首页 > 最新文献

Geoscience frontiers最新文献

英文 中文
Lithospheric thickness controls the porphyry Cu mineralization: Evidence from neighboring arc volcanic rocks 岩石圈厚度控制斑岩型铜成矿:来自邻近弧火山岩的证据
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-10-29 DOI: 10.1016/j.gsf.2025.102189
Yin-Hong Wang, Jun Deng, Jia-Jun Liu, Fang-Fang Zhang, Jin-Gao Liu, Shan Ke, Kang Wang, Zhong-Yu Zhang
It is widely considered that porphyry Cu deposits formed via oceanic slab subduction are closely associated with hydrous and oxidized arc magmas. Of note, two suites of neighboring (∼40 km apart) Carboniferous arc volcanic rocks in Northwest China show different extents of mineralization: volcanic rocks from the Dananhu arc (DNHA) host one of the most important porphyry Cu deposit belts in China, whereas those from the Yamansu arc (YMSA), adjacent to DNHA, are ore-barren. These arc volcanic rocks, thus, provide a precious opportunity to explore the main factor that controls the genetic links between coeval arc lavas and porphyry Cu mineralization. Here we report whole rock major and trace element compositions and Mg–Sr–Nd–Pb isotopic data, generating a comprehensive geochemical comparison for these two suites of volcanic rocks from basalt to dacite. The whole-rock geochemical analyses suggest that at a given SiO2 content, the YMSA basalts show lower MgO, CaO, Fe2O3T, and TiO2 contents than the DNHA basalts. The DNHA volcanic rocks have higher Sr/Y and (La/Yb)N ratios, which are positively correlated, indicating that these two suites of rocks were derived from different magma sources. The DNHA rocks are characterized by radiogenic Pb isotopic compositions with 206Pb/204Pb up to 19.457, clearly distinct from the YMSA volcanic rocks with less radiogenic Pb isotopic compositions (206Pb/204Pb = 18.146–18.487), suggesting variable assimilation of crust-derived components during magma evolution. The δ26Mg values of the DNHA rocks (−0.35‰ to +0.06‰) are largely similar to those of the YMSA rocks (−0.24‰ to +0.04‰), and both sets of isotopic ratio ranges have tendency toward heavy Mg isotopes, which could be attributed to serpentinite-derived high-δ26Mg fluids in their mantle sources. Both suites of arc lavas have constant Cu contents and Cu/Sc ratios, indicating inconspicuous pre-enrichment of Cu contents. Geochemical comparisons indicate that the DNHA rocks were derived from partial melting of peridotite at the depth around the spinel-garnet transitional stability field, whereas the YMSA rocks were derived from partial melting of spinel peridotite, and the DNHA magmas had a thicker overlying plate than that of the YMSA magmas. The thickened arc lithosphere facilitates water-rich magmas accumulation and garnet fractionation, driving the magmas to become more oxidized, thereby preventing sulfide segregation and releasing sulfide-bound Cu. Thus, magmas differentiation in the thickened arc lithosphere is a key factor influencing porphyry Cu ore potential.
普遍认为,洋板俯冲形成的斑岩型铜矿床与含水氧化弧岩浆密切相关。值得注意的是,中国西北两套相邻的石炭系弧火山岩(相距约40公里)显示出不同程度的成矿作用:来自大南湖弧(DNHA)的火山岩是中国最重要的斑岩型铜矿带之一,而来自与DNHA相邻的亚曼苏弧(YMSA)的火山岩则是无矿的。这些弧火山岩为探索控制同代弧熔岩与斑岩型铜成矿成因联系的主要因素提供了宝贵的机会。本文报道了全岩主微量元素组成和Mg-Sr-Nd-Pb同位素数据,对玄武岩-英安岩两套火山岩进行了全面的地球化学比较。全岩地球化学分析表明,在一定SiO2含量下,YMSA玄武岩的MgO、CaO、Fe2O3T和TiO2含量低于DNHA玄武岩。DNHA火山岩具有较高的Sr/Y和(La/Yb)N比值,两者正相关,表明两套火山岩来源于不同的岩浆源。DNHA火山岩具有206Pb/204Pb高达19.457的放射性成因Pb同位素组成特征,与放射性成因较少的YMSA火山岩(206Pb/204Pb = 18.146 ~ 18.487)明显不同,表明岩浆演化过程中地壳源成分的同化作用是变化的。DNHA岩石的δ26Mg值(- 0.35‰~ +0.06‰)与YMSA岩石的δ26Mg值(- 0.24‰~ +0.04‰)基本相似,两组同位素比值范围均有重Mg同位素的趋势,这可能是由于地幔源中蛇纹岩衍生的高δ26Mg流体所致。两套弧熔岩的Cu含量和Cu/Sc比值均保持不变,表明其预富集不明显。地球化学对比表明,DNHA岩石来源于尖晶石-石榴石过渡稳定场周围深部橄榄岩的部分熔融,而YMSA岩石来源于尖晶石橄榄岩的部分熔融,且DNHA岩浆的上覆板块较YMSA岩浆厚。加厚的弧形岩石圈有利于富水岩浆的聚集和石榴石分选,促使岩浆更加氧化,从而阻止硫化物偏析,释放出硫化物结合的Cu。因此,加厚弧岩石圈岩浆分异是影响斑岩型铜矿潜力的关键因素。
{"title":"Lithospheric thickness controls the porphyry Cu mineralization: Evidence from neighboring arc volcanic rocks","authors":"Yin-Hong Wang,&nbsp;Jun Deng,&nbsp;Jia-Jun Liu,&nbsp;Fang-Fang Zhang,&nbsp;Jin-Gao Liu,&nbsp;Shan Ke,&nbsp;Kang Wang,&nbsp;Zhong-Yu Zhang","doi":"10.1016/j.gsf.2025.102189","DOIUrl":"10.1016/j.gsf.2025.102189","url":null,"abstract":"<div><div>It is widely considered that porphyry Cu deposits formed via oceanic slab subduction are closely associated with hydrous and oxidized arc magmas. Of note, two suites of neighboring (∼40 km apart) Carboniferous arc volcanic rocks in Northwest China show different extents of mineralization: volcanic rocks from the Dananhu arc (DNHA) host one of the most important porphyry Cu deposit belts in China, whereas those from the Yamansu arc (YMSA), adjacent to DNHA, are ore-barren. These arc volcanic rocks, thus, provide a precious opportunity to explore the main factor that controls the genetic links between coeval arc lavas and porphyry Cu mineralization. Here we report whole rock major and trace element compositions and Mg–Sr–Nd–Pb isotopic data, generating a comprehensive geochemical comparison for these two suites of volcanic rocks from basalt to dacite. The whole-rock geochemical analyses suggest that at a given SiO<sub>2</sub> content, the YMSA basalts show lower MgO, CaO, Fe<sub>2</sub>O<sub>3</sub><sup>T</sup>, and TiO<sub>2</sub> contents than the DNHA basalts. The DNHA volcanic rocks have higher Sr/Y and (La/Yb)<sub>N</sub> ratios, which are positively correlated, indicating that these two suites of rocks were derived from different magma sources. The DNHA rocks are characterized by radiogenic Pb isotopic compositions with <sup>206</sup>Pb/<sup>204</sup>Pb up to 19.457, clearly distinct from the YMSA volcanic rocks with less radiogenic Pb isotopic compositions (<sup>206</sup>Pb/<sup>204</sup>Pb = 18.146–18.487), suggesting variable assimilation of crust-derived components during magma evolution. The <em>δ</em><sup>26</sup>Mg values of the DNHA rocks (−0.35‰ to +0.06‰) are largely similar to those of the YMSA rocks (−0.24‰ to +0.04‰), and both sets of isotopic ratio ranges have tendency toward heavy Mg isotopes, which could be attributed to serpentinite-derived high-<em>δ</em><sup>26</sup>Mg fluids in their mantle sources. Both suites of arc lavas have constant Cu contents and Cu/Sc ratios, indicating inconspicuous pre-enrichment of Cu contents. Geochemical comparisons indicate that the DNHA rocks were derived from partial melting of peridotite at the depth around the spinel-garnet transitional stability field, whereas the YMSA rocks were derived from partial melting of spinel peridotite, and the DNHA magmas had a thicker overlying plate than that of the YMSA magmas. The thickened arc lithosphere facilitates water-rich magmas accumulation and garnet fractionation, driving the magmas to become more oxidized, thereby preventing sulfide segregation and releasing sulfide-bound Cu. Thus, magmas differentiation in the thickened arc lithosphere is a key factor influencing porphyry Cu ore potential.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"17 1","pages":"Article 102189"},"PeriodicalIF":8.9,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145474586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Revealing fluid dynamics in unconventional reservoir rocks: A novel approach of T1-T2 analysis 揭示非常规储层岩石流体动力学:一种新的T1-T2分析方法
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-10-22 DOI: 10.1016/j.gsf.2025.102186
Zishuo Li , Yanbin Yao , Xueguang Zhu
Fluid distribution and migration characteristics hold significant importance in evaluating the quality of reservoir rocks. Two-dimensional nuclear magnetic resonance (2D NMR) measurements have been widely applied to identify specific hydrocarbon contents within rocks. However, due to the complexity of the pore and fluid system, this technique was not fully exploited and was limited by existing data processing methods. In this study, a novel centroid method was developed to enhance the quantification of 2D NMR data for fluids in reservoir rocks. This method calculates the centroid of the 2D NMR map, which correlates with the average pore size derived from the imbibition process. To validate its effectiveness, the method was applied to analyze the T1 (longitudinal relaxation time) – T2 (transverse relaxation time) relationships taken during imbibition processes in three different reservoir rocks. Results demonstrate that the position of centroid can be used to analyze the dominant type of water in pores involved in the imbibition process. Besides, this method can also successfully assess state changes for different water types inside samples by tracking centroids’ movements and fluctuations in centroid T1/T2 ratios, as well as utilizing the 2D NMR map’s signal partitioning capacity. Compared to other approaches, it elucidates the distribution and migration characteristics of water in different types of pores and provides significant advantages in the quantitative processing and comparative analyses of 2D NMR data across various water-bearing conditions. Furthermore, it also demonstrates significant potential for investigating interactions and dynamics of multiphase fluids in unconventional reservoirs.
流体分布和运移特征对储层质量评价具有重要意义。二维核磁共振(2D NMR)测量已被广泛应用于识别岩石中特定的碳氢化合物含量。然而,由于孔隙和流体系统的复杂性,该技术并未得到充分利用,并且受到现有数据处理方法的限制。本文提出了一种新的质心方法,以增强储层流体二维核磁共振数据的定量化。该方法计算二维核磁共振图的质心,该质心与由吸胀过程得出的平均孔径相关。为了验证该方法的有效性,应用该方法分析了3种不同储层岩石吸胀过程中T1(纵向松弛时间)- T2(横向松弛时间)的关系。结果表明,质心位置可以用来分析吸胀过程中孔隙中主要的水类型。此外,该方法还可以通过跟踪质心的运动和质心T1/T2比值的波动,以及利用二维核磁共振图的信号划分能力,成功评估样品内部不同水类型的状态变化。与其他方法相比,它阐明了水在不同类型孔隙中的分布和运移特征,在不同含水条件下二维核磁共振数据的定量处理和对比分析方面具有显著优势。此外,它还显示了研究非常规油藏中多相流体相互作用和动力学的巨大潜力。
{"title":"Revealing fluid dynamics in unconventional reservoir rocks: A novel approach of T1-T2 analysis","authors":"Zishuo Li ,&nbsp;Yanbin Yao ,&nbsp;Xueguang Zhu","doi":"10.1016/j.gsf.2025.102186","DOIUrl":"10.1016/j.gsf.2025.102186","url":null,"abstract":"<div><div>Fluid distribution and migration characteristics hold significant importance in evaluating the quality of reservoir rocks. Two-dimensional nuclear magnetic resonance (2D NMR) measurements have been widely applied to identify specific hydrocarbon contents within rocks. However, due to the complexity of the pore and fluid system, this<!--> <!-->technique was not fully exploited and was limited by existing data processing methods. In this study, a novel centroid method was developed to enhance the quantification of 2D NMR data for fluids in reservoir rocks. This method calculates the centroid of the 2D NMR map, which correlates with the average pore size derived from the imbibition process. To validate its effectiveness, the method was applied to analyze the <em>T</em><sub>1</sub> (longitudinal relaxation time) – <em>T</em><sub>2</sub> (transverse relaxation time) relationships taken during imbibition processes in three different reservoir rocks. Results demonstrate that the position of centroid can be used to analyze the dominant type of water in pores involved in the imbibition process. Besides, this method can also successfully assess state changes for different water types inside samples by tracking centroids’ movements and fluctuations in centroid <em>T</em><sub>1</sub>/<em>T</em><sub>2</sub> ratios, as well as utilizing the 2D NMR map’s signal partitioning capacity. Compared to other approaches, it elucidates the distribution and migration characteristics of water in different types of pores and provides significant advantages in the quantitative processing and comparative analyses of 2D NMR data across various water-bearing conditions. Furthermore, it also demonstrates significant potential for investigating interactions and dynamics of multiphase fluids in unconventional reservoirs.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"17 1","pages":"Article 102186"},"PeriodicalIF":8.9,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145418514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Late Mesozoic porphyry copper deposits in NE China: Post-collisional versus subduction-related magmatic systems 中国东北晚中生代斑岩型铜矿床:后碰撞与俯冲岩浆体系
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-10-27 DOI: 10.1016/j.gsf.2025.102190
Bizheng Yang , Fanbo Meng , Yuzhou Feng , Xinran Ni , Changzhou Deng , Jingjing Zhu , Runsheng Yin , Huayong Chen
Recent discoveries of Late Mesozoic porphyry Cu deposits (PCDs) in Northeast (NE) China reveal a distinct spatial metallogenic zonation, with Late Jurassic PCDs in the north dominated by Cu-Mo and Early Cretaceous PCDs in the east marked by Cu-Au mineralization. However, the mechanisms controlling this metallogenic contrast remain unclear. To tackle this issue, we combined geological, geochronological, and geochemical data to determine the genesis of these deposits and the key factors controlling their distinct Cu-Mo and Cu-Au mineralization. Geochronological data show that the Late Jurassic PCDs were formed during a short-lived mineralization event (ca. 150–147 Ma), in contrast to the Early Cretaceous PCDs, which exhibit a prolonged formation history (ca. 120–95 Ma). Geochemical data demonstrate that the northern Cu-Mo PCDs originate from partial melting of thickened juvenile lower crust, whereas the eastern Cu-Au PCDs result from oceanic crust-derived melts contaminated by mantle wedge materials. Integrated analysis suggests that the Cu-Mo PCDs formed in a post-collisional setting after the Mongol-Okhotsk Ocean closure, while the Cu-Au PCDs formed in a subduction setting associated with Paleo-Pacific oceanic plate subduction. Despite the presence of hydrous and oxidized magmas in both regions, the northern PCDs exhibit higher Sr/Y, La/Yb, and Sm/Yb ratios than the eastern PCDs, indicating greater magma differentiation depths controlled by crustal thickness. We therefore propose that the depths of magma differentiation govern the metallogenic zoning of Late Mesozoic PCDs in NE China.
中国东北晚中生代斑岩型铜矿床的新发现显示出明显的空间成矿分带,北部晚侏罗世斑岩型铜矿床以Cu- mo为主,东部早白垩世斑岩型铜矿床以Cu- au成矿为主。然而,控制这种成矿对比的机制尚不清楚。为了解决这一问题,我们结合地质、年代学和地球化学数据,确定了这些矿床的成因以及控制其独特的Cu-Mo和Cu-Au成矿作用的关键因素。地质年代学资料表明,晚侏罗世多聚体形成于一个短暂的成矿事件(约150 ~ 147 Ma),而早白垩世多聚体形成时间较长(约120 ~ 95 Ma)。地球化学资料表明,北部Cu-Mo多聚体来源于增厚幼年下地壳的部分熔融,而东部Cu-Au多聚体来源于地幔楔块物质污染的洋壳熔融体。综合分析表明,Cu-Mo多聚体形成于蒙古-鄂霍次克洋闭合后的碰撞环境,而Cu-Au多聚体形成于古太平洋板块俯冲后的俯冲环境。尽管两区均存在含水岩浆和氧化岩浆,但北段的Sr/Y、La/Yb和Sm/Yb比值均高于东段,表明岩浆分异深度受地壳厚度控制较大。因此,岩浆分异深度决定了中国东北晚中生代多聚体的成矿分带。
{"title":"Late Mesozoic porphyry copper deposits in NE China: Post-collisional versus subduction-related magmatic systems","authors":"Bizheng Yang ,&nbsp;Fanbo Meng ,&nbsp;Yuzhou Feng ,&nbsp;Xinran Ni ,&nbsp;Changzhou Deng ,&nbsp;Jingjing Zhu ,&nbsp;Runsheng Yin ,&nbsp;Huayong Chen","doi":"10.1016/j.gsf.2025.102190","DOIUrl":"10.1016/j.gsf.2025.102190","url":null,"abstract":"<div><div>Recent discoveries of Late Mesozoic porphyry Cu deposits (PCDs) in Northeast (NE) China reveal a distinct spatial metallogenic zonation, with Late Jurassic PCDs in the north dominated by Cu-Mo and Early Cretaceous PCDs in the east marked by Cu-Au mineralization. However, the mechanisms controlling this metallogenic contrast remain unclear. To tackle this issue, we combined geological, geochronological, and geochemical data to determine the genesis of these deposits and the key factors controlling their distinct Cu-Mo and Cu-Au mineralization. Geochronological data show that the Late Jurassic PCDs were formed during a short-lived mineralization event (ca. 150–147 Ma), in contrast to the Early Cretaceous PCDs, which exhibit a prolonged formation history (ca. 120–95 Ma). Geochemical data demonstrate that the northern Cu-Mo PCDs originate from partial melting of thickened juvenile lower crust, whereas the eastern Cu-Au PCDs result from oceanic crust-derived melts contaminated by mantle wedge materials. Integrated analysis suggests that the Cu-Mo PCDs formed in a post-collisional setting after the Mongol-Okhotsk Ocean closure, while the Cu-Au PCDs formed in a subduction setting associated with Paleo-Pacific oceanic plate subduction. Despite the presence of hydrous and oxidized magmas in both regions, the northern PCDs exhibit higher Sr/Y, La/Yb, and Sm/Yb ratios than the eastern PCDs, indicating greater magma differentiation depths controlled by crustal thickness. We therefore propose that the depths of magma differentiation govern the metallogenic zoning of Late Mesozoic PCDs in NE China.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"17 1","pages":"Article 102190"},"PeriodicalIF":8.9,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145475009","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In situ Raman spectroscopic measurement of the 13C/12C ratio of dissolved CO2 at high temperatures and pressures: Method and implications 高温高压下溶解二氧化碳13C/12C比值的原位拉曼光谱测量:方法和意义
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-10-12 DOI: 10.1016/j.gsf.2025.102180
Yuzhou Ge , Zhendong Luan , Lianfu Li , Shichuan Xi , Zengfeng Du , Xin Zhang
<div><div>Submarine hydrothermal activities release a large amount of greenhouse gases such as CO<sub>2</sub> and CH<sub>4</sub> into the ocean, influencing the global carbon cycle. Carrying out high-temperature and high-pressure hydrothermal experiments to simulate these geochemical processes is a prerequisite for clarifying the source of carbon-containing substances in the hydrothermal fluid. In situ monitoring of the change in carbon isotope composition of CO<sub>2</sub> is essential for high-temperature and high-pressure simulation experiments, but it is also a great technical challenge. In recent years, laser Raman spectroscopy has attracted wide attention as a supplementary means to mass spectrometry for measuring the <sup>13</sup>C/<sup>12</sup>C value of CO<sub>2</sub>. However, the existing research is limited to the Raman spectroscopy study of the carbon isotope composition of supercritical/liquid CO<sub>2</sub>, and there is little research on dissolved CO<sub>2</sub> in solution. In this study, we systematically studied the Raman spectral characteristics of dissolved <sup>13</sup>CO<sub>2</sub> and <sup>12</sup>CO<sub>2</sub> in the H<sub>2</sub>O ± <sup>13</sup>CO<sub>2</sub> ± <sup>12</sup>CO<sub>2</sub> system at 25–300 °C and 10–350 bar. The results show that the peak position of the Raman characteristic band of <sup>13</sup>CO<sub>2</sub> (aq) is 1367–1370 cm<sup>−1</sup>, which is 14–17 cm<sup>−1</sup> lower than that of <sup>12</sup>CO<sub>2</sub> (aq), and the full width at half maximum is 2–3 cm<sup>−1</sup> smaller than that of <sup>12</sup>CO<sub>2</sub>, which indicate the <sup>13</sup>CO<sub>2</sub> (aq) and <sup>12</sup>CO<sub>2</sub> (aq) can be identified by Raman spectroscopy. On this basis, we proposed the optimal likelihood curve fitting method (OLCF) for the first time to decompose the overlapping bands and accurately obtain the peak height ratio (H<sub>13</sub>/H<sub>12</sub>) of dissolved <sup>13</sup>CO<sub>2</sub> and <sup>12</sup>CO<sub>2</sub>. It has been shown that the G-factor ratios (G<sub>13</sub>/G<sub>12</sub>) are significantly affected by temperature and the relative content of <sup>13</sup>CO<sub>2</sub> and <sup>12</sup>CO<sub>2</sub>. Obtaining an appropriate G-factor ratio is a prerequisite for accurately determining the <sup>13</sup>C/<sup>12</sup>C of dissolved CO<sub>2</sub>. Based on the functional relationship between the H<sub>13</sub>/H<sub>12</sub> and the <sup>13</sup>C/<sup>12</sup>C, we established an empirical equation to quickly estimate the <sup>13</sup>C/<sup>12</sup>C value, thereby assisting in selecting an appropriate G-factor ratio. The calibrated G-factor can be well used to determine the <sup>13</sup>C/<sup>12</sup>C of dissolved CO<sub>2</sub> in the hydrothermal experiments with <sup>13</sup>C labelled. In-situ monitoring experiments show that the phase separation of the hydrothermal fluid hardly causes changes in the carbon isotope composition of dissolved CO<sub>2</sub>.
海底热液活动向海洋释放大量CO2、CH4等温室气体,影响全球碳循环。开展高温高压热液实验模拟这些地球化学过程是厘清热液中含碳物质来源的前提。现场监测CO2碳同位素组成的变化是高温高压模拟实验必不可少的,但也是一项巨大的技术挑战。近年来,激光拉曼光谱作为质谱法测量二氧化碳13C/12C值的补充手段受到了广泛关注。然而,现有的研究仅限于超临界/液态CO2碳同位素组成的拉曼光谱研究,对溶液中溶解CO2的研究很少。在本研究中,我们系统地研究了溶解13CO2和12CO2在H2O±13CO2±12CO2体系中,在25-300℃,10-350 bar条件下的拉曼光谱特性。结果表明,13CO2 (aq)的拉曼特征带峰位为1367 ~ 1370 cm−1,比12CO2 (aq)低14 ~ 17 cm−1,半峰全宽比12CO2小2 ~ 3 cm−1,表明13CO2 (aq)和12CO2 (aq)可以通过拉曼光谱进行识别。在此基础上,我们首次提出了最优似然曲线拟合方法(OLCF),对重叠波段进行分解,准确得到溶解13CO2和12CO2的峰高比(H13/H12)。结果表明,温度、13CO2和12CO2的相对含量对g因子比(G13/G12)有显著影响。获得合适的g因子比是准确测定溶解CO2 13C/12C的先决条件。根据H13/H12与13C/12C之间的函数关系,建立经验方程,快速估算13C/12C值,从而帮助选择合适的g因子比。标定后的g因子可以很好地用于13C标记水热实验中溶解CO2的13C/12C的测定。现场监测实验表明,热液流体的相分离对溶解CO2的碳同位素组成影响不大。而有机质(如草酸)的污染会导致热液中CO2含量升高,δ13C负向增大。
{"title":"In situ Raman spectroscopic measurement of the 13C/12C ratio of dissolved CO2 at high temperatures and pressures: Method and implications","authors":"Yuzhou Ge ,&nbsp;Zhendong Luan ,&nbsp;Lianfu Li ,&nbsp;Shichuan Xi ,&nbsp;Zengfeng Du ,&nbsp;Xin Zhang","doi":"10.1016/j.gsf.2025.102180","DOIUrl":"10.1016/j.gsf.2025.102180","url":null,"abstract":"&lt;div&gt;&lt;div&gt;Submarine hydrothermal activities release a large amount of greenhouse gases such as CO&lt;sub&gt;2&lt;/sub&gt; and CH&lt;sub&gt;4&lt;/sub&gt; into the ocean, influencing the global carbon cycle. Carrying out high-temperature and high-pressure hydrothermal experiments to simulate these geochemical processes is a prerequisite for clarifying the source of carbon-containing substances in the hydrothermal fluid. In situ monitoring of the change in carbon isotope composition of CO&lt;sub&gt;2&lt;/sub&gt; is essential for high-temperature and high-pressure simulation experiments, but it is also a great technical challenge. In recent years, laser Raman spectroscopy has attracted wide attention as a supplementary means to mass spectrometry for measuring the &lt;sup&gt;13&lt;/sup&gt;C/&lt;sup&gt;12&lt;/sup&gt;C value of CO&lt;sub&gt;2&lt;/sub&gt;. However, the existing research is limited to the Raman spectroscopy study of the carbon isotope composition of supercritical/liquid CO&lt;sub&gt;2&lt;/sub&gt;, and there is little research on dissolved CO&lt;sub&gt;2&lt;/sub&gt; in solution. In this study, we systematically studied the Raman spectral characteristics of dissolved &lt;sup&gt;13&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt; and &lt;sup&gt;12&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt; in the H&lt;sub&gt;2&lt;/sub&gt;O ± &lt;sup&gt;13&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt; ± &lt;sup&gt;12&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt; system at 25–300 °C and 10–350 bar. The results show that the peak position of the Raman characteristic band of &lt;sup&gt;13&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt; (aq) is 1367–1370 cm&lt;sup&gt;−1&lt;/sup&gt;, which is 14–17 cm&lt;sup&gt;−1&lt;/sup&gt; lower than that of &lt;sup&gt;12&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt; (aq), and the full width at half maximum is 2–3 cm&lt;sup&gt;−1&lt;/sup&gt; smaller than that of &lt;sup&gt;12&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt;, which indicate the &lt;sup&gt;13&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt; (aq) and &lt;sup&gt;12&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt; (aq) can be identified by Raman spectroscopy. On this basis, we proposed the optimal likelihood curve fitting method (OLCF) for the first time to decompose the overlapping bands and accurately obtain the peak height ratio (H&lt;sub&gt;13&lt;/sub&gt;/H&lt;sub&gt;12&lt;/sub&gt;) of dissolved &lt;sup&gt;13&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt; and &lt;sup&gt;12&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt;. It has been shown that the G-factor ratios (G&lt;sub&gt;13&lt;/sub&gt;/G&lt;sub&gt;12&lt;/sub&gt;) are significantly affected by temperature and the relative content of &lt;sup&gt;13&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt; and &lt;sup&gt;12&lt;/sup&gt;CO&lt;sub&gt;2&lt;/sub&gt;. Obtaining an appropriate G-factor ratio is a prerequisite for accurately determining the &lt;sup&gt;13&lt;/sup&gt;C/&lt;sup&gt;12&lt;/sup&gt;C of dissolved CO&lt;sub&gt;2&lt;/sub&gt;. Based on the functional relationship between the H&lt;sub&gt;13&lt;/sub&gt;/H&lt;sub&gt;12&lt;/sub&gt; and the &lt;sup&gt;13&lt;/sup&gt;C/&lt;sup&gt;12&lt;/sup&gt;C, we established an empirical equation to quickly estimate the &lt;sup&gt;13&lt;/sup&gt;C/&lt;sup&gt;12&lt;/sup&gt;C value, thereby assisting in selecting an appropriate G-factor ratio. The calibrated G-factor can be well used to determine the &lt;sup&gt;13&lt;/sup&gt;C/&lt;sup&gt;12&lt;/sup&gt;C of dissolved CO&lt;sub&gt;2&lt;/sub&gt; in the hydrothermal experiments with &lt;sup&gt;13&lt;/sup&gt;C labelled. In-situ monitoring experiments show that the phase separation of the hydrothermal fluid hardly causes changes in the carbon isotope composition of dissolved CO&lt;sub&gt;2&lt;/sub&gt;. ","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"17 1","pages":"Article 102180"},"PeriodicalIF":8.9,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145361145","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Two phases of high potassic-shoshonitic magmatism and coeval Sn polymetallic mineralization in the Bozhushan orefield, southwestern China 博竹山矿田两期高钾-粗玄岩岩浆活动与同时期锡多金属成矿作用
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-11-01 Epub Date: 2025-09-18 DOI: 10.1016/j.gsf.2025.102157
Yanbin Liu , Guochen Dong , M. Santosh , Dapeng Li , Liangliang Zhang , Sen Wang
The Cretaceous granitoid magmatism in the Gejiu-Bozhushan-Laojunshan region records tectonic transitions from the Neotethys to the South China Block and is genetically linked to Sn-polymetallic mineralization. However, the tectonic settings of magmatism and metallogeny remain unclear, particularly in the Bozhushan orefield. Integrated whole-rock geochemistry, Sr-Nd-Pb isotopes, zircon U-Pb-Hf-O isotopes, monazite U-Th-Pb-Nd isotopes, apatite U-Pb-REE data from the Bozhushan pluton, and cassiterite U-Pb dating from three Sn-polymetallic deposits are presented to understand the crustal architecture and tectonic-magmatic-metallogeny. The pluton consists of six interdigitated units characterized by high potassic-shoshonitic and peraluminous compositions, which are further subdivided into two magmatic stages: (1) Rim-located granodiorites (Units 1‒3, 91‒90 Ma, Stage I): I-type, characterized by the presence of biotite + K-feldspar + plagioclase, and featuring high Sr/Y, (La/Yb)N, and LREE-enriched apatite. They likely originate from lithospheric mantle melting during eastward Neotethys subduction, which triggered crustal melting and is linked to peripheral Ag-Pb-Zn-W polymetallic mineralization (ca. 91‒89 Ma, defined as Phase I magmatic-metallogenic event). (2) Core-located high evolved monzogranites (Units 4‒6, 87‒86 Ma, Stage II): S-type, containing muscovite + K-feldspar + plagioclase ± tourmaline, with LREE-depleted apatite, higher SiO2 and Rb/Sr, derived from the low-pressure partial melting of Neoproterozoic biotite-rich metagreywackes in the shallow crust during ongoing Neotethys subduction-induced collision, associated with Sn-dominated mineralization (87‒80 Ma, defined as Phase II magmatic-metallogenic event). Geochemical and Isotopic trends suggest mantle-crust interaction during Stage I and crustal recycling during Stage II, both driven by the ongoing subduction of Neotethys. This dual-stage magmatism establishes a dynamic model in which tectonic processes control magma sources, isotopic signatures, and metal partitioning, providing key insights into granite-related Sn polymetallic mineralization in the Bozhushan orefield.
葛九-伯珠山-老君山地区白垩系花岗岩类岩浆活动记录了新特提斯期到华南地块的构造过渡,并与锡多金属成矿有遗传联系。然而,岩浆作用和成矿作用的构造背景仍不清楚,特别是在博珠山矿田。综合全岩地球化学、Sr-Nd-Pb同位素、锆石U-Pb- hf - o同位素、独居石U-Th-Pb-Nd同位素、磷灰石U-Pb- ree数据、锡石U-Pb测年等资料,对3个锡多金属矿床的地壳结构和构造-岩浆成矿作用进行了研究。岩体由6个互指单元组成,其特征为高钾玄玄岩和过铝质成分,并进一步划分为两个岩浆阶段:(1)边缘花岗闪长岩(1 - 3单元,91-90 Ma,第1阶段):I型,以黑云母+钾长石+斜长石为特征,具有高Sr/Y、(La/Yb)N和富lree磷灰石的特征。它们可能源于新特提斯东俯冲过程中岩石圈地幔熔融引发的地壳熔融,并与外围的Ag-Pb-Zn-W多金属成矿作用(约91 ~ 89 Ma,定义为ⅰ期岩浆成矿事件)有关。(2)位于岩心的高演化二长花岗岩(4 ~ 6单元,87 ~ 86 Ma, II期):s型,含白云母+钾长石+斜长石±电气石,含贫lree磷灰石,较高的SiO2和Rb/Sr,形成于新元古代在新特提斯期俯冲诱发碰撞过程中,浅部地壳中富含黑云母的偏长花岗岩低压部分熔融,与锡为主的成矿作用(87 ~ 80 Ma,定义为II期岩浆成矿事件)有关。地球化学和同位素趋势表明,第一阶段的幔壳相互作用和第二阶段的地壳再循环都是由新特提斯的持续俯冲所驱动的。这一双期岩浆活动建立了构造过程控制岩浆来源、同位素特征和金属分配的动力学模型,为研究博珠山矿田花岗岩相关锡多金属成矿提供了重要依据。
{"title":"Two phases of high potassic-shoshonitic magmatism and coeval Sn polymetallic mineralization in the Bozhushan orefield, southwestern China","authors":"Yanbin Liu ,&nbsp;Guochen Dong ,&nbsp;M. Santosh ,&nbsp;Dapeng Li ,&nbsp;Liangliang Zhang ,&nbsp;Sen Wang","doi":"10.1016/j.gsf.2025.102157","DOIUrl":"10.1016/j.gsf.2025.102157","url":null,"abstract":"<div><div>The Cretaceous granitoid magmatism in the Gejiu-Bozhushan-Laojunshan region records tectonic transitions from the Neotethys to the South China Block and is genetically linked to Sn-polymetallic mineralization. However, the tectonic settings of magmatism and metallogeny remain unclear, particularly in the Bozhushan orefield. Integrated whole-rock geochemistry, Sr-Nd-Pb isotopes, zircon U-Pb-Hf-O isotopes, monazite U-Th-Pb-Nd isotopes, apatite U-Pb-REE data from the Bozhushan pluton, and cassiterite U-Pb dating from three Sn-polymetallic deposits are presented to understand the crustal architecture and tectonic-magmatic-metallogeny. The pluton consists of six interdigitated units characterized by high potassic-shoshonitic and peraluminous compositions, which are further subdivided into two magmatic stages: (1) Rim-located granodiorites (Units 1‒3, 91‒90 Ma, Stage I): I-type, characterized by the presence of biotite + K-feldspar + plagioclase, and featuring high Sr/Y, (La/Yb)<sub>N</sub>, and LREE-enriched apatite. They likely originate from lithospheric mantle melting during eastward Neotethys subduction, which triggered crustal melting and is linked to peripheral Ag-Pb-Zn-W polymetallic mineralization (ca. 91‒89 Ma, defined as Phase I magmatic-metallogenic event). (2) Core-located high evolved monzogranites (Units 4‒6, 87‒86 Ma, Stage II): S-type, containing muscovite + K-feldspar + plagioclase ± tourmaline, with LREE-depleted apatite, higher SiO<sub>2</sub> and Rb/Sr, derived from the low-pressure partial melting of Neoproterozoic biotite-rich metagreywackes in the shallow crust during ongoing Neotethys subduction-induced collision, associated with Sn-dominated mineralization (87‒80 Ma, defined as Phase II magmatic-metallogenic event). Geochemical and Isotopic trends suggest mantle-crust interaction during Stage I and crustal recycling during Stage II, both driven by the ongoing subduction of Neotethys. This dual-stage magmatism establishes a dynamic model in which tectonic processes control magma sources, isotopic signatures, and metal partitioning, providing key insights into granite-related Sn polymetallic mineralization in the Bozhushan orefield.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102157"},"PeriodicalIF":8.9,"publicationDate":"2025-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266543","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The H2 generation mechanisms of natural gas in the Sulige gas field, Ordos Basin, China 鄂尔多斯盆地苏里格气田天然气生氢机理
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-11-01 Epub Date: 2025-09-12 DOI: 10.1016/j.gsf.2025.102153
Panpan Zhang , Zhijun Jin , Xiaomei Wang , Kun He , Zhenguang Shang , Jinhao Guo , Xuan Tang , Runchao Liu , Runze Cui , Qitu Hu
Due to its renewability, zero-emissions, and low production cost, natural hydrogen (H2) holds considerable potential as a carbon-free energy resource and represents a key focus for enabling energy transition and achieving carbon neutrality. The generation mechanisms and accumulation patterns of H2 need further investigation, particularly with regard to the sources of H2 in sedimentary basin. This knowledge gap hinders the exploration and development of H2 resources. The study reports the concentrations and isotopic compositions of H2 and hydrocarbons of natural gas in the Sulige gas field. The results suggest that the H2 content in natural gas can reach up to 22.98 %, with H2 isotope values (δ2H-H2) ranging from −809‰ to −700‰. Based on comprehensive analysis of carbon and hydrogen isotopes of hydrocarbons, geological conditions, and hydrogen isotope fractionation mechanisms of H2, this study reveals that the H2 in the Upper Paleozoic natural gas is likely derived primarily from organic matter pyrolysis in coal-bearing source rocks, while the H2 in the Lower Paleozoic natural gas is probably generated mainly through water radiolytic in basement granite and metamorphic rocks. The diffusion fractionation model demonstrates that significant isotopic fractionation occurs during the migration of deep-sourced H2 to sedimentary reservoirs, resulting in notably depleted δ2H-H2 values in the Lower Paleozoic natural gas. The H2 generation through organic matter pyrolysis primarily occurs during the late gas generation stage, with peak production concentrated in the Late Triassic to Early Cretaceous periods. Given the genetic correlation between H2 and hydrocarbons, the H2 may accumulate with natural gas in reservoirs. In contrast, H2 generation through water radiolysis in the study area exhibits multi-source characteristics and prolonged duration, demonstrating significant potential for independent accumulation. This study not only elucidates the generation mechanisms of H2 but also provides a significant geological case study for understanding the distribution characteristics and resource potential of H2 in sedimentary basins.
由于其可再生、零排放和低生产成本,天然氢(H2)作为一种无碳能源具有相当大的潜力,是实现能源转型和实现碳中和的关键焦点。H2的生成机制和富集模式有待进一步研究,特别是沉积盆地H2的来源问题。这种知识差距阻碍了H2资源的勘探和开发。研究报告了苏里格气田天然气中H2和碳氢化合物的浓度和同位素组成。结果表明,天然气中H2含量可达22.98%,H2同位素值(δ2H-H2)在−809‰~−700‰之间。综合分析烃类碳、氢同位素、地质条件和氢同位素分馏机理,认为上古生界天然气中的H2可能主要来源于含煤烃源岩中的有机质热解,而下古生界天然气中的H2可能主要来源于基底花岗岩和变质岩中的水辐射裂解。扩散分馏模型表明,深源H2向沉积储层运移过程中发生了明显的同位素分馏,导致下古生界天然气δ2H-H2值明显下降。有机质热解制氢主要发生在晚期生气阶段,高峰期集中在晚三叠世至早白垩世。考虑到H2与烃类的成因相关性,H2可能随天然气在储层中聚集。研究区水溶制氢具有多源、持续时间长的特点,具有较大的独立富集潜力。该研究不仅阐明了H2的生成机制,而且为了解沉积盆地H2的分布特征和资源潜力提供了重要的地质实例研究。
{"title":"The H2 generation mechanisms of natural gas in the Sulige gas field, Ordos Basin, China","authors":"Panpan Zhang ,&nbsp;Zhijun Jin ,&nbsp;Xiaomei Wang ,&nbsp;Kun He ,&nbsp;Zhenguang Shang ,&nbsp;Jinhao Guo ,&nbsp;Xuan Tang ,&nbsp;Runchao Liu ,&nbsp;Runze Cui ,&nbsp;Qitu Hu","doi":"10.1016/j.gsf.2025.102153","DOIUrl":"10.1016/j.gsf.2025.102153","url":null,"abstract":"<div><div>Due to its renewability, zero-emissions, and low production cost, natural hydrogen (H<sub>2</sub>) holds considerable potential as a carbon-free energy resource and represents a key focus for enabling energy transition and achieving carbon neutrality. The generation mechanisms and accumulation patterns of H<sub>2</sub> need further investigation, particularly with regard to the sources of H<sub>2</sub> in sedimentary basin. This knowledge gap hinders the exploration and development of H<sub>2</sub> resources. The study reports the concentrations and isotopic compositions of H<sub>2</sub> and hydrocarbons of natural gas in the Sulige gas field. The results suggest that the H<sub>2</sub> content in natural gas can reach up to 22.98 %, with H<sub>2</sub> isotope values (<em>δ</em><sup>2</sup>H-H<sub>2</sub>) ranging from −809‰ to −700‰. Based on comprehensive analysis of carbon and hydrogen isotopes of hydrocarbons, geological conditions, and hydrogen isotope fractionation mechanisms of H<sub>2</sub>, this study reveals that the H<sub>2</sub> in the Upper Paleozoic natural gas is likely derived primarily from organic matter pyrolysis in coal-bearing source rocks, while the H<sub>2</sub> in the Lower Paleozoic natural gas is probably generated mainly through water radiolytic in basement granite and metamorphic rocks. The diffusion fractionation model demonstrates that significant isotopic fractionation occurs during the migration of deep-sourced H<sub>2</sub> to sedimentary reservoirs, resulting in notably depleted <em>δ</em><sup>2</sup>H-H<sub>2</sub> values in the Lower Paleozoic natural gas. The H<sub>2</sub> generation through organic matter pyrolysis primarily occurs during the late gas generation stage, with peak production concentrated in the Late Triassic to Early Cretaceous periods. Given the genetic correlation between H<sub>2</sub> and hydrocarbons, the H<sub>2</sub> may accumulate with natural gas in reservoirs. In contrast, H<sub>2</sub> generation through water radiolysis in the study area exhibits multi-source characteristics and prolonged duration, demonstrating significant potential for independent accumulation. This study not only elucidates the generation mechanisms of H<sub>2</sub> but also provides a significant geological case study for understanding the distribution characteristics and resource potential of H<sub>2</sub> in sedimentary basins.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102153"},"PeriodicalIF":8.9,"publicationDate":"2025-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266545","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characteristics and drivers of carbonaceous aerosol pollution in a coastal city of northern China 中国北方沿海城市碳质气溶胶污染特征及其驱动因素
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-11-01 Epub Date: 2025-09-09 DOI: 10.1016/j.gsf.2025.102151
Li Fang , He Meng , Yanjun Yang , Ruiyu Li , Yang Yue , Caiqing Yan
Carbonaceous aerosols significantly impact air quality, human health and climate change, yet their concentration levels and influencing factors exhibit significant regional variability. This study examined the concentration levels and temporal variations of carbonaceous aerosols in Qingdao, a typical coastal city in China, using a year-long, high-time-resolution dataset of organic carbon (OC) and elemental carbon (EC) measurements. The impacts of meteorological conditions, primary emissions, atmospheric oxidants, and sea-land breezes were systematically analyzed by employing an interpretable machine learning model. The results revealed that atmospheric OC and EC concentration levels were relatively low in Qingdao, but secondary organic carbon (SOC) accounted for 43 % of OC, emphasizing the substantial influence of secondary sources. SOC concentrations peaked in the evening, whereas primary organic carbon (POC) and EC concentrations peaked during morning rush hours. The elevated carbonaceous aerosol concentration observed in winter likely resulted from enhanced primary emissions coupled with unfavorable dispersion conditions, whereas intensive photochemical activities during summer facilitated SOC formation. Higher SOC levels were observed during sea-land breeze days than non-sea-land breeze days. The machine learning model indicated that atmospheric oxidants played an important role in SOC formation during sea-land breeze days, while combustion related emissions may be the key factor on non-sea-land breeze days. Furthermore, SOC levels were higher under land breezes compared to sea breezes, likely due to enhanced primary emissions from terrestrial sources coupled with confined pollutant dispersion. These findings revealed complex emission-meteorology-chemistry interactions affecting coastal air quality, informing targeted air pollution mitigation strategies.
碳质气溶胶显著影响空气质量、人类健康和气候变化,但其浓度水平和影响因子表现出显著的区域差异。本研究利用为期一年的高时间分辨率有机碳(OC)和元素碳(EC)测量数据,研究了中国典型沿海城市青岛含碳气溶胶的浓度水平和时间变化。通过采用可解释的机器学习模型,系统地分析了气象条件、一次排放、大气氧化剂和海风的影响。结果表明,青岛市大气OC和EC浓度水平相对较低,但二次有机碳(SOC)占OC的43%,表明二次源对OC的影响较大。有机碳(SOC)浓度在傍晚达到峰值,而原生有机碳(POC)和有机碳(EC)浓度在早高峰时段达到峰值。冬季观测到的碳质气溶胶浓度升高可能是由于一次排放增加加上不利的扩散条件,而夏季强烈的光化学活动促进了有机碳的形成。海陆风日土壤有机碳含量高于非海陆风日。机器学习模型表明,大气氧化剂在海陆风日对有机碳形成起重要作用,而燃烧相关排放可能是非海陆风日的关键因素。此外,与海风相比,陆风下的有机碳水平更高,这可能是由于陆地源的一次排放增加,加上污染物扩散受限。这些发现揭示了影响沿海空气质量的复杂的排放-气象-化学相互作用,为有针对性的空气污染缓解策略提供了信息。
{"title":"Characteristics and drivers of carbonaceous aerosol pollution in a coastal city of northern China","authors":"Li Fang ,&nbsp;He Meng ,&nbsp;Yanjun Yang ,&nbsp;Ruiyu Li ,&nbsp;Yang Yue ,&nbsp;Caiqing Yan","doi":"10.1016/j.gsf.2025.102151","DOIUrl":"10.1016/j.gsf.2025.102151","url":null,"abstract":"<div><div>Carbonaceous aerosols significantly impact air quality, human health and climate change, yet their concentration levels and influencing factors exhibit significant regional variability. This study examined the concentration levels and temporal variations of carbonaceous aerosols in Qingdao, a typical coastal city in China, using a year-long, high-time-resolution dataset of organic carbon (OC) and elemental carbon (EC) measurements. The impacts of meteorological conditions, primary emissions, atmospheric oxidants, and sea-land breezes were systematically analyzed by employing an interpretable machine learning model. The results revealed that atmospheric OC and EC concentration levels were relatively low in Qingdao, but secondary organic carbon (SOC) accounted for 43 % of OC, emphasizing the substantial influence of secondary sources. SOC concentrations peaked in the evening, whereas primary organic carbon (POC) and EC concentrations peaked during morning rush hours. The elevated carbonaceous aerosol concentration observed in winter likely resulted from enhanced primary emissions coupled with unfavorable dispersion conditions, whereas intensive photochemical activities during summer facilitated SOC formation. Higher SOC levels were observed during sea-land breeze days than non-sea-land breeze days. The machine learning model indicated that atmospheric oxidants played an important role in SOC formation during sea-land breeze days, while combustion related emissions may be the key factor on non-sea-land breeze days. Furthermore, SOC levels were higher under land breezes compared to sea breezes, likely due to enhanced primary emissions from terrestrial sources coupled with confined pollutant dispersion. These findings revealed complex emission-meteorology-chemistry interactions affecting coastal air quality, informing targeted air pollution mitigation strategies.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102151"},"PeriodicalIF":8.9,"publicationDate":"2025-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145105640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermokarst disturbance responses to climate change across the circumpolar permafrost regions from 1990 to 2023 1990 - 2023年环极多年冻土区热岩溶扰动对气候变化的响应
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-11-01 Epub Date: 2025-09-02 DOI: 10.1016/j.gsf.2025.102147
Ya Liu , Haijun Qiu , Ninglian Wang , Dongdong Yang , Kailiang Zhao , Guoqing Yang , Wenchao Huangfu , Wanqi Luo
Warming climate drives permafrost degradation and forms serious thermokarst disturbances, with significant impacts on geomorphology, hydrology, and ecological processes. However, the long-term monitoring of thermokarst disturbances and their next development remains a challenge across the circumpolar permafrost regions. Here, we calculate six spectral indices from Landsat images to represent greenness, wetness, and brightness, quantifying the spatiotemporal characteristics of thermokarst landscape dynamics and further revealing their development with a warming climate. Additionally, DNMI, NDWI, and NDVI are selected to verify the occurrence and severity of retrogressive thaw slumps, thermokarst lake expansion, and drainage by the LandTrendr algorithm on the Google Earth Engine platform. Three major types of thermokarst events show a consistent disturbance year, correlating with the summer temperature increase point around 2000. Their correlation analysis also reveals that the subsequent landscape development of thermokarst disturbances is related to the warming context, showing vegetation greening and soil wetting trends. These findings highlight the dynamic characteristics of thermokarst disturbances from 1990 to 2023, providing a comprehensive understanding of thermokarst development under a changing climate.
气候变暖导致多年冻土退化,形成严重的热岩溶扰动,对地貌、水文和生态过程产生重大影响。然而,对热岩溶扰动及其下一步发展的长期监测仍然是整个极地多年冻土区的一个挑战。在此基础上,我们利用Landsat图像计算了代表绿度、湿度和亮度的6个光谱指数,量化了热岩溶景观动态的时空特征,并进一步揭示了它们随气候变暖的发展。利用谷歌Earth Engine平台上的LandTrendr算法,选择DNMI、NDWI和NDVI来验证退行性融塌、热岩溶湖扩张和排水的发生和严重程度。三种主要热岩溶事件表现出一致的扰动年,与2000年左右的夏季增温点相关。二者的相关分析还表明,热岩溶扰动的后续景观发展与气候变暖背景有关,表现为植被绿化和土壤湿润趋势。这些发现突出了1990 - 2023年热岩溶扰动的动态特征,为全面了解气候变化下的热岩溶发育提供了依据。
{"title":"Thermokarst disturbance responses to climate change across the circumpolar permafrost regions from 1990 to 2023","authors":"Ya Liu ,&nbsp;Haijun Qiu ,&nbsp;Ninglian Wang ,&nbsp;Dongdong Yang ,&nbsp;Kailiang Zhao ,&nbsp;Guoqing Yang ,&nbsp;Wenchao Huangfu ,&nbsp;Wanqi Luo","doi":"10.1016/j.gsf.2025.102147","DOIUrl":"10.1016/j.gsf.2025.102147","url":null,"abstract":"<div><div>Warming climate drives permafrost degradation and forms serious thermokarst disturbances, with significant impacts on geomorphology, hydrology, and ecological processes. However, the long-term monitoring of thermokarst disturbances and their next development remains a challenge across the circumpolar permafrost regions. Here, we calculate six spectral indices from Landsat images to represent greenness, wetness, and brightness, quantifying the spatiotemporal characteristics of thermokarst landscape dynamics and further revealing their development with a warming climate. Additionally, DNMI, NDWI, and NDVI are selected to verify the occurrence and severity of retrogressive thaw slumps, thermokarst lake expansion, and drainage by the LandTrendr algorithm on the Google Earth Engine platform. Three major types of thermokarst events show a consistent disturbance year, correlating with the summer temperature increase point around 2000. Their correlation analysis also reveals that the subsequent landscape development of thermokarst disturbances is related to the warming context, showing vegetation greening and soil wetting trends. These findings highlight the dynamic characteristics of thermokarst disturbances from 1990 to 2023, providing a comprehensive understanding of thermokarst development under a changing climate.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102147"},"PeriodicalIF":8.9,"publicationDate":"2025-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145105584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crustal contamination and insights into diachronous changes toward modern tectonics: evidence from Hf-Nd-O-Pb isotope of sanukitoids from the Amazonian craton 地壳污染及其对现代构造历时变化的认识:来自亚马逊克拉通sanukit类Hf-Nd-O-Pb同位素的证据
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-11-01 Epub Date: 2025-10-23 DOI: 10.1016/j.gsf.2025.102172
Aline Costa do Nascimento , Davis Carvalho de Oliveira , Esa Heilimo , Marco Antonio Galarza , Eleilson Oliveira Gabriel , Martin Whitehouse , Matti Kurhila , Cláudio Nery Lamarão
Archean sanukitoids provide crucial insights into crust-mantle interactions during the early Earth’s geodynamic evolution. However, the role of crustal contamination in their genesis remains uncertain. Sanukitoids identified in the Sapucaia subdomain of the southern Carajás Province are represented by two plutons Água Limpa and Água Azul, collectively referred to as the Água Limpa sanukitoid suite. These plutons are compositionally similar to low-Ti sanukitoids (< 0.63 % TiO2) and their zircon isotopic data record a short period of magmatic activity around ca. 2.87 Ga. Sanukitoids zircons reveal εHf(t) values ranging from –3.31 to + 2.14, Hf and Nd model ages between 2.91 Ga and 3.28 Ga, whole-rock εNd(t) values from –1.64 to + 1.76, and δ18O values ranging from 5.0 ‰ to 7.6 ‰. The Pb isotopic compositions in K-feldspar (µ > 10) suggests a Mesoarchean mantle source affected by slight crustal contribution and/or contamination. Result of geochemical modelling indicates that the sanukitoids were formed by ∼ 15 % partial melting of mantle peridotite previously enriched by ∼ 30 % of slab-derived melts, with orthopyroxene, garnet, clinopyroxene, phlogopite, and magnetite as residual phases. The integration of our data with previously published results leads us to suggest that modern-style plate tectonics may have initiated along the northern Carajás Province during the Mesoarchean, while the Rio Maria domain to the south remained dominated by mantle plume-driven crustal growth and vertical tectonics.
太古代sanukitoids提供了对早期地球动力学演化过程中地壳-地幔相互作用的重要见解。然而,地壳污染在其成因中的作用仍不确定。在Carajás省南部Sapucaia亚域中发现的sanukitoid以Água Limpa和Água Azul两个岩体为代表,统称为Água Limpa sanukitoid套。这些岩体在成分上与低钛类岩浆岩(< 0.63% TiO2)相似,它们的锆石同位素数据记录了大约2.87 Ga左右的短时间岩浆活动。Sanukitoids锆石的εHf(t)值在-3.31 ~ + 2.14之间,Hf和Nd模式年龄在2.91 ~ 3.28 Ga之间,全岩εNd(t)值在-1.64 ~ + 1.76之间,δ18O值在5.0‰~ 7.6‰之间。钾长石Pb同位素组成(µ> 10)表明中太古代地幔源受到轻微地壳贡献和/或污染的影响。地球化学模拟结果表明,类sanukitoite是由地幔橄榄岩的~ 15%部分熔融形成的,之前富含~ 30%的板岩衍生熔体,剩余相为正辉石、石榴石、斜辉石、辉云母和磁铁矿。综合我们的数据和先前发表的结果,我们认为现代板块构造可能在中太古宙期间沿Carajás省北部开始,而南部的里约热内卢Maria域仍然以地幔柱驱动的地壳生长和垂直构造为主。
{"title":"Crustal contamination and insights into diachronous changes toward modern tectonics: evidence from Hf-Nd-O-Pb isotope of sanukitoids from the Amazonian craton","authors":"Aline Costa do Nascimento ,&nbsp;Davis Carvalho de Oliveira ,&nbsp;Esa Heilimo ,&nbsp;Marco Antonio Galarza ,&nbsp;Eleilson Oliveira Gabriel ,&nbsp;Martin Whitehouse ,&nbsp;Matti Kurhila ,&nbsp;Cláudio Nery Lamarão","doi":"10.1016/j.gsf.2025.102172","DOIUrl":"10.1016/j.gsf.2025.102172","url":null,"abstract":"<div><div>Archean sanukitoids provide crucial insights into crust-mantle interactions during the early Earth’s geodynamic evolution. However, the role of crustal contamination in their genesis remains uncertain. Sanukitoids identified in the Sapucaia subdomain of the southern Carajás Province are represented by two plutons Água Limpa and Água Azul, collectively referred to as the Água Limpa sanukitoid suite. These plutons are compositionally similar to low-Ti sanukitoids (&lt; 0.63 % TiO<sub>2</sub>) and their zircon isotopic data record a short period of magmatic activity around ca. 2.87 Ga. Sanukitoids zircons reveal <em>ε</em><sub>Hf</sub>(<em>t</em>) values ranging from –3.31 to + 2.14, Hf and Nd model ages between 2.91 Ga and 3.28 Ga, whole-rock <em>ε</em><sub>Nd</sub>(<em>t</em>) values from –1.64 to + 1.76, and <em>δ</em><sup>18</sup>O values ranging from 5.0 ‰ to 7.6 ‰. The Pb isotopic compositions in K-feldspar (<em>µ</em> &gt; 10) suggests a Mesoarchean mantle source affected by slight crustal contribution and/or contamination. Result of geochemical modelling indicates that the sanukitoids were formed by ∼ 15 % partial melting of mantle peridotite previously enriched by ∼ 30 % of slab-derived melts, with orthopyroxene, garnet, clinopyroxene, phlogopite, and magnetite as residual phases. The integration of our data with previously published results leads us to suggest that modern-style plate tectonics may have initiated along the northern Carajás Province during the Mesoarchean, while the Rio Maria domain to the south remained dominated by mantle plume-driven crustal growth and vertical tectonics.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102172"},"PeriodicalIF":8.9,"publicationDate":"2025-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145358042","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Generative AI with prompt engineering in construction: Enhancing predictive slope stability modelling for safe, sustainable, climate-smart mining practices 生成式人工智能与施工中的快速工程:加强预测边坡稳定性建模,实现安全、可持续、气候智能型采矿实践
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-11-01 Epub Date: 2025-09-22 DOI: 10.1016/j.gsf.2025.102163
Muhammad Kamran , Muhammad Faizan , Shuhong Wang , Danial Jahed Armaghani , Panagiotis G. Asteris , Biswajeet Pradhan
Generative AI (GenAI) and prompt engineering are rapidly advancing in industries such as construction and mining, leading to significant improvements in efficiency, accuracy, and decision-making processes. These technologies are transforming the construction sector by automating tasks and optimizing workflows, thereby enhancing productivity and risk management. This study explores the application of Google’s Gemini AI tool, a notable breakthrough in GenAI, specifically for predictive modeling of slope stability. The Gemini AI tool is utilized within the Python programming language to generate prompts that incorporate key factors influencing slope stability, with the Google Colab interface facilitating prompt generation and testing. Initially, these prompts are employed for data analysis and visualization, followed by their application in both unsupervised and supervised machine learning approaches. The performance evaluation metrics indicate that the integrated approaches, which combine GenAI and prompt engineering, predict slope stability with a high level of accuracy. The model achieved 99% accuracy, with precision, recall, and F1-scores ranging from 0.98 to 1.00 for both stable and unstable slope classes. This innovative methodology seeks to advance the implementation of GenAI in civil and mining engineering, offering more precise and efficient solutions for managing slope stability and supporting safe, sustainable, and climate-smart mining operations.
生成式人工智能(GenAI)和即时工程在建筑和采矿等行业迅速发展,大大提高了效率、准确性和决策过程。这些技术正在通过自动化任务和优化工作流程来改变建筑行业,从而提高生产力和风险管理。本研究探索了谷歌的Gemini AI工具的应用,该工具是GenAI的重大突破,专门用于边坡稳定性的预测建模。Gemini AI工具在Python编程语言中用于生成包含影响边坡稳定性的关键因素的提示,谷歌Colab接口促进提示生成和测试。最初,这些提示用于数据分析和可视化,然后将其应用于无监督和有监督的机器学习方法。性能评价指标表明,将GenAI和提示工程相结合的综合方法预测边坡稳定性具有较高的精度。该模型达到了99%的准确率,对于稳定和不稳定的斜坡类别,精度、召回率和f1得分范围为0.98到1.00。这种创新的方法旨在推进GenAI在土木和采矿工程中的实施,为管理边坡稳定性和支持安全、可持续和气候智能型采矿作业提供更精确、更有效的解决方案。
{"title":"Generative AI with prompt engineering in construction: Enhancing predictive slope stability modelling for safe, sustainable, climate-smart mining practices","authors":"Muhammad Kamran ,&nbsp;Muhammad Faizan ,&nbsp;Shuhong Wang ,&nbsp;Danial Jahed Armaghani ,&nbsp;Panagiotis G. Asteris ,&nbsp;Biswajeet Pradhan","doi":"10.1016/j.gsf.2025.102163","DOIUrl":"10.1016/j.gsf.2025.102163","url":null,"abstract":"<div><div>Generative AI (GenAI) and prompt engineering are rapidly advancing in industries such as construction and mining, leading to significant improvements in efficiency, accuracy, and decision-making processes. These technologies are transforming the construction sector by automating tasks and optimizing workflows, thereby enhancing productivity and risk management. This study explores the application of Google’s Gemini AI tool, a notable breakthrough in GenAI, specifically for predictive modeling of slope stability. The Gemini AI tool is utilized within the Python programming language to generate prompts that incorporate key factors influencing slope stability, with the Google Colab interface facilitating prompt generation and testing. Initially, these prompts are employed for data analysis and visualization, followed by their application in both unsupervised and supervised machine learning approaches. The performance evaluation metrics indicate that the integrated approaches, which combine GenAI and prompt engineering, predict slope stability with a high level of accuracy. The model achieved 99% accuracy, with precision, recall, and F<sub>1</sub>-scores ranging from 0.98 to 1.00 for both stable and unstable slope classes. This innovative methodology seeks to advance the implementation of GenAI in civil and mining engineering, offering more precise and efficient solutions for managing slope stability and supporting safe, sustainable, and climate-smart mining operations.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 6","pages":"Article 102163"},"PeriodicalIF":8.9,"publicationDate":"2025-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145154657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Geoscience frontiers
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1