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Early–Middle Permian paleogeomorphic transformations in the northwestern Upper Yangtze region: Implications for the evolution of the eastern Paleo-Tethys oceans 上扬子地区西北部早-中二叠世古地貌转变:对古特提斯东部海洋演化的启示
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-11-01 DOI: 10.1016/j.gsf.2025.102204
Minglong Li , Qiang Xu , Xiucheng Tan , Bing Luo , Yuan Zhong , Di Xiao , Zhanfeng Qiao , Wenjie Yang , Qilong Yang , Yu Cao
Understanding how the multi-branches subduction of the Paleo-Tethyan Ocean controlled the intraplate tectono-sedimentary evolution of the South China Block (SCB) is fundamental to comprehending the mechanisms of ocean-continent transformation in cratonic basins and the formation of the Sichuan super-basin. This study investigated the Lower–Middle Permian successions (Liangshan, Chihsia, and Maokou formations) on the northwestern margin of the SCB, a critical area lies at the junction between the Songpan–Garzê and Qinling tectonic domains. These Permian successions are subdivided into four three-order sequences based on an isochronous stratigraphic framework that integrates various analyses of lithofacies, gamma-ray, stable isotopes, and zircon U-Pb ages. Lithofacies associations reveal that Lower-Middle Permian sequences record the sedimentary evolution process from shore–swamp environments to rimmed platforms. The paleogeomorphology pattern transitioned from a northwest lowland and southeast highland in the early Permian to a northeast lowland and southwest highland in the middle Permian, with corresponding development of linear high-energy grain shoals trending to northeast and northwest, respectively. These changes in lithofacies and paleogeography were attributed to the evolution of multiple branches of the Paleo-Tethyan, including the opening of the Garzê–Litang back-arc Ocean, along the western margin of the SCB in the Early Permian, followed by the rapid northward subduction of the Mianlue Ocean stretching along the northern margin of the SCB. Our findings demonstrate the regional cratonic tectono-sedimentary evolution coupled the multi-stage and multi-directional subduction of Paleo-Tethyan oceanic branches enhances our understanding of global deep-time multi-sphere interactions.
了解古特提斯洋多支俯冲作用如何控制华南地块的板内构造-沉积演化,是理解克拉通盆地洋陆转换机制和四川超级盆地形成的基础。本文研究了华南西北缘下-中二叠统(凉山组、赤峡组和茅口组),这是Songpan-Garzê和秦岭构造域交界处的关键区域。根据等时地层格架,结合各种岩相、伽马射线、稳定同位素和锆石U-Pb年龄分析,这些二叠纪序列被细分为四个三阶层序。岩相组合揭示了下-中二叠统层序记录了滨沼环境到边缘台地的沉积演化过程。古地貌格局由早二叠世的西北低地、东南高地向中二叠世的东北低地、西南高地转变,相应发育向东北、向西北的线状高能粒滩。这些岩相和古地理的变化归因于古特提斯的多个分支的演化,包括早二叠世沿南海西缘的Garzê-Litang弧后洋的打开,以及随后沿南海北缘的绵略洋的快速北俯冲。研究结果表明,区域性克拉通构造-沉积演化与古特提斯大洋分支的多阶段多向俯冲相结合,增强了我们对全球深时多球相互作用的认识。
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引用次数: 0
An integrated geochemical and hydrological approach for the conceptualization of surface-water/groundwater interactions in a transboundary river basin of the western Himalayas 西喜马拉雅跨界河流流域地表水/地下水相互作用概念化的综合地球化学和水文方法
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-11-01 DOI: 10.1016/j.gsf.2025.102203
Tanveer Dar , Nachiketa Rai , Akhtar Jahan , Mohd Aadil Bhat , Sudhir Kumar
Surface water–groundwater (SW–GW) interactions at the basin scale are critical for effective water resource management but remain poorly constrained in Himalayan river systems. This study integrates hydrogeochemical (major and trace elements), isotopic (2H, 3H, 18O), and hydrogeological data to investigate water origin, residence time, hydrochemical evolution, and SW–GW connectivity in the transboundary Upper Jhelum River Basin (UJRB), western Himalayas. Hydrogeochemical facies analysis reveals that recharge waters (RW) and shallow groundwater (SGW) are dominated by Ca2+–Mg2+–HCO3 facies, while deep groundwater (DGW) evolves towards Ca2+–Na+–HCO3 facies, reflecting prolonged water–rock interaction. Seasonal variability highlights the influence of aquifer residence time and localized anthropogenic inputs on water chemistry. SW–GW interactions are evident in the transition from Ca2+–Mg2+–HCO3 in tributary waters to mixed facies in groundwater, indicating active recharge and subsequent mineral dissolution. Mixing model results (δ18O and EC) show that groundwater is the dominant contributor to river baseflow, with contributions of 66 % ± 7 % in winter and 39 % ± 10 % in spring. River gaining conditions were identified along the alluvial and lacustrine plains, while localized losing stream conditions occurred near mountain front zones. Water–rock interactions, confirmed by Gibbs plots, govern basin hydrochemistry. Carbonate dissolution, gypsum dissolution, and silicate weathering are the primary processes, while Na-silicate weathering from the Panjal Traps shapes tributary chemistry. Ion exchange (Ca2+–Na+ and Mg2+–Na+ substitutions) further modifies groundwater composition along flow paths. Anthropogenic impacts, including wastewater infiltration and agricultural runoff, contribute to elevated Cl, SO42−, and trace metal levels in specific zones. Evaporation effects are limited but elevate TDS locally. Glacier meltwater, characterized by Na+–Cl–SO42− facies, reflects atmospheric deposition and plays a minor hydrochemical role. These integrated findings underpin a conceptual flow model demonstrating how lithology, recharge dynamics, and anthropogenic pressures collectively shape SW–GW interactions. The results provide critical insights for managing transboundary Himalayan aquifers and sustaining river baseflows essential for regional water security.
地表水-地下水(SW-GW)在流域尺度上的相互作用对有效的水资源管理至关重要,但在喜马拉雅河流系统中仍然缺乏约束。综合水文地球化学(主要元素和微量元素)、同位素(2H、3H、18O)和水文地质资料,对喜马拉雅西部跨界上杰勒姆河流域(UJRB)的水源、停留时间、水化学演化和SW-GW连通性进行了研究。水文地球化学相分析表明,补给水(RW)和浅层地下水(SGW)以Ca2+ -Mg2 + -HCO3−相为主,而深层地下水(DGW)则向Ca2+ -Na + -HCO3−相演化,反映了长期的水岩相互作用。季节变率突出了含水层停留时间和局部人为输入对水化学的影响。从支流的Ca2+ -Mg2 + -HCO3 -向地下水的混合相转变过程中,SW-GW相互作用明显,表明活跃的补给和随后的矿物溶解。混合模型(δ18O和EC)结果表明,地下水是河流基流的主要贡献者,冬季贡献66%±7%,春季贡献39%±10%。沿冲积平原和湖泊平原确定了河流获得条件,而局部河流失去条件发生在山前带附近。吉布斯图证实了水岩相互作用支配着盆地的水化学。碳酸盐溶蚀、石膏溶蚀和硅酸盐风化是主要的作用过程,而来自Panjal圈闭的钠硅酸盐风化形成了支流化学。离子交换(Ca2+ -Na +和Mg2+ -Na +取代)进一步改变了沿流道的地下水成分。人为影响,包括废水入渗和农业径流,导致特定区域Cl−、SO42−和痕量金属水平升高。蒸发效应有限,但局部升高TDS。冰川融水以Na+ -Cl−-SO42−相为特征,反映大气沉积,水化学作用较小。这些综合发现支持了一个概念性流动模型,该模型展示了岩性、补给动力学和人为压力如何共同影响SW-GW相互作用。研究结果为管理跨界喜马拉雅含水层和维持对区域水安全至关重要的河流基流提供了重要见解。
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引用次数: 0
Ecological risk of selenium, cadmium, and arsenic in high-background sedimentary terranes: Insights from element enrichment and speciation in rocks 高背景沉积地体中硒、镉和砷的生态风险:来自岩石元素富集和物种形成的见解
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-10-30 DOI: 10.1016/j.gsf.2025.102191
Minglong Li , Hai-Bo Qin , Yunfen Zhu , Lan Yao , Xunru Ai , Liang Qiu , Deshun Zheng
The main geological factors causing high levels of heavy metals (HMs) in soils in areas with sedimentary rocks are the exposure of black rock series (BRS) and the development of karst. The combined relationships, background concentrations, and speciation of Se and HMs in clastic rocks, carbonate rocks, and BRS remain unclear, which restricts HM traceability and remediation in high background soils. This study focuses on Ediacaran to Jurassic sedimentary rocks in South China and determines the total concentrations of Se, Cu, Zn, Pb, Hg, Cd, Cr, As, Ni, and total organic carbon (TOC), as well as their speciation. The results indicate that the TOC in sedimentary rocks is significantly positively correlated with Se, Hg, Cd, Cr, and Ni, followed by Cu and As, but not Pb and Zn. Cluster analysis reveals that Se is strongly associated with Cd and As. Compared with those in the upper continental crust (UCC), the enrichment levels of elements in BRS are ordered Se > Cd > Hg > As > Cr > Ni > Cu > Pb > Zn. The mean concentrations of Se, Cd, Hg, and As in BRS are 957.8, 62.9, 28.4, and 8.5 times those in the UCC, respectively. These elements are also relatively enriched in carbonate rocks. A risk assessment based on speciation indicates that Cd, Se and As in BRS have the greatest ecological risks, as well as Cd and As in carbonate rocks. Active speciation of Hg in all three rock types is less than 0.1% of the soil risk screening, indicating low risk. Therefore, the elevated risks of Cd, Se, and As in high-background areas may fundamentally stem from parent rocks. With a limited budget, the immediate focus should be on remediating Cd, As, and Se in the BRS areas, while also stepping up monitoring of Cd and As in the karst zones.
沉积岩区土壤中重金属含量高的主要地质因素是黑色岩系的暴露和岩溶发育。碎屑岩、碳酸盐岩和BRS中Se和HM的组合关系、背景浓度和形态尚不清楚,这限制了高背景土壤中HM的可追溯性和修复。以华南埃迪卡拉系—侏罗系沉积岩为研究对象,测定了Se、Cu、Zn、Pb、Hg、Cd、Cr、As、Ni、总有机碳(TOC)的总浓度及其形态。结果表明:沉积岩TOC与Se、Hg、Cd、Cr、Ni呈显著正相关,其次为Cu、As, Pb、Zn不显著;聚类分析表明,硒与镉、砷有较强的相关性。与上陆壳(UCC)相比,BRS元素富集程度依次为Se >; Cd > Hg > As > Cr > Ni > Cu > Pb > Zn。BRS中Se、Cd、Hg和As的平均浓度分别是UCC的957.8倍、62.9倍、28.4倍和8.5倍。这些元素在碳酸盐岩中也相对富集。基于物种形态的风险评价表明,BRS中Cd、Se和As的生态风险最大,碳酸盐岩中Cd和As的生态风险最大。三种岩石类型中汞的活性形态均低于土壤风险筛选的0.1%,表明风险较低。因此,Cd、Se和As在高背景地区的风险升高可能主要来自母岩。在预算有限的情况下,当务之急应该是修复BRS地区的Cd、As和Se,同时加强喀斯特地区Cd和As的监测。
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引用次数: 0
Lithospheric thickness controls the porphyry Cu mineralization: Evidence from neighboring arc volcanic rocks 岩石圈厚度控制斑岩型铜成矿:来自邻近弧火山岩的证据
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-10-29 DOI: 10.1016/j.gsf.2025.102189
Yin-Hong Wang, Jun Deng, Jia-Jun Liu, Fang-Fang Zhang, Jin-Gao Liu, Shan Ke, Kang Wang, Zhong-Yu Zhang
It is widely considered that porphyry Cu deposits formed via oceanic slab subduction are closely associated with hydrous and oxidized arc magmas. Of note, two suites of neighboring (∼40 km apart) Carboniferous arc volcanic rocks in Northwest China show different extents of mineralization: volcanic rocks from the Dananhu arc (DNHA) host one of the most important porphyry Cu deposit belts in China, whereas those from the Yamansu arc (YMSA), adjacent to DNHA, are ore-barren. These arc volcanic rocks, thus, provide a precious opportunity to explore the main factor that controls the genetic links between coeval arc lavas and porphyry Cu mineralization. Here we report whole rock major and trace element compositions and Mg–Sr–Nd–Pb isotopic data, generating a comprehensive geochemical comparison for these two suites of volcanic rocks from basalt to dacite. The whole-rock geochemical analyses suggest that at a given SiO2 content, the YMSA basalts show lower MgO, CaO, Fe2O3T, and TiO2 contents than the DNHA basalts. The DNHA volcanic rocks have higher Sr/Y and (La/Yb)N ratios, which are positively correlated, indicating that these two suites of rocks were derived from different magma sources. The DNHA rocks are characterized by radiogenic Pb isotopic compositions with 206Pb/204Pb up to 19.457, clearly distinct from the YMSA volcanic rocks with less radiogenic Pb isotopic compositions (206Pb/204Pb = 18.146–18.487), suggesting variable assimilation of crust-derived components during magma evolution. The δ26Mg values of the DNHA rocks (−0.35‰ to +0.06‰) are largely similar to those of the YMSA rocks (−0.24‰ to +0.04‰), and both sets of isotopic ratio ranges have tendency toward heavy Mg isotopes, which could be attributed to serpentinite-derived high-δ26Mg fluids in their mantle sources. Both suites of arc lavas have constant Cu contents and Cu/Sc ratios, indicating inconspicuous pre-enrichment of Cu contents. Geochemical comparisons indicate that the DNHA rocks were derived from partial melting of peridotite at the depth around the spinel-garnet transitional stability field, whereas the YMSA rocks were derived from partial melting of spinel peridotite, and the DNHA magmas had a thicker overlying plate than that of the YMSA magmas. The thickened arc lithosphere facilitates water-rich magmas accumulation and garnet fractionation, driving the magmas to become more oxidized, thereby preventing sulfide segregation and releasing sulfide-bound Cu. Thus, magmas differentiation in the thickened arc lithosphere is a key factor influencing porphyry Cu ore potential.
普遍认为,洋板俯冲形成的斑岩型铜矿床与含水氧化弧岩浆密切相关。值得注意的是,中国西北两套相邻的石炭系弧火山岩(相距约40公里)显示出不同程度的成矿作用:来自大南湖弧(DNHA)的火山岩是中国最重要的斑岩型铜矿带之一,而来自与DNHA相邻的亚曼苏弧(YMSA)的火山岩则是无矿的。这些弧火山岩为探索控制同代弧熔岩与斑岩型铜成矿成因联系的主要因素提供了宝贵的机会。本文报道了全岩主微量元素组成和Mg-Sr-Nd-Pb同位素数据,对玄武岩-英安岩两套火山岩进行了全面的地球化学比较。全岩地球化学分析表明,在一定SiO2含量下,YMSA玄武岩的MgO、CaO、Fe2O3T和TiO2含量低于DNHA玄武岩。DNHA火山岩具有较高的Sr/Y和(La/Yb)N比值,两者正相关,表明两套火山岩来源于不同的岩浆源。DNHA火山岩具有206Pb/204Pb高达19.457的放射性成因Pb同位素组成特征,与放射性成因较少的YMSA火山岩(206Pb/204Pb = 18.146 ~ 18.487)明显不同,表明岩浆演化过程中地壳源成分的同化作用是变化的。DNHA岩石的δ26Mg值(- 0.35‰~ +0.06‰)与YMSA岩石的δ26Mg值(- 0.24‰~ +0.04‰)基本相似,两组同位素比值范围均有重Mg同位素的趋势,这可能是由于地幔源中蛇纹岩衍生的高δ26Mg流体所致。两套弧熔岩的Cu含量和Cu/Sc比值均保持不变,表明其预富集不明显。地球化学对比表明,DNHA岩石来源于尖晶石-石榴石过渡稳定场周围深部橄榄岩的部分熔融,而YMSA岩石来源于尖晶石橄榄岩的部分熔融,且DNHA岩浆的上覆板块较YMSA岩浆厚。加厚的弧形岩石圈有利于富水岩浆的聚集和石榴石分选,促使岩浆更加氧化,从而阻止硫化物偏析,释放出硫化物结合的Cu。因此,加厚弧岩石圈岩浆分异是影响斑岩型铜矿潜力的关键因素。
{"title":"Lithospheric thickness controls the porphyry Cu mineralization: Evidence from neighboring arc volcanic rocks","authors":"Yin-Hong Wang,&nbsp;Jun Deng,&nbsp;Jia-Jun Liu,&nbsp;Fang-Fang Zhang,&nbsp;Jin-Gao Liu,&nbsp;Shan Ke,&nbsp;Kang Wang,&nbsp;Zhong-Yu Zhang","doi":"10.1016/j.gsf.2025.102189","DOIUrl":"10.1016/j.gsf.2025.102189","url":null,"abstract":"<div><div>It is widely considered that porphyry Cu deposits formed via oceanic slab subduction are closely associated with hydrous and oxidized arc magmas. Of note, two suites of neighboring (∼40 km apart) Carboniferous arc volcanic rocks in Northwest China show different extents of mineralization: volcanic rocks from the Dananhu arc (DNHA) host one of the most important porphyry Cu deposit belts in China, whereas those from the Yamansu arc (YMSA), adjacent to DNHA, are ore-barren. These arc volcanic rocks, thus, provide a precious opportunity to explore the main factor that controls the genetic links between coeval arc lavas and porphyry Cu mineralization. Here we report whole rock major and trace element compositions and Mg–Sr–Nd–Pb isotopic data, generating a comprehensive geochemical comparison for these two suites of volcanic rocks from basalt to dacite. The whole-rock geochemical analyses suggest that at a given SiO<sub>2</sub> content, the YMSA basalts show lower MgO, CaO, Fe<sub>2</sub>O<sub>3</sub><sup>T</sup>, and TiO<sub>2</sub> contents than the DNHA basalts. The DNHA volcanic rocks have higher Sr/Y and (La/Yb)<sub>N</sub> ratios, which are positively correlated, indicating that these two suites of rocks were derived from different magma sources. The DNHA rocks are characterized by radiogenic Pb isotopic compositions with <sup>206</sup>Pb/<sup>204</sup>Pb up to 19.457, clearly distinct from the YMSA volcanic rocks with less radiogenic Pb isotopic compositions (<sup>206</sup>Pb/<sup>204</sup>Pb = 18.146–18.487), suggesting variable assimilation of crust-derived components during magma evolution. The <em>δ</em><sup>26</sup>Mg values of the DNHA rocks (−0.35‰ to +0.06‰) are largely similar to those of the YMSA rocks (−0.24‰ to +0.04‰), and both sets of isotopic ratio ranges have tendency toward heavy Mg isotopes, which could be attributed to serpentinite-derived high-<em>δ</em><sup>26</sup>Mg fluids in their mantle sources. Both suites of arc lavas have constant Cu contents and Cu/Sc ratios, indicating inconspicuous pre-enrichment of Cu contents. Geochemical comparisons indicate that the DNHA rocks were derived from partial melting of peridotite at the depth around the spinel-garnet transitional stability field, whereas the YMSA rocks were derived from partial melting of spinel peridotite, and the DNHA magmas had a thicker overlying plate than that of the YMSA magmas. The thickened arc lithosphere facilitates water-rich magmas accumulation and garnet fractionation, driving the magmas to become more oxidized, thereby preventing sulfide segregation and releasing sulfide-bound Cu. Thus, magmas differentiation in the thickened arc lithosphere is a key factor influencing porphyry Cu ore potential.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"17 1","pages":"Article 102189"},"PeriodicalIF":8.9,"publicationDate":"2025-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145474586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Late Mesozoic porphyry copper deposits in NE China: Post-collisional versus subduction-related magmatic systems 中国东北晚中生代斑岩型铜矿床:后碰撞与俯冲岩浆体系
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-10-27 DOI: 10.1016/j.gsf.2025.102190
Bizheng Yang , Fanbo Meng , Yuzhou Feng , Xinran Ni , Changzhou Deng , Jingjing Zhu , Runsheng Yin , Huayong Chen
Recent discoveries of Late Mesozoic porphyry Cu deposits (PCDs) in Northeast (NE) China reveal a distinct spatial metallogenic zonation, with Late Jurassic PCDs in the north dominated by Cu-Mo and Early Cretaceous PCDs in the east marked by Cu-Au mineralization. However, the mechanisms controlling this metallogenic contrast remain unclear. To tackle this issue, we combined geological, geochronological, and geochemical data to determine the genesis of these deposits and the key factors controlling their distinct Cu-Mo and Cu-Au mineralization. Geochronological data show that the Late Jurassic PCDs were formed during a short-lived mineralization event (ca. 150–147 Ma), in contrast to the Early Cretaceous PCDs, which exhibit a prolonged formation history (ca. 120–95 Ma). Geochemical data demonstrate that the northern Cu-Mo PCDs originate from partial melting of thickened juvenile lower crust, whereas the eastern Cu-Au PCDs result from oceanic crust-derived melts contaminated by mantle wedge materials. Integrated analysis suggests that the Cu-Mo PCDs formed in a post-collisional setting after the Mongol-Okhotsk Ocean closure, while the Cu-Au PCDs formed in a subduction setting associated with Paleo-Pacific oceanic plate subduction. Despite the presence of hydrous and oxidized magmas in both regions, the northern PCDs exhibit higher Sr/Y, La/Yb, and Sm/Yb ratios than the eastern PCDs, indicating greater magma differentiation depths controlled by crustal thickness. We therefore propose that the depths of magma differentiation govern the metallogenic zoning of Late Mesozoic PCDs in NE China.
中国东北晚中生代斑岩型铜矿床的新发现显示出明显的空间成矿分带,北部晚侏罗世斑岩型铜矿床以Cu- mo为主,东部早白垩世斑岩型铜矿床以Cu- au成矿为主。然而,控制这种成矿对比的机制尚不清楚。为了解决这一问题,我们结合地质、年代学和地球化学数据,确定了这些矿床的成因以及控制其独特的Cu-Mo和Cu-Au成矿作用的关键因素。地质年代学资料表明,晚侏罗世多聚体形成于一个短暂的成矿事件(约150 ~ 147 Ma),而早白垩世多聚体形成时间较长(约120 ~ 95 Ma)。地球化学资料表明,北部Cu-Mo多聚体来源于增厚幼年下地壳的部分熔融,而东部Cu-Au多聚体来源于地幔楔块物质污染的洋壳熔融体。综合分析表明,Cu-Mo多聚体形成于蒙古-鄂霍次克洋闭合后的碰撞环境,而Cu-Au多聚体形成于古太平洋板块俯冲后的俯冲环境。尽管两区均存在含水岩浆和氧化岩浆,但北段的Sr/Y、La/Yb和Sm/Yb比值均高于东段,表明岩浆分异深度受地壳厚度控制较大。因此,岩浆分异深度决定了中国东北晚中生代多聚体的成矿分带。
{"title":"Late Mesozoic porphyry copper deposits in NE China: Post-collisional versus subduction-related magmatic systems","authors":"Bizheng Yang ,&nbsp;Fanbo Meng ,&nbsp;Yuzhou Feng ,&nbsp;Xinran Ni ,&nbsp;Changzhou Deng ,&nbsp;Jingjing Zhu ,&nbsp;Runsheng Yin ,&nbsp;Huayong Chen","doi":"10.1016/j.gsf.2025.102190","DOIUrl":"10.1016/j.gsf.2025.102190","url":null,"abstract":"<div><div>Recent discoveries of Late Mesozoic porphyry Cu deposits (PCDs) in Northeast (NE) China reveal a distinct spatial metallogenic zonation, with Late Jurassic PCDs in the north dominated by Cu-Mo and Early Cretaceous PCDs in the east marked by Cu-Au mineralization. However, the mechanisms controlling this metallogenic contrast remain unclear. To tackle this issue, we combined geological, geochronological, and geochemical data to determine the genesis of these deposits and the key factors controlling their distinct Cu-Mo and Cu-Au mineralization. Geochronological data show that the Late Jurassic PCDs were formed during a short-lived mineralization event (ca. 150–147 Ma), in contrast to the Early Cretaceous PCDs, which exhibit a prolonged formation history (ca. 120–95 Ma). Geochemical data demonstrate that the northern Cu-Mo PCDs originate from partial melting of thickened juvenile lower crust, whereas the eastern Cu-Au PCDs result from oceanic crust-derived melts contaminated by mantle wedge materials. Integrated analysis suggests that the Cu-Mo PCDs formed in a post-collisional setting after the Mongol-Okhotsk Ocean closure, while the Cu-Au PCDs formed in a subduction setting associated with Paleo-Pacific oceanic plate subduction. Despite the presence of hydrous and oxidized magmas in both regions, the northern PCDs exhibit higher Sr/Y, La/Yb, and Sm/Yb ratios than the eastern PCDs, indicating greater magma differentiation depths controlled by crustal thickness. We therefore propose that the depths of magma differentiation govern the metallogenic zoning of Late Mesozoic PCDs in NE China.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"17 1","pages":"Article 102190"},"PeriodicalIF":8.9,"publicationDate":"2025-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145475009","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-stage exhumation and preservation of the Mujicun porphyry Cu-Mo deposit, North China: A geo-thermochronological perspective 华北木鸡村斑岩型铜钼矿床的多阶段发掘与保存:地球-热年代学视角
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-10-24 DOI: 10.1016/j.gsf.2025.102184
Fan Yang , Jingwen Mao , Gilby Jepson , Fuquan Yang , Leon Bagas , Yingjie Li , Zhenyu Qin
Porphyry deposits are critical global sources of Cu, Mo, and Au. However, the mechanisms of post-mineralisation modification, exhumation, and preservation across different tectonic regimes remain poorly understood. The Mujicun deposit, a rare intracontinental porphyry Cu-Mo deposit in the North China Block, formed during the Early Cretaceous lithospheric thinning induced by the Paleo-Pacific slab rollback. Early studies focused predominantly on its genesis, the lack of research on post-mineralisation evolution has hindered regional prospecting. This study employs multiple geo-thermochronology, including zircon-apatite U-Pb and (U-Th)/He dating, as well as apatite fission-track analysis, combined with associated thermal history modelling, to elucidate the deposit’s temporal evolution, exhumation history, and preservation potential. Geochronological data indicate that dioritic magma emplacement and related Cu-Mo mineralisation at Mujicun occurred at ca. 146–141 Ma and ca. 145–138 Ma, respectively, coinciding with regional extension driven by Paleo-Pacific subduction. Integrated geo-thermochronological data and thermal history modelling reveal four tectono-thermal phases: (1) Late Cretaceous rapid cooling (ca. 110–95 Ma) and slow cooling during ca. 95–66 Ma, linked to lithospheric thinning of the eastern North China Block and the early uplift of the Taihang Mountains, triggered by Paleo-Pacific subduction and Okhotomorsk-Eurasia collision; (2) Late Cretaceous to Paleogene weak reheating (ca. 85–35 Ma), attributed to coeval sedimentary burial in the North Taihang Mountain and the nearby Bohai Basin; (3) Paleogene slow cooling (ca. 66–35 Ma), correlated with Pacific slab rollback and far-field effects from the India-Eurasia collision, inducing extensional uplift and exhumation of the Taihang Mountains; and (4) Neogene enhanced cooling (ca. 35–15 Ma), driven by Pacific subduction, India-Eurasia convergence, Tibetan Plateau extrusion, and the intensified East Asian monsoon, resulting in differential exhumation and planation of the Taihang Mountains. The Mujicun deposit shows exceptional preservation, as its total exhumation depth since ∼110 Ma (∼3.56 km) closely aligns with its original ore-forming depth (∼3.2–3.9 km). This indicates minimal post-mineralisation exhumation and limited erosional modification. Whereas current exploration targets shallow mineralisation (<1.5 km), significantly deeper regional ore-forming depths (e.g., Dawan Mo deposit: 0.76–9.76 km) highlight the important potential for undiscovered Cu-Mo resources at depth within the North Taihang Mountain.
斑岩矿床是全球铜、钼和金的重要来源。然而,在不同的构造制度下,矿化后的改造、挖掘和保存机制仍然知之甚少。木积村铜钼矿床是华北地块内罕见的斑岩型铜钼矿床,形成于早白垩世古太平洋板块回滚引起的岩石圈减薄时期。早期研究主要集中在成因上,缺乏成矿后演化研究,阻碍了区域找矿。本研究采用多种地热年代学方法,包括锆石-磷灰石U-Pb和(U-Th)/He测年,以及磷灰石裂变径迹分析,结合相关的热历史模拟,阐明矿床的时间演化、发掘历史和保存潜力。年代学资料表明,木鸡村闪长质岩浆侵位和相关铜钼矿化分别发生在约146 ~ 141 Ma和145 ~ 138 Ma,与古太平洋俯冲作用驱动的区域伸展相吻合。综合地-热年代学数据和热历史模拟揭示了4个构造-热阶段:(1)晚白垩世(约110-95 Ma)快速冷却和约95-66 Ma缓慢冷却,与古太平洋俯冲和Okhotomorsk-Eurasia碰撞引发的华北地块东部岩石圈减薄和太行山早期隆升有关;(2)晚白垩世—古近纪弱再加热(约85 ~ 35 Ma),与北太行山和渤海盆地的同期沉积埋藏有关;(3)古近系缓慢冷却(约66 ~ 35 Ma),与太平洋板块回滚和印度-欧亚碰撞的远场影响有关,诱发太行山的伸展隆升和掘出;(4)新近纪强化冷却(约)。Mujicun矿床表现出特殊的保存能力,因为其自~ 110 Ma (~ 3.56 km)以来的总发掘深度与原始成矿深度(~ 3.2-3.9 km)密切相关。这表明矿化后挖掘很少,侵蚀作用有限。目前的勘探目标是浅层矿化(1.5 km),而更深层的区域成矿深度(如大湾钼矿床:0.76 ~ 9.76 km)凸显了北太行山深层未发现铜钼资源的重要潜力。
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引用次数: 0
Fluid-silicate melt Cl partition and its implications on magmatic fluid exsolution and hydrothermal ore genesis 流体-硅酸盐熔体Cl分配及其对岩浆溶蚀和热液成矿的意义
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-10-24 DOI: 10.1016/j.gsf.2025.102187
Jianping Li , Xing Ding , Huayong Chen
Partition coefficients for Cl between felsic melts and a supercritical aqueous fluid (∼4–16 wt.% NaCleq) were experimentally determined to better constrain Cl behavior during magmatic fluid exsolution in upper-crustal magma chambers. Experiments were conducted at 850 °C, 200 MPa, and oxygen fugacity near NNO + 0.5, using a range of melt and fluid compositions. At constant total chlorinity of 1 mol/kg H2O, DClfluid/melt values range from 11.3 to 21.1, negatively correlated with both the melt’s aluminum saturation index (ASI) and the HCl/total Cl ratio in the fluid. For a fixed melt composition (ASI = 1.02), DClfluid/melt values increase linearly from 18.7 to 60.1 as total chlorinity rises from 1 to 4 mol/kg H2O. Rayleigh fractionation modeling of fluid exsolution from upper-crustal magmas using these data indicates that during progressive crystallization, chlorinity of exsolved fluids rapidly decline before stabilizing at ∼1 mol/kg H2O (∼4 wt.% NaCleq), regardless of initial fluid chlorinity or H2O content in melt. This implies that the majority of exsolution fluids released from felsic magmas in the upper crust are of low salinity (∼1 mol/kg H2O). Copper transfer modeling further suggests that efficient metal extraction occurs in Cl- and H2O-rich magmas, particularly where early H2O saturation is achieved, thus favoring the formation of high-grade porphyry copper deposits.
通过实验确定了长硅熔体和超临界流体(~ 4-16 wt.% NaCleq)之间Cl的分配系数,以更好地约束上地壳岩浆房中岩浆流体析出过程中Cl的行为。实验在850°C、200 MPa和接近NNO + 0.5的氧逸度下进行,使用了一系列熔体和流体成分。当总氯浓度为1 mol/kg H2O时,熔体的DClfluid/melt值在11.3 ~ 21.1之间,与熔体的铝饱和指数(ASI)和流体中HCl/total Cl比值呈负相关。对于固定的熔体成分(ASI = 1.02),当总氯浓度从1 mol/kg H2O增加到4 mol/kg H2O时,DClfluid/melt值从18.7线性增加到60.1。利用这些数据对上地壳岩浆的流体析出进行的瑞利分馏模拟表明,在渐进结晶过程中,无论初始流体氯含量或熔体中H2O含量如何,析出流体的氯含量迅速下降,然后稳定在~ 1 mol/kg H2O (~ 4 wt.% NaCleq)。这表明,上地壳长英质岩浆释放的溶出液大部分盐度较低(~ 1 mol/kg H2O)。铜转移模型进一步表明,在富Cl-和富H2O的岩浆中,特别是在早期H2O饱和的岩浆中,有效的金属提取有利于形成高品位斑岩铜矿床。
{"title":"Fluid-silicate melt Cl partition and its implications on magmatic fluid exsolution and hydrothermal ore genesis","authors":"Jianping Li ,&nbsp;Xing Ding ,&nbsp;Huayong Chen","doi":"10.1016/j.gsf.2025.102187","DOIUrl":"10.1016/j.gsf.2025.102187","url":null,"abstract":"<div><div>Partition coefficients for Cl between felsic melts and a supercritical aqueous fluid (∼4–16 wt.% NaCl<sub>eq</sub>) were experimentally determined to better constrain Cl behavior during magmatic fluid exsolution in upper-crustal magma chambers. Experiments were conducted at 850 °C, 200 MPa, and oxygen fugacity near NNO + 0.5, using a range of melt and fluid compositions. At constant total chlorinity of 1 mol/kg H<sub>2</sub>O, <span><math><mrow><msubsup><mtext>D</mtext><mrow><mtext>Cl</mtext></mrow><mrow><mtext>fluid/melt</mtext></mrow></msubsup></mrow></math></span> values range from 11.3 to 21.1, negatively correlated with both the melt’s aluminum saturation index (ASI) and the HCl/total Cl ratio in the fluid. For a fixed melt composition (ASI = 1.02), <span><math><mrow><msubsup><mtext>D</mtext><mrow><mtext>Cl</mtext></mrow><mrow><mtext>fluid/melt</mtext></mrow></msubsup></mrow></math></span> values increase linearly from 18.7 to 60.1 as total chlorinity rises from 1 to 4 mol/kg H<sub>2</sub>O. Rayleigh fractionation modeling of fluid exsolution from upper-crustal magmas using these data indicates that during progressive crystallization, chlorinity of exsolved fluids rapidly decline before stabilizing at ∼1 mol/kg H<sub>2</sub>O (∼4 wt.% NaCl<sub>eq</sub>), regardless of initial fluid chlorinity or H<sub>2</sub>O content in melt. This implies that the majority of exsolution fluids released from felsic magmas in the upper crust are of low salinity (∼1 mol/kg H<sub>2</sub>O). Copper transfer modeling further suggests that efficient metal extraction occurs in Cl- and H<sub>2</sub>O-rich magmas, particularly where early H<sub>2</sub>O saturation is achieved, thus favoring the formation of high-grade porphyry copper deposits.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"17 1","pages":"Article 102187"},"PeriodicalIF":8.9,"publicationDate":"2025-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145475008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crustal contamination and insights into diachronous changes toward modern tectonics: evidence from Hf-Nd-O-Pb isotope of sanukitoids from the Amazonian craton 地壳污染及其对现代构造历时变化的认识:来自亚马逊克拉通sanukit类Hf-Nd-O-Pb同位素的证据
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-10-23 DOI: 10.1016/j.gsf.2025.102172
Aline Costa do Nascimento , Davis Carvalho de Oliveira , Esa Heilimo , Marco Antonio Galarza , Eleilson Oliveira Gabriel , Martin Whitehouse , Matti Kurhila , Cláudio Nery Lamarão
Archean sanukitoids provide crucial insights into crust-mantle interactions during the early Earth’s geodynamic evolution. However, the role of crustal contamination in their genesis remains uncertain. Sanukitoids identified in the Sapucaia subdomain of the southern Carajás Province are represented by two plutons Água Limpa and Água Azul, collectively referred to as the Água Limpa sanukitoid suite. These plutons are compositionally similar to low-Ti sanukitoids (< 0.63 % TiO2) and their zircon isotopic data record a short period of magmatic activity around ca. 2.87 Ga. Sanukitoids zircons reveal εHf(t) values ranging from –3.31 to + 2.14, Hf and Nd model ages between 2.91 Ga and 3.28 Ga, whole-rock εNd(t) values from –1.64 to + 1.76, and δ18O values ranging from 5.0 ‰ to 7.6 ‰. The Pb isotopic compositions in K-feldspar (µ > 10) suggests a Mesoarchean mantle source affected by slight crustal contribution and/or contamination. Result of geochemical modelling indicates that the sanukitoids were formed by ∼ 15 % partial melting of mantle peridotite previously enriched by ∼ 30 % of slab-derived melts, with orthopyroxene, garnet, clinopyroxene, phlogopite, and magnetite as residual phases. The integration of our data with previously published results leads us to suggest that modern-style plate tectonics may have initiated along the northern Carajás Province during the Mesoarchean, while the Rio Maria domain to the south remained dominated by mantle plume-driven crustal growth and vertical tectonics.
太古代sanukitoids提供了对早期地球动力学演化过程中地壳-地幔相互作用的重要见解。然而,地壳污染在其成因中的作用仍不确定。在Carajás省南部Sapucaia亚域中发现的sanukitoid以Água Limpa和Água Azul两个岩体为代表,统称为Água Limpa sanukitoid套。这些岩体在成分上与低钛类岩浆岩(< 0.63% TiO2)相似,它们的锆石同位素数据记录了大约2.87 Ga左右的短时间岩浆活动。Sanukitoids锆石的εHf(t)值在-3.31 ~ + 2.14之间,Hf和Nd模式年龄在2.91 ~ 3.28 Ga之间,全岩εNd(t)值在-1.64 ~ + 1.76之间,δ18O值在5.0‰~ 7.6‰之间。钾长石Pb同位素组成(µ> 10)表明中太古代地幔源受到轻微地壳贡献和/或污染的影响。地球化学模拟结果表明,类sanukitoite是由地幔橄榄岩的~ 15%部分熔融形成的,之前富含~ 30%的板岩衍生熔体,剩余相为正辉石、石榴石、斜辉石、辉云母和磁铁矿。综合我们的数据和先前发表的结果,我们认为现代板块构造可能在中太古宙期间沿Carajás省北部开始,而南部的里约热内卢Maria域仍然以地幔柱驱动的地壳生长和垂直构造为主。
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引用次数: 0
Sorting carbonate clay-type lithium ores using a deep learning model with adaptive spectral-texture feature fusion 基于自适应光谱-纹理特征融合的深度学习模型对碳酸盐岩粘土型锂矿进行分选
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-10-23 DOI: 10.1016/j.gsf.2025.102185
Qunjia Zhang , Jiacheng Mei , Lujun Lin , Lei Liu , Hanjie Wen , Le Wang
Carbonate clay-type lithium ore holds significant potential due to its extensive reserves, broad distribution, and relatively easy extraction. However, it presents significant beneficiation challenges due to its coexistence with karst-type bauxite, which often results in mixed, low-lithium ores. For the first time, spectral–texture features derived from hyperspectral imaging (HSI) are jointly modeled with a deep learning framework to explore the feasibility of pre-sorting carbonate clay-type lithium ores. Initially, the spectral responses reflecting mineral composition and the texture features characterizing structural differences were analyzed to evaluate the feasibility of using HSI for ore sorting. Furthermore, the influence of band selection, data standardization, and water absorption regions on pre-sorting performance was systematically investigated through comparative analysis of multiple dataset configurations. Two classification schemes, primary ore types classification and multi grade classification, were employed to assess sorting accuracy and identify key influencing factors. The proposed model, A2ST-OSNet, achieves excellent results in both ore localization and classification through staged data input with varying dimensions and a modular design. Results revealed that joint modeling of spectral and texture features enables efficient and accurate pre-sorting, whereas models relying solely on either spectral or texture features were insufficient, as discriminative information for ore sorting is jointly determined by mineral composition and structural characteristics. Moreover, refined feature extraction and fusion strategies, including spectral–texture feature selection and attention mechanisms, proved critical in enhancing classification performance. The proposed approach offers valuable technical support for ore beneficiation and tailings reutilization, contributing to sustainable resource utilization and providing an effective solution for the efficient recycling of carbonate clay-type lithium ores.
碳酸盐岩粘土型锂矿储量大、分布广、开采相对容易,具有重要的开发潜力。然而,由于它与岩溶型铝土矿共存,往往导致混合的低锂矿石,给选矿带来了很大的挑战。该研究首次将高光谱成像(HSI)的光谱纹理特征与深度学习框架联合建模,探索碳酸盐岩粘土型锂矿石预分选的可行性。首先,分析了反映矿物成分的光谱响应和表征结构差异的纹理特征,以评估使用HSI进行矿石分选的可行性。此外,通过多数据集配置的对比分析,系统研究了波段选择、数据标准化和吸水区域对预分选性能的影响。采用原生矿石类型分级和多品位分级两种分级方案,对分选精度进行评价,找出影响分选精度的关键因素。本文提出的A2ST-OSNet模型通过分阶段的变维数据输入和模块化设计,在矿石定位和分类方面都取得了很好的效果。结果表明,光谱和纹理特征的联合建模可以实现高效、准确的预分选,而单纯依赖光谱或纹理特征的模型是不够的,因为分选的判别信息是由矿物组成和结构特征共同决定的。此外,改进特征提取和融合策略,包括光谱纹理特征选择和关注机制,是提高分类性能的关键。该方法为矿石选矿和尾矿资源化利用提供了宝贵的技术支持,有利于资源的可持续利用,为碳酸盐岩粘土型锂矿石的高效回收提供了有效的解决方案。
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引用次数: 0
Wetting of olivine by sulfide liquid: an example from the Central Asian Orogenic belt in NW China 硫化液对橄榄石的润湿作用:以中国西北中亚造山带为例
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-10-22 DOI: 10.1016/j.gsf.2025.102183
Jian Kang , Xie-Yan Song , Wei Xie , Yu-Feng Deng , Bo Wei , Stephen J. Barnes , Wen Chen , Wei-Dong Li
Experimental studies have demonstrated that olivine can be wetted by sulfide liquid under specific conditions. In this study, we investigate elongated sulfide-olivine patches in lherzolite from the Dahuangshan mafic–ultramafic complex (Central Asian Orogenic Belt, NW China), which display textural evidence indicative of this phenomenon. Two-dimensional (2D) microbeam X-ray fluorescence (micro-XRF) mapping and three-dimensional (3D) high-resolution X-ray computed tomography (HRXCT) scanning reveal that the sulfide-olivine patches are 1.0‒4.8 cm long, 0.3‒2.3 cm wide and 0.2‒2.0 cm thick, and have sharp boundaries in the lherzolite matrix. These patches consist entirely of olivine (Fo781.9) embedded within interstitial sulfides. The sulfides dominantly comprise pyrrhotite (>94 vol%), minor pentlandite (< 6 vol%) and trace chalcopyrite, and contain a total of 1.1‒1.9 wt.% (Ni + Cu + Co). Low olivine-olivine-sulfide dihedral angles (averaging 44.9°) indicate that olivine was wetted by the sulfide liquid in these patches. The crystal size distributions (CSDs) of the olivine grains in the sulfide-olivine patches are different from those of the olivine in the lherzolite matrix. These observations can be explained by the entrainment of pre-existing sulfide-olivine cumulates into flowing magma. The elongated shape and parallel distribution of the sulfide-olivine patches indicate that the magma flow was laminar. These findings support the hypothesis that sulfide liquid can wet olivine and under the right conditions can be transported and deposited as sulfide-olivine aggregates within magma conduits.
实验研究表明,在特定条件下,橄榄石可以被硫化物液体润湿。本文研究了中亚造山带大黄山基性-超基性杂岩的长条形硫化物-橄榄石斑,显示了这种现象的结构证据。二维(2D)微束x射线荧光(micro-XRF)成像和三维(3D)高分辨率x射线计算机断层扫描(HRXCT)扫描显示,硫化物-橄榄石斑块长1.0 ~ 4.8 cm,宽0.3 ~ 2.3 cm,厚0.2 ~ 2.0 cm,在橄榄岩基质中具有清晰的边界。这些斑块完全由嵌套在间隙硫化物中的橄榄石(Fo7-81.9)组成。硫化物主要由磁黄铁矿(>94 vol%)、少量镍黄铁矿(< 6 vol%)和微量黄铜矿组成,总含量为1.1 ~ 1.9 wt.% (Ni + Cu + Co)。低的橄榄石-橄榄石-硫化物二面角(平均44.9°)表明橄榄石被硫化物液体润湿。硫化物-橄榄石斑块中橄榄石颗粒的晶粒尺寸分布(CSDs)与橄榄石基质中的橄榄石不同。这些观察结果可以解释为先前存在的硫化物-橄榄石堆积被夹带到流动的岩浆中。硫化物-橄榄石斑块呈细长状平行分布,表明岩浆流为层流。这些发现支持了硫化物液体可以湿润橄榄石的假设,并且在适当的条件下可以在岩浆管道中以硫化物-橄榄石集合体的形式运输和沉积。
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引用次数: 0
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Geoscience frontiers
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