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Physics-guided deep learning for global sea surface temperature forecasting: Balancing accuracy and stability across timescales 物理引导的深度学习用于全球海面温度预报:跨时间尺度平衡精度和稳定性
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-03-01 Epub Date: 2026-01-17 DOI: 10.1016/j.gsf.2026.102255
Shiji Dong , Yan Li , Xiaobin Yin , Qing Xu , Peng Mao
Accurate sea surface temperature (SST) forecasting across multiple timescales remains challenging. Daily forecasting frequently relies on autoregressive models prone to instability and over-smoothing, whereas monthly forecasting suffers from sparse data and the complex dynamics of ocean systems. Existing deep learning methods struggle to address these diverse challenges simultaneously. We introduce SSTFormer, a novel physics-guided deep learning framework that achieves leading results, with root mean squared error of 0.17 °C for daily forecasts and 0.60 °C for monthly forecasts, yielding lower bias and improved spatial coherence. The model’s core innovation is its unified and flexible architecture. For multi-step daily forecasts (1–15 days), it deploys as a “two-phase sequential ensemble” that replaces conventional autoregression and uses ocean current to solve instability and mitigate error accumulation. For single-step monthly forecasts, it is used in a direct forecasting configuration, proving effective at handling “sparse data” and “complex ocean dynamics.” SSTFormer demonstrates how a single architecture, through flexible deployment, can address the unique challenges of multi-scale SST forecasting, highlighting its potential as a unified and robust framework.
准确预测跨多个时间尺度的海表温度(SST)仍然具有挑战性。每日预报经常依赖于容易不稳定和过度平滑的自回归模型,而每月预报则受到稀疏数据和海洋系统复杂动态的影响。现有的深度学习方法很难同时解决这些不同的挑战。我们引入了一种新的物理引导深度学习框架SSTFormer,该框架取得了领先的结果,每日预测的均方根误差为0.17°C,每月预测的均方根误差为0.60°C,从而降低了偏差,提高了空间相干性。该模型的核心创新是其统一灵活的架构。对于多步每日预报(1-15天),它部署为“两相序列集合”,取代传统的自回归,并使用洋流来解决不稳定性和减少误差积累。对于单步月度预报,它被用于直接预报配置,证明在处理“稀疏数据”和“复杂的海洋动力学”方面是有效的。SSTFormer展示了单一架构如何通过灵活部署来应对多尺度SST预测的独特挑战,突出了其作为统一和强大框架的潜力。
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引用次数: 0
Landslide susceptibility assessment using machine learning with a novel SHAP-based sampling strategy 基于shap采样策略的机器学习滑坡易感性评估
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-03-01 Epub Date: 2025-10-22 DOI: 10.1016/j.gsf.2025.102188
Lei-Lei Liu , Can Duan , Jun-Hua Gao , Hao Xiao , Wen-Qing Zhu , Can Yang
The landslide and non-landslide samples are important inputs for machine learning-based landslide susceptibility assessment. Compared to landslide samples, non-landslide samples generally present higher uncertainty due to random sampling. However, most sampling strategies (e.g., the feature space-based) for non-landslides only consider the characteristics of a single factor or the overall characteristics of all factors, which subsequently leads to either excessive artificial concentration of non-landslide samples or sampling information redundancy. To address these issues, a SHapley Additive exPlanations (SHAP) based sampling strategy considering combined characteristics of landslide conditioning factors (LCFs) is proposed. This strategy sorts the importance of LCFs based on SHAP algorithm and generates multiple sampling spaces using different numbers of LCFs in the sense of importance order. The optimal sampling space is selected according to the Bayesian optimization algorithm. Then, random forest (RF) and extreme gradient boosting (XGBoost) models are utilized to assess the susceptibility of Chaling County, Yanling County, and Guidong County, China, based on the proposed strategy and traditional random sampling. The results indicate that, compared with the traditional RF and XGBoost models, the improved models show better performance with an 8.2% and 9.0% increase in the AUC, respectively. Furthermore, the SHAP-based sampling framework demonstrates good adaptability across the study areas with different geological and geomorphic conditions, suggesting its potential transferability to other regions, although local optimization of parameter settings may still be required.
滑坡和非滑坡样本是基于机器学习的滑坡易感性评估的重要输入。与滑坡样本相比,非滑坡样本通常由于随机抽样而具有更高的不确定性。然而,大多数非滑坡采样策略(如基于特征空间的采样策略)只考虑单个因素的特征或所有因素的总体特征,从而导致非滑坡样本的人工过度集中或采样信息冗余。为了解决这些问题,提出了一种基于SHapley加性解释(SHAP)的采样策略,该策略考虑了滑坡调节因子(LCFs)的组合特征。该策略基于SHAP算法对lcf的重要性进行排序,使用不同数量的lcf按重要性顺序产生多个采样空间。根据贝叶斯优化算法选择最优采样空间。然后,利用随机森林(RF)和极端梯度增强(XGBoost)模型,在传统随机抽样的基础上,对中国茶陵县、鄢陵县和桂东县进行了敏感性评估。结果表明,与传统的RF和XGBoost模型相比,改进模型的AUC分别提高了8.2%和9.0%,具有更好的性能。此外,基于shap的采样框架在不同地质地貌条件的研究区域表现出良好的适应性,表明其可能可转移到其他区域,尽管仍需要局部优化参数设置。
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引用次数: 0
Cross-regional extrapolation of landslide susceptibility mapping via transfer learning 基于迁移学习的滑坡易感性制图跨区域外推
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-03-01 Epub Date: 2025-11-17 DOI: 10.1016/j.gsf.2025.102212
Yunhao Wang , Wengang Zhang , Luqi Wang , Songlin Liu , Kaiqiang Zhang , Pengfei Liu , Weixin Sun , Shuihua Jiang
Landslide susceptibility mapping (LSM) is an essential tool for the prevention and management of landslide-related disasters. Conventional machine learning-based LSM method faces significant limitations in cross-regional extrapolation. To address this challenge, this study develops a transfer learning (TL) model based on the Convolutional Neural Network–Bidirectional Long Short-Term Memory (CNN-BiLSTM) framework, specifically designed for cross-regional LSM. A total of 11 modelling scenarios is established to compare the cross-regional extrapolation performance of Random Forest (RF), CNN-BiLSTM, and TL models, with Wanzhou District and Wushan County in Chongqing used as case studies. The results indicate that, compared to the strategy of directly expanding training dataset used by RF and CNN-BiLSTM models, the pre-training and fine-tuning strategy employed by the TL model is more suitable for county-scale LSM and its cross-regional extrapolation. Additionally, the cross-regional extrapolation performance of the TL model improves as the volume of source domain data increases. Finally, the SHAP algorithm is used to provide a global interpretation of the TL #3 model, which demonstrates the best performance in cross-regional model extrapolation.
滑坡易感性测绘是预防和管理滑坡相关灾害的重要工具。传统的基于机器学习的LSM方法在跨区域外推方面存在很大的局限性。为了解决这一挑战,本研究开发了一个基于卷积神经网络-双向长短期记忆(CNN-BiLSTM)框架的迁移学习(TL)模型,专门为跨区域LSM设计。以重庆市万州区和巫山县为例,建立了11个模拟情景,比较随机森林(Random Forest, RF)、CNN-BiLSTM和TL模型的跨区域外推效果。结果表明,与RF模型和CNN-BiLSTM模型直接扩展训练数据集的策略相比,TL模型采用的预训练和微调策略更适合县级LSM及其跨区域外推。此外,TL模型的跨区域外推性能随着源域数据量的增加而提高。最后,利用SHAP算法对TL #3模型进行了全局解释,证明了该算法在跨区域模型外推中的最佳性能。
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引用次数: 0
Transport of colloidal Au-bearing nanoparticles driven by metamorphic decarbonization 变质脱碳驱动胶体含金纳米颗粒的输运
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-03-01 Epub Date: 2025-12-21 DOI: 10.1016/j.gsf.2025.102240
Zhenjiang Wang , Shaorui Zhao , Jingbo Li , Yanfei Zhang , Chao Wang , Dan Li , Zhenmin Jin
The genesis of bonanza-style gold deposits, characterized by weight-percent-level Au enrichment, challenges conventional models of chemical transport via aqueous complexes. Through high-pressure experiments (0.5–1.5 GPa, 600–1150 °C) combined with thermodynamic modeling and transmission electron microscopy (TEM) analyses, we demonstrate that CO2-rich fluids generated by metamorphic decarbonization create overpressures exceeding ∼ 200 MPa. This initiates explosive upward migration of sulfide liquids containing Au-Ag nanoparticles (NPs) into porous peridotite at velocities up to 55.9 ± 12.9 μm/h. High-resolution TEM analyses furthermore confirm the mechanical entrainment of Au-Ag NPs within sulfides. Fractal analysis (FD = 1.55–1.62) of dendritic sulfide networks reveals that viscous fingering dominates fluid dynamics. We propose a unified model where gas-driven filter pressing extracts Au-bearing sulfides from subducted slabs, while viscous fingering further facilitates kilometer-scale transport through lithospheric faults. This novel mechanism bridges mantle-derived carbon fluxes with crustal mineralization, offering new insights into the formation of ultrahigh-grade gold deposits.
以金富集为特征的富矿型金矿床的成因挑战了传统的通过水络合物进行化学输运的模式。通过高压实验(0.5-1.5 GPa, 600-1150°C),结合热力学模型和透射电镜(TEM)分析,我们证明了变质脱碳产生的富含co2的流体产生超过~ 200 MPa的超压。这引发了含有Au-Ag纳米颗粒(NPs)的硫化液体以55.9±12.9 μm/h的速度向上迁移到多孔橄榄岩中。高分辨率TEM分析进一步证实了Au-Ag NPs在硫化物中的机械夹带。枝状硫化物网络的分形分析(FD = 1.55 ~ 1.62)表明,黏性指指在流体动力学中占主导地位。我们提出了一个统一的模型,即气体驱动的压滤从俯冲板块中提取含金硫化物,而粘性指移进一步促进了通过岩石圈断层的千米尺度运输。这一新的机制将地幔源碳通量与地壳成矿作用联系起来,为超品位金矿床的形成提供了新的认识。
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引用次数: 0
Topographic and morphological effects of global earthquake- and rainstorm-induced landslides 全球地震和暴雨引起的滑坡的地形和形态效应
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-03-01 Epub Date: 2025-11-24 DOI: 10.1016/j.gsf.2025.102215
Wenchao Huangfu , Haijun Qiu , Jiading Wang , Ninglian Wang , Yang Zhang , Ya Liu , Ali Darvishi Boloorani , Mohib Ullah
Landslides have different topographic and morphological characteristics due to their different triggering mechanisms. However, the differences in the characteristics of earthquake- and rainstorm-induced landslides remain unclear. In this paper, we collect 12 cases of earthquake- and rainstorm-induced landslides around the world and reveal the differences in characteristics of the two types of landslides. By examining the geometric characteristics and location distribution of the landslides, the results show that earthquake-induced landslides tend to have larger areas, perimeter, lengths, widths, area to perimeter ratios (area/perimeter), major axis (SM), and minor axis (sm) than rainstorm-induced landslides. In addition, earthquake-induced landslides have more complex, rounded, and compact shapes than rainstorm-induced landslides. Earthquake-induced landslides are predominantly clustered near ridges, whereas rainstorm-induced landslides are predominantly clustered near valleys. The results also indicate that earthquake- and rainstorm-induced landslides mostly occur on 30°–50° and 10°–30° slopes, respectively, and both types are more likely to occur on sunny slopes. Moreover, the compactness and major axis are negatively logarithmically correlated for earthquake-induced landslides, while they are negatively exponentially correlated for rainstorm-induced landslides. Additional earthquake- and rainstorm-induced landslide events have verified the reliability and extensibility of the research conclusions. This work is beneficial for the management of landslide hazards and the effective implementation of landslide prediction and risk assessment.
山体滑坡因其触发机制不同而具有不同的地形形态特征。然而,地震和暴雨引发的滑坡在特征上的差异仍然不清楚。本文收集了世界范围内12例地震和暴雨引发的滑坡,揭示了这两种滑坡在特征上的差异。研究结果表明:地震诱发滑坡的面积、周长、长度、宽度、面积周长比(面积/周长)、长轴(SM)和短轴(SM)均大于暴雨诱发滑坡;此外,地震引发的山体滑坡比暴雨引发的山体滑坡具有更复杂、更圆、更紧凑的形状。地震引起的滑坡主要集中在山脊附近,而暴雨引起的滑坡主要集中在山谷附近。地震诱发滑坡和暴雨诱发滑坡分别多发生在30°~ 50°和10°~ 30°边坡上,且两种类型均多发生在阳坡上。地震诱发滑坡的密实度与长轴呈负对数相关,暴雨诱发滑坡的密实度与长轴呈负指数相关。额外的地震和暴雨引发的滑坡事件验证了研究结论的可靠性和可扩展性。这项工作有利于滑坡灾害管理和滑坡预测与风险评估的有效实施。
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引用次数: 0
Multi-modal characterization of ultramafic rock: Precursors relevant to serpentinization and hydrogen generation 超镁质岩石的多模态表征:与蛇纹石化和生氢有关的前体
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-03-01 Epub Date: 2025-11-30 DOI: 10.1016/j.gsf.2025.102220
Jiejie Li , Emma Black , Christopher Miller , Kunning Tang , Peyman Mostaghimi , Andrew Feitz , T.David Waite , Ryan T. Armstrong
Natural hydrogen (H2) generated by the reaction of ultramafic rocks with water is increasingly recognized as a promising low-carbon energy resource with the analysis of rock mineralogy and structural characteristics recognized to play a crucial role in assessing its subsurface generation potential. In this study, micro-computed tomography (micro-CT), micro-X-ray fluorescence spectroscopy (micro-XRF), X-ray diffraction (XRD), and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDS) are employed to analyze the density, elemental distribution, mineral composition, and surface spatial relationships of an ultramafic rock sample. In addition, deep learning-based image analysis is employed to achieve high-resolution mineral phase characterization, enabling quantitative analysis of the spatial distribution, co-location, and contact surfaces of the mineral phases. Focusing on a particular sample that was considered a likely initiator of hydrogen generation due to its mineral contents, our results indicate that the sample is primarily composed of Fe-Mg-rich olivine and silicate minerals, with most olivine phases being Mg-rich forsterite or mixtures of forsterite and Fe-rich fayalite. The sample also contains Fe-S sulfides and high-density metal-enriched phases, including Ni-rich phases that may enhance the H2-generating potential of serpentinization reactions. These findings highlight the mineralogical complexity of the studied ultramafic rock and the value of integrating compositional and spatial data when considering the potential of particular materials for hydrogen generation. The integrated analytical approach proposed in this study provides new insights and practical tools for evaluating the hydrogen generation potential associated with subsurface serpentinization in ultramafic rock.
超镁铁质岩石与水反应生成的天然氢气作为一种极具潜力的低碳能源日益被人们所认识,岩石矿物学和构造特征分析在评估其地下生成潜力方面发挥着至关重要的作用。本研究采用微计算机断层扫描(micro-CT)、微x射线荧光光谱(micro-XRF)、x射线衍射(XRD)、扫描电镜结合能量色散x射线能谱(SEM-EDS)等方法分析了超镁质岩石样品的密度、元素分布、矿物组成和表面空间关系。此外,利用基于深度学习的图像分析实现高分辨率矿物相表征,可以定量分析矿物相的空间分布、共位和接触面。我们的研究结果表明,该样品主要由富铁镁橄榄石和硅酸盐矿物组成,大多数橄榄石相是富镁橄榄石或富铁橄榄石和富铁橄榄石的混合物。样品还含有Fe-S硫化物和高密度富金属相,包括富ni相,这可能会增强蛇纹石化反应的h2生成潜力。这些发现突出了所研究的超镁质岩石的矿物学复杂性,以及在考虑特定物质的产氢潜力时整合成分和空间数据的价值。本研究提出的综合分析方法为评价超镁质岩地下蛇纹石化产氢潜力提供了新的见解和实用工具。
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引用次数: 0
Contrasted detection of lipid biomarkers in Ediacaran stromatolites from Amane-n’Tourhart in the Moroccan Anti-Atlas 摩洛哥Anti-Atlas中Amane-n 'Tourhart地区埃迪卡拉纪叠层石中脂类生物标志物的对比检测
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-03-01 Epub Date: 2026-01-08 DOI: 10.1016/j.gsf.2026.102251
Daniel Carrizo , Mohamed Beraaouz , Mohamed Hssaisoune , Laura Sánchez-García , Olga Prieto-Ballesteros , Víctor Parro
During the Ediacaran Period (635538.8 Ma), the photosynthetic activity due to cyanobacterial communities and early photosynthetic eukaryotes prompted the wide oxygenation of the terrestrial atmosphere. Biogeochemical evidence of this type of communities and activity in different terrestrial environments is very scarce. In this work, we search for lipid biomarkers and their carbon specific isotopic composition in stromatolites from an Ediacaran volcanic alkaline lake in the Anti-Atlas Mountains, in Morocco. Molecular analysis reveals the presence of n-alkanes, isoprenoids, hopanes and steranes in the Amane-n’Tourhart stromatolites, with compound-specific δ13C values for n-alkanes and isoprenoids within the range of autotrophic organisms using the Calvin-Benson-Bassham cycle. Results from contamination controls and laboratory tests attest for the indigeneity and syngenicity of the detected biomarkers. In addition, molecular and isotopic analysis of hydrocarbons allows for the recognition of phototrophic activity from the prokaryotic and eukaryotic communities developed in this extreme alkaline lake in anoxic conditions. These unique results shed light on a key Period in the evolution of life on Earth in the particular region of Amane-n’Tourhart. The set of molecular and isotopic biomarkers detected in the Amane-n’Tourhart stromatolites supports the presence of some of the first complex organisms (i.e. fungi and early animals) and the relevance of the most prominent metabolism in present day biology (i.e. Calvin cycle), and expands the catalog of biomarkers preserved from that geological Period to reconstruct its paleobiology.
在埃迪卡拉纪(635-538.8 Ma),蓝藻群落和早期光合真核生物的光合作用促进了陆地大气的广泛氧化。在不同的陆地环境中,这类群落和活动的生物地球化学证据非常少。在这项工作中,我们在摩洛哥反阿特拉斯山脉埃迪卡拉纪火山碱性湖的叠层石中寻找脂质生物标志物及其碳比同位素组成。分子分析表明,Amane-n 'Tourhart叠层石中存在正构烷烃、类异戊二烯、藿烷和甾烷,并利用Calvin-Benson-Bassham循环测定了正构烷烃和类异戊二烯在自养生物范围内的δ13C值。污染控制和实验室测试的结果证明了检测到的生物标记物的原生性和同质性。此外,碳氢化合物的分子和同位素分析可以识别出在缺氧条件下在这个极端碱性湖泊中发育的原核和真核生物群落的光营养活性。这些独特的结果揭示了地球上生命进化的关键时期在阿曼内-恩图尔哈特的特定地区。在Amane-n 'Tourhart叠层石中检测到的一组分子和同位素生物标志物支持了一些最早的复杂生物(即真菌和早期动物)的存在,以及现代生物学中最突出的代谢(即卡尔文循环)的相关性,并扩展了该地质时期保存的生物标志物目录,以重建其古生物学。
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引用次数: 0
Microstructure-driven prediction of undrained shear strength of deep-sea sediments: A multivariate approach bridging physical–mechanical properties 深海沉积物不排水剪切强度的微观结构驱动预测:一种连接物理-力学特性的多元方法
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-03-01 Epub Date: 2025-12-29 DOI: 10.1016/j.gsf.2025.102243
Yu-Min Shi , Fu-Ping Gao , Ning Wang , Wen-Gang Qi , Jian-Tao Liu , Jun-Qin Wang
An innovative framework for correlating physical–mechanical properties of deep-sea sediments is established through a comprehensive database integrating microstructural, mineralogical, and geotechnical data from over 300 samples. Advanced cold field emission SEM analyses reveal unique flocculated-laminated microstructures dominated by organic components and smectite-rich clay minerals. Microstructural parameters and relationships between macroscopic and microscopic characteristics are further examined, which enhances the fundamental understanding of the correlations between physical and mechanical properties. Statistical analyses demonstrate strong interdependencies among water content, buoyant unit weight, and void ratio, confirming their equivalence as physical descriptors. Crucially, conventional terrestrial soil models show limited applicability for predicting undrained shear strength in deep-sea environments, particularly underestimating strength parameters by neglecting sediment sensitivity and liquidity index. Through multiple nonlinear regression and the construction of multivariate distribution, predictive models are developed incorporating buoyant unit weight, liquidity index, and sensitivity as key governing factors, achieving superior accuracy compared to existing methods. This investigation advances the understanding of physical–mechanical properties of deep-sea sediments, thus providing critical insights for assessing subsea geo-hazards.
通过整合来自300多个样品的微观结构、矿物学和岩土数据的综合数据库,建立了一个创新的深海沉积物物理力学特性关联框架。先进的冷场发射SEM分析揭示了独特的絮凝层状微观结构,主要由有机成分和富蒙脱石粘土矿物组成。进一步研究了微观结构参数以及宏观和微观特征之间的关系,从而增强了对物理和力学性能之间相关性的基本理解。统计分析表明,含水量、浮力单位重量和空隙比之间存在很强的相互依赖性,证实了它们作为物理描述符的等效性。重要的是,传统的陆地土壤模型在预测深海环境不排水剪切强度方面适用性有限,特别是由于忽略了沉积物敏感性和流动性指数而低估了强度参数。通过多元非线性回归和多元分布的构建,建立了以浮力单位重量、流动性指数和灵敏度为主要控制因素的预测模型,与现有方法相比,预测精度更高。这项研究促进了对深海沉积物物理力学特性的理解,从而为评估海底地质灾害提供了重要的见解。
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引用次数: 0
Potassium isotopic evidence for the petrogenesis of Precambrian granitoids and implications for early crustal evolution of the accretionary orogen 前寒武纪花岗岩类岩石成因的钾同位素证据及其对增生造山带早期地壳演化的意义
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-03-01 Epub Date: 2025-12-19 DOI: 10.1016/j.gsf.2025.102239
Xinyu Long , Wenliang Xu , Feng Wang , Chenyang Sun , Jie Tang
Stable potassium (K) isotopes are emerging as a novel geochemical tracer for investigating magmatic differentiation and source characteristics. This study presents the K isotopic analyses of Neoarchean–Paleoproterozoic granitoids from the Xing’an Massif, a key microcontinent within the eastern Central Asian Orogenic Belt (CAOB), providing new insights into the granitoid petrogenesis and early crustal evolution of this accretionary orogen. The 2568 Ma peraluminous A-type monzogranite exhibits significantly heavier δ41K values (−0.22‰ to −0.05‰) compared to the range of the upper continental crust. Subduction zones can effectively transfer heavy K isotopic signature to the mantle wedge through slab-derived fluids/melts. The monzogranite could be formed through co-melting and mixing of previously metasomatized mantle materials and recycled supracrustal metapelites, followed by high degree of fractional crystallization in a post-collisional extensional setting. Although both the 1881 Ma monzogranite and 1843 Ma syenogranite share geochemical affinities with adakites, their markedly different K isotopic compositions and distinct geochemical fingerprints point to substantial heterogeneity within their source regions. The 1881 Ma monzogranite shows more pronounced heavy K isotopic enrichment (δ41K = −0.39‰ to −0.18‰) and elevated zircon δ18O values (7.28‰–8.93‰). These features demonstrate the incorporation of mantle components metasomatized by melts of altered oceanic crust (with elevated δ41K values) into the lower crustal source. In contrast, the 1843 Ma syenogranite displays ultrapotassic affinity with lighter K isotopic compositions (δ41K = −0.45‰ to −0.38‰) and strongly negative zircon εHf(t) values (−11.5 to −10.2), indicating a thickened lower crustal source with contributions from ancient supracrustal sediments. Collectively, K isotopic compositions of the ca. 1.8 Ga adakitic granitoids overcome the limitations of traditional geochemical and isotopic proxies in revealing the complex granite petrogenesis, and they potentially provide evidence for a cycle of plate tectonics, from oceanic crust alteration at mid-ocean ridges through slab subduction to continental collision. The onset of plate tectonics promoted remelting of Archean igneous and sedimentary crust, generating abundant peraluminous and potassic granitoids during the late Archean to Paleoproterozoic and driving crustal compositional maturation in this accretionary orogen.
稳定钾同位素作为一种新的地球化学示踪剂,正逐渐成为研究岩浆分异和来源特征的重要手段。本文对中亚造山带东部重要微大陆——兴安地块新太古代-古元古代花岗岩进行了钾同位素分析,为该增生造山带的花岗岩成因和早期地壳演化提供了新的认识。2568 Ma过铝a型二长花岗岩的δ41K值明显高于上陆地壳(- 0.22‰~ - 0.05‰)。俯冲带可以通过板块衍生的流体/熔体有效地将重K同位素特征转移到地幔楔上。二长花岗岩可能是在前交代的地幔物质与再循环的壳上变质岩共融混合后,在碰撞后的伸展环境中发生了高度的分离结晶作用。尽管1881 Ma二长花岗岩和1843 Ma正长花岗岩与埃达岩具有地球化学上的相似性,但它们明显不同的钾同位素组成和不同的地球化学指纹表明它们的来源区域具有明显的非均质性。1881 Ma二长花岗岩重K同位素富集(δ41K = - 0.39‰~ - 0.18‰),锆石δ18O值升高(7.28‰~ 8.93‰)。这些特征表明,变质洋壳(δ41K值升高)熔体交代的地幔成分被纳入下地壳源。而1843 Ma正长花岗岩则表现出较轻的K同位素(δ41K = - 0.45‰~ - 0.38‰)和较强的负锆石εHf(t)值(- 11.5 ~ - 10.2)的超古典亲和性,表明下地壳源区增厚,并有古表壳上沉积物的贡献。总的来说,约1.8 Ga阿达克岩花岗岩的钾同位素组成克服了传统地球化学和同位素指标在揭示复杂花岗岩岩石成因方面的局限性,并可能为板块构造循环提供证据,从洋中脊的洋壳蚀变到板块俯冲再到大陆碰撞。板块构造的发生促进了太古宙火成岩和沉积地壳的重熔,在晚太古宙至古元古代形成了丰富的过铝质和钾质花岗岩,推动了该增生造山带地壳成分的成熟。
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引用次数: 0
Spatial distributions of macronutrients, heavy metals and microplastics in surface sediments of the mainstem and lakes in the middle part of the Yellow River Basin 黄河中游干流和湖泊表层沉积物中常量营养素、重金属和微塑料的空间分布
IF 8.9 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-11-25 DOI: 10.1016/j.gsf.2025.102214
Xiajie Zhai , Lijuan Cui , Wei Li , Xinsheng Zhao , Chenxi Liu , Hua Ma , Mingshuo Xiong
The Yellow River provides an important foundation for the sustainable development of Chinese civilization. Compared with the upper part (dominated by the Tibetan Plateau) and the lower part (represented by the Yellow River Delta), the central part of the Yellow River Basin (encompassing most of the Loess Plateau) is the most arid and exhibits the most complex relationship between humans and nature. The Chinese government is continuously promoting the protection and management of the ecological environment in the central part of the Yellow River Basin, as it is related to the country’s food security and people’s health, biodiversity conservation and sustainable socio-economic development. However, the distribution patterns and evolution of key ecological elements in the region, which are important determinants of ecosystem productivity and health, have yet to be revealed. This study focused on three key ecological elements, namely, macronutrients (sediment organic carbon, SOC, total nitrogen, TN and total phosphorous, TP), heavy metals (Cu, Ni, Pb, Zn, Cr, Cd, Hg, and As) and microplastics, and aimed to systematically elucidate the change patterns of their concentrations and compositions in sediments from the mainstem of the Yellow River and neighboring typical lakes. The results revealed that the TN content was mostly greater than the SOC content in the sediments from the mainstem of the Yellow River. Moreover, the TN, SOC and heavy metal concentrations increased significantly as a result of agricultural cultivation. Among the six typical lakes, the highest concentrations of both macronutrients and heavy metals were observed in sediment samples from Mingcui Lake (MC; an urban wetland), followed by those in sediment samples from Wuliangsuhai Lake (WLS; surrounded by agricultural fields). Among the heavy metals, the concentrations of Zn and Cr were highest. The abundance of microplastics in the sediments from the mainstream of the Yellow River ranged from 233 to 3333 items kg−1, while the abundance of microplastics in lake sediments ranged from 967 to 1556 items kg−1. The other characteristics of microplastics were consistent, including the concentration of microplastic particles within the 0.2–2 mm range. The main colors of the sampled microplastics were blue, transparent, and gray-black. In addition, rayon accounted for the highest proportion among all polymer types, followed by PET and PE + PP. In general, the amount of the above three environmental elements is closely correlated with the intensity of human activities such as agriculture and urbanization. Stronger correlations were obtained between the concentrations of macronutrients and heavy metals. This study systematically reveals the change patterns of key ecological elements in the study area and advances the understanding of environmental changes, ecosystem evolution and sustainable development in the Yellow River Basin.
黄河是中华文明可持续发展的重要基础。中国政府正在不断推进黄河流域中部生态环境的保护和治理,因为这关系到国家的粮食安全和人民的身体健康,关系到生物多样性的保护和社会经济的可持续发展。然而,作为生态系统生产力和健康的重要决定因素的关键生态要素在该地区的分布格局和演变尚未揭示。本研究以黄河干流及周边典型湖泊沉积物的宏量元素(沉积物有机碳、有机碳、全氮、全氮、全磷、总磷)、重金属(Cu、Ni、Pb、Zn、Cr、Cd、Hg、As)和微塑料为研究对象,系统阐述了它们的浓度和组成变化规律。结果表明,黄河干流沉积物中TN含量大多大于SOC含量。此外,农业耕作显著增加了土壤全氮、有机碳和重金属含量。6个典型湖泊中,宏量营养素和重金属含量均以城市湿地明翠湖最高,其次为农田环绕的五粮素海。重金属中,锌和铬的浓度最高。黄河干流沉积物中微塑料丰度为233 ~ 3333项kg−1,湖泊沉积物中微塑料丰度为967 ~ 1556项kg−1。微塑料的其他特征是一致的,包括0.2-2 mm范围内的微塑料颗粒浓度。微塑料样品的主要颜色是蓝色、透明和灰黑色。此外,在所有聚合物类型中,人造丝所占比例最高,其次是PET和PE + PP。总的来说,上述三种环境要素的含量与农业、城市化等人类活动的强度密切相关。宏量营养素浓度与重金属之间存在较强的相关性。本研究系统揭示了研究区关键生态要素的变化规律,促进了对黄河流域环境变化、生态系统演化与可持续发展的认识。
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Geoscience frontiers
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