Pub Date : 2022-03-07DOI: 10.1088/2631-6331/ac5b1a
N. M. Nurazzi, M. Norrrahim, F. A. Sabaruddin, S. S. Shazleen, R. A. Ilyas, S. Lee, F. N. M. Padzil, G. Aizat, H. A. Aisyah, N. A. Mohidem, M. Asyraf, N. Abdullah, S. M. Sapuan, K. Abdan, N. M. Nor
This paper reviews the mechanical performance of bamboo fibre reinforced polymer composites (BFRPs) for structural applications. Bamboo fibres are very promising reinforcements for polymer composites production due to their high aspect ratio, renewability, environmentally friendly, non-toxicity, cheap cost, non-abrasives, full biodegradability, and strong mechanical performances. Besides, bamboo has its own prospects and good potential to be used in biopolymer composites as an alternative for petroleum-based materials to be used in several advanced applications in the building and construction industry. For bamboo fibre to be reinforced with polymer, they must have good interfacial bond between the polymer, as better fibre and matrix interaction results in good interfacial adhesion between fibre/matrix and fewer voids in the composite. Several important factors to improve matrix-fibre bonding and enhance the mechanical properties of BFRP are by fibre treatment, hybridisation, lamination, and using coupling agent. Moreover, mechanical properties of BFRP are greatly influenced by few factors, such as type of fibre and matrix used, fibre-matrix adhesion, fibre dispersion, fibre orientation, composite manufacturing technique used, void content in composites, and porosity of composite. In order to better understand their reinforcing potential, the mechanical properties of this material is critically discussed in this review paper. In addition, the advantages of bamboo fibres as the reinforcing phase in polymer composites is highlighted in this review paper. Besides that, the bamboo-based products such as laminated bamboo lumber, glued-laminated bamboo, hybrid bamboo polymer composites, parallel bamboo strand lumber, parallel strand bamboo, bamboo-oriented strand board, and bamboo-scrimber have lately been developed and used in structural applications.
{"title":"Mechanical performance evaluation of bamboo fibre reinforced polymer composites and its applications: a review","authors":"N. M. Nurazzi, M. Norrrahim, F. A. Sabaruddin, S. S. Shazleen, R. A. Ilyas, S. Lee, F. N. M. Padzil, G. Aizat, H. A. Aisyah, N. A. Mohidem, M. Asyraf, N. Abdullah, S. M. Sapuan, K. Abdan, N. M. Nor","doi":"10.1088/2631-6331/ac5b1a","DOIUrl":"https://doi.org/10.1088/2631-6331/ac5b1a","url":null,"abstract":"This paper reviews the mechanical performance of bamboo fibre reinforced polymer composites (BFRPs) for structural applications. Bamboo fibres are very promising reinforcements for polymer composites production due to their high aspect ratio, renewability, environmentally friendly, non-toxicity, cheap cost, non-abrasives, full biodegradability, and strong mechanical performances. Besides, bamboo has its own prospects and good potential to be used in biopolymer composites as an alternative for petroleum-based materials to be used in several advanced applications in the building and construction industry. For bamboo fibre to be reinforced with polymer, they must have good interfacial bond between the polymer, as better fibre and matrix interaction results in good interfacial adhesion between fibre/matrix and fewer voids in the composite. Several important factors to improve matrix-fibre bonding and enhance the mechanical properties of BFRP are by fibre treatment, hybridisation, lamination, and using coupling agent. Moreover, mechanical properties of BFRP are greatly influenced by few factors, such as type of fibre and matrix used, fibre-matrix adhesion, fibre dispersion, fibre orientation, composite manufacturing technique used, void content in composites, and porosity of composite. In order to better understand their reinforcing potential, the mechanical properties of this material is critically discussed in this review paper. In addition, the advantages of bamboo fibres as the reinforcing phase in polymer composites is highlighted in this review paper. Besides that, the bamboo-based products such as laminated bamboo lumber, glued-laminated bamboo, hybrid bamboo polymer composites, parallel bamboo strand lumber, parallel strand bamboo, bamboo-oriented strand board, and bamboo-scrimber have lately been developed and used in structural applications.","PeriodicalId":12652,"journal":{"name":"Functional Composites and Structures","volume":" 78","pages":""},"PeriodicalIF":2.8,"publicationDate":"2022-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41255217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-03-03DOI: 10.1088/2631-6331/ac5a5f
Eunjung Kim, D. Jung, Woong‐Ryeol Yu, Wonjin Na
Deterioration of the physical properties of fiber-reinforced composites is inevitable under a high temperature and humidity environment. The resin transfer molding (RTM) process for large composite parts is often accompanied by micropore formation, making the composite more sensitive to water absorption. In this study, carbon fiber-reinforced composite specimens were manufactured using the RTM process at room temperature, and their water absorption and mechanical properties were investigated. The water absorption was saturated after about 40 d, and the absorption ratio was higher at 75 °C than at 50 °C. The tensile strength of water-soaked specimens was decreased by 15%, exhibiting interlaminar delamination. However, plasticization of the cured epoxy resin by water increased interlaminar fracture toughness. These results indicate that water absorption accelerated interlaminar cracking initiated by micropore and interfacial failure in toughened resin, especially under low-temperature curing condition.
{"title":"Influence of water absorption on the mechanical behavior of CFRPs manufactured by RTM at room temperature","authors":"Eunjung Kim, D. Jung, Woong‐Ryeol Yu, Wonjin Na","doi":"10.1088/2631-6331/ac5a5f","DOIUrl":"https://doi.org/10.1088/2631-6331/ac5a5f","url":null,"abstract":"Deterioration of the physical properties of fiber-reinforced composites is inevitable under a high temperature and humidity environment. The resin transfer molding (RTM) process for large composite parts is often accompanied by micropore formation, making the composite more sensitive to water absorption. In this study, carbon fiber-reinforced composite specimens were manufactured using the RTM process at room temperature, and their water absorption and mechanical properties were investigated. The water absorption was saturated after about 40 d, and the absorption ratio was higher at 75 °C than at 50 °C. The tensile strength of water-soaked specimens was decreased by 15%, exhibiting interlaminar delamination. However, plasticization of the cured epoxy resin by water increased interlaminar fracture toughness. These results indicate that water absorption accelerated interlaminar cracking initiated by micropore and interfacial failure in toughened resin, especially under low-temperature curing condition.","PeriodicalId":12652,"journal":{"name":"Functional Composites and Structures","volume":" ","pages":""},"PeriodicalIF":2.8,"publicationDate":"2022-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48129127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-02-24DOI: 10.1088/2631-6331/ac586d
P. Awate, Shivprakash B. Barve
In this research, graphene/Al6061 aluminum matrix nanocomposites were fabricated by stir casting, and the influence of graphene nanoplates on microstructure and mechanical properties of the 6061 aluminum alloy were investigated by field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy, tensile and hardness testing analysis methods. The major limitation in the utilization of 6061 aluminum alloy in heavy stress applications such as airplane fuselages, wings, internal panels, and luxury vehicles chassis is low strength and hardness. This deficiency of 6061 aluminum alloy was tackled by successful reinforcement of graphene nanoplates in 2, 4, 6, 8 and 10 wt.%, using the stir casting process. The FESEM micrographs showed that the graphene nanoplates were uniformly distributed in the 6061-aluminum matrix alloy and tensile strength, hardness, and yield strength enhanced remarkably as compared with unreinforced 6061 aluminum alloy. The as-cast tensile strength, hardness, and yield strength of the graphene/Al6061 nanocomposites were improved by 127%, 158%, and 402%, respectively, compared with the unreinforced Al6061 alloy. It is concluded that the nano thickness of graphene, reinforcement quantity, and manufacturing process are the major factors for the enhancement of microstructure and mechanical properties of graphene/Al6061 nanocomposites.
{"title":"Enhanced microstructure and mechanical properties of Al6061 alloy via graphene nanoplates reinforcement fabricated by stir casting","authors":"P. Awate, Shivprakash B. Barve","doi":"10.1088/2631-6331/ac586d","DOIUrl":"https://doi.org/10.1088/2631-6331/ac586d","url":null,"abstract":"In this research, graphene/Al6061 aluminum matrix nanocomposites were fabricated by stir casting, and the influence of graphene nanoplates on microstructure and mechanical properties of the 6061 aluminum alloy were investigated by field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy, tensile and hardness testing analysis methods. The major limitation in the utilization of 6061 aluminum alloy in heavy stress applications such as airplane fuselages, wings, internal panels, and luxury vehicles chassis is low strength and hardness. This deficiency of 6061 aluminum alloy was tackled by successful reinforcement of graphene nanoplates in 2, 4, 6, 8 and 10 wt.%, using the stir casting process. The FESEM micrographs showed that the graphene nanoplates were uniformly distributed in the 6061-aluminum matrix alloy and tensile strength, hardness, and yield strength enhanced remarkably as compared with unreinforced 6061 aluminum alloy. The as-cast tensile strength, hardness, and yield strength of the graphene/Al6061 nanocomposites were improved by 127%, 158%, and 402%, respectively, compared with the unreinforced Al6061 alloy. It is concluded that the nano thickness of graphene, reinforcement quantity, and manufacturing process are the major factors for the enhancement of microstructure and mechanical properties of graphene/Al6061 nanocomposites.","PeriodicalId":12652,"journal":{"name":"Functional Composites and Structures","volume":" ","pages":""},"PeriodicalIF":2.8,"publicationDate":"2022-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48516667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-02-24DOI: 10.1088/2631-6331/ac586c
Gurpreet Virk, Balkaran Singh, Y. Singh, Shubham Sharma, R. A. Ilyas, Vikas Patyal
Natural-fiber-reinforced composites are progressively attracting interest in the aerospace, automotive, aeronautics, and marine sectors due to their good strength-to-weight ratios, long lifetimes and cost-effectiveness. Traditional machining methods have trouble machining such composite materials. However, abrasive water jet machining (AWJM) provides an alternative quality machining method that can be accomplished by regulating various process variables. The efficiency of the AWJM method has been the subject of extensive study, due to its negligible heat-affected zone. This review attempts to focus on an exploration of the thermal and mechanical properties and the AWJM efficiency of various coir-fiber-based composites in relation to various parameters and to determine the best AWJM operating conditions. There are numerous process variables that influence AWJM machined surface quality. However, the standoff distance, hydraulic pressure, abrasive mass flow rate, nozzle diameter, and transverse speed are all important factors to consider. Kerf taper, kerf width, and surface roughness are considered key response factors.
{"title":"Abrasive water jet machining of coir fiber reinforced epoxy composites: a review","authors":"Gurpreet Virk, Balkaran Singh, Y. Singh, Shubham Sharma, R. A. Ilyas, Vikas Patyal","doi":"10.1088/2631-6331/ac586c","DOIUrl":"https://doi.org/10.1088/2631-6331/ac586c","url":null,"abstract":"Natural-fiber-reinforced composites are progressively attracting interest in the aerospace, automotive, aeronautics, and marine sectors due to their good strength-to-weight ratios, long lifetimes and cost-effectiveness. Traditional machining methods have trouble machining such composite materials. However, abrasive water jet machining (AWJM) provides an alternative quality machining method that can be accomplished by regulating various process variables. The efficiency of the AWJM method has been the subject of extensive study, due to its negligible heat-affected zone. This review attempts to focus on an exploration of the thermal and mechanical properties and the AWJM efficiency of various coir-fiber-based composites in relation to various parameters and to determine the best AWJM operating conditions. There are numerous process variables that influence AWJM machined surface quality. However, the standoff distance, hydraulic pressure, abrasive mass flow rate, nozzle diameter, and transverse speed are all important factors to consider. Kerf taper, kerf width, and surface roughness are considered key response factors.","PeriodicalId":12652,"journal":{"name":"Functional Composites and Structures","volume":" ","pages":""},"PeriodicalIF":2.8,"publicationDate":"2022-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44119614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-02-21DOI: 10.1088/2631-6331/ac5730
I. Yeswanth, K. Jha, S. Bhowmik, Rajeev Kumar, Shubham Sharma, R. Ilyas
The need to develop radar absorbing materials (RAMs) that meet the structural requirement of defense applications is growing swiftly, due to the extensive use of electromagnetic waves in Radar. With the major developments and extensive use of Radar in military applications, the role of Radar absorbing, light weight and high strength structures has become a prime objective for researcher working on the development of RAMs. Various composites have been developed by using reinforcements which are dielectric, such as carbon nanotubes (CNT), magnetic materials like ferrites, that have been extensively used for reinforcement when developing RAMs. Ferromagnetic materials have a high density and can only achieve a narrow bandwidth of absorption. CNT have very good electrical, mechanical and thermal properties and can achieve high dielectric losses but their complex synthesis process is a barrier to commercial applications. Research on reinforcing multi-walled carbon nanotubes (MWCNT) with ferrites and metal oxides can also be extended to the study of thermoplastic polymers like polyether ether ketone and polyaryletherketone, which are gaining prominence in aeronautical applications, owing to their superior mechanical and low moisture absorbing properties. Further research can be carried out on reinforcing metal oxides, as metal oxides, when reinforced with MWCNT enhance the dielectric properties which improve the reflection losses as reported in a few studies.
{"title":"Recent developments in RAM based MWCNT composite materials: a short review","authors":"I. Yeswanth, K. Jha, S. Bhowmik, Rajeev Kumar, Shubham Sharma, R. Ilyas","doi":"10.1088/2631-6331/ac5730","DOIUrl":"https://doi.org/10.1088/2631-6331/ac5730","url":null,"abstract":"The need to develop radar absorbing materials (RAMs) that meet the structural requirement of defense applications is growing swiftly, due to the extensive use of electromagnetic waves in Radar. With the major developments and extensive use of Radar in military applications, the role of Radar absorbing, light weight and high strength structures has become a prime objective for researcher working on the development of RAMs. Various composites have been developed by using reinforcements which are dielectric, such as carbon nanotubes (CNT), magnetic materials like ferrites, that have been extensively used for reinforcement when developing RAMs. Ferromagnetic materials have a high density and can only achieve a narrow bandwidth of absorption. CNT have very good electrical, mechanical and thermal properties and can achieve high dielectric losses but their complex synthesis process is a barrier to commercial applications. Research on reinforcing multi-walled carbon nanotubes (MWCNT) with ferrites and metal oxides can also be extended to the study of thermoplastic polymers like polyether ether ketone and polyaryletherketone, which are gaining prominence in aeronautical applications, owing to their superior mechanical and low moisture absorbing properties. Further research can be carried out on reinforcing metal oxides, as metal oxides, when reinforced with MWCNT enhance the dielectric properties which improve the reflection losses as reported in a few studies.","PeriodicalId":12652,"journal":{"name":"Functional Composites and Structures","volume":"4 1","pages":""},"PeriodicalIF":2.8,"publicationDate":"2022-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"61184416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-02-11DOI: 10.1088/2631-6331/ac5466
A. A. Alabi, B. Samuel, Maiwada Elisha Peter, S. M. Tahir
The chemical treatment of natural fibres for its surface modification for the development of polymer composites is popular but it comes with an adverse effect of a chemical change of the fibres. In this study, the surface modification of natural fibres (doum palm nut (DPN) fibres) with low-temperature heat treatment (30 °C–75 °C) has been reported as an alternative method to the treatment of natural fibres for the development of polymer composites. Taguchi method of the design of experiment was employed to determine the effect of temperature and fibre content on the mechanical properties (hardness and fracture toughness) of DPN fibre-reinforced phenolic resin polymer composite. The process showed that the best combination of fibre content and fibre treatment temperature for optimum hardness and fracture toughness and results proved to be at 5% and 75 °C respectively. Statistical analysis established the significance of heat treatment in improving the fracture toughness of DPN fibre reinforced phenolic resin composites. Physical observation with scanning electron microscope and Fourier-transform infrared spectroscopy confirmed the improvement in interfacial bonding between the fibre and the matrix with the increase in fibre treatment temperature without a change in the chemical properties of the treated fibres. The study concludes that the treatment of fibres with temperature is an alternative and effective method to the chemical treatment.
{"title":"Optimization and modelling of the fracture inhibition potential of heat treated doum palm nut fibres in phenolic resin matrix polymer composite: a Taguchi approach","authors":"A. A. Alabi, B. Samuel, Maiwada Elisha Peter, S. M. Tahir","doi":"10.1088/2631-6331/ac5466","DOIUrl":"https://doi.org/10.1088/2631-6331/ac5466","url":null,"abstract":"The chemical treatment of natural fibres for its surface modification for the development of polymer composites is popular but it comes with an adverse effect of a chemical change of the fibres. In this study, the surface modification of natural fibres (doum palm nut (DPN) fibres) with low-temperature heat treatment (30 °C–75 °C) has been reported as an alternative method to the treatment of natural fibres for the development of polymer composites. Taguchi method of the design of experiment was employed to determine the effect of temperature and fibre content on the mechanical properties (hardness and fracture toughness) of DPN fibre-reinforced phenolic resin polymer composite. The process showed that the best combination of fibre content and fibre treatment temperature for optimum hardness and fracture toughness and results proved to be at 5% and 75 °C respectively. Statistical analysis established the significance of heat treatment in improving the fracture toughness of DPN fibre reinforced phenolic resin composites. Physical observation with scanning electron microscope and Fourier-transform infrared spectroscopy confirmed the improvement in interfacial bonding between the fibre and the matrix with the increase in fibre treatment temperature without a change in the chemical properties of the treated fibres. The study concludes that the treatment of fibres with temperature is an alternative and effective method to the chemical treatment.","PeriodicalId":12652,"journal":{"name":"Functional Composites and Structures","volume":" ","pages":""},"PeriodicalIF":2.8,"publicationDate":"2022-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43093868","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-02-07DOI: 10.1088/2631-6331/ac529e
J. Cha, S. Yoon
This study presents the way to determine the shift factor for predicting the long-term behavior of a carbon fiber/epoxy composite using the time-temperature superposition (TTS) principle. We conducted the multi-frequency, creep TTS, and stress relaxation TTS tests and obtained the dynamic mechanical analysis responses such as the storage modulus, creep compliance, and relaxation modulus. A shift factor determining the data movement is essential in creating the master curves. The shift factor was estimated using several methods such as the Arrhenius equation, William–Landel–Ferry equation, and manual shift method. The change in viscoelastic properties over a wide range of time was investigated by comparing the master curves to determine the most rational approach for estimating the shift factor. The master curves were obtained from the three methods based on the storage modulus. For the Arrhenius equation, the smooth master curves could not be obtained when applying a constant activation energy value. Still, using two activation energy values for the carbon fiber reinforced composite, the smooth master curves could be obtained. However, the manual shift method could get the master curves that overlap smoothly in the creep TTS and stress relaxation TTS, even without calculating activation energy values. Since the proposed procedure can estimate the long-term viscoelastic properties reasonably, the life span of the structure can be predicted at the design stage by using the master curves considering the viscoelastic properties.
{"title":"Determination of shift factor for long-term life prediction of carbon/fiber epoxy composites using the time-temperature superposition principle","authors":"J. Cha, S. Yoon","doi":"10.1088/2631-6331/ac529e","DOIUrl":"https://doi.org/10.1088/2631-6331/ac529e","url":null,"abstract":"This study presents the way to determine the shift factor for predicting the long-term behavior of a carbon fiber/epoxy composite using the time-temperature superposition (TTS) principle. We conducted the multi-frequency, creep TTS, and stress relaxation TTS tests and obtained the dynamic mechanical analysis responses such as the storage modulus, creep compliance, and relaxation modulus. A shift factor determining the data movement is essential in creating the master curves. The shift factor was estimated using several methods such as the Arrhenius equation, William–Landel–Ferry equation, and manual shift method. The change in viscoelastic properties over a wide range of time was investigated by comparing the master curves to determine the most rational approach for estimating the shift factor. The master curves were obtained from the three methods based on the storage modulus. For the Arrhenius equation, the smooth master curves could not be obtained when applying a constant activation energy value. Still, using two activation energy values for the carbon fiber reinforced composite, the smooth master curves could be obtained. However, the manual shift method could get the master curves that overlap smoothly in the creep TTS and stress relaxation TTS, even without calculating activation energy values. Since the proposed procedure can estimate the long-term viscoelastic properties reasonably, the life span of the structure can be predicted at the design stage by using the master curves considering the viscoelastic properties.","PeriodicalId":12652,"journal":{"name":"Functional Composites and Structures","volume":" ","pages":""},"PeriodicalIF":2.8,"publicationDate":"2022-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44705384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-22DOI: 10.1088/2631-6331/ac4de9
Niranjanmurthi Lingappan, Sungmook Lim, Guk-Hwan Lee, Huynh Thanh Tung, Van Hoang Luan, Wonoh Lee
Engineering the conventional electrode designs as well as exploring prospective materials and prominent electrolytes, all of which are critically required to tackle the fundamental limitations associated with the current sustainable energy technologies. Structural supercapacitors (SSCs) have recently emerged as next-generation energy storage and conversion devices by virtue of their abilities to store the electrochemical energy whilst sustain high mechanical loads simultaneously. Composite materials as well as electrolytes with multifunctional characteristics, especially outstanding electrical/ionic conductivities and high mechanical robustness represent the key requirements to realize such exemplary multifunctional devices. In this review, we provide an overview, structural design, and the recent progress of the SSCs devices enabled by various carbon fiber-reinforced composites electrodes. Special emphases are given to the assessment on the significance of solid polymer electrolytes and their composites in SSCs. Finally, we conclude with feasible applications of the SSCs and outline the challenges that still need to be addressed for deploying high-performance SSCs for practical applications.
{"title":"Recent advances on fiber-reinforced multifunctional composites for structural supercapacitors","authors":"Niranjanmurthi Lingappan, Sungmook Lim, Guk-Hwan Lee, Huynh Thanh Tung, Van Hoang Luan, Wonoh Lee","doi":"10.1088/2631-6331/ac4de9","DOIUrl":"https://doi.org/10.1088/2631-6331/ac4de9","url":null,"abstract":"Engineering the conventional electrode designs as well as exploring prospective materials and prominent electrolytes, all of which are critically required to tackle the fundamental limitations associated with the current sustainable energy technologies. Structural supercapacitors (SSCs) have recently emerged as next-generation energy storage and conversion devices by virtue of their abilities to store the electrochemical energy whilst sustain high mechanical loads simultaneously. Composite materials as well as electrolytes with multifunctional characteristics, especially outstanding electrical/ionic conductivities and high mechanical robustness represent the key requirements to realize such exemplary multifunctional devices. In this review, we provide an overview, structural design, and the recent progress of the SSCs devices enabled by various carbon fiber-reinforced composites electrodes. Special emphases are given to the assessment on the significance of solid polymer electrolytes and their composites in SSCs. Finally, we conclude with feasible applications of the SSCs and outline the challenges that still need to be addressed for deploying high-performance SSCs for practical applications.","PeriodicalId":12652,"journal":{"name":"Functional Composites and Structures","volume":" ","pages":""},"PeriodicalIF":2.8,"publicationDate":"2022-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45248175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-11DOI: 10.1088/2631-6331/ac49f3
Siddesh Kumar N M, C. S, Talluri Nikhil, Dhruthi
An enormous amount of research has been conducted on aluminium alloys in friction stir processing (FSP), despite magnesium alloys reporting severe weight reduction when compared to aluminium alloys; a very slight amount of research has testified for FSP of magnesium alloys. Magnesium is highly reactive and susceptible to corrosion in the presence of an aggressive environment. This highly corrosive nature of magnesium limits its applications. Surface properties like crystal structure, composition, and microstructure influence the corrosion and wear properties of the material. Coating techniques and alloying techniques like laser surface modifications are performed to passivate the magnesium surface from corrosion. Coating techniques, however, have been found to be insufficient in corrosion protection due to coating defects like pores, cracks, etc, adhesion problems due to poor surface preparation of the substrate, and impurities present in the coating which provide microgalvanic cells for corrosion. The current study gives a detailed overview of different types of surface modification methods, such as physical vapour deposition, chemical vapour deposition, chemical conversion coating, and ion implantation coating techniques, and also focuses on a few alloying or surface processing methods, such as laser surface modification – namely laser surface melting, laser surface cladding, laser shot peening, laser surface alloying and FSP. FSP is a novel surface modification method derived from friction stir welding, which modifies the microstructure and composition of surface layer without changing the bulk properties to enhance corrosion resistance. FSP enhances and homogenizes the microstructure but also eliminates the breakup of the brittle-network phases and cast microstructure imperfections. Indeed, FSP can produce particle and fibre-reinforced magnesium-based surface composites. FSP empowers the manufacturing of magnesium by adding additives. The different methods of coating and surface modification are compared with FSP.
{"title":"A review on friction stir processing over other surface modification processing techniques of magnesium alloys","authors":"Siddesh Kumar N M, C. S, Talluri Nikhil, Dhruthi","doi":"10.1088/2631-6331/ac49f3","DOIUrl":"https://doi.org/10.1088/2631-6331/ac49f3","url":null,"abstract":"An enormous amount of research has been conducted on aluminium alloys in friction stir processing (FSP), despite magnesium alloys reporting severe weight reduction when compared to aluminium alloys; a very slight amount of research has testified for FSP of magnesium alloys. Magnesium is highly reactive and susceptible to corrosion in the presence of an aggressive environment. This highly corrosive nature of magnesium limits its applications. Surface properties like crystal structure, composition, and microstructure influence the corrosion and wear properties of the material. Coating techniques and alloying techniques like laser surface modifications are performed to passivate the magnesium surface from corrosion. Coating techniques, however, have been found to be insufficient in corrosion protection due to coating defects like pores, cracks, etc, adhesion problems due to poor surface preparation of the substrate, and impurities present in the coating which provide microgalvanic cells for corrosion. The current study gives a detailed overview of different types of surface modification methods, such as physical vapour deposition, chemical vapour deposition, chemical conversion coating, and ion implantation coating techniques, and also focuses on a few alloying or surface processing methods, such as laser surface modification – namely laser surface melting, laser surface cladding, laser shot peening, laser surface alloying and FSP. FSP is a novel surface modification method derived from friction stir welding, which modifies the microstructure and composition of surface layer without changing the bulk properties to enhance corrosion resistance. FSP enhances and homogenizes the microstructure but also eliminates the breakup of the brittle-network phases and cast microstructure imperfections. Indeed, FSP can produce particle and fibre-reinforced magnesium-based surface composites. FSP empowers the manufacturing of magnesium by adding additives. The different methods of coating and surface modification are compared with FSP.","PeriodicalId":12652,"journal":{"name":"Functional Composites and Structures","volume":" ","pages":""},"PeriodicalIF":2.8,"publicationDate":"2022-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46441661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-01DOI: 10.1088/2631-6331/ac5d27
D. Komaraiah, Eppa Radha, J. Sivakumar, R. Sayanna
The spin coating process has been used to deposit pure and Fe3+ doped brookite titania films onto glass substrates. In essence, such as films annealed at 500 °C are found to be orthorhombic crystal structure with brookite phase. X-ray diffractometer measurements revealed that Fe ions are incorporated into cation sites of TiO2. The crystallite size reduces with the doping of Fe3+ ions. The scanning electron microscope images show highly uniform, crack free films and the particles size is found to be within the range of 150–200 nm. Energy-dispersive x-ray spectroscopy analysis Fe3+ doped TiO2 films confirmed good stoichiometry of chemical compositions. The Raman spectra of brookite TiO2 exhibit a very strong characteristic band at 153cm−1. The optical band gap was found to be declined from 3.08 eV to 2.54 eV with adding the Fe ions into TiO2 matrix. The EPR studies approve incorporation of Fe3+ in the crystal lattice of brookite by substituting Ti4+ and generation of defects, and Ti3+ states. Photocatalytic ability of films has been studied by degradation of methyl orange solution under illumination of visible light. The 7% Fe doped brookite film was exhibited high catalytic activity compared to other pure and doped films.
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