Marliana Tri Widyastuti, Budiman Minasny, Wartini Ng, Patrice de Caritat, José Padarian, Alex McBratney
Vanadium (V) is increasingly recognised as a critical mineral due to its potential for decarbonisation technologies. Australia holds an estimated quarter of global V resources, yet there is limited knowledge of how these resources are distributed across the country. Here, we employed digital soil mapping techniques to map the distribution of soil V content at a 90 m resolution. Using remotely sensed data as environmental covariates (i.e., barest Earth Landsat imagery, gamma-ray spectrometry maps) and layers representing soil, climate, and topography, we calibrated Cubist machine learning models on 1315 nationally sampled data points of aqua-regia-extracted V content. Our models performed reasonably well in predicting V content in top outlet sediment (0–10 cm) and bottom outlet sediment (on average ~60–80 cm), with an average concordance correlation coefficient of 0.49 and 0.52 on the validation data. Independent validation using top outlet sediment data from northern Australia (n = 780) demonstrated that our models maintained consistent accuracy. Feature importance ranking revealed that spectral images at barest soil condition, climate and soil texture were the most influential predictors. High V contents predominantly occurred on Kandosols and iron-rich Tenosols, particularly in Western Australia. This first explicit prediction of soil V content provides essential baseline information for sustainable resource planning and management across Australia.
{"title":"Digital Mapping of Soil Vanadium Across Australia","authors":"Marliana Tri Widyastuti, Budiman Minasny, Wartini Ng, Patrice de Caritat, José Padarian, Alex McBratney","doi":"10.1111/ejss.70237","DOIUrl":"10.1111/ejss.70237","url":null,"abstract":"<p>Vanadium (V) is increasingly recognised as a critical mineral due to its potential for decarbonisation technologies. Australia holds an estimated quarter of global V resources, yet there is limited knowledge of how these resources are distributed across the country. Here, we employed digital soil mapping techniques to map the distribution of soil V content at a 90 m resolution. Using remotely sensed data as environmental covariates (i.e., barest Earth Landsat imagery, gamma-ray spectrometry maps) and layers representing soil, climate, and topography, we calibrated Cubist machine learning models on 1315 nationally sampled data points of aqua-regia-extracted V content. Our models performed reasonably well in predicting V content in top outlet sediment (0–10 cm) and bottom outlet sediment (on average ~60–80 cm), with an average concordance correlation coefficient of 0.49 and 0.52 on the validation data. Independent validation using top outlet sediment data from northern Australia (<i>n</i> = 780) demonstrated that our models maintained consistent accuracy. Feature importance ranking revealed that spectral images at barest soil condition, climate and soil texture were the most influential predictors. High V contents predominantly occurred on Kandosols and iron-rich Tenosols, particularly in Western Australia. This first explicit prediction of soil V content provides essential baseline information for sustainable resource planning and management across Australia.</p>","PeriodicalId":12043,"journal":{"name":"European Journal of Soil Science","volume":"76 6","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://bsssjournals.onlinelibrary.wiley.com/doi/epdf/10.1111/ejss.70237","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145515948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ye Wang, Sara L. Bauke, Martina I. Gocke, Christian von Sperber, Julien Guigue, Kathlin Schweitzer, Sabine J. Seidel, Federica Tamburini, Wulf Amelung
Liming enhances both organic phosphorus (P) mineralization and the precipitation of inorganic phosphates with calcium (Ca) cations. To better understand how P storage and cycling in soil profiles are regulated by the interaction of long-term P fertilization and liming, we collected soil samples from three German arable long-term field experiments in Berlin-Dahlem (Albic Luvisol; sandy topsoil [0–30 cm], and loamy subsoil [> 30 cm]), Dikopshof (Haplic Luvisol; silty-loamy topsoil, and clayey-loamy subsoil), and Thyrow (Albic Luvisol; sandy soil). Treatments within each of these experiments had received mineral fertilization with NKPCa (N: nitrogen; K: potassium; P: phosphorus; Ca: calcium, referring to liming), NKCa, NKP, and NK or no fertilizer application (none) for at least 60 years. Soil P stocks down to 100 cm depth were assessed by Hedley sequential P fractionation and the oxygen isotopic composition of 1 M HCl-extractable phosphate (δ18OP) was analyzed as an indicator of the degree of microbial P cycling over the decades of experimental duration. We found that mineral P fertilization increased soil total P stocks in all P fractions regardless of differences in soil clay content among the different experiments. Liming significantly decreased NaHCO3-Pi (Pi: inorganic P) and NaOH-Pi stocks by up to 50% across the three experiments and soil depths, but tended to increase Po (organic P) stocks in these fractions by up to 40%, reflecting enhanced P uptake into plant and microbial biomass when acidic soil conditions were improved by lime application. Soil HCl-Pi stocks in treatments with long-term P fertilization and liming were larger by a factor of up to 1.8 compared to the unfertilized control plots, while especially the plots without P fertilization showed smaller δ18OP values of 11‰ in the subsoil. These results indicate that, on the one hand, biological P cycling was enhanced in fertilized treatments, but on the other hand, soluble Pi was precipitated as secondary Ca–P minerals into stable P fractions. These changes occurred both in the topsoil and upper subsoil (30–50 cm). We conclude that the combined application of long-term P fertilization and liming to the surface soil also increased the utilization of subsoil P.
{"title":"Liming Enhances Soil Phosphorus Cycling in Long-Term Agricultural Fields","authors":"Ye Wang, Sara L. Bauke, Martina I. Gocke, Christian von Sperber, Julien Guigue, Kathlin Schweitzer, Sabine J. Seidel, Federica Tamburini, Wulf Amelung","doi":"10.1111/ejss.70238","DOIUrl":"10.1111/ejss.70238","url":null,"abstract":"<p>Liming enhances both organic phosphorus (P) mineralization and the precipitation of inorganic phosphates with calcium (Ca) cations. To better understand how P storage and cycling in soil profiles are regulated by the interaction of long-term P fertilization and liming, we collected soil samples from three German arable long-term field experiments in Berlin-Dahlem (Albic Luvisol; sandy topsoil [0–30 cm], and loamy subsoil [> 30 cm]), Dikopshof (Haplic Luvisol; silty-loamy topsoil, and clayey-loamy subsoil), and Thyrow (Albic Luvisol; sandy soil). Treatments within each of these experiments had received mineral fertilization with NKPCa (N: nitrogen; K: potassium; P: phosphorus; Ca: calcium, referring to liming), NKCa, NKP, and NK or no fertilizer application (none) for at least 60 years. Soil P stocks down to 100 cm depth were assessed by Hedley sequential P fractionation and the oxygen isotopic composition of 1 M HCl-extractable phosphate (δ<sup>18</sup>O<sub>P</sub>) was analyzed as an indicator of the degree of microbial P cycling over the decades of experimental duration. We found that mineral P fertilization increased soil total P stocks in all P fractions regardless of differences in soil clay content among the different experiments. Liming significantly decreased NaHCO<sub>3</sub>-Pi (Pi: inorganic P) and NaOH-Pi stocks by up to 50% across the three experiments and soil depths, but tended to increase Po (organic P) stocks in these fractions by up to 40%, reflecting enhanced P uptake into plant and microbial biomass when acidic soil conditions were improved by lime application. Soil HCl-Pi stocks in treatments with long-term P fertilization and liming were larger by a factor of up to 1.8 compared to the unfertilized control plots, while especially the plots without P fertilization showed smaller δ<sup>18</sup>O<sub>P</sub> values of 11‰ in the subsoil. These results indicate that, on the one hand, biological P cycling was enhanced in fertilized treatments, but on the other hand, soluble Pi was precipitated as secondary Ca–P minerals into stable P fractions. These changes occurred both in the topsoil and upper subsoil (30–50 cm). We conclude that the combined application of long-term P fertilization and liming to the surface soil also increased the utilization of subsoil P.</p>","PeriodicalId":12043,"journal":{"name":"European Journal of Soil Science","volume":"76 6","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://bsssjournals.onlinelibrary.wiley.com/doi/epdf/10.1111/ejss.70238","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145498375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}