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Variability in wind energy on interannual and decadal scales and its influence on hydrogen energy storage 风能在年际和十年尺度上的变化及其对氢能储存的影响
Pub Date : 2024-06-19 DOI: 10.1002/est2.671
Alberto Boretti, Stefania Castelletto

Forecasting future wind electricity generation requires diverse methods and tools to estimate potential output at specific locations. This study utilizes historical meteorological data and simple models at particular sites, along with past electricity production records from selected wind farms. The interannual and decadal oscillations of wind energy production at the grid level are computed. The large-scale, long-term energy storage needed to achieve dispatchable electricity, addressing generation variability is assessed. For the continental United States, the estimated storage requirement is approximately 1300 GWh per GW of installed capacity. The inclusion of solar power generation and the round-trip efficiency of energy storage positively or negatively impact this estimation.

预测未来风力发电量需要多种方法和工具,以估算特定地点的潜在发电量。本研究利用特定地点的历史气象数据和简单模型,以及选定风电场过去的发电记录。计算了电网层面风能生产的年际和十年振荡。评估了实现可调度电力所需的大规模长期储能,以解决发电量变化问题。就美国大陆而言,每 GW 装机容量估计需要约 1300 GWh 的储能。太阳能发电的加入以及储能的往返效率都会对这一估算产生积极或消极的影响。
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引用次数: 0
Performance augmentation of photovoltaic solar chimneys using asphalt material 使用沥青材料提高光伏太阳能烟囱的性能
Pub Date : 2024-06-18 DOI: 10.1002/est2.640
Mansour J. Saleh, Faris S. Atallah, Omer K. Ahmed, Sameer Algburi

In this study, an experimental model of a photovoltaic (PV) solar chimney (SC) was built and study the extent to which the asphalt material, being a phase-change material, affects its performance electrical and thermal. Results were taken for the two systems: The photovoltaic solar chimney which contains phase change material (SCPV-PCM), and the photovoltaic solar chimney which does not contain phase change material (SCPV). The finding demonstrated that the PCM affects the SCPV electrical and thermal performance; the results were as follows: The electrical power for the SCPV-PCM system increased during the day and its highest value at noon was 384.34 W, and then it began to decrease. The SCPV system had a higher power at the end of the test, 73.24 W, due to the lower temperature of the PV panel. The highest electrical efficiency was for the SCPV-PCM system at the beginning of the test, reaching the highest value of 13.12%, then it decreased at the end of the test to be less than the SCPV system at 5:00 pm. The thermal efficiency of the SCPV-PCM arrangement is lesser than the arrangement that does not contain PCM, reaching its highest value at noon, which was 57.1% for the SCPV system. The total efficiency of the SCPV-PCM system is lesser than the SCPV system from the beginning of the test until 3:30 pm approximately, reaching its highest value of 68.05% at noon.

本研究建立了一个光伏太阳能烟囱(SC)的实验模型,并研究了沥青材料作为一种相变材料对其电气和热性能的影响程度。两个系统的结果均已得出:包含相变材料的光伏太阳能烟囱(SCPV-PCM)和不包含相变材料的光伏太阳能烟囱(SCPV)。研究结果表明,PCM 会影响 SCPV 的电热性能;结果如下:SCPV-PCM 系统的电功率在白天有所增加,中午时的最高值为 384.34 W,随后开始下降。由于光伏板的温度较低,SCPV 系统在测试结束时的功率较高,为 73.24 W。在测试开始时,SCPV-PCM 系统的电效率最高,达到 13.12% 的最高值,然后在测试结束时有所下降,在下午 5:00 时低于 SCPV 系统。SCPV-PCM 布置的热效率低于不含 PCM 的布置,在中午达到最高值,而 SCPV 系统的热效率为 57.1%。从测试开始到下午 3:30 左右,SCPV-PCM 系统的总效率低于 SCPV 系统,中午达到最高值 68.05%。
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引用次数: 0
Printable supercapacitors and their printing technologies: A review 可印刷超级电容器及其印刷技术:综述
Pub Date : 2024-06-17 DOI: 10.1002/est2.666
Y. C. Goswami, Sangar Begzaad

The review on printable supercapacitors (SCs) and their printing technologies delves into the realm of energy storage devices, focusing on the advancements in SC technology and the role of printing techniques in their fabrication. The abstract highlights the key advantages of SCs over traditional batteries and the latest developments in materials and fabrication methods. Highlighting materials like graphene oxide and carbon nanotubes showcases their role in printable inks for SCs. Additive manufacturing techniques like inkjet printing enable precise electrode deposition, leading to high-performance SCs with enhanced energy storage capabilities. The integration of printable SCs in portable electronics, wearable devices, and soft robotics demonstrates their versatility and impact across industries. Future research directions aim to optimize material formulations, enhance printing processes, and explore novel applications in emerging fields like IoT devices and smart textiles. Through a comprehensive analysis of research articles and studies, this review provides valuable insights into the potential of printable SCs to revolutionize the energy storage landscape.

这篇关于可印刷超级电容器(SC)及其印刷技术的综述深入探讨了储能设备领域,重点是 SC 技术的进步以及印刷技术在其制造中的作用。摘要强调了可印刷电容器相对于传统电池的主要优势,以及材料和制造方法的最新发展。重点介绍了氧化石墨烯和碳纳米管等材料,展示了它们在可印刷 SC 油墨中的作用。喷墨打印等快速成型技术可实现精确的电极沉积,从而生产出具有更强储能能力的高性能 SC。可印刷 SC 集成到便携式电子设备、可穿戴设备和软机器人中,显示了其多功能性和对各行各业的影响。未来的研究方向旨在优化材料配方,改进打印工艺,并探索在物联网设备和智能纺织品等新兴领域的新型应用。通过对研究文章和研究的全面分析,本综述对可印刷 SC 彻底改变能源存储领域的潜力提供了宝贵的见解。
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引用次数: 0
Enhanced energy density of high entropy alloy (Fe-Co-Ni-Cu-Mn) and green graphene hybrid supercapacitor 增强高熵合金(铁-铜-镍-铜-锰)和绿色石墨烯混合超级电容器的能量密度
Pub Date : 2024-06-17 DOI: 10.1002/est2.668
Gobinda Chandra Mohanty, Chinmayee Chowde Gowda, Pooja Gakhad, Anu Verma, Shubhasikha Das, Shamik Chowdhary, Jayanta Bhattacharya, Abhishek K Singh, Koushik Biswas, Chandra Sekhar Tiwary

Given the growing demand for new materials for supercapacitor applications, high entropy alloys (HEAs) are being extensively investigated. They are an efficient alternative to existing energy sources due to their synergistic contribution from individual element. We demonstrate the development of nanostructured HEA (FeCoNiCuMn) as a cathode material with specific capacitance (Cs) of ~388 F g−1 (5 mV s−1). As anode material, green graphene (rice straw biochar) synthesized using pyrolysis shows a maximum Cs of ~560 F g−1 at similar scan rate (5 mV s−1). A hybrid asymmetric liquid state device was assembled using the FeCoNiCuMn nanostructured HEA and green graphene as electrodes. Utilizing the green source, the device provided a high Cs of 83.22 F g−1 at 2 A g−1. The specific energy of the device was 33.4 Wh kg−1 and specific power of 1.7 kW kg−1. The electrochemical behavior of each element in the high entropy composition was studied through post X-ray photoelectron spectroscopy and scanning electron microscopic analysis. The chemical behavior of FeCoNiCuMn is further investigated using DFT studies. The enhanced electrochemical properties and synergistic contribution of each element of the HEA is studied via d-band theory. The current study can be utilized to develop asymmetric hybrid supercapacitors as environmental friendly energy source.

鉴于超级电容器应用对新材料的需求日益增长,高熵合金(HEAs)正受到广泛研究。由于单个元素的协同作用,高熵合金是现有能源的有效替代品。我们展示了纳米结构高熵合金(FeCoNiCuMn)作为阴极材料的开发成果,其比电容(Cs)为 ~388 F g-1 (5 mV s-1)。用热分解法合成的绿色石墨烯(稻草生物炭)作为阳极材料,在类似的扫描速率(5 mV s-1)下,最大比电容(Cs)约为 560 F g-1。利用铁钴镍铜锰纳米结构 HEA 和绿色石墨烯作为电极,组装了一个混合非对称液态装置。利用绿色源,该装置在 2 A g-1 电流条件下提供了 83.22 F g-1 的高铯。该装置的比能量为 33.4 Wh kg-1,比功率为 1.7 kW kg-1。通过后 X 射线光电子能谱和扫描电子显微镜分析,研究了高熵成分中各元素的电化学行为。利用 DFT 研究进一步探讨了铁钴镍铜锰的化学行为。通过 d 波段理论研究了 HEA 中各元素增强的电化学特性和协同贡献。目前的研究可用于开发作为环保能源的不对称混合超级电容器。
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引用次数: 0
A hierarchical optimization technique for placement of battery energy storage system to improve grid transient stability 用于布置电池储能系统以提高电网暂态稳定性的分层优化技术
Pub Date : 2024-06-14 DOI: 10.1002/est2.659
Sabrina Shams, Abdul H. Chowdhury, Md. Minarul Islam, Md. Shafiullah, Taha S. Ustun, Samsun Nahar, Kashem M. Muttaqi, Danny Sutanto

A battery energy storage system (BESS), due to its very fast dynamic response, plays an essential role in improving the transient frequency stability of a grid. The performance of the BESS varies with the system's installation site. Hence, the optimal location of the BESS is of utmost importance for improving transient frequency stability. Therefore, this paper presents a hierarchical approach for optimizing the BESS placement to improve a grid's transient frequency stability. In most research, frequency nadir and rate of change of frequency (ROCOF) have been considered for studying frequency stability. This paper considers two more parameters, along with frequency nadir and ROCOF, to study the transient frequency stability, settling time, and decay ratio. A novel frequency stability index (FSI) using the four transient frequency parameters has been developed. After a significant disturbance in a benchmarked test system, the FSI was used to identify the optimal location of the BESS for stabilizing the frequency. It has been observed that, after a sudden generator outage, the ROCOF and the frequency nadir improve the best when the BESS is located at the bus closest to the generator experiencing the outage. However, considering the other two parameters as well, the value of the FSI is the minimum; that is, the optimum solution is when the BESS is located at the bus that is the second closest to the generator experiencing the outage. Results of similar studies validate the proposed FSI in indicating the optimal location of the BESS in improving the transient frequency behavior of the system.

电池储能系统(BESS)具有极快的动态响应速度,在改善电网瞬态频率稳定性方面发挥着至关重要的作用。BESS 的性能随系统安装地点的不同而变化。因此,BESS 的最佳安装位置对于提高瞬态频率稳定性至关重要。因此,本文提出了一种优化 BESS 位置的分层方法,以改善电网的瞬态频率稳定性。在大多数研究中,频率最低点和频率变化率(ROCOF)都被用来研究频率稳定性。本文在研究频率稳定度、沉降时间和衰减率时,还考虑了频率下限和频率变化率这两个参数。利用四个瞬态频率参数开发了一种新的频率稳定指数(FSI)。在基准测试系统中发生重大扰动后,频率稳定指数被用来确定 BESS 的最佳位置,以稳定频率。结果表明,在发电机突然停电后,当 BESS 位于最靠近停电发电机的母线上时,ROCOF 和频率低点的改善效果最好。然而,考虑到其他两个参数,FSI 的值也是最小的;也就是说,当 BESS 位于距离发生停电的发电机第二近的母线时,才是最佳解决方案。类似研究的结果验证了所提出的 FSI 值,该值可指示 BESS 的最佳位置,从而改善系统的瞬态频率行为。
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引用次数: 0
Magnetic micro-fluidics in 3D microchannel at the micro-scale: Unlocking nano-porous electrode potential for lithium-ion micro-batteries 微尺度三维微通道中的磁性微流体:释放锂离子微型电池的纳米多孔电极潜力
Pub Date : 2024-06-13 DOI: 10.1002/est2.662
Adeel Ashraf, Tareq Manzoor, Shaukat Iqbal, Tauseef Anwar, Muhammad Farooq-i-Azam, Zeashan Khan, Habib Ullah Manzoor

Enhancing the nanosized-electrolyte's characteristics in Lithium-driven micro-batteries (LIMBs) is indispensable to improve the overall efficiency, security, and lifespan of these energy devices, designing nano-sized electrolyte with a wide electrochemical stability window while keeping them compatible with electrode materials is one of the improvement goals. Battery technologies must go through this optimization process in order to be used practically. A sensing mechanism to keep an eye on the health of Li-ion energy devices through the magnetization. Magnetic micro-fluidic patterns that change could be a sign of battery deterioration or other problems with performance. Li-ion battery health is one application of magnetic sensing that you can do with magnetic sensing. Battery health variations and other performance problems can be found using magnetic mass transport patterns. Present study examines the effects of magnetic field on Eyring–Powel mass transport in nano-porous channels over a stretching sheet. The principal equations exhibiting the phenomenon are transformed into non-linear differential equation by second-order approximation by using a similarity transformation. Furthermore, a semi-analytic technique named optimal homotopy asymptotic method (OHAM) is used to solve the transformed Eyring–Powell model. The numerical results demonstrated the impact of variations in velocity, skin-friction coefficient and Sherwood number for the proposed scheme.

要提高锂驱动微型电池(LIMB)的整体效率、安全性和寿命,就必须增强这些能源设备中纳米电解质的特性,而设计具有宽电化学稳定性窗口的纳米电解质,同时保持其与电极材料的兼容性,正是改进的目标之一。电池技术必须经过这一优化过程才能得到实际应用。通过磁化监测锂离子能源设备健康状况的传感机制。磁性微流体图案的变化可能是电池性能恶化或出现其他问题的信号。锂离子电池的健康状况是磁感应的一种应用。电池健康状况的变化和其他性能问题可以通过磁性质量传输模式来发现。本研究探讨了磁场对拉伸片上纳米多孔通道中艾林-鲍尔质量传输的影响。利用相似性变换,通过二阶近似将表现该现象的主方程转化为非线性微分方程。此外,还使用了一种名为最优同调渐近法(OHAM)的半解析技术来求解转换后的艾林-鲍威尔模型。数值结果表明了速度、表皮摩擦系数和舍伍德数的变化对拟议方案的影响。
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引用次数: 0
A comprehensive review of the aging mechanism and degradation costs of fresh and second-life batteries based on analytical and deterministic methods 基于分析和确定性方法对新电池和二次寿命电池的老化机制和降解成本进行全面审查
Pub Date : 2024-06-12 DOI: 10.1002/est2.661
Musa Terkes, Alpaslan Demirci, Erdin Gokalp

Batteries' aging evolution and degradation functions may vary depending on the application area and various stress factors. Studies on its aging characteristics are ongoing, considering the unpredictable tendency of battery degradation during first and secondary usage periods. Battery degradation directly affects operating costs and prevents many stakeholders from making reliable short- or long-term investment plans. Thus, this review study first introduces the battery models commonly used by researchers and provides an overview of the aging mechanism and estimation methods for health status and remaining capacity. Analytical and deterministic aging/degradation functions/models proposed by the researchers are discussed in detail, and cost equations based on degradation are reviewed. This approach was followed for the fresh and second-life batteries by further investigating the impact of stress factors on the aging process and cost. The details of aging prediction approaches based on traditional methods, machine learning, and artificial intelligence are out of the scope of this review article. Discussing the shortcomings of aging analyses/functions and introducing different perspectives on the degradation characteristics will help researchers and provide a roadmap for many stakeholders.

电池的老化演变和降解功能可能因应用领域和各种应力因素而异。考虑到电池在第一次和第二次使用期间不可预测的退化趋势,对其老化特性的研究仍在进行中。电池老化会直接影响运营成本,使许多利益相关者无法制定可靠的短期或长期投资计划。因此,本综述研究首先介绍了研究人员常用的电池模型,并概述了老化机制以及健康状况和剩余容量的估算方法。详细讨论了研究人员提出的分析性和确定性老化/降解函数/模型,并回顾了基于降解的成本方程。通过进一步研究应力因素对老化过程和成本的影响,对新电池和二次寿命电池采用了这种方法。基于传统方法、机器学习和人工智能的老化预测方法的细节不在本综述文章的讨论范围之内。讨论老化分析/功能的不足之处并介绍有关降解特征的不同观点将有助于研究人员的工作,并为许多利益相关者提供路线图。
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引用次数: 0
Study of composite polymer degradation for high pressure hydrogen vessel by machine learning approach 利用机器学习方法研究高压氢气容器的复合聚合物降解问题
Pub Date : 2024-06-07 DOI: 10.1002/est2.645
K. Kadri, A. Kallel, G. Guerard, A. Ben Abdallah, S. Ballut, J. Fitoussi, M. Shirinbayan

The aim of this article is to study the degradation of a composite material under static pressure. The high pressure condition is similar to the one encountered inside hydrogen tanks. Damage modeling was used to evaluate the behavior of hydrogen tanks to high pressure. A practical approach, coupling a finite element method (FEM) simulation and machine learning (ML) algorithm, is suggested. The representative volume element (RVE) was used in association with a choice of a behavior law and a damage law as an input data. Algorithms for ML classification such as K-nearest neighbors (k-NN) and a special k-NN with a dynamic time warping metric were used. The hierarchical clustering through dendrograms visualizations allowed to exhibit the impact of composite parameters in relation to fiber, matrix properties and fiber volume fraction on the strain degradation under external static pressure. Continuing this, the optimum RVE which shows a low degradation value will be exhibited.

本文旨在研究复合材料在静压条件下的降解问题。高压条件与氢气罐内遇到的情况类似。损伤建模用于评估氢气罐在高压下的行为。提出了一种将有限元法(FEM)模拟和机器学习(ML)算法相结合的实用方法。将代表性体积元素(RVE)与行为法则和损伤法则的选择结合起来作为输入数据。使用了 K-近邻(k-NN)和具有动态时间扭曲度量的特殊 K-NN 等 ML 分类算法。通过树枝图的可视化分层聚类,可以展示与纤维、基体特性和纤维体积分数有关的复合材料参数对外部静压下应变降解的影响。接下来,将展示降解值较低的最佳 RVE。
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引用次数: 0
All-solid-state Li-ion battery: A study on the charge/discharge mechanism of an LMO-BCD-MgC system 全固态锂离子电池:LMO-BCD-MgC 系统的充放电机制研究
Pub Date : 2024-06-06 DOI: 10.1002/est2.664
Po-Ting Wu, Jun-Ren Zhao, Fei-Yi Hung, Hsin Kuan

This study presents the fabrication of an all-solid-state lithium-ion battery using lithium manganese oxide (LiMn2O4; LMO) as the cathode, graphite (C), and carbon-coated magnesium (MgC) as the anode, along with a silicate-based solid electrolyte. To assess the charge/discharge mechanism, three polymeric membranes with varying weight percentages (5%, 30%, and 50%) of magnesium silicate are produced through battery-cloth deposition (BCD) for use as the solid electrolyte. The findings reveal that enhancing the magnesium silicate content in the solid electrolyte (particularly at 50%) results in an increased specific capacity of the battery. The MgC anode exhibits a peak capacity of approximately 780 mAh/g during the third cycle, maintaining capacity retention of 100% over 26 cycles, addressing the issues of low specific capacity and self-discharge in the solid-state Li-ion battery. Nevertheless, prolonged charge/discharge testing leads to an escalation in the surface roughness and porosity of the carbon coating on the MgC anode, resulting in a decline in capacity. These results demonstrate that the LMO-BCD-MgC battery system proposed in this study is a secure, eco-friendly, and cost-effective option with potential applications in energy storage.

本研究介绍了一种全固态锂离子电池的制造方法,该电池采用锂锰氧化物(LiMn2O4;LMO)作为阴极,石墨(C)和碳包覆镁(MgC)作为阳极,并使用硅酸盐基固体电解质。为了评估充电/放电机制,通过电池布沉积(BCD)生产了三种不同重量百分比(5%、30% 和 50%)的硅酸镁聚合物膜,用作固体电解质。研究结果表明,提高固态电解质中的硅酸镁含量(尤其是 50%)可提高电池的比容量。MgC 阳极在第三个循环中显示出约 780 mAh/g 的峰值容量,并在 26 个循环中保持 100% 的容量,从而解决了固态锂离子电池中低比容量和自放电的问题。然而,长时间的充放电测试会导致 MgC 阳极碳涂层的表面粗糙度和孔隙率增加,从而导致容量下降。这些结果表明,本研究中提出的 LMO-BCD-MgC 电池系统是一种安全、环保、经济高效的选择,在能源存储领域具有潜在的应用前景。
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引用次数: 0
Lead-free perovskite Cs2NaGaBr6 n-i-p solar cell for higher power conversion efficiency to improved energy storage performance 无铅过氧化物 Cs2NaGaBr6 ni-i-p 太阳能电池,从提高功率转换效率到改善储能性能
Pub Date : 2024-06-06 DOI: 10.1002/est2.665
Neha Gupta, Ravi Gupta, Aditya Jain, Rajeev Gupta, Bharat Choudhary, Kaushal Kumar, Amit Kumar Goyal, Yehia Massoud, Ajay Kumar

It is important to enhance the efficiency of perovskite solar cells (PSCs) to improve the energy storage performance within a time frame. In this study, a lead-free perovskite Cs2NaGaBr6 n-i-p solar cell is presented for higher PCE to improve energy storage performance. Keeping the toxicity of lead-based perovskite in mind we have made attempts to study the characteristics of n-i-p solar cells based on lead-free double halide perovskite Cs2NaGaBr6 novel material. In the proposed photovoltaic framework, M21+N2+N3+X61− as a double perovskite material is used, where N2+ = Na, M21+ = Cs, N3+ = Ga, and X61− = Br. The Cs2NaGaBr6 is an organic-inorganic perovskite material because of its direct band gap structure with a band gap of 1.762 eV. The solar cell proposed in the present framework has achieved a higher efficiency of 26.09% with optimized parameters specific to device design in terms of different absorber layer thicknesses (0.6–1.2 μm), and absorber layer doping concentrations (1 × 1018 cm−3 to 1 × 1022 cm−3). In the present study, improved results are obtained such as electric field, current density, energy band profile, generation and recombination factor, quantum efficiency, and generation/ recombination factor by suitably varying the absorber layer thicknesses and absorber layer doping concentrations. Additionally, many parameters related to the photovoltaic performance of solar cells such as Jsc (19.535 mA/cm2), Voc (1.775 V), FF (91.35%), and PCE (η) (27.81%) have been evaluated in the present study. Therefore, the device, that is, solar cell based on lead-free double halide perovskite Cs2NaGaBr6 novel material, proposed in the present study may be used to manufacture much more efficient lead-free perovskites for photovoltaic applications and also improve the energy storage performance within a time frame.

提高过氧化物太阳能电池(PSCs)的效率对于在一定时间内改善储能性能非常重要。本研究提出了一种无铅包晶 Cs2NaGaBr6 ni-i-p 太阳能电池,以提高 PCE,改善储能性能。考虑到铅基透辉石的毒性,我们尝试研究了基于无铅双卤化物透辉石 Cs2NaGaBr6 新型材料的 ni-i-p 太阳能电池的特性。在提出的光伏框架中,使用了 M21+N2+N3+X61- 作为双包晶石材料,其中 N2+ = Na,M21+ = Cs,N3+ = Ga,X61- = Br。Cs2NaGaBr6 是一种有机-无机包晶石材料,因为它具有直接带隙结构,带隙为 1.762 eV。本框架中提出的太阳能电池通过优化不同吸收层厚度(0.6-1.2 μm)和吸收层掺杂浓度(1 × 1018 cm-3 至 1 × 1022 cm-3)的器件设计特定参数,实现了 26.09% 的较高效率。在本研究中,通过适当改变吸收层厚度和吸收层掺杂浓度,电场、电流密度、能带轮廓、生成和重组因子、量子效率以及生成/重组因子等结果都得到了改善。此外,本研究还评估了与太阳能电池光伏性能有关的许多参数,如 Jsc(19.535 mA/cm2)、Voc(1.775 V)、FF(91.35%)和 PCE (η) (27.81%)。因此,本研究提出的设备,即基于无铅双卤化物包晶 Cs2NaGaBr6 新型材料的太阳能电池,可用于制造更高效的光伏应用无铅包晶,并在一定时间内提高储能性能。
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引用次数: 0
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Energy Storage
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