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Potassium isotopic evidence for the petrogenesis of Precambrian granitoids and implications for early crustal evolution of the accretionary orogen 前寒武纪花岗岩类岩石成因的钾同位素证据及其对增生造山带早期地壳演化的意义
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-19 DOI: 10.1016/j.gsf.2025.102239
Xinyu Long , Wenliang Xu , Feng Wang , Chenyang Sun , Jie Tang
Stable potassium (K) isotopes are emerging as a novel geochemical tracer for investigating magmatic differentiation and source characteristics. This study presents the K isotopic analyses of Neoarchean–Paleoproterozoic granitoids from the Xing’an Massif, a key microcontinent within the eastern Central Asian Orogenic Belt (CAOB), providing new insights into the granitoid petrogenesis and early crustal evolution of this accretionary orogen. The 2568 Ma peraluminous A-type monzogranite exhibits significantly heavier δ41K values (−0.22‰ to −0.05‰) compared to the range of the upper continental crust. Subduction zones can effectively transfer heavy K isotopic signature to the mantle wedge through slab-derived fluids/melts. The monzogranite could be formed through co-melting and mixing of previously metasomatized mantle materials and recycled supracrustal metapelites, followed by high degree of fractional crystallization in a post-collisional extensional setting. Although both the 1881 Ma monzogranite and 1843 Ma syenogranite share geochemical affinities with adakites, their markedly different K isotopic compositions and distinct geochemical fingerprints point to substantial heterogeneity within their source regions. The 1881 Ma monzogranite shows more pronounced heavy K isotopic enrichment (δ41K = −0.39‰ to −0.18‰) and elevated zircon δ18O values (7.28‰–8.93‰). These features demonstrate the incorporation of mantle components metasomatized by melts of altered oceanic crust (with elevated δ41K values) into the lower crustal source. In contrast, the 1843 Ma syenogranite displays ultrapotassic affinity with lighter K isotopic compositions (δ41K = −0.45‰ to −0.38‰) and strongly negative zircon εHf(t) values (−11.5 to −10.2), indicating a thickened lower crustal source with contributions from ancient supracrustal sediments. Collectively, K isotopic compositions of the ca. 1.8 Ga adakitic granitoids overcome the limitations of traditional geochemical and isotopic proxies in revealing the complex granite petrogenesis, and they potentially provide evidence for a cycle of plate tectonics, from oceanic crust alteration at mid-ocean ridges through slab subduction to continental collision. The onset of plate tectonics promoted remelting of Archean igneous and sedimentary crust, generating abundant peraluminous and potassic granitoids during the late Archean to Paleoproterozoic and driving crustal compositional maturation in this accretionary orogen.
稳定钾同位素作为一种新的地球化学示踪剂,正逐渐成为研究岩浆分异和来源特征的重要手段。本文对中亚造山带东部重要微大陆——兴安地块新太古代-古元古代花岗岩进行了钾同位素分析,为该增生造山带的花岗岩成因和早期地壳演化提供了新的认识。2568 Ma过铝a型二长花岗岩的δ41K值明显高于上陆地壳(- 0.22‰~ - 0.05‰)。俯冲带可以通过板块衍生的流体/熔体有效地将重K同位素特征转移到地幔楔上。二长花岗岩可能是在前交代的地幔物质与再循环的壳上变质岩共融混合后,在碰撞后的伸展环境中发生了高度的分离结晶作用。尽管1881 Ma二长花岗岩和1843 Ma正长花岗岩与埃达岩具有地球化学上的相似性,但它们明显不同的钾同位素组成和不同的地球化学指纹表明它们的来源区域具有明显的非均质性。1881 Ma二长花岗岩重K同位素富集(δ41K = - 0.39‰~ - 0.18‰),锆石δ18O值升高(7.28‰~ 8.93‰)。这些特征表明,变质洋壳(δ41K值升高)熔体交代的地幔成分被纳入下地壳源。而1843 Ma正长花岗岩则表现出较轻的K同位素(δ41K = - 0.45‰~ - 0.38‰)和较强的负锆石εHf(t)值(- 11.5 ~ - 10.2)的超古典亲和性,表明下地壳源区增厚,并有古表壳上沉积物的贡献。总的来说,约1.8 Ga阿达克岩花岗岩的钾同位素组成克服了传统地球化学和同位素指标在揭示复杂花岗岩岩石成因方面的局限性,并可能为板块构造循环提供证据,从洋中脊的洋壳蚀变到板块俯冲再到大陆碰撞。板块构造的发生促进了太古宙火成岩和沉积地壳的重熔,在晚太古宙至古元古代形成了丰富的过铝质和钾质花岗岩,推动了该增生造山带地壳成分的成熟。
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引用次数: 0
Multi-task deep transfer learning for complicated seismic dynamic response prediction in slope systems 斜坡系统复杂地震动力响应预测的多任务深度迁移学习
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-13 DOI: 10.1016/j.gsf.2025.102238
Xu Han , Yu Huang , Xiaoyan Jin , Liuyuan Zhao , Chung Yee Kwok
Slope engineering is an uncertain, dynamic, and complex nonlinear spatiotemporal system with time delays. High-fidelity prediction of slope seismic stability has long been a formidable challenge due to the inherent randomness and uncertainty associated with ground motion, geo-material properties, complex topography, etc. Traditional numerical modelling always takes a simplified model by forcedly ignoring those uncertainties, thus failing to replicate precisely the intricate nonlinear interactions between factors that affect slope instability. Notably, the newly emerging deep learning methods have the capability of handling multiple factors with uncertainties. However, these methods heavily rely on extensive and comprehensive sensor data, while arranging sensors at certain important positions is sometimes unachievable. Therefore, we propose a multi-task deep transfer learning (MT-DTL) framework in this study to enhance the prediction accuracy of slope seismic response especially in data-limited conditions. The dynamic response at the locations without sufficient accessible sensor data can be effectively predicted with a newly developed algorithm. To collect the necessary sensor data, we conduct a series of physics experiments with the world’s largest multifunctional shaking table equipment. We demonstrate the efficacy and accuracy of our approach on the shaking-table datasets through comparisons with traditional machine learning (ML) methods. Our findings reveal that the MT-DTL framework can improve the confidence level of prediction results (within 5%) from the highest 86.4% by the optimal traditional ML methods to 92.7%, achieving comparable results with two-thirds fewer data. Additionally, a single response example showed that the trained deep transfer learning model has significantly improved the computational efficiency (0.018 – 0.019 s) compared to the dynamic finite element calculation with GeoStudio (10 min). This highlights its potential for integration into geo-hazards digital twin systems, facilitating rapid risk analysis based on real-time monitoring data.
边坡工程是一个不确定的、动态的、复杂的、具有时滞的非线性时空系统。由于地面运动、地质材料性质、复杂地形等因素的随机性和不确定性,边坡地震稳定性的高保真预测一直是一项艰巨的挑战。传统的数值模拟总是采用简化的模型,强行忽略了这些不确定性因素,从而无法精确地复制影响边坡失稳因素之间复杂的非线性相互作用。值得注意的是,新兴的深度学习方法具有处理多个不确定因素的能力。然而,这些方法严重依赖于广泛而全面的传感器数据,而在某些重要位置布置传感器有时是无法实现的。因此,本研究提出了一个多任务深度迁移学习(MT-DTL)框架,以提高边坡地震反应的预测精度,特别是在数据有限的条件下。本文提出的一种新算法可以有效地预测传感器数据不足位置的动态响应。为了收集必要的传感器数据,我们使用世界上最大的多功能振动台设备进行了一系列物理实验。通过与传统机器学习(ML)方法的比较,我们证明了我们的方法在振动台数据集上的有效性和准确性。我们的研究结果表明,MT-DTL框架可以将预测结果的置信度(5%以内)从最优传统ML方法的最高86.4%提高到92.7%,在减少三分之二数据的情况下获得可比结果。此外,单个响应示例表明,与GeoStudio动态有限元计算(10 min)相比,训练后的深度迁移学习模型的计算效率显著提高(0.018 - 0.019 s)。这突出了它与地质灾害数字孪生系统集成的潜力,促进了基于实时监测数据的快速风险分析。
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引用次数: 0
Fine characterization of micro-nano fractures and analysis of network connectivity: Mechanistic controls on hydrocarbon enrichment in shale reservoirs 微纳裂缝精细表征及网络连通性分析:页岩储层油气富集的机理控制
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-09 DOI: 10.1016/j.gsf.2025.102233
Boyang Wang , Dengfu Yuan , Jingjing Li , Shichao Li , Fei Xiao , Shansi Tian , Mengjing Yin , Jianguo Yang
Micro-nano fractures serve as the bridge connecting nanopores and macro-fractures. The unclear understanding of their developmental characteristics and controlling factors significantly hinders the large-scale, efficient development of continental shale oil. To address this, this study employs the entropy weight method to establish an evaluation model for fracture development strength that comprehensively considers fracture number, average width, areal density, and areal porosity. Additionally, topology is introduced to evaluate fracture connectivity. The research clarifies the differences in micro-nano fracture developmental characteristics and primary controlling factors among different lithofacies and elucidates the impact of micro-nano fracture development on pore structure and hydrocarbon accumulation in Gulong shale. The results indicate that the HQS (high-organic laminated felsic shale) lithofacies exhibits high micro-nano fracture development strength and connectivity, yielding the highest comprehensive evaluation index. The HCS (high-organic laminated mixed shale) shows high development strength but low connectivity, resulting in a secondary comprehensive evaluation index. Higher organic matter content correlates with greater fracture development strength; clay mineral content controls the characteristics of nano-fracture development; felsic mineral content positively influences fracture connectivity. The development of micro-nano fractures not only enhances macropore content and average pore size but also effectively connects pores of various scales, increasing the effectiveness of the pore-fracture system. Lithofacies with low fracture connectivity (primarily HCS) exhibit more complex pore structures. Shale oil in such lithofacies mainly accumulates via a self-sealing model, making it difficult to form complex fracture networks during hydraulic fracturing and hindering efficient development. Conversely, the HQS lithofacies demonstrates optimal pore-fracture connectivity, favorable oil content, and represents the most favorable lithofacies for Gulong shale oil development. These findings contribute to the optimization of sweet-spot intervals for shale oil exploration in the study area.
微纳裂缝是连接纳米孔和宏观裂缝的桥梁。对陆相页岩油的发育特征和控制因素认识不清,严重阻碍了陆相页岩油的大规模高效开发。针对这一问题,本文采用熵权法建立了综合考虑裂缝数、平均宽度、面密度、面孔隙度的裂缝发育强度评价模型。此外,还引入了拓扑学来评估裂缝连通性。研究明确了不同岩相间微纳裂缝发育特征的差异及主控因素,阐明了微纳裂缝发育对古龙页岩孔隙结构和油气成藏的影响。结果表明,HQS(高有机质层状长英质页岩)岩相具有较高的微纳裂缝发育强度和连通性,综合评价指标最高。高有机质层状混合页岩发育强度高,但连通性低,形成二级综合评价指标。有机质含量越高,裂缝发育强度越大;黏土矿物含量控制着纳米裂缝发育特征;长硅矿物含量正影响裂缝连通性。微纳裂缝的发育不仅提高了大孔隙含量和平均孔径,而且有效连接了不同尺度的孔隙,提高了孔隙-裂缝系统的有效性。裂缝连通性低的岩相(主要是HCS)孔隙结构更为复杂。该岩相页岩油主要以自封闭模式聚集,水力压裂时难以形成复杂的裂缝网络,阻碍了高效开发。相反,HQS岩相孔缝连通性最佳,含油量有利,是古龙页岩油开发的最有利岩相。研究结果为研究区页岩油甜点层段的优选提供了理论依据。
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引用次数: 0
Probabilistic quantification of global drought risk amplification from temperature-enhanced evapotranspiration under climate change 气候变化下温度增强蒸散发对全球干旱风险放大的概率量化
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-08 DOI: 10.1016/j.gsf.2025.102235
Akinwale T. Ogunrinde , Paul Adigun , Xian Xue , Koji Dairaku , Sabab Ali Shah , Ifeoluwa S. Adawa
Droughts pose escalating threats to global water security, agriculture, and socioeconomic stability amid anthropogenic climate change, with projections indicating an increase in frequency, duration, and severity driven by altered precipitation patterns and amplified evaporative demand. This study introduces a probabilistic framework to quantify drought risk amplification, employing the Risk Ratio (RR) methodology integrated with extreme value theory and non-parametric inference. Utilizing multi-model ensemble (MME) from the Coupled Model Intercomparison Project Phase 6 (CMIP6) under Shared Socioeconomic Pathways (SSP2-4.5 and SSP5-8.5), we evaluate changes in drought characteristics—duration, frequency, and severity — via the Standardized Precipitation Evapotranspiration Index (SPEI) at 3- and 12-month timescales for near-future (NF) and far-future (FF) periods. Our analyses reveal pervasive global intensification, with over 90% of land grids exhibiting positive severity shifts under SSP5-8.5 in the FF, attributed to atmospheric evaporative demand, which accounts for approximately 44% of the trends in SPEI. Threshold-stratified RR assessments reveal nonlinear escalations at higher percentiles (P90 vs. P75), compressing the return periods of extreme events by 20%–30% under high-emission scenarios. Regional hotspots, including the Amazon basin, sub-Saharan Africa, southwestern North America, and Central Asian drylands, exhibit frequency risks that are 4-fold or more amplified, signaling transitions to chronic water stress and potential ecosystem tipping points. These findings underscore the dominance of thermodynamic drivers in drought dynamics, advocating for emissions mitigation to curtail risks by 15%–25% under moderate pathways. By addressing uncertainties in non-stationary regimes, this framework provides adaptive strategies for resilient water management, offering policymakers critical insights to mitigate cascading impacts on global food security and biodiversity in a warming world.
在人为气候变化的背景下,干旱对全球水安全、农业和社会经济稳定构成的威胁不断升级,预测表明,由于降水模式的改变和蒸发需求的扩大,干旱的频率、持续时间和严重程度都会增加。本文采用风险比(RR)方法,结合极值理论和非参数推理,提出了干旱风险放大量化的概率框架。利用共享社会经济路径(SSP2-4.5和SSP5-8.5)下的耦合模式比对项目第6阶段(CMIP6)的多模式集成(MME),通过标准化降水蒸散指数(SPEI)在近未来(NF)和远未来(FF)时期的3个月和12个月时间尺度上评估了干旱特征的变化——持续时间、频率和严重程度。我们的分析揭示了普遍的全球强化,超过90%的陆地网格在FF的SSP5-8.5下表现出正的严重变化,这归因于大气蒸发需求,这占SPEI趋势的约44%。阈值分层RR评估显示,在高排放情景下,较高百分位数(P90 vs P75)的非线性上升,将极端事件的重现期压缩了20%-30%。包括亚马逊盆地、撒哈拉以南非洲、北美西南部和中亚旱地在内的区域热点地区,呈现出4倍或更多的频率风险,标志着向慢性水压力和潜在生态系统临界点的转变。这些发现强调了干旱动力学中热力学驱动因素的主导地位,主张在适度途径下减少排放,将风险降低15%-25%。通过解决非平稳机制中的不确定性,该框架为弹性水管理提供了适应性战略,为政策制定者提供了关键见解,以减轻全球变暖对全球粮食安全和生物多样性的连锁影响。
{"title":"Probabilistic quantification of global drought risk amplification from temperature-enhanced evapotranspiration under climate change","authors":"Akinwale T. Ogunrinde ,&nbsp;Paul Adigun ,&nbsp;Xian Xue ,&nbsp;Koji Dairaku ,&nbsp;Sabab Ali Shah ,&nbsp;Ifeoluwa S. Adawa","doi":"10.1016/j.gsf.2025.102235","DOIUrl":"10.1016/j.gsf.2025.102235","url":null,"abstract":"<div><div>Droughts pose escalating threats to global water security, agriculture, and socioeconomic stability amid anthropogenic climate change, with projections indicating an increase in frequency, duration, and severity driven by altered precipitation patterns and amplified evaporative demand. This study introduces a probabilistic framework to quantify drought risk amplification, employing the Risk Ratio (RR) methodology integrated with extreme value theory and non-parametric inference. Utilizing multi-model ensemble (MME) from the Coupled Model Intercomparison Project Phase 6 (CMIP6) under Shared Socioeconomic Pathways (SSP2-4.5 and SSP5-8.5), we evaluate changes in drought characteristics—duration, frequency, and severity — via the Standardized Precipitation Evapotranspiration Index (SPEI) at 3- and 12-month timescales for near-future (NF) and far-future (FF) periods. Our analyses reveal pervasive global intensification, with over 90% of land grids exhibiting positive severity shifts under SSP5-8.5 in the FF, attributed to atmospheric evaporative demand, which accounts for approximately 44% of the trends in SPEI. Threshold-stratified RR assessments reveal nonlinear escalations at higher percentiles (P90 vs. P75), compressing the return periods of extreme events by 20%–30% under high-emission scenarios. Regional hotspots, including the Amazon basin, sub-Saharan Africa, southwestern North America, and Central Asian drylands, exhibit frequency risks that are 4-fold or more amplified, signaling transitions to chronic water stress and potential ecosystem tipping points. These findings underscore the dominance of thermodynamic drivers in drought dynamics, advocating for emissions mitigation to curtail risks by 15%–25% under moderate pathways. By addressing uncertainties in non-stationary regimes, this framework provides adaptive strategies for resilient water management, offering policymakers critical insights to mitigate cascading impacts on global food security and biodiversity in a warming world.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"17 2","pages":"Article 102235"},"PeriodicalIF":8.9,"publicationDate":"2025-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145797652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
First observation of coexisting crystalline and amorphous mineral phases in the Bhawad LL6 chondrite: Evidence from Micro-Raman spectroscopic studies 在Bhawad LL6球粒陨石中首次观察到共存的晶体和非晶矿物相:来自微拉曼光谱研究的证据
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-08 DOI: 10.1016/j.gsf.2025.102236
Bhaskar J. Saikia , G. Parthasarathy , Binoy K. Saikia , Puja Bordoloi , Rashmi R. Borah
We report here for the first time the detailed spectroscopic investigations on Bhawad meteorite using micro-Raman spectroscopic and high-resolution transmission electron microscopy (HR-TEM) investigation of the Bhawad LL6 ordinary chondrite, focusing on its mineralogical composition and carbonaceous phases. Raman spectroscopy reveals crystalline silicates including olivine, pyroxene, and plagioclase, along with accessory chromite containing ≤20% of Al. Carbonaceous material exhibits broad ID (∼1336 cm−1) and IG (∼1587 cm−1) bands with an ID/IG ratio of ∼1.04, indicative of disordered graphite and nanocrystalline carbon, reflecting shock-induced metamorphism. High-pressure TiO2 polymorphs are identified by characteristic Raman modes at 146, 394, 446, and 610 cm−1. HR-TEM imaging confirms the presence of nanocrystalline TiO2 particles embedded within amorphous carbonaceous matrices, demonstrating the coexistence of crystalline and amorphous phases. The Raman spectra of the Bhawad meteorite reveal the presence of high-temperature plagioclase phases, characterized by these distinct vibrational features. This observation indicates possible quenching of the melts having feldspar components, representing the complex thermal and shock metamorphic history of the meteorite. This coexistence of crystalline and amorphous phases highlights the complex thermal and shock history of the Bhawad meteorite, revealing insights into phase transitions and structural order–disorder phase transition induced by impact processes.
本文首次利用微拉曼光谱和高分辨率透射电镜(hrtem)对Bhawad LL6普通球粒陨石进行了详细的光谱研究,重点研究了其矿物组成和碳质相。拉曼光谱显示,晶体硅酸盐包括橄榄石、辉石和斜长石,以及含铝量≤20%的铬铁矿。碳质材料显示出宽ID (~ 1336 cm−1)和IG (~ 1587 cm−1)波段,ID/IG比值为~ 1.04,表明无序石墨和纳米晶碳,反映了冲击诱发的变质作用。在146、394、446和610 cm−1处,通过特征拉曼模式鉴定出了高压TiO2多晶。HR-TEM成像证实了纳米晶TiO2颗粒嵌入在非晶碳质基体中,证明了晶相和非晶相共存。Bhawad陨石的拉曼光谱揭示了高温斜长石相的存在,其特征是这些明显的振动特征。这一观察结果表明,含有长石成分的熔体可能被淬火,代表了陨石复杂的热变质和冲击变质历史。这种晶体和非晶相的共存突出了Bhawad陨石复杂的热历史和冲击历史,揭示了由撞击过程引起的相变和结构有序-无序相变的见解。
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引用次数: 0
Physics-informed dictionary learning of time-varying 3D settlements from sparse monitoring data and 2D numerical models with consideration of complex stratigraphy 基于稀疏监测数据和考虑复杂地层的二维数值模型的时变三维沉降的物理字典学习
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-02 DOI: 10.1016/j.gsf.2025.102222
Dan-Ni Zhang , Hua-Ming Tian , Yu Wang , Chao Shi , Kostas Senetakis
Digital twins of geotechnical structures replicate their physical counterparts, such as underground spaces developed from land reclamations. These spaces often exhibit intricate three-dimensional (3D) stratigraphic distributions, including irregular and interbedded soil layers. Developing a virtual 3D model, such as finite element model (FEM), with complex stratigraphy poses significant computational challenges due to the necessity for numerous stratum voxels, high-resolution meshing, and prohibitive analysis times. Incorporating field settlement data for model updating escalates the computational burden, as repeated evaluations of 3D FEM models are required for each model updating. To address this challenge, this study develops a novel approach for efficiently predicting time-varying 3D settlement from two-dimensional (2D) numerical models with sparsely measured monitoring data. Settlements from 2D FEM analyses, which account for complex stratigraphy, are compiled within a dictionary learning framework and combined with limited monitoring data to estimate time-varying settlements at multiple 2D cross-sections. The 2D settlements are then utilized to reconstruct high-resolution 3D settlements through 3D compressive sampling (3D-CS), eliminating a need for additional numerical model evaluations when integrating new monitoring data. The proposed approach is illustrated using a reclamation project in Hong Kong, China.
岩土工程结构的数字双胞胎复制了它们的物理对应物,例如从土地复垦中开发的地下空间。这些空间通常呈现复杂的三维(3D)地层分布,包括不规则和互层的土层。由于需要大量的地层体素、高分辨率网格划分和令人望而却步的分析时间,开发具有复杂地层的虚拟3D模型(如有限元模型(FEM))带来了巨大的计算挑战。采用现场沉降数据进行模型更新会增加计算量,因为每次更新模型都需要对三维有限元模型进行重复评估。为了解决这一挑战,本研究开发了一种新的方法,可以通过稀疏测量的监测数据从二维(2D)数值模型有效地预测时变的3D沉降。二维有限元沉降分析解释了复杂的地层,在字典学习框架内编制,并结合有限的监测数据来估计多个二维截面上随时间变化的沉降。然后利用2D沉降,通过3D压缩采样(3D- cs)重建高分辨率3D沉降,在整合新的监测数据时无需额外的数值模型评估。以中国香港的一个填海工程为例,说明建议的方法。
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引用次数: 0
Fast production of large lithologic maps using lithologic sample generation strategies based on 3D spatial positioning 利用基于三维空间定位的岩性样品生成策略快速生成大型岩性图
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-02 DOI: 10.1016/j.gsf.2025.102217
Tao Zhang , Zhifang Zhao , Min Zeng , Haiying Yang
The acquisition of spatiotemporal information for lithological mapping with timeliness, accuracy, and high precision is crucial for mineral resource exploration and geological hazard prevention. However, large-scale lithological mapping remains severely constrained by the limitations of visual interpretation in obtaining representative samples from remote sensing data and error propagation during sample collection based on existing geological maps. To address this, we propose a three-dimensional spatial dual-positioning sample generation methodology (SG-3DSD) using Sentinel-2 (S2) and Landsat 8 (L8) data on the Google Earth Engine (GEE) platform, enabling automated generation of 11 lithological class samples across the Beishan region of Gansu Province, China (covering approximately 6,000 km2). First, boundary association rules were established to reconstruct 1:200,000-scale geological maps, mitigating data acquisition biases and cartographic compilation errors. Second, principal component analysis (PCA) was performed on seven S2 spectral bands, with the first three principal components (capturing > 98% information variance) constituting a 3D feature space for localized clustering. Concurrently, four L8 bands were selected through lithological spectral curve analysis to implement band ratio (BR) transformations for secondary positioning. Finally, a two-step refinement strategy was implemented to filter high-confidence samples across 11 lithological classes, balancing intraclass feature consistency and sample purity. Applying SG-3DSD-derived samples to multiple machine learning models revealed that (1) the Stacking ensemble model demonstrated superior lithological discrimination capability compared to conventional algorithms, achieving peak accuracy of 94.15% and mean F1-score of 93.87%; (2) integrating topographic data (especially Elevation) enhanced lithological positioning accuracy by 4.43% ± 1.13%; (3) PCA and BR transformations effectively enhanced lithological separability, particularly at lithological boundary zones; (4) while SG-3DSD enables efficient large-scale sample generation, it is advisable to avoid using excessively large training samples for regional-scale mapping. This methodology mitigates the weighting dependence on geological maps during sample selection and dilutes inherent cartographic error propagation, providing a novel paradigm for large-scale lithological mapping with broad application potential.
及时、准确、高精度地获取岩性填图的时空信息,对矿产资源勘查和地质灾害防治至关重要。然而,大规模的岩性填图仍然受到遥感数据中获得代表性样品的目视解释的局限性和基于现有地质图的样品采集过程中的误差传播的严重制约。为了解决这个问题,我们提出了一种三维空间双定位样本生成方法(SG-3DSD),利用谷歌地球引擎(GEE)平台上的Sentinel-2 (S2)和Landsat 8 (L8)数据,在中国甘肃省北山地区(面积约6000平方公里)自动生成11个岩性类样本。首先,建立边界关联规则,重构1:20万比例尺地质图,减少数据采集偏差和制图编制误差;其次,对7个S2光谱波段进行主成分分析(PCA),其中前3个主成分(捕获98%的信息方差)构成三维特征空间进行局部聚类;同时,通过岩性光谱曲线分析,选择4个L8波段,进行波段比变换,进行二次定位。最后,采用两步优化策略过滤11个岩性类别的高置信度样本,平衡类内特征一致性和样本纯度。将sg - 3dsd衍生样本应用于多个机器学习模型表明:(1)与传统算法相比,叠加系综模型具有更强的岩性识别能力,峰值精度为94.15%,平均f1分数为93.87%;(2)整合地形数据(尤其是高程数据)可使岩性定位精度提高4.43%±1.13%;(3) PCA和BR变换有效增强了岩性可分性,特别是在岩性边界带;(4) SG-3DSD虽然能够高效地生成大尺度样本,但在区域比例尺制图时,建议避免使用过大的训练样本。该方法减轻了样本选择过程中对地质图的权重依赖,淡化了固有的制图误差传播,为大规模岩性填图提供了一种新的范例,具有广阔的应用潜力。
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引用次数: 0
Knowledge-based data-driven prediction of shield tail clearance under karst geological condition 岩溶地质条件下盾构尾间隙数据驱动的知识预测
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.gsf.2025.102221
Wengang Zhang , Han Han , Weixin Sun , Yunhao Wang , Zhihao Wu , Peng Xiao , Yumiao Yan
Precise control of shield tail clearance is a critical factor influencing the safety and quality of shield tunneling construction. Although various methods exist for accurately measuring shield tail clearance, predictive capabilities remain insufficient. This study is based on a shield tunnel project in the karst region of Longgang, Shenzhen, China. By integrating geological parameters obtained from advanced geological prediction with shield construction monitoring data, a predictive calculation method for shield tail clearance is developed, grounded in the spatial relationship between the shield machine and the pipe segments. A knowledge-based data-driven prediction approach is proposed using a Transformer-LSTM deep learning model. Case analysis demonstrates that the proposed Transformer–LSTM model consistently outperformed baseline models such as GRU, LSTM, and pure Transformer. The predicted R2 values for the four positions of the shield tail—top, bottom, left, and right—reached 0.990, 0.901, 0.976, and 0.908, respectively, while error indicators (MAE, RMSE, and MAPE) were also minimized. These results confirm that the proposed hybrid approach effectively captures both global dependencies and temporal dynamics, enabling accurate prediction of shield tail clearance and offering practical engineering significance for guiding shield tunneling construction.
盾构尾隙的精确控制是影响盾构隧道施工安全和质量的关键因素。虽然有各种方法可以精确测量盾尾间隙,但预测能力仍然不足。本文以深圳龙岗岩溶地区的盾构隧道工程为研究对象。基于盾构机与管段的空间关系,将超前地质预测得到的地质参数与盾构施工监测数据相结合,提出了盾构尾间隙的预测计算方法。利用Transformer-LSTM深度学习模型,提出了一种基于知识的数据驱动预测方法。案例分析表明,所提出的Transformer - LSTM模型始终优于基准模型,如GRU、LSTM和纯Transformer。盾尾上、下、左、右4个位置的预测R2分别达到0.990、0.901、0.976、0.908,误差指标MAE、RMSE、MAPE均达到最小。这些结果证实了所提出的混合方法有效地捕获了全局依赖关系和时间动态,能够准确预测盾构尾间隙,对指导盾构隧道施工具有实际的工程意义。
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引用次数: 0
Genesis of shallow-water manganese nodules with uniquely high Mn/Fe ratios 具有独特高锰铁比的浅水锰结核成因
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.gsf.2025.102219
Hyo Jin Koo , Hyen Goo Cho , Young Keun Jin , Dong-Hun Lee , Ji-Hoon Kim , Tae Siek Rhee , Jong Kuk Hong , Sung Keun Lee
While manganese (Mn) nodules are authigenic metal concretions that form predominantly on deep-sea seafloor, they have also been found along shallow seafloors. The formation environments of these nodules — deep sea vs. shallow water — often result in distinct chemical and morphological characteristics. As Mn is one of the essential components of energy-storing technologies, assessing the proper estimation of Mn and metal contents in both deep- and shallow-water Mn nodules is critical. It has been found that the Mn content of shallow-water nodules is often lower than that from deep-sea environments. Here, we report the discovery of shallow-water Mn nodules with exceptionally high Mn/Fe ratios on the continental slope of the East Siberian Sea, Arctic Ocean. Despite their shallow-water origin, Mn nodules show morphological and chemical characteristics that are typically unique to deep-sea nodules. These distinctive features, including exceptionally high Mn/Fe ratios, may reflect suboxic diagenesis and the preferential remobilization and re-precipitation of Mn from the adjacent continental shelf. The formation of high Mn/Fe nodules may reflect unique ocean circulation patterns that provided oxygenated bottom waters to the study area. Particularly, Pacific Water entering through the Bering Strait, which overlaps with the nodule formation depth (160 – 240 m) and is enriched in dissolved oxygen, could facilitate Mn-rich nodule growth under suboxic diagenetic conditions since the Holocene. Shallow-water Mn nodules with uniquely high Mn/Fe ratios may offer a novel paleo-environmental proxy for reconstructing paleohydrology and bio-geochemical evolutions in shallow marine environments.
虽然锰结核是自生金属结块,主要形成于深海海底,但在浅海海底也发现了锰结核。这些结核的形成环境——深海和浅水——往往导致不同的化学和形态特征。由于锰是储能技术的重要组成部分之一,因此评估深水和浅水锰结核中锰和金属含量的正确估计至关重要。研究发现,浅水结核中的锰含量往往低于深海环境中的锰含量。在这里,我们报告了在北冰洋东西伯利亚海大陆斜坡上发现的具有异常高Mn/Fe比的浅水锰结核。尽管锰结核起源于浅水,但其形态和化学特征却是深海结核所特有的。这些独特的特征,包括异常高的Mn/Fe比率,可能反映了缺氧成岩作用和来自邻近大陆架的Mn的优先再移动和再沉淀。高锰铁结核的形成可能反映了独特的海洋环流模式,为研究区提供了含氧的底部水。特别是进入白令海峡的太平洋海水,与结核形成深度(160 ~ 240 m)重叠,且富含溶解氧,有利于全新世以来富锰结核在缺氧成岩条件下的生长。浅水锰结核具有独特的高锰铁比特征,可为重建浅海环境古水文和生物地球化学演化提供新的古环境指标。
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引用次数: 0
Coda of the snowball: combined U-Pb LA-ICPMS dating of calcite-after-aragonite crystal fans and clumped isotope thermometry of Ediacaran cap carbonates 雪球的终结:结合方解石-文石后晶体扇的U-Pb LA-ICPMS定年和埃迪卡拉纪盖层碳酸盐岩的团块同位素测温
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-11-30 DOI: 10.1016/j.gsf.2025.102218
Fabrício A. Caxito , Cristiano Lana , Davi Carvalho , Gabriel J. Uhlein , Carolina Reis , Paulo Henrique A. Dias , Denise Canabrava , Juliana Okubo , George Luiz Luvizotto , Lucas Warren , Shuhai Xiao , Tian Gan , Galen Halverson , Peter Crockford , Kristin Bergmann , Katharine W. Huntington , Andrew J. Schauer , Mariana M. Leite
<div><div>Direct dating of sedimentary successions is a main challenge in geochronology, key for the establishment of chronostratigraphic frameworks for both regional and global events. U-Pb in-situ LA-ICPMS direct dating of carbonate samples is emerging as a promising tool, but complications such as mobility and low U contents hinder most of the attempts on common carbonate rocks. We present new U-Pb in-situ LA-ICPMS data for Ediacaran cap carbonate and related successions from Brazil, China and Canada, along with stable carbon, oxygen, and clumped isotope data for the same samples. The novel dataset reveals that in some instances, especially within calcite-after-aragonite crystal fans and microbialite facies, U is retained from early diagenesis through intermediate to deep burial, resulting in tightly constrained and well-spread linear fits in the Concordia space. Calcite-after-aragonite crystal fan samples from the Guia Fm. (Brazil) and Hayhook Fm. (Canada) caps, sitting immediately above glacial diamictite, yielded 632 ± 14 Ma and 631 ± 6 Ma, respectively, supporting quick deposition and diagenesis following Marinoan deglaciation. Clumped isotope apparent equilibrium temperatures (<em>T</em><sub>Δ47</sub>) of 79 (+12/−11) °C and 181 (+14/−13) °C (95% confidence level), respectively, indicate that the U-Pb system remained unreset within the crystal fans even through the deep burial realm. In the Sete Lagoas Formation of the Bambuí Group (Brazil), crystal fans are not restricted to the immediate cap carbonate sitting above glacial deposits, but instead occur throughout ca. 400 m of carbonate-dominated facies, in distinct stratigraphic intervals corresponding to the Pedro Leopoldo and Lagoa Santa members. Samples from the basal Pedro Leopoldo member yielded U-Pb ages between 625 Ma and 605 Ma. A crystal-fan bearing sample of the Acauã Formation in the Sergipano Belt (Brazil) yielded similar results, suggesting protracted deposition/diagenesis of the negative <em>δ</em><sup>13</sup>C-bearing limestone above the basal cap dolostone. Crystal fans in the topmost Lagoa Santa member, just below the contact with the mudstone-rich Serra de Santa Helena Formation and 330 m above the contact with the glacials, yielded late Ediacaran ages at ca. 570–550 Ma. All of these yielded <em>T</em><sub>Δ47</sub> of around 110–149 °C. These ages are identical within uncertainty to U-Pb ages obtained in stromatolites at the same stratigraphic level, and from the phosphorite-bearing stromatolites of the Salitre Formation, Una Group, further north in the São Francisco craton, which yielded a lower <em>T</em><sub>Δ47</sub> of 91 ± 7 °C. Finally, both the cap dolostone matrix and isopachous cement filling sheet-cavities from a sample of the basal Doushantuo Formation of South China align in a regression with a lower intercept at ca. 619 Ma. The new U-Pb carbonate data are highly coherent with available U-Pb zircon and Re-Os whole-rock data worldwide, and also with previou
沉积序列的直接定年是地质年代学的主要挑战,是建立区域和全球事件的年代地层格架的关键。碳酸盐样品的原位LA-ICPMS U- pb直接测年正在成为一种有前途的工具,但诸如迁移率和低U含量等问题阻碍了大多数对普通碳酸盐岩的尝试。本文介绍了来自巴西、中国和加拿大的埃迪卡拉纪盖层碳酸盐岩及其相关序列的新的原位LA-ICPMS U-Pb数据,以及相同样品的稳定碳、氧和团块同位素数据。新的数据显示,在某些情况下,特别是在方解石-文石-后方解石晶体扇和微生物岩相中,U从早期成岩作用一直保留到中深埋藏,导致Concordia空间的线性拟合受到严格约束,分布良好。贵州地区方解石后文石晶体扇样品。(巴西)和Hayhook Fm。(加拿大)帽状岩位于冰川二晶岩上方,分别产生632±14 Ma和631±6 Ma,支持Marinoan脱冰后的快速沉积和成岩作用。团块同位素表观平衡温度(TΔ47)分别为79(+12/−11)°C和181(+14/−13)°C(95%置信水平),表明U-Pb体系在晶体扇内即使在深埋区也保持未重置状态。在巴西Bambuí组的Sete Lagoas组中,晶体扇并不局限于位于冰川沉积之上的直接盖层碳酸盐岩,而是分布在约400 m的碳酸盐岩为主的相中,在与Pedro Leopoldo和Lagoa Santa成员相对应的不同地层间隔中。Pedro Leopoldo基段样品的U-Pb年龄在625 ~ 605 Ma之间。巴西Sergipano带Acauã组含晶扇样品也得到了类似的结果,表明基底盖白云岩上方的负δ 13c灰岩沉积/成岩作用较长。拉古阿圣塔最顶端的水晶扇,就在与富含泥岩的圣海伦娜山组接触的下方,与冰川接触的上方330米处,得出的埃迪卡拉晚期年龄约为570-550 Ma。所有这些都产生了TΔ47约110-149°C。这些年龄在不确定范围内与同一地层水平的叠层石中获得的U-Pb年龄相同,也与 o Francisco克拉通更北的Una组Salitre组含磷叠层石中获得的U-Pb年龄相同,其TΔ47值较低,为91±7°C。最后,华南陡山沱组盖层白云岩基质和等径胶结充填板状空腔均在619 Ma的低截距回归中排列一致。新的U-Pb碳酸盐岩数据与世界范围内现有的U-Pb锆石和Re-Os全岩数据高度一致,也与之前的LA-ICPMS碳酸盐岩定年结果一致,表明埃迪卡拉纪碳酸盐-硅质混合单元保留了一个共同的全球沉积趋势。其特征是下埃迪卡拉纪(635 ~ 600 Ma)盖层碳酸盐岩层序致密(厚达几十米),其次是较发育和连续的晚埃迪卡拉纪(575 ~ 540 Ma)含化石的混合碳酸盐岩-硅质沉积层序。本研究验证了一种相对较新的方法的可行性,该方法利用了全球分布的单元样品和通过其他方法独立建立的沉积年龄,展示了直接U-Pb碳酸盐岩测年的潜力。
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Geoscience frontiers
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