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Metamorphic evolution of blueschists in the Heilongjiang Complex: Implications for the subduction history of the Mudanjiang Ocean
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-03-15 DOI: 10.1016/j.gsf.2025.102039
Guang-Ming Sun , Xu-Ping Li , Hans-Peter Schertl , Wen-Yong Duan
The Heilongjiang Complex in northeast China (NE China) separates the Jiamusi and Songliao blocks and marks the suture zone of the former Mudanjiang Ocean, as evidenced by a variety of oceanic basalt-derived blueschists. Understanding the closure history of the Mudanjiang Ocean is crucial to unravelling the tectonic transition from the final amalgamation of the Central Asian Orogenic Belt (CAOB) to the onset of the Paleo-Pacific subduction. In this study, we investigate epidote-ferroglaucophane (Ep-Fgl) and garnet-ferrobarroisite (Grt-Fbrs) schists from the Yilan area of the Heilongjiang Complex through petrological, mineralogical, thermodynamic modelling, whole-rock geochemical, and geochronological analyses. The Ep-Fgl schists preserve a peak assemblage of ferroglaucophane + epidote + chlorite + clinopyroxene + phengite + titanite with peak P–T conditions of 13.5–15.8 kbar and 458–495 °C. On the other hand, the Grt-Fbrs schists exhibit a peak assemblage of garnet + glaucophane/ferroglaucophane + lawsonite + chlorite + phengite + rutile ± clinopyroxene ± titanite, deriving peak P–T conditions of 16.4–18.3 kbar and 457–475 °C. Both types of schist record similar clockwise P–T paths, with three metamorphic stages: a peak epidote-to-lawsonite blueschist-facies stage, a post-peak decompression stage in the epidote amphibolite-facies, and a late greenschist-facies overprint stage. The Ep-Fgl schists display alkaline OIB-like geochemical affinities, while the Grt-Fbrs schists show tholeiitic MORB-like characteristics, suggesting that the protoliths represent fragments of the Mudanjiang oceanic crust. Magmatic zircon grains from Ep-Fgl schists yield protolith ages of 276 ± 1 Ma and 280 ± 1 Ma, whereas zircon of Grt-Fbrs schists document protolith ages of 249 ± 2 Ma and 248 ± 2 Ma, indicating that the Mudanjiang Ocean existed since at least the early Permian. Reconstruction of the metamorphic P–T evolution, combined with previous magmatic and metamorphic age data from rocks of the Heilongjiang Complex and of adjacent tectonic units suggests that the subduction and eventual closure of the Mudanjiang Ocean occurred between the late Triassic and middle Jurassic, driven by a regional stress regime shift caused by the westward subduction of the Paleo-Pacific Plate beneath Eurasia.
{"title":"Metamorphic evolution of blueschists in the Heilongjiang Complex: Implications for the subduction history of the Mudanjiang Ocean","authors":"Guang-Ming Sun ,&nbsp;Xu-Ping Li ,&nbsp;Hans-Peter Schertl ,&nbsp;Wen-Yong Duan","doi":"10.1016/j.gsf.2025.102039","DOIUrl":"10.1016/j.gsf.2025.102039","url":null,"abstract":"<div><div>The Heilongjiang Complex in northeast China (NE China) separates the Jiamusi and Songliao blocks and marks the suture zone of the former Mudanjiang Ocean, as evidenced by a variety of oceanic basalt-derived blueschists. Understanding the closure history of the Mudanjiang Ocean is crucial to unravelling the tectonic transition from the final amalgamation of the Central Asian Orogenic Belt (CAOB) to the onset of the Paleo-Pacific subduction. In this study, we investigate epidote-ferroglaucophane (Ep-Fgl) and garnet-ferrobarroisite (Grt-Fbrs) schists from the Yilan area of the Heilongjiang Complex through petrological, mineralogical, thermodynamic modelling, whole-rock geochemical, and geochronological analyses. The Ep-Fgl schists preserve a peak assemblage of ferroglaucophane + epidote + chlorite + clinopyroxene + phengite + titanite with peak P–T conditions of 13.5–15.8 kbar and 458–495 °C. On the other hand, the Grt-Fbrs schists exhibit a peak assemblage of garnet + glaucophane/ferroglaucophane + lawsonite + chlorite + phengite + rutile ± clinopyroxene ± titanite, deriving peak P–T conditions of 16.4–18.3 kbar and 457–475 °C. Both types of schist record similar clockwise P–T paths, with three metamorphic stages: a peak epidote-to-lawsonite blueschist-facies stage, a post-peak decompression stage in the epidote amphibolite-facies, and a late greenschist-facies overprint stage. The Ep-Fgl schists display alkaline OIB-like geochemical affinities, while the Grt-Fbrs schists show tholeiitic MORB-like characteristics, suggesting that the protoliths represent fragments of the Mudanjiang oceanic crust. Magmatic zircon grains from Ep-Fgl schists yield protolith ages of 276 ± 1 Ma and 280 ± 1 Ma, whereas zircon of Grt-Fbrs schists document protolith ages of 249 ± 2 Ma and 248 ± 2 Ma, indicating that the Mudanjiang Ocean existed since at least the early Permian. Reconstruction of the metamorphic P–T evolution, combined with previous magmatic and metamorphic age data from rocks of the Heilongjiang Complex and of adjacent tectonic units suggests that the subduction and eventual closure of the Mudanjiang Ocean occurred between the late Triassic and middle Jurassic, driven by a regional stress regime shift caused by the westward subduction of the Paleo-Pacific Plate beneath Eurasia.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102039"},"PeriodicalIF":8.5,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143682274","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rethinking energy and policy: Driving the circular economy through renewables versus nuclear energy in OECD countries
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-03-13 DOI: 10.1016/j.gsf.2025.102037
Zhaohui Yang , Danish , Yiting Qiu
The circular economy (CE) presents a promising approach to integrating industry with sustainability and circularity, which helps minimize ecological harm and preserve natural resources for future generations. This study focused on the roles of nuclear energy, renewables, and climate policies in advancing a CE. It examined the intentions of OECD countries regarding CE practices and the various factors influencing these intentions from 2000 to 2019. This study utilized second-generation panel data tools, such as slope homogeneity and stationarity tests, to assess cross-sectional dependence and heterogeneity in the panel dataset. The study employed the moment quantile regression (MM-QR) method to obtain regression estimates and analyze the conditional distribution across all quantiles. The findings indicated that the role of nuclear energy in promoting CE was negative across all quantiles. In contrast, renewable energy positively supports achieving CE in OECD countries. Climate policies assisted OECD countries in progressing toward CE in both the nuclear energy and renewable energy models. We conducted a robust check using a non-parametric panel Granger causality test, which confirmed the expected results for all other factors. The collaborative efforts for waste minimization ensure that nuclear energy systems are resilient, economically feasible, and environmentally sustainable.
{"title":"Rethinking energy and policy: Driving the circular economy through renewables versus nuclear energy in OECD countries","authors":"Zhaohui Yang ,&nbsp;Danish ,&nbsp;Yiting Qiu","doi":"10.1016/j.gsf.2025.102037","DOIUrl":"10.1016/j.gsf.2025.102037","url":null,"abstract":"<div><div>The circular economy (CE) presents a promising approach to integrating industry with sustainability and circularity, which helps minimize ecological harm and preserve natural resources for future generations. This study focused on the roles of nuclear energy, renewables, and climate policies in advancing a CE. It examined the intentions of OECD countries regarding CE practices and the various factors influencing these intentions from 2000 to 2019. This study utilized second-generation panel data tools, such as slope homogeneity and stationarity tests, to assess cross-sectional dependence and heterogeneity in the panel dataset. The study employed the moment quantile regression (MM-QR) method to obtain regression estimates and analyze the conditional distribution across all quantiles. The findings indicated that the role of nuclear energy in promoting CE was negative across all quantiles. In contrast, renewable energy positively supports achieving CE in OECD countries. Climate policies assisted OECD countries in progressing toward CE in both the nuclear energy and renewable energy models. We conducted a robust check using a non-parametric panel Granger causality test, which confirmed the expected results for all other factors. The collaborative efforts for waste minimization ensure that nuclear energy systems are resilient, economically feasible, and environmentally sustainable.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102037"},"PeriodicalIF":8.5,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143746627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Spatiotemporal analysis of AGB and BGB in China: Responses to climate change under SSP scenarios
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-03-12 DOI: 10.1016/j.gsf.2025.102038
Chuanmei Zhu , Yupu Li , Jianli Ding , Jiexin Rao , Yihang Xiang , Xiangyu Ge , Jinjie Wang , Jingzhe Wang , Xiangyue Chen , Zipeng Zhang
Aboveground biomass (AGB) and belowground biomass (BGB) are key components of carbon storage, yet their responses to future climate changes remain poorly understood, particularly in China. Understanding these dynamics is essential for global carbon cycle modeling and ecosystem management. This study integrates field observations, machine learning, and multi-source remote sensing data to reconstruct the distributions of AGB and BGB in China from 2000 to 2020. Then CMIP6 was used to predict the distribution of China under three SSP scenarios (SSP1-1.9, SSP2-4.5, SSP5-8.5) from 2020 to 2100 to fill the existing knowledge gap. The predictive accuracy for AGB (R2 = 0.85) was significantly higher than for BGB (R2 = 0.48), likely due to the greater complexity of modeling belowground dynamics. NDVI (Normalized Difference Vegetation Index) and soil organic carbon density (SOC) were identified as the primary drivers of AGB and BGB changes. During 2000–2020, AGB in China remained stable at approximately 10.69 Pg C, while BGB was around 5.06 Pg C. Forest ecosystems contributed 88.52% of AGB and 43.83% of BGB. AGB showed a relatively slow annual increase, while BGB demonstrated a significant annual growth rate of approximately 37 Tg C yr−1. Under the low-emission scenario, both AGB and BGB show fluctuations and steady growth, particularly in South China and the northwestern part of Northeast China. Under the moderate-emission scenario, AGB and BGB show significant declines and increases, respectively. In the high-emission scenario, both AGB and BGB decline significantly, particularly in the southwestern and central regions. These results provide valuable insights into ecosystem carbon dynamics under climate change, emphasizing the relatively low responsiveness of AGB and BGB to climatic variability, and offering guidance for sustainable land use and management strategies.
地上生物量(AGB)和地下生物量(BGB)是碳储存的关键组成部分,但人们对它们对未来气候变化的反应仍然知之甚少,尤其是在中国。了解这些动态变化对于全球碳循环建模和生态系统管理至关重要。本研究整合了野外观测、机器学习和多源遥感数据,重建了2000年至2020年中国AGB和BGB的分布。然后,利用 CMIP6 预测了 2020 至 2100 年三种 SSP 情景(SSP1-1.9、SSP2-4.5、SSP5-8.5)下中国的 AGB 和 BGB 分布,以填补现有知识空白。AGB 的预测精度(R2 = 0.85)明显高于 BGB(R2 = 0.48),这可能是由于地下动态建模更为复杂。归一化差异植被指数(NDVI)和土壤有机碳密度(SOC)被认为是 AGB 和 BGB 变化的主要驱动因素。2000-2020 年间,中国的 AGB 保持稳定,约为 10.69 Pg C,而 BGB 约为 5.06 Pg C,森林生态系统贡献了 88.52% 的 AGB 和 43.83% 的 BGB。AGB 的年增长率相对缓慢,而 BGB 的年增长率显著,约为 37 Tg C/yr-1。在低排放情景下,AGB 和 BGB 均呈现波动和稳定增长,尤其是在华南和东北西北地区。在中度排放情景下,AGB 和 BGB 分别显著下降和上升。在高排放情景下,AGB 和 BGB 都显著下降,尤其是在西南和中部地区。这些结果为气候变化下的生态系统碳动态提供了宝贵的见解,强调了AGB和BGB对气候变异的响应性相对较低,为可持续土地利用和管理策略提供了指导。
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引用次数: 0
A plate geodynamic game changer: Effects of the 66 Ma Chicxulub asteroid collision
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-03-04 DOI: 10.1016/j.gsf.2025.102032
Amit Segev , Nadav Wetzler , Craig O’Neill , Gideon Rosenbaum
At the end of the Cretaceous period, 66 million years ago, the 7 − 19 km diameter Chicxulub asteroid hit the Yucatan Peninsula in Mexico, triggering global catastrophic environmental changes and mass extinction. The contributions of this event towards changes in plate and plume geodynamics are not fully understood. Here we present a range of geological observations indicating that the impact marked a tectonic turning point in the behavior of mantle plume and plate motion in the Caribbean region and worldwide. At a regional scale, the impact coincides with the termination of seafloor spreading in the Caribbean Ridge. Shortly after the Cretaceous–Paleogene transition, magmatism associated with the Caribbean Large Igneous Province waned, and intensive Paleogene volcanism was initiated. These events happened synchronously with anomalously high mid-ocean ridge magmatism worldwide and an abrupt change in the relative motion of the South American and North American tectonic plates. The evidence for such abrupt changes in plate kinematics and plume behavior raises the possibility that the Chicxulub impact triggered a chain of effects that modified melt reservoirs, subducting plates, mantle flows, and lithospheric deformation. To explain how an asteroid impact could modify tectonic behavior, we discuss two end-member mechanisms: quasi-static and dynamic triggering mechanisms. We designed a numerical model to investigate the strain field and the relative plate motion before and after the impact. The model predicts an enhanced deformation associated with the impact, which surficially tapers off ∼ 500 km from the crater. The impact modifies the subjacent mantle flow field, contributing to long-term mantle-driven dynamic changes. Additionally, deformation associated with seismic effects may have contributed to far-field effects and global changes. We conclude that large asteroid impacts, such as the Chicxulub collision, could trigger cascading effects sufficient to disrupt and significantly modify plate geodynamics.
{"title":"A plate geodynamic game changer: Effects of the 66 Ma Chicxulub asteroid collision","authors":"Amit Segev ,&nbsp;Nadav Wetzler ,&nbsp;Craig O’Neill ,&nbsp;Gideon Rosenbaum","doi":"10.1016/j.gsf.2025.102032","DOIUrl":"10.1016/j.gsf.2025.102032","url":null,"abstract":"<div><div>At the end of the Cretaceous period, 66 million years ago, the 7 − 19 km diameter Chicxulub asteroid hit the Yucatan Peninsula in Mexico, triggering global catastrophic environmental changes and mass extinction. The contributions of this event towards changes in plate and plume geodynamics are not fully understood. Here we present a range of geological observations indicating that the impact marked a tectonic turning point in the behavior of mantle plume and plate motion in the Caribbean region and worldwide. At a regional scale, the impact coincides with the termination of seafloor spreading in the Caribbean Ridge. Shortly after the Cretaceous–Paleogene transition, magmatism associated with the Caribbean Large Igneous Province waned, and intensive Paleogene volcanism was initiated. These events happened synchronously with anomalously high mid-ocean ridge magmatism worldwide and an abrupt change in the relative motion of the South American and North American tectonic plates. The evidence for such abrupt changes in plate kinematics and plume behavior raises the possibility that the Chicxulub impact triggered a chain of effects that modified melt reservoirs, subducting plates, mantle flows, and lithospheric deformation. To explain how an asteroid impact could modify tectonic behavior, we discuss two end-member mechanisms: quasi-static and dynamic triggering mechanisms. We designed a numerical model to investigate the strain field and the relative plate motion before and after the impact. The model predicts an enhanced deformation associated with the impact, which surficially tapers off ∼ 500 km from the crater. The impact modifies the subjacent mantle flow field, contributing to long-term mantle-driven dynamic changes. Additionally, deformation associated with seismic effects may have contributed to far-field effects and global changes. We conclude that large asteroid impacts, such as the Chicxulub collision, could trigger cascading effects sufficient to disrupt and significantly modify plate geodynamics.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102032"},"PeriodicalIF":8.5,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143682273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Implications of the newly discovered Triassic suites from the eastern segment in the giant Tongshan porphyry Cu deposit, northeast China
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-03-02 DOI: 10.1016/j.gsf.2025.102034
Chenglin Bai , Guiqing Xie , Yang Liu , Jie Chen , Qiaoqiao Zhu , Wei Li
The Tongshan porphyry Cu deposit is well known as one of the most economically significant porphyry deposits in northeast China. Recently, Tongshan has become the largest porphyry Cu deposit in northeast China with the successful exploration of the concealed ore zone V. Ore zone V has the largest Cu tonnage (562 Mt @ 0.50% Cu) and extends into the eastern segment at Tongshan. Compared with ore zones I–III, which are hosted within granitic rocks in the western segment, the ore zone V mainly occurs in Duobaoshan volcanic rocks and the roof pendants of newly discovered intrusions. Here, we conducted a study of the understudied eastern ore zone and found that copper mineralization is associated with the newly discovered suites in the eastern segment at Tongshan. Two periods of ore-bearing quartz veins with different widths have been recognized, including quartz-chalcopyrite-pyrite veinlets (0.1–0.2 cm) and quartz-chalcopyrite-polymetallic sulfide wide veins (>0.5 cm). The latter veins can be divided into four stages (I–IV) of mineralization and alteration, which are closely related to the newly discovered granodiorite and dacite porphyry. Our new zircon U–Pb ages show that the granodiorite and dacite porphyry were developed between 228–223 Ma, suggesting that the overprinting porphyry copper mineralization occurred in the Triassic. The Triassic suites have adakite-like character with high Sr/Y, and show no or minimal negative Eu anomalies, indicating early dominant amphibole with limited plagioclase fractionation. For the Triassic intrusions, the high zircon Eu/Eu* (0.67–0.89), ΔFMQ (1.04 ± 0.53; where ΔFMQ is the log fO2 difference between the sample value and the fayalite-magnetite-quartz mineral buffer), hygrometer values (∼7.19 wt.% H2O) and high whole-rock Fe2O3/FeO, Sr/Y, V/Sc and 10,000×(Eu/Eu*)/Y ratios together indicate the Triassic magmas were oxidized and hydrous. These contents and ratios of the Triassic suites are significantly higher than those of the Ordovician suites (ΔFMQ = 0.74 ± 0.26, ∼5.90 wt.% H2O), suggesting that the newly discovered Triassic magmas are more oxidized and hydrous, with high potential for porphyry copper mineralization. Based on the investigation of mineralization and the above results, we proposed that multiple superimposed mineralizations can help form a large-scale deposit and the southeastern segment is a favorable exploration area at Tongshan.
{"title":"Implications of the newly discovered Triassic suites from the eastern segment in the giant Tongshan porphyry Cu deposit, northeast China","authors":"Chenglin Bai ,&nbsp;Guiqing Xie ,&nbsp;Yang Liu ,&nbsp;Jie Chen ,&nbsp;Qiaoqiao Zhu ,&nbsp;Wei Li","doi":"10.1016/j.gsf.2025.102034","DOIUrl":"10.1016/j.gsf.2025.102034","url":null,"abstract":"<div><div>The Tongshan porphyry Cu deposit is well known as one of the most economically significant porphyry deposits in northeast China. Recently, Tongshan has become the largest porphyry Cu deposit in northeast China with the successful exploration of the concealed ore zone V. Ore zone V has the largest Cu tonnage (562 Mt @ 0.50% Cu) and extends into the eastern segment at Tongshan. Compared with ore zones I–III, which are hosted within granitic rocks in the western segment, the ore zone V mainly occurs in Duobaoshan volcanic rocks and the roof pendants of newly discovered intrusions. Here, we conducted a study of the understudied eastern ore zone and found that copper mineralization is associated with the newly discovered suites in the eastern segment at Tongshan. Two periods of ore-bearing quartz veins with different widths have been recognized, including quartz-chalcopyrite-pyrite veinlets (0.1–0.2 cm) and quartz-chalcopyrite-polymetallic sulfide wide veins (&gt;0.5 cm). The latter veins can be divided into four stages (I–IV) of mineralization and alteration, which are closely related to the newly discovered granodiorite and dacite porphyry. Our new zircon U–Pb ages show that the granodiorite and dacite porphyry were developed between 228–223 Ma, suggesting that the overprinting porphyry copper mineralization occurred in the Triassic. The Triassic suites have adakite-like character with high Sr/Y, and show no or minimal negative Eu anomalies, indicating early dominant amphibole with limited plagioclase fractionation. For the Triassic intrusions, the high zircon Eu/Eu* (0.67–0.89), Δ<sub>FMQ</sub> (1.04 ± 0.53; where Δ<sub>FMQ</sub> is the log <em>f</em>O<sub>2</sub> difference between the sample value and the fayalite-magnetite-quartz mineral buffer), hygrometer values (∼7.19 wt.% H<sub>2</sub>O) and high whole-rock Fe<sub>2</sub>O<sub>3</sub>/FeO, Sr/Y, V/Sc and 10,000×(Eu/Eu*)/Y ratios together indicate the Triassic magmas were oxidized and hydrous. These contents and ratios of the Triassic suites are significantly higher than those of the Ordovician suites (Δ<sub>FMQ</sub> = 0.74 ± 0.26, ∼5.90 wt.% H<sub>2</sub>O), suggesting that the newly discovered Triassic magmas are more oxidized and hydrous, with high potential for porphyry copper mineralization. Based on the investigation of mineralization and the above results, we proposed that multiple superimposed mineralizations can help form a large-scale deposit and the southeastern segment is a favorable exploration area at Tongshan.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102034"},"PeriodicalIF":8.5,"publicationDate":"2025-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143611723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of a comprehensive framework for wetland ecosystem assessment and management
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-03-02 DOI: 10.1016/j.gsf.2025.102036
Manob Das , Arijit Das , Suman Singha
This study focuses on the assessment of ecosystem health (EH), ecosystem services (ES), and ecosystem risk (ER) in East Kolkata Wetland (EKW). A comprehensive framework on the EH, ES and ER has been developed using remote sesning and geo-spatial techniques for the year 2000, 2005, 2010, 2015, and 2020. The study also assessed ecosystem structure and fragmentation using landscape metrics calculated using fragstats, which showed a significant influence of land use and land cover (LULC) changes on the wetland’s ecological integrity. The study revealed that 6.86% of EKW fallen under a very low EH zone, while 20% was categorized as having very high EH. Spatio-temporal analysis of ES indicated that 30% of the area had very low ES value, with only 8% exhibiting very high ES. ER assessment revealed that 7% of the study area was highly ER, while 12% identified within a high ER zone, reflecting frequent LULC changes. The correlation analysis highlighted strong negative relationships between landscape deviation degree (LDD) and EH (−0.971), and between normalized difference water index (NDWI) and normalized difference vegetation index (NDVI) (−0.991). Additionally, landscape metrics such as the number of patches (NP) and the largest patch index (LPI) exhibited significant correlations, emphasizing the impact of fragmentation on EH and resilience. This comprehensive assessment underscores the importance of integrated approaches to monitor and manage wetland ecosystems, particularly in urban areas facing significant environmental stressors. The findings are crucial for informed decision-making and sustainable management of the wetland ecosystems, particularly in the cities of the global south.
本研究的重点是评估东加尔各答湿地(EKW)的生态系统健康(EH)、生态系统服务(ES)和生态系统风险(ER)。利用遥感和地理空间技术,为 2000 年、2005 年、2010 年、2015 年和 2020 年的生态系统健康、生态系统服务和生态系统风险制定了一个综合框架。该研究还利用使用 fragstats 计算的景观指标对生态系统结构和破碎化进行了评估,结果表明,土地利用和土地覆被 (LULC) 变化对湿地的生态完整性有显著影响。研究结果显示,6.86% 的东九龙湖湿地属于极低 EH 区,20% 的湿地属于极高 EH 区。ES的时空分析表明,30%的区域ES值极低,只有8%的区域ES值极高。ER评估显示,7%的研究区域为高ER区,12%的研究区域为高ER区,这反映了土地利用、土地利用变化和土地利用变化的频繁变化。相关性分析表明,景观偏差度(LDD)与 EH(-0.971)之间以及归一化差异水指数(NDWI)与归一化差异植被指数(NDVI)(-0.991)之间存在很强的负相关关系。此外,斑块数量(NP)和最大斑块指数(LPI)等景观指标也表现出显著的相关性,强调了破碎化对 EH 和恢复力的影响。这项综合评估强调了采用综合方法监测和管理湿地生态系统的重要性,尤其是在面临重大环境压力的城市地区。这些发现对于湿地生态系统的知情决策和可持续管理至关重要,尤其是在全球南部城市。
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引用次数: 0
Cobalt enrichment in Paleoproterozoic African and Brazilian manganese deposits
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-03-01 DOI: 10.1016/j.gsf.2025.102035
Evilarde Carvalho Uchôa Filho , Felipe Holanda dos Santos , Douglas Teixeira Martins , Wagner da Silva Amaral , José Alberto Rodrigues do Vale
<div><div>This study highlights a new by-product source for cobalt by recycling Paleoproterozoic Mn deposits. We present a geochemical modeling approach utilizing Principal Component Analysis (PCA) for available geochemical data of Paleoproterozoic manganese deposits found in Africa and Brazil, which exhibit anomalous cobalt contents (up to 1200 ppm) along with other metals such as copper, nickel, and vanadium. The PCA results for the correlation coefficient matrix of the Enrichment Factor (EF) values of major and trace elements from samples of eight Mn deposits found in Africa and Brazil (Kisenge-Kamata, Moanda, Nsuta in Africa, and Azul, Buritirama, Lagoa do Riacho, Morro da Mina, and Serra do Navio in Brazil) yielded a cumulative variance of 53.3% for PC1 (34%) and PC2 (19.3%). In PC1, the highest positive loadings correspond to the variables Mn<sub>EF</sub>, Ni<sub>EF</sub>, and Co<sub>EF</sub>, while the highest negative loadings correspond to the variables Si<sub>EF</sub>, Fe<sub>EF</sub>, K<sub>EF</sub>, Ti<sub>EF</sub>, Cr<sub>EF</sub>, and Zr<sub>EF</sub>. PC2 exhibits the highest positive loadings for the variables Ca<sub>EF</sub>, Mg<sub>EF</sub>, and P<sub>EF</sub>, while the highest negative loadings are for Cu<sub>EF</sub> and V<sub>EF</sub>. The biplot diagram representation showed that clusters of vectors Mn<sub>EF</sub>, Ni<sub>EF</sub>, Co<sub>EF</sub>, V<sub>EF</sub>, and Cu<sub>EF</sub> influence samples of Mn-carbonate rock, Mn-carbonate–silicate rock, Mn-silicate rock, and Mn-carbonate-siliciclastic rock, all with high Co<sub>EF</sub> values (up to 414). The cluster of vectors Ca<sub>EF</sub>, Mg<sub>EF</sub>, and P<sub>EF</sub> significantly influence carbonate rock and dolomite marble, which have low Co<sub>EF</sub> values (close to 0). The cluster of vectors Si<sub>EF</sub>, Fe<sub>EF</sub>, K<sub>EF</sub>, Ti<sub>EF</sub>, Cr<sub>EF</sub>, and Zr<sub>EF</sub> strongly influences siliciclastic rock, which exhibits low Co<sub>EF</sub> values. On the other hand, the cluster of vectors Cu<sub>EF</sub> and V<sub>EF</sub> influences oxidized Mn ore, which exhibits Co<sub>EF</sub> values of up to 108. The results reveal a dichotomy regarding the origin of cobalt and other metal enrichments in these deposits linked to the Mn redox cycle. This process involves the formation of Mn-oxyhydroxides with the adsorption of Co and other metals under oxic conditions, followed by the burial of these Mn oxides in an anoxic diagenetic environment, where microbial sulfate reduction leads to the nucleation of Mn-carbonates and the formation of metal-rich sulfides (Fe, Co, Ni, V). Additionally, detrital input and sulfide phases (e.g., framboidal pyrite) for the formation of Mn-rich siliciclastic rocks associated with Mn-carbonate rocks are evidenced by proxies Si<sub>EF</sub>, Fe<sub>EF</sub>, K<sub>EF</sub>, Ti<sub>EF</sub>, Cr<sub>EF</sub>, and Zr<sub>EF</sub>. This new exploration approach, supported by geochemical modeling through PCA, enha
本研究强调了通过回收利用古生代锰矿床获得钴的新副产品来源。我们针对非洲和巴西发现的古生代锰矿床的现有地球化学数据,提出了一种利用主成分分析(PCA)的地球化学建模方法,这些矿床的钴含量(高达 1200 ppm)与铜、镍和钒等其他金属一起呈现出异常。非洲和巴西发现的八个锰矿床(非洲的 Kisenge-Kamata、Moanda、Nsuta 和巴西的 Azul、Buritirama、Lagoa do Riacho、Morro da Mina 和 Serra do Navio)样品中主要元素和微量元素富集因子(EF)值的相关系数矩阵的 PCA 结果显示,PC1(34%)和 PC2(19.3%)的累积方差为 53.3%。在 PC1 中,正载荷最高的变量是 MnEF、NiEF 和 CoEF,负载荷最高的变量是 SiEF、FeEF、KEF、TiEF、CrEF 和 ZrEF。PC2 中,正载荷最高的变量是 CaEF、MgEF 和 PEF,负载荷最高的变量是 CuEF 和 VEF。双折线图显示,锰-碳酸盐岩、镍-碳酸盐岩、钴-碳酸盐岩、锰-碳酸盐-硅酸盐岩和锰-碳酸盐-硅质岩的 CoEF 值都很高(最高达 414),而锰-碳酸盐岩、镍-碳酸盐岩、钴-碳酸盐岩、钒-碳酸盐岩和铜-碳酸盐岩的 CoEF 值都很低。CaEF、MgEF 和 PEF 矢量群对 CoEF 值较低(接近 0)的碳酸盐岩和白云石大理岩有显著影响。SiEF、FeEF、KEF、TiEF、CrEF 和 ZrEF 向量群对硅质岩影响较大,其 CoEF 值较低。另一方面,CuEF 和 VEF 向量群对氧化锰矿石有影响,其 CoEF 值高达 108。研究结果表明,这些矿床中钴和其他金属富集的起源与锰氧化还原循环有关。这一过程包括在氧化条件下吸附钴和其他金属形成锰氧氢氧化物,然后将这些锰氧化物埋藏在缺氧的成岩环境中,微生物的硫酸盐还原作用导致锰碳酸盐成核并形成富含金属的硫化物(铁、钴、镍、钒)。此外,SiEF、FeEF、KEF、TiEF、CrEF 和 ZrEF 等代用指标也证明了与锰碳酸盐岩相关的富锰硅质岩形成的碎屑输入和硫化物相(如框架黄铁矿)。这种新的勘探方法得到了通过PCA建立地球化学模型的支持,增强了我们对这些古新生代锰矿床成因的了解,并为钴勘探指明了一条新的道路。随着全球对钴的需求不断增加,特别是在涉及电动汽车电池和能源储存的应用中,勘探这些矿床成为生产这些关键金属的替代来源。
{"title":"Cobalt enrichment in Paleoproterozoic African and Brazilian manganese deposits","authors":"Evilarde Carvalho Uchôa Filho ,&nbsp;Felipe Holanda dos Santos ,&nbsp;Douglas Teixeira Martins ,&nbsp;Wagner da Silva Amaral ,&nbsp;José Alberto Rodrigues do Vale","doi":"10.1016/j.gsf.2025.102035","DOIUrl":"10.1016/j.gsf.2025.102035","url":null,"abstract":"&lt;div&gt;&lt;div&gt;This study highlights a new by-product source for cobalt by recycling Paleoproterozoic Mn deposits. We present a geochemical modeling approach utilizing Principal Component Analysis (PCA) for available geochemical data of Paleoproterozoic manganese deposits found in Africa and Brazil, which exhibit anomalous cobalt contents (up to 1200 ppm) along with other metals such as copper, nickel, and vanadium. The PCA results for the correlation coefficient matrix of the Enrichment Factor (EF) values of major and trace elements from samples of eight Mn deposits found in Africa and Brazil (Kisenge-Kamata, Moanda, Nsuta in Africa, and Azul, Buritirama, Lagoa do Riacho, Morro da Mina, and Serra do Navio in Brazil) yielded a cumulative variance of 53.3% for PC1 (34%) and PC2 (19.3%). In PC1, the highest positive loadings correspond to the variables Mn&lt;sub&gt;EF&lt;/sub&gt;, Ni&lt;sub&gt;EF&lt;/sub&gt;, and Co&lt;sub&gt;EF&lt;/sub&gt;, while the highest negative loadings correspond to the variables Si&lt;sub&gt;EF&lt;/sub&gt;, Fe&lt;sub&gt;EF&lt;/sub&gt;, K&lt;sub&gt;EF&lt;/sub&gt;, Ti&lt;sub&gt;EF&lt;/sub&gt;, Cr&lt;sub&gt;EF&lt;/sub&gt;, and Zr&lt;sub&gt;EF&lt;/sub&gt;. PC2 exhibits the highest positive loadings for the variables Ca&lt;sub&gt;EF&lt;/sub&gt;, Mg&lt;sub&gt;EF&lt;/sub&gt;, and P&lt;sub&gt;EF&lt;/sub&gt;, while the highest negative loadings are for Cu&lt;sub&gt;EF&lt;/sub&gt; and V&lt;sub&gt;EF&lt;/sub&gt;. The biplot diagram representation showed that clusters of vectors Mn&lt;sub&gt;EF&lt;/sub&gt;, Ni&lt;sub&gt;EF&lt;/sub&gt;, Co&lt;sub&gt;EF&lt;/sub&gt;, V&lt;sub&gt;EF&lt;/sub&gt;, and Cu&lt;sub&gt;EF&lt;/sub&gt; influence samples of Mn-carbonate rock, Mn-carbonate–silicate rock, Mn-silicate rock, and Mn-carbonate-siliciclastic rock, all with high Co&lt;sub&gt;EF&lt;/sub&gt; values (up to 414). The cluster of vectors Ca&lt;sub&gt;EF&lt;/sub&gt;, Mg&lt;sub&gt;EF&lt;/sub&gt;, and P&lt;sub&gt;EF&lt;/sub&gt; significantly influence carbonate rock and dolomite marble, which have low Co&lt;sub&gt;EF&lt;/sub&gt; values (close to 0). The cluster of vectors Si&lt;sub&gt;EF&lt;/sub&gt;, Fe&lt;sub&gt;EF&lt;/sub&gt;, K&lt;sub&gt;EF&lt;/sub&gt;, Ti&lt;sub&gt;EF&lt;/sub&gt;, Cr&lt;sub&gt;EF&lt;/sub&gt;, and Zr&lt;sub&gt;EF&lt;/sub&gt; strongly influences siliciclastic rock, which exhibits low Co&lt;sub&gt;EF&lt;/sub&gt; values. On the other hand, the cluster of vectors Cu&lt;sub&gt;EF&lt;/sub&gt; and V&lt;sub&gt;EF&lt;/sub&gt; influences oxidized Mn ore, which exhibits Co&lt;sub&gt;EF&lt;/sub&gt; values of up to 108. The results reveal a dichotomy regarding the origin of cobalt and other metal enrichments in these deposits linked to the Mn redox cycle. This process involves the formation of Mn-oxyhydroxides with the adsorption of Co and other metals under oxic conditions, followed by the burial of these Mn oxides in an anoxic diagenetic environment, where microbial sulfate reduction leads to the nucleation of Mn-carbonates and the formation of metal-rich sulfides (Fe, Co, Ni, V). Additionally, detrital input and sulfide phases (e.g., framboidal pyrite) for the formation of Mn-rich siliciclastic rocks associated with Mn-carbonate rocks are evidenced by proxies Si&lt;sub&gt;EF&lt;/sub&gt;, Fe&lt;sub&gt;EF&lt;/sub&gt;, K&lt;sub&gt;EF&lt;/sub&gt;, Ti&lt;sub&gt;EF&lt;/sub&gt;, Cr&lt;sub&gt;EF&lt;/sub&gt;, and Zr&lt;sub&gt;EF&lt;/sub&gt;. This new exploration approach, supported by geochemical modeling through PCA, enha","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102035"},"PeriodicalIF":8.5,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143637626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Erratum to “Cretaceous magmatic arc in Hainan and the peri-South China Sea as evidenced by geochemical fingerprinting of granitoids in the region” [Geosci. Front. 15(5) (2024) 101866]
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-03-01 DOI: 10.1016/j.gsf.2024.101963
Xiao-Yan Jiang , Yildirim Dilek , Xian-Hua Li
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引用次数: 0
Geochemical cycling, tectonic drivers and environmental impacts of CH4-rich mud extrusions in subduction zones
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-02-24 DOI: 10.1016/j.gsf.2025.102029
Umair Khan , Shiguo Wu , Majid Khan , Jinwei Gao , Junjin Chen
Subduction zones are critical interfaces for lithospheric volatile fluxes, where complex tectonic and geochemical interactions facilitate the release of gases and fluids from deep-seated reservoirs within the Earth’s crust. Mud volcanism, as a dynamic manifestation of these processes, contributes CH4 emissions that influence the global methane budget and impact marine ecosystems. Although ∼2000 CH4-rich mud extrusions have been documented in subduction zones globally, the geological origins and subduction-related geochemical and tectonic mechanisms driving these emissions remain poorly understood. This research examines the Makran subduction zone which hosts one of the world’s largest accretionary wedge and extensive CH4-rich mud extrusions, as a model system. Integrated geochemical, geophysical, and geological observations reveal that thermogenic CH4 and clay-rich fluidized muds originate from deeply buried Himalayan turbidites (underthrusted sediments), driven by organic-rich sediment maturation and high fluid overpressure. Key tectonic features, including thrust faults, overburden pressure of wedge-top sediments, normal faults, brittle fractures, and seismicity, facilitate CH4-rich mud extrusions into the hydrosphere and atmosphere. The extruded gases are predominantly CH4, with minor C2H6, C3H8, i-C4H10, and n-C4H10 while the mud breccia exhibits a chemical composition dominated by SiO2, Al2O3, and Fe2O3, enriched with trace elements (Rb, Zr, and V) and clay minerals, quartz, and carbonates. Geochemical indicators suggest intense chemical weathering and mature sediments classifying the mud breccia as litharenite and sub-litharenite, indicative of deep burial and compaction. These findings model the evolution of CH4-rich mud extrusions through three geological stages: (i) Eocene to Early Miocene pre-thermogenic formation of the CH4-rich source, (ii) Middle Miocene to Pliocene syn-thermogenic CH4 and fluidized mud generation, and (iii) Pleistocene to Recent post-thermogenic CH4-rich fluidized mud migration. These findings underscore the critical yet often overlooked role of subduction-related geochemical and tectonic processes in CH4 generation and emission, with significant implications for the global CH4 budget and marine ecosystems.
俯冲带是岩石圈挥发性通量的关键界面,在这里,复杂的构造和地球化学相互作用促进了地壳深层储层中气体和液体的释放。泥火山活动是这些过程的动态表现形式,它排放的甲烷影响全球甲烷预算,并对海洋生态系统产生影响。虽然全球俯冲带已记录了 2000 ∼ 2000 次富含 CH4 的泥浆喷出,但人们对这些排放的地质起源以及与俯冲相关的地球化学和构造机制仍然知之甚少。本研究以拥有世界上最大增生楔之一和大量富含 CH4 的泥浆挤出的马克兰俯冲带为模型系统进行研究。综合地球化学、地球物理和地质观测结果表明,在富含有机质的沉积物成熟和高流体超压的驱动下,热成CH4和富含粘土的流化泥源自深埋的喜马拉雅浊积岩(下推沉积物)。主要的构造特征,包括推断断层、楔顶沉积物的上覆压力、正断层、脆性断裂和地震,促进了富含甲烷的泥浆挤出到水圈和大气中。挤出的气体主要是 CH4,还有少量 C2H6、C3H8、i-C4H10 和 n-C4H10,而泥质角砾岩的化学成分主要是 SiO2、Al2O3 和 Fe2O3,富含微量元素(Rb、Zr 和 V)以及粘土矿物、石英和碳酸盐。地球化学指标表明,强烈的化学风化和成熟的沉积物将泥质角砾岩划分为石英岩和亚石英岩,表明了深埋和压实。这些发现模拟了富含 CH4 的泥浆挤出物在三个地质阶段的演变过程:(i) 始新世至中新世早期富含 CH4 的热源形成前阶段,(ii) 中新世至上新世同温层 CH4 和流化泥浆生成阶段,以及 (iii) 更新世至近世富含 CH4 的流化泥浆热源形成后迁移阶段。这些发现强调了与俯冲有关的地球化学和构造过程在甲烷生成和排放中的关键作用,但这一作用往往被忽视,对全球甲烷预算和海洋生态系统具有重大影响。
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引用次数: 0
CAUM: A software for calculating and assessing chemical ages of uranium minerals
IF 8.5 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-02-24 DOI: 10.1016/j.gsf.2025.102031
Hao Song , Tao Xiao , Guoxiang Chi , Zexin Wang , Zhengqi Xu , Mingcai Hou
It has been shown that the age of minerals in which U ± Th are a major (e.g., uraninite, pitchblende and thorite) or minor (e.g., monazite, xenotime) component can be calculated from the concentrations of U ± Th and Pb rather than their isotopes, and such ages are referred to as chemical ages. Although equations for calculating the chemical ages have been well established and various computation programs have been reported, there is a lack of software that can not only calculate the chemical ages of individual analytical points but also provide an evaluation of the errors of individual ages as well as the whole dataset. In this paper, we develop a software for calculating and assessing the chemical ages of uranium minerals (CAUM), an open-source Python-based program with a friendly Graphical User Interface (GUI). Electron probe microanalysis (EPMA) data of uranium minerals are first imported from Excel files and used to calculate the chemical ages and associated errors of individual analytical points. The age data are then visualized to aid evaluating if the dataset comprises one or multiple populations and whether or not there are meaningful correlations between the chemical ages and impurities. Actions can then be taken to evaluate the errors within individual populations and the significance of the correlations. The use of the software is demonstrated with examples from published data.
{"title":"CAUM: A software for calculating and assessing chemical ages of uranium minerals","authors":"Hao Song ,&nbsp;Tao Xiao ,&nbsp;Guoxiang Chi ,&nbsp;Zexin Wang ,&nbsp;Zhengqi Xu ,&nbsp;Mingcai Hou","doi":"10.1016/j.gsf.2025.102031","DOIUrl":"10.1016/j.gsf.2025.102031","url":null,"abstract":"<div><div>It has been shown that the age of minerals in which U ± Th are a major (e.g., uraninite, pitchblende and thorite) or minor (e.g., monazite, xenotime) component can be calculated from the concentrations of U ± Th and Pb rather than their isotopes, and such ages are referred to as chemical ages. Although equations for calculating the chemical ages have been well established and various computation programs have been reported, there is a lack of software that can not only calculate the chemical ages of individual analytical points but also provide an evaluation of the errors of individual ages as well as the whole dataset. In this paper, we develop a software for calculating and assessing the chemical ages of uranium minerals (CAUM), an open-source Python-based program with a friendly Graphical User Interface (GUI). Electron probe microanalysis (EPMA) data of uranium minerals are first imported from Excel files and used to calculate the chemical ages and associated errors of individual analytical points. The age data are then visualized to aid evaluating if the dataset comprises one or multiple populations and whether or not there are meaningful correlations between the chemical ages and impurities. Actions can then be taken to evaluate the errors within individual populations and the significance of the correlations. The use of the software is demonstrated with examples from published data.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102031"},"PeriodicalIF":8.5,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143550692","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Geoscience frontiers
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