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Si3N4 as an Alternative of Silicon for the Anode Application in All-Solid-State Li-Ion Batteries Si3N4 作为硅的替代品在全固态锂离子电池中的阳极应用
Pub Date : 2024-08-05 DOI: 10.1002/est2.70010
Anil Kumar Sharma, Khushbu Sharma, Mukesh Kumar Gupta, Fangqin Guo, Takayuki Ichikawa, Ankur Jain, Shivani Agarwal

The intermittent nature of renewable energy generation can be tackled by integrating them with electrochemical energy storage, which can also close the gap between supply and demand effectively. It has recently been demonstrated that Si3N4-based negative electrodes are a promising option for lithium-ion batteries due to their large theoretical capacity and appropriate working potential with extremely low polarization. In the present work, Si3N4 was utilized as anode material in all-solid-state lithium-ion battery with lithium borohydride as a solid electrolyte and Li foil placed as a counter electrode. The electrochemical properties were investigated using galvanostatic charge/discharge profiling whereas the mechanism of lithiation delithiation was investigated in detail using x-ray diffraction (XRD). The highest capacity of the composite materials was obtained as 1700 mAhg−1 at 0.05 C current rate in the first cycle, which is reduced to 370 in 5 cycles. However, a stability in the capacity was observed in subsequent cycles and a retention of almost 88% could be achieved in 150 cycles. The interfacial resistance before and after the electrochemical cycling was observed as 326 Ω and 13 kΩ, respectively which is also supported by the microstructural investigations where the cracks are observed because of thermochemical reactions.

将可再生能源发电与电化学储能相结合,可以解决可再生能源发电的间歇性问题,还能有效缩小供需差距。最近的研究表明,基于 Si3N4 的负电极具有理论容量大、工作电位合适、极化极低的特点,是锂离子电池的理想选择。在本研究中,Si3N4 被用作全固态锂离子电池的负极材料,以硼氢化锂为固态电解质,锂箔为反电极。利用电静态充放电分析研究了其电化学特性,并利用 X 射线衍射(XRD)详细研究了锂化脱锂的机理。在 0.05 C 电流速率下,复合材料在第一个循环中获得的最高容量为 1700 mAhg-1,5 个循环后降至 370 mAhg-1。然而,在随后的循环中观察到了容量的稳定性,在 150 个循环中可达到近 88% 的容量保持率。电化学循环前后的界面电阻分别为 326 Ω 和 13 kΩ,这也得到了微观结构研究的支持,在微观结构研究中,由于热化学反应观察到了裂纹。
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引用次数: 0
Carbon-Based Cathode Design for Next-Generation Potassium-Sulfur Batteries: Status and Perspective 下一代钾硫电池的碳基阴极设计:现状与展望
Pub Date : 2024-08-05 DOI: 10.1002/est2.70011
Vikram Kishore Bharti, Tim Dawsey, Ram K. Gupta

The increasing concern for environmental pollution has fastened the development of energy storage devices. Among various devices, lithium-ion battery (LIB) technology has been leapfrogged owing to its stable performance for various applications ranging from electronic gadgets to electric vehicles (EVs). For ever-increasing number of EVs has increased the demand for batteries increasing the overall cost. An alternative energy storage device that can replace the dependence on lithium reserves can be another game changer in this area. Potassium-sulfur batteries (KSBs) have attracted enormous attention owing to the higher abundance of sulfur and potassium. In addition, sulfur bears the highest capacity as a cathodic material (nearly five times higher than the commercial LIBs) and when clubbed with potassium anode can deliver a theoretical energy density of 914 Wh/kg (significantly higher for EVs). However, KSB development is still in the nascent stage owing to the intrinsic challenges including insulating sulfur, volume variation, and shuttle effect of polysulfides. In addition, unstable potassium anode and its dendrite formation is another thorny problem for KSB. The use of carbon matrices for cathode fabrication has been proven to be an excellent choice by initial research on KSB and experience with other metal-sulfur batteries. This can be related to the higher electronic conductivity of carbon, easy tunability, high specific surface area, and porous morphology. This review is an attempt to show the usage of carbon as a sulfur host for KSBs and its performance. Further, we shed light on flexible and binder-free carbon electrodes for the development of KSBs, which can be adopted to develop flexible batteries to be used in wearable devices. Finally, we present our perspective for developing a high-performance carbon-based cathode material for developing a reliable and long-cycle life KSB.

对环境污染的日益关注加速了储能设备的发展。在各种设备中,锂离子电池(LIB)技术因其稳定的性能在从电子产品到电动汽车(EV)的各种应用中得到了飞跃发展。由于电动汽车的数量不断增加,对电池的需求也随之增加,从而增加了总体成本。一种可取代对锂储备依赖的替代能源存储设备可能会改变这一领域的游戏规则。由于硫和钾的含量较高,钾硫电池(KSB)引起了人们的极大关注。此外,硫作为阴极材料具有最高的容量(比商用锂离子电池高出近五倍),与钾阳极结合可提供 914 Wh/kg 的理论能量密度(对于电动汽车而言明显更高)。然而,由于绝缘硫、体积变化和多硫化物的穿梭效应等内在挑战,KSB 的开发仍处于初级阶段。此外,不稳定的钾阳极及其枝晶的形成也是 KSB 面临的另一个棘手问题。对 KSB 的初步研究和其他金属硫电池的经验证明,使用碳基质制造阴极是一个很好的选择。这可能与碳的较高电子电导率、易调性、高比表面积和多孔形态有关。本综述试图展示碳作为 KSB 硫宿主的用途及其性能。此外,我们还介绍了用于开发 KSB 的柔性无粘合剂碳电极,这种电极可用于开发可穿戴设备中使用的柔性电池。最后,我们提出了开发高性能碳基阴极材料的观点,以开发可靠、长循环寿命的 KSB。
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引用次数: 0
A simulation approach in analyzing performance of fly ash nanofluid for optimizing battery thermal management system used in EVs 分析粉煤灰纳米流体性能以优化电动汽车电池热管理系统的模拟方法
Pub Date : 2024-08-01 DOI: 10.1002/est2.70005
Prajwal Thorat, Sudarshan Sanap, Shashank Gawade, Sateesh Patil

Electric vehicles (EVs) are a fundamental paradigm shift in the automotive industry, driven by the desire to achieve sustainable mobility, ameliorate climate change, and cut greenhouse gas emissions. Electric vehicle (EV) technology has advanced significantly in recent years, with improvements in battery efficiency, range, and charging infrastructure among them. Lithium-ion battery technology has evolved tremendously, boosting energy density and cutting costs as the primary energy storage option for electric vehicles. The advancement of fast-charging stations and smart grid integration, which have significantly resolved concerns with convenience and charging time, has also fostered a wider acceptance of EVs. Nonetheless, the operating temperature range of the lithium-ion cells currently in use is 15°C-35°C. The vehicle's range and battery performance can be impacted by temperatures above or below. For efficient cooling and to keep the cells within the operational temperature range, a suitable Battery Thermal Management System (BTMS) must be implemented. The utilization of fly ash nanoparticles dispersed in water-ethylene glycol base fluid as coolant in indirect liquid cooling systems is the main topic of the current work. For 14 LFP cylindrical cells with a 2S7P configuration and a serpentine cooling channel between the cells, an ANSYS FLUENT model has been created. The goal of the current study is to comprehend the rise in temperature at the outlet for various flow velocities by using fly ash nanofluid with 5% particle concentration as cooling. When the fluid flow rate was 0.1 m/s, the cooling performance was better, resulting in an outlet temperature rise of 311.976 K and a 4% temperature rise above the 300 K inlet fluid flow temperature. Indicating efficient cooling at lower fluid flow velocities, the percentage difference between the rise in temperature of the fluid's outflow at 0.1 and 3 m/s is 3.07%. Compared to the current coolant, ethylene glycol, the average increase in temperature difference (∆T)% is between 0.9% and 1.2% using fly ash nanofluid. Thus, the use of Fly ash as a nanofluid in battery cooling applications will certainly help to reduce the temperature of the battery pack and can provide a sustainable solution leading to lesser degradation of the environment.

电动汽车(EV)是汽车行业模式的根本转变,其驱动力是实现可持续交通、改善气候变化和减少温室气体排放。近年来,电动汽车(EV)技术取得了长足的进步,其中包括电池效率、续航里程和充电基础设施的改善。作为电动汽车的主要储能选择,锂离子电池技术取得了巨大进步,提高了能量密度,降低了成本。快速充电站和智能电网集成的发展极大地解决了人们对便利性和充电时间的担忧,也促进了电动汽车被更广泛地接受。然而,目前使用的锂离子电池的工作温度范围为 15°C-35°C。温度过高或过低都会影响车辆的续航里程和电池性能。为了有效冷却并使电池保持在工作温度范围内,必须采用合适的电池热管理系统(BTMS)。在间接液体冷却系统中利用分散在水-乙二醇基液中的粉煤灰纳米颗粒作为冷却剂是当前工作的主要课题。针对 14 个 2S7P 配置的 LFP 圆柱形电池和电池之间的蛇形冷却通道,我们创建了一个 ANSYS FLUENT 模型。本次研究的目的是通过使用颗粒浓度为 5%的粉煤灰纳米流体作为冷却剂,了解不同流速下出口处的温度升高情况。当流体流速为 0.1 m/s 时,冷却性能较好,出口温度上升了 311.976 K,比 300 K 的入口流体温度高出 4%。0.1 米/秒和 3 米/秒时流体流出温度上升的百分比差为 3.07%,表明在较低的流体流速下冷却效率较高。与当前的冷却剂乙二醇相比,使用粉煤灰纳米流体的平均温差(ΔT)增加率在 0.9% 到 1.2% 之间。因此,在电池冷却应用中使用粉煤灰作为纳米流体肯定有助于降低电池组的温度,并能提供一种可持续的解决方案,减少环境退化。
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引用次数: 0
High-performance supercapacitors using nanostructured polyaniline-based carbon: Effect of electrolytes 使用纳米聚苯胺基碳的高性能超级电容器:电解质的影响
Pub Date : 2024-08-01 DOI: 10.1002/est2.70009
K.A.U. Madhushani, A.A.P.R. Perera, Wang Lin, Jolaikha Sultana, Sanjay R. Mishra, Felio Perez, Ram K. Gupta

Developing high-performance materials for electrochemical energy storage devices such as batteries, and supercapacitors is a significant topic in material chemistry-based research. The high consumption and limited availability of numerous materials used in energy devices lead to the development of alternative, effective, and cost-effective materials exhibiting superior electrochemical chemical performance. A porous activated carbon, derived from polyaniline (PANI) synthesized through chemical oxidative polymerization, can be considered a viable solution in this context. In this study, the electrochemical window of the nitrogen-doped porous activated carbon was enhanced through a combined synthesis process involving the carbonization and activation of PANI nanotubes with KOH. Moreover, alternations in surface area and porosity were evaluated using BET analysis for the samples having PANI to KOH ratios 1:0.5, 1:1, and 1:2. The results revealed a significant improvement in surface area and pore volume, increasing from 18 to 3535 m2/g from pure PANI to chemically treated samples. Among those materials, the PANI to KOH ratio of 1:1 exhibited the highest surface area of 3535 m2/g and the highest pore volume of 0.7131 cm3/g. Subsequently, the electrochemical performance of all materials was evaluated using a three-electrode cell system and a symmetrical coin-cell device. Electrodes fabricated with PANI to KOH ratio of 1:1 by weight showed better electrochemical performance in an aqueous electrolyte (6 M KOH) in both systems. This material exhibited the highest capacitance of 378 F/g (at 0.5 A/g) in the three-electrode system and 143 F/g (at 0.5 A/g) in the SCCD. The SCCD achieved a maximum energy density of 23 Wh/kg with a power density of 544 W/kg. Additionally, these supercapacitors provided a good Coulombic efficiency of about 99% with capacitance retention of 97% at 7 A/g current density after 10 000 charge–discharge cycles. Further, this study expanded by investigating variations of electrochemical performance across various electrolytes, including aqueous, organic, and ionic liquids in coin-cell supercapacitors. The findings reveal promising results, suggesting potential commercial applications for this facile approach to synthesize nitrogen-doped activated carbon, especially for supercapacitors with aqueous electrolytes.

为电池和超级电容器等电化学储能设备开发高性能材料是材料化学研究的一个重要课题。由于能源设备中使用的众多材料消耗量大且可用性有限,因此需要开发具有优异电化学化学性能、高效且经济实惠的替代材料。在此背景下,由化学氧化聚合法合成的聚苯胺(PANI)衍生的多孔活性炭可被视为一种可行的解决方案。在本研究中,通过采用 KOH 对 PANI 纳米管进行碳化和活化的组合合成工艺,氮掺杂多孔活性炭的电化学窗口得到了增强。此外,还利用 BET 分析评估了 PANI 与 KOH 的比例为 1:0.5、1:1 和 1:2 的样品的表面积和孔隙率变化。结果表明,从纯 PANI 到经过化学处理的样品,表面积和孔隙率都有了显著改善,从 18 m2/g 增加到 3535 m2/g。在这些材料中,PANI 与 KOH 的比例为 1:1 时,表面积最大,为 3535 m2/g,孔隙率最大,为 0.7131 cm3/g。随后,使用三电极电池系统和对称钮扣电池装置对所有材料的电化学性能进行了评估。在两种系统中,PANI 与 KOH 的重量比均为 1:1,在水性电解质(6 M KOH)中显示出更好的电化学性能。在三电极系统中,这种材料的电容最高,为 378 F/g(0.5 A/g 时),在 SCCD 中为 143 F/g(0.5 A/g 时)。SCCD 的最大能量密度为 23 Wh/kg,功率密度为 544 W/kg。此外,这些超级电容器的库仑效率约为 99%,在 7 A/g 电流密度下,经过 10 000 次充放电循环后,电容保持率为 97%。此外,这项研究还进一步调查了纽扣电池超级电容器中不同电解质(包括水性、有机和离子液体)的电化学性能变化。研究结果表明,这种合成掺氮活性炭的简便方法具有良好的商业应用前景,尤其适用于使用水性电解质的超级电容器。
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引用次数: 0
Synergistic integration of nickel, porous silicon, and thermally reduced graphene oxide for solid-state hydrogen energy storage 镍、多孔硅和热还原氧化石墨烯的协同集成用于固态氢能存储
Pub Date : 2024-08-01 DOI: 10.1002/est2.70008
Rama Chandra Muduli, Neeraj Kumar Nishad, Dinesh Dashbabu, Anil Kumar Emadabathuni, Paresh Kale

Solid-state hydrogen storage using metal hydrides offers the potential for high energy storage capacities. However, the requirement for high-temperature operations (above 400°C) and challenges with heat exchange are significant drawbacks. From this perspective, adsorption on porous materials presents a viable solution to these challenges. Carbon nanostructures, such as graphene and graphene oxide (GO) derivatives, are well-suited for hydrogen storage because of their lightweight nature, low density, and large surface area. However, the primary obstacle for practical applications is the poor storage capacity of carbon nanostructures under ambient conditions. Utilizing a cost-effective transition element such as nickel as a catalyst offers significant potential for storing hydrogen in atomic and molecular forms by invoking the spillover mechanism. Thermally reduced graphene oxide (TrGO) modifies the surface, providing abundant active sites that attract hydrogen effectively. Porous silicon (PS) enhances the surface properties of graphene sheets, attracting hydrogen to the surface. The current study assesses a synthesized TrGO, PS, and Ni composition to leverage their individual properties for hydrogen storage. Field-emission scanning electron microscopy examines the sheet structure of TrGO (used as the host material) and the incorporation of PS and Ni on its surface. The calculated specific surface area of TrGO is ~450 m2 g−1. X-ray diffraction is used to identify the various phases in the composition, while Raman spectroscopy measures the degree of disorder within the composition. The pressure-composition isotherms reveal hydrogen storage capacities of ~6.53 wt% for the TrGO + PS composition and ~2.43 wt% for the TrGO + PS + Ni composition. Despite the decrease in weight percentage of TrGO + PS + Ni due to the higher Ni content, dissociation enhances the adsorption rate from 0.35 to 0.53 wt% h−1.

使用金属氢化物的固态氢存储为实现高能量存储提供了潜力。然而,高温操作要求(400°C 以上)和热交换方面的挑战是其显著的缺点。从这个角度来看,在多孔材料上进行吸附是应对这些挑战的可行方案。碳纳米结构,如石墨烯和氧化石墨烯(GO)衍生物,因其轻质、低密度和大表面积而非常适合储氢。然而,实际应用的主要障碍是碳纳米结构在环境条件下的存储能力较差。利用具有成本效益的过渡元素(如镍)作为催化剂,通过利用溢出机制,为以原子和分子形式储存氢气提供了巨大的潜力。热还原氧化石墨烯(TrGO)对表面进行了改性,提供了丰富的活性位点,能有效吸引氢气。多孔硅(PS)增强了石墨烯薄片的表面特性,将氢吸引到表面。本研究评估了合成的 TrGO、PS 和镍成分,以利用它们各自的特性进行氢气存储。场发射扫描电子显微镜检查了 TrGO(用作宿主材料)的片状结构以及在其表面加入 PS 和 Ni 的情况。计算得出的 TrGO 比表面积约为 450 m2 g-1。X 射线衍射用于识别成分中的各种相,而拉曼光谱则用于测量成分中的无序程度。压力-沉积等温线显示,TrGO + PS 成分的储氢能力约为 6.53 wt%,TrGO + PS + Ni 成分的储氢能力约为 2.43 wt%。尽管由于镍含量较高,TrGO + PS + Ni 的重量百分比有所下降,但解离作用使吸附率从 0.35 wt% h-1 提高到 0.53 wt%。
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引用次数: 0
Estimation of hybrid energy generation of solar-wind tower for electric vehicle charging: A case study of Indian highway 用于电动汽车充电的太阳能-风能混合发电塔的估算:印度高速公路案例研究
Pub Date : 2024-08-01 DOI: 10.1002/est2.70004
Samarendra Pratap Singh, Prabhakar Tiwari, S.N. Singh, Praveen Prakash Singh

Advances in non-conventional energy technologies and increasing fossil fuel prices along with environmental concerns have made hybrid renewable energy systems important. In view of this scenario, solar panel mounted on a vertical axis wind turbine (called as solar-wind tower) can be utilized to produce more electric energy than individual one. This solar-wind tower will be located in the space available between two opposite roads of expressways/highways. Solar-wind tower located in such a manner that the air velocity produced from driving vehicles on both sides of the road is adequate to cut the turbine blades which will produce unidirectional torque. A battery energy storage system (BESS) stores the power produced by the solar-wind tower so that it can subsequently be used for local loads and electric vehicle charging stations (EVCS) and remaining energy can be supplied to the grid. In this work, a hybrid system composed of wind and solar is designed and modelled in Simulink (MATLAB) and tested on real data of wind speed and validated by Opal-RT simulator. From the simulation result, it is estimated that total electrical power output of a single solar-wind tower is around 15 to 20 kWh in a day under the assumed conditions.

非常规能源技术的进步、化石燃料价格的上涨以及对环境的担忧,使得混合可再生能源系统变得非常重要。在这种情况下,安装在垂直轴风力涡轮机(称为太阳能风力塔)上的太阳能电池板可以比单个太阳能电池板产生更多的电能。该太阳能风塔将位于快速路/高速公路两条相对道路之间的空地上。太阳能风塔的位置应使道路两侧车辆行驶时产生的气流速度足以切割涡轮叶片,从而产生单向扭矩。电池储能系统(BESS)可储存太阳能风塔产生的电能,以便随后用于本地负载和电动汽车充电站(EVCS),并将剩余电能供应给电网。在这项工作中,设计了一个由风能和太阳能组成的混合系统,并在 Simulink(MATLAB)中进行了建模,在真实风速数据上进行了测试,并通过 Opal-RT 模拟器进行了验证。根据模拟结果估计,在假设条件下,单个太阳能风能塔一天的总发电量约为 15 至 20 千瓦时。
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引用次数: 0
Studies on supercapacitor electrode performance of novel (AlCuCoFeMnNi)3O4 high entropy spinel oxide admixed with different carbon-based additives 新型(AlCuCoFeMnNi)3O4 高熵尖晶石氧化物与不同碳基添加剂混合的超级电容器电极性能研究
Pub Date : 2024-07-18 DOI: 10.1002/est2.70002
Amit K. Gupta, Ankit Kumar, Mina Marndi, Neeraj K. Giri, Rohit R. Shahi

The present investigation aims to synthesize a novel (AlCuCoFeMnNi)3O4 type high entropy spinel oxide through the sol-gel and investigate the effect of different carbon-based additives on charge storage performance. The formation of the inverse spinel phase of [B(AB)O4] type inverse spinel phase was confirmed through the detailed x-ray diffraction analysis of the synthesized sample. The synthesized spinel phase was indexed with the space group of Fd−3m and has a lattice parameter of 8.2697 Å. The synthesized high entropy oxide (HEO) phase Ni, Co, and Fe coexists in +2 and +3 states. At the same time, Cu in +2 state, Al in +3 state, and Mn in +3 and +4 states confirmed through x-ray photoelectron spectroscopy. The electrochemical charge storage performance of synthesized HEO was measured through the three-electrode setup in 2 M KOH aqueous electrolyte solution in two different potential windows, such as −0.2 to 0.4 V and 0.0 to 0.5 V. Different carbon-based conducting materials such as acetylene black, reduced graphene oxide (RGO), and carbon particles obtained from 10-hour ball-milling of used dry cell carbon electrode (CP). The charge storage mechanism changes from electrochemical double layer capacitance to pseudocapacitive type as the potential window varies from −0.2 to 0.4 to 0 to 0.5 V. The value of specific capacitance for an electrode made of HEO with acetylene black, RGO, and CP was found to be 32.67, 7.50, and 4.58 F/g and 30.68, 16.33, and 9.05 F/g in the potential window of −0.2 to 0.4 V and 0 to 0.5 V at a scan rate of 5 mV/s, respectively. The cyclic performance of the developed three electrodes was measured at a scan rate of 100 mV/s for 1000 cycles, and it was found to be 94%, 98%, and 99% for electrodes made of HEO with acetylene black, RGO, and CP, respectively.

本研究旨在通过溶胶凝胶法合成一种新型(AlCuCoFeMnNi)3O4 型高熵尖晶石氧化物,并研究不同碳基添加剂对电荷存储性能的影响。通过对合成样品进行详细的 X 射线衍射分析,证实了 [B(AB)O4] 型反尖晶石相的形成。合成的尖晶石相的空间群为 Fd-3m,晶格参数为 8.2697 Å。合成的高熵氧化物(HEO)相镍、钴和铁共存于 +2 和 +3 态。同时,通过 X 射线光电子能谱证实,铜处于 +2 态,铝处于 +3 态,锰处于 +3 和 +4 态。在 2 M KOH 电解质水溶液中,在两个不同的电位窗口(如 -0.2 至 0.4 V 和 0.0 至 0.5 V)内,通过三电极设置测量了合成 HEO 的电化学电荷存储性能。不同的碳基导电材料,如乙炔黑、还原氧化石墨烯(RGO),以及用过的干电池碳电极(CP)经过 10 小时球磨得到的碳颗粒。当电位窗口从 -0.2 到 0.4 到 0 到 0.5 V 变化时,电荷存储机制从电化学双层电容变为伪电容型。在扫描速率为 5 mV/s 时,乙炔黑、RGO 和 CP 制成的 HEO 电极的比电容值分别为 32.67、7.50 和 4.58 F/g 以及 30.68、16.33 和 9.05 F/g,电位窗口分别为 -0.2 至 0.4 V 和 0 至 0.5 V。在 100 mV/s 的扫描速率下,对所开发的三种电极的循环性能进行了 1000 次测量,结果发现,由 HEO 与乙炔黑、RGO 和 CP 制成的电极的循环性能分别为 94%、98% 和 99%。
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引用次数: 0
A synergy of Cr2O3 with eco-friendly and thermally stable CsSnCl3 perovskite for solar energy storage: Density functional theory and SCAPS-1D analysis 用于太阳能存储的 Cr2O3 与环保且热稳定的 CsSnCl3 包晶的协同作用:密度泛函理论和 SCAPS-1D 分析
Pub Date : 2024-07-15 DOI: 10.1002/est2.70001
Ankur Pandya, Atish Kumar Sharma, Misaree Bhatt, Prafulla K. Jha, Keyur Sangani, Nitesh K. Chourasia, Ritesh Kumar Chourasia

The present study employs rigorous DFT analysis using WIEN2k for the best suitability of the Cr2O3 as an electron transport layer, synergetic with nontoxic and thermally stable CsSnCl3 perovskite solar energy storage device, configured as FTO/Cr2O3/CsSnCl3/CBTS/Au. The main objective of our investigation is to improve the device performance by optimizing thickness, carrier concentration, bulk defect density of each layer, interface defects, operating temperature, as well as the impact of parasitic elements on device performance. SCAPS-1D tool was used to optimize the novel device architecture. The simulation results reveal that a CsSnCl3 layer with an optimized thickness of 800 nm and a doping concentration of 1 × 1015 cm−3 yields noteworthy outcomes, specifically, champion efficiency (𝜂) of 22.01% along with an open-circuit voltage (Voc) of 1.12 V, a short-circuit current (Jsc) of 23.86 mA/cm2, and a fill factor of 81.65%. These improved findings were compared with existing theoretical and experimental reported data and found to exhibit the best performance. The present research substantially enhances the understanding of eco-friendly CsSnCl3 perovskite solar cell optimization, thereby extending its applicability to future photovoltaic and optoelectronic devices.

本研究利用 WIEN2k 进行了严格的 DFT 分析,以确定 Cr2O3 作为电子传输层的最佳适用性,并与无毒、热稳定的 CsSnCl3 包晶太阳能存储设备协同作用,配置为 FTO/Cr2O3/CsSnCl3/CBTS/Au。我们研究的主要目的是通过优化各层的厚度、载流子浓度、块状缺陷密度、界面缺陷、工作温度以及寄生元件对器件性能的影响来提高器件性能。我们使用 SCAPS-1D 工具对新型器件结构进行了优化。模拟结果表明,厚度优化为 800 nm、掺杂浓度为 1 × 1015 cm-3 的 CsSnCl3 层产生了值得注意的结果,具体来说,冠军效率 (𝜂) 为 22.01%,开路电压 (Voc) 为 1.12 V,短路电流 (Jsc) 为 23.86 mA/cm2,填充因子为 81.65%。这些改进结果与现有的理论和实验报告数据进行了比较,发现其表现出最佳性能。本研究大大加深了人们对环保型硒氯化铯包晶太阳能电池优化的理解,从而将其应用于未来的光伏和光电设备。
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引用次数: 0
Charging control of lithium-ion battery and energy management system in electric vehicles 电动汽车中的锂离子电池充电控制和能量管理系统
Pub Date : 2024-07-14 DOI: 10.1002/est2.667
Mali Satya Naga Krishna Konijeti, Bharathi Murugan Lakshmi

In terms of electric vehicle architectures, the drivetrain offers unprecedented freedom, but it also creates new obstacles in terms of achieving all needs. The architecture of electric vehicles is simplified and adjustable at the component level because they don't have a combustion engine or fuel tank, only an electric motor and a battery. Implementing safe zones within electric vehicles (EVs) to accommodate battery packs necessitates significant adjustments to ensure the secure integration of the battery. A Battery EV, also known as a pure EV, solely relies on rechargeable battery packs as its source of energy, without any additional propulsion system. The Battery Management System (BMS) plays a significant role in maintaining the safety of electric vehicles by controlling the electronics of rechargeable batteries, whether they are individual cells or battery packs. The BMS plays crucial role in protecting both the user and the battery by monitoring and maintaining the cell's operation within safe limits. This research paper focuses on the control of solar-powered charging for lithium-ion batteries. An optimized FOPID controller is utilized to maximize power extraction from PV array and efficiently charge the battery. A hybrid optimization model is employed to optimize the gain parameters of the FOPID controller.

就电动汽车结构而言,动力传动系统提供了前所未有的自由度,但也为实现所有需求带来了新的障碍。由于电动汽车没有内燃机或油箱,只有电动机和电池,因此其结构在组件层面得到了简化和调整。要在电动汽车(EV)内设置安全区以容纳电池组,就必须进行重大调整,以确保电池的安全集成。电池电动车(也称为纯电动车)完全依靠可充电电池组作为能源,没有任何额外的推进系统。电池管理系统(BMS)通过控制充电电池(无论是单个电池还是电池组)的电子装置,在维护电动汽车安全方面发挥着重要作用。BMS 通过监控和维持电池在安全范围内的运行,在保护用户和电池方面发挥着至关重要的作用。本研究论文的重点是锂离子电池的太阳能充电控制。利用优化的 FOPID 控制器最大限度地从光伏阵列中提取电能,并高效地为电池充电。本文采用混合优化模型来优化 FOPID 控制器的增益参数。
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引用次数: 0
Optimization method for capacity of BESS considering charge-discharge cycle and renewable energy penetration rate 考虑充放电循环和可再生能源渗透率的 BESS 容量优化方法
Pub Date : 2024-07-14 DOI: 10.1002/est2.70003
Yu Zhao, Zhongge Luo, Yi Zhang, Mengjing Wu, Li Wen, Gen Li

In order to achieve the “carbon peaking and carbon neutrality” goals, we must vigorously develop renewable energy power generation. As the penetration of renewables progressively escalates, the corresponding demand for battery energy storage systems (BESS) within the power grid rises concomitantly. This paper presents an innovative optimization approach for configuring BESS, taking into account the incremental variations in renewable energy penetration levels and BESS charge-discharge cycles. Employing incremental analytical techniques and pivotal metrics such as capacity elasticity, the proposed method determines the optimal penetration rate and corresponding BESS capacity outcomes for deploying energy storage systems. An example analysis of a rural power distribution benchmark is carried out by using the method in this paper, which proves the effectiveness of the method in this paper. This methodology was substantiated through its application to a case study of a rural power distribution benchmark, thereby validating its efficacy. Furthermore, it was compared with the particle swarm optimization, providing a comparative assessment of their relative performance.

为了实现 "碳调峰和碳中和 "的目标,我们必须大力发展可再生能源发电。随着可再生能源渗透率的逐步提高,电网对电池储能系统(BESS)的需求也相应增加。考虑到可再生能源渗透水平和 BESS 充放电周期的增量变化,本文提出了一种创新的 BESS 配置优化方法。该方法采用增量分析技术和容量弹性等关键指标,确定了部署储能系统的最佳渗透率和相应的 BESS 容量结果。本文使用该方法对农村配电基准进行了实例分析,证明了本文方法的有效性。通过对农村配电基准的案例研究,证明了该方法的有效性。此外,本文还将该方法与粒子群优化法进行了比较,对两者的相对性能进行了比较评估。
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引用次数: 0
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Energy Storage
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