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The Investigation on Mineral Wool Performance as a Potential Filter to Remove TSS in Cikapayang River, East Jawa, Indonesia 矿棉去除印尼东爪哇Cikapayang河TSS的性能研究
Q3 Environmental Science Pub Date : 2022-10-05 DOI: 10.32526/ennrj/21/202200118
W. Prayogo, J. Siregar, P. Soewondo, Z. Nasution, Z. Hanami, M. F. Ikhwali, A. Estim, I. W. Suryawan
Mineral wool has been used as a filter medium that reaches approximately 95% removal efficiency of total suspended solids (TSS) on a laboratory scale. However, there is no research available has been applied on a larger scale. Hence, this study investigated the ability of mineral wool to remove TSS in two separate segments of the Cikapayang River at different seasons. This analysis utilizes a mineral wool type I, with a dimension of 180×30×120 cm placed in segment 2, and a mineral wool type II with a dimension of 325×30×100 cm placed in segment 9. Samples were taken using the grab sampling method to analyze the TSS concentration before and after being filtered by mineral wool. This investigation concluded that mineral wool could reduce the TSS concentration by up to 65%, and the removal capacity increased by about 6.82% during the dry season. The concentration of TSS in the dry season positively correlates with the increase in the removal capacity of the media. Mineral wool of type I in segment 2 had a better removal ability (31.43%) than type II in segment 9 (14.71%). This research shows that mineral wool can be used as a support material in sanitation sites in large cities experiencing quality degradation in their water bodies.
矿棉已被用作过滤介质,在实验室规模上,其对总悬浮固体(TSS)的去除效率达到约95%。然而,目前还没有可用于更大规模应用的研究。因此,本研究调查了矿棉在不同季节对次卡帕扬河两个不同河段TSS的去除能力。该分析利用了放置在片段2中的尺寸为180×30×120cm的I型矿棉和放置在片段9中的尺寸为325×30×100cm的II型矿棉。采用抓斗取样法对矿棉过滤前后的TSS浓度进行分析。研究表明,在旱季,矿棉可将TSS浓度降低65%,去除能力提高约6.82%。旱季TSS的浓度与培养基去除能力的增加呈正相关。第2段中的I型矿棉的去除能力(31.43%)比第9段中的II型矿棉(14.71%)更好。本研究表明,矿棉可以用作大型城市卫生场所的支撑材料,这些城市的水体质量正在下降。
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引用次数: 3
Biochar Derived from Sesbania sesban Plant as a Potential Low-Cost Adsorbent for Removal of Methylene Blue 从田菁植物中提取的生物炭作为一种潜在的低成本吸附剂去除亚甲基蓝
Q3 Environmental Science Pub Date : 2022-09-14 DOI: 10.32526/ennrj/20/202200119
Nguyen Trung Hiep, Ta Thi Hoai Thu, Lam Thi Thanh Quyen, Phan Dinh Dong, Tran Tuyet Suong, Thai Phuong Vu
In this study, biochar made from the Sesbania sesban plant, under slow pyrolysis at 300°C was used to adsorb methylene blue (MB) in aqueous solution. The biochar properties were clarified by diverse analytical methods such as FTIR, SEM, and BET. The results indicated that the surface of biochar was relatively smooth, had porous texture, and stacked evenly. In addition, the biochar had a large specific surface area of 561.8 m2/g and the pHpzc value was 6.9. The effect of adsorbent dosage, initial pH, contact time, and concentration of dye solution on biochar were investigated. The optimum conditions for MB adsorption were found at the MB concentration of 50 mg/L, initial pH of 11, biochar mass of 0.6 mg, and contact time of 30 min. Under these optimal conditions, MB dye removal efficiency was above 90%. Adsorption isotherm data were fitted with the Langmuir isotherm model (R2=0.897) suggesting the adsorption was monolayer, and its maximum adsorption capacity was about 6.6 mg/g. The adsorption kinetic models showed that the linear pseudo-second-order by R2=0.999 was well fitted. The results indicated the enormous potential of Sesbania sesban plant to produce biochar as a low-cost and rather high-effective adsorbent for dye removal from wastewater as well as water quality improvement.
在本研究中,以田菁为原料,在300℃慢速热解下制备生物炭,用于吸附水溶液中的亚甲基蓝(MB)。利用红外光谱(FTIR)、扫描电镜(SEM)和BET等多种分析方法对生物炭的性质进行了澄清。结果表明:生物炭表面较为光滑,具有多孔结构,堆积均匀;生物炭的比表面积为561.8 m2/g, pHpzc值为6.9。考察了吸附剂用量、初始pH、接触时间和染料溶液浓度对生物炭的影响。最佳吸附条件为:MB浓度为50 mg/L,初始pH为11,生物炭质量为0.6 mg,接触时间为30 min,在此条件下,MB染料去除率可达90%以上。吸附等温线数据符合Langmuir等温线模型(R2=0.897),表明吸附为单层吸附,最大吸附量约为6.6 mg/g。吸附动力学模型拟合良好,R2=0.999。研究结果表明,田菁植物生产生物炭作为一种低成本、高效的废水脱除染料和改善水质的吸附剂具有巨大的潜力。
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引用次数: 2
Population Structure and Spatial Distribution of Tree Species in Lower Montane Forest, Doi Suthep-Pui National Park, Northern Thailand 泰国北部多素贴国家公园下山地森林的种群结构和树种空间分布
Q3 Environmental Science Pub Date : 2022-09-13 DOI: 10.32526/ennrj/20/202200139
Dokrak Marod, P. Duengkae, S. Sangkaew, Phruet Racharak, Warong Suksavate, Suwimon Uthairatsamee, L. Asanok, T. Kamyo, Sathid Thinkampheang, Sutheera Heumhuk, Panida Kachina, Jakkapong Thongsawi, Wongsatorn Phumpuang, Paanwaris Paansri, Wimonmart Nuipakdee, Pisut Nakmuenwai, Sura Pattanakiat
Plant diversity is important for sustainable development, particularly in watershed areas. This study explored tree population and diversity in a lower montane forest (LMF). A 16-ha permanent plot was established in LMF at Huai Kogma sub-watershed, northern Thailand. All trees with a diameter at breast height ≥ 2 cm were tagged, measured, identified, and their coordinates were mapped. The results showed that 220 species in 139 genera from 63 plant families were found. The dominant families based on species numbers and tree density were Fagaceae, Lauraceae, and Theaceae. The most dominant species were Castanopsis acuminatissima, Schima wallichii, Castanopsis armata, and Styrax benzoides. Diameter classes for climax species frequently followed negative exponential distributions, indicating their populations could be maintained into the future. By contrast, pioneer species, such as Macaranga indica, Morus macroura, and Rhus javanica, had discontinuous distribution, and were mostly found in gap areas, indicating successful regeneration may require high light intensity. Spatial distribution patterns based on Morisita’s index showed that most of the selected species had clumped patterns, particularly those in the Fagaceae family, which were predominantly distributed along the mountain ridge. Tree distribution patterns can affect ecological dynamics, thus reinforcing patterns dependent on local interactions such as the abundance of and distance to available resources. Our finding can aid evaluations of forest sustainability, and support the biodiversity conservation plans. In particular, the selection of suitable species for LMF restoration programs where mixed plantings of pioneer and climax species are planned.
植物多样性对可持续发展非常重要,特别是在流域地区。本研究对低山林的树木种群和多样性进行了研究。在泰国北部怀Kogma小流域的LMF中建立了一个16公顷的永久性地块。对胸高≥2 cm的所有树木进行标记、测量、鉴定,并绘制坐标图。结果表明,共发现63科139属220种。主要科为壳斗科、樟科和山茶科。优势种分别为尖槠、木荷、香槠和苯甲酸Styrax。顶极物种的径级往往呈负指数分布,表明其种群在未来可能保持不变。相比之下,先驱种如Macaranga indica、Morus macroura和Rhus javanica的分布不连续,且大多分布在林间,表明成功的更新可能需要较高的光照强度。基于Morisita指数的空间分布格局显示,大部分被选物种呈块状分布,其中壳壳科植物以沿山脊分布为主。树木分布格局可以影响生态动态,从而加强依赖于当地相互作用的格局,如可用资源的丰富程度和距离。研究结果可为森林可持续性评价提供依据,为生物多样性保护规划提供依据。特别是在规划先锋种与顶极种混合种植的LMF恢复方案中,适宜物种的选择。
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引用次数: 0
Selectivity of Malachite Green on Cationic Dye Mixtures Toward Adsorption on Magnetite Humic Acid 孔雀石绿在阳离子染料混合物上对磁铁矿腐植酸吸附的选择性
Q3 Environmental Science Pub Date : 2022-09-07 DOI: 10.32526/ennrj/20/202200142
N. Ahmad, Fitri Suryani Arsyad, I. Royani, A. Lesbani
Magnetite humic acid (MHA) was successfully synthesized by the coprecipitation method followed by hydrothermal process, as evidenced by the XRD, FTIR, VSM, and SEM analysis characterization results. XRD diffraction shows diffraction peaks at 2θ=21.53º, 35.95º, and 57.93º. The FTIR spectra have a typical absorption at 3,410, 1,589, 1,396, 1,026, 910, 794, and 540 cm-1. Magnetite humic acid was paramagnetic with magnetization (Ms) 17.04 emu/g. Humic acid and magnetite humic acid have an irregular structure; the morphology of magnetite humic acid is smoother than humic acid. Malachite green was more selective than methylene blue and rhodamine B on magnetite humic acid. The adsorption of malachite green on humic acid and magnetite humic acid was carried out at pHpzc 8.06 and 6.08. The adsorption capacity (Qmax) of humic acid (77.519 mg/g) and magnetite humic acid (169.492 mg/g) were found with pseudo-second-order kinetic and Langmuir isotherm models. After five regeneration cycles, the adsorption percentages of malachite green with humic acid and magnetite humic acid ranged from 94.67-61.37% and 62.03-21.11%, respectively. Magnetite humic acid has high stability and reusability. The good regeneration of MHA was supported by the XRD diffractogram. Magnetic properties in the material simplify the adsorption process and minimize the potential for damage to the surface of the material.
通过XRD、FTIR、VSM、SEM等分析表征,采用共沉淀法、水热法成功合成了磁性腐植酸(MHA)。XRD衍射峰位于2θ=21.53º、35.95º和57.93º处。FTIR光谱在3,410,1,589,1,396,1,026,910,794和540 cm-1处具有典型的吸收。磁性腐植酸具有顺磁性,磁化强度(Ms)为17.04 emu/g。腐植酸和磁铁矿腐植酸具有不规则结构;磁铁矿腐植酸的形貌比腐植酸光滑。孔雀石绿对磁性腐殖酸的选择性高于亚甲基蓝和罗丹明B。在pHpzc为8.06和6.08时,孔雀石绿对腐植酸和磁铁矿腐植酸进行吸附。采用拟二级动力学模型和Langmuir等温模型,得到了腐植酸(77.519 mg/g)和磁铁矿腐植酸(169.492 mg/g)的吸附量Qmax。5次再生循环后,孔雀石绿对腐植酸和磁铁矿腐植酸的吸附率分别为94.67 ~ 61.37%和62.03 ~ 21.11%。磁性腐植酸具有较高的稳定性和可重复使用性。XRD衍射图证实了MHA具有良好的再生性能。材料中的磁性简化了吸附过程,并最大限度地减少了对材料表面损坏的可能性。
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引用次数: 3
Methane and Nitrous Oxide Emissions from Lowland Rice as Affected by Farmers’ Adopted Fertilizer Applications under Two Crop Establishment Methods in Myanmar 缅甸两种种植方式下农民施肥对低地水稻甲烷和一氧化氮排放的影响
Q3 Environmental Science Pub Date : 2022-09-06 DOI: 10.32526/ennrj/20/202200095
Myo Thet Tin, A. Chidthaisong, N. Pumijumnong, Noppol Arunrat, M. Yuttitham
Identifying the optimal rice establishment option combined with specific fertilizer application can lower the global warming potential (GWP) and greenhouse gases intensity (GHGI) of rice production. In this study, methane (CH4) and nitric oxide (N2O) emissions and rice yields under different fertilizer application methods and two different planting methods, transplanted rice (TPR) and wet bed direct seeded rice (WDSR), was measured. Field experiments using a split plot design and closed chamber-GC method for gas flux measurements were conducted. CH4 and N2O emissions ranged from 1.83-4.68 mg/m2/h and 0.073-0.135 mg/m2/h, respectively. Minimum CH4 and N2O emissions were observed at 48-69 days after seedling (DAS) (tiller stage), while maximum emissions were generally found at 90 DAS or early primordial initiation (EPI) stage. It was found that TPR produced more CH4 and N2O than WDSR across fertilizers methods almost each growth stage throughout the growing period. Regarding GHGs emission factors, CH4 emissions were negatively correlated with soil pH (-0.35*, N=18). At higher soil pH, lower CH4 emissions were found in early growth stages. The N2O emissions did not correlate with soil pH (-0.04 ns, N=18). The highest average CH4 emission was reached in 90 days after seedling and EPI when the soil temperature was maximal at 34.8ºC. The correlation coefficient (r) between CH4 emission and soil temperature was 0.48*, N=18, indicating a positive correlation.
确定最佳水稻种植方案并结合特定施肥,可以降低水稻生产的全球变暖潜值(GWP)和温室气体强度(GHGI)。本研究测定了不同施肥方式和移栽水稻(TPR)和湿床直播水稻(WDSR)两种不同种植方式下水稻甲烷(CH4)和一氧化氮(N2O)排放与产量的关系。采用分块设计和封闭室气相色谱法进行了气体通量测量的现场实验。CH4和N2O排放量分别为1.83 ~ 4.68 mg/m2/h和0.073 ~ 0.135 mg/m2/h。CH4和N2O的排放量在幼苗后48 ~ 69天(分蘖期)达到最小,而最大排放量一般在幼苗后90天或早期原始发育期(EPI)达到最大。结果表明,在整个生育期,TPR几乎在每个生育期都比WDSR产生更多的CH4和N2O。在温室气体排放因子方面,CH4排放量与土壤pH呈负相关(-0.35*,N=18)。土壤pH值越高,生长初期CH4排放量越低。N2O排放量与土壤pH值无相关性(-0.04 ns, N=18)。苗期和EPI后90 d平均CH4排放量最高,土壤温度最高,为34.8℃。CH4排放量与土壤温度的相关系数(r)为0.48*,N=18,呈正相关。
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引用次数: 0
Interactive Governance for the Sustainability of Marine and Coastal Resources in Thailand 泰国海洋和沿海资源可持续性的互动治理
Q3 Environmental Science Pub Date : 2022-08-25 DOI: 10.32526/ennrj/20/202200115
Suvaluck Satumantpan, R. Chuenpagdee
Coastal zones are biodiverse, with complex and dynamic interconnectivity between terrestrial and marine areas, and with multiple interactions between ecological and social systems. Despite on-going efforts to conserve and protect these ecosystems, destructive extraction and unsustainable resource utilization are persistent, posing challenges for governance. Issues and concerns in coastal zones are cross-sectoral and cross-boundary, often with overlapping jurisdictions. They are considered ‘wicked’ governance problems, requiring nuanced approaches to address, rather than technical quick fixes. Interactive governance is one such approach that examines relationships within and between the ecological and social systems, as well as with the governing system. Theoretically, the governability of coastal zones depends on the inherent quality of these systems and their interactions, and improving governability needs to take place in all three orders of governance. At the ‘first order’, a better understanding of the diversity, complexity and dynamics of coastal zones, and related scale issues is required. Improving governability at the ‘second order’ involves evaluating and adjusting the existing legal and institutional frameworks to improve the performance and the correspondence with the systems they aim to govern. Finally, discussion about coastal governance needs to be elevated to ‘meta-order’ where principles are set and values derived so that hard choices can be made, for instance, between conservation and utilization of coastal resources. Guided by the interactive governance framework, the paper presents an overview of coastal governance in Thailand, summarizing key features of the natural, social and governing systems associated with coastal zones, and discussing what can be done to improve coastal governability.
海岸带是生物多样性的,陆地和海洋区域之间具有复杂而动态的相互联系,生态系统和社会系统之间具有多种相互作用。尽管正在努力养护和保护这些生态系统,但破坏性的开采和不可持续的资源利用仍然存在,给治理带来了挑战。沿海地区的问题和关切是跨部门和跨边界的,管辖权往往重叠。它们被认为是“邪恶的”治理问题,需要细致入微的方法来解决,而不是技术上的快速解决方案。互动治理是一种研究生态系统和社会系统内部和之间以及与治理系统之间关系的方法。从理论上讲,沿海地区的可治理性取决于这些系统的内在质量及其相互作用,提高可治理性需要在所有三个治理顺序中进行。在“第一级”,需要更好地了解沿海地区的多样性、复杂性和动态,以及相关的规模问题。提高“第二秩序”的治理能力包括评估和调整现有的法律和体制框架,以提高绩效并与他们旨在治理的系统保持一致。最后,关于海岸治理的讨论需要提升到“元秩序”,在那里制定原则并得出价值观,以便在保护和利用海岸资源之间做出艰难的选择。在互动治理框架的指导下,本文概述了泰国的海岸治理,总结了与海岸带相关的自然、社会和治理系统的主要特征,并讨论了如何提高海岸治理能力。
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引用次数: 1
Bacterial Community of Klong Tub Mangrove Forest in Chonburi Province, Thailand 泰国春武里省Klong Tub红树林的细菌群落
Q3 Environmental Science Pub Date : 2022-08-23 DOI: 10.32526/ennrj/20/202200058
Papon Ganjanasiripong, Pimmnapar Neesanant, T. Taechowisan, N. Kitkumthorn, T. Chuen-Im
Mangrove forests are located in the transition zone of terrestrial and river/marine ecosystems, making these forests a unique environment harbouring diverse microbes. This study investigated the bacterial community of Klong Tub Mangrove Forest in Chonburi Province, Thailand. The distinct feature of this forest is its nearby location to a narrowleaf cattail wetland. Assessment of the abiotic parameters of the sediments from site#1 nearby the narrowleaf cattail wetland and site#2 in the mangrove forest revealed differences in pH and salinity values between these two sites. Biochemical identification of bacterial isolates (n=233) indicated that these species belonged to 16 families and 29 genera as follows: Moraxellaceae (17.60%) > Vibrionaceae (16.31%) > Paenibacillaceae (15.88%) > Staphylococcaceae and Bacillaceae (9.87% each) > Aeromonadaceae and Pseudomonadaceae (8.58% each) > Enterobacteriaceae (4.29%) > Lactobacillaceae (2.58%) > Moraxellaceae (2.15%) > Comamonadaceae (1.72%) > Alcaligenaceae (0.86%) > Morganellaceae, Burkholderiaceae, Pasteurellaceae and Streptococcaceae (0.43% each). Among the genera, 12 were commonly isolated from both sites. Bacterial strains from 7 and 10 genera were detected only in site#1 and site#2, respectively. Analysis of the partial 16s rRNA gene sequence of four filamentous gram-positive isolates showed their high sequence similarity to three genera, including three novel species, Streptomyces sp. NA03103, Micromonospora fluminis sp. nov. and Bacillus velezensis sp. nov. In conclusion, the Klong Tub Mangrove Forest possesses high microbial diversity, and the bacterial taxon in the sediments differ between the narrowleaf cattail wetland and mangrove forest. Several bacterial isolates from the forest show a high biotechnological potential.
红树林位于陆地和河流/海洋生态系统的过渡地带,使这些森林成为孕育多种微生物的独特环境。本研究调查了泰国春武里省Klong Tub红树林的细菌群落。这片森林的独特之处在于它靠近窄叶香蒲湿地。对窄叶香蒲湿地附近的1号站点和红树林中2号站点沉积物的非生物参数进行了评估,发现两个站点之间的pH和盐度值存在差异。233株分离菌经生化鉴定隶属于16科29属:Moraxellaceae(17.60%) >弧菌科(16.31%)> Paenibacillaceae(15.88%) >葡萄球菌科和杆菌科(9.87%)>气单胞菌科和假单胞菌科(8.58%)>肠杆菌科(4.29%)>乳酸杆菌科(2.58%)> Moraxellaceae (2.15%) > Comamonadaceae (1.72%) > Alcaligenaceae(0.86%) >摩根菌科、伯克霍尔德菌科、巴氏杆菌科和链球菌科(0.43%)。其中12个属在两个地点均有分离。仅在1号位点和2号位点检出了7属和10属的菌株。对4株革兰氏阳性丝状菌的16s rRNA部分序列分析表明,它们与3个属(包括3个新种:Streptomyces sp. NA03103、Micromonospora fluuminis sp. 11和Bacillus velezensis sp. 11)序列相似性较高。由此可见,Klong Tub红树林具有较高的微生物多样性,且窄叶香蒲湿地与红树林沉积物中的细菌分类群存在差异。从森林中分离出的几种细菌显示出很高的生物技术潜力。
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引用次数: 1
Exploration of Potential Indigenous Non-phytopathogenic Fungi for Bio-organic Fertilizer Recycling from Organic Waste 利用有机废弃物回收生物有机肥的潜在本土非植物致病真菌的探索
Q3 Environmental Science Pub Date : 2022-08-18 DOI: 10.32526/ennrj/20/202200110
Abul Hossain Molla, Hasnat Zahan, M. M. D. Oliver, M. Khaled Mosharaf
Using potential microbes in biodegradable solid waste management is an emerging science. Microbes play a significant role in recycling of organic solid wastes. Therefore, the present project was carried out to isolate indigenous potential non-phytopathogenic fungi from local relevant decomposed substrates for the purpose of organic waste recycling as bio-organic fertilizer (BOF). A total of thirteen fungal strains were isolated. Seven of them were identified as Trichoderma spp., and the rest were Penicillium spp. Germination of mung bean (Vigna radiata), mustard (Brassica campestris), and wheat (Triticum aestivum) seeds were assessed by application of 13 fungal isolate suspensions. Significant increase of germination percent was achieved in mung bean (98.35%), mustard (96.65%), and wheat (93.35%) by fungal treatments RW-T02, PL-P01, and CD-T01/MSW-T05, respectively, compared to the controls. But radicle and plumule lengths were not promoted by fungal treatments in the majority of cases. Significantly, the longest radicle and plumule lengths of mung bean and mustard were found in control treatments. Conversely, in wheat the longest radicle and plumule length were achieved in treatments MSW-T05 and RW-T03, respectively. Based on superior performances of percent germination and radicle/plumule length, six fungal isolates were selected for compatibility performance in mixed cultures. In the compatibility tests, two fungal combinations (ABF and BCE) presented superior mutual intermingle appearances. Perhaps these combinations may play significant roles in biodegradation of organic wastes.
利用潜在微生物进行可生物降解固体废物管理是一门新兴的科学。微生物在有机固体废物的循环利用中起着重要的作用。因此,本项目旨在从当地相关分解基质中分离出潜在的本地非植物病原真菌,用于有机废物循环利用作为生物有机肥(BOF)。共分离到13株真菌。应用13种分离真菌悬浮液对绿豆(Vigna radiata)、芥菜(Brassica campestris)和小麦(Triticum aestivum)种子的萌发进行了评价。与对照相比,RW-T02、PL-P01和CD-T01/MSW-T05处理的绿豆、芥菜和小麦的发芽率分别显著提高(98.35%)、96.65%和93.35%。但在大多数情况下,真菌处理并没有促进胚根和胚珠的长度。对照处理中绿豆和芥菜的胚根和胚芽最长。相反,在小麦中,MSW-T05和RW-T03处理的胚根和胚粒长度分别最长。基于发芽率和胚根/胚芽长度的优异表现,选择了6株真菌进行混合培养的相容性试验。在相容性试验中,两个真菌组合(ABF和BCE)表现出较好的相互混种现象。这些组合可能在有机废物的生物降解中发挥重要作用。
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引用次数: 1
Evaluating Ecological Risk Associated with Heavy Metals in Agricultural Soil in Dong Thap Province, Vietnam 越南同塔省农业土壤重金属生态风险评价
Q3 Environmental Science Pub Date : 2022-08-16 DOI: 10.32526/ennrj/20/202200114
Nguyen Thanh Giao, Huynh Thi Hong Nhien, Phan Kim Anh
Heavy metal pollution in soil has received more attention in recent years because of an increase in human activities and its potential effects on ecology and human health. This study assessed the occurrence of heavy metals (As, Pb, Cu, Zn, and Cd) in different cultivated land and their ecological risk in Dong Thap Province, Vietnam. Seventeen samples collected in paddy, vegetable, perennials, and ornamental soils were measured for heavy metal concentrations and soil structure. The data were analyzed using Pearson correlation, principal component analysis (PCA), cluster analysis (CA), Nemerow pollution index (PIN), geoaccumulation index (Igeo), pollution load index (PLI), and potential ecological risk index (RI). The results revealed that the soil structure was clay loam and silt clay loam. Heavy metal concentrations were within the national limits with the order of Zn>Cu>Pb>As>Cd. Pearson correlation and PCA indicated that heavy metals were strongly correlated, and agriculture and soil formation were responsible for their presence in soil. The sampling sites were divided into four groups using CA, in which paddy and crop soils had the highest content of heavy metals. Based on PIN values (0.82-2.92), the heavy metal pollution ranged from warning to moderate level. As had the highest accumulation potential in the soil, with the Igeo values ranging from 0.12-2.05. The risk of heavy metal pollution in agricultural soil to ecology was low to moderate. Despite that, it is recommended to annually monitor the occurrence of heavy metals in agricultural soils to have proper solutions to protect public health.
近年来,由于人类活动的增加及其对生态和人体健康的潜在影响,土壤重金属污染受到越来越多的关注。研究了越南同塔省不同耕地重金属(As、Pb、Cu、Zn、Cd)的赋存状况及其生态风险。对水稻、蔬菜、多年生植物和观赏土壤中的17个样品进行了重金属浓度和土壤结构的测定。采用Pearson相关、主成分分析(PCA)、聚类分析(CA)、Nemerow污染指数(PIN)、地质积累指数(Igeo)、污染负荷指数(PLI)和潜在生态风险指数(RI)对数据进行分析。结果表明,土壤结构为粘壤土和粉砂质粘壤土。重金属浓度为Zn>Cu>Pb>As>Cd,均在国家限定范围内。Pearson相关分析和PCA分析表明,土壤中重金属的存在与农业和土壤形成密切相关。采用CA法将采样点分为4组,其中水稻和作物土壤重金属含量最高。根据PIN值(0.82-2.92),重金属污染范围为预警至中度。其积累势最高,Igeo值为0.12 ~ 2.05。农业土壤重金属污染对生态的危害程度为低至中度。尽管如此,建议每年监测农业土壤中重金属的出现情况,以便有适当的解决办法来保护公众健康。
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引用次数: 0
Soil Contamination by Phthalate Esters in Cultivated and Non-Cultivated Soils in North African Arid Regions: A Tunisian Case Study 北非干旱地区栽培和非栽培土壤中邻苯二甲酸酯类的土壤污染:突尼斯案例研究
Q3 Environmental Science Pub Date : 2022-08-15 DOI: 10.32526/ennrj/20/202200049
A. Bouajila, Z. Omar, Rim Saoud, R. Rahmani
Over the last decades, several studies showed that phthalic acid esters (PAEs) were ubiquitous environmental contaminants and became a major threat to human health. This study provided the first case study about the concentration and the potential sources of soil’s PAEs, both in Tunisia and North Africa. Soil samples were collected from four cultivated (CS) and two adjacent native soils (NS) at 0-10 cm and 10-30 cm layers in southeastern Tunisia. The PAEs concentrations were analyzed using a gas chromatography-mass spectrometry (GC-MS) system. Results showed that the total concentration of PAEs ranged from 2.40 to 11.05%. Higher values were detected in NS in the 0-10 cm layer contrary to CS which showed higher PAEs concentration in 10-30 cm depth. The di-n-butyl phthalate (DBP) and di-(2-ethylhexyl) phthalate (DEHP) were the most abundant PAEs. In the 0-10 cm layer, PAEs concentration was highly related to the age of the plastic film in CS. We observed a positive association between PAEs concentration and conductivity (EC) values. The PAEs concentrations were affected by the presence of soil organic matter (SOM) in CS. This decrease of PAEs in CS compared to the NS may be related to the microbial decomposition activity stimulated by the presence of fresh organic residues and fertilizers. These results showed that CS and adjacent NS in the studied regions were contaminated by PAEs which is probably a result of agricultural activities. More investigations on PAEs concentrations in various soil managements are needed to confirm these results.
在过去的几十年里,一些研究表明,邻苯二甲酸酯(PAEs)是普遍存在的环境污染物,成为对人类健康的主要威胁。该研究首次对突尼斯和北非地区土壤中PAEs的浓度和潜在来源进行了案例研究。土壤样品采集于突尼斯东南部0-10 cm和10-30 cm土层的4个栽培土壤(CS)和2个邻近的原生土壤(NS)。采用气相色谱-质谱联用(GC-MS)系统分析PAEs浓度。结果表明,PAEs总浓度在2.40% ~ 11.05%之间。在0-10 cm土层中,NS的PAEs浓度较高,而CS在10-30 cm土层中PAEs浓度较高。邻苯二甲酸二丁酯(DBP)和邻苯二甲酸二(2-乙基己基)酯(DEHP)是含量最多的PAEs。CS中0 ~ 10 cm层PAEs浓度与膜龄高度相关。我们观察到PAEs浓度与电导率(EC)值呈正相关。土壤有机质(SOM)的存在影响了土壤中PAEs的浓度。与NS相比,CS中PAEs的减少可能与新鲜有机残留物和肥料的存在刺激了微生物分解活性有关。这些结果表明,研究区域的CS和邻近的NS受到PAEs的污染,这可能是农业活动的结果。需要对不同土壤管理中PAEs浓度进行更多的调查来证实这些结果。
{"title":"Soil Contamination by Phthalate Esters in Cultivated and Non-Cultivated Soils in North African Arid Regions: A Tunisian Case Study","authors":"A. Bouajila, Z. Omar, Rim Saoud, R. Rahmani","doi":"10.32526/ennrj/20/202200049","DOIUrl":"https://doi.org/10.32526/ennrj/20/202200049","url":null,"abstract":"Over the last decades, several studies showed that phthalic acid esters (PAEs) were ubiquitous environmental contaminants and became a major threat to human health. This study provided the first case study about the concentration and the potential sources of soil’s PAEs, both in Tunisia and North Africa. Soil samples were collected from four cultivated (CS) and two adjacent native soils (NS) at 0-10 cm and 10-30 cm layers in southeastern Tunisia. The PAEs concentrations were analyzed using a gas chromatography-mass spectrometry (GC-MS) system. Results showed that the total concentration of PAEs ranged from 2.40 to 11.05%. Higher values were detected in NS in the 0-10 cm layer contrary to CS which showed higher PAEs concentration in 10-30 cm depth. The di-n-butyl phthalate (DBP) and di-(2-ethylhexyl) phthalate (DEHP) were the most abundant PAEs. In the 0-10 cm layer, PAEs concentration was highly related to the age of the plastic film in CS. We observed a positive association between PAEs concentration and conductivity (EC) values. The PAEs concentrations were affected by the presence of soil organic matter (SOM) in CS. This decrease of PAEs in CS compared to the NS may be related to the microbial decomposition activity stimulated by the presence of fresh organic residues and fertilizers. These results showed that CS and adjacent NS in the studied regions were contaminated by PAEs which is probably a result of agricultural activities. More investigations on PAEs concentrations in various soil managements are needed to confirm these results.","PeriodicalId":11784,"journal":{"name":"Environment and Natural Resources Journal","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41350674","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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Environment and Natural Resources Journal
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