首页 > 最新文献

Energy Storage最新文献

英文 中文
Advanced Energy Management, Storage, and Control in Microgrids: AI and Blockchain Perspectives 微电网中的先进能源管理、存储和控制:AI和区块链的观点
Pub Date : 2025-11-23 DOI: 10.1002/est2.70297
Mohd Bilal,  Imdadullah, Salman Hameed

This paper examines artificial intelligence and blockchain applications for optimizing energy in multi-energy microgrids. It begins with historical energy context and the need for efficient microgrid solutions. The study reviews different energy resources and their conversion processes, followed by an in-depth review of the advanced energy storage systems, including battery, supercapacitor, superconducting magnetic, fuel cell, flywheel, and hybrid energy storage systems. Control of microgrid systems is analyzed for centralized, decentralized, distributed, hierarchical, and predictive controls, discussing their advantages and limitations. Modern control strategies based on artificial intelligence and blockchain are critically reviewed and compared. Artificial intelligence used in microgrid (MG) is discussed in detail, which improves scalability, resilience, and efficiency. Machine learning techniques employed in MG are discussed which enhance the accuracy of predictions in terms of energy distribution, demand, and stability. Finally, around 125 research publications on the subject are also appended for quick reference.

本文研究了人工智能和区块链在多能微电网能源优化中的应用。它从历史能源背景和对高效微电网解决方案的需求开始。本研究回顾了不同的能源资源及其转换过程,然后深入回顾了先进的储能系统,包括电池、超级电容器、超导磁、燃料电池、飞轮和混合储能系统。分析了微电网系统的集中控制、分散控制、分布式控制、分层控制和预测控制,讨论了它们的优点和局限性。对基于人工智能和区块链的现代控制策略进行了批判性的回顾和比较。详细讨论了人工智能在微电网中的应用,提高了微电网的可扩展性、弹性和效率。讨论了MG中使用的机器学习技术,这些技术可以提高能源分布、需求和稳定性方面的预测准确性。最后,还附上了关于该主题的大约125份研究出版物,以供快速参考。
{"title":"Advanced Energy Management, Storage, and Control in Microgrids: AI and Blockchain Perspectives","authors":"Mohd Bilal,&nbsp; Imdadullah,&nbsp;Salman Hameed","doi":"10.1002/est2.70297","DOIUrl":"https://doi.org/10.1002/est2.70297","url":null,"abstract":"<div>\u0000 \u0000 <p>This paper examines artificial intelligence and blockchain applications for optimizing energy in multi-energy microgrids. It begins with historical energy context and the need for efficient microgrid solutions. The study reviews different energy resources and their conversion processes, followed by an in-depth review of the advanced energy storage systems, including battery, supercapacitor, superconducting magnetic, fuel cell, flywheel, and hybrid energy storage systems. Control of microgrid systems is analyzed for centralized, decentralized, distributed, hierarchical, and predictive controls, discussing their advantages and limitations. Modern control strategies based on artificial intelligence and blockchain are critically reviewed and compared. Artificial intelligence used in microgrid (MG) is discussed in detail, which improves scalability, resilience, and efficiency. Machine learning techniques employed in MG are discussed which enhance the accuracy of predictions in terms of energy distribution, demand, and stability. Finally, around 125 research publications on the subject are also appended for quick reference.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145625702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nano-Engineered Composite Phase Change Material: A High Thermal Stability and Energy-Efficient Thermal Management Strategy for Li-Ion Batteries 纳米工程复合相变材料:锂离子电池的高热稳定性和高能效热管理策略
Pub Date : 2025-11-19 DOI: 10.1002/est2.70299
Rajesh Nasinathan, Kamatchi Rajaram

Thermal management of lithium-ion batteries (LIBs) faces challenges in ensuring optimal performance, safety, and lifespan due to excessive heat generation during high power discharging cycles. Recently, nano-enhanced phase change materials have been considered as sustainable passive cooling techniques to enhance the LIBs' performance. Unlike previous studies that focused on single or binary filler systems, this work introduces a novel multicomponent composite phase change material (CPCM) by incorporating varying loadings of expanded graphite (EG), hexagonal boron nitride nanosheets (h-BNNSs), MXene (Ti3C2Tx), and epoxy resin (ER) into the matrix of paraffin wax/polyethylene glycol/lauric acid to synergistically enhance thermal performance. Three different CPCM samples (CPCM 1, CPCM 2, and CPCM 3) are synthesized and characterized by XRD, FTIR, and SEM. Thermal properties are evaluated by DSC and TGA. Among all, CPCM 1 results in a maximum latent heat of 153.28 J/g and thermal conductivity of 1.26 W/m K in addition to superior antileakage performance. Additionally, CPCM 1 is applied to a 4S6P LIB module and tested under 1C, 2C, and 3C discharge rates. At 3C, the peak temperature remained within the safe threshold of 50°C with a temperature variation of just 1.91°C between the cells. The battery module retained a capacity of 1207.56 mAh over 50 discharge cycles. The results highlight the potential of the developed CPCM as an effective, lightweight, and energy-efficient passive cooling solution for next-generation LIB thermal management systems.

由于在高功率放电循环过程中产生过多的热量,锂离子电池(LIBs)的热管理面临着确保最佳性能、安全性和寿命的挑战。近年来,纳米增强相变材料被认为是一种可持续的被动冷却技术,可以提高锂离子电池的性能。与以往研究单一或二元填充体系不同,本研究引入了一种新型的多组分复合相变材料(CPCM),通过将不同负载的膨胀石墨(EG)、六方氮化硼纳米片(h-BNNSs)、MXene (Ti3C2Tx)和环氧树脂(ER)加入石蜡/聚乙二醇/月桂酸基体中,协同提高热性能。合成了三种不同的CPCM样品(CPCM 1、CPCM 2和CPCM 3),并用XRD、FTIR和SEM对其进行了表征。热性能通过DSC和TGA进行了评价。其中,CPCM 1的最大潜热为153.28 J/g,导热系数为1.26 W/m K,且具有优异的防漏性能。此外,CPCM 1应用于4S6P LIB模块,并在1C, 2C和3C放电率下进行测试。在3C时,峰值温度保持在50°C的安全阈值内,电池之间的温度变化仅为1.91°C。电池模块在50次放电循环中保持1207.56 mAh的容量。研究结果突出了CPCM作为下一代LIB热管理系统的有效、轻量化和节能的被动冷却解决方案的潜力。
{"title":"Nano-Engineered Composite Phase Change Material: A High Thermal Stability and Energy-Efficient Thermal Management Strategy for Li-Ion Batteries","authors":"Rajesh Nasinathan,&nbsp;Kamatchi Rajaram","doi":"10.1002/est2.70299","DOIUrl":"https://doi.org/10.1002/est2.70299","url":null,"abstract":"<div>\u0000 \u0000 <p>Thermal management of lithium-ion batteries (LIBs) faces challenges in ensuring optimal performance, safety, and lifespan due to excessive heat generation during high power discharging cycles. Recently, nano-enhanced phase change materials have been considered as sustainable passive cooling techniques to enhance the LIBs' performance. Unlike previous studies that focused on single or binary filler systems, this work introduces a novel multicomponent composite phase change material (CPCM) by incorporating varying loadings of expanded graphite (EG), hexagonal boron nitride nanosheets (h-BNNSs), MXene (Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>), and epoxy resin (ER) into the matrix of paraffin wax/polyethylene glycol/lauric acid to synergistically enhance thermal performance. Three different CPCM samples (CPCM 1, CPCM 2, and CPCM 3) are synthesized and characterized by XRD, FTIR, and SEM. Thermal properties are evaluated by DSC and TGA. Among all, CPCM 1 results in a maximum latent heat of 153.28 J/g and thermal conductivity of 1.26 W/m K in addition to superior antileakage performance. Additionally, CPCM 1 is applied to a 4S6P LIB module and tested under 1C, 2C, and 3C discharge rates. At 3C, the peak temperature remained within the safe threshold of 50°C with a temperature variation of just 1.91°C between the cells. The battery module retained a capacity of 1207.56 mAh over 50 discharge cycles. The results highlight the potential of the developed CPCM as an effective, lightweight, and energy-efficient passive cooling solution for next-generation LIB thermal management systems.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145580978","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Field-Scale Evaluation of Underwater Compressed Air Energy Storage System at Marine Depths 海洋深处水下压缩空气储能系统的现场评价
Pub Date : 2025-11-18 DOI: 10.1002/est2.70300
Wenxian Tang, Jooyoung Im, Thomas Finkbeiner

Underwater Compressed Air Energy Storage (UWCAES) offers a scalable solution for storing intermittent renewable energy. It has high volumetric energy density, does not require cushion gas, provides flexible offshore sites, and requires minimal onshore land use. To date, field-scale validation of such systems in real marine environments, especially at practical depths (> 30 m), remains limited. To address this gap, we present the first field trial of a rigid-tank UWCAES system deployed at depths of 30–70 m in the Red Sea. The system comprises a 294 L rigid PVC tank with an open bottom designed for air–seawater displacement during repeated charging and discharging cycles. Real-time measurements of pressure, temperature, and flow rate were conducted across different outlet nozzle configurations and storage depths. Experimental results demonstrated stable system operation and effective energy delivery. During discharge, the volumetric flow rate remained nearly constant, indicating consistent power output. Increased storage depth led to higher flow rates, highlighting the role of hydrostatic pressure in enhancing system performance. Despite the expected cooling from adiabatic expansion, the compressed air temperature along the submerged hose sections remained close to the local seawater temperature and increased further in the above-water sections. This temperature profile suggested passive thermal buffering from the surrounding seawater and additional warming from ambient air exposure near the outlet. These findings provide new empirical insights into the thermal dynamics, operational stability, and offshore deployment feasibility of UWCAES systems at practical depths.

水下压缩空气储能(UWCAES)为存储间歇性可再生能源提供了可扩展的解决方案。它具有高的体积能量密度,不需要缓冲气体,提供灵活的海上场地,并且需要最小的陆上土地使用。到目前为止,这种系统在实际海洋环境中的现场规模验证,特别是在实际深度(30米),仍然有限。为了解决这一问题,我们首次在红海30-70米深处进行了刚性储罐UWCAES系统的现场试验。该系统包括一个294升的硬质PVC罐,其底部是开放式的,用于在反复充放电循环中进行空气-海水置换。在不同的出口喷嘴配置和储存深度下,进行了压力、温度和流量的实时测量。实验结果表明,系统运行稳定,能量输送有效。在放电过程中,体积流量几乎保持恒定,表明功率输出一致。储层深度的增加导致了更高的流量,突出了静水压力在提高系统性能方面的作用。尽管预期的绝热膨胀冷却,但水下软管段的压缩空气温度仍然接近当地海水温度,并且在水上部分进一步升高。这一温度分布表明来自周围海水的被动热缓冲和来自出口附近环境空气暴露的额外变暖。这些发现为UWCAES系统在实际深度的热动力学、运行稳定性和海上部署可行性提供了新的经验见解。
{"title":"Field-Scale Evaluation of Underwater Compressed Air Energy Storage System at Marine Depths","authors":"Wenxian Tang,&nbsp;Jooyoung Im,&nbsp;Thomas Finkbeiner","doi":"10.1002/est2.70300","DOIUrl":"https://doi.org/10.1002/est2.70300","url":null,"abstract":"<div>\u0000 \u0000 <p>Underwater Compressed Air Energy Storage (UWCAES) offers a scalable solution for storing intermittent renewable energy. It has high volumetric energy density, does not require cushion gas, provides flexible offshore sites, and requires minimal onshore land use. To date, field-scale validation of such systems in real marine environments, especially at practical depths (&gt; 30 m), remains limited. To address this gap, we present the first field trial of a rigid-tank UWCAES system deployed at depths of 30–70 m in the Red Sea. The system comprises a 294 L rigid PVC tank with an open bottom designed for air–seawater displacement during repeated charging and discharging cycles. Real-time measurements of pressure, temperature, and flow rate were conducted across different outlet nozzle configurations and storage depths. Experimental results demonstrated stable system operation and effective energy delivery. During discharge, the volumetric flow rate remained nearly constant, indicating consistent power output. Increased storage depth led to higher flow rates, highlighting the role of hydrostatic pressure in enhancing system performance. Despite the expected cooling from adiabatic expansion, the compressed air temperature along the submerged hose sections remained close to the local seawater temperature and increased further in the above-water sections. This temperature profile suggested passive thermal buffering from the surrounding seawater and additional warming from ambient air exposure near the outlet. These findings provide new empirical insights into the thermal dynamics, operational stability, and offshore deployment feasibility of UWCAES systems at practical depths.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145581002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Integrating Machine Learning With SCAPS-1D to Optimize Lead-Free LCCZO Perovskites for Sustainable Solar Energy Harvesting 集成机器学习与SCAPS-1D优化无铅LCCZO钙钛矿用于可持续太阳能收集
Pub Date : 2025-11-15 DOI: 10.1002/est2.70302
Ranadip Kundu

Perovskite solar cells (PSCs) have rapidly advanced as a next-generation photovoltaic technology due to their high efficiency and flexible fabrication routes; however, the reliance on lead-based absorbers raises concerns regarding toxicity and long-term stability. This study introduces La0.5Ce0.5Co0.9Zn0.1O3 (LCCZO), a double perovskite oxide, as a lead-free, stable absorber candidate for eco-friendly PSCs. First-principles calculations validate its crystallographic stability and predict a direct bandgap of ~1.8 eV, suitable for efficient visible-light absorption. Optical analysis reveals strong absorption and favorable dielectric properties, supporting low exciton binding and effective charge separation. Device simulations using SCAPS-1D integrating TiO2 and NiO as transport layers demonstrate optimal performance upon tuning absorber thickness, carrier density, and defect levels. A maximum power conversion efficiency (PCE) of 23.41% is achieved, with an open-circuit voltage (Voc) of 1.42 V, short-circuit current density (Jsc) of 18.56 mA cm−2, and fill factor (FF) of 88.92%. The device exhibits robust tolerance to bulk and interfacial defects, attributed to favorable band offsets and intrinsic defect chemistry. A machine learning model trained on simulated datasets accelerates performance prediction across parameter regimes, achieving ~82.5% accuracy and reducing computation time significantly. These results position LCCZO as a promising lead-free absorber and highlight the synergy of computational design and machine learning for sustainable solar energy development.

钙钛矿太阳能电池(PSCs)由于其高效率和灵活的制造路线而迅速发展成为下一代光伏技术;然而,对铅基吸收剂的依赖引起了对毒性和长期稳定性的担忧。本研究介绍了La0.5Ce0.5Co0.9Zn0.1O3 (LCCZO),一种双钙钛矿氧化物,作为无铅、稳定的环保psc吸收剂候选材料。第一性原理计算验证了其晶体稳定性,并预测了~1.8 eV的直接带隙,适合于有效的可见光吸收。光学分析表明,它具有较强的吸收和良好的介电性能,支持低激子结合和有效的电荷分离。使用SCAPS-1D集成TiO2和NiO作为传输层的器件模拟表明,在调整吸收剂厚度、载流子密度和缺陷水平时,器件性能最佳。在开路电压(Voc)为1.42 V,短路电流密度(Jsc)为18.56 mA cm−2,填充系数(FF)为88.92%的情况下,实现了23.41%的最大功率转换效率(PCE)。由于良好的能带偏移和内在缺陷化学性质,该器件对体积和界面缺陷具有强大的耐受性。在模拟数据集上训练的机器学习模型加速了跨参数制度的性能预测,达到了~82.5%的准确率,并显着减少了计算时间。这些结果将LCCZO定位为一种有前途的无铅吸收剂,并突出了计算设计和机器学习在可持续太阳能发展中的协同作用。
{"title":"Integrating Machine Learning With SCAPS-1D to Optimize Lead-Free LCCZO Perovskites for Sustainable Solar Energy Harvesting","authors":"Ranadip Kundu","doi":"10.1002/est2.70302","DOIUrl":"https://doi.org/10.1002/est2.70302","url":null,"abstract":"<div>\u0000 \u0000 <p>Perovskite solar cells (PSCs) have rapidly advanced as a next-generation photovoltaic technology due to their high efficiency and flexible fabrication routes; however, the reliance on lead-based absorbers raises concerns regarding toxicity and long-term stability. This study introduces La<sub>0.5</sub>Ce<sub>0.5</sub>Co<sub>0.9</sub>Zn<sub>0.1</sub>O<sub>3</sub> (LCCZO), a double perovskite oxide, as a lead-free, stable absorber candidate for eco-friendly PSCs. First-principles calculations validate its crystallographic stability and predict a direct bandgap of ~1.8 eV, suitable for efficient visible-light absorption. Optical analysis reveals strong absorption and favorable dielectric properties, supporting low exciton binding and effective charge separation. Device simulations using SCAPS-1D integrating TiO<sub>2</sub> and NiO as transport layers demonstrate optimal performance upon tuning absorber thickness, carrier density, and defect levels. A maximum power conversion efficiency (PCE) of 23.41% is achieved, with an open-circuit voltage (<i>V</i><sub>oc</sub>) of 1.42 V, short-circuit current density (<i>J</i><sub>sc</sub>) of 18.56 mA cm<sup>−2</sup>, and fill factor (FF) of 88.92%. The device exhibits robust tolerance to bulk and interfacial defects, attributed to favorable band offsets and intrinsic defect chemistry. A machine learning model trained on simulated datasets accelerates performance prediction across parameter regimes, achieving ~82.5% accuracy and reducing computation time significantly. These results position LCCZO as a promising lead-free absorber and highlight the synergy of computational design and machine learning for sustainable solar energy development.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145522045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailoring Zinc Ferrite With Mg and Mn: Dual Dopant Synergy for Hybrid Energy Storage Supercapacitor Devices 用Mg和Mn裁剪锌铁氧体:混合储能超级电容器器件的双掺杂协同作用
Pub Date : 2025-11-15 DOI: 10.1002/est2.70296
Abu Fahad, Jitendra Kumar Yadav, Bharti Rani, Priyanka Saini, Pragya Mishra, Ambesh Dixit, Manoj K. Singh

Doping ZnFe2O4 with Magnesium (Mg) and Manganese (Mn) promotes beneficial defects by tuning the bandgap and enhances the electronic conductivity, along with improvement in the electrochemical performance. Incorporating these dopants optimizes the crystal structure and provides additional active sites, leading to a superior rate capability and improved charge storage capacity compared to pristine ZnFe2O4 for the supercapacitors (SCs). Zn(1−x)MgxFe(2−x)MnxO4 (ZMFMO), with x = 0.00, 0.05, and 0.10, was synthesized using the sol–gel autocombustion technique and confirmed with the physical characterizations, including the detailed X-ray diffraction (XRD), Raman and UV–visible spectroscopy, field emission scanning electron microscopy (FESEM), and energy dispersive X-ray spectroscopy (EDX) analysis. Brunauer–Emmett–Teller (BET) isotherms were analyzed, which show the impact of doping on the surface area. The electrochemical performance of the prepared symmetric coin cell and three-electrode system was explored using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and galvanostatic charging and discharging (GCD) studies. The three-electrode characterization suggests high specific capacitance (Csp) of 121.5, 130.2, and 162.5 F g−1 for ZMFMO_00, ZMFMO_05, and ZMFMO_10, respectively, while the Csp was found to be 34.8, 36.4, and 47.3 F g−1 at 1 mV s−1 for ZMFMO_00, ZMFMO_05, and ZMFMO_10 in symmetric coin cells, respectively. It also shows excellent charge–discharge characteristics with a 23.9, 28.6, and 43.6 s discharging time for ZMFMO_00, ZMFMO_05, and ZMFMO_10, respectively, at 392 mA g−1. It illustrates the energy and power density 5.01, 5.08, 8.19 Wh kg−1 and 29.52, 28.09, 28.11 W kg−1 at 39 mA g−1 for ZMFMO_00, ZMFMO_05, and ZMFMO_10 symmetric coin cell devices, respectively. Ex situ XRD analysis was performed to check the electrode stability after long-term cycling. The results indicated that the developed doped nanomaterial exhibits excellent charge storage characteristics, followed by an LED light demonstration.

在ZnFe2O4中掺杂镁(Mg)和锰(Mn)可以通过调节带隙来促进有益缺陷的产生,提高电子导电性,改善电化学性能。与原始的ZnFe2O4相比,加入这些掺杂剂可以优化晶体结构并提供额外的活性位点,从而提高超级电容器(SCs)的倍率能力和电荷存储容量。采用溶胶-凝胶自燃烧技术合成了x = 0.00, 0.05和0.10的Zn(1−x)MgxFe(2−x)MnxO4 (ZMFMO),并进行了详细的x射线衍射(XRD),拉曼光谱和紫外可见光谱,场发射扫描电镜(FESEM)和能量色散x射线光谱(EDX)分析等物理表征。分析了brunauer - emmet - teller (BET)等温线,揭示了掺杂对表面面积的影响。利用循环伏安法(CV)、电化学阻抗谱(EIS)和恒流充放电(GCD)研究了所制备的对称硬币电池和三电极体系的电化学性能。三电极表征表明,ZMFMO_00、ZMFMO_05和ZMFMO_10的比电容(Csp)分别为121.5、130.2和162.5 F g−1,而ZMFMO_00、ZMFMO_05和ZMFMO_10在1 mV s−1下的比电容分别为34.8、36.4和47.3 F g−1。ZMFMO_00、ZMFMO_05和ZMFMO_10在392 mA g−1下的放电时间分别为23.9、28.6和43.6 s,具有良好的充放电特性。图中显示了ZMFMO_00、ZMFMO_05和ZMFMO_10对称硬币电池器件在39 mA g - 1时的能量和功率密度分别为5.01、5.08、8.19 Wh kg - 1和29.52、28.09、28.11 W kg - 1。通过x射线衍射(Ex - situ XRD)分析,验证了长期循环后电极的稳定性。结果表明,所制备的掺杂纳米材料具有优异的电荷存储特性,并进行了LED光演示。
{"title":"Tailoring Zinc Ferrite With Mg and Mn: Dual Dopant Synergy for Hybrid Energy Storage Supercapacitor Devices","authors":"Abu Fahad,&nbsp;Jitendra Kumar Yadav,&nbsp;Bharti Rani,&nbsp;Priyanka Saini,&nbsp;Pragya Mishra,&nbsp;Ambesh Dixit,&nbsp;Manoj K. Singh","doi":"10.1002/est2.70296","DOIUrl":"https://doi.org/10.1002/est2.70296","url":null,"abstract":"<div>\u0000 \u0000 <p>Doping ZnFe<sub>2</sub>O<sub>4</sub> with Magnesium (Mg) and Manganese (Mn) promotes beneficial defects by tuning the bandgap and enhances the electronic conductivity, along with improvement in the electrochemical performance. Incorporating these dopants optimizes the crystal structure and provides additional active sites, leading to a superior rate capability and improved charge storage capacity compared to pristine ZnFe<sub>2</sub>O<sub>4</sub> for the supercapacitors (SCs). Zn<sub>(1−<i>x</i>)</sub>Mg<sub><i>x</i></sub>Fe<sub>(2−<i>x</i>)</sub>Mn<sub><i>x</i></sub>O<sub>4</sub> (ZMFMO), with <i>x</i> = 0.00, 0.05, and 0.10, was synthesized using the sol–gel autocombustion technique and confirmed with the physical characterizations, including the detailed X-ray diffraction (XRD), Raman and UV–visible spectroscopy, field emission scanning electron microscopy (FESEM), and energy dispersive X-ray spectroscopy (EDX) analysis. Brunauer–Emmett–Teller (BET) isotherms were analyzed, which show the impact of doping on the surface area. The electrochemical performance of the prepared symmetric coin cell and three-electrode system was explored using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and galvanostatic charging and discharging (GCD) studies. The three-electrode characterization suggests high specific capacitance (<i>C</i><sub>sp</sub>) of 121.5, 130.2, and 162.5 F g<sup>−1</sup> for ZMFMO_00, ZMFMO_05, and ZMFMO_10, respectively, while the <i>C</i><sub>sp</sub> was found to be 34.8, 36.4, and 47.3 F g<sup>−1</sup> at 1 mV s<sup>−1</sup> for ZMFMO_00, ZMFMO_05, and ZMFMO_10 in symmetric coin cells, respectively. It also shows excellent charge–discharge characteristics with a 23.9, 28.6, and 43.6 s discharging time for ZMFMO_00, ZMFMO_05, and ZMFMO_10, respectively, at 392 mA g<sup>−1</sup>. It illustrates the energy and power density 5.01, 5.08, 8.19 Wh kg<sup>−1</sup> and 29.52, 28.09, 28.11 W kg<sup>−1</sup> at 39 mA g<sup>−1</sup> for ZMFMO_00, ZMFMO_05, and ZMFMO_10 symmetric coin cell devices, respectively. Ex situ XRD analysis was performed to check the electrode stability after long-term cycling. The results indicated that the developed doped nanomaterial exhibits excellent charge storage characteristics, followed by an LED light demonstration.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145522049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Porous Carbon Aerogels for High-Performance Lithium-Sulfur Battery 高性能锂硫电池用多孔碳气凝胶
Pub Date : 2025-11-14 DOI: 10.1002/est2.70295
Wang Lin, Daniel Nframah Ampong, Kwadwo Mensah-Darkwa, Ram K. Gupta

The rationale for designing cathode material for a high-performance lithium-sulfur (Li-S) battery, which offers high-rate capability and stability for energy storage applications, has been adopted in this work. Sodium carbonate solution was utilized as a catalyst to prepare porous carbon aerogels from resorcinol and formaldehyde via freeze-drying and carbonization at 800°C in an N2 atmosphere. The synthesized materials were used as a composite with sulfur to fabricate electrodes for Li-S batteries. The prepared carbon/sulfur composite (HG-40%) delivered an initial capacity of 1510 mAh/g at 0.25 C with a very high level of reversibility. The cycling tests showed very good stability at 1 C, maintaining a discharge specific capacity of about 71% of the initially recorded value (from 639 to 455 mAh/g) after 500 cycles. These performances can be attributed to the improvement in accommodating more active species, resulting in a shorter ionic path within the aerogel-based carbon matrix. This research opens a new avenue for synthesizing and fabricating cathode materials for high-performance Li-S batteries, benefiting the electrochemical industry.

为高性能锂硫(Li-S)电池设计阴极材料的基本原理,为储能应用提供了高倍率能力和稳定性,已被采用在这项工作中。以碳酸钠溶液为催化剂,以间苯二酚和甲醛为原料,在800℃N2气氛下进行冷冻干燥和碳化制备多孔碳气凝胶。将合成的材料与硫作为复合材料制备锂硫电池电极。所制备的碳/硫复合材料(HG-40%)在0.25℃时的初始容量为1510 mAh/g,具有非常高的可逆性。循环测试显示,电池在1c下的稳定性非常好,在500次循环后,放电比容量保持在初始记录值(从639 mAh/g到455 mAh/g)的71%左右。这些性能可归因于容纳更多活性物质的改进,导致气凝胶基碳基体内的离子路径更短。本研究为高性能锂电池正极材料的合成和制造开辟了新的途径,有利于电化学工业的发展。
{"title":"Porous Carbon Aerogels for High-Performance Lithium-Sulfur Battery","authors":"Wang Lin,&nbsp;Daniel Nframah Ampong,&nbsp;Kwadwo Mensah-Darkwa,&nbsp;Ram K. Gupta","doi":"10.1002/est2.70295","DOIUrl":"https://doi.org/10.1002/est2.70295","url":null,"abstract":"<div>\u0000 \u0000 <p>The rationale for designing cathode material for a high-performance lithium-sulfur (Li-S) battery, which offers high-rate capability and stability for energy storage applications, has been adopted in this work. Sodium carbonate solution was utilized as a catalyst to prepare porous carbon aerogels from resorcinol and formaldehyde via freeze-drying and carbonization at 800°C in an N<sub>2</sub> atmosphere. The synthesized materials were used as a composite with sulfur to fabricate electrodes for Li-S batteries. The prepared carbon/sulfur composite (HG-40%) delivered an initial capacity of 1510 mAh/g at 0.25 C with a very high level of reversibility. The cycling tests showed very good stability at 1 C, maintaining a discharge specific capacity of about 71% of the initially recorded value (from 639 to 455 mAh/g) after 500 cycles. These performances can be attributed to the improvement in accommodating more active species, resulting in a shorter ionic path within the aerogel-based carbon matrix. This research opens a new avenue for synthesizing and fabricating cathode materials for high-performance Li-S batteries, benefiting the electrochemical industry.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145522037","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of the Capacitive Properties of Bimetallic Iron–Nickel Organic Framework and Carbon Nanotube Composite on Carbon Felt Electrode 双金属铁镍有机骨架与碳纳米管复合材料在碳毡电极上的电容性能研究
Pub Date : 2025-11-14 DOI: 10.1002/est2.70298
Yudum Tepeli Büyüksünetçi

The increasing global population and rapid depletion of energy resources have intensified the demand for renewable energy and advanced energy storage solutions. Supercapacitors, with their high power density, long cycle life, and fast charging capability, are emerging as a promising alternative to conventional batteries. This study reports, for the first time, the capacitive performance of a bimetallic FeNi metal-organic framework (MOF) combined with multi-walled carbon nanotubes (MWCNTs) on a carbon felt electrode. The composite was synthesized via a hydrothermal route and applied through a drop-casting method. Electrochemical performance was evaluated using cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge–discharge techniques. The resulting electrode demonstrated a specific capacitance of about 180 F/g over a wide current density range, nearly 100% coulombic efficiency, a power density up to 3600 W/kg, and an energy density of about 91 Wh/kg. Moreover, it retained 90% of its capacity after 700 charge–discharge cycles, underscoring its stability. These findings highlight the FeNi MOF-MWCNT composite as a promising candidate for high-performance supercapacitor electrodes.

全球人口的增长和能源资源的迅速枯竭加剧了对可再生能源和先进储能解决方案的需求。超级电容器以其高功率密度、长循环寿命和快速充电能力,正在成为传统电池的一个有前途的替代品。本研究首次报道了双金属FeNi金属有机骨架(MOF)与多壁碳纳米管(MWCNTs)在碳毡电极上的电容性能。采用水热法合成了该复合材料,并采用滴铸法制备。利用循环伏安法、电化学阻抗谱和恒流充放电技术对电化学性能进行了评价。结果表明,该电极在宽电流密度范围内的比电容约为180 F/g,库仑效率接近100%,功率密度高达3600 W/kg,能量密度约为91 Wh/kg。此外,在700次充放电循环后,它的容量保持了90%,强调了它的稳定性。这些发现突出了FeNi MOF-MWCNT复合材料作为高性能超级电容器电极的有前途的候选者。
{"title":"Investigation of the Capacitive Properties of Bimetallic Iron–Nickel Organic Framework and Carbon Nanotube Composite on Carbon Felt Electrode","authors":"Yudum Tepeli Büyüksünetçi","doi":"10.1002/est2.70298","DOIUrl":"https://doi.org/10.1002/est2.70298","url":null,"abstract":"<div>\u0000 \u0000 <p>The increasing global population and rapid depletion of energy resources have intensified the demand for renewable energy and advanced energy storage solutions. Supercapacitors, with their high power density, long cycle life, and fast charging capability, are emerging as a promising alternative to conventional batteries. This study reports, for the first time, the capacitive performance of a bimetallic FeNi metal-organic framework (MOF) combined with multi-walled carbon nanotubes (MWCNTs) on a carbon felt electrode. The composite was synthesized via a hydrothermal route and applied through a drop-casting method. Electrochemical performance was evaluated using cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge–discharge techniques. The resulting electrode demonstrated a specific capacitance of about 180 F/g over a wide current density range, nearly 100% coulombic efficiency, a power density up to 3600 W/kg, and an energy density of about 91 Wh/kg. Moreover, it retained 90% of its capacity after 700 charge–discharge cycles, underscoring its stability. These findings highlight the FeNi MOF-MWCNT composite as a promising candidate for high-performance supercapacitor electrodes.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145522005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid Energy Storage System in Load Frequency Control Using Slime Mould Algorithm Under Deregulated Market 市场放松管制下基于黏菌算法的负荷变频混合储能系统
Pub Date : 2025-11-14 DOI: 10.1002/est2.70287
F. Lalhmangaihzuala, Subir Datta, Samuel Lalngaihawma, Hassan Abdurrahman Shuaibu, Taha Selim Ustun

In deregulated power systems, maintaining stable load frequency control (LFC) is increasingly challenging due to the integration of diverse energy sources and the unpredictable nature of demand and generation. Traditional control strategies often struggle to provide robust performance under these dynamic conditions, especially when contract violations occur. Additionally, ensuring frequency stability across multi-area grids with mixed energy profiles especially integration of hybrid energy storage systems, requires advanced and adaptive control mechanisms. This paper proposes a novel application of the Slime Mold Algorithm (SMA) to optimize a novel TIIDN-P controller under a deregulated environment. This paper also proposes a novel three-area hybrid power system. Each area comprises a thermal power plant integrated with a renewable energy source and a dedicated energy storage system (ESS): Area 1 includes a wind turbine, Area 2 features geothermal energy, and Area 3 incorporates biogas. The proposed system is chosen since it has not yet been investigated and those energy sources are easily available in India. By leveraging the adaptive search capabilities of SMA, the proposed TIIDN-P control strategy achieves significantly improved frequency regulation performance compared to other controllers. In comparison to PSO (Particle Swarm Optimization), FA (Firefly Algorithm), GWO (Grey Wolf Optimizer) and MBA (Mine Blast Algorithm), the proposed algorithm reduced settling time significantly up to 40% for different areas' frequency. Simulation results confirm that TIIDN-P controllers offer superior dynamic response, reduced overshoot, and enhanced robustness under varying system conditions. The integration of hybrid ESS configurations not only stabilizes system frequency but also effectively mitigates the impact of uncontracted power fluctuations. Sensitivity analysis further validates the resilience of the proposed approach. The sensitivity analysis proved that the proposed system as well as the controller, is robust enough in various cases. The stability analysis using eigenvalue analysis revealed that the proposed system is stable in various conditions. Moreover, this paper presents an intensive comparison of various types of Energy Storage Systems and their hybrid systems to find out the best ESS and the best hybrid system which is the first-ever of its kind. An investigation reveals that RFBESS and FWESS hybrids are the best option from the case study.

在放松管制的电力系统中,由于多种能源的整合以及需求和发电的不可预测性,维持稳定负荷频率控制(LFC)越来越具有挑战性。传统的控制策略往往难以在这些动态条件下提供稳健的性能,尤其是在发生违反合同的情况下。此外,确保混合能源分布的多区域电网的频率稳定性,特别是混合储能系统的集成,需要先进的自适应控制机制。本文提出了一种新的应用黏菌算法(SMA)来优化一种放松管制环境下的新型TIIDN-P控制器。本文还提出了一种新型的三区混合动力系统。每个区域包括一个集成了可再生能源和专用储能系统(ESS)的火力发电厂:1区包括风力涡轮机,2区以地热能为特色,3区包括沼气。之所以选择这个拟议的系统,是因为它还没有经过调查,而这些能源在印度很容易获得。通过利用SMA的自适应搜索能力,与其他控制器相比,所提出的TIIDN-P控制策略显著提高了频率调节性能。与PSO (Particle Swarm Optimization)、FA (Firefly Algorithm)、GWO (Grey Wolf Optimizer)和MBA (Mine Blast Algorithm)算法相比,该算法在不同区域频率下的沉降时间可显著缩短40%。仿真结果证实,在不同的系统条件下,TIIDN-P控制器提供了更好的动态响应,减少了超调量,增强了鲁棒性。混合ESS配置的集成不仅可以稳定系统频率,还可以有效减轻非收缩功率波动的影响。敏感性分析进一步验证了该方法的弹性。灵敏度分析证明了所提出的系统和控制器在各种情况下都具有足够的鲁棒性。利用特征值分析进行稳定性分析,表明系统在各种条件下都是稳定的。此外,本文还对各种类型的储能系统及其混合系统进行了深入的比较,以找出最佳ESS和最佳混合系统,这是同类系统中首次出现的。一项调查显示,RFBESS和FWESS混合是案例研究的最佳选择。
{"title":"Hybrid Energy Storage System in Load Frequency Control Using Slime Mould Algorithm Under Deregulated Market","authors":"F. Lalhmangaihzuala,&nbsp;Subir Datta,&nbsp;Samuel Lalngaihawma,&nbsp;Hassan Abdurrahman Shuaibu,&nbsp;Taha Selim Ustun","doi":"10.1002/est2.70287","DOIUrl":"https://doi.org/10.1002/est2.70287","url":null,"abstract":"<div>\u0000 \u0000 <p>In deregulated power systems, maintaining stable load frequency control (LFC) is increasingly challenging due to the integration of diverse energy sources and the unpredictable nature of demand and generation. Traditional control strategies often struggle to provide robust performance under these dynamic conditions, especially when contract violations occur. Additionally, ensuring frequency stability across multi-area grids with mixed energy profiles especially integration of hybrid energy storage systems, requires advanced and adaptive control mechanisms. This paper proposes a novel application of the Slime Mold Algorithm (SMA) to optimize a novel TIIDN-P controller under a deregulated environment. This paper also proposes a novel three-area hybrid power system. Each area comprises a thermal power plant integrated with a renewable energy source and a dedicated energy storage system (ESS): Area 1 includes a wind turbine, Area 2 features geothermal energy, and Area 3 incorporates biogas. The proposed system is chosen since it has not yet been investigated and those energy sources are easily available in India. By leveraging the adaptive search capabilities of SMA, the proposed TIIDN-P control strategy achieves significantly improved frequency regulation performance compared to other controllers. In comparison to PSO (Particle Swarm Optimization), FA (Firefly Algorithm), GWO (Grey Wolf Optimizer) and MBA (Mine Blast Algorithm), the proposed algorithm reduced settling time significantly up to 40% for different areas' frequency. Simulation results confirm that TIIDN-P controllers offer superior dynamic response, reduced overshoot, and enhanced robustness under varying system conditions. The integration of hybrid ESS configurations not only stabilizes system frequency but also effectively mitigates the impact of uncontracted power fluctuations. Sensitivity analysis further validates the resilience of the proposed approach. The sensitivity analysis proved that the proposed system as well as the controller, is robust enough in various cases. The stability analysis using eigenvalue analysis revealed that the proposed system is stable in various conditions. Moreover, this paper presents an intensive comparison of various types of Energy Storage Systems and their hybrid systems to find out the best ESS and the best hybrid system which is the first-ever of its kind. An investigation reveals that RFBESS and FWESS hybrids are the best option from the case study.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145522063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Review on Conductive Composite for Heat Exchange in Electric Vehicle Battery Packs 电动汽车电池包热交换用导电复合材料研究进展
Pub Date : 2025-11-13 DOI: 10.1002/est2.70291
Nakeeran Elangkeeran, Arputham Arul Jeya Kumar

The most prominent transition has all to do with the electric vehicles within the evolving technological environment facing rapid advancement today. Effective thermal performance of an electric vehicle battery pack is of utmost importance, in terms of both safety and performance, longevity. In this review a context of conductive composite materials in battery heat exchange systems (BHES) is explored, thus giving indication into the importance of architecture in optimizing heat transfer within EV battery modules. The ultimate aim is to present up-to-date developments in material science that will improve the thermal performance of battery thermal management systems (BTMS), achieve uniform heat distribution, and increase battery efficiency. In this regard, future aspects' emphasis is put on porous foam composites incorporating phase change materials (PCM), which are highly promising in improving thermal regulation under variable operational conditions. This study is something different from previous reviews because this article particularly highlights conductive composite phase change materials in thermal regulation for EV battery packs and recent advances. The review will also give a comparative account of conventional and advanced cooling methods, the challenges of which mainly lie in material integration and costs and will point toward possible futures of research and development in thermal management strategies for EV batteries.

最突出的转变与电动汽车在不断发展的技术环境中面临的快速发展有关。电动汽车电池组的有效热性能对于安全性、性能和寿命都至关重要。本文探讨了电池热交换系统(BHES)中导电复合材料的背景,从而表明了结构在优化电动汽车电池模块内传热中的重要性。最终目的是展示材料科学的最新发展,以改善电池热管理系统(BTMS)的热性能,实现均匀的热量分配,并提高电池效率。在这方面,未来的重点将放在包含相变材料(PCM)的多孔泡沫复合材料上,这在改善可变操作条件下的热调节方面非常有前途。本研究与以往的综述有所不同,因为本文特别强调了导电复合相变材料在电动汽车电池组热调节中的应用及其最新进展。该综述还将对传统和先进的冷却方法进行比较,主要挑战在于材料集成和成本,并将指出电动汽车电池热管理策略研究和开发的可能未来。
{"title":"A Review on Conductive Composite for Heat Exchange in Electric Vehicle Battery Packs","authors":"Nakeeran Elangkeeran,&nbsp;Arputham Arul Jeya Kumar","doi":"10.1002/est2.70291","DOIUrl":"https://doi.org/10.1002/est2.70291","url":null,"abstract":"<div>\u0000 \u0000 <p>The most prominent transition has all to do with the electric vehicles within the evolving technological environment facing rapid advancement today. Effective thermal performance of an electric vehicle battery pack is of utmost importance, in terms of both safety and performance, longevity. In this review a context of conductive composite materials in battery heat exchange systems (BHES) is explored, thus giving indication into the importance of architecture in optimizing heat transfer within EV battery modules. The ultimate aim is to present up-to-date developments in material science that will improve the thermal performance of battery thermal management systems (BTMS), achieve uniform heat distribution, and increase battery efficiency. In this regard, future aspects' emphasis is put on porous foam composites incorporating phase change materials (PCM), which are highly promising in improving thermal regulation under variable operational conditions. This study is something different from previous reviews because this article particularly highlights conductive composite phase change materials in thermal regulation for EV battery packs and recent advances. The review will also give a comparative account of conventional and advanced cooling methods, the challenges of which mainly lie in material integration and costs and will point toward possible futures of research and development in thermal management strategies for EV batteries.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145521753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Novel Fast-Charging Framework Based on Model Predictive Control 基于模型预测控制的新型快速充电框架
Pub Date : 2025-11-12 DOI: 10.1002/est2.70293
Haijun Yu, Aina Tian, Bingrui Qu, Tiezhou Wu, Qingzheng Cao, Jiuchun Jiang

Charging strategy optimization for lithium-ion batteries is crucial to improve the efficiency of new energy devices. In this study, three conventional methods are compared: constant-current constant-voltage (CCCV) charging is the most efficient but slowest, pulse charging (PC) is the fastest but least efficient, and multistage constant-current (MSCC) is a compromise between speed and efficiency. To this end, we propose a dynamic optimal charging strategy based on model predictive control (MPC) that balances rapid-charging speed with battery safety. By integrating a low-order electrochemical–thermal–aging coupled model with real-time state estimation provided by an extended Kalman filter (EKF), a rolling-horizon framework is established to track both state-of-charge (SOC) and temperature reference trajectories. Experiments show that EKF has stronger initial error robustness (maximum deviation < 2%) than unscented Kalman filter (UKF) and unscented Kalman Bucy filter (UKBF), which provides reliable feedback for MPC. The new strategy achieves an optimal balance between charging efficiency and safety by dynamically adjusting the charging profile and significantly improves the charging speed under closed-loop control compared to the CCCV method, while controlling the temperature rise within 5°C.

锂离子电池充电策略优化是提高新能源设备效率的关键。本文比较了恒流恒压(CCCV)充电效率最高但最慢,脉冲充电速度最快但效率最低,多级恒流(MSCC)充电是一种速度与效率的折衷方案。为此,我们提出了一种基于模型预测控制(MPC)的动态最优充电策略,以平衡快速充电速度和电池安全性。通过将低阶电化学-热老化耦合模型与扩展卡尔曼滤波(EKF)提供的实时状态估计相结合,建立了滚动水平框架来跟踪荷电状态(SOC)和温度参考轨迹。实验表明,EKF比unscented Kalman滤波(UKF)和unscented Kalman Bucy滤波(UKBF)具有更强的初始误差鲁棒性(最大偏差为2%),为MPC提供了可靠的反馈。该策略通过动态调整充电轮廓,实现了充电效率和安全性的最佳平衡,在闭环控制下,与CCCV方法相比,充电速度显著提高,同时将温升控制在5℃以内。
{"title":"A Novel Fast-Charging Framework Based on Model Predictive Control","authors":"Haijun Yu,&nbsp;Aina Tian,&nbsp;Bingrui Qu,&nbsp;Tiezhou Wu,&nbsp;Qingzheng Cao,&nbsp;Jiuchun Jiang","doi":"10.1002/est2.70293","DOIUrl":"https://doi.org/10.1002/est2.70293","url":null,"abstract":"<div>\u0000 \u0000 <p>Charging strategy optimization for lithium-ion batteries is crucial to improve the efficiency of new energy devices. In this study, three conventional methods are compared: constant-current constant-voltage (CCCV) charging is the most efficient but slowest, pulse charging (PC) is the fastest but least efficient, and multistage constant-current (MSCC) is a compromise between speed and efficiency. To this end, we propose a dynamic optimal charging strategy based on model predictive control (MPC) that balances rapid-charging speed with battery safety. By integrating a low-order electrochemical–thermal–aging coupled model with real-time state estimation provided by an extended Kalman filter (EKF), a rolling-horizon framework is established to track both state-of-charge (SOC) and temperature reference trajectories. Experiments show that EKF has stronger initial error robustness (maximum deviation &lt; 2%) than unscented Kalman filter (UKF) and unscented Kalman Bucy filter (UKBF), which provides reliable feedback for MPC. The new strategy achieves an optimal balance between charging efficiency and safety by dynamically adjusting the charging profile and significantly improves the charging speed under closed-loop control compared to the CCCV method, while controlling the temperature rise within 5°C.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145521815","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Energy Storage
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1