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Performance of a Simplified Computational Fluid Dynamics Model for a Phase Change Material–Water Finned Heat Exchanger Under Different Orientations 相变材料-水翅片热交换器的简化计算流体动力学模型在不同方向上的性能
Pub Date : 2024-08-28 DOI: 10.1002/est2.70021
Francisco Javier González Gallero, Gabriel González Siles, Ismael Rodríguez Maestre, Juan Luis Foncubierta Blázquez, Luis Pérez-Lombard

The prevalent numerical models for simulating axially finned heat exchangers with phase change materials (PCMs) and water as the heat transfer fluid rely on computational fluid dynamics (CFD) techniques, with a primary focus on phase change modeling. However, the computational demands of these models, incorporating phase change effects and resolving PCM movement in the liquid state, are substantial. From experiments suggesting that conduction in the solidified PCM around the finned tube dominates heat transfer during the heat discharge process, this article introduces a simplified CFD-based model in which convective flow of the PCM is neglected. The model is experimentally validated using a 1-m-long axially finned heat exchanger prototype with four fins, recording temperatures under different water flow rates and orientations (horizontal and vertical). Results show that the proposed model predicts outlet water temperature satisfactorily, with absolute errors below 1.0°C and 2.2°C for the horizontal and vertical orientations, respectively. Additionally, the model can capture the temperature trend inside the PCM for the horizontal orientation.

模拟使用相变材料 (PCM) 和水作为传热流体的轴向翅片式热交换器的主流数值模型依赖于计算流体动力学 (CFD) 技术,主要侧重于相变建模。然而,这些模型的计算要求很高,既要考虑相变效应,又要解决 PCM 在液态下的运动问题。实验表明,在热量排放过程中,翅片管周围凝固 PCM 的传导主导了热量传递,因此本文介绍了一种基于 CFD 的简化模型,其中忽略了 PCM 的对流。该模型使用一个 1 米长、带四个翅片的轴向翅片换热器原型进行了实验验证,记录了不同水流速和方向(水平和垂直)下的温度。结果表明,所提出的模型对出口水温的预测令人满意,水平和垂直方向的绝对误差分别低于 1.0°C 和 2.2°C。此外,在水平方向上,该模型还能捕捉到 PCM 内部的温度变化趋势。
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引用次数: 0
Increasing the Efficacy of an Air Conditioning Unit by Utilizing Phase Change Material With Cylindrical Configuration 利用圆柱形结构的相变材料提高空调设备的效率
Pub Date : 2024-08-27 DOI: 10.1002/est2.70025
Arun Kumar Sao, Arun Arora, Mukesh Kumar Sahu

The goal of the current study is to determine how the SST kω$$ k-omega $$ and the standard kɛ$$ k-varepsilon $$ turbulence models prediction on PCM with cylindrical configuration affect AC performance and PCM discharging when coupled with an AC unit. For simulation, 308.15 K and 318.15 K, the inflow air temperature has been considered with a fixed 33.6 L/s intake air flow rate. The low outside temperature charges the PCMs during the night. During the daytime, heated ambient air is cooled by the PCM heat exchanger before passing over the unit condenser. The present outcomes show that using the standard kε$$ k-varepsilon $$ model, the cylindrical PCM has the lowest time of complete melting. The temperature contours demonstrate that turbulence occurs, particularly at higher temperatures, in the PCM melting zone within the solid region. This implies that there is increased convection in this area. The maximum improved percentage in COP increases as the rising input air temperature for both turbulence models increases. The average power saving of AC at 308.15 K of an input air temperature for 83.33 min is predicted by both the standard kɛ$$ k-varepsilon $$ and the SST kω$$ k-omega $$ to be 14.0905 W and 14.1089 W, respectively.

当前研究的目标是确定 SST k - ω $$ k-omega $$ 和标准 k - ɛ $$ k-varepsilon $$ 湍流模型对圆柱形结构 PCM 的预测如何影响空调性能以及与空调设备耦合时 PCM 的排出。在模拟时,考虑了 308.15 K 和 318.15 K 的进气温度和固定的 33.6 L/s 进气流速。较低的室外温度会在夜间对 PCM 进行充电。在白天,加热的环境空气在通过机组冷凝器之前被 PCM 热交换器冷却。本研究结果表明,使用标准 k - ε $$ k-varepsilon $$ 模型,圆柱形 PCM 的完全熔化时间最短。温度等值线表明,在固体区域内的 PCM 熔化区出现了湍流,尤其是在较高温度下。这意味着该区域的对流增加。随着两种湍流模型输入空气温度的升高,COP 的最大改善百分比也在增加。根据标准 k - ɛ $$ k-varepsilon $$ 和 SST k - ω $$ k-omega $$ 预测,在输入空气温度为 308.15 K 时,交流电的平均节电时间为 83.33 分钟,分别为 14.0905 W 和 14.1089 W。
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引用次数: 0
Lignocellulosic Biomass-Derived Graphene: Fabrication, Challenges and Its Potential for Hydrogen Storage Application 木质纤维素生物质衍生石墨烯:制造、挑战及其在储氢应用中的潜力
Pub Date : 2024-08-27 DOI: 10.1002/est2.70019
Anjali Singh, Aman John Tudu, Basant Lal, Shafiul Haque, Bhawna Verma

This review explores the utilization of lignocellulosic biomass (LCB) waste in the fabrication of graphene and its applications in hydrogen storage. Several LCB wastes, such as rice straws, coconut shells, wheat straws, and sugarcane bagasse, along with the methodology used and the characteristics of the final graphene, have been discussed in detail. It was found that the coconut shells produced crumpled multilayered graphene, rice husks (RHs) provided a mix of graphene layers and amorphous carbon, wheat straw yielded few-layered graphene, and sugarcane bagasse contributed to different graphene-like materials. This review has also focused on the various synthesis processes, such as carbonization, hydrothermal carbonization (HTC), chemical activation, pyrolysis, chemical vapor deposition (CVD), and Hummers' method for graphene fabrication from LCB waste, along with their advantages and disadvantages, for a better understanding. Various results have been discussed exploring the use of lignocellulosic biomass-derived graphene (LCB-G) and its various modified forms for hydrogen storage applications. Various challenges in graphene fabrication from LCB, such as low yield, product quality, scalability, use of expensive synthesis methods, and toxic chemicals, along with some potential solutions, have been mentioned. Finally, the review concludes with insights into the future of LCB-G and its role in hydrogen storage while identifying some gaps, such as scalability and product quality, for further research and development.

本综述探讨了利用木质纤维素生物质(LCB)废物制造石墨烯及其在储氢中的应用。文中详细讨论了几种木质纤维生物质废物,如稻草、椰子壳、小麦秸秆和甘蔗渣,以及所使用的方法和最终石墨烯的特性。研究发现,椰子壳产生了皱缩的多层石墨烯,稻壳(RHs)提供了石墨烯层和无定形碳的混合物,小麦秸秆产生了少层石墨烯,甘蔗渣则产生了不同的石墨烯类材料。本综述还重点介绍了各种合成工艺,如碳化、水热碳化 (HTC)、化学活化、热解、化学气相沉积 (CVD),以及从 LCB 废物中制造石墨烯的 Hummers 方法及其优缺点,以便更好地理解这些工艺。在探索使用木质纤维素生物质衍生石墨烯(LCB-G)及其各种改性形式进行储氢应用方面,已经讨论了各种成果。还提到了从 LCB 制备石墨烯过程中面临的各种挑战,如产量低、产品质量、可扩展性、使用昂贵的合成方法和有毒化学品,以及一些潜在的解决方案。最后,综述对 LCB-G 的未来及其在储氢中的作用进行了总结,同时指出了一些差距,例如可扩展性和产品质量,以供进一步研究和开发。
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引用次数: 0
Hydrogen Storage Using Platinum-Supported Ceria Dispersed on Activated Carbon 利用分散在活性炭上的铂支撑铈储存氢气
Pub Date : 2024-08-26 DOI: 10.1002/est2.70032
Anass Wahby, Zinab Abdelouahab-Reddam, Rachad El Mail, Joaquín Silvestre-Albero, Antonio Sepúlveda-Escribano

In the current work, carbon materials were used in the hydrogen adsorption process, specifically as carbons doped with platinum dispersed on ceria. The textural characterization results of the prepared samples and the starting carbon showed the presence of both micro- and mesopores. On the other hand, it has been observed that the specific areas were inversely proportional to the CeO2 loading. In addition, the amount of adsorbed hydrogen increased after doping the carbon with platinum and, even more, when the carbon was doped with Pt dispersed on ceria (2.2 mg/g at 25°C and 30 bar). However, there was a ceria optimum from which the adsorption capacity decreased (10% wt). The results of temperature-programmed desorption (TPD) of hydrogen indicated a high affinity between Pt and H2 that enhanced H2 adsorption process by establishing chemical bonds between the metal particles and H2. Precisely, the presence of metallic Pt particles dispersed on ceria considerably promotes the spillover process of hydrogen on carbon. This can be confirmed by hydrogen adsorption–desorption isotherms, that showed that complete desorption of chemisorbed hydrogen required an increase of temperature.

在目前的工作中,碳材料被用于氢吸附过程,特别是在铈上掺杂铂的碳。制备的样品和起始碳的纹理表征结果表明存在微孔和介孔。另一方面,还观察到比面积与 CeO2 的负载量成反比。此外,在碳中掺入铂后,吸附氢的量会增加,而在碳中掺入分散在铈上的铂(2.2 毫克/克,25°C 和 30 巴)后,吸附氢的量会增加得更多。不过,铈的吸附能力有一个最佳值(10% wt),从该值开始吸附能力下降。氢气的温度编程解吸(TPD)结果表明,铂和 H2 之间具有很高的亲和力,通过在金属颗粒和 H2 之间建立化学键,增强了对 H2 的吸附过程。确切地说,分散在铈上的金属铂粒子的存在大大促进了碳上氢的溢出过程。这一点可以通过氢吸附-解吸等温线得到证实,该等温线表明化学吸附氢的完全解吸需要温度的升高。
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引用次数: 0
Enhancing Power Production: A Novel Hydrogen-Based Scheme With Comprehensive Analysis and AI-Optimized Criteria 提高发电量:采用综合分析和人工智能优化标准的新型氢基方案
Pub Date : 2024-08-22 DOI: 10.1002/est2.70013
Vahid Mohammadzadeh, Zoheir Saboohi, Fathollah Ommi, Ehsan Gholamian

Despite being a cutting-edge technology, the proton exchange membrane fuel cell (PEMFC) generates a lot of heat as it works, which makes it wasteful with energy. In order to enhance energy efficiency via waste heat recovery, we provide and analyze a novel integrated energy system that utilizes PEMFC and ORC technology. There are a lot of ways to put the waste heat from fuel cells (FCs) to good use, but the most efficient one is the organic Rankine cycle (ORC) with the right working fluid. This research aims to find the optimal way to use the waste heat of the FC by testing several working fluids. The optimal solution is derived using a genetic algorithm by monitoring the objective functions that characterize the system's overall performance as they vary across different system parameters. The results show that the proposed efficient integration achieves high energy and exergy efficiency levels and achieves rates of total cost and environmental impact that are within acceptable limits. Since the fuel usage element's content significantly affects the system indicators in several ways, the results also demonstrate that it is quite relevant. Since the exergo-environmental metric and the exergy efficiency meter are always moving in different directions, choosing a design condition that meets several requirements is crucial. According to the results, fuel cells had the highest irreversibility rate at 12.2, making them the most energy-conserving piece of machinery.

尽管质子交换膜燃料电池(PEMFC)是一项尖端技术,但它在工作时会产生大量热量,从而造成能源浪费。为了通过余热回收提高能源效率,我们提供并分析了一种利用 PEMFC 和 ORC 技术的新型集成能源系统。将燃料电池(FC)产生的废热加以充分利用的方法有很多,但最有效的方法是采用合适工作流体的有机朗肯循环(ORC)。这项研究旨在通过测试几种工作流体,找到利用燃料电池余热的最佳方法。通过监测表征系统整体性能的目标函数在不同系统参数下的变化情况,利用遗传算法得出最佳解决方案。结果表明,所建议的高效集成实现了较高的能效和放能效水平,并将总成本和环境影响控制在可接受的范围内。由于燃料使用要素的内容会在多个方面对系统指标产生重大影响,因此结果也证明了它的相关性。由于能量环境指标和能量效率指标总是朝着不同的方向发展,因此选择一个满足多项要求的设计条件至关重要。结果显示,燃料电池的不可逆率最高,为 12.2,是最节能的设备。
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引用次数: 0
High-Performance Single-Phase Bi-Directional Novel On-Board Charger for Electric Vehicles 用于电动汽车的高性能单相双向新型车载充电器
Pub Date : 2024-08-21 DOI: 10.1002/est2.70014
Md Inayat Ali, Rajib Mandal, Amitesh Kumar

The design and development of a 550 W non-isolated single-phase two-stage level-1 bidirectional on-board battery charger (OBC) for electric vehicles (EVs) have been discussed in this article, which is also capable of supplying the utility grid's reactive power needs. There are two stages in this topology. The first stage consists of a full bridge bidirectional AC to DC converter, and the second stage consists of a half-bridge bidirectional DC to DC converter with enhanced vehicle-to-vehicle (V2V) capabilities for emergency roadside charging assistance scenarios. In an emergency, if there is not a charging station nearby and the battery is dead, EVs can use this feature to charge from other EVs. It can also work like a regular vehicle-to-grid (V2G) or grid-to-vehicle (G2V) system. The suggested charging topology has a maximum efficiency of 99.09%, a power factor of 0.99, and a total harmonic distortion (THD) of 6.31%. MATLAB/Simulink is used to develop and simulate the suggested EV charger, and simulation results are compared with the other on-board chargers in the literature.

本文讨论了用于电动汽车(EV)的 550 W 非隔离单相两级一级双向车载电池充电器(OBC)的设计和开发,该充电器还能满足公用电网的无功功率需求。该拓扑结构分为两个阶段。第一阶段由全桥双向交流到直流转换器组成,第二阶段由半桥双向直流到直流转换器组成,具有增强的车对车(V2V)功能,适用于紧急路边充电援助场景。在紧急情况下,如果附近没有充电站,而电池又没电了,电动汽车可以利用这一功能从其他电动汽车上充电。它也可以像普通的车对网(V2G)或网对车(G2V)系统一样工作。建议的充电拓扑结构的最高效率为 99.09%,功率因数为 0.99,总谐波失真 (THD) 为 6.31%。我们使用 MATLAB/Simulink 对建议的电动汽车充电器进行了开发和仿真,并将仿真结果与文献中的其他车载充电器进行了比较。
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引用次数: 0
Electric Vehicle Smart-Charging Control for Parking Lots Based on Individual State of Charge Priority 基于个人充电状态优先级的停车场电动汽车智能充电控制
Pub Date : 2024-08-21 DOI: 10.1002/est2.70017
Frederico Haasis, Oscar Solano, Daniel Dias, Bruno Borba

The integration of electric vehicles (EVs) into the power grid could pose challenges to power quality (PQ) depending on quantity of EVs and when they are connected. To mitigate these impacts without using drastic measures, such as disconnecting EVs, this study investigates centralized control strategies within parking facilities that prioritize EV charging based on individual State of Charge (SoC) levels. The study utilizes the IEEE 34 Bus system and conducts 3888 simulations for different scenarios to assess the impact of the quantity and placement of EVs in parking lots. The study applies the Monte Carlo method to compare the performance of different proposed controls: (i) limiting the charging current to a fixed level and (ii) varying the current based on the voltage droop step. Furthermore, Power Hardware-in-the-Loop (PHIL) simulations were carried out to validate the hierarchical control using the droop step control, demonstrating the best average performance in the previous scenarios. The findings indicated that the control responded within the expected timeframe and successfully addressed voltage sag issues, maintaining PQ in the distribution system in most cases, with its performance being influenced by the placement of parking lots in the network. Additionally, it was confirmed through quartiles that the classification based on SoC leads to a more balanced charging time for different SoC levels.

将电动汽车(EV)并入电网可能会对电能质量(PQ)带来挑战,这取决于电动汽车的数量和连接时间。为了在不采取断开电动汽车连接等严厉措施的情况下减轻这些影响,本研究调查了停车设施内的集中控制策略,该策略可根据单个充电状态 (SoC) 级别对电动汽车充电进行优先排序。该研究利用 IEEE 34 总线系统,针对不同场景进行了 3888 次模拟,以评估停车场中电动汽车数量和位置的影响。研究采用蒙特卡洛法比较了不同控制建议的性能:(i) 将充电电流限制在固定水平;(ii) 根据电压下降阶跃改变电流。此外,还进行了电源硬件在环(PHIL)仿真,以验证使用下垂阶跃控制的分层控制,结果表明在前几种情况下平均性能最佳。结果表明,该控制在预期时间内做出响应,成功解决了电压下陷问题,在大多数情况下保持了配电系统的 PQ,其性能受到网络中停车场位置的影响。此外,通过四分法证实,基于 SoC 的分类使不同 SoC 水平的充电时间更加均衡。
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引用次数: 0
Investigating the Dual Synergistic Amalgamation of CeO2@WO3/GO Electrodes for Supercapacitor Application 研究超级电容器应用中 CeO2@WO3/GO 电极的双重协同混合物
Pub Date : 2024-08-20 DOI: 10.1002/est2.70020
Raphael M. Obodo, Hope E. Nsude, Chimezie U. Eze, Miletus O. Duru, Imosobomeh L. Ikhioya, Joseph N. Anosike, Joseph N. Aniezi, Ekwevugbe Omugbe, Chinonso Mbamara, Ugochukwu C. Elejere, Muhammad Usman, Ishaq Ahmad, M. Maaza

Scientists and researchers are investigating new energy conversion and storage devices continuously because of the current global hike in energy crisis. In this study, we utilized graphene oxide (GO) and composites of transition metallic oxides (CeO2@WO3) to fabricate electrodes intended for use in supercapacitor electrodes. These electrodes' morphology demonstrates a uniform distribution of sphere and platelet nanoparticles. The XRD measurements for these manufactured electrodes showed a noticeable crystalline character. These electrodes have outstanding electrochemical performance due to their relatively low bandgap energies. The electrochemical tests demonstrated the exceptional charge storage capabilities of the different electrodes, suggesting that CeO2/GO, WO3/GO, and CeO2@WO3/GO electrodes could be useful electrodes for supercapacitor applications. Numerous electrochemical findings made it abundantly evident that the creation of bimetallic CeO2@WO3/GO composites enhanced the supercapacitive performance and cycle stability of the electrodes.

由于当前全球能源危机加剧,科学家和研究人员正在不断研究新的能源转换和存储设备。在这项研究中,我们利用氧化石墨烯(GO)和过渡金属氧化物的复合材料(CeO2@WO3)制造出了用于超级电容器电极的电极。这些电极的形态显示出球状和板状纳米颗粒的均匀分布。这些电极的 XRD 测量显示出明显的结晶特征。这些电极的带隙能相对较低,因此具有出色的电化学性能。电化学测试表明,不同电极都具有出色的电荷存储能力,这表明 CeO2/GO、WO3/GO 和 CeO2@WO3/GO 电极可作为超级电容器应用的有用电极。大量电化学研究结果表明,双金属 CeO2@WO3/GO 复合材料的产生增强了电极的超级电容器性能和循环稳定性。
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引用次数: 0
Investigation of an eco-friendly polyacrylic acid binder system on LiFePO4 cathode electrode processing to enhance the performance of coin-cell and pouch-cell graphite||LiFePO4 batteries 研究环保型聚丙烯酸粘合剂系统对磷酸铁锂电池正极电极的处理,以提高纽扣电池和袋式电池石墨||磷酸铁锂电池的性能
Pub Date : 2024-08-06 DOI: 10.1002/est2.70006
Tram Tran Bich Vo, Minh Thu Nguyen, Thanh Liem Pham, Trung Thien Nguyen, Van Gia Tran, Van Man Tran, Phung My Loan Le

This study investigates the influence of two types of binders (aqueous and nonaqueous) on the LiFePO4 (LFP) electrode processing and its electrochemical properties. Specifically, polyvinylidene fluoride (PVDF) and polyacrylic acid (PAA) were dissolved in NMP (N-methyl-2-pyrrolidone) or the aqueous solvent (H2O) at varying mass ratios of 5%, 10%, and 15%. Binder durability and inertness were assessed by immersing prepared LFP electrodes in an electrolyte comprising 1.0 M LiPF6 in EC:DEC:DMC (1:1:1 in vol%). Notably, PVDF/NMP 10% and PAA/H2O 10%-based electrodes displayed good durability without peeling. Electrochemical characteristics were evaluated through cycling voltammetry and galvanostatic cycling with potential limitation. The PAA/H2O 10%-based-LFP electrode exhibited a specific capacity of ~148.9 mAh g−1 with a Coulombic efficiency (CE) of around 97.27%, surpassing PVDF/NMP 10%. The graphite||PAA/H2O 10%-based-LFP electrode in a full cell demonstrated higher capacity and superior retention after 30 cycles. In a pouch cell (6 cm × 4 cm), utilizing graphite||LFP with PAA/H2O 10%, a capacity of 25.5 mAh was achieved, maintaining 93% capacity with a CE of about 99% after 30 cycles at a rate of 0.1C.

本研究探讨了两种粘合剂(水性和非水性)对磷酸铁锂(LFP)电极加工及其电化学特性的影响。具体来说,聚偏二氟乙烯(PVDF)和聚丙烯酸(PAA)以 5%、10% 和 15%的不同质量比溶解在 NMP(N-甲基-2-吡咯烷酮)或水性溶剂(H2O)中。将制备好的 LFP 电极浸入由 1.0 M LiPF6 和 EC:DEC:DMC (体积比为 1:1:1)组成的电解液中,对粘合剂的耐久性和惰性进行了评估。值得注意的是,基于 PVDF/NMP 10% 和 PAA/H2O 10% 的电极显示出良好的耐久性,没有剥落。电化学特性通过循环伏安法和电位限制电位静态循环法进行了评估。基于 PAA/H2O 10% 的 LFP 电极的比容量约为 148.9 mAh g-1,库仑效率(CE)约为 97.27%,超过了 PVDF/NMP 10% 电极。在全电池中,基于石墨||PAA/H2O 10%的 LFP 电极在 30 次循环后显示出更高的容量和优异的保持能力。在一个小袋电池(6 cm × 4 cm)中,使用 PAA/H2O 10% 的石墨||LFP,实现了 25.5 mAh 的容量,在 0.1C 速率下循环 30 次后,容量保持率为 93%,CE 约为 99%。
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引用次数: 0
Development of Flexible High-Efficient Aluminum ion Supercapacitors With 2D Niobium MXene Electrode 利用二维铌 MXene 电极开发柔性高效铝离子超级电容器
Pub Date : 2024-08-06 DOI: 10.1002/est2.70012
Latha Malyala, Sampath Karingula, Thirupathi Bhookya, Gobi K Vengatajalabathy

A high-performance aluminum-ion supercapacitor is fabricated using 2D few-layered Nb2CTx MXene, as an active electrode material and Al2(SO4)3 electrolyte for efficient energy storage. Nb2CTx MXene has been synthesized from Nb2AlC MAX phase using HF. Nb2CTx MXene coated on carbon cloth (Nb@CC) displays a capacitance of 307 F g−1 with 90% coulombic efficiency. The specific capacitance of Nb@CC in Al2(SO4)3 electrolyte is exceptionally high compared to those (≤32.2 F g−1) in H2SO4, Na2SO4, and MgSO4 electrolytes. Both symmetric and asymmetric aluminum ion supercapacitors are fabricated with Nb@CC electrode. The Nb@CC//Nb@CC symmetric device exhibits a capacitance of 122 F g−1 with a high energy density (Ed) of 33.2 Wh kg−1 at 1.41 kW kg−1 power density (Pd). An asymmetric supercapacitor device (ASC), Nb@CC//CNT@CC, with carbon nanotube (CNT@CC) cathode delivers a maximum Ed of 24.7 Wh kg−1 at 3.41 kW kg−1 Pd and excellent stability with 90% capacitance retention after 4000 cycles. A remarkably high Pd of 34 kW kg−1 is maintained with 13.2 Wh kg−1 Ed, and the rate capability is 53% for a 10-fold increase in current density. These results offer the feasibility of efficient aqueous supercapacitors with Al-ion as guest species, presenting new possibilities for supercapacitors.

使用二维少层 Nb2CTx MXene 作为活性电极材料,并使用 Al2(SO4)3 电解质制造了一种高性能铝离子超级电容器,用于高效储能。Nb2CTx MXene 是用高频从 Nb2AlC MAX 相合成的。涂覆在碳布(Nb@CC)上的 Nb2CTx MXene 的电容为 307 F g-1,库仑效率为 90%。与在 H2SO4、Na2SO4 和 MgSO4 电解质中的比电容(≤32.2 F g-1)相比,Nb@CC 在 Al2(SO4)3 电解质中的比电容特别高。对称和不对称铝离子超级电容器都是用 Nb@CC 电极制造的。Nb@CC//Nb@CC 对称器件的电容为 122 F g-1,在 1.41 kW kg-1 功率密度(Pd)条件下,能量密度(Ed)高达 33.2 Wh kg-1。采用碳纳米管(CNT@CC)阴极的非对称超级电容器器件(ASC)--Nb@CC//CNT@CC--在 3.41 kW kg-1 Pd 条件下的最大 Ed 值为 24.7 Wh kg-1,且稳定性极佳,4000 次循环后电容保持率为 90%。在 13.2 Wh kg-1 Ed 的条件下,Pd 可保持在 34 kW kg-1 的极高水平,在电流密度增加 10 倍的情况下,速率能力提高了 53%。这些结果提供了以铝离子为客体的高效水性超级电容器的可行性,为超级电容器提供了新的可能性。
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引用次数: 0
期刊
Energy Storage
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