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Prospects and problems in the development of biochar-filled plastic composites: a review 生物炭填充塑料复合材料的发展前景与问题综述
IF 2.8 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-01-09 DOI: 10.1088/2631-6331/acb19b
A. Adeniyi, K. Iwuozor, E. Emenike, Mubarak A. Amoloye, Emmanuel S Aransiola, Fawaz O. Motolani, Sodiq H Kayode
This study is a review of published literature that discusses the utilization of biochar (BC) and plastics as filler and matrix, respectively, in a composite material. These composites, referred to as Biochar-filled plastic composites (BFPCs), play a significant role in the production of environmentally friendly materials. This paper provides an overview of BFPCs, their properties (mechanical, rheological, morphological, electrical, and thermal properties), fabrication techniques, and prospects and challenges associated with their development. Even though there have been previous studies on BFPCs, none of these studies have discussed the drawbacks and potential associated with the development of BFPCs. BCs’ small weight makes them a more appealing option than traditional mineral fillers when it comes to reducing vehicle weight. Due to their superior mechanical and thermal qualities, as well as their low carbon footprint, BC-filled plastic composites (BFPCs) play a significant role in the production of environmentally friendly materials. It was observed that either melt extrusion or injection molding are usually used to fabricate BFPC. It was observed that the properties of BFPCs are influenced by several factors such as the type and concentration of plastic, method of fabrication, the BC content, mixing uniformity of the mixture, wetting, and particle dispersion. Challenges of BFPCs were also discussed, such as the issue of particle agglomeration and poor interfacial bonding at high BC concentrations in the composite. Composites made from recycled polymers or biodegradable polymers can be developed to improve the composites’ overall sustainability.
本研究综述了已发表的文献,这些文献讨论了生物炭(BC)和塑料在复合材料中分别作为填料和基质的用途。这些复合材料被称为生物炭填充塑料复合材料(BFPC),在生产环保材料方面发挥着重要作用。本文概述了BFPC及其性能(机械、流变、形态、电学和热学性能)、制造技术,以及与发展相关的前景和挑战。尽管之前有关于BFPC的研究,但这些研究都没有讨论与BFPC发展相关的缺点和潜力。在减轻车辆重量方面,BCs的小重量使其成为比传统矿物填料更具吸引力的选择。由于其优异的机械和热性能以及低碳足迹,BC填充塑料复合材料(BFPC)在生产环保材料方面发挥着重要作用。观察到,通常使用熔融挤出或注射成型来制造BFPC。据观察,BFPC的性能受到几个因素的影响,如塑料的类型和浓度、制造方法、BC含量、混合物的混合均匀性、润湿性和颗粒分散性。还讨论了BFPC的挑战,例如在复合材料中高BC浓度下颗粒团聚和界面结合不良的问题。可以开发由回收聚合物或可生物降解聚合物制成的复合材料,以提高复合材料的整体可持续性。
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引用次数: 3
A review of the dynamic analysis and free vibration analysis on fiber metal laminates (FMLs) 金属纤维层合板的动力分析与自由振动分析综述
IF 2.8 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-01-07 DOI: 10.1088/2631-6331/acb135
Quanjin Ma, M. Merzuki, M. Rejab, M. Sani, Bo Zhang
It is a challenging target to improve the dynamic analysis and free vibration analysis of fiber metal laminates (FMLs) while providing great promise as lightweight structural components. FMLs have attracted increasing research interest in various multi-stack FML components to enlarge industrial applications. This review paper concentrates on the free vibration analysis of FMLs, which mainly refers to dynamic analysis, macro mechanical and micro mechanical approaches, and temperature effects. The available types of experimental vibration methods on FMLs are described. Moreover, dynamic analysis of FMLs is mainly reviewed in recent studies of FMLs on the macro mechanical and micromechanical scale aspects, and the temperature effect is also studied. Furthermore, several classical theoretical equations of different FMLs on free vibration analysis are summarized. In addition, optimization studies on FMLs under dynamic analysis are further discussed.
如何在提高金属纤维层压板的动力分析和自由振动分析水平的同时,为其轻量化结构提供了广阔的前景,是一个具有挑战性的目标。为了扩大工业应用范围,各种多层叠FML组件已引起人们越来越多的研究兴趣。本文综述了FMLs的自由振动分析,主要包括动力学分析、宏观力学和微观力学方法以及温度效应。介绍了FMLs实验振动方法的种类。此外,本文主要从宏观力学和微观力学两方面综述了近年来关于FMLs的动态分析,并对温度效应进行了研究。在此基础上,总结了自由振动分析的几种经典理论方程。在此基础上,进一步探讨了动态分析条件下FMLs的优化研究。
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引用次数: 2
Manufacturing of stereolithographic 3D printed boron nitride nanotube-reinforced ceramic composites with improved thermal and mechanical performance 立体光刻3D打印氮化硼纳米管增强陶瓷复合材料的制造,具有更好的热性能和机械性能
IF 2.8 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-01-06 DOI: 10.1088/2631-6331/acb12a
M. Tank, Ana De Leon, Wentao Huang, Mitesh Patadia, Joshua Degraff, R. Sweat
Boron nitride nanotubes (BNNTs) are the perfect candidate for nanofillers in high-temperature multifunctional ceramics due to their high thermal stability, oxidation resistance, good mechanical properties, high thermal conductivity, and radiation shielding. In this paper, 3D printed ceramic nanocomposite with 0.1 wt% of BNNT was prepared by fusing it at high temperatures. Samples were built with three different print directions to study the effect of print layers on mechanical performance along with BNNT addition. Dynamic mechanical analysis is performed to study the length effect of nanoscale reinforcements on the mechanical properties of the printed ceramic composites reporting significant improvements up to 55% in bending strength and 72% in bending modulus with just 0.1 wt% BNNT addition. A 63% thermal diffusivity improvement of ceramic by adding BNNTs is observed using laser flash analysis. The bridging and pull-out effect of nanotubes with a longer aspect ratio was observed with high-resolution microscopy. Such composites’ modeling and simulation approaches are crucial for virtual testing and industrial applications. Understanding the effect of nanoscale synthetic fillers for 3D printed high-temperature ceramics can revolutionize future extreme environment structures.
氮化硼纳米管(BNNT)具有高的热稳定性、抗氧化性、良好的机械性能、高导热性和辐射屏蔽性,是高温多功能陶瓷中纳米填料的完美候选者。本文通过在高温下熔融制备了含有0.1wt%BNNT的3D打印陶瓷纳米复合材料。构建了具有三个不同印刷方向的样品,以研究印刷层对添加BNNT的机械性能的影响。进行了动态力学分析,以研究纳米级增强体的长度对印刷陶瓷复合材料的机械性能的影响,报告了仅添加0.1wt%的BNNT,弯曲强度和弯曲模量就显著提高了55%和72%。使用激光闪光分析观察到通过添加BNNT使陶瓷的热扩散率提高了63%。用高分辨率显微镜观察了长径比纳米管的桥接和拔出效应。这种复合材料的建模和仿真方法对于虚拟测试和工业应用至关重要。了解纳米级合成填料对3D打印高温陶瓷的影响可以彻底改变未来的极端环境结构。
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引用次数: 0
Structural integrity and performance investigations of a novel chemically treated cellulosic paper corn/polyester sustainable biocomposites 一种新型化学处理纤维素纸玉米/聚酯可持续生物复合材料的结构完整性和性能研究
IF 2.8 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-01-01 DOI: 10.1088/2631-6331/acbf20
F. Al-Oqla, M. Hayajneh, M. E. Hoque
Facilitating finding low-cost renewable and sustainable environmental functional alternative materials for green products has been recently emphasized. Lignocellulosic materials are of such potential alternatives to enhance the modern cleaner production theme. In this work, several structural parameters, reinforcement conditions, and chemical treatments have been investigated to reveal their effects on the final desired mechanical performance of lignocellulosic corn/polyester composites for sustainable green products. Low-cost treatment solutions as sodium chloride, phosphoric and citric acids were considered for Mediterranean corn agro waste lignocellulosic fibers. Results have revealed that superior mechanical performance enhancements were occurred for the produced bio-composites. It was demonstrated that prepared composites were capable of enhancing the tensile strength as well as modulus for all types of treatment. About 157% tensile strength enhancement was achieved in case of 30 wt.% fiber content when treated with phosphoric and citric acids. Moreover, sodium chloride treatment was capable of achieving 81 MPa for the 20 wt.% fiber loading comparable to 54.7 MPa for the matrix. The modulus of elasticity property was also enhanced more than 600% for the untreated fibers and sodium chloride treated ones. This obviously demonstrates the potential of such low-cost fiber/low cost treatment synergy to fabricate potential green materials for sustainable industrial applications as well as enhance evaluating such materials from various technical stand points for the future sustainable cleaner production.
促进寻找低成本可再生和可持续的环保功能替代材料的绿色产品最近被强调。木质纤维素材料是增强现代清洁生产主题的潜在替代品。在这项工作中,研究了几种结构参数,增强条件和化学处理,以揭示它们对可持续绿色产品的木质纤维素玉米/聚酯复合材料最终所需机械性能的影响。采用氯化钠、磷酸和柠檬酸等低成本处理方法处理地中海玉米农业废弃物木质纤维素纤维。结果表明,所制备的生物复合材料具有优异的机械性能增强。结果表明,所制备的复合材料在各种处理下都能提高拉伸强度和模量。当磷和柠檬酸处理纤维含量为30wt .%时,拉伸强度提高约157%。此外,氯化钠处理在20% wt.%纤维负载下能够达到81 MPa,而基体的压力为54.7 MPa。未经处理和氯化钠处理的纤维的弹性模量也提高了600%以上。这显然表明了这种低成本纤维/低成本处理协同作用的潜力,可以为可持续的工业应用制造潜在的绿色材料,并从各种技术角度加强对这些材料的评价,以促进未来可持续的清洁生产。
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引用次数: 6
Evaluation of energy absorption enhancement of additively manufactured polymer composite lattice structures 增材制造聚合物复合材料晶格结构的能量吸收增强评价
IF 2.8 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-01-01 DOI: 10.1088/2631-6331/acc0d0
Praveen Kumar A, Quanjin Ma
The unique compressive behaviour of lattice cubic structures as well as their high specific strength and significant energy absorbing characteristics makes them an attractive solution for crashworthiness applications. Hence in this research study, the crashworthiness behaviour and energy absorbing characteristics of the thermoplastic polymer composite lattice cubic structures were experimentally investigated under quasi-static compression. Four design patterns such as Cuboctahedron, Kelvin cell, Truncated cube in square and dividend square geometrics were considered and fabricated through fused deposition modelling technique. The proposed structures were additively manufactured with four different thermoplastic polymer based filament materials and their influence on the crashworthiness characteristics were investigated experimentally. The obtained results revealed that the PLA-CF based KC configuration exhibited SEA of 2.50 kJ g−1 and the maximum value of CFE is 84.91% for PETG-CF based KC configuration. Furthermore, the experimental results indicated that the proposed thermoplastic polymer composite based lattice cubic structures are potentially a suitable component for crashworthiness applications owing to their significant energy absorption ability.
晶格立方结构独特的压缩性能以及高比强度和显著的吸能特性使其成为耐撞应用的有吸引力的解决方案。因此,本研究对热塑性聚合物复合材料晶格立方结构在准静态压缩下的耐撞性能和吸能特性进行了实验研究。采用熔融沉积建模技术,研究了长方体、开尔文单元、正方形截方和红利正方形四种几何形状。采用四种不同的热塑性聚合物基长丝材料增材制造了该结构,并对其耐撞性能的影响进行了实验研究。结果表明,PLA-CF基KC构型的SEA为2.50 kJ g−1,PETG-CF基KC构型的CFE最大值为84.91%。此外,实验结果表明,基于晶格立方结构的热塑性聚合物复合材料具有显著的能量吸收能力,是一种潜在的适合耐碰撞应用的组件。
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引用次数: 2
Optimization and statistical modeling of the thermal conductivity of a pumice powder and carbonated coal particle hybrid reinforced aluminum metal matrix composite for brake disc application: a Taguchi approach 浮石粉和碳化煤颗粒混合增强铝金属基复合材料制动盘导热性能的优化和统计建模:田口方法
IF 2.8 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-01-01 DOI: 10.1088/2631-6331/acc0d1
T. Ibrahim, D. Yawas, Bashar Danasabe, A. A. Adebisi
Aluminum metal matrix composites have been gaining traction in recent years due to their good mechanical properties and low weight. Particulate reinforcements for the improvement of its properties have been explored. This research aimed to determine the optimal composition of the reinforcement content (pumice powder and carbonated coal particles) and processing parameters (stirring speed, processing temperature, and stirring time) on the thermal conductivity of the developed material and also to characterize the constituents using x-ray fluorescence, x-ray diffraction, and scanning electron microscope/energy dispersive x-ray. The Taguchi optimization approach and regression analysis were used for the optimization and statistical analysis, respectively. The Taguchi optimization results gave an optimum thermal conductivity of 111.5, 112.5, 111.7, 112.9, and 112.4 W m−1 °C for pumice, carbonated coal, stirring speed, processing temperature, and stirring time respectively. The optimization also revealed the optimum setting for reinforcements and stir casting process factors as regards thermal conductivity to be 2.5%, 5.0%, 300 rpm, 850 °C, and 5 min for pumice powder, carbonated coal particles, stirring speed, temperature, and time, respectively. The optimal thermal conductivity of 120.40 W m−1 °C was obtained for the hybrid composite which gives a 131.54% improvement over the conventional grey cast iron brake disc. The particulate reinforcements (pumice powder and carbonated coal particles) and the processing factors all had significant effects on the thermal conductivity of the material, with the carbonated coal particles having the highest percentage contribution of 16.51%, as established by the analysis of variance. A model for predicting the thermal conductivity was developed using regression analysis, and high prediction accuracy was established with R-Square, R-Square (adj), and R-Square (pred) values of 94.68%, 88.60%, and 79.94%, respectively. The results of the characterization show the presence of hard compounds such as silica, iron oxide, and alumina in pumice powder and carbonated coal particles.
近年来,铝金属基复合材料因其良好的力学性能和较轻的重量而受到越来越多的关注。研究了颗粒增强剂改善其性能的方法。本研究旨在确定增强量(浮石粉和碳化煤颗粒)的最佳组成和工艺参数(搅拌速度、加工温度和搅拌时间)对所制备材料导热性的影响,并利用x射线荧光、x射线衍射和扫描电镜/能量色散x射线对所制备材料的成分进行表征。采用田口优化法进行优化,采用回归分析进行统计分析。Taguchi优化结果表明,浮石、碳酸煤、搅拌速度、加工温度和搅拌时间的最佳导热系数分别为111.5、112.5、111.7、112.9和112.4 W m−1°C。优化结果表明,浮石粉、碳化煤颗粒、搅拌速度、搅拌温度、搅拌时间的最佳参数为2.5%、5.0%、300 rpm、850℃、5min。复合材料的最佳导热系数为120.40 W m−1°C,比传统灰口铸铁制动盘的导热系数提高了131.54%。颗粒增强剂(浮石粉和碳化煤颗粒)和加工因素对材料导热系数均有显著影响,其中碳化煤颗粒对材料导热系数的贡献率最高,达到16.51%。利用回归分析建立了导热系数预测模型,R-Square、R-Square (adj)和R-Square (pred)分别为94.68%、88.60%和79.94%,预测精度较高。表征结果表明,浮石粉和碳酸煤颗粒中存在二氧化硅、氧化铁和氧化铝等硬质化合物。
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引用次数: 0
Development of highly sensitive capacitive proximity sensor based on stacked monocharged electrets 基于堆叠单电荷驻极体的高灵敏度电容式接近传感器的研制
IF 2.8 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2022-12-01 DOI: 10.1088/2631-6331/acaa19
Donghan Lee, Sumin Cho, Sunmin Jang, Sung Jea Park, D. Choi
Recently, the demand for miniaturization and high sensitivity of the capacitive proximity sensors has increased noticeably for development of sensor networks. However, the volume and weight of conventional sensor devices are emerging as limitations in the practical application. In this paper, the stacked electrets-based highly sensitive noncontact capacitive sensor system (SENS) is proposed. The SENS is fabricated in compact-sized and light weight because electrets, which are dielectric materials that have quasi-permanent injected electric charges so can form external electric field, substitute the transmitter electrode and the external power source. Also, sensitivity of the SENS is effectively improved by stacking electrets. For experimental analysis, the electrostatic properties of the stacked electrets, which are due to the injected charges, and resultant influences on the sensitivity of the SENS are studied. In addition, based on experimental results, a proximity notification system with the SENS is developed using a LabVIEW program to demonstrate the practicality of the SENS.
近年来,随着传感器网络的发展,对电容式接近传感器的小型化和高灵敏度的要求越来越高。然而,传统传感器设备的体积和重量在实际应用中逐渐成为限制因素。提出了一种基于堆叠驻极体的高灵敏度非接触电容式传感器系统。SENS的制造体积小,重量轻,因为驻极体是一种具有准永久注入电荷的介电材料,可以代替发射电极和外部电源形成外部电场。此外,通过叠置驻极体有效地提高了SENS的灵敏度。在实验分析中,研究了由注入电荷引起的堆叠驻极体的静电特性及其对SENS灵敏度的影响。此外,在实验结果的基础上,利用LabVIEW程序开发了一个带有SENS的邻近通知系统,以验证SENS的实用性。
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引用次数: 1
Finite element-based homogenization model to determine effective properties of 0–3 and 1–3 electrostrictive composite 基于有限元的均匀化模型确定0-3和1-3电致伸缩复合材料的有效性能
IF 2.8 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2022-11-30 DOI: 10.1088/2631-6331/aca753
Diwakar Singh, Raj Kumar, R. Vaish
Representative volume element (RVE) based finite element method is employed to evaluate all the effective properties of electrostrictive composite. The attention is paid to designing the periodic boundary conditions to be applied to RVEs of electrostrictive study. The present study is conducted on particulate and fiber electrostrictive composites, in which electrostrictive ceramic (Pb(Mg1/3Nb2/3)O3-PbTO3- BaTiO3, PMN-PT-BT) is embedded into a non electrostrictive polymer (epoxy) matrix. In particulate composite, the spherical particles are randomly distributed and in fiber composites, cylindrical fibers are arranged in a square and hexagonal pattern. The study reveals that the electrostrictive composite does not only depends on the inclusion’s volume but also on their microstructure. The electrostrictive coefficient of the proposed composite is more than its constituent materials owing to the auxiliary flexibility of polymer matrix.
采用基于代表性体积元(RVE)的有限元方法对电致伸缩复合材料的各项有效性能进行了评价。注意设计用于电致伸缩研究的周期边界条件。本研究将电致伸缩陶瓷(Pb(Mg1/3Nb2/3)O3-PbTO3- BaTiO3, PMN-PT-BT)嵌入到非电致伸缩聚合物(环氧树脂)基体中,制备微粒和纤维电致伸缩复合材料。在颗粒复合材料中,球形颗粒是随机分布的,而在纤维复合材料中,圆柱形纤维以正方形和六角形排列。研究表明,电致伸缩复合材料不仅取决于夹杂物的体积,还取决于夹杂物的微观结构。由于聚合物基体的辅助柔韧性,该复合材料的电致伸缩系数大于其组成材料。
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引用次数: 2
Surface-modified carbon fiber for enhanced electromagnetic interference shielding performance in thermoplastic polyurethane composites 热塑性聚氨酯复合材料中增强电磁干扰屏蔽性能的表面改性碳纤维
IF 2.8 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2022-11-29 DOI: 10.1088/2631-6331/aca74f
Dongchan Yi, Gwajeong Jeong, S. Park, M. Yoo, Hyunseung Yang
There has been a growing interest in developing carbon-based polymer composites for electromagnetic interference (EMI) shielding materials. To achieve a high EMI shielding performance, the morphology of fillers in composites must be controlled. Although carbon fibers (CFs) have remarkable thermal and electrical properties and low density, their poor dispersion behavior within polymer matrix limits their practical applications as EMI shielding materials. In this study, we report an efficient method to disperse CFs within a thermoplastic polyurethane (TPU) matrix using pyranine-functionalized polyether (polyether–pyranine) as a dispersing agent. polyether–pyranine was grafted on the CF surfaces through π–π interactions between the CF and pyranine groups to produce surface-modified CFs (SCFs). Compared to CFs, the SCFs exhibited an improved dispersion stability within a TPU polymer matrix. Furthermore, a TPU composite with SCFs achieved an enhanced electrical conductivity and EMI shielding performance, which was primarily ascribed to the increased structural connectivity between the SCFs due to excellent dispersion.
碳基聚合物复合材料作为电磁干扰(EMI)屏蔽材料的研究日益受到关注。为了获得高的电磁屏蔽性能,必须控制复合材料中填料的形态。虽然碳纤维具有优异的热电性能和低密度,但其在聚合物基体中的分散性能差,限制了其作为电磁干扰屏蔽材料的实际应用。在这项研究中,我们报告了一种有效的方法来分散碳纤维在热塑性聚氨酯(TPU)基体中,使用pyranine功能化聚醚(聚醚- pyranine)作为分散剂。通过CF与pyranine基团之间的π -π相互作用,将聚醚- pyranine接枝到CF表面,制备表面修饰的CF (SCFs)。与CFs相比,SCFs在TPU聚合物基体中表现出更好的分散稳定性。此外,含有SCFs的TPU复合材料具有更高的导电性和EMI屏蔽性能,这主要归功于SCFs之间的结构连接性。
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引用次数: 3
Formation of tantalum coatings with a given structure on the surface of niti alloy by magnetron sputter deposition 磁控溅射沉积在镍钛合金表面形成特定结构的钽涂层
IF 2.8 Q2 MATERIALS SCIENCE, COMPOSITES Pub Date : 2022-11-20 DOI: 10.1088/2631-6331/aca461
А. Larionov, А. Dikov, S. O. Akayev, L. Dikova, Е. Zhakanbayev, К. B. Sarsenbaeva
Way for applying tantalum coating with a given structure to the surface of an alloy with a shape memory effect NiTi to increase the biocompatibility of implants from this alloy is presented. The coating was synthesized by direct current (DC) magnetron sputtering. The changes sequence of the structural-phase states depending on the thickness of the coating, that is, the rate of its deposition, has been established. It is shown that at a low magnetron power, ∼14 W in present study, a single-phase α-Ta coating with a bcc structure and a high degree of perfection of the crystal lattice is successfully synthesized on the titanium nickelide surface.
提出了在具有形状记忆效应的NiTi合金表面涂覆具有给定结构的钽涂层以提高该合金植入物的生物相容性的方法。采用直流磁控溅射法合成了涂层。已经确定了结构相状态根据涂层厚度的变化顺序,即其沉积速率。研究表明,在低磁控管功率~14W的条件下,在镍化钛表面成功地合成了具有bcc结构和高度完美晶格的单相α-Ta涂层。
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引用次数: 0
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Functional Composites and Structures
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