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Identification of Stable Intermetallic Compounds for Hydrogen Storage via Machine Learning
Pub Date : 2025-01-06 DOI: 10.1002/est2.70115
A. S. Athul, Aswin V. Muthachikavil, Venkata Sudheendra Buddhiraju, Karundev Premraj, Venkataramana Runkana

Hydrogen is one of the most promising alternatives to fossil fuels for energy as it is abundant, clean and efficient. Storage and transportation of hydrogen are two key challenges faced in utilizing it as a fuel. Storing H2 in the form of metal hydrides is safe and cost effective when compared to its compression and liquefaction. Metal hydrides leverage the ability of metals to absorb H2 and the stored H2 can be released from the hydride by applying heat when needed. A multi-step methodology is proposed to identify intermetallic compounds that are thermodynamically stable and have high hydrogen storage capacity (HSC). It combines compound generation, thermodynamic stability analysis, prediction of properties of the metal hydride and ranking of discovered materials based on predicted properties. The US Department of Energy (DoE) Hydrogen Storage Materials Database and the Open Quantum Materials Database (OQMD) are utilized for building and testing machine learning (ML) models for enthalpy of formation of the intermetallic compounds, stability analysis, and enthalpy of formation, equilibrium pressure and HSC of metal hydrides. The models proposed here require only attributes of elements involved and compositional information as inputs and do no need any experimental data. Random forest algorithm was found to be the most accurate amongst the ML algorithms explored for predicting all the properties of interest. A total of 349 772 hypothetical intermetallic compounds were generated initially, out of which, only 8568 compounds were found to be stable. The highest predicted HSC of these stable compounds was found to be 3.6. Magnesium, Lithium and Germanium constitute majority of the high HSC compounds. The predictions of HSC using the present models for metal hydrides that are not in the DoE database were reasonably close to the experimental data published recently but there is scope for improvement in prediction accuracy for metal hydrides with high HSC. The findings of this study will be useful in reducing the time required for development and discovery of new hydrogen storage materials and can be used to check the practical applicability of the hydride compound using the predicted properties.

{"title":"Identification of Stable Intermetallic Compounds for Hydrogen Storage via Machine Learning","authors":"A. S. Athul,&nbsp;Aswin V. Muthachikavil,&nbsp;Venkata Sudheendra Buddhiraju,&nbsp;Karundev Premraj,&nbsp;Venkataramana Runkana","doi":"10.1002/est2.70115","DOIUrl":"https://doi.org/10.1002/est2.70115","url":null,"abstract":"<div>\u0000 \u0000 <p>Hydrogen is one of the most promising alternatives to fossil fuels for energy as it is abundant, clean and efficient. Storage and transportation of hydrogen are two key challenges faced in utilizing it as a fuel. Storing H<sub>2</sub> in the form of metal hydrides is safe and cost effective when compared to its compression and liquefaction. Metal hydrides leverage the ability of metals to absorb H<sub>2</sub> and the stored H<sub>2</sub> can be released from the hydride by applying heat when needed. A multi-step methodology is proposed to identify intermetallic compounds that are thermodynamically stable and have high hydrogen storage capacity (HSC). It combines compound generation, thermodynamic stability analysis, prediction of properties of the metal hydride and ranking of discovered materials based on predicted properties. The US Department of Energy (DoE) Hydrogen Storage Materials Database and the Open Quantum Materials Database (OQMD) are utilized for building and testing machine learning (ML) models for enthalpy of formation of the intermetallic compounds, stability analysis, and enthalpy of formation, equilibrium pressure and HSC of metal hydrides. The models proposed here require only attributes of elements involved and compositional information as inputs and do no need any experimental data. Random forest algorithm was found to be the most accurate amongst the ML algorithms explored for predicting all the properties of interest. A total of 349 772 hypothetical intermetallic compounds were generated initially, out of which, only 8568 compounds were found to be stable. The highest predicted HSC of these stable compounds was found to be 3.6. Magnesium, Lithium and Germanium constitute majority of the high HSC compounds. The predictions of HSC using the present models for metal hydrides that are not in the DoE database were reasonably close to the experimental data published recently but there is scope for improvement in prediction accuracy for metal hydrides with high HSC. The findings of this study will be useful in reducing the time required for development and discovery of new hydrogen storage materials and can be used to check the practical applicability of the hydride compound using the predicted properties.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143112494","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improving Electric Vehicle Air-Cooled Cylindrical Battery Temperature Control Systems: A Computational Fluid Dynamics (CFD) Study of an Innovative Uniform Flow Distribution Plate
Pub Date : 2025-01-06 DOI: 10.1002/est2.70108
Shweta S. Suryavanshi, P. M. Ghanegaonkar

Temperature significantly affects the operation of lithium-ion batteries in electric vehicles (EVs). A battery temperature management system (BTMS) is necessary for battery safety and extended lifespan. This study proposes an innovative flow circulation technique to achieve uniform airflow distribution throughout the 26 650 cylindrical cells arranged in a 5P5S configuration. The 3D models of nine aluminum perforated plates with varying topologies have been developed to identify a more effective cooling method for rectangular battery packs. The CFD simulations examine the effects of air velocities, air inlet temperatures, C rate, and cell spacing (L) on the nine-plate structure. Optimal cooling is achieved with 2 mm cell spacing, evenly dispersing airflow and enhancing heat dissipation. An investigation has been conducted for various C rates. The best thermal performance is obtained at air speeds of 0.8 m/s for 0.5 C, 5 m/s for 1C, and 30 m/s for 2C. The outcome shows that altering the flow distribution layout is a practical way to improve the BP's cooling capacity.

{"title":"Improving Electric Vehicle Air-Cooled Cylindrical Battery Temperature Control Systems: A Computational Fluid Dynamics (CFD) Study of an Innovative Uniform Flow Distribution Plate","authors":"Shweta S. Suryavanshi,&nbsp;P. M. Ghanegaonkar","doi":"10.1002/est2.70108","DOIUrl":"https://doi.org/10.1002/est2.70108","url":null,"abstract":"<div>\u0000 \u0000 <p>Temperature significantly affects the operation of lithium-ion batteries in electric vehicles (EVs). A battery temperature management system (BTMS) is necessary for battery safety and extended lifespan. This study proposes an innovative flow circulation technique to achieve uniform airflow distribution throughout the 26 650 cylindrical cells arranged in a 5P5S configuration. The 3D models of nine aluminum perforated plates with varying topologies have been developed to identify a more effective cooling method for rectangular battery packs. The CFD simulations examine the effects of air velocities, air inlet temperatures, C rate, and cell spacing (L) on the nine-plate structure. Optimal cooling is achieved with 2 mm cell spacing, evenly dispersing airflow and enhancing heat dissipation. An investigation has been conducted for various C rates. The best thermal performance is obtained at air speeds of 0.8 m/s for 0.5 C, 5 m/s for 1C, and 30 m/s for 2C. The outcome shows that altering the flow distribution layout is a practical way to improve the BP's cooling capacity.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143112496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance Analysis of Supercapacitors With Graphene and Graphyne Electrodes
Pub Date : 2025-01-06 DOI: 10.1002/est2.70114
Henrique de Araujo Chagas, Thaciana Malaspina, Eudes Eterno Fileti, Guilherme Colherinhas

Graphene and graphyne electrodes exhibit considerable relevance in electrochemical energy storage applications owing to their distinct physical and chemical characteristics. Graphyne has garnered increased attention due to its larger specific surface area, enhanced electronic mobility, and intrinsic band gap compared to graphene. Our analyses unveil pertinent aspects of graphyne electrodes in interaction with ionic liquid (Emim-BF4) and aqueous salt (NaCl) solution based electrolytes. Despite the existing body of research on graphyne, there remains a gap in the comprehensive analysis of its performance as an electrode for supercapacitors and its interactions with electrolyte. In this investigation, molecular dynamics were employed to explore properties of graphene/graphyne electrodes based supercapacitors. The characteristics of the EDL are elucidated through structural and energetic analyses, while the capacitive performance of the devices is discussed in light of electrostatic properties, total capacitance, and storage energy density. Throughout the analysis, key differences and underlying similarities between the models are delineated.

{"title":"Performance Analysis of Supercapacitors With Graphene and Graphyne Electrodes","authors":"Henrique de Araujo Chagas,&nbsp;Thaciana Malaspina,&nbsp;Eudes Eterno Fileti,&nbsp;Guilherme Colherinhas","doi":"10.1002/est2.70114","DOIUrl":"https://doi.org/10.1002/est2.70114","url":null,"abstract":"<div>\u0000 \u0000 <p>Graphene and graphyne electrodes exhibit considerable relevance in electrochemical energy storage applications owing to their distinct physical and chemical characteristics. Graphyne has garnered increased attention due to its larger specific surface area, enhanced electronic mobility, and intrinsic band gap compared to graphene. Our analyses unveil pertinent aspects of graphyne electrodes in interaction with ionic liquid (Emim-BF<sub>4</sub>) and aqueous salt (NaCl) solution based electrolytes. Despite the existing body of research on graphyne, there remains a gap in the comprehensive analysis of its performance as an electrode for supercapacitors and its interactions with electrolyte. In this investigation, molecular dynamics were employed to explore properties of graphene/graphyne electrodes based supercapacitors. The characteristics of the EDL are elucidated through structural and energetic analyses, while the capacitive performance of the devices is discussed in light of electrostatic properties, total capacitance, and storage energy density. Throughout the analysis, key differences and underlying similarities between the models are delineated.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143112495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyethylene Oxide Incorporated Ammonium Iodide Doped With Ionic Liquid Trihexyl (Tetradecy) Phosphonium Dicyanamide-Based Polymer Electrolyte for Dual Energy Storage Devices
Pub Date : 2025-01-06 DOI: 10.1002/est2.70107
Suneyana Rawat, Pramod K. Singh, M. Z. A. Yahya, S. N. F. Yusuf, Markus Diantoro, Famiza Abdul Latif, Ram Chandra Singh

Cation phosphonium-based ionic liquids (PBILs) have recently gained attention since the 2000s due to their thermal stability and low viscosity for better ionic conduction in electrochemical devices. This paper introduces a new low-viscosity phosphonium-based ionic liquids (PBILs)—trihexyl (tetradecy) phosphonium dicyanamide—infused in polyethylene oxide: ammonium iodide (NH4I) complex polymer electrolyte. The electrochemical impedance spectroscopy studies indicate that the ionic conductivity reaches 2.03 × 10−4 S/cm at 6 wt.% PBILs at ambient temperature. The PBILs-doped polymer electrolyte is predominantly ionic confirm by ionic transference numbers (tion) calculation. Also the electrochemical stability window was found to be 3.2 V suitable for energy storage devices. The highest achieve ionic conductivity PBILs-doped polymer electrolyte sandwich between the electrodes for dual energy devices like electric double layer capacitors (EDLCs) and dye-sensitized solar cells (DSSCs). This study shows improvements in ionic conduction, double-layer stability, and light-harvesting efficiency, resulting in higher energy density and power density in EDLCs and better photovoltaic performance in DSSCs. These findings highlight the versatility and efficacy of phosphonium-based ionic liquid-doped polymer electrolytes for advanced energy storage and conversion applications.

{"title":"Polyethylene Oxide Incorporated Ammonium Iodide Doped With Ionic Liquid Trihexyl (Tetradecy) Phosphonium Dicyanamide-Based Polymer Electrolyte for Dual Energy Storage Devices","authors":"Suneyana Rawat,&nbsp;Pramod K. Singh,&nbsp;M. Z. A. Yahya,&nbsp;S. N. F. Yusuf,&nbsp;Markus Diantoro,&nbsp;Famiza Abdul Latif,&nbsp;Ram Chandra Singh","doi":"10.1002/est2.70107","DOIUrl":"https://doi.org/10.1002/est2.70107","url":null,"abstract":"<div>\u0000 \u0000 <p>Cation phosphonium-based ionic liquids (PBILs) have recently gained attention since the 2000s due to their thermal stability and low viscosity for better ionic conduction in electrochemical devices. This paper introduces a new low-viscosity phosphonium-based ionic liquids (PBILs)—trihexyl (tetradecy) phosphonium dicyanamide—infused in polyethylene oxide: ammonium iodide (NH<sub>4</sub>I) complex polymer electrolyte. The electrochemical impedance spectroscopy studies indicate that the ionic conductivity reaches 2.03 × 10<sup>−4</sup> S/cm at 6 wt.% PBILs at ambient temperature. The PBILs-doped polymer electrolyte is predominantly ionic confirm by ionic transference numbers (t<sub>ion</sub>) calculation. Also the electrochemical stability window was found to be 3.2 V suitable for energy storage devices. The highest achieve ionic conductivity PBILs-doped polymer electrolyte sandwich between the electrodes for dual energy devices like electric double layer capacitors (EDLCs) and dye-sensitized solar cells (DSSCs). This study shows improvements in ionic conduction, double-layer stability, and light-harvesting efficiency, resulting in higher energy density and power density in EDLCs and better photovoltaic performance in DSSCs. These findings highlight the versatility and efficacy of phosphonium-based ionic liquid-doped polymer electrolytes for advanced energy storage and conversion applications.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143112555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring the Potential of Lanthanum-Doped ZnFe2O4 Nanomaterials as Electrode Materials for Next-Generation Supercapacitors
Pub Date : 2025-01-06 DOI: 10.1002/est2.70100
Apoorva Rai, Prashant Tripathi, P. Kumar, Kedar Singh, H. S. Tewari, Jai Singh

In this study, we synthesized ZnFe2-xLaxO4 nanoparticles with varying lanthanum (La) content (x = 0, 0.01, 0.03, 0.05) via a cost-effective combustion method utilizing citric acid as a fuel. This method was selected for its cost-effectiveness and its capability to produce high-quality nanoparticles with tailored properties. X-ray diffraction (XRD) analysis confirmed the cubic structure of the synthesized ZnFe2O4 product, revealing planes (220), (311), (400), (511), and (440) within the Fd-3m space group, with no additional peaks observed, indicating phase purity. The study proceeded to calculate essential parameters including lattice parameter, particle size, and strain, utilizing the Williamson–Hall method, offering important insights into the structural features and behaviors of synthesized nanoparticles. The crystallite size and surface morphology were investigated by TEM analysis. Additionally, Raman spectroscopy revealed five distinct Raman-active modes (A1g + Eg + 3F2g), consistent with the spinel structure. The electrochemical properties of the electrodes were assessed using a three-electrode system in a 2 M KOH electrolyte, employing cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). At a scan rate of 2 mV/s, a specific capacitance of 109.58 F/g was achieved with the nanomaterial synthesized via the combustion technique.

{"title":"Exploring the Potential of Lanthanum-Doped ZnFe2O4 Nanomaterials as Electrode Materials for Next-Generation Supercapacitors","authors":"Apoorva Rai,&nbsp;Prashant Tripathi,&nbsp;P. Kumar,&nbsp;Kedar Singh,&nbsp;H. S. Tewari,&nbsp;Jai Singh","doi":"10.1002/est2.70100","DOIUrl":"https://doi.org/10.1002/est2.70100","url":null,"abstract":"<div>\u0000 \u0000 <p>In this study, we synthesized ZnFe<sub>2-<i>x</i></sub>La<sub><i>x</i></sub>O<sub>4</sub> nanoparticles with varying lanthanum (La) content (<i>x</i> = 0, 0.01, 0.03, 0.05) via a cost-effective combustion method utilizing citric acid as a fuel. This method was selected for its cost-effectiveness and its capability to produce high-quality nanoparticles with tailored properties. X-ray diffraction (XRD) analysis confirmed the cubic structure of the synthesized ZnFe<sub>2</sub>O<sub>4</sub> product, revealing planes (220), (311), (400), (511), and (440) within the Fd-3m space group, with no additional peaks observed, indicating phase purity. The study proceeded to calculate essential parameters including lattice parameter, particle size, and strain, utilizing the Williamson–Hall method, offering important insights into the structural features and behaviors of synthesized nanoparticles. The crystallite size and surface morphology were investigated by TEM analysis. Additionally, Raman spectroscopy revealed five distinct Raman-active modes (A1g + Eg + 3F2g), consistent with the spinel structure. The electrochemical properties of the electrodes were assessed using a three-electrode system in a 2 M KOH electrolyte, employing cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). At a scan rate of 2 mV/s, a specific capacitance of 109.58 F/g was achieved with the nanomaterial synthesized via the combustion technique.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143112619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Techno Economic Analysis of Grid Connected Photovoltaic Systems With Battery Energy Storage: A Comprehensive Review
Pub Date : 2025-01-06 DOI: 10.1002/est2.70119
Shiv Saurabh, Adesh Kumar, Roushan Kumar

The usage of solar photovoltaic (PV) systems for power generation has significantly increased due to the global demand for sustainable and clean energy sources. When combined with Battery Energy Storage Systems (BESS) and grid loads, photovoltaic (PV) systems offer an efficient way of optimizing energy use, lowering electricity expenses, and improving grid resilience. The study highlights the environmental and economic advantages, such as reduced carbon emissions, lower energy expenses, and job creation, while facilitating grid modernization through bi-directional power flow and enhanced energy management. The findings demonstrate the evolution towards a sustainable energy future by analyzing the incorporation of photovoltaic systems and battery energy storage systems, investigating standards for the secure and efficient integration of grid-connected solar photovoltaic systems, and evaluating the environmental and techno-economic implications of these systems. The techno-economic analysis, encompassing estimates of payback period, return on investment, and net present value, is utilized to evaluate the economic feasibility of the integrated system. The findings from this research aim to aid consumers, businesses, utilities, and legislators in making informed decisions that optimize solar energy advantages, diminish grid reliance, and alleviate environmental consequences.

{"title":"Techno Economic Analysis of Grid Connected Photovoltaic Systems With Battery Energy Storage: A Comprehensive Review","authors":"Shiv Saurabh,&nbsp;Adesh Kumar,&nbsp;Roushan Kumar","doi":"10.1002/est2.70119","DOIUrl":"https://doi.org/10.1002/est2.70119","url":null,"abstract":"<div>\u0000 \u0000 <p>The usage of solar photovoltaic (PV) systems for power generation has significantly increased due to the global demand for sustainable and clean energy sources. When combined with Battery Energy Storage Systems (BESS) and grid loads, photovoltaic (PV) systems offer an efficient way of optimizing energy use, lowering electricity expenses, and improving grid resilience. The study highlights the environmental and economic advantages, such as reduced carbon emissions, lower energy expenses, and job creation, while facilitating grid modernization through bi-directional power flow and enhanced energy management. The findings demonstrate the evolution towards a sustainable energy future by analyzing the incorporation of photovoltaic systems and battery energy storage systems, investigating standards for the secure and efficient integration of grid-connected solar photovoltaic systems, and evaluating the environmental and techno-economic implications of these systems. The techno-economic analysis, encompassing estimates of payback period, return on investment, and net present value, is utilized to evaluate the economic feasibility of the integrated system. The findings from this research aim to aid consumers, businesses, utilities, and legislators in making informed decisions that optimize solar energy advantages, diminish grid reliance, and alleviate environmental consequences.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143112650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Zn3(PO4)2·4H2O/TiO2 Structure for Superior Oxygen Evolution Reaction and Energy Storage Applications
Pub Date : 2025-01-06 DOI: 10.1002/est2.70112
Mosin Khan, Ritu Raj, Mange Ram, Anju Rani, Krishna Kanta Haldar

In this study, we present the synthesis and characterization of a high-performance Zn3(PO4)2·4H₂O/TiO2 nanocomposite, designed as a versatile electrocatalyst for advanced energy storage and conversion applications. The synthesis of the Zn3(PO4)2·4H₂O/TiO2 nanocomposite was confirmed using various sophisticated analytical techniques such as powder x-ray diffraction, FTIR, UV spectroscopy, FESEM imaging, EDX, and XPS etc. Notably, the nanocomposite demonstrates exceptional performance in the oxygen evolution reaction (OER), with a low overpotential of 250 mV at a current density of 50 mV/cm2 and a Tafel slope of 129 mV/dec, indicating superior kinetics. Furthermore, it demonstrates a specific capacitance of 112 F/g at a scan rate of 20 mV/s and remarkable cyclic stability, retaining 91% capacitance over 1000 cycles in supercapacitor applications. Additionally, in a practical application, the nanocomposite successfully powered a red light-emitting diode (LED) for 11 min. The combined effect of Zn3(PO4)2·4H₂O2 and TiO2 contributes to its outstanding electrochemical properties. This makes it a promising candidate for sustainable energy solutions, with the potential to enhance the efficiency and durability of energy storage and conversion systems.

{"title":"Zn3(PO4)2·4H2O/TiO2 Structure for Superior Oxygen Evolution Reaction and Energy Storage Applications","authors":"Mosin Khan,&nbsp;Ritu Raj,&nbsp;Mange Ram,&nbsp;Anju Rani,&nbsp;Krishna Kanta Haldar","doi":"10.1002/est2.70112","DOIUrl":"https://doi.org/10.1002/est2.70112","url":null,"abstract":"<div>\u0000 \u0000 <p>In this study, we present the synthesis and characterization of a high-performance Zn<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>·4H₂O/TiO<sub>2</sub> nanocomposite, designed as a versatile electrocatalyst for advanced energy storage and conversion applications. The synthesis of the Zn<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>·4H₂O/TiO<sub>2</sub> nanocomposite was confirmed using various sophisticated analytical techniques such as powder x-ray diffraction, FTIR, UV spectroscopy, FESEM imaging, EDX, and XPS etc. Notably, the nanocomposite demonstrates exceptional performance in the oxygen evolution reaction (OER), with a low overpotential of 250 mV at a current density of 50 mV/cm<sup>2</sup> and a Tafel slope of 129 mV/dec, indicating superior kinetics. Furthermore, it demonstrates a specific capacitance of 112 F/g at a scan rate of 20 mV/s and remarkable cyclic stability, retaining 91% capacitance over 1000 cycles in supercapacitor applications. Additionally, in a practical application, the nanocomposite successfully powered a red light-emitting diode (LED) for 11 min. The combined effect of Zn<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>·4H₂O<sub>2</sub> and TiO<sub>2</sub> contributes to its outstanding electrochemical properties. This makes it a promising candidate for sustainable energy solutions, with the potential to enhance the efficiency and durability of energy storage and conversion systems.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143112535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Low-Temperature Solar Thermal Energy Storage Using LaNi5−xMx (M = Al, Fe, Ga, and Zn) Alloys
Pub Date : 2025-01-06 DOI: 10.1002/est2.70113
K. Sarath Babu, Dinesh Dashbabu, E. Anil Kumar

Lanthanum based alloys are used in this current work to store the low temperature (less than 120°C) thermal energy, as they absorb and desorb hydrogen gas reversibly. LaNi5−xMx (M = Al, Fe, Ga, and Zn) alloys are compared at constant energy storage and recovery temperatures based on their absorption characteristics. A comparison is made between a Simple Absorption System (SAS), a Compressor Operated Absorption system (CAS), and a Cascade Resorption System (CRS) to store thermal energy at low temperatures. van't Hoff relation is used to estimate the lowest temperature to store energy and the maximum temperature to extract it. The energy was successfully upgraded by CAS and CRS. For various La-based alloys, the three systems' performances were thermodynamically examined and compared. A maximum COP of 0.86 and 0.74 is obtained in a simple absorption and compressor operated absorption system, respectively, using LaNi4.75Fe0.25 due to low hysteresis. Maximum heat upgradation with the Al, Fe, Ga, and Zn substitution is reported as 50°C, 20°C, 48°C, and 60°C, respectively, at a compressor ratio of 5 with CAS. The CRS with same substitution gives the highest heat upgradation of 66°C, 43°C, 88°C, and 107°C at regeneration temperature of 120°C respectively.

{"title":"Low-Temperature Solar Thermal Energy Storage Using LaNi5−xMx (M = Al, Fe, Ga, and Zn) Alloys","authors":"K. Sarath Babu,&nbsp;Dinesh Dashbabu,&nbsp;E. Anil Kumar","doi":"10.1002/est2.70113","DOIUrl":"https://doi.org/10.1002/est2.70113","url":null,"abstract":"<div>\u0000 \u0000 <p>Lanthanum based alloys are used in this current work to store the low temperature (less than 120°C) thermal energy, as they absorb and desorb hydrogen gas reversibly. LaNi<sub>5−x</sub>M<sub>x</sub> (<i>M</i> = Al, Fe, Ga, and Zn) alloys are compared at constant energy storage and recovery temperatures based on their absorption characteristics. A comparison is made between a Simple Absorption System (SAS), a Compressor Operated Absorption system (CAS), and a Cascade Resorption System (CRS) to store thermal energy at low temperatures. van't Hoff relation is used to estimate the lowest temperature to store energy and the maximum temperature to extract it. The energy was successfully upgraded by CAS and CRS. For various La-based alloys, the three systems' performances were thermodynamically examined and compared. A maximum COP of 0.86 and 0.74 is obtained in a simple absorption and compressor operated absorption system, respectively, using LaNi<sub>4.75</sub>Fe<sub>0.25</sub> due to low hysteresis. Maximum heat upgradation with the Al, Fe, Ga, and Zn substitution is reported as 50°C, 20°C, 48°C, and 60°C, respectively, at a compressor ratio of 5 with CAS. The CRS with same substitution gives the highest heat upgradation of 66°C, 43°C, 88°C, and 107°C at regeneration temperature of 120°C respectively.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143112536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of PPy/rGO/NiCoFe2O4 Ternary Composite and rGO/NiCoFe2O4 Binary Composite Hybrid Materials for the Fabrication of Flexible Carbon Cloth Electrodes for Supercapacitors
Pub Date : 2025-01-06 DOI: 10.1002/est2.70105
Ansari Novman Nabeel, Alok Jain, Talal Alharbi, Akbar Ahmad, Dilawar Husain, Sajid Naeem

This study presents a simple, scalable approach for synthesizing binary and ternary composites tailored for electrode materials, with a focus on supercapacitor applications. The composites were fabricated by integrating reduced graphene oxide (rGO) with NiCoFe2O4 metal oxides and the conductive polymer polypyrrole (PPy). The significance of this work lies in the development of supercapacitors, which are highly valued for their superior energy density, fast charge and discharge rates, prolonged life cycle, and cost-effectiveness. The binary composite, rGO/NiCoFe2O4, was synthesized using a sol–gel auto-combustion method, with carbon cloth serving as the electrode substrate for electrochemical testing. Electrochemical analysis showed that the rGO/NiCoFe2O4 binary composite exhibited a specific capacitance of 154 F/g at a scan rate of 10 mV/s. The addition of PPy resulted in the formation of the ternary composite, PPy/rGO/NiCoFe2O4, which demonstrated a markedly improved specific capacitance of 210 F/g under the same conditions, underscoring the synergistic effect of PPy. Furthermore, galvanostatic charge–discharge (GCD) analysis revealed specific capacitance values of 222.5 F/g at 1 A/g and 145 F/g at 2 A/g for the ternary composite, compared to 157.1 F/g and 110 F/g for the binary composite. The findings of this investigation emphasize the significant potential of the PPy/rGO/NiCoFe2O4 composite for the development of high-performance supercapacitors, leveraging the combined benefits of rGO, NiCoFe2O4, and PPy for superior energy storage capabilities.

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引用次数: 0
Determination of Optimal Shape for Gas Storage Salt Caverns
Pub Date : 2025-01-06 DOI: 10.1002/est2.70109
Mehdi Noroozi, Ali Rezaei, Hadi Fathipour-Azar

In this study, the optimal shape for a gas storage cavern was determined by considering the elements that affect its stability and convergence. The considered factors influencing the stability of caverns include the bulk modulus of salt rock, ambient temperature, internal gas pressure, cavern depth, and cavern shape. By varying these parameters and creating various combinations, 45 scenarios were defined. Numerical models were constructed for each scenario to systematically investigate the factors affecting cavern stability. Through a comparison of the results from these numerical models, the most stable cavern shape under different conditions was determined. The study focuses on the pre-salt environments in the Santos Basin, southeast Brazil. The findings of this study may aid in the construction of gas storage salt caverns. The results indicate that the cavern's size and geometry have a greater effect on its volume loss in salt layers with a lower bulk modulus (between 5 and 15 GPa). Additionally, when the bulk modulus is low, the rate of change of the cavern convergence to the bulk modulus is larger. Moreover, the effects of the rock salt characteristics on the cavern convergence are much less pronounced at larger depths, so a depth of 1200 m can be ignored. In comparison to the bulk modulus of salt rock, internal gas pressure has a far greater effect on the convergence of salt caverns. At shallow depths, the salt creep phenomena primarily affect the cavern's roof area, and as the depth of the cavern deepens, it increasingly damages the floor and middle walls. When precise control of the gas pressure in proportion to the cavern depth is not attainable, the optimal form for designing gas storage salt caverns with varying depths based on the minimal convergence criterion is a horizontal ellipsoid. In contrast, the vertical ellipsoidal cavern always results in the greatest volume loss and displacement and is hence regarded as the least acceptable alternative. A downward pear-shaped cavern can be a good alternative to a horizontal ellipsoidal cavern for higher depths. The design and construction of the downward pear-shaped cavern instead of the upward pear-shaped cavern leads to better control and the reduction of the displacements.

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引用次数: 0
期刊
Energy Storage
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