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South Tibetan Detachment System (STDS), NW Himalaya: A possible Cambro–Ordovician tectonic terrane boundary, and its Cenozoic remobilization 喜马拉雅山西北部的藏南支系(STDS):可能的寒武-奥陶纪构造地层边界及其新生代再动化
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-30 DOI: 10.1016/j.gr.2024.08.008
Gargi G. Deshmukh , A.K. Jain , P.K. Mukherjee , Saurabh Singhal , Rahul Dixit , D.C. Srivastava

The South Tibetan Detachment System is an important extensional fault zone, separating the Greater Himalayan Sequence from the overlying Tethyan Himalayan Sequence, and is well exposed in the upper reaches of the Dhauliganga valley, NW Himalaya. This fault system is characterized by the occurrence of an extensive Cambro–Ordovician granite belt between Sutlej and Dhauliganga valleys, although only a few small granitoids intrude the high-grade mylonite gneiss of the Greater Himalayan Sequence in its immediate footwall. These bodies yielded U-Pb zircon crystallization ages between 498.92 ± 5.5 Ma and 486.54 ± 2.3 Ma. This work postulates that the South Tibetan Detachment System evolved as a major proto-tectonic marginal extensional terrane boundary during the Cambro–Ordovician Kurgiakh/Bhimphedian Orogeny, when it was the conduit for emplacement of the Cambro–Ordovician granite belt. Denudation of the Neoproterozoic Greater Himalayan Sequence and the Paleozoic granites on its footwall provided approximately ∼ 10 km thick sediments into the Tethyan Basin due to this fault system as a master growth fault. Reactivation of this fault system controlled further melting and emplacement of the Higher Himalayan Leucogranite belt during the Cenozoic. Zircon growth is observed in two distinct modes: pulsative from the Late Eocene to Early Oligocene, with peaks at 33.99 ± 1.07 Ma, 30.53 ± 0.32 Ma and 25.03 ± 0.54 Ma; and in the continuous mode from 23.68 ± 0.94 Ma to 13.30 ± 0.30 Ma, in the Miocene, for nearly 10.0 myr. These datasets reveal some of the oldest pulsative movements in the Late Eocene–Early Oligocene during crustal thickening, thrusting and associated metamorphism, followed by continuous extension during the Miocene. Data from the South Tibetan Detachment System are distinct in character, and do not support either its eastwards younging or diachronous movements along the Dhauliganga valley.

藏南剥离系统是一个重要的伸展断层带,将大喜马拉雅山系与上覆的泰西喜马拉雅山系分隔开来。该断层系统的特点是在 Sutlej 谷和 Dhauliganga 谷之间出现了一个广阔的寒武-奥陶纪花岗岩带,尽管只有一些小的花岗岩侵入其紧邻的脚墙的大喜马拉雅岩序的高品位麦饭石片麻岩。这些岩体的 U-Pb 锆石结晶年龄介于 498.92 ± 5.5 Ma 和 486.54 ± 2.3 Ma 之间。这项工作推测,藏南脱落系是在寒武-奥陶纪库尔吉克/宾格迭造山运动期间作为一个主要的原构造边缘延伸地层边界演化而成的,当时它是寒武-奥陶纪花岗岩带的置换通道。新近纪大喜马拉雅山系及其山麓古生代花岗岩的剥蚀作用为哲海盆提供了约 10 千米厚的沉积物,因为该断层系统是一个主生长断层。在新生代,该断层系统的重新激活控制了高喜马拉雅白花岗岩带的进一步熔融和移位。锆石的生长有两种不同的模式:从晚始新世到渐新世早期的脉冲式生长,峰值分别为 33.99 ± 1.07 Ma、30.53 ± 0.32 Ma 和 25.03 ± 0.54 Ma;以及从 23.68 ± 0.94 Ma 到 13.30 ± 0.30 Ma(中新世)近 10.0 Myr 的连续式生长。这些数据集揭示了晚始新世-早渐新世一些最古老的脉动运动,发生在地壳增厚、推移和相关变质过程中,随后是中新世时期的持续延伸。藏南脱落系的数据具有独特的特征,既不支持其向东年轻化,也不支持沿道里京河谷的非同步运动。
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引用次数: 0
Synchronous felsic volcanism and carbonate sedimentation as a setting for VMS deposits localization at the Salair terrane, NE Central Asian Orogenic Belt 中亚造山带东北部萨拉尔地层的同步长岩火山活动和碳酸盐沉积为 VMS 矿床定位提供了环境
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-30 DOI: 10.1016/j.gr.2024.08.014
N.I. Vetrova, E.V. Vetrov

The Salair terrane located in the northern part of the Central Asian Orogenic Belt (CAOB) contains many epithermal deposits including volcanogenic massive sulphide (VMS) deposits. The host rocks mainly consist of felsic volcanic rocks such as lavas, volcanic breccias and tuffs that associated with thick strata of carbonates. In this study, we present zircon U–Pb ages, whole rock geochemistry, and Nd isotope data from the volcanic rocks, and results of geochemical and isotope (Sr, C, O) studies of carbonates to constrain their age and petrogenesis, and to characterize the tectonic setting. Zircon U–Pb dating reveals that the ore-bearing felsic lavas have age of 519.3 ± 1.9 Ma, while the felsic tuffs have age of 516.0 ± 0.9 Ma. These volcanic rocks are characterized by high SiO2 and Na2O contents, enrichment in light rare-earth elements, remarkable negative Eu anomalies, and pronounced depletion in Nb, Ta, P, and Ti. They have depleted ɛNd(t) values ranging from +4.9 to +6.3, and young two-stage Nd model ages (from 0.82 to 0.64 Ga). The felsic volcanic rocks from the Salair terrane are interpreted as highly evolved I-type magmatic rocks that might be produced by high degree partial melting of juvenile lower crust without a significant contribution of ancient crust and without crustal reworking.

Felsic volcanism was accompanied by the formation of thick strata of carbonates. These carbonates are marine limestones with Mg/Ca ratios less than 0.007, δ18O(SMOW) values from 17.1 to 23.8 ‰ and δ13C(PDB) values between –0.9 and +0.9. Their Sr isotope composition varies in a narrow range within 0.70844–0.70859 that interpreted as representing proxy for coeval seawater. These values are consistent with depositional ages of 520–510 Ma and confirms the synchronicity of the formation of carbonates and felsic volcanism. Based on the regional geology and geochemistry, the ore-host rocks of the Salair terrane were formed in the back-arc setting where the marine transgression occurred as a result of graben subsidence. It is important for better understanding epithermal deposits in the northern CAOB and might provide new insights about prospecting the VMS deposits in similar tectonic settings.

位于中亚造山带(CAOB)北部的萨拉伊尔(Salair)地层包含许多热液矿床,其中包括火山成因块状硫化物(VMS)矿床。母岩主要由熔岩、火山碎屑岩和凝灰岩等长粒火山岩组成,并伴有厚厚的碳酸盐地层。在本研究中,我们介绍了火山岩的锆石 U-Pb 年龄、全岩地球化学和钕同位素数据,以及碳酸盐岩的地球化学和同位素(Sr、C、O)研究结果,以确定其年龄和成岩过程,并描述构造环境的特征。锆石 U-Pb 测定显示,含矿长岩熔岩的年龄为 519.3 ± 1.9 Ma,而长岩凝灰岩的年龄为 516.0 ± 0.9 Ma。这些火山岩的特点是SiO2和Na2O含量高,轻稀土元素富集,Eu负异常显著,Nb、Ta、P和Ti明显贫化。它们的ɛNd(t)值介于+4.9至+6.3之间,具有年轻的两阶段Nd模型年龄(0.82至0.64 Ga)。萨拉尔地层中的长英质火山岩被解释为高度演化的I型岩浆岩,可能由幼年下地壳的高度部分熔融产生,没有古地壳的大量参与,也没有地壳再加工。这些碳酸盐是海相灰岩,镁/钙比小于0.007,δ18O(SMOW)值在17.1至23.8‰之间,δ13C(PDB)值在-0.9至+0.9之间。它们的锶同位素组成在 0.70844-0.70859 的狭窄范围内变化,被解释为代表共生海水。这些数值与 520-510 Ma 的沉积年龄一致,证实了碳酸盐的形成与长岩火山活动的同步性。根据区域地质学和地球化学,Salair 陆相的矿床岩石是在弧后环境中形成的,在弧后环境中,由于地堑下沉,发生了海相侵蚀。这对更好地了解 CAOB 北部的热液矿床非常重要,并可能为在类似构造环境中勘探 VMS 矿床提供新的见解。
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引用次数: 0
Scheelite as a microtextural and geochemical tracer of multistage ore-forming processes in skarn mineralization: A case study from the giant Xintianling W deposit, South China 白钨矿作为矽卡岩成矿多阶段成矿过程的微观纹理和地球化学示踪剂:华南新田岭W巨型矿床案例研究
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-30 DOI: 10.1016/j.gr.2024.08.010
Hongfei Di , Yong-Jun Shao , Yi-Qu Xiong , Han Zheng , Xiang Fang , Wenjie Fang

The Xintianling deposit is one of the largest skarn-type scheelite deposit in China. Recent discoveries of quartz-vein-type scheelite mineralization within the deposit have raised questions about its origin and the evolution of ore-forming fluids, hindering a comprehensive understanding of the ore-forming process. We investigate the microtextures, trace elements, and oxygen isotope compositions of scheelite from different stages in both skarn-type and quartz-vein-type W mineralizations. Combined with apatite geochemistry and U–Pb dating, we determine the timing of quartz-vein-type mineralization and the evolution of magmatic-hydrothermal system. Based on detailed petrological observation, three types (seven subtypes) of scheelite and two types of apatite are identified. The Mo contents and Eu/Eu* ratios of scheelite, along with the Ce/Ce* ratios of apatite indicate the oxygen fugacity of fluids during the skarn metallogenic episode is generally higher than that during the quartz-vein metallogenic episode. Furthermore, the Y/Ho ratios and REE patterns of scheelite indicate the presence of at least three significant stages of fluid influx and fluid-rock interactions throughout entire ore-forming process. The O isotope compositions of scheelite in the quartz-vein-type metallogenic episode reveal that the ore-forming fluids are originated from a magmatic source, and meteoric water was mixed into the system, leading to the precipitation of the latest stage of scheelite. The apatites closely coexist with scheelite, from the early and the late stages of quartz-vein metallogenic episode, yield consistent U–Pb ages within error of 160.4 ± 2.4 Ma and 158.4 ± 1.3 Ma, respectively, indicating a close genetic link between quartz-vein-type W mineralization and the fine-grained porphyritic biotite granite. Our study highlights the significance of pulsed fluid exsolution and the combined effects of multiple mechanisms, including fluid-rock interaction, fluid mixing, and physicochemical condition changes, in the formation of large W deposits.

新田岭矿床是中国最大的矽卡岩型白钨矿床之一。最近在该矿床中发现的石英脉型白钨矿化现象引发了人们对其成矿起源和成矿流体演化的疑问,阻碍了对成矿过程的全面了解。我们研究了矽卡岩型和石英脉型白钨矿化不同阶段的白钨矿的微量成分、微量元素和氧同位素组成。结合磷灰石地球化学和U-Pb年代测定,我们确定了石英脉型成矿的时间和岩浆-热液系统的演化过程。根据详细的岩石学观察,确定了三种类型(七个亚型)的白钨矿和两种类型的磷灰石。白钨矿的 Mo 含量和 Eu/Eu* 比值以及磷灰石的 Ce/Ce* 比值表明,矽卡岩成矿期流体的氧富集度普遍高于石英脉成矿期。此外,白钨矿的Y/Ho比率和REE模式表明,在整个成矿过程中至少存在三个重要的流体流入和流体与岩石相互作用阶段。石英脉型成矿事件中白钨矿的O同位素组成显示,成矿流体来源于岩浆源,陨石水混入系统,导致了白钨矿最新阶段的沉淀。在石英脉成矿早期和晚期,与白钨矿紧密共生的磷灰石的U-Pb年龄一致,误差分别为160.4±2.4Ma和158.4±1.3Ma,表明石英脉型W矿化与细粒斑状生物花岗岩之间存在密切的遗传联系。我们的研究强调了脉冲流体外溶解的重要性,以及流体与岩石相互作用、流体混合和物理化学条件变化等多种机制在形成大型W矿床过程中的综合作用。
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引用次数: 0
Pollution level and distribution characteristics of heavy metals and microplastics in the soils from the Qionghai Lake Wetland, Southwest China 中国西南邛海湖湿地土壤中重金属和微塑料的污染程度及分布特征
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-29 DOI: 10.1016/j.gr.2024.07.027
Jinjin Wang , Zailin Chen , Xuemei Wang , Yanqun Wang , Huibin Shi , Yi Huang

Urban wetlands are reported to be ideal habitats for accumulation of HMs and MPs. However, study on combined pollution of HMs and MPs in soil is rare in urban wetland environment. In this study, the characteristics of HMs and MPs in the soils of the Qionghai Lake wetland in southwest China were studied by using ICP–MS, and FTIR. The results showed that the average concentration of HMs in soil ranges from 0.84 to 552.75 (mg/kg). According to the EF and Igeo analysis results, Cd and Cr in the soil were significant enriched (EF=12.64) and moderately enriched (EF=2.09), and were at the moderate to heavy pollution level (Igeo = 2.83) and the unpolluted to moderate pollution level (Igeo = 0.23), and the other elements were at a low level. MPs are emerging micropollutants in the soil environment, and the abundance (pieces/g) of MPs in the soil was 3.90, 7.00, 3.10, 3.40, 14.80, and 1.10 at Stations M1, M2, M3, M4, M8, and M9, respectively, with an average of 5.55 ± 4.92. Films represented the main microplastic shape, accounting for 81.55 %, followed by fibers, accounting for 11.33 %. The proportion of MPs with a particle size of 0.1–0.5 mm is the highest. Black, blue, and green are the predominant colors found in MPs. Polyethylene (PE) and polypropylene (PP) were the main MP materials based on FTIR identification, accounting for 52.16 % and 42.31 % of the total MPs, respectively. The pollution load index (PLI) of MPs was 2.2, which is a level Ⅰ pollution. The research on HMs and MPs in urban wetland soil is still in its preliminary stage. Our aim is to offer a fresh perspective for evaluating the pollution status and risk associated with these two pollutants in urban wetland soil, while also providing a valuable reference for subsequent studies on wetland soil pollutants.

据报道,城市湿地是积累 HMs 和 MPs 的理想栖息地。然而,有关城市湿地环境中土壤中 HMs 和 MPs 复合污染的研究却很少见。本研究采用 ICP-MS 和傅立叶变换红外光谱法研究了中国西南地区琼海湖湿地土壤中 HMs 和 MPs 的特征。结果表明,土壤中 HMs 的平均浓度为 0.84 至 552.75(mg/kg)。根据 EF 和 Igeo 分析结果,土壤中的镉和铬呈显著富集(EF=12.64)和中度富集(EF=2.09),处于中度至重度污染水平(Igeo=2.83)和未受污染至中度污染水平(Igeo=0.23),其他元素处于较低水平。MPs是土壤环境中新出现的微污染物,M1、M2、M3、M4、M8和M9站土壤中MPs的丰度(件/克)分别为3.90、7.00、3.10、3.40、14.80和1.10,平均为5.55±4.92。微塑料的主要形状是薄膜,占 81.55%,其次是纤维,占 11.33%。粒径为 0.1-0.5 毫米的微塑料比例最高。多孔塑料的主要颜色为黑色、蓝色和绿色。根据傅立叶变换红外光谱鉴定,聚乙烯(PE)和聚丙烯(PP)是主要的 MP 材料,分别占 MP 总量的 52.16 % 和 42.31 %。MPs的污染负荷指数(PLI)为2.2,属于Ⅰ级污染。对城市湿地土壤中 HMs 和 MPs 的研究仍处于初步阶段。我们的目的是为评价城市湿地土壤中这两种污染物的污染状况和相关风险提供一个全新的视角,同时也为湿地土壤污染物的后续研究提供有价值的参考。
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引用次数: 0
Editorial Board (IFC) 编辑委员会(国际金融公司)
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-27 DOI: 10.1016/S1342-937X(24)00234-X
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引用次数: 0
A mid-Cretaceous carbon isotope reference curve for the SE Neo-Tethys region (Zagros, W Iran) 新特提斯东南部地区(伊朗西部,扎格罗斯)白垩纪中期碳同位素参考曲线
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-27 DOI: 10.1016/j.gr.2024.07.025
Amin Navidtalab , Ulrich Heimhofer , Elaheh Zarei

Stable carbon isotope chemostratigraphy and the associated reference curves have proved to be valuable tools for stratigraphic calibration and long-distance correlations. Nonetheless, the reference curves covering the Cretaceous have mostly been produced from localities located within the W Neo-Tethys. In order to establish a reference curve for the SE Neo-Tethys margin, an Aptian–Albian hemipelagic carbonate-rich succession deposited along the Zagros Basin (SW Iran) was examined for planktic foraminifera biostratigraphy, carbon isotope stratigraphy, and sedimentological characteristics. Eight biozones including Globigerinelloides ferreolensis, Globigerinelloides algerianus, Hedbergella trocoidea, Paraticinella bejaouaensis, Muricohedbergella planispira, Ticinella (T.) primula, Biticinella breggiensis, and Pseudothalmanninella (P.)ticinensis as well as two subzones enclosing T. praeticinensis and P. subticinensis assign the strata to the early late Aptian–late Albian age. A carbon isotope record constrained by the planktic foraminifera zonation scheme shows good concordance with existing composite reference curves from the W Neo-Tethys region. Several carbon isotope excursions (CIEs) characterizing global marine events including Oceanic Anoxic Event (OAE) 1a, OAE1b, OAE1c and associated sub-events can be identified in the studied section. Deoxygenated bottom waters associated with the formation of OAE1a and OAE1b are indicated by distinct lithological signatures including enrichment in pyrite and glauconite, nodular and stratiform chert beds, as well as enhanced organic matter contents. We integrate the here-studied interval with a previously published upper Albian−Turonian succession from the same outcrop section, forming a composite, stratigraphically well-constrained section. This results in a high-resolution carbon isotope record for the SE Neo-Tethys margin, considered to represent an expedient reference Aptian–Turonian curve for this region. Correlation of this new curve with previously published records from the Middle East has helped to address ambiguities regarding the stratigraphic positions of the early/late Aptian and Aptian/Albian boundaries identified by previous studies.

稳定碳同位素化合地层学和相关参考曲线已被证明是地层校准和远距离关联的重要工具。然而,涵盖白垩纪的参考曲线大多来自新特提斯西部的一些地方。为了建立新特提斯东南边缘的参考曲线,对沿扎格罗斯盆地(伊朗西南部)沉积的富含碳酸盐的安普顿-阿尔卑斯半沉积演替进行了浮游有孔虫生物地层学、碳同位素地层学和沉积学特征研究。八个生物区包括 Globigerinelloides ferreolensis、Globigerinelloides algerianus、Hedbergella trocoidea、Paraticinella bejaouaensis、Muricohedbergella planispira、Ticinella (T.)primula、Biticinella (T.)。T.praeticinensis和P.subticinensis所包围的两个亚带,将地层归入早安迭纪晚期-晚白垩纪。受浮游有孔虫分带方案制约的碳同位素记录与新特提斯西部地区现有的复合参考曲线显示出很好的一致性。在所研究的断面上,可以发现一些碳同位素偏移(CIEs),它们是全球海洋事件的特征,包括大洋缺氧事件(OAE)1a、OAE1b、OAE1c 和相关的子事件。与 OAE1a 和 OAE1b 的形成相关的脱氧底层水体表现为不同的岩性特征,包括黄铁矿和青铜矿的富集、结核状和层状白垩岩床以及有机质含量的增加。我们将所研究的区间与之前发表的来自同一露头剖面的上白垩统-都灵统演替进行了整合,形成了一个复合的、地层约束良好的剖面。这就形成了新特提斯东南边缘的高分辨率碳同位素记录,被认为代表了这一地区的权宜参考安息-土伦曲线。将这条新曲线与以前发表的中东地区的记录进行比对,有助于解决以前的研究中发现的早/晚安普世和安普世/阿尔卑斯边界地层位置不明确的问题。
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引用次数: 0
Discovery of mafic dikes in northeastern Tibet plateau belonging to the Emeishan large igneous province: Implications for paleocontinental reconstruction and mineral exploration 在西藏高原东北部发现属于峨眉山大型火成岩省的岩浆岩穴:对古大陆重建和矿产勘探的启示
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-24 DOI: 10.1016/j.gr.2024.07.026
Kang Yang , Wei-Guang Zhu , Chusi Li , Zhong-Jie Bai , Yan-Jun Wang , Shi-Ji Zheng , Peng-Cheng Hu

Due to the lack of paleomagnetic data and paleoclimatic records, the paleocontinental belonging of the Yidun terrane in northeastern Tibet plateau is debated. In this paper, we use the distribution of the Emeishan large igneous province (ELIP) to put the issue to rest. The ELIP is the product of mantle plume activity, which took place at 260 ± 3 Ma in the western margin of the Yangtze craton. The Yangtze craton is the northern part of the South China paleocontinental block. Our new discovery of four mafic dikes in the Yidun terrane with ages and chemistry like the ELIP strongly supports a new interpretation that this terrane was an integral part of the Yangtze craton during the ELIP magmatic event. Baddeleyites from these mafic dikes yield the U–Pb ages of 257.1 ± 4.8, 259.8 ± 8.5, 260.2 ± 4.5 and 261.5 ± 6.8 Ma for each of these dikes, which are similar to the zircon U-Pb ages of the mafic–ultramafic intrusions of the ELIP within the Yangtze craton. The Yidun mafic dikes and some high-Ti basalts of the ELIP within the Yangtze craton have similar Sr-Nd isotope compositions and mantle-normalized incompatible trace element distribution patterns, indicating similar mantle source compositions. Mixing calculation using Sr-Nd isotope compositions shows that the parental magmas for the Yidun mafic dikes experienced only 2–3 % crustal contamination. Partial melting modelling shows that the primary magmas for the Yidun mafic dikes were produced by 5–6 % mantle partial melting at the depths > 85 km below surface, consistent with mantle plume-related magmatism in a continental setting. The Yidun terrane is a new exploration frontier for magmatic Fe-Ti-V oxide deposits that are present elsewhere in the ELIP.

由于缺乏古地磁资料和古气候记录,西藏高原东北部的宜敦地层的古大陆归属问题一直存在争议。本文利用峨眉山大火成岩省(ELIP)的分布来澄清这一问题。峨眉山大火成岩省是地幔羽流活动的产物,发生于260±3Ma的长江克拉通西缘。长江克拉通是华南古大陆块的北部。我们在宜墩地层中新发现了四块岩浆岩,其年龄和化学成分与ELIP相似,这有力地支持了一种新的解释,即在ELIP岩浆活动期间,该地层是长江克拉通的一个组成部分。这些岩浆岩尖晶石的巴德利石的U-Pb年龄分别为257.1±4.8 Ma、259.8±8.5 Ma、260.2±4.5 Ma和261.5±6.8 Ma,与长江克拉通ELIP岩浆-超基性侵入体的锆石U-Pb年龄相似。宜都岩浆岩尖晶石和长江克拉通ELIP的一些高钛玄武岩具有相似的Sr-Nd同位素组成和地幔正化不相容微量元素分布模式,表明相似的地幔源组成。利用Sr-Nd同位素成分进行的混合计算表明,宜都岩浆岩母体仅受到2-3%的地壳污染。部分熔融模型显示,宜墩岩浆岩穴的原生岩浆是在地表以下85千米深处由5-6%的地幔部分熔融产生的,这与大陆环境中的地幔羽状岩浆活动相一致。伊墩地层是勘探 ELIP 其他地区岩浆铁-钛-钒氧化物矿床的新前沿。
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引用次数: 0
Pollution index and distribution characteristics of soil heavy metals among four distinct land use patterns of Taojia River Basin in China 中国陶家河流域四种不同土地利用模式的土壤重金属污染指数及分布特征
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-24 DOI: 10.1016/j.gr.2024.07.024
Wei Liu , Chenglin Yuan , Taimoor Hassan Farooq , Peirou Chen , Miao Yang , Ziyi Ouyang , Yao Fu , Yitao Yuan , Guangjun Wang , Wende Yan , Jun Wang

The accumulation of heavy metals (HMs) in soil has become a pressing global concern due to their persistent and non-degradable nature, resulting in the accumulation of toxic levels in the environment. In recent years, human activities have significantly altered land use patterns, leading to a marked increase in soil HM levels and subsequent land degradation. This research focused on four distinct land use patterns (vegetable fields (VGF), woodland (WDL), cultivated land (CVL), and wasteland (WSL)) commonly found in the Taojia River Basin, Hunan, China, which is facing severe HM pollution. Soil samples were collected from three different depths (0–10 cm, 10–20 cm, and 20–30 cm) to investigate HM distribution and intensity (cadmium (Cd), lead (Pb), copper (Cu), nickel (Ni), and zinc (Zn)), comprehensive soil pollution index, and their relationship with soil microbial and enzymatic activities. The results revealed that the Cd content exceeded the national standard for soil environmental quality, whereas concentrations of other HMs did not exceed the national standard across the four land use patterns. Most soil HMs were concentrated in the surface layer, with Cu, Pb, and Zn concentrations gradually decreasing with increasing soil depth. Conversely, Ni and Cd concentrations tended to increase with greater soil depth. There were significant positive correlations among HMs, indicating homogeneity among them. The pollution index across the HMs ranked as Cd > Ni > Zn > Cu and Pb, with land uses following the order of VGF (2.70) > CVL (2.12) > WSL (1.72) > WDL (1.63). Soil microbial and enzymatic activity was not the primary factor influencing HM concentration. The specific impacts of land use changes on soil HMs depend on management practices, local conditions, and the distribution characteristics of the HMs involved.

土壤中重金属(HMs)的积累已成为全球亟待解决的问题,因为它们具有持久性和不可降解性,会导致环境中有毒水平的积累。近年来,人类活动极大地改变了土地利用模式,导致土壤中的重金属含量显著增加,进而造成土地退化。本研究重点关注了中国湖南陶家河流域常见的四种不同的土地利用模式(菜地(VGF)、林地(WDL)、耕地(CVL)和荒地(WSL)),该流域正面临着严重的 HM 污染。本文采集了三个不同深度(0-10 cm、10-20 cm、20-30 cm)的土壤样品,研究了土壤中有害有机物(镉、铅、铜、镍、锌)的分布和强度、土壤污染综合指数及其与土壤微生物和酶活性的关系。结果表明,在四种土地利用模式中,镉含量超过了土壤环境质量国家标准,而其他有害有机物的浓度均未超过国家标准。大多数土壤 HMs 都集中在表层,铜、铅和锌的浓度随着土壤深度的增加而逐渐降低。相反,镍和镉的浓度则随着土壤深度的增加而增加。HMs 之间存在明显的正相关性,表明它们之间存在同质性。各 HMs 的污染指数依次为 Cd > Ni > Zn > Cu 和 Pb,土地用途依次为 VGF (2.70) > CVL (2.12) > WSL (1.72) > WDL (1.63)。土壤微生物和酶活性不是影响 HM 浓度的主要因素。土地利用变化对土壤 HMs 的具体影响取决于管理方法、当地条件以及相关 HMs 的分布特征。
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引用次数: 0
First multi-proxy chronostratigraphy of the lower Cambrian Byrd Group, Transantarctic Mountains and correlation within East Gondwana 跨南极山脉下寒武纪伯德群首次多代理年代地层学研究及东冈瓦纳内部的相关性
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-23 DOI: 10.1016/j.gr.2024.07.022
Marissa J. Betts , Thomas M. Claybourn , Lars E. Holmer , Christian B. Skovsted , Paul M. Myrow , Lars Stemmerik , Timothy P. Topper , Tae-Yoon S. Park , Nigel C. Hughes , James L. Crowley , Elizabeth A. Jagodzinski , Glenn A. Brock

Antarctica and Australia were sutured together at the equator during the major pulse of animal biodiversification associated with the Cambrian radiation. However, the lack of detailed systematic chemostratigraphic and biostratigraphic sampling of lower Cambrian sedimentary successions from Antarctica has significantly impeded precise age determination and correlation with Cambrian strata on other palaeocontinents. This study is the first to present integrated, simultaneously sampled biostratigraphic and chemostratigraphic (δ13C isotopes) data from the same measured stratigraphic sections through the lower Cambrian Byrd Group in the Transantarctic Mountains. Shelly fossil assemblages (brachiopods, tommotiids, molluscs, bradoriids, trilobites) from the Holyoake Range and Churchill Mountains facilitate direct correlation with the Dailyatia odyssei Zone of South Australia (Cambrian Stages 3–4), and trilobites provide strong correlation between the Starshot Formation and the Cymbric Vale Formation in western New South Wales. A new ID-TIMS radiometric date of 514.96 ± 0.16 Ma from a tuff in the lower Cymbric Vale Formation is similar to dates from tuff beds in the Third Plain Creek Member of the Mernmerna Formation in the Flinders Ranges, providing an important absolute-age tie point between these lower Cambrian successions. Chemostratigraphic data from the upper Shackleton Limestone in the Holyoake Range capture a negative δ13C excursion that can be correlated to negative values within the multi-peaked MICE (cycles V–VIII in Siberia). Integrated faunal and chemostratigraphic data indicate a Cambrian Stages 3–4 age, giving robust chronostratigraphic context for the upper Shackleton Limestone–Holyoake Formation–Starshot Formation succession for the first time, permitting reconstruction of the depositional history of the lower Cambrian of Antarctica and global correlation of Byrd Group strata.

在与寒武纪辐射相关的动物生物多样化大潮中,南极洲和澳大利亚在赤道缝合在一起。然而,由于缺乏对南极洲下寒武统沉积统进行详细系统的化学地层学和生物地层学取样,这极大地阻碍了精确年龄的确定以及与其他古大陆寒武纪地层的关联。本研究首次从横贯南极山脉的下寒武统伯德组的同一测量地层剖面中同时采集生物地层学和化学地层学(δ13C 同位素)的综合数据。来自霍利约克山脉和丘吉尔山脉的雪莱化石群(腕足动物、瘤齿类、软体动物、腕足动物、三叶虫)有助于与南澳大利亚的Dailyatia odyssei区(寒武纪第3-4期)直接相关,而三叶虫则为新南威尔士州西部的Starshot地层和Cymbric Vale地层提供了强有力的相关性。来自 Cymbric Vale Formation 下层凝灰岩的新 ID-TIMS 放射性测定日期为 514.96 ± 0.16 Ma,与来自弗林德斯山脉 Mernmerna Formation 第三平原溪岩层凝灰岩床的日期相似,为这些下寒武纪演替之间提供了一个重要的绝对年代联系点。来自霍利约克山脉上部沙克尔顿石灰岩的化学地层学数据捕捉到了负的δ13C偏移,该偏移可与多峰MICE(西伯利亚的周期V-VIII)中的负值相关联。动物和化学地层学综合数据显示了寒武纪第 3-4 阶段的年龄,首次为上沙克尔顿石灰岩-霍利约克地层-斯塔肖特地层演替提供了可靠的年代地层学背景,从而可以重建南极洲下寒武纪的沉积历史以及伯德群地层的全球相关性。
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引用次数: 0
Interaction of accretion mechanisms and deep fluids in continental orogenesis 大陆造山运动中增生机制与深层流体的相互作用
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-23 DOI: 10.1016/j.gr.2024.08.009
G. Giacomuzzi, C. Chiarabba

Mountain-building often involves the subduction of continental margins during the convergence of tectonic plates. Rheological heterogeneities and structural inheritance in the subducting lithosphere are main factors controlling the evolution of the process and deformation partitioning in orogenic wedges. Here, we present tomographic evidence of a main along-strike change in the structure of the Apennines belt, where frontal accretion diminishes laterally, as well as plate bending, and the contribution of underplating to crustal thickening becomes evident. We hypothesize that the diverse mechanisms of mountain formation can be attributed to rheological heterogeneity in the crust and interactions with fluids liberated during the subduction process. The development of shallow decollements versus underplating is favored by differing amounts and styles of deep fluid liberation from the subducting crust.

造山运动通常涉及构造板块汇聚过程中大陆边缘的俯冲。俯冲岩石圈的流变异质性和结构继承性是控制造山楔过程演变和变形分区的主要因素。在这里,我们提出了亚平宁半岛带结构沿走向主要变化的断层扫描证据,在这一变化中,锋面增生和板块弯曲都在横向减弱,底侵对地壳增厚的贡献变得明显。我们假设,山脉形成的不同机制可归因于地壳的流变异质性以及与俯冲过程中释放的流体之间的相互作用。从俯冲地壳中释放的深层流体的数量和方式不同,有利于浅层解块和底板的形成。
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引用次数: 0
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Gondwana Research
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