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Geochemical Assessment of Trace Metal Distribution and Contamination in the Surface Sediments of the Coast of Okinawa Island, Japan 日本冲绳岛海岸表层沉积物中痕量金属分布及污染的地球化学评价
Pub Date : 2016-11-17 DOI: 10.5539/EP.V6N1P1
I. Diallo, H. Ishiga
In this study, sediment samples were collected from the Awase tidal, the Minamigusuku, and Nakagusuku areas located in the Okinawa Island. The collected samples were analyzed using X-ray fluorescence to determine their geochemical compositions and distribution, and to assess the sediment quality in the study areas. Contamination factor (CF), geoaccumulation index (Igeo), and the United State Environmental Protection Agency Sediment Quality Guideline (US EPA SQG) were used to assess the sediment quality. The results show that the highest average concentrations of As (11mg/kg), Pb (8 mg/kg), Zn (19 mg/kg), Cu (6 mg/kg), and Cr (14mg/kg) occurred in the Minamigusuku area. The CF and Igeo values, and the US EPA SQG indicate that among the selected trace metals only As displays significant values in the study areas. The CF values of As in the Minamigusuku area show moderate enrichment, and in this same area, the Igeo values of As present significant values, ranging from moderate to considerable contaminations, implying a possible effect on the biota in this location. Compared to the US EPA SQG, the Awase tidal flat and Nakagusuku areas are moderately polluted, whereas Minamigusuku is heavily polluted, suggesting that As may possible impact the biota in these areas. Consequently, for a better sustainable development of the coast of  Okinawa Island , a regular monitoring and assessment of study areas, particularly the Minamigusuku area, is necessary to determine over time the concentration of As.
在本研究中,沉积物样本采集于冲绳岛的Awase tidal、Minamigusuku和Nakagusuku地区。利用x射线荧光分析了样品的地球化学组成和分布,并对研究区沉积物质量进行了评价。采用污染因子(CF)、地质累积指数(Igeo)和美国环境保护署沉积物质量指南(US EPA SQG)对沉积物质量进行评价。结果表明,As (11mg/kg)、Pb (8mg /kg)、Zn (19mg /kg)、Cu (6mg /kg)和Cr (14mg/kg)的平均浓度最高的地区为南古陆地区。CF值和Igeo值以及美国EPA SQG值表明,所选微量金属中只有As在研究区域具有显著值。南古陆地区砷的CF值呈现中等富集,同一地区砷的Igeo值呈现显著值,污染程度从中等到相当,可能对该地区的生物群造成影响。与美国环保局SQG相比,Awase潮滩和中久陆地区污染程度中等,而南久陆地区污染严重,表明As可能影响这些地区的生物区系。因此,为了冲绳岛海岸更好的可持续发展,有必要定期监测和评估研究地区,特别是南古陆地区,以确定一段时间内砷的浓度。
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引用次数: 0
Assessing the Impact of an Operating Tailings Storage Facility on Catchment Surface and Groundwater Quality in the Ellembele District of the Western Region of Ghana 评估正在运行的尾矿储存设施对加纳西部地区埃伦贝莱区集水区地表和地下水质量的影响
Pub Date : 2016-09-29 DOI: 10.5539/EP.V5N2P26
E. Acheampong, D. Nukpezah
The study assessed the impact of an operating Tailings Storage Facility (TSF) of Adamus Resources Limited (Nzema Gold Mine) in the Ellembele District of the Western of Ghana on catchment surface and groundwater quality. Water samples were collected between June and December 2014 from seventeen (17) sampling sites including the TSF decant water (TSF-DW), three (3) streams, a water storage dam, a pond and eleven (11) groundwater monitoring boreholes within 500 m radius of the mine’s Tailings Storage Facility. Samples were analyzed for pH, true colour, electrical conductivity (EC), total dissolved solids (TDS), total suspended solids (TSS), biological oxygen demand (BOD), dissolved metals (arsenic, cadmium, copper, mercury) and cyanide (weak acid dissociable cyanide (WAD), free cyanide and total cyanide) using standard procedures. The TSF-DW reported elevated arsenic, free cyanide and TSS concentrations above GHEPA guideline for effluent discharge. Elevated TSS and arsenic concentrations above GHEPA limits were reported in PWSD which is a pond uphill of the TSF and a receptor to effluents from illegal mining sites on the mine’s concession. All other parameters recorded in surface and groundwater bodies studied were within WHO guideline limit for potable water. Results of the study suggest that the quality of surface and groundwater around the TSF has not been adversely affected even though the TSF is contaminated. Study findings suggest that well-engineered tailings dam ofARLwith its effective liner and management systems may have provided a safe structure and prevented contamination of water resources within its catchment.
该研究评估了加纳西部Ellembele地区Adamus资源有限公司(Nzema金矿)的尾矿储存设施(TSF)对集水区地表和地下水质量的影响。2014年6月至12月期间,从17个采样点采集了水样,包括TSF倒液水(TSF- dw)、3条溪流、1个蓄水坝、1个池塘和11个地下水监测钻孔,采样点位于该矿尾矿储存设施半径500米范围内。采用标准程序分析样品的pH、真色、电导率(EC)、总溶解固体(TDS)、总悬浮固体(TSS)、生物需氧量(BOD)、溶解金属(砷、镉、铜、汞)和氰化物(弱酸可解离氰化物(WAD)、游离氰化物和总氰化物)。据TSF-DW报告,砷、游离氰化物和TSS浓度升高,超过了GHEPA污水排放准则。据报道,在污水处理厂,TSS和砷的浓度超过了环保标准的限制。该处理厂是污水处理厂上坡的一个池塘,是矿山特许经营范围内非法采矿场废水的受体。所研究的地表水和地下水中记录的所有其他参数均在世卫组织饮用水指导限值之内。研究结果表明,即使污染了TSF,但TSF周围的地表水和地下水的质量并未受到不利影响。研究结果表明,精心设计的arl尾矿坝及其有效的衬砌和管理系统可能提供了一个安全的结构,并防止了其集水区水资源的污染。
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引用次数: 2
Risks of Domestic Underground Water Sources in Informal Settlement in Kabwe – Zambia 赞比亚Kabwe非正式住区家庭地下水源的风险
Pub Date : 2016-09-29 DOI: 10.5539/EP.V5N2P1
A. Phiri
Informal settlements are a hot spot for disaster risks worldwide. They are characterised by limited provision of basic services. Water being a critical life support resource is not adequately provided. Residents usually rely on unsafe water sources of hand dug wells. Pit latrines are a major facility for sanitary purposes. Further, informal settlements high population density residing in poor housing units is a common characteristics. Risks of underground water pollution are high due to the proximity of sanitation facilities to unprotected shallow wells increasing the possibility of feacal contamination by ecoli and coli form. This paper presents a case of Makululu informal settlement in Zambia. A total of 385 respondents were identified at random while purposive sampling identified key informants. Water samples collected from 12 hand dug wells located close to pit latrines were tested for coli form and ecoli. Testing was done before and after the rainy season to analyse the relationship between pit latrines and wells as well as the relationship with rainfall distribution pattern to ascertain levels of risks. Water was tested to determine the levels of contamination based on the presence of ecoli and coli form. Laboratory results indicated that 90 percent of water consumed in Makululu informal settlement is highly contaminated by faecal coliforms.
非正式定居点是全球灾害风险的一个热点。它们的特点是提供的基本服务有限。水是维持生命的重要资源,但供应不足。居民通常依靠不安全的手挖井水源。坑式厕所是一项主要的卫生设施。此外,非正式住区的共同特点是居住在简陋住房单元的人口密度高。由于卫生设施靠近无保护的浅井,增加了大肠杆菌和大肠杆菌形式的粪便污染的可能性,因此地下水污染的风险很高。本文介绍了赞比亚马库鲁鲁人非正式定居点的一个案例。共有385名受访者被随机识别,而有目的的抽样确定了关键的线人。从靠近坑式厕所的12口手挖井中采集的水样进行了大肠杆菌和大肠杆菌检测。在雨季前后进行测试,分析坑式厕所与水井之间的关系以及与降雨分布模式的关系,以确定风险水平。对水进行了检测,以确定是否存在大肠杆菌和大肠杆菌形式的污染程度。实验室结果表明,Makululu非正式住区所消耗的90%的水受到粪便大肠菌的严重污染。
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引用次数: 6
Effects of Land Use, Soil Depth and Topography on Soil Physicochemical Properties along the Toposequence at the Wadla Delanta Massif, Northcentral Highlands of Ethiopia 埃塞俄比亚中北部高地Wadla Delanta地块土地利用、土壤深度和地形对土壤理化性质的影响
Pub Date : 2016-09-29 DOI: 10.5539/EP.V5N2P57
Nahusenay Abate, K. Kibret
The study was conducted to investigate the effects of land use, depth and topography on soil physicochemical properties at the Wadla Delanta Massif, northcentral Ethiopia. Four land uses (natural forest, shrub, grazing and cultivated land), three soil depths (0-20, 20-40, 40-60 cm) and three topographic positions (upper, middle and lower) in three replications were considered for this study. A total of 108 composite samples were collected for laboratory analysis. The results show that particle size distribution was affected by the main effects of land use and soil depth; bulk and particle densities, total porosity, organic matter and total nitrogen contents, C:N ratio and available phosphorus were significantly affected by the interaction of land use by soil depth only, whereas, soil pH, electrical conductivity, exchangeable bases, cation exchange capacity, percent base saturation and extractable micronutrients were affected by the interaction effects of the three factors. Highest clay and bulk density were recorded at the bottom layer of the cultivated land soils, while the utmost porosity, organic matter and nitrogen contents, and available phosphorus were recorded at the surface layers of the natural forest land soils. Highest pH was at the bottom layer of the cultivated land at the three topographic positions. Highest exchangeable bases and cation exchange capacity were observed in the bottom layers of soils under the four land use types at the lower topographic position, whilst extractable micronutrients were recorded at the surface layers of the forest land soils at the upper topographic position. In general, most of the measured soil properties were measured better in forest than in other land use soils and the lower topographic positions than the upper and middle ones. Interaction of land use with topography showed negative effects especially on cultivated and grazing land soils in all topographic positions. Therefore, integrated soil fertility management and soil conservation measures are required in all topographic positions to maintain soil physicochemical properties.
在埃塞俄比亚中北部的Wadla Delanta地块,研究了土地利用、深度和地形对土壤理化性质的影响。研究考虑了3个重复的4种土地利用方式(天然林、灌丛、放牧和耕地)、3种土壤深度(0-20、20-40、40-60 cm)和3种地形位置(上、中、下)。共采集108份复合样品进行实验室分析。结果表明:土壤粒径分布受土地利用方式和土壤深度的主要影响;土壤体积和颗粒密度、总孔隙度、有机质和全氮含量、C:N比和速效磷仅受土壤深度的交互作用显著影响,土壤pH、电导率、交换碱、阳离子交换容量、碱饱和度百分比和可提取微量元素受3个因素的交互作用影响。耕地土壤的黏度和容重在底层最高,而孔隙度、有机质、氮含量和有效磷在表层最高。3个地形位置的土壤pH值均以耕地底层最高。4种土地利用方式下,下层土壤交换碱和阳离子交换容量最高,上层林地土壤表层可提取微量元素含量最高。总体而言,森林土壤的大部分性质测量结果优于其他土地利用土壤,地形位置较低的土壤性质测量结果优于地形位置较高和中部的土壤性质测量结果。土地利用与地形的交互作用对所有地形位置的耕地和放牧土壤均有负面影响。因此,需要在所有地形位置进行综合土壤肥力管理和土壤保持措施,以保持土壤的理化性质。
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引用次数: 19
Determination of Polycyclic Aromatic Hydrocarbons in Cigarettes and Cigarette Smoke 卷烟和烟气中多环芳烃的测定
Pub Date : 2016-09-29 DOI: 10.5539/EP.V5N2P15
H. Shimazu
The present study examines the concentrations of polycyclic aromatic hydrocarbons (PAHs) in cigarettes and sidestream cigarette smoke. Nine PAHs were determined in sidestream cigarette smokes for five types of cigarettes. The volume of the experimental room is approximately 66 m 3 . The air samples in the room were collected before and after smoking. The total PAH concentrations were approximately 1.0 ng/m 3 before smoking, but the median concentration and the range of PAHs were 29.1 ng/m 3 and from 7.62 to 57.6 ng/m 3 after smoking. The relationship between suspended particulate matter (SPM) and total PAHs after smoking is significant and proportional. This may indicate that the SPM formation is associated with PAH formation during smoking. Furthermore, nine PAHs were determined in the cigarettes. Median PAH contents in the five brands of cigarettes ranged from 221 to 936 ng per cigarette before smoking and from 66.9 to 266 ng per cigarette after smoking. Mean PAH emissions from cigarettes while smoking ranged from 257 to 1490 ng per cigarette. The results show that PAHs in the cigarettes, and those generated during smoking, were emitted into the air.
本研究检测了香烟和侧流香烟烟雾中多环芳烃(PAHs)的浓度。在5种卷烟的侧流烟气中检测出9种多环芳烃。实验房间的体积约为66平方米。吸烟前后分别采集了室内空气样本。吸烟前多环芳烃总浓度约为1.0 ng/m 3,吸烟后多环芳烃中位浓度为29.1 ng/m 3,吸烟后多环芳烃中位浓度范围为7.62 ~ 57.6 ng/m 3。吸烟后空气中悬浮颗粒物(SPM)与总多环芳烃(PAHs)呈显著正比关系。这可能表明吸烟期间SPM的形成与多环芳烃的形成有关。此外,在卷烟中检测到9种多环芳烃。五种品牌香烟的多环芳烃含量中位数在吸烟前为每支221至936纳克,吸烟后为每支66.9至266纳克。吸烟时香烟的多环芳烃平均排放量为每根香烟257至1490纳克。结果表明,香烟中的多环芳烃以及吸烟过程中产生的多环芳烃被排放到空气中。
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引用次数: 6
Extending the Applications of the ADM1 to Predict Performance of the Induced Bed Reactor (IBR) Co-Digesting Municipal Sludge with Bakery Waste 扩展ADM1在诱导床反应器(IBR)共消化城市污泥与烘焙废弃物性能预测中的应用
Pub Date : 2016-09-29 DOI: 10.5539/EP.V5N2P41
M. E. Demitry, C. Hansen, D. Stevens, M. Mcfarland
The goal of this research was to examine the stability of the induced bed reactor (IBR) digesting municipal sludge (MS) mixed with bakery waste (BW) by experiment and modeling. It was necessary to modify the Anaerobic Digestion Model number1(ADM1) to accurately predict the performance of the IBR for this mixed waste. The total mixed influent COD was 50 g/L with hydraulic retention times that varied from 27 to 6 days at mesophilic temperatures. The reactor reached the steady state at each HRT with no sign of inhibition or failure, however, the COD removal efficiency of the digester decreased from 92% to 72% with decreasing HRT. The modified ADM1 outputs agreed well with the measured stability indicators (pH, total volatile fatty acid (TVFA), Q (gas production), percent CH4 at the longer retention times of 27, and 20 days. The model overestimated the pH, and methane percentage and underestimated the TVFA when the HRT was shorter (12, 9 and 6 days). However, the model predicted well the trends of the observed data and the overall stability process of the digester until 6 d HRT. This research provided an alternative for the disposal of industrial bakery waste and also pointed out the ability of the IBR to manage high waste loads stably, while providing high energy production.
本研究的目的是通过实验和模型研究诱导床反应器(IBR)消化城市污泥(MS)与面包废弃物(BW)混合的稳定性。为了准确预测IBR处理该混合废物的性能,需要对厌氧消化模型1(ADM1)进行修改。在中温条件下,混合进水COD总量为50 g/L,水力停留时间为27 ~ 6天。各HRT下反应器均达到稳定状态,无抑制或失效迹象,但随着HRT的降低,沼气池COD去除率由92%下降至72%。在27天和20天的保留时间内,改进的ADM1输出值与测量的稳定性指标(pH、总挥发性脂肪酸(TVFA)、Q(产气量)、CH4百分比)吻合良好。当HRT较短(12、9和6 d)时,模型高估了pH和甲烷百分比,低估了TVFA。然而,该模型很好地预测了观测数据的趋势和蒸煮池整体稳定过程,直到6 d HRT。本研究为工业烘焙废弃物的处理提供了一种替代方案,也指出了IBR在提供高能量生产的同时稳定管理高废物负荷的能力。
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引用次数: 1
Designating Marine Reserves Is not Just an Ecological Process 划定海洋保护区不仅仅是一个生态过程
Pub Date : 2016-09-29 DOI: 10.5539/EP.V5N2P72
Jing Li
Marine natural resource and ocean species are endangered because of human activities. In order to avoid marine natural resource depletion and recover marine ecosystem, marine reserves are created. The report will introduce the marine reserve definition and its functions. In addition, the report will describe three main marine reserves in Australia. Moreover, it will explain why designating marine reserves is not an ecological process.
由于人类活动,海洋自然资源和海洋物种濒临灭绝。为了避免海洋自然资源枯竭,恢复海洋生态系统,建立了海洋保护区。报告将介绍海洋保护区的定义及其功能。此外,报告还将介绍澳大利亚的三个主要海洋保护区。此外,它将解释为什么指定海洋保护区不是一个生态过程。
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引用次数: 0
Some Elemental Content of Soil Within Catchment of River Jakara in Kano, Nigeria 尼日利亚卡诺贾卡拉河流域土壤元素含量研究
Pub Date : 2016-04-28 DOI: 10.5539/EP.V5N1P119
Dike N. I., S. Oniye
The use of untreated urban wastes and domestic sewage contaminated water for the irrigation of agricultural soils is on the rise particularly in the developing countries and is a public health concern with regards to the consumption of vegetables and fruits produced in them which may indirectly accumulate heavy metals in their edible portions. Using the atomic absorption spectrophotometry (AAS), concentrations of Ca, Mg, Na, K (essential bulk elements), Pb, Cd, Cr, Ni, Cu, Zn, Co and Fe (trace elements) were determined in 3 designated areas within the catchment area of River Jakara in Kano Nigeria. Samples were collected from two depths 0-15cm and 15-30cm to cover both dry and wet seasons. The mean concentrations of elements obtained ranged from 0.026 mg/g Cd to 46.83 mg/g Fe and occurred in the magnitude of Fe > Ca > K > Na > Pb >Zn > Co > Cu >Cr > Ni > Cd. The concentrations of the trace elements in the soils in the two depths exceeded the international recommended permissible limits establishing the pollution of the irrigation soils with the trace elements investigated. Based on the findings, it is recommended among others that the relevant organ of government should find an alternative farmland for the farmers within the catchment area of River Jakara where unpolluted waste sources can be utilized for the irrigation of vegetables.
使用未经处理的城市废物和受生活污水污染的水灌溉农业土壤的情况正在增加,特别是在发展中国家,这是一个公共健康问题,因为食用这些地区生产的蔬菜和水果可能间接地在其可食用部分积累重金属。采用原子吸收分光光度法(AAS)测定了尼日利亚卡诺贾卡拉河流域3个指定区域内Ca、Mg、Na、K(必需体积元素)、Pb、Cd、Cr、Ni、Cu、Zn、Co和Fe(微量元素)的浓度。样品采集深度分别为0-15cm和15-30cm,覆盖旱季和雨季。所得元素的平均浓度范围为0.026 mg/g Cd ~ 46.83 mg/g Fe,其量级为Fe > Ca > K > Na > Pb >Zn > Co > Cu >Cr > Ni > Cd。这两种深度土壤中微量元素的浓度均超过了国际推荐的允许限度,从而确定了所调查的灌溉土壤中微量元素的污染程度。根据调查结果,除其他外,建议政府有关机关为贾卡拉河集水区内的农民寻找替代农田,在那里可以利用未受污染的废物来源灌溉蔬菜。
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引用次数: 0
Seasonal Nearshore Occurrence of the Neurotoxin β-N-methylamino-L-alanine (BMAA) in Lake Winnipeg, Canada 加拿大温尼伯湖近岸神经毒素β- n -甲氨基- l -丙氨酸(BMAA)的季节性发生
Pub Date : 2016-04-28 DOI: 10.5539/EP.V5N1P110
E. Pip, Kimber E. Munford, L. Bowman
Seasonal fluctuation patterns of the neurotoxic amino acid β N methylamino L alanine (BMAA) were examined at four-day intervals during the ice-free season in water at three nearshore stations in the south basin of Lake Winnipeg, Canada. BMAA patterns were significantly exponentially correlated with concurrent phaeophytin, and inversely with chlorophyll a, indicating that free BMAA concentrations increased as blooms declined. BMAA was also significantly related to preceding microcystin concentrations, and as chlorophyll a declined, the proportion of BMAA relative to microcystin increased. Cross correlations identified significant relationships between BMAA and immediately preceding nitrate-N/inorganic phosphorus ratios, nitrate-N, rainfall, and a marginal inverse correlation with inorganic phosphorus. Total suspended solids levels were also significantly associated with BMAA, likely due to shading effects. A very high BMAA concentration was found under collapse of intense bloom conditions. These results have implications for water quality monitoring, nutrient management strategies and public health.
在加拿大温尼伯湖南部盆地的三个近岸站,每隔4天检测了无冰季节水体中神经毒性氨基酸β N甲基氨基L丙氨酸(BMAA)的季节波动模式。BMAA模式与并发的褐藻素呈极显著指数相关,与叶绿素a呈负相关,表明游离BMAA浓度随花华减少而增加。BMAA也与前期微囊藻毒素浓度显著相关,并且随着叶绿素a的降低,BMAA相对于微囊藻毒素的比例增加。交叉相关发现,BMAA与前一阶段的硝酸盐- n /无机磷比率、硝酸盐- n、降雨量之间存在显著相关性,与无机磷之间存在边际负相关。总悬浮固体水平也与BMAA显著相关,可能是由于遮阳效应。在强花塌条件下,BMAA浓度非常高。这些结果对水质监测、营养物管理策略和公共卫生具有重要意义。
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引用次数: 12
Implementation and Evaluation of a Communication Strategy to Control Ragweed Pollen 豚草花粉传播策略的实施与评价
Pub Date : 2016-04-28 DOI: 10.5539/EP.V5N1P87
C. Plante, A. Smargiassi, F. Hubert, Sophie Goudreau
The common ragweed ( Ambrosia artemisiifolia ) is widespread in southwestern areas of Quebec, Canada. It is known to release large quantities of pollen from July through September, triggering allergic reactions such as rhinitis and generating significant costs for public health. The objective of this study was to implement and evaluate a communication intervention aimed at decreasing ragweed pollen. Selected lands with potential ragweed presence were visited twice, before and after the intervention, on three seasons in the East of the Montreal Island, Quebec. At the first visit done in 2010, 2011, and 2012, ragweed plots were located and measured; at the second visit in 2012, the measures were redone. Various numbers of communications were sent to owners of ragweed-infested lands that included explanations of health impacts of ragweed pollen and the importance of mowing. Mixed logistic regressions were used to test the effect of the number of communications on the mow. In the group that received four notices, a statistically significant three-fold increase in the proportion of land owners that had cut ragweed plots (OR = 3.20; 95 %CI: 1.16-8.84) was noted, compared to the group that received only one notice. For owners of vacant lands, the effect was somewhat more pronounced (OR = 3.82; 95%CI: 1.23-11.67). Nonetheless, the change from one to three communications showed no increase of mowing. In conclusion, the results of the present study suggest that communications and reminders of the importance of ragweed cut to landowners could be an effective measure to limit ragweed pollen.
普通豚草(Ambrosia artemisiifolia)广泛分布于加拿大魁北克省的西南部地区。众所周知,从7月到9月,它会释放大量花粉,引发鼻炎等过敏反应,并给公众健康造成巨大损失。本研究的目的是实施和评价一种旨在减少豚草花粉的传播干预。在干预之前和之后,在魁北克蒙特利尔岛东部的三个季节中,对可能存在豚草的选定土地进行了两次访问。在2010年、2011年和2012年的第一次访问中,对豚草地块进行了定位和测量;在2012年的第二次访问中,这些措施被重新制定。向豚草丛生的土地的所有者发送了各种数量的通信,其中包括豚草花粉对健康的影响以及割草的重要性的解释。使用混合逻辑回归来检验通信数量对现在的影响。在收到四份通知的小组中,有割豚草地块的土地所有者比例增加了三倍(OR = 3.20;95% CI: 1.16-8.84),与只收到一次通知的组相比。对于空置土地的所有者,影响更为明显(OR = 3.82;95%置信区间:1.23—-11.67)。尽管如此,从一次通信到三次通信的变化并没有显示出刈割的增加。综上所述,本研究结果表明,向土地所有者宣传和提醒割草的重要性可能是限制豚草花粉的有效措施。
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引用次数: 2
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Environment and Pollution
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