Environmental Geochemistry and Health最新文献

Multilayer composite soil chamber was proposed to extract the Cr of contaminated site soil and insight into transformation of Cr fractionation associated with valence states. The variations of current, soil pH and moisture content were explored, as well as the migration of Cr fractionation and redistribution of Cr. Results indicated that duration of half peak current could be used to adjust treatment time and it varied among different composite ways. Moreover, extraction efficiency of Cr in soil near cathode was relatively higher and reached 60% when citric acid was used. Citric acid could promote the transformation between different Cr fractionations or different valence states. It could also improve the desorption of Cr, and could prevent excessive fluctuations of moisture content at the same time. Cr redistributed acrossed the soil chamber after extraction. When deionized water was used, Cr(VI) significantly migrated toward anode mainly in the form of exchangeable fractionation (EXC) while Fe-Mn oxides fractionation (Fe-Mn) which may be in the form of cationic Cr(III) hydroxides migrated toward cathode. When using citric acid, fractionations that were difficult to migrate of Cr, especially for Fe-Mn in site soils could be activated and became EXC and carbonate fractionation (CAR), then migrated to the anode or cathode. The migration of exchangeable Cr(III) was dramatically enhanced. But the use of citric acid could cause Cr(VI) transformation to Cr(III) near anode. In addition, during the migration process, EXC could go back to Fe-Mn again or transform to residue fractionation (RES).

The issue of heavy metal pollution is a critical global concern that requires urgent solution. However, conventional heavy metal adsorbents are too costly to be applied in large-scale engineering. In this study, adsorption behavior and mechanism of sintering red mud (RM-A) and bayer red mud (RM-B) for heavy metals were investigated to address the disposal of red mud as industrial waste and remediation of heavy metal pollution. Batch adsorption experiments were conducted to explore the adsorption performances of RM-A and RM-B under various conditions. Characterization of RM-A and RM-B before and after adsorption by XRD, FTIR and SEM-EDX was applied to investigate the specific adsorption behavior and mechanism. Adsorption experiments of both RM-A and RM-B fitted pseudo-second-order kinetic model and Langmuir isotherm model, with estimated maximum adsorption capacity of 21.96 and 25.19 mg/g for Cd²⁺, 21.47 and 26.06 mg/g for Cu²⁺ and 55.47 and 59.65 mg/g for Pb²⁺, respectively. Precipitation transformation of calcite was the primary adsorption mechanism for RM-A, whereas ion exchange of cancrinite, surface coordination compounds of hematite and minor precipitation transformation of calcite accounted for the adsorption mechanism for RM-B. Overall, RM-A and RM-B exhibited best adsorption performance for Pb²⁺, with RM-B showing greater adsorption capacity attributed to its higher specific surface area. This study compared the adsorption properties of RM-A and RM-B for the first time and demonstrated that both red muds can be effectively applied to remove heavy metals, thereby contributing to the sustainable industrial waste management and resourceful reuse.

The increasing contamination of aquatic bodies by heavy metals poses a significant threat to environment and human health, necessitates innovative, sustainable and cost-effective remediation strategies. Due to their persistence and toxicity, heavy metals like copper (Cu), lead (Pb), mercury (Hg), and cadmium (Cd) pose severe threats, even in trace amounts. Traditional removal methods of these heavy metals, like chemical precipitation, oxidation/reduction, filtration, ion exchange, membrane separation, and adsorption, are costly, inefficient, and have drawbacks. As an efficient and low-cost adsorbent, biochar has the potential for heavy metal remediation from water. Biochar is a versatile carbonaceous material produced through pyrolysis of organic wastes, emerged as a powerful adsorbent for heavy metal removal from contaminated water. The unique property of biochar makes it an effective medium immobilizing and capturing of heavy metals like Pb, Cd, As and Hg. Various factors affect its adsorption potential and capacity. Feedstocks type, composition, activation methods, and production processes including the pyrolysis temperature, temperature rate and residence time significantly impact the efficacy of biochar. Therefore, this review has assessed, compared, and contrasted different forms of biochar along with their production methods, modification techniques and mechanisms for their potential use as an adsorbent for heavy metal removal from the contaminated water. Modified biochar offers an environmentally friendly and cost-effective solution for water purification and remediation of toxic heavy metals from water. This review highlights the biochar potential as a crucial component for future research projects focusing on water treatment technologies, providing avenues for safer and cleaner water resources.

Artisanal gold mining can lead to soil contamination with potentially toxic elements (PTEs), necessitating soil quality monitoring due to environmental and human health risks. However, determining PTE levels through acid digestion is time-consuming, generates chemical waste, and requires significant resources. As an alternative, portable X-ray fluorescence (pXRF) offers a faster, more cost-effective, and sustainable analysis. This study compared total As, Ba, Cr, Cu, Fe, Mn, Ni, Pb, Sr, Ti, V, and Zn obtained from pXRF with their pseudo-total contents obtained through acid digestion (USEPA method 3051A) in areas influenced by artisanal gold mining in the Eastern Amazon, Brazil. pXRF data and machine learning algorithms were used to predict extractable Cu, Fe, Mn, and Zn. Linear regression models were fitted to compare the two methods, and random forest and support vector machine techniques were used to predict extractable contents. The best regression model fits for the pseudo-total PTE contents were those for Cu, Fe, Mn and Pb in agricultural areas (R² > 0.80); Fe and Mn in gold mining residue (R² > 0.70); and Ba, Cu and Mn in urban areas (R² > 0.80). The best models for predicting the extractable PTE contents were those for Cu (R² = 0.72; RMSE = 2.58 mg dm^-3) and Zn (R² = 0.71; RMSE = 1.44 mg dm^-3) in agricultural areas and for Zn (R² = 0.72; RMSE = 0.43 mg dm^-3) in gold mining residue. The results demonstrated that pXRF can characterize and predict PTE contents in mining-impacted areas, offering a sustainable approach to soil quality analysis.

Due to environmental pollution, the risk of cadmium stress for crops is soaring, so researchers are exploring inexpensive solutions to enhance cultivated crops in contaminated soil. Using microorganisms to reduce cadmium risk has been one of the most effective strategies in recent decades. Serendipita indica (Piriformospora indica) is one of the best endophyte fungi that, in addition to reducing heavy metal stress for crops, can significantly reduce the threat of other abiotic stresses. As part of this research, cadmium in soil has been investigated, as well as its effects on plants' morphophysiological and biochemical characteristics. The present review has also attempted to identify the role of Serendipita indica in improving the growth and performance of crops, as well as its possible effect on reducing the risk of cadmium. The results showed that Serendipita indica enhance the growth and productivity of plants in contaminated environments by improving soil quality, reducing cadmium absorption, improving the activity of antioxidant enzymes and secondary metabolites, raising water and mineral absorption, and altering morphophysiological structures.

The risk of arsenic contamination is rising globally, and it has negative impacts on the physiological processes and growth of plants. Metal removal from contaminated soils can be accomplished affordably and effectively with plant growth promoting rhizobacteria (PGPR)-based microbial management. From this angle, this research evaluated the mitigation of arsenic toxicity using the bacteria isolated from contaminated site, Mettur, Salem district, South India. The newly isolated bacterial strain was screened for plant growth promotion potential and arsenic tolerance such as (100 ppm, 250 ppm, 500 ppm, 800 ppm and 1200 ppm). The metal tolerant rhizobacteria was identified using 16S rRNA gene sequence analysis as Pseudomonas alcaliphila strain PAS1 (GenBank accession number: OQ804624). Pigeon pea (Cajanus cajan) plants were used in pot culture experiments with varying concentrations of arsenic, (5 ppm, 10 ppm and 25 ppm) both with and without bacterial culture, for a period of 45 days. At the concentration of 25 ppm after the application of PAS1 enhanced the plant growth, protein and carbohydrate by 35.69%, 18.31% respectively. Interestingly, P. alcaliphila strain PAS1 significantly reduced the stress-induced elevated levels of proline, flavonoid, phenol and antioxidant enzyme in pigeon pea plants was 40%, 31.11%, 27.80% and 20.12%, respectively. Consequently, PAS1 may significantly reduce the adverse effects that arsenic causes to plant development in acidic soils, improve plant uptake of nutrients, and increase plant production. The findings of this study reveal that P. alcaliphila PAS1 is intrinsic for phytoremediation by reducing arsenic accumulation in the root and shoot.

Soil contamination of heavy metals in urban greenspaces can exert detrimental impacts on ecological biodiversity and the health of inhabitants through cross-media migration-induced risks. Here, a total of 72 topsoil samples were collected from greenspaces in the popular tourist city of Tianshui, ranging from areas with parks, residential, road, industrial and educational soils. The study aimed to evaluate an integrated source-specific ecological and human health risk assessment of heavy metals. Among the analyzed heavy metals, except Cr (mean), all exceeded the local background values by 1.30-5.67-fold, and Hg, Cd, Pb and As were the metals with large CV values. The I_geo and CF results showed Hg, Cd, As and Pb exhibited significantly high pollution levels and were the primary pollution factors. The mean PLI values indicated moderate pollution in educational (2.21), industrial (2.07), and road (2.02) soils but slight pollution in park (1.84) and residential (1.39) greenspaces. The I_geo, CF, and PLI results also revealing that these heavy metals are more likely to be affected by human activity. Four primary source factors were identified based on PMF model: coal combustion (25.57%), agricultural sources (14.49%), atmospheric deposition (20.44%) and mixed sources (39.50%). In terms of ecological risk, the mean IRI values showed considerable risks in educational soils (287.52) and moderate risks in road (215.09), park (151.27) and residential (136.71) soils. And the contribution ratio of atmospheric deposition for park, residential, road, industrial and educational greenspaces were 57.72%, 65.41%, 67.69%, 59.60% and 75.76%, respectively. In terms of human health risk, the HI (below 1) and CR (below 1.00E-04) for adults from soils of all land use types was negligible. However, children have more significant non-carcinogenic and carcinogenic hazards especially in residential soils, the HI (above 1) and CR (above 1.00E-04) revealed the significance of regarding legacy As contamination from coal combustion when formulating risk mitigation strategies in this area. The proposed method for source and risk identification makes the multifaceted concerns of pollution and the different relevant risks into a concrete decision-making process, providing robust support for soil contamination control.

Soil salinization poses a significant ecological challenge, emerging as a critical constraint to agricultural development in the arid and semi-arid regions of China, especially in southern Xinjiang. In particular, Yuepuhu County, situated in Kashgar, faces a distinctive issue. Impermeable thin clay layers within the vadose zone impede year-round leaching of salts, significantly impacting the growth of cotton. Through a combination of indoor testing, experiments, and statistical analyses, this study elucidated the varying permeability of soil layers at different depths and explored the forms and accumulation characteristics of soil salts in Yuepuhu County. It unveiled patterns of water and salt movement in soils with variable permeability layers, identifying key influencing factors. The research also proposed an irrigation regime suitable for cultivating vadose zone soils in the local context. The findings revealed a progression of increasing soil complexity and decreasing burial depth of clay layers from northwest to southeast, aligned with the direction of groundwater flow. With increasing depth, a noticeable reduction in soil saturated hydraulic conductivity was observed, indicating significant variability in permeability. Predominantly chloride-sulfate type saline soils in Yuepuhu County contained potassium (K⁺) and sodium (Na⁺) as the main cations in surface soils. Salinity strongly correlated with calcium (Ca²⁺) and magnesium (Mg²⁺). Chloride (Cl^-), sulfate (SO₄^2-), K⁺, Na⁺, and bicarbonate (HCO₃^-) reflected the degree of soil salinization in Yuepuhu County. The clay interlayers in variable permeability zones significantly impeded water and salt movement in the vadose zone. Moving from west to east, thicker and shallower clay interlayers hindered downward water movement, increasing the difficulty of salt leaching. Additionally, the irrigation regime influenced water and salt movement in the vadose zone. Under the same soil structure, flood irrigation with a higher water flux resulted in more significant salt leaching, and lower total dissolved solids (TDS) in irrigation water were more favorable for effective salt leaching. Collectively, our findings provided a theoretical foundation for improving and managing local saline soils, as well as guiding the implementation of rational agricultural irrigation practices.

Nitrosamines and semi-volatile organic compounds (SVOCs) are carcinogenic contaminants in water and biological matrices. Conventional analytical methods often struggle to detect trace concentrations due to poor extraction efficacies. This study presents a novel, low-cost, in-syringe-assisted fast extraction cum cleanup technique coupled with GC-FID for monitoring four nitrosamines and two SVOCs in drinking water and human urine samples to measure the contamination and exposure levels. This extraction protocol combines a novel green in-syringe liquid-liquid extraction step using dimethyl carbonate as the green extraction solvent, coupled with a semi-automated solid-phase extraction cleanup process. Then, the final extractant is analyzed using gas chromatography-flame ionization detection (GC-FID) for monitoring. The method demonstrated excellent linearity (R² > 0.998) between 1.5 and 500 ng mL⁻¹ for all six target compounds. Detection limits ranged from 1.0 to 2.0 ng mL⁻¹. Extraction recoveries were between 87 and 105% for both urine samples and water samples. Intra-day and inter-day precision were below 9% RSD. The blue applicability grade index evaluation scored 70.0, indicating good practical applicability. The developed analytical protocol offers a sensitive, accurate, low-cost, rapid, and environmentally friendly method for simultaneously quantifying multiple nitrosamines and SVOCs in environmental and human samples. Its performance characteristics and sustainability metrics suggest the potential for broad application in monitoring and exposure studies.

Rice is susceptible to cadmium (Cd) accumulation, which poses a threat to human health. Traditional methods for mitigating moderately contaminated soils can be impractical or prohibitively expensive, necessitating innovative approaches to reduce Cd uptake in rice. Nutrient management has emerged as a promising solution by leveraging the antagonistic interactions between nutrients and cadmium. However, the research on the synergistic effects of multiple nutrients on Cd toxicity in rice is limited. To address this limitation, pot experiments was utilized to investigate the combined effects of selenium (Se), calcium (Ca), and magnesium (Mg) denoted as (SeCM) on Cd uptake and translocation in rice. The synergistic application of SeCM reduced grain Cd levels by 55.0%, surpassing the individual effects of Se (42.1%) and CM (40.5%), and bringing Cd content below the safe consumption limits. SeCM treatment exhibited multiple beneficial effects: it decreased malondialdehyde (MDA) levels, enhanced catalase (CAT), peroxidase (POD) and glutathione (GSH) enzyme activities, limited Cd translocation from roots to shoots, promoted iron plaque formation, and reduced Cd transfer from soil to iron plaque and subsequently to rice grains. Correlation analysis revealed strong negative relationships between rice Cd content, Cd translocation factors, and the translocation factors of selenium, calcium, and magnesium. These findings suggest that selenium, calcium, and magnesium collaboratively mitigate Cd toxicity through antagonistic and competitive interactions. These nutrients enhance the uptake of beneficial elements, while competitively inhibiting the translocation and accumulation of Cd in rice plants. SeCM application offers a promising strategy for producing nutrient-rich, and Cd-safe rice in contaminated soils.