未经整理的织物更早稳定(老化),因此有望在更长的时间内提供更一致的过滤行为。
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引用次数: 8
Spatial Distribution and Bioavailability of Some Essential Trace Elements in Southern Ondo State Nigeria 尼日利亚南部翁多州一些必需微量元素的空间分布和生物利用度
Pub Date : 2015-09-28 DOI: 10.5539/ep.v4n4p24
W. B. Tomori, I. Amoo, A. Aiyesanmi, E. Yanful, Petrik Leslie
The total elemental content of soil though may give abundance of element concentration but have been found not to be suitable for prediction of environmental bioavailability and toxicity by scientific community. Surface (0-30cm) and subsurface (60-90cm) soil profile in the Southern Ondo State Nigeria were investigated for spatial distribution, bioavailability and mobility of some essential trace elements (Cu, Fe, Mn, Zn). Their spatial distribution were very similar in both surface and subsurface soil environment indicating that similar geochemical factors may be responsible for their distribution. The North was composed of basement complex while the South was largely undifferentiated sedimentary rock. Higher concentrations of Cu, Fe, Mn and Zn were recorded in the North through the centre of study area to lower concentrations in the South. The spatial concentration of the trace elements may have been influenced by the nature of underlying bedrock type. Cu was potentially bioavailable in both surface and subsurface soil environment considering the fact that >50% of its total concentration were in the nonresidual fraction. Other trace elements were not bioavailable because >60% of their total concentrations were found in residual fractions. The relative risk assessment code of Cu (surface; subsurface) indicated progressive risk (MoF1, MoF2, MoF3) from low (2-10; 1-6) through medium (12-30; 10-21) to high risk (25-40; 21-35) in both surface and subsurface soil environment while Zn (surface) shows similar trend (1-5; 11-21; 22-35) only in the surface soil environment. Other elements show some level of risk to no risk. There is likelihood that Cu and/or Mn may be associated with anthropogenic sources.
土壤全元素含量虽然可以提供丰富的元素浓度,但科学界发现不适合预测环境的生物有效性和毒性。研究了尼日利亚南部Ondo州表层(0 ~ 30cm)和地下(60 ~ 90cm)土壤中必需微量元素(Cu、Fe、Mn、Zn)的空间分布、生物有效性和流动性。它们在地表和地下土壤环境中的空间分布非常相似,表明它们的分布可能与相似的地球化学因素有关。北部为基底杂岩,南部主要为未分化的沉积岩。从研究区中心到南部,铜、铁、锰和锌的浓度均较低。微量元素的空间富集可能受下伏基岩类型的影响。铜在表层和地下土壤环境中均具有潜在的生物可利用性,因为其总浓度的50%以上为非残留部分。其他微量元素不具有生物可利用性,因为它们总浓度的60%左右存在于残留馏分中。铜表面相对风险评价规范;地下)表明从低(2-10;1-6)通过介质(12-30;10-21)至高风险(25-40;表层和地下土壤环境中Zn(表层)的变化趋势相似(1-5;乳;22-35)只在表层土壤环境中。其他元素显示出一定程度的风险,甚至没有风险。铜和/或锰可能与人为来源有关。
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引用次数: 0
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Environment and Pollution
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