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Better integrating battery and fuel cells in electric vehicles 在电动汽车中更好地集成电池和燃料电池
Pub Date : 2024-06-25 DOI: 10.1002/est2.669
Alberto Boretti

This paper presents an innovative approach to enhancing the range of battery electric vehicles (BEVs) through the integration of a hydrogen fuel cell range extender. By combining the high energy efficiency of BEVs with the rapid refueling capability and extended range of hydrogen fuel cells, this hybrid system addresses the limitations of current electric vehicles in scenarios demanding longer driving ranges or quicker refueling options. Our study encompasses both experimental and theoretical analyses, leading to the proposal of a BEV configuration that includes a smaller battery complemented by a fuel cell range extender. The conventional fuel cell electric vehicle (FCV) examined relies exclusively on hydrogen fuel and features a minimal battery without plug-in functionality, resulting in suboptimal energy economy. In contrast, our proposed BEV with a fuel cell range extender employs a larger battery capacity of 12 to 16 kWh alongside a downsized fuel cell stack and reduced hydrogen tank size. This configuration significantly improves energy recovery during braking and extends electric operation, thereby doubling the vehicle's energy economy. The proposed system not only enhances energy efficiency but also reduces the weight and volume of the overall energy storage system. Preliminary estimates suggest that the miles-per-gallon equivalent (MPGe) of this hybrid solution could exceed 140 over the US EPA certification cycle, outperforming existing PHEVs, BEVs, and FCVs.

本文介绍了一种通过集成氢燃料电池增程器来提高电池电动汽车(BEV)续航里程的创新方法。这种混合动力系统将电池电动汽车的高能效与氢燃料电池的快速补充燃料能力和延长续航里程相结合,解决了当前电动汽车在需要更长行驶里程或更快补充燃料的情况下的局限性。我们的研究包括实验分析和理论分析,最终提出了一种 BEV 配置,其中包括一个较小的电池和一个燃料电池增程器。所研究的传统燃料电池电动汽车(FCV)完全依赖氢燃料,电池容量极小,不具备插电功能,因此能源经济性不理想。相比之下,我们提出的带燃料电池增程器的 BEV 采用了 12 到 16 kWh 的较大电池容量,同时缩小了燃料电池堆,并减小了氢气罐的尺寸。这种配置大大提高了制动时的能量回收率,延长了电动运行时间,从而使车辆的能源经济性提高了一倍。拟议的系统不仅提高了能源效率,还减少了整个储能系统的重量和体积。初步估计表明,在美国环保署认证周期内,这种混合动力解决方案的每加仑等效英里数(MPGe)可超过 140 英里,优于现有的 PHEV、BEV 和 FCV。
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引用次数: 0
A study of different machine learning algorithms for state of charge estimation in lithium-ion battery pack 针对锂离子电池组充电状态估计的不同机器学习算法研究
Pub Date : 2024-06-25 DOI: 10.1002/est2.658
Mangesh Maurya, Shashank Gawade, Neha Zope

Forecasting the state of charge (SOC) using battery control systems is laborious because of their longevity and reliability. Since battery degradation is typically nonlinear, predicting SOC estimation with significantly less degradation is laborious. So, the estimation of SOC is an increasingly major problem in ensuring the effectiveness and safety of the battery. To overcome these issues in SOC estimation, we found many methods in the scientific literature, with differing degrees of precision and intricacy. The SOC of lithium-ion batteries can now be precisely predicted using supervised learning approaches. Reliable assessment of the SOC of a battery ensures safe operation, extends battery lifespan, and optimizes system performance. This work compares and studies the performance, benefits, and drawbacks of five supervised learning techniques for SOC estimates. Different SOC estimate methods are discussed, including both conventional and contemporary methods. These consist of techniques using voltage and current measurements and more complex algorithms using electrochemical models, impedance spectroscopy, and machine learning methods, incorporating the use of artificial intelligence and machine learning for flexible SOC estimation. In the future, SOC estimates will be a crucial component of a larger ecosystem for energy management, allowing for the seamless integration of energy storage into smart grids and adopting more environmentally friendly energy habits. The five methods we compare are random forest RF, gradient boosting machines, extra tree regressor, XG Boost, and DT. In these five methods, we are going to investigate, review, and discuss the current algorithms and overcome them to select one of the most precise and accurate algorithms to predict the accurate estimation of lithium-ion battery SOC.

由于电池的寿命和可靠性,使用电池控制系统预测充电状态(SOC)非常费力。由于电池的衰减通常是非线性的,因此要预测衰减明显较小的 SOC 估计值十分费力。因此,在确保电池的有效性和安全性方面,SOC 估算日益成为一个重大问题。为了克服 SOC 估算中的这些问题,我们在科学文献中找到了许多方法,这些方法的精确度和复杂程度各不相同。现在,使用监督学习方法可以精确预测锂离子电池的 SOC。对电池 SOC 的可靠评估可确保安全运行、延长电池寿命并优化系统性能。本研究比较并研究了用于 SOC 评估的五种监督学习技术的性能、优点和缺点。文中讨论了不同的 SOC 估算方法,包括传统方法和现代方法。这些方法包括使用电压和电流测量的技术,以及使用电化学模型、阻抗光谱和机器学习方法的更复杂算法,并结合使用人工智能和机器学习来灵活估算 SOC。未来,SOC 估值将成为能源管理大型生态系统的重要组成部分,从而实现储能与智能电网的无缝集成,并养成更环保的用能习惯。我们比较的五种方法是随机森林 RF、梯度提升机、额外树回归器、XG Boost 和 DT。在这五种方法中,我们将对当前的算法进行研究、回顾和讨论,并对其进行克服,从而选择一种最精确、最准确的算法来预测锂离子电池 SOC 的准确估算。
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引用次数: 0
Dynamic modeling and simulation of advanced nuclear reactor with thermal energy storage 带热能储存的先进核反应堆的动态建模与模拟
Pub Date : 2024-06-25 DOI: 10.1002/est2.672
Seth J. Dana, Aiden S. Meek, Jacob A. Bryan, Manjur R. Basnet, Hailei Wang

The increasing installment of solar and wind renewable energy systems create a volatile energy demand to be met by electricity providers. A nuclear hybrid energy system is a nuclear reactor with energy storage that integrates into the grid with renewable energy sources. The Natrium design by TerraPower and GE Hitachi is a sodium fast reactor with molten salt energy storage. The Natrium design operates at steady state of 345 MWe and can boost up to 500 MWe for 5.5 hours. This study uses Dymola and the Modelica language to model the Natrium-based nuclear-renewable hybrid energy system. The dynamic system model is tested using hourly historical data from the state of Texas 2021 to show how renewables affect the electricity demand and how energy storage affects the Natrium system response to the demand. According to the results, while the available storage will allow the Natrium design to boost electricity production when the demand and electricity price is high making it more economically viable, the current molten salt storage is slightly undersized for the ERCOT market.

太阳能和风能可再生能源系统的安装量不断增加,导致电力供应商需要满足不稳定的能源需求。核电混合能源系统是一种带有储能装置的核反应堆,与可再生能源一起并入电网。TerraPower 公司和通用电气日立公司设计的 Natrium 是一种带熔盐储能的钠快堆。Natrium 设计的稳态运行功率为 345 兆瓦,可在 5.5 小时内将功率提升至 500 兆瓦。本研究使用 Dymola 和 Modelica 语言对基于 Natrium 的核能-可再生能源混合能源系统进行建模。利用德克萨斯州 2021 年的每小时历史数据对动态系统模型进行了测试,以说明可再生能源如何影响电力需求,以及储能如何影响 Natrium 系统对需求的响应。结果表明,虽然可用的储能将使 Natrium 设计在需求和电价较高时提高发电量,使其更具经济可行性,但目前的熔盐储能在 ERCOT 市场上略显不足。
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引用次数: 0
Nickel sulfide and potato-peel-derived carbon spheres composite for high-performance asymmetric supercapacitor electrodes 用于高性能不对称超级电容器电极的硫化镍和马铃薯皮衍生碳球复合材料
Pub Date : 2024-06-25 DOI: 10.1002/est2.660
Mahima Sheoran, Rohit Sharma, Anit Dawar, Sunil Ojha, Anurag Srivastav, R K Sharma, Om Prakash Sinha

In the present work, a novel composite of nickel sulfide (NiS) and potato peel-derived carbon spheres (NiS/PPCS) with higher specific capacitance and cyclic performance was synthesized as electrode material for supercapacitor applications. The composite was deposited on a graphite rod to be use as an electrode. The electrochemical performance studies using CV, GCD, and EIS revealed that the prepared electrode showed an improved current response and higher specific capacitance than the pristine NiS electrode. The maximum specific capacitance for the NiS/PPCS electrode was found to be 2185 F/g at 0.2 A/g current density. More precisely, it was observed that the NiS/PPCS composite exhibited an excellent retention capacity of 95.04% after 20 000 continuous charge-discharge cycles, showing its exceptional cyclic performance. The impedance studies revealed that the reaction between the NiS/PPCS electrode and electrolyte was rapid and highly reversible. Based on the findings of the electrochemical performances, NiS/PPCS electrode appears to be a potential candidate for highly efficient and economical asymmetric supercapacitors.

本研究合成了一种硫化镍(NiS)和马铃薯皮衍生碳球(NiS/PPCS)的新型复合材料,作为超级电容器应用的电极材料,具有更高的比电容和循环性能。复合材料沉积在石墨棒上用作电极。使用 CV、GCD 和 EIS 进行的电化学性能研究表明,与原始 NiS 电极相比,制备的电极显示出更好的电流响应和更高的比电容。在 0.2 A/g 的电流密度下,NiS/PPCS 电极的最大比电容为 2185 F/g。更确切地说,经过 20,000 次连续充放电循环后,NiS/PPCS 复合材料显示出 95.04% 的出色电容量保持率,显示出其卓越的循环性能。阻抗研究表明,NiS/PPCS 电极与电解液之间的反应迅速且高度可逆。根据电化学性能的研究结果,NiS/PPCS 电极似乎是高效、经济的不对称超级电容器的潜在候选材料。
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引用次数: 0
A novel battery management scheme for critical loads 用于关键负载的新型电池管理方案
Pub Date : 2024-06-25 DOI: 10.1002/est2.675
Lakshmi Sravan Bandatmakuru, Srinivasa Rao Sandepudi

This article proposes a novel battery management system (BMS) to ensure uninterruptible power delivery to a 48 V DC bus used for electric vehicle charging stations, data centers, telecommunication systems, and critical care units such as hospitals. The proposed BMS facilitates constant current and constant voltage charging to maintain optimal battery performance during normal operation. This BMS is designed for effective control, monitoring and protection of two lead-acid battery units to form battery energy storage system (BESS). Furthermore, it is capable of isolating batteries in abnormal conditions and operates them independently to provide reliable supply at output terminals with full capacity. The system utilizes a 30 V DC source derived from AC mains or solar photovoltaic system. This supply is used to charge the BESS and also supply to the load. In the event of failure of 30 V supply, it seamlessly transits to BESS mode to supply power to boost converter to maintain constant 48 V DC output at load terminal. The proposed system architecture not only enhances power reliability but also improves overall system efficiency, making it well-suited for critical applications require continuous and stable power supply. Simulation studies using Matlab/Simulink and analytical results using TINA (Tool kit for Interactive Network Analysis) are presented to show that 48 V DC supply is maintained at output terminals during failure of input 30 V DC source or failure of one battery unit.

本文提出了一种新型电池管理系统(BMS),以确保向电动汽车充电站、数据中心、电信系统和医院等重症监护室使用的 48 V 直流总线不间断供电。拟议的 BMS 可实现恒流和恒压充电,从而在正常运行期间保持最佳的电池性能。该 BMS 设计用于有效控制、监测和保护两个铅酸电池单元,以形成电池储能系统(BESS)。此外,它还能在异常情况下隔离电池,并使其独立运行,为输出端提供可靠的全容量供电。该系统利用交流电源或太阳能光伏系统提供的 30 V 直流电源。该电源用于为 BESS 充电,同时也为负载供电。如果 30 V 电源出现故障,系统会无缝切换到 BESS 模式,为升压转换器供电,以保持负载端 48 V 直流输出恒定。所提出的系统架构不仅增强了电源可靠性,还提高了整体系统效率,非常适合需要持续稳定供电的关键应用。使用 Matlab/Simulink 进行的仿真研究和使用 TINA(交互式网络分析工具包)得出的分析结果表明,在输入 30 V 直流电源失效或一个电池单元失效时,输出端仍能保持 48 V 直流电源。
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引用次数: 0
Investigation of partial charging of enhanced ice storage systems 对强化冰储存系统部分充电的研究
Pub Date : 2024-06-24 DOI: 10.1002/est2.676
Abdelghani Laouer, Lahcene Bellahcene, Aissa Atia, Amine Toufik Benhouia, Mohamed Teggar

Partial storage strategy can save energy and reduce emissions. In this study, analysis of the partial melting process of ice inserted with nanoparticles inside a square enclosure is investigated for thermal energy storage. The lattice Boltzmann method is for melting and heat transfer in the storage unit. The validation demonstrates strong concurrence between the current findings and the experimental data documented in the literature. The analysis is performed for various Rayleigh numbers, nanoparticle volume fractions, and their effect on melting time and energy storage. Two types of nanoparticles are tested that is, copper and alumina. The outcomes indicate that the Rayleigh number and volume fraction of nanoparticles have a significant impact on the phase change process. The nanoparticles addition leads to homogenous and hence expedited melting process including the final stage of the ice melting process which is very slow without nanoparticles. Furthermore, copper nanoparticles are slightly more effective than alumina. Moreover, using 6% copper nanoparticles can reduce the melting time by up to 12.4%.

部分存储策略可以节约能源并减少排放。本研究分析了在方形外壳内插入纳米颗粒的冰的部分熔化过程,以进行热能储存。晶格玻尔兹曼法用于分析存储单元中的融化和热传递。验证结果表明,目前的研究结果与文献中记载的实验数据非常吻合。分析针对不同的瑞利数、纳米粒子体积分数及其对熔化时间和能量储存的影响。测试了两种类型的纳米粒子,即铜和氧化铝。结果表明,纳米粒子的雷利数和体积分数对相变过程有重大影响。纳米粒子的加入会导致均匀的熔化过程,从而加快熔化速度,包括冰熔化过程的最后阶段,而没有纳米粒子的情况下,熔化速度非常缓慢。此外,纳米铜微粒的效果略高于氧化铝。此外,使用 6% 的纳米铜粒子可将熔化时间缩短 12.4%。
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引用次数: 0
Twin graphene as an anode material for potassium-ion battery: A first principle study 作为钾离子电池阳极材料的双石墨烯:第一原理研究
Pub Date : 2024-06-21 DOI: 10.1002/est2.673
Nirmal Barman, Utpal Sarkar

Using density functional theory, we have investigated the usage of twin graphene as an anode material for potassium-ion batteries (KIBs). Twin graphene demonstrates excellent structural and cycling stability, with minimal changes in lattice parameters and negative cohesive energy during K charge/discharge cycles. Notably, the host material (twin graphene) offers multiple stable adsorption sites for potassium ions. We even observed that the pristine twin graphene, which is a semiconductor, consequently becomes metallic upon potassium adsorption. Twin graphene provides a high theoretical capacity of 495.84 mAh/g, along with low diffusion barrier of 0.290 V for K diffusion. Furthermore, the high electrical conductivity and low open-circuit voltage of the chosen host will definitely enhance its performance as a KIB material. The structural integrity of twin graphene is also retained with the adsorption of potassium ion, as checked through ab initio molecular dynamics simulation. These findings suggest that twin graphene may be considered as a promising anode material for KIBs.

我们利用密度泛函理论研究了如何将孪晶石墨烯用作钾离子电池(KIB)的负极材料。孪晶石墨烯具有出色的结构和循环稳定性,在 K 充放电循环过程中,其晶格参数和负内聚能的变化极小。值得注意的是,宿主材料(孪生石墨烯)为钾离子提供了多个稳定的吸附位点。我们甚至观察到,作为半导体的原始孪晶石墨烯在吸附钾离子后会变成金属。孪生石墨烯的理论容量高达 495.84 mAh/g,钾离子的扩散阻抗低至 0.290 V。此外,所选主材料的高导电性和低开路电压也必将提高其作为 KIB 材料的性能。孪生石墨烯的结构完整性也在吸附钾离子后得以保持,这一点已通过原子分子动力学模拟进行了验证。这些发现表明,孪生石墨烯可被视为一种很有前途的 KIB 阳极材料。
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引用次数: 0
Effect of multi-tubes and eccentricity on melting performance of honeybee wax thermal energy storage system: A comprehensive numerical study and experimental validation 多管和偏心率对蜜蜂蜡热能储存系统熔化性能的影响:综合数值研究与实验验证
Pub Date : 2024-06-20 DOI: 10.1002/est2.670
Shubam Khajuria,  Vikas, Himanshu Kumar, Ankit Yadav, Müslüm Arıcı

When it comes to solar thermal power systems, a latent heat energy storage unit is one possible solution to the imbalance in supply and demand. On a shell-tube type heat storage system, computational and experimental research was done to determine how to charge a heat storage system using honeybee wax-biodegradable phase change material. This paper examines the impact of single, double, and triple inner heat transfer fluid tubes on the melting properties of bee wax in relation to vertical and horizontal eccentricity. Through the experimental examination of a lab-scale prototype, the computational model was verified. A computational model was used to investigate the impact of eccentricity on different configurations for the melting process. Utilizing multiple tubes significantly shortened the charging time, according to the system analysis. In a vertically downward direction, melting time reduced as eccentricity increased. Compared to the single tube concentric case, the maximum melting time reduction for the single-, double-, and triple-tube cases was 63.7%, 67.0%, and 68.34%, respectively.

在太阳能热发电系统中,潜热储能装置是解决供需不平衡的一个可行方案。针对壳管式蓄热系统,我们进行了计算和实验研究,以确定如何为使用蜜蜂蜡-生物降解相变材料的蓄热系统充电。本文研究了单层、双层和三层内部导热流体管对蜂蜡熔化特性的影响与垂直和水平偏心率的关系。通过对实验室规模的原型进行实验检查,验证了计算模型。计算模型用于研究偏心对熔化过程中不同配置的影响。根据系统分析,使用多个管道大大缩短了装料时间。在垂直向下的方向上,熔化时间随着偏心率的增加而缩短。与单管同心情况相比,单管、双管和三管情况的最大熔化时间缩短率分别为 63.7%、67.0% 和 68.34%。
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引用次数: 0
Recent advances and research progress on the role of carbon-based biomass in ultra-capacitors: A systematic review 关于碳基生物质在超级电容器中的作用的最新进展和研究进展:系统综述
Pub Date : 2024-06-19 DOI: 10.1002/est2.646
Dhinesh Balasubramanian, Hariharan Varadharajan, Inbanaathan Papla Venugopal, Edwin Geo Varuvel

Biomass-derived carbon material has drawn significant attention recently due to its wide availability, environmentally free, and effective performance of the resulting porous carbons for supercapacitor (SC) applications. Carbon electrode material derived from biomass is used for energy storage (ES) because it has distinct qualities in porosity, a large specific surface area, and excellent conductivity. Furthermore, these materials' homogeneous, flawless biological structures can be used as models to create electrode materials with accurate geometries. The ES devices, known as SCs, also known as ultra-capacitors, serve as a link between a capacitor and a battery. Due to their charge storage, SCs can produce a much higher density than batteries. Several factors, including the electrode's potential window, the electrode materials characteristics, and the electrolyte choice, have a major effect on SC performance. Therefore, all efforts have been made to develop SC electrode materials. This paper explains the different types of SCs and how they work. The various available biomass resources, as well as the methods for producing them, are outlined. In addition, the different types of electrode materials, activation methods, heteroatom functionalization, and electrolyte types are all thoroughly examined. The application and research advancement of biomass-derived carbon used in SCs over the past 3 years are highlighted. Furthermore, this research outlines the benefits of SCs for the environment and the economy, as well as present challenges and future recommendations for advancing biomass-derived carbon applications. This article aims to give an in-depth knowledge of carbon-based biomass materials that are used in SCs.

生物质衍生碳材料因其广泛的可获得性、对环境的无害性以及所产生的多孔碳在超级电容器(SC)应用中的有效性能,最近引起了人们的极大关注。从生物质中提取的碳电极材料可用于储能(ES),因为它具有独特的多孔性、大比表面积和优异的导电性。此外,这些材料均匀、无暇的生物结构可用作模型,制造出具有精确几何形状的电极材料。这种 ES 设备被称为 SC,也被称为超级电容器,是电容器和电池之间的纽带。由于具有电荷存储功能,SC 可以产生比电池高得多的密度。电极电位窗口、电极材料特性和电解液选择等因素对 SC 性能有重大影响。因此,人们一直在努力开发 SC 电极材料。本文介绍了不同类型的 SC 及其工作原理。本文概述了各种可用的生物质资源及其生产方法。此外,还对不同类型的电极材料、活化方法、杂原子官能化和电解质类型进行了深入探讨。重点介绍了生物质衍生碳在过去 3 年中在 SC 中的应用和研究进展。此外,本研究还概述了气相沉积物对环境和经济的益处,以及在推进生物质衍生碳应用方面所面临的挑战和未来建议。本文旨在深入介绍 SC 中使用的碳基生物质材料。
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引用次数: 0
Experimental investigation on the effects of natural convection on cylindrical LiFePO4 battery module for energy storage application 自然对流对用于储能应用的圆柱形磷酸铁锂电池模块影响的实验研究
Pub Date : 2024-06-19 DOI: 10.1002/est2.663
Jayapradha P., Debabrata Barik

The experiments with a LiFePO4 battery pack operating at room temperature and with various charge and discharge rates to analyze its durability are described in this study. At a temperature of 23°C with natural convection, the thermal performance of a cylindrical (LFP) battery is experimentally studied. In this study, the battery is fully charged. After reaching 14.6 V, the battery is charged at a current of 4.8 A for 10 min to allow for stabilization. The battery is then depleted at 4.8 A until its voltage hits 10.5 V, followed by an additional 10-min resting time. The processes reached their highest and lowest temperatures, respectively, were 29°C and 22°C. The battery is charged for a total of 46.877 Ampere-hours (Ah) during the course of the 10-h operation at a constant current of 4.8 A. Similar to this, a 10-h discharge operation is carried out with a constant current of 4.8 A, yielding a discharge of 47.207 Ah. The processes reached their highest and lowest temperatures, respectively, were 36°C and 24°C. Another possibility is to charge the battery at a steady 24 A until the voltage reaches 14.6 V, then let it rest for 10 min, a further 10-min rest period is added after it is discharged at 24 A until its voltage hits 10.5 V. After 5 h of charging at 24 A, the capacity is 46.958 Ah, and after 5 h and 47.51 min of discharging at 24 A, the capacity is 47 Ah. The processes reached their highest and lowest temperatures, respectively, were 49°C and 33°C.

本研究介绍了在室温下以各种充放电速率运行的磷酸铁锂电池组的实验,以分析其耐用性。在温度为 23°C 的自然对流条件下,对圆柱形(LFP)电池的热性能进行了实验研究。在本研究中,电池充满电。电池电压达到 14.6 V 后,以 4.8 A 的电流充电 10 分钟,使其趋于稳定。然后以 4.8 A 的电流耗尽电池,直到电压达到 10.5 V,再静置 10 分钟。过程中达到的最高和最低温度分别为 29°C 和 22°C。在以 4.8 安培的恒定电流运行 10 小时的过程中,电池共充电 46.877 安培小时(Ah)。与此类似,以 4.8 安培的恒定电流进行了 10 小时的放电操作,放电量为 47.207 Ah。过程中达到的最高和最低温度分别为 36°C 和 24°C。另一种方法是以稳定的 24 A 电流对电池充电,直到电压达到 14.6 V,然后让其休息 10 分钟,在以 24 A 电流放电后再休息 10 分钟,直到电压达到 10.5 V。在 24 安培下充电 5 小时后,容量为 46.958 Ah,在 24 安培下放电 5 小时 47.51 分钟后,容量为 47 Ah。过程中达到的最高和最低温度分别为 49°C 和 33°C。
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引用次数: 0
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