首页 > 最新文献

Geoscience frontiers最新文献

英文 中文
Craton boundary detection from full-waveform tomography model reveals links to critical metal deposits 全波形层析成像模型的克拉通边界探测揭示了与关键金属矿床的联系
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-10-02 DOI: 10.1016/j.gsf.2025.102176
Hojat Shirmard , Ben Mather , Ehsan Farahbakhsh , Karol Czarnota , R. Dietmar Müller
Craton margins play a crucial role in mineral exploration as they host faults, fractures, and shear zones that facilitate hydrothermal fluid movement, transporting and depositing dissolved metals into valuable mineral deposits. We use the high-resolution full-waveform seismic inversion model REVEAL to extract horizontal shear wave velocity (VSH), vertical shear wave velocity (VSV), and isotropic P-wave velocity (VP) across depth slices from 150 to 200 km, a range that captures most cratonic lithosphere based on tectonic age and lithospheric thickness analyses. Machine learning, applied through clustered maps, demonstrates that VSH effectively delineates craton boundaries, aligning with target mineral deposits, including iron oxide copper–gold (IOCG) and sediment-hosted lead, zinc, and copper deposits. These boundaries are characterized by high horizontal shear velocities (4.58–4.68 km/s), and trace the edges of cratons, accreted passive margins, orogens, and thick volcanic arcs. Using published thermal and lithospheric thickness models, we distinguish cratons from other thick lithospheric features and identify their edges and associated deposits. Our results show that ∼85 % of the total metal content (Cu + Pb + Zn) in target deposits lies within ∼120 km of high-velocity cluster boundaries identified as craton edges. Near-craton deposits reveal ∼80 % of the total metal content within ∼90 km of craton boundaries. The weighted cumulative distribution function shows a steeper gradient in metal content closer to craton boundaries, indicating higher concentrations near these tectonic features. Focusing on just 16 % of Earth’s continental areas can reveal over 80 % of known target deposits, highlighting the significance of craton boundaries quantitatively mapped in this study.
克拉通边缘在矿产勘探中起着至关重要的作用,因为它们拥有断层、裂缝和剪切带,有利于热液流体的运动,将溶解的金属运输并沉积成有价值的矿床。利用高分辨率全波形地震反演模型REVEAL在150 ~ 200 km的深度切片上提取水平横波速度(VSH)、垂直横波速度(VSV)和各向同性纵波速度(VP),根据构造年龄和岩石圈厚度分析,这一范围可以捕获大部分克拉通岩石圈。通过聚类地图应用的机器学习表明,VSH有效地划定了克拉通的边界,并与目标矿床对齐,包括氧化铁铜金(IOCG)和沉积物中的铅、锌和铜矿床。这些边界具有高水平剪切速度(4.58 ~ 4.68 km/s)的特征,并可追溯克拉通、被动增生边缘、造山带和厚火山弧的边缘。利用已发表的热模型和岩石圈厚度模型,我们将克拉通与其他厚岩石圈特征区分开来,并识别其边缘和伴生矿床。我们的研究结果表明,目标矿床中总金属含量(Cu + Pb + Zn)的~ 85%位于被确定为克拉通边缘的高速簇边界~ 120公里内。近克拉通矿床显示,在克拉通边界~ 90公里范围内的金属含量占总金属含量的~ 80%。加权累积分布函数表明,靠近克拉通边界的金属含量梯度较大,表明这些构造特征附近的金属含量较高。仅关注地球16%的大陆区域,就可以揭示超过80%的已知目标矿床,突出了克拉通边界在本研究中定量绘制的重要性。
{"title":"Craton boundary detection from full-waveform tomography model reveals links to critical metal deposits","authors":"Hojat Shirmard ,&nbsp;Ben Mather ,&nbsp;Ehsan Farahbakhsh ,&nbsp;Karol Czarnota ,&nbsp;R. Dietmar Müller","doi":"10.1016/j.gsf.2025.102176","DOIUrl":"10.1016/j.gsf.2025.102176","url":null,"abstract":"<div><div>Craton margins play a crucial role in mineral exploration as they host faults, fractures, and shear zones that facilitate hydrothermal fluid movement, transporting and depositing dissolved metals into valuable mineral deposits. We use the high-resolution full-waveform seismic inversion model REVEAL to extract horizontal shear wave velocity (<em>V</em><sub>SH</sub>), vertical shear wave velocity (<em>V</em><sub>SV</sub>), and isotropic P-wave velocity (<em>V</em><sub>P</sub>) across depth slices from 150 to 200 km, a range that captures most cratonic lithosphere based on tectonic age and lithospheric thickness analyses. Machine learning, applied through clustered maps, demonstrates that <em>V</em><sub>SH</sub> effectively delineates craton boundaries, aligning with target mineral deposits, including iron oxide copper–gold (IOCG) and sediment-hosted lead, zinc, and copper deposits. These boundaries are characterized by high horizontal shear velocities (4.58–4.68 km/s), and trace the edges of cratons, accreted passive margins, orogens, and thick volcanic arcs. Using published thermal and lithospheric thickness models, we distinguish cratons from other thick lithospheric features and identify their edges and associated deposits. Our results show that ∼85 % of the total metal content (Cu + Pb + Zn) in target deposits lies within ∼120 km of high-velocity cluster boundaries identified as craton edges. Near-craton deposits reveal ∼80 % of the total metal content within ∼90 km of craton boundaries. The weighted cumulative distribution function shows a steeper gradient in metal content closer to craton boundaries, indicating higher concentrations near these tectonic features. Focusing on just 16 % of Earth’s continental areas can reveal over 80 % of known target deposits, highlighting the significance of craton boundaries quantitatively mapped in this study.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102176"},"PeriodicalIF":8.9,"publicationDate":"2025-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Noble gas constraints on fluid flow and hydrocarbon accumulation in the Yinggehai Basin, Northwestern South China Sea 莺歌海盆地稀有气对流体流动和油气成藏的约束
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-29 DOI: 10.1016/j.gsf.2025.102169
Rui Liu , Rui Xu , Tao Wen , Khi Atchinson , Ziqi Feng , Fang Hao , Lin Hu , Jinqiang Tian , Yazhen Zhang , Jianzhang Liu , Lei Tuo
Multiple physicochemical processes involving organic and inorganic components may alter hydrocarbon composition and isotopic signatures, posing a challenge in accurately tracing natural gas accumulation. In contrast, noble gases are chemically inert and highly sensitive to fluid flow processes, offering a powerful tool for precisely tracing natural gas accumulation. By analyzing and modeling noble gas geochemistry data of gas samples from gas fields in the Yinggehai Basin, South China Sea, we constrained fluid flow patterns and traced the natural gas accumulation process. In particular, the low 3He/4He and high 40Ar/36Ar values of gas samples suggested atmospheric-crustal mixing, with the suspected central fault significantly influencing the 40Ar* (* denotes crustal noble gas) proportion and 40Ar/36Ar value in charging fluids. Binary mixing of atmospheric and crustal noble gases elevated the 40Ar*/4He* value in well-preserved gas fields. Diapir activity and/or long-term artificial extraction had likely promoted noble gas leakage which further elevated the 40Ar*/4He* to abnormally high levels. Three key time windows for 4He* accumulation, i.e., 4–4.5 Ma, 1–2 Ma, and 0–0.5 Ma, were identified in well-preserved gas fields. The suspected central fault facilitated the migration of both high 40Ar/36Ar fluids and highly mature hydrocarbons characterized by heavier δ13C1 and high C1/C1-5 ratios. In most gas fields, methane (C1) migration was dominated by the gas phase, as indicated by the high C1/36Ar value. However, in a few leaked or shallow-buried gas fields, low C1/36Ar ratios suggest that C1 also migrated with water. The duration of trap sealing and the depth of the transport system played critical roles in hydrocarbon accumulation. Longer trap sealing and greater transport system depth favored hydrocarbons derived from the Lower Miocene Sanya Formation. In contrast, shorter trap sealing durations and limited transport system depth led to the accumulation of hydrocarbons sourced from the Middle Miocene Meishan Formation.
涉及有机和无机组分的多种物理化学过程可能会改变油气组成和同位素特征,这给准确追踪天然气聚集带来了挑战。相比之下,惰性气体是化学惰性的,对流体流动过程高度敏感,为精确追踪天然气聚集提供了有力的工具。通过对南海莺歌海盆地气田天然气样品地球化学数据的分析和建模,对流体流动模式进行了约束,并对天然气成藏过程进行了追踪。特别是气体样品中3He/4He较低,40Ar/36Ar较高,表明大气-地壳混合,疑似中心断裂对充注流体中40Ar*(*为地壳稀有气体)比例和40Ar/36Ar值有显著影响。在保存完好的天然气田中,大气和地壳惰性气体的二元混合使40Ar*/4He*值升高。底辟尔活动和/或长期人工开采可能促进惰性气体泄漏,进一步将40Ar*/4He*提高到异常高的水平。在保存完好的气田中,确定了4-4.5 Ma、1-2 Ma和0-0.5 Ma 3个4He*成藏关键时间窗。疑似中心断裂既有利于高40Ar/36Ar流体的运移,也有利于δ13C1重、C1/C1-5比值高的高成熟油气的运移。在大多数气田中,甲烷(C1)运移以气相为主,C1/ 36ar值较高。然而,在少数泄漏或浅埋气田中,C1/ 36ar比值较低,表明C1也随水运移。圈闭封闭的持续时间和输导系统的深度对油气成藏起着关键作用。较长的圈闭封闭和较大的输运系统深度有利于下中新统三亚组油气的形成。圈闭封闭时间较短,输运系统深度有限,形成了中中新世梅山组烃源岩。
{"title":"Noble gas constraints on fluid flow and hydrocarbon accumulation in the Yinggehai Basin, Northwestern South China Sea","authors":"Rui Liu ,&nbsp;Rui Xu ,&nbsp;Tao Wen ,&nbsp;Khi Atchinson ,&nbsp;Ziqi Feng ,&nbsp;Fang Hao ,&nbsp;Lin Hu ,&nbsp;Jinqiang Tian ,&nbsp;Yazhen Zhang ,&nbsp;Jianzhang Liu ,&nbsp;Lei Tuo","doi":"10.1016/j.gsf.2025.102169","DOIUrl":"10.1016/j.gsf.2025.102169","url":null,"abstract":"<div><div>Multiple physicochemical processes involving organic and inorganic components may alter hydrocarbon composition and isotopic signatures, posing a challenge in accurately tracing natural gas accumulation. In contrast, noble gases are chemically inert and highly sensitive to fluid flow processes, offering a powerful tool for precisely tracing natural gas accumulation. By analyzing and modeling noble gas geochemistry data of gas samples from gas fields in the Yinggehai Basin, South China Sea, we constrained fluid flow patterns and traced the natural gas accumulation process. In particular, the low <sup>3</sup>He/<sup>4</sup>He and high <sup>40</sup>Ar/<sup>36</sup>Ar values of gas samples suggested atmospheric-crustal mixing, with the suspected central fault significantly influencing the <sup>40</sup>Ar* (* denotes crustal noble gas) proportion and <sup>40</sup>Ar/<sup>36</sup>Ar value in charging fluids. Binary mixing of atmospheric and crustal noble gases elevated the <sup>40</sup>Ar*/<sup>4</sup>He* value in well-preserved gas fields. Diapir activity and/or long-term artificial extraction had likely promoted noble gas leakage which further elevated the <sup>40</sup>Ar*/<sup>4</sup>He* to abnormally high levels. Three key time windows for <sup>4</sup>He* accumulation, i.e., 4–4.5 Ma, 1–2 Ma, and 0–0.5 Ma, were identified in well-preserved gas fields. The suspected central fault facilitated the migration of both high <sup>40</sup>Ar/<sup>36</sup>Ar fluids and highly mature hydrocarbons characterized by heavier <em>δ</em><sup>13</sup>C<sub>1</sub> and high C<sub>1</sub>/C<sub>1-5</sub> ratios. In most gas fields, methane (C<sub>1</sub>) migration was dominated by the gas phase, as indicated by the high C<sub>1</sub>/<sup>36</sup>Ar value. However, in a few leaked or shallow-buried gas fields, low C<sub>1</sub>/<sup>36</sup>Ar ratios suggest that C<sub>1</sub> also migrated with water. The duration of trap sealing and the depth of the transport system played critical roles in hydrocarbon accumulation. Longer trap sealing and greater transport system depth favored hydrocarbons derived from the Lower Miocene Sanya Formation. In contrast, shorter trap sealing durations and limited transport system depth led to the accumulation of hydrocarbons sourced from the Middle Miocene Meishan Formation.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102169"},"PeriodicalIF":8.9,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145265362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unlocking marginal SDG dynamics: A KRLS machine learning analysis of AI technologies and solar energy 解锁边际可持续发展目标动态:人工智能技术和太阳能的KRLS机器学习分析
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-28 DOI: 10.1016/j.gsf.2025.102167
Zahoor Ahmed , Stefania Pinzon , Muhammad Qamar Rasheed
Studies quantifying AI’s impact on Sustainable Development Goals (SDGs) often rely on proxies that inaccurately reflect AI progress. Moreover, focusing solely on environmental and growth indicators provides an incomplete picture of AI’s overall contribution to the SDGs, as the SDG framework encompasses a broader set of interconnected goals. Therefore, this study unveils the marginal impacts of AI and solar energy (SEN) directly on the SDG Index (SDGI) by using the Kernel-Based Regularized Least Squares (KRLS) machine learning approach for the 10 largest economies from 2000‒2022. While the study found an overall positive average marginal impact of AI on the SDG Index, indicating significant progress driven by AI technologies, the analysis across different quantiles revealed variability. Specifically, at the 25th quantile, AI appears to hinder SDG progress. This could be due to negative externalities from AI adoption, like its use in accelerating non-renewable energy production and resource-intensive consumption, or from countries’ insufficient technological application capabilities. However, at higher quantiles (likely representing countries with better SDG achievement and greater AI maturity), the marginal effects of AI become increasingly positive, suggesting its beneficial use in areas that support SDGs. Marginal effects of SEN on SDGI are found to be positive, showing a positive connection between SDGs’ achievements and solar energy adoption. The marginal effects of economic globalization (EGB) and institutional productive capacity (INP) on SDGI are found to be positive. Finally, policies to boost AI and solar energy adoption, as well as exploring potential applications of AI across various sectors for sustainable development, are discussed.
量化人工智能对可持续发展目标(sdg)影响的研究往往依赖于不能准确反映人工智能进展的代理。此外,仅仅关注环境和增长指标不能全面反映人工智能对可持续发展目标的总体贡献,因为可持续发展目标框架包含了一系列更广泛的相互关联的目标。因此,本研究通过使用基于核的正则化最小二乘(KRLS)机器学习方法,揭示了2000年至2022年10个最大经济体的人工智能和太阳能(SEN)直接对可持续发展目标指数(SDGI)的边际影响。虽然该研究发现人工智能对可持续发展目标指数的总体平均边际影响为正,表明人工智能技术推动了重大进展,但不同分位数的分析显示了差异。具体而言,在第25分位数,人工智能似乎阻碍了可持续发展目标的进展。这可能是由于人工智能应用带来的负面外部性,比如人工智能在加速不可再生能源生产和资源密集型消费方面的应用,或者是由于各国技术应用能力不足。然而,在更高的分位数(可能代表可持续发展目标取得更好成就和人工智能成熟度更高的国家),人工智能的边际效应变得越来越积极,这表明它在支持可持续发展目标的领域得到了有益的使用。SEN对SDGI的边际效应为正,表明可持续发展目标的成就与太阳能的采用呈正相关。经济全球化(EGB)和制度生产能力(INP)对可持续发展指数的边际效应为正。最后,讨论了促进人工智能和太阳能采用的政策,以及探索人工智能在各个领域的潜在应用,以促进可持续发展。
{"title":"Unlocking marginal SDG dynamics: A KRLS machine learning analysis of AI technologies and solar energy","authors":"Zahoor Ahmed ,&nbsp;Stefania Pinzon ,&nbsp;Muhammad Qamar Rasheed","doi":"10.1016/j.gsf.2025.102167","DOIUrl":"10.1016/j.gsf.2025.102167","url":null,"abstract":"<div><div>Studies quantifying AI’s impact on Sustainable Development Goals (SDGs) often rely on proxies that inaccurately reflect AI progress. Moreover, focusing solely on environmental and growth indicators provides an incomplete picture of AI’s overall contribution to the SDGs, as the SDG framework encompasses a broader set of interconnected goals. Therefore, this study unveils the marginal impacts of AI and solar energy (SEN) directly on the SDG Index (SDGI) by using the Kernel-Based Regularized Least Squares (KRLS) machine learning approach for the 10 largest economies from 2000‒2022. While the study found an overall positive average marginal impact of AI on the SDG Index, indicating significant progress driven by AI technologies, the analysis across different quantiles revealed variability. Specifically, at the 25th quantile, AI appears to hinder SDG progress. This could be due to negative externalities from AI adoption, like its use in accelerating non-renewable energy production and resource-intensive consumption, or from countries’ insufficient technological application capabilities. However, at higher quantiles (likely representing countries with better SDG achievement and greater AI maturity), the marginal effects of AI become increasingly positive, suggesting its beneficial use in areas that support SDGs. Marginal effects of SEN on SDGI are found to be positive, showing a positive connection between SDGs’ achievements and solar energy adoption. The marginal effects of economic globalization (EGB) and institutional productive capacity (INP) on SDGI are found to be positive. Finally, policies to boost AI and solar energy adoption, as well as exploring potential applications of AI across various sectors for sustainable development, are discussed.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102167"},"PeriodicalIF":8.9,"publicationDate":"2025-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Searching for the age of the upper Vindhyan basin, India: A view from paleomagnetism and geochronology 从古地磁和地质年代学的角度探讨印度上温德扬盆地的年龄
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-27 DOI: 10.1016/j.gsf.2025.102168
Samuel Kwafo , Joseph G. Meert , Manoj K. Pandit , Anup K. Sinha , Nirmal Kant Verma
The closure age of the Proterozoic Vindhyan basin is a long-standing puzzle, unresolved due to inconsistencies between paleontological, geochronological, and paleomagnetic data. Some fossil findings from the Upper Vindhyan basin suggest an Ediacaran closure age, Pb-Pb dating of carbonate units yield dates ranging from ∼750–910 Ma, and detrital zircon data generally support a Kleisian (800–1000 Ma) closure age. In this study, we review published detrital zircon data and apply a statistically robust method to estimate the maximum depositional age (MDA) of the upper Vindhyan Kaimur, Bhander, and Rewa groups. Additionally, we present new paleomagnetic data from the folded Bhander sandstones near the Great Boundary fault to establish the primary nature of the Bhander-Rewa paleomagnetic pole. Our analysis reveals an MDA of 945 ± 7 Ma, which aligns closely with the youngest zircon population in the spectra. This MDA also corresponds to the onset of the Delhi Orogeny to the west of the Vindhyan basin; collisional orogenesis in the Central Indian Tectonic Zone to the south; and more distal high-grade metamorphism and collisional tectonism in the northern Eastern Ghats belt providing a geologically meaningful context for the basin closure age. Our paleomagnetic data offers a robust field test for the Vindhyan pole and we demonstrate that proposals for terminal Tonian closure of the basin (∼850–770 Ma) are incompatible with extant paleomagnetic data from India.
由于古生物学、地质年代学和古地磁资料的不一致,元古宙温德扬盆地的闭合年龄是一个长期存在的难题。上温德海盆地的一些化石发现表明,该盆地的封闭年龄为埃迪卡拉纪,碳酸盐岩单元的Pb-Pb定年结果在~ 750-910 Ma之间,碎屑锆石数据一般支持克虏世(800-1000 Ma)的封闭年龄。在本研究中,我们回顾了已发表的碎屑锆石资料,并应用统计稳健的方法估计了上Vindhyan Kaimur, Bhander和Rewa组的最大沉积年龄(MDA)。此外,我们在大边界断裂附近的褶皱Bhander砂岩中获得了新的古地磁资料,以确定Bhander- rewa古地磁极的主要性质。我们的分析显示,MDA为945±7 Ma,与光谱中最年轻的锆石种群密切一致。这一MDA也对应于温德扬盆地西部德里造山运动的开始;向南为印度中部构造带的碰撞造山作用;东高止带北部的远端高变质作用和碰撞构造作用为盆地闭合时代提供了有意义的地质背景。我们的古地磁数据为Vindhyan极提供了强有力的现场测试,我们证明了盆地(~ 850-770 Ma)的托尼末期闭合的建议与印度现有的古地磁数据不相容。
{"title":"Searching for the age of the upper Vindhyan basin, India: A view from paleomagnetism and geochronology","authors":"Samuel Kwafo ,&nbsp;Joseph G. Meert ,&nbsp;Manoj K. Pandit ,&nbsp;Anup K. Sinha ,&nbsp;Nirmal Kant Verma","doi":"10.1016/j.gsf.2025.102168","DOIUrl":"10.1016/j.gsf.2025.102168","url":null,"abstract":"<div><div>The closure age of the Proterozoic Vindhyan basin is a long-standing puzzle, unresolved due to inconsistencies between paleontological, geochronological, and paleomagnetic data. Some fossil findings from the Upper Vindhyan basin suggest an Ediacaran closure age, Pb-Pb dating of carbonate units yield dates ranging from ∼750–910 Ma, and detrital zircon data generally support a Kleisian (800–1000 Ma) closure age. In this study, we review published detrital zircon data and apply a statistically robust method to estimate the maximum depositional age (MDA) of the upper Vindhyan Kaimur, Bhander, and Rewa groups. Additionally, we present new paleomagnetic data from the folded Bhander sandstones near the Great Boundary fault to establish the primary nature of the Bhander-Rewa paleomagnetic pole. Our analysis reveals an MDA of 945 ± 7 Ma, which aligns closely with the youngest zircon population in the spectra. This MDA also corresponds to the onset of the Delhi Orogeny to the west of the Vindhyan basin; collisional orogenesis in the Central Indian Tectonic Zone to the south; and more distal high-grade metamorphism and collisional tectonism in the northern Eastern Ghats belt providing a geologically meaningful context for the basin closure age. Our paleomagnetic data offers a robust field test for the Vindhyan pole and we demonstrate that proposals for terminal Tonian closure of the basin (∼850–770 Ma) are incompatible with extant paleomagnetic data from India.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"17 1","pages":"Article 102168"},"PeriodicalIF":8.9,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145361147","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intra-shell stable isotopes in land snail as proxies of seasonal climate variability: Ontogenetic evidence from cultured and field specimens 陆地蜗牛壳内稳定同位素作为季节气候变化的代用物:来自培养和野外标本的个体发育证据
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-26 DOI: 10.1016/j.gsf.2025.102164
Xiulan Zong , Jibao Dong , Hong Yan , Yougui Song , Huifang Liu , Shugang Kang , Zheng Wang , Hongxuan Lu , Yunning Cao , Guozhen Wang , Chengcheng Liu , Yana Jia , Qian Zhang , Haijiao Gan
Land snail shells preserve stable oxygen and carbon isotope compositions (δ18Oshell and δ13Cshell) that offer valuable seasonal to weather-scale records of terrestrial environmental changes. However, the extent to which ontogenetic processes influence these signals remains insufficiently understood. Here, we investigated intra-shell isotopic variations in giant African land snails from laboratory cultured Achatina fulica and field collected Lissachatina fulica from Panzhihua, China. Laboratory experiments show that adult snail exhibits a δ18Oshell enrichment of up to 0.8‰, likely driven by internal physiological processes such as biomineralization and metabolism. In addition, δ13Cshell show an enrichment of 1.3‰ in subadult and adult shells, potentially associate with increased carbonate ingestion. In natural settings, intra-shell δ18Oshell variations primarily reflects seasonal fluctuation in precipitation δ18O, with physiological effects exerting only a minor influence. Although δ13Cshell values in wild snails fall within the expected range of C3 plant-based diets, the potential roles of carbonate ingestion and dietary selectivity should be considered when reconstructing vegetation isotope signatures. These findings establish land snail shells as robust proxies of sub-annual climate variability and offer a modern calibration framework to enhance the use of terrestrial biocarbonates in paleoclimate reconstructions, particularly across monsoonal and moisture-sensitive regions.
陆地蜗牛壳保持稳定的氧和碳同位素组成(δ18Oshell和δ13Cshell),为陆地环境变化提供了宝贵的季节和天气尺度记录。然而,个体发生过程对这些信号的影响程度仍然没有得到充分的了解。本文研究了实验室培养的非洲大蜗牛和野外采集的非洲大蜗牛壳内同位素的变化。实验结果表明,成螺的δ18Oshell富集程度可达0.8‰,可能与生物矿化、代谢等内部生理过程有关。此外,δ13Cshell在亚成体和成体壳中富集1.3‰,可能与碳酸盐摄入增加有关。在自然环境下,壳内δ18O的变化主要反映降水δ18O的季节波动,生理效应的影响较小。尽管野生蜗牛的δ13Cshell值落在C3植物性饮食的预期范围内,但在重建植被同位素特征时,应考虑碳酸盐摄入和饮食选择性的潜在作用。这些发现确立了陆地蜗牛壳作为次年气候变化的可靠代用物,并提供了一个现代校准框架,以加强陆地生物碳酸盐在古气候重建中的使用,特别是在季风和湿度敏感地区。
{"title":"Intra-shell stable isotopes in land snail as proxies of seasonal climate variability: Ontogenetic evidence from cultured and field specimens","authors":"Xiulan Zong ,&nbsp;Jibao Dong ,&nbsp;Hong Yan ,&nbsp;Yougui Song ,&nbsp;Huifang Liu ,&nbsp;Shugang Kang ,&nbsp;Zheng Wang ,&nbsp;Hongxuan Lu ,&nbsp;Yunning Cao ,&nbsp;Guozhen Wang ,&nbsp;Chengcheng Liu ,&nbsp;Yana Jia ,&nbsp;Qian Zhang ,&nbsp;Haijiao Gan","doi":"10.1016/j.gsf.2025.102164","DOIUrl":"10.1016/j.gsf.2025.102164","url":null,"abstract":"<div><div>Land snail shells preserve stable oxygen and carbon isotope compositions (<em>δ</em><sup>18</sup>O<sub>shell</sub> and <em>δ</em><sup>13</sup>C<sub>shell</sub>) that offer valuable seasonal to weather-scale records of terrestrial environmental changes. However, the extent to which ontogenetic processes influence these signals remains insufficiently understood. Here, we investigated intra-shell isotopic variations in giant African land snails from laboratory cultured <em>Achatina fulica</em> and field collected <em>Lissachatina fulica</em> from Panzhihua, China. Laboratory experiments show that adult snail exhibits a <em>δ</em><sup>18</sup>O<sub>shell</sub> enrichment of up to 0.8‰, likely driven by internal physiological processes such as biomineralization and metabolism. In addition, <em>δ</em><sup>13</sup>C<sub>shell</sub> show an enrichment of 1.3‰ in subadult and adult shells, potentially associate with increased carbonate ingestion. In natural settings, intra-shell <em>δ</em><sup>18</sup>O<sub>shell</sub> variations primarily reflects seasonal fluctuation in precipitation <em>δ</em><sup>18</sup>O, with physiological effects exerting only a minor influence. Although <em>δ</em><sup>13</sup>C<sub>shell</sub> values in wild snails fall within the expected range of C<sub>3</sub> plant-based diets, the potential roles of carbonate ingestion and dietary selectivity should be considered when reconstructing vegetation isotope signatures. These findings establish land snail shells as robust proxies of sub-annual climate variability and offer a modern calibration framework to enhance the use of terrestrial biocarbonates in paleoclimate reconstructions, particularly across monsoonal and moisture-sensitive regions.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102164"},"PeriodicalIF":8.9,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145332895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Holocene to anthropocene burial of organic carbon in the Yangtze delta 全新世至人类世长江三角洲有机碳埋藏
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-22 DOI: 10.1016/j.gsf.2025.102162
Jianfeng Su , Yijing Wu , Daidu Fan
Holocene organic carbon (OC) burial in mega-deltas is considered to have played a crucial role in modulating long-term atmospheric CO2 levels, but this role has likely been significantly altered by human activities during the Anthropocene. The absence of precise estimates for Holocene deltaic OC burial rates hinders a comprehensive understanding of carbon cycle evolution. This study, using data from 50 Holocene boreholes and 216 modern surface sediment samples, examines changes in OC sources and their controlling factors, and quantifies OC burial rates in the Yangtze Delta (YD) from the mid-Holocene to the Anthropocene. The results reveal three distinct stages of OC burial evolution. From 8 ka to 2 ka, the weakening East Asian Summer Monsoon reduced terrestrial OC contributions, but the YD maintained slow progradation and stable OC burial rates (∼0.79 Mt/yr). After 2 ka, human activities emerged as the dominant driver, triggering a 78 % increase in OC burial rates (1.40 – 1.44 Mt/yr). Following the impoundment of the Three Gorges Dam, the YD entered an erosion-driven destruction phase, with OC burial rates declining by 59 % compared to pre-dam levels. Accounting for subaqueous delta erosion, the YD has shifted from a net OC burial system to a net OC source, contributing ∼0.81 Mt/yr of OC to the Zhejiang-Fujian mud belt. These findings underscore the pivotal role of sediment burial rates in regulating OC sequestration in mega-deltas and highlight the global implications of human-altered sediment dynamics, suggesting that deltas worldwide may similarly transition from positive and negative OC sequestration.
全新世有机碳(OC)埋藏在大三角洲被认为在调节长期大气二氧化碳水平方面发挥了关键作用,但这一作用可能已被人类世期间的人类活动显著改变。缺乏对全新世三角洲OC埋藏速率的精确估计,阻碍了对碳循环演化的全面理解。本文利用50个全新世钻孔资料和216个现代表层沉积物样本,分析了长江三角洲中全新世至人类世OC来源的变化及其控制因素,并对OC埋藏率进行了定量分析。结果揭示了古岩埋藏演化的三个不同阶段。从8 ~ 2 ka,东亚夏季风的减弱减少了陆地OC的贡献,但YD保持了缓慢的进积和稳定的OC埋藏速率(~ 0.79 Mt/yr)。2 ka后,人类活动成为主要驱动因素,导致OC埋藏率增加78% (1.40 - 1.44 Mt/yr)。三峡大坝蓄水后,黄土高原进入侵蚀破坏阶段,土壤有机质埋藏率较蓄水前下降59%。考虑到水下三角洲侵蚀,YD已经从净OC埋藏系统转变为净OC来源,为浙闽泥带贡献了~ 0.81 Mt/yr的OC。这些发现强调了沉积物埋藏率在调节大三角洲碳封存中的关键作用,并强调了人类改变的沉积物动力学的全球意义,表明世界范围内的三角洲可能类似地从正碳封存和负碳封存过渡。
{"title":"Holocene to anthropocene burial of organic carbon in the Yangtze delta","authors":"Jianfeng Su ,&nbsp;Yijing Wu ,&nbsp;Daidu Fan","doi":"10.1016/j.gsf.2025.102162","DOIUrl":"10.1016/j.gsf.2025.102162","url":null,"abstract":"<div><div>Holocene organic carbon (OC) burial in mega-deltas is considered to have played a crucial role in modulating long-term atmospheric CO<sub>2</sub> levels, but this role has likely been significantly altered by human activities during the Anthropocene. The absence of precise estimates for Holocene deltaic OC burial rates hinders a comprehensive understanding of carbon cycle evolution. This study, using data from 50 Holocene boreholes and 216 modern surface sediment samples, examines changes in OC sources and their controlling factors, and quantifies OC burial rates in the Yangtze Delta (YD) from the mid-Holocene to the Anthropocene. The results reveal three distinct stages of OC burial evolution. From 8 ka to 2 ka, the weakening East Asian Summer Monsoon reduced terrestrial OC contributions, but the YD maintained slow progradation and stable OC burial rates (∼0.79 Mt/yr). After 2 ka, human activities emerged as the dominant driver, triggering a 78 % increase in OC burial rates (1.40 – 1.44 Mt/yr). Following the impoundment of the Three Gorges Dam, the YD entered an erosion-driven destruction phase, with OC burial rates declining by 59 % compared to pre-dam levels. Accounting for subaqueous delta erosion, the YD has shifted from a net OC burial system to a net OC source, contributing ∼0.81 Mt/yr of OC to the Zhejiang-Fujian mud belt. These findings underscore the pivotal role of sediment burial rates in regulating OC sequestration in mega-deltas and highlight the global implications of human-altered sediment dynamics, suggesting that deltas worldwide may similarly transition from positive and negative OC sequestration.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102162"},"PeriodicalIF":8.9,"publicationDate":"2025-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Generative AI with prompt engineering in construction: Enhancing predictive slope stability modelling for safe, sustainable, climate-smart mining practices 生成式人工智能与施工中的快速工程:加强预测边坡稳定性建模,实现安全、可持续、气候智能型采矿实践
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-22 DOI: 10.1016/j.gsf.2025.102163
Muhammad Kamran , Muhammad Faizan , Shuhong Wang , Danial Jahed Armaghani , Panagiotis G. Asteris , Biswajeet Pradhan
Generative AI (GenAI) and prompt engineering are rapidly advancing in industries such as construction and mining, leading to significant improvements in efficiency, accuracy, and decision-making processes. These technologies are transforming the construction sector by automating tasks and optimizing workflows, thereby enhancing productivity and risk management. This study explores the application of Google’s Gemini AI tool, a notable breakthrough in GenAI, specifically for predictive modeling of slope stability. The Gemini AI tool is utilized within the Python programming language to generate prompts that incorporate key factors influencing slope stability, with the Google Colab interface facilitating prompt generation and testing. Initially, these prompts are employed for data analysis and visualization, followed by their application in both unsupervised and supervised machine learning approaches. The performance evaluation metrics indicate that the integrated approaches, which combine GenAI and prompt engineering, predict slope stability with a high level of accuracy. The model achieved 99% accuracy, with precision, recall, and F1-scores ranging from 0.98 to 1.00 for both stable and unstable slope classes. This innovative methodology seeks to advance the implementation of GenAI in civil and mining engineering, offering more precise and efficient solutions for managing slope stability and supporting safe, sustainable, and climate-smart mining operations.
生成式人工智能(GenAI)和即时工程在建筑和采矿等行业迅速发展,大大提高了效率、准确性和决策过程。这些技术正在通过自动化任务和优化工作流程来改变建筑行业,从而提高生产力和风险管理。本研究探索了谷歌的Gemini AI工具的应用,该工具是GenAI的重大突破,专门用于边坡稳定性的预测建模。Gemini AI工具在Python编程语言中用于生成包含影响边坡稳定性的关键因素的提示,谷歌Colab接口促进提示生成和测试。最初,这些提示用于数据分析和可视化,然后将其应用于无监督和有监督的机器学习方法。性能评价指标表明,将GenAI和提示工程相结合的综合方法预测边坡稳定性具有较高的精度。该模型达到了99%的准确率,对于稳定和不稳定的斜坡类别,精度、召回率和f1得分范围为0.98到1.00。这种创新的方法旨在推进GenAI在土木和采矿工程中的实施,为管理边坡稳定性和支持安全、可持续和气候智能型采矿作业提供更精确、更有效的解决方案。
{"title":"Generative AI with prompt engineering in construction: Enhancing predictive slope stability modelling for safe, sustainable, climate-smart mining practices","authors":"Muhammad Kamran ,&nbsp;Muhammad Faizan ,&nbsp;Shuhong Wang ,&nbsp;Danial Jahed Armaghani ,&nbsp;Panagiotis G. Asteris ,&nbsp;Biswajeet Pradhan","doi":"10.1016/j.gsf.2025.102163","DOIUrl":"10.1016/j.gsf.2025.102163","url":null,"abstract":"<div><div>Generative AI (GenAI) and prompt engineering are rapidly advancing in industries such as construction and mining, leading to significant improvements in efficiency, accuracy, and decision-making processes. These technologies are transforming the construction sector by automating tasks and optimizing workflows, thereby enhancing productivity and risk management. This study explores the application of Google’s Gemini AI tool, a notable breakthrough in GenAI, specifically for predictive modeling of slope stability. The Gemini AI tool is utilized within the Python programming language to generate prompts that incorporate key factors influencing slope stability, with the Google Colab interface facilitating prompt generation and testing. Initially, these prompts are employed for data analysis and visualization, followed by their application in both unsupervised and supervised machine learning approaches. The performance evaluation metrics indicate that the integrated approaches, which combine GenAI and prompt engineering, predict slope stability with a high level of accuracy. The model achieved 99% accuracy, with precision, recall, and F<sub>1</sub>-scores ranging from 0.98 to 1.00 for both stable and unstable slope classes. This innovative methodology seeks to advance the implementation of GenAI in civil and mining engineering, offering more precise and efficient solutions for managing slope stability and supporting safe, sustainable, and climate-smart mining operations.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102163"},"PeriodicalIF":8.9,"publicationDate":"2025-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145154657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Volcano-sedimentary response to a mantle plume decay: A case study from the Eastern Mediterranean margin 火山-沉积对地幔柱衰变的响应:地中海东部边缘的一个案例研究
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-22 DOI: 10.1016/j.gsf.2025.102161
A. Segev , E. Sass , U. Schattner
The decay of a mantle plume is characterized by a decline in magmatic activity, localized volcanic pulses, and short-term topographic fluctuations. These processes are better preserved in marine settings than on land, offering a clearer record of surface dynamics. This study examines the decay of the Levant mantle plume during the Albian-Cenomanian by analyzing the effect of recurring volcanism and vertical motions on the volcano-sedimentary stratigraphy exposed in Mt. Carmel, located on the eastern Mediterranean continental margin, a gas giant province. Geological mapping and 40Ar/39Ar dating reveal four distinct volcanic pulses (V1–V4) between ∼99 Ma and 95.4 Ma, each associated with surface uplift followed by subsidence and sedimentation. These cycles suggest pressure accumulation and release, likely driven by residual plume-related magmatic activity rather than regional tectonics. Volcanism, vertical motions, and shallow marine areas created local basins with varying connections to the sea, resulting in diverse depositional environments characterized by lithologies such as chalk, limestone, dolomite, marl, and tuff. The volcanic structures influenced facies changes and contributed to the formation of dolomite in shallow, partially closed marine environments. A final pulse, V5 at 82 Ma, occurred after 13 Myr of quiescence, marking a shift in the regional tectonic setting. The lack of post-Maastrichtian volcanism and a 25 Myr long period of subsidence indicate plume termination. These findings demonstrate how a decaying plume loses its ability to influence surface dynamics. The Albian-Turonian reefs, situated atop a long-lasting crustal high structural block (swell) at the Arabian platform’s edge, serve as a significant example for analogous worldwide.
地幔柱衰变的特征是岩浆活动的减少、局部火山脉冲和短期地形波动。这些过程在海洋环境中比在陆地环境中保存得更好,提供了更清晰的地表动力学记录。本研究通过分析反复出现的火山活动和垂直运动对卡梅尔火山-沉积地层学的影响,考察了地中海-塞诺曼尼亚时期黎凡特地幔柱的衰变。卡梅尔火山位于地中海大陆东部边缘,是一个天然气巨省。地质填图和40Ar/39Ar测年显示了4个不同的火山脉冲(V1-V4),介于~ 99 Ma和95.4 Ma之间,每个脉冲都与地表隆起有关,然后是沉降和沉积。这些循环表明压力的积累和释放可能是由残余羽状柱相关的岩浆活动驱动的,而不是由区域构造驱动的。火山活动、垂直运动和浅海区域形成了与海洋有不同联系的局部盆地,形成了以白垩、石灰岩、白云岩、泥灰岩和凝灰岩等岩性为特征的多样化沉积环境。火山构造影响了相变化,促进了浅层部分封闭海洋环境白云岩的形成。最后一次脉冲是82 Ma的V5,发生在13 Myr的静止之后,标志着区域构造环境的转变。缺乏后马斯特里赫特火山活动和25迈的长期沉降表明羽流终止。这些发现证明了衰变的羽流是如何失去影响地表动力学的能力的。位于阿拉伯平台边缘的长期地壳高构造块(膨胀)顶部的阿尔比安-图尔onian珊瑚礁是世界范围内类似的一个重要例子。
{"title":"Volcano-sedimentary response to a mantle plume decay: A case study from the Eastern Mediterranean margin","authors":"A. Segev ,&nbsp;E. Sass ,&nbsp;U. Schattner","doi":"10.1016/j.gsf.2025.102161","DOIUrl":"10.1016/j.gsf.2025.102161","url":null,"abstract":"<div><div>The decay of a mantle plume is characterized by a decline in magmatic activity, localized volcanic pulses, and short-term topographic fluctuations. These processes are better preserved in marine settings than on land, offering a clearer record of surface dynamics. This study examines the decay of the Levant mantle plume during the Albian-Cenomanian by analyzing the effect of recurring volcanism and vertical motions on the volcano-sedimentary stratigraphy exposed in Mt. Carmel, located on the eastern Mediterranean continental margin, a gas giant province. Geological mapping and <sup>40</sup>Ar/<sup>39</sup>Ar dating reveal four distinct volcanic pulses (V<sub>1</sub>–V<sub>4</sub>) between ∼99 Ma and 95.4 Ma, each associated with surface uplift followed by subsidence and sedimentation. These cycles suggest pressure accumulation and release, likely driven by residual plume-related magmatic activity rather than regional tectonics. Volcanism, vertical motions, and shallow marine areas created local basins with varying connections to the sea, resulting in diverse depositional environments characterized by lithologies such as chalk, limestone, dolomite, marl, and tuff. The volcanic structures influenced facies changes and contributed to the formation of dolomite in shallow, partially closed marine environments. A final pulse, V<sub>5</sub> at 82 Ma, occurred after 13 Myr of quiescence, marking a shift in the regional tectonic setting. The lack of post-Maastrichtian volcanism and a 25 Myr long period of subsidence indicate plume termination. These findings demonstrate how a decaying plume loses its ability to influence surface dynamics. The Albian-Turonian reefs, situated atop a long-lasting crustal high structural block (swell) at the Arabian platform’s edge, serve as a significant example for analogous worldwide.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102161"},"PeriodicalIF":8.9,"publicationDate":"2025-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145154671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dynamics of disordered mackinawite (FeSm) at low temperatures and its geochemical implications 低温下无序麦金石(FeSm)的动力学及其地球化学意义
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-19 DOI: 10.1016/j.gsf.2025.102160
Hoon Young Jeong , Hyun Hwi Lee , Minji Park , Sookyung Kim , Kim Ford Hayes , So-Jeong Kim , Young-Soo Han
Disordered mackinawite (FeSm), an initial iron sulfide forming under ambient, anoxic conditions, plays a central role in sedimentary iron and sulfur cycling and may have contributed to early biochemical processes relevant to the origin of life. However, its structural variability complicates the assessments of its geochemical behavior and environmental impacts. Here, we demonstrate that FeSm undergoes anoxic corrosion at 25 °C, generating H2 even in the absence of traditional oxidants such as hydrogen sulfide (H2S) or elemental sulfur (S0). This abiotic H2 production provides a potential reductant for early Earth carbon fixation and may support modern oligotrophic ecosystems by influencing carbon cycling. The pH-dependent H2 production kinetics suggests that protons (H+) likely act as the primary oxidant in FeSm corrosion. The formation of Fe(III)-rich surface layers during this process passivates further corrosion and modulates surface reactivity—potentially facilitating the oxidation of H2S to S0 and intermediate species, thus driving FeSm transformation into greigite (Fe3S4) and pyrite (FeS2). Particle growth mechanisms vary with pH: Ostwald ripening dominates under acidic conditions, while oriented attachment is favored at neutral to alkaline pH. Instead, with prolonged aging, FeSm becomes stabilized through less-oriented attachment, producing polycrystalline particles. Both surface passivation and particle growth contribute to the resilience and dynamic behavior of FeSm under diverse geochemical conditions, reinforcing its role in sustaining iron and sulfur biogeochemical cycles. This study offers mechanistic insights into the structural evolution of FeSm, with implications for both early Earth environments and modern sedimentary systems.
无序硫化铁(FeSm)是一种在环境缺氧条件下形成的初始硫化铁,在沉积铁和硫循环中起着核心作用,可能对与生命起源相关的早期生化过程做出了贡献。然而,其结构变异性使其地球化学行为和环境影响的评估复杂化。在这里,我们证明了FeSm在25°C下经历缺氧腐蚀,即使在没有硫化氢(H2S)或单质硫(S0)等传统氧化剂的情况下也会产生H2。这种非生物制氢为早期地球碳固定提供了潜在的还原剂,并可能通过影响碳循环来支持现代少营养生态系统。ph依赖的H2生成动力学表明,质子(H+)可能是FeSm腐蚀中的主要氧化剂。在这一过程中,富Fe(III)表层的形成进一步钝化了腐蚀,并调节了表面反应性——可能促进H2S氧化为S0和中间物质,从而推动FeSm转化为灰长岩(Fe3S4)和黄铁矿(FeS2)。颗粒生长机制随pH值的变化而变化:酸性条件下奥斯特瓦尔德成熟占优势,而中性至碱性条件下有利于取向附着。相反,随着老化时间的延长,FeSm通过较少的取向附着而变得稳定,产生多晶颗粒。表面钝化和颗粒生长都有助于FeSm在不同地球化学条件下的弹性和动态行为,增强其在维持铁和硫生物地球化学循环中的作用。这项研究为FeSm的构造演化提供了机制上的见解,对早期地球环境和现代沉积体系都有启示。
{"title":"Dynamics of disordered mackinawite (FeSm) at low temperatures and its geochemical implications","authors":"Hoon Young Jeong ,&nbsp;Hyun Hwi Lee ,&nbsp;Minji Park ,&nbsp;Sookyung Kim ,&nbsp;Kim Ford Hayes ,&nbsp;So-Jeong Kim ,&nbsp;Young-Soo Han","doi":"10.1016/j.gsf.2025.102160","DOIUrl":"10.1016/j.gsf.2025.102160","url":null,"abstract":"<div><div>Disordered mackinawite (FeS<sub>m</sub>), an initial iron sulfide forming under ambient, anoxic conditions, plays a central role in sedimentary iron and sulfur cycling and may have contributed to early biochemical processes relevant to the origin of life. However, its structural variability complicates the assessments of its geochemical behavior and environmental impacts. Here, we demonstrate that FeS<sub>m</sub> undergoes anoxic corrosion at 25 °C, generating H<sub>2</sub> even in the absence of traditional oxidants such as hydrogen sulfide (H<sub>2</sub>S) or elemental sulfur (S<sup>0</sup>). This abiotic H<sub>2</sub> production provides a potential reductant for early Earth carbon fixation and may support modern oligotrophic ecosystems by influencing carbon cycling. The pH-dependent H<sub>2</sub> production kinetics suggests that protons (H<sup>+</sup>) likely act as the primary oxidant in FeS<sub>m</sub> corrosion. The formation of Fe(III)-rich surface layers during this process passivates further corrosion and modulates surface reactivity—potentially facilitating the oxidation of H<sub>2</sub>S to S<sup>0</sup> and intermediate species, thus driving FeS<sub>m</sub> transformation into greigite (Fe<sub>3</sub>S<sub>4</sub>) and pyrite (FeS<sub>2</sub>). Particle growth mechanisms vary with pH: Ostwald ripening dominates under acidic conditions, while oriented attachment is favored at neutral to alkaline pH. Instead, with prolonged aging, FeS<sub>m</sub> becomes stabilized through less-oriented attachment, producing polycrystalline particles. Both surface passivation and particle growth contribute to the resilience and dynamic behavior of FeS<sub>m</sub> under diverse geochemical conditions, reinforcing its role in sustaining iron and sulfur biogeochemical cycles. This study offers mechanistic insights into the structural evolution of FeS<sub>m</sub>, with implications for both early Earth environments and modern sedimentary systems.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102160"},"PeriodicalIF":8.9,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Two phases of high potassic-shoshonitic magmatism and coeval Sn polymetallic mineralization in the Bozhushan orefield, southwestern China 博竹山矿田两期高钾-粗玄岩岩浆活动与同时期锡多金属成矿作用
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-09-18 DOI: 10.1016/j.gsf.2025.102157
Yanbin Liu , Guochen Dong , M. Santosh , Dapeng Li , Liangliang Zhang , Sen Wang
The Cretaceous granitoid magmatism in the Gejiu-Bozhushan-Laojunshan region records tectonic transitions from the Neotethys to the South China Block and is genetically linked to Sn-polymetallic mineralization. However, the tectonic settings of magmatism and metallogeny remain unclear, particularly in the Bozhushan orefield. Integrated whole-rock geochemistry, Sr-Nd-Pb isotopes, zircon U-Pb-Hf-O isotopes, monazite U-Th-Pb-Nd isotopes, apatite U-Pb-REE data from the Bozhushan pluton, and cassiterite U-Pb dating from three Sn-polymetallic deposits are presented to understand the crustal architecture and tectonic-magmatic-metallogeny. The pluton consists of six interdigitated units characterized by high potassic-shoshonitic and peraluminous compositions, which are further subdivided into two magmatic stages: (1) Rim-located granodiorites (Units 1‒3, 91‒90 Ma, Stage I): I-type, characterized by the presence of biotite + K-feldspar + plagioclase, and featuring high Sr/Y, (La/Yb)N, and LREE-enriched apatite. They likely originate from lithospheric mantle melting during eastward Neotethys subduction, which triggered crustal melting and is linked to peripheral Ag-Pb-Zn-W polymetallic mineralization (ca. 91‒89 Ma, defined as Phase I magmatic-metallogenic event). (2) Core-located high evolved monzogranites (Units 4‒6, 87‒86 Ma, Stage II): S-type, containing muscovite + K-feldspar + plagioclase ± tourmaline, with LREE-depleted apatite, higher SiO2 and Rb/Sr, derived from the low-pressure partial melting of Neoproterozoic biotite-rich metagreywackes in the shallow crust during ongoing Neotethys subduction-induced collision, associated with Sn-dominated mineralization (87‒80 Ma, defined as Phase II magmatic-metallogenic event). Geochemical and Isotopic trends suggest mantle-crust interaction during Stage I and crustal recycling during Stage II, both driven by the ongoing subduction of Neotethys. This dual-stage magmatism establishes a dynamic model in which tectonic processes control magma sources, isotopic signatures, and metal partitioning, providing key insights into granite-related Sn polymetallic mineralization in the Bozhushan orefield.
葛九-伯珠山-老君山地区白垩系花岗岩类岩浆活动记录了新特提斯期到华南地块的构造过渡,并与锡多金属成矿有遗传联系。然而,岩浆作用和成矿作用的构造背景仍不清楚,特别是在博珠山矿田。综合全岩地球化学、Sr-Nd-Pb同位素、锆石U-Pb- hf - o同位素、独居石U-Th-Pb-Nd同位素、磷灰石U-Pb- ree数据、锡石U-Pb测年等资料,对3个锡多金属矿床的地壳结构和构造-岩浆成矿作用进行了研究。岩体由6个互指单元组成,其特征为高钾玄玄岩和过铝质成分,并进一步划分为两个岩浆阶段:(1)边缘花岗闪长岩(1 - 3单元,91-90 Ma,第1阶段):I型,以黑云母+钾长石+斜长石为特征,具有高Sr/Y、(La/Yb)N和富lree磷灰石的特征。它们可能源于新特提斯东俯冲过程中岩石圈地幔熔融引发的地壳熔融,并与外围的Ag-Pb-Zn-W多金属成矿作用(约91 ~ 89 Ma,定义为ⅰ期岩浆成矿事件)有关。(2)位于岩心的高演化二长花岗岩(4 ~ 6单元,87 ~ 86 Ma, II期):s型,含白云母+钾长石+斜长石±电气石,含贫lree磷灰石,较高的SiO2和Rb/Sr,形成于新元古代在新特提斯期俯冲诱发碰撞过程中,浅部地壳中富含黑云母的偏长花岗岩低压部分熔融,与锡为主的成矿作用(87 ~ 80 Ma,定义为II期岩浆成矿事件)有关。地球化学和同位素趋势表明,第一阶段的幔壳相互作用和第二阶段的地壳再循环都是由新特提斯的持续俯冲所驱动的。这一双期岩浆活动建立了构造过程控制岩浆来源、同位素特征和金属分配的动力学模型,为研究博珠山矿田花岗岩相关锡多金属成矿提供了重要依据。
{"title":"Two phases of high potassic-shoshonitic magmatism and coeval Sn polymetallic mineralization in the Bozhushan orefield, southwestern China","authors":"Yanbin Liu ,&nbsp;Guochen Dong ,&nbsp;M. Santosh ,&nbsp;Dapeng Li ,&nbsp;Liangliang Zhang ,&nbsp;Sen Wang","doi":"10.1016/j.gsf.2025.102157","DOIUrl":"10.1016/j.gsf.2025.102157","url":null,"abstract":"<div><div>The Cretaceous granitoid magmatism in the Gejiu-Bozhushan-Laojunshan region records tectonic transitions from the Neotethys to the South China Block and is genetically linked to Sn-polymetallic mineralization. However, the tectonic settings of magmatism and metallogeny remain unclear, particularly in the Bozhushan orefield. Integrated whole-rock geochemistry, Sr-Nd-Pb isotopes, zircon U-Pb-Hf-O isotopes, monazite U-Th-Pb-Nd isotopes, apatite U-Pb-REE data from the Bozhushan pluton, and cassiterite U-Pb dating from three Sn-polymetallic deposits are presented to understand the crustal architecture and tectonic-magmatic-metallogeny. The pluton consists of six interdigitated units characterized by high potassic-shoshonitic and peraluminous compositions, which are further subdivided into two magmatic stages: (1) Rim-located granodiorites (Units 1‒3, 91‒90 Ma, Stage I): I-type, characterized by the presence of biotite + K-feldspar + plagioclase, and featuring high Sr/Y, (La/Yb)<sub>N</sub>, and LREE-enriched apatite. They likely originate from lithospheric mantle melting during eastward Neotethys subduction, which triggered crustal melting and is linked to peripheral Ag-Pb-Zn-W polymetallic mineralization (ca. 91‒89 Ma, defined as Phase I magmatic-metallogenic event). (2) Core-located high evolved monzogranites (Units 4‒6, 87‒86 Ma, Stage II): S-type, containing muscovite + K-feldspar + plagioclase ± tourmaline, with LREE-depleted apatite, higher SiO<sub>2</sub> and Rb/Sr, derived from the low-pressure partial melting of Neoproterozoic biotite-rich metagreywackes in the shallow crust during ongoing Neotethys subduction-induced collision, associated with Sn-dominated mineralization (87‒80 Ma, defined as Phase II magmatic-metallogenic event). Geochemical and Isotopic trends suggest mantle-crust interaction during Stage I and crustal recycling during Stage II, both driven by the ongoing subduction of Neotethys. This dual-stage magmatism establishes a dynamic model in which tectonic processes control magma sources, isotopic signatures, and metal partitioning, providing key insights into granite-related Sn polymetallic mineralization in the Bozhushan orefield.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102157"},"PeriodicalIF":8.9,"publicationDate":"2025-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266543","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Geoscience frontiers
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1