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Ridge subduction and island arc evolution in the Duobaoshan region during early Paleozoic: Insights from crustal thickness and lava geochemistry 多宝山地区早古生代脊俯冲和岛弧演化:来自地壳厚度和熔岩地球化学的启示
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-07 DOI: 10.1016/j.gr.2025.12.007
Tianjiao Sang , Fuping Pei , Bingqian Ding , Kai Song , Pengyi Li , Guanwen Yu
The Duobaoshan island arc contains early Paleozoic association of adakitic high-Mg andesite, Nb-enriched basalt, and porphyry Cu deposits, concurrently indicating the ridge subduction in the eastern Xing’an Massif. This study further understands the unique island arc setting through the mantle metasomatism, oxygen fugacity and crustal thickness based on the zircon U–Pb geochronologic and Hf isotopic data from the early Paleozoic igneous and sedimentary rocks, as well as the whole–rock geochemical and Sr–Nd–Hf isotopic data from the igneous rocks in the Duobaoshan region, Xing’an Massif. The early Paleozoic igneous rocks are typical arc–type with low (La/Yb)N ratios (3.37–6.60), exhibiting highly depleted zircon Hf (εHf(t) = +12.44∼+16.50) and whole–rock Sr–Nd–Hf isotopic data ((87Sr/86Sr)i = 0.7036–0.7048; εNd(t) = +4.76∼+8.17; εHf(t) = +12.44∼+16.50), which were derived from the depleted mantle metasomatized mainly by slab fluid accompanied with the altered oceanic crust melt and pelagic sediment melt, and reflected the maturing process of the island arc. In addition, the Early Ordovician igneous rocks indicated the increase of mantle temperature and oxygen fugacity (ΔFMQ > 2) leading to the solubility of metallogenetic elements, and the thickening crust was also conducive to the mineralization. Then we further revealed the existence of a Precambrian basement of the Xing’an Massif based on the sedimentary rocks, the geochronology of which revealed the youngest ages of 504–478 Ma, yielding the age peaks at 771 Ma, ∼860 Ma, ∼950 Ma, and ∼1800 Ma ∼2500 Ma. In the meanwhile, the Hf isotopic data of 600–478 Ma detrital zircons show depleted to more enriched εHf(t) values (–10.22 to +12.70) and a proximal depositional traits, indicating that majority of the Neoproterozoic and early Paleozoic detrital zircons migrated from the Duobaoshan region, Xing’an Massif.
多宝山岛弧发育早古生代艾达质高镁安山岩、富铌玄武岩和斑岩型铜矿组合,同时显示了兴安地块东部的脊状俯冲。本研究基于兴安地块多宝山地区早古生代火成岩和沉积岩的锆石U-Pb年代学和Hf同位素数据,以及火成岩的全岩地球化学和Sr-Nd-Hf同位素数据,通过地幔交代作用、氧逸度和地壳厚度进一步了解独特的岛弧背景。早古生代火成岩为典型的弧型,低(La/Yb)N比值(3.37 ~ 6.60),锆石Hf高度贫化(εHf(t) = +12.44 ~ +16.50),全岩Sr-Nd-Hf同位素数据((87Sr/86Sr) = 0.7036 ~ 0.7043;εNd (t) = + 5.71∼+ 8.17;εHf(t) = +12.44 ~ +16.50),主要来源于以板块流体为主的衰竭地幔交代作用,并伴有蚀变的洋壳熔体和上层沉积物熔体,反映了岛弧的成熟过程。此外,早奥陶世火成岩表明地幔温度和氧逸度升高(ΔFMQ > 2),导致成矿元素溶解度增大,地壳增厚也有利于成矿作用。根据沉积岩进一步揭示了兴安地块前寒武纪基底的存在,其最年轻年龄为504 ~ 478 Ma,年龄峰值为771 Ma、864 Ma、942 Ma、~ 1800 Ma和~ 2500 Ma。同时,600 ~ 478 Ma碎屑锆石Hf同位素数据显示εHf(t)值(-10.22 ~ +12.70)为贫至富,具有近端沉积特征,表明新元古代和早古生代碎屑锆石主要来自兴安地块多宝山地区。
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引用次数: 0
Episodic early Paleozoic arc magmatism of the Proto-Tethys Ocean: Evidence from geochronology, geochemistry and Sr-Nd-Hf isotopes of plutonic rocks in the southern East Kunlun Orogen 原特提斯洋早古生代幕式弧岩浆活动:来自东昆仑造山带南部深成岩年代学、地球化学和Sr-Nd-Hf同位素的证据
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-26 DOI: 10.1016/j.gr.2025.12.022
Xiang Ren , Yunpeng Dong , Inna Safonova , Shengsi Sun , Dengfeng He , Xiaoyan Zhao , Yuangang Yue , Bo Hui , Qiuming Pei , Baoping Gan
The southern East Kunlun Orogen (EKO) experienced protracted orogeny linked to the Proto-Tethys and Paleo-Tethys oceans. However, the evolution of the Proto-Tethys Ocean remains much less understood leaving the question of the timing of subduction initiation and magmatism. Here, we studied three early Paleozoic plutons exposed in the southern EKO: Kekesha (KKS) and Xialawen (XLW) gabbro-dioritic plutons and Longwakalu (LWKL) granitic pluton for geochronology, geochemistry and Sr-Nd-Hf isotopes. A KKS quartz diorite, XLW hornblende gabbro, and LWKL granite crystallized at 494, 470 and 477 Ma, respectively. The KKS gabbro-granodiorite series and XLW hornblende gabbros are enriched in light rare earth elements and large ion lithophile elements, but depleted in high strength field elements. The LWKL granites possess adakitic features: high Na2O content, Sr/Y and La/YbN ratios and differentiated heavy REEs. Isotopically, XLW hornblende gabbros and LWKL granites are less enriched isotopes (εNd(t) = −4.3 to −3.9; εHf(t) = −4.6 to +2.0) than KKS gabbro and granodiorite (εNd(t) = −7.0; εHf(t) = −7.2 to −4.8). Sr-Nd isotopic modeling suggests that KKS and XLW plutons were derived through partial melting of mantle wedge modified by different amounts of subducted terrigenous-dominated sediment derived melts. The LWKL adakitic granites were formed by high-pressure reworking of underplated arc-type intermediate rocks. The emplacement of early Paleozoic gabbro-granodiorite series and adakitic granites was related to subduction of the Proto-Tethys Ocean which started no later than ca. 500 Ma. Our new data along with available ages suggest that the supra-subduction magmatism of the Proto-Tethys Ocean in the southern EKO is episodic with peaks at ca. 495, 470, and 430 Ma. The first two episodes of magmatism mainly represent melting of enriched mantle wedge, and the third is the main pulse of magmatism formed by simultaneous melting of multiple sources of crustal rocks, subducted oceanic slab and mantle wedge.
东昆仑造山带南部经历了与原特提斯洋和古特提斯洋有关的长期造山运动。然而,对原特提斯洋的演化仍然知之甚少,留下了俯冲开始和岩浆活动的时间问题。在此基础上,对鄂东南部3个早古生代的克克沙(KKS)和下阿拉文(XLW)辉长闪长岩和龙瓦卡鲁(LWKL)花岗岩体进行了年代学、地球化学和Sr-Nd-Hf同位素研究。KKS石英闪长岩、XLW角闪辉长岩和LWKL花岗岩分别在494、470和477 Ma结晶。KKS辉长-花岗闪长岩系列和XLW角闪长辉长岩富集轻稀土元素和大离子亲石元素,缺乏强场元素。LWKL花岗岩具有高Na2O含量、高Sr/Y、高La/YbN比值和分异重稀土元素特征。同位素上,XLW角闪辉长岩和LWKL花岗岩富集程度较低(εNd(t) = −4.3 ~−3.9;εHf(t) = −4.6 ~ +2.0)优于KKS辉长岩和花岗闪长岩(εNd(t) = −7.0;εHf(t) = −7.2 ~−4.8)。Sr-Nd同位素模拟表明,KKS和XLW岩体是由不同数量的陆源主导的俯冲沉积物衍生熔体修饰的地幔楔的部分熔融形成的。LWKL埃达克花岗岩是由下镀弧型中间岩高压改造而成。早古生代辉长-花岗闪长岩系列和埃达质花岗岩的侵位与不迟于约500 Ma的原特提斯洋俯冲有关。我们的新数据和现有的年龄表明,EKO南部原特提斯洋的超俯冲岩浆活动是幕式的,峰值大约在495,470和430 Ma。前两期岩浆活动主要代表富集地幔楔的熔融作用,第三期岩浆活动是多源地壳岩、俯冲洋板和地幔楔同时熔融作用形成的岩浆活动主脉冲。
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引用次数: 0
Oil mobility evaluation and light hydrocarbon restoration in shale reservoirs: a review 页岩储层油流性评价与轻烃恢复研究进展
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-18 DOI: 10.1016/j.gr.2025.12.010
Yue Feng , Xianming Xiao , Enze Wang , Chengang Lu , Changrong Li , Gang Li , Yineng Tan
Organic matter-rich shale, a widely developed fine-grained sedimentary rock, hosts critical unconventional petroleum resources. Accurately assessing the resource potential and economic value of shale oil reservoirs is crucial for energy strategy decision-making, yet two challenges persist: evaluating oil mobility, and addressing light hydrocarbon evaporation. This study provides a review of these two critical dimensions. Laboratory testing forms the foundation of oil mobility assessment. In practice, method selection should be guided by the specific geological settings, data availability, and economic considerations. Notably, artificial intelligence offers the potential to generate accurate predictions even from limited datasets. This study establishes a generalizable framework validated through a case study on oil mobility evaluation under small-sample dataset scenarios. The second part divides the light hydrocarbon loss process from coring to experimental data acquisition into four distinct stages. The loss is continuously influenced by time-related degradation, with each stage characterized by different controlling factors. Nonetheless, the oil properties of shale and its own attributes remain consistent overarching influences. Minimizing additional losses through comprehensive and practical strategies represents the most effective solution. Future advances in experimental technologies, refined frameworks, and the deep mining and integration of data will enhance assessment accuracy. The findings of this study are expected to provide a solid theoretical foundation for the precise evaluation of resources in shale systems and the efficient delineation of prospective exploration targets.
富含有机质的页岩是一种广泛发育的细粒沉积岩,蕴藏着重要的非常规石油资源。准确评估页岩油储层的资源潜力和经济价值对于能源战略决策至关重要,但仍然存在两个挑战:评估原油流动性和解决轻烃蒸发问题。本研究提供了对这两个关键维度的回顾。实验室测试是油品流动性评价的基础。在实践中,方法的选择应以具体的地质环境、数据的可用性和经济考虑为指导。值得注意的是,人工智能提供了即使从有限的数据集生成准确预测的潜力。本研究建立了一个可推广的框架,并通过小样本数据集情景下的原油流动性评价案例进行了验证。第二部分将从取心到实验数据采集的轻烃损失过程划分为四个不同的阶段。损失持续受到时间相关退化的影响,每个阶段都有不同的控制因素。尽管如此,页岩油的性质及其本身的属性仍然是最重要的影响因素。通过全面和实用的策略来减少额外损失是最有效的解决办法。未来在实验技术、精细化框架以及数据深度挖掘和整合方面的进步将提高评估的准确性。研究结果将为页岩系统资源的精准评价和远景勘探目标的有效圈定提供坚实的理论基础。
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引用次数: 0
Navigating climate challenges: harnessing energy, eco-innovation, and climate policy in achieving sustainable development goals 应对气候挑战:利用能源、生态创新和气候政策实现可持续发展目标
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2025-12-31 DOI: 10.1016/j.gr.2025.12.004
Huangxin Chen , Li Zhang , Stefania Pinzon , Meijin Chen , Bin Chen
Carbon emissions cause climate change, a danger to society and the environment. Despite efforts, the US remains one of the largest carbon dioxide emitters, which may lead to rising seas, increased natural disasters, and ecological catastrophes. Therefore, we need policies that are immediately effective in preventing carbon emissions. In this perspective, this study scrutinizes the role of Energy Transition (ET), Eco-Innovation (EINO), Globalization (GN), Sustainable Consumption (SC), and Climate Policy Uncertainty (CPU) on CO2 emissions and Load Capacity Factor (LCF) from 1980 to 2019. Utilizing cutting-edge econometric techniques includes dynamic Autoregressive Distributed Lag (ARDL) simulations and Cumulative Fourier Frequency Domain Causality (CFFDC). The results indicate that EINO reduces emissions, while ET and CPU provide short-term reductions. Conversely, GN and SC shortly upsurge emissions, though SC behaves differently under CFFDC analysis. The study also divulges bidirectional causality among most variables, with GN and SC significantly impacting LCF in specific models. These findings underscore the importance of implementing targeted policies, such as carbon taxes, incentives for renewable energy adoption, and stringent emissions regulations, to achieve Sustainable Development Goals (SDGs) 7 and 13. In conclusion, such policy measures are critical for the United States to contribute effectively to global efforts to combat climate change.
碳排放导致气候变化,对社会和环境构成威胁。尽管做出了努力,但美国仍然是最大的二氧化碳排放国之一,这可能导致海平面上升,自然灾害和生态灾难增加。因此,我们需要立即有效防止碳排放的政策。在这一视角下,本研究考察了1980 - 2019年能源转型(ET)、生态创新(EINO)、全球化(GN)、可持续消费(SC)和气候政策不确定性(CPU)对二氧化碳排放和负荷能力因子(LCF)的影响。利用尖端的计量经济学技术,包括动态自回归分布滞后(ARDL)模拟和累积傅立叶频域因果关系(CFFDC)。结果表明,EINO减少排放,而ET和CPU提供短期减排。相反,GN和SC很快就会增加排放,尽管SC在CFFDC分析下表现不同。该研究还揭示了大多数变量之间的双向因果关系,在特定模型中,GN和SC显著影响LCF。这些发现强调了实施有针对性的政策(如碳税、可再生能源采用激励措施和严格的排放法规)对实现可持续发展目标7和13的重要性。总而言之,这些政策措施对于美国有效地为应对气候变化的全球努力作出贡献至关重要。
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引用次数: 0
Water circulation, redox, and productivity dynamics shaped late Ediacaran ecosystems: Insights from trace elements and combined Sr–Cr–Cd isotopes in the Corumbá Group, Brazil 水循环、氧化还原和生产力动态塑造了埃迪卡拉晚期生态系统:来自巴西corumb<e:1>群微量元素和Sr-Cr-Cd组合同位素的见解
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-04 DOI: 10.1016/j.gr.2026.01.006
Henrique Albuquerque Fernandes , Paulo César Boggiani , Jesper Allan Frederiksen , Thales Pescarini , Vinicius Cardoso Lucas , Gustavo Paula Santos , Eric Elias , Marly Babinski , Juliana Leme , Catherine V. Rose , Ricardo Ivan Ferreira Trindade , Robert Frei
The relationship between marine oxygenation and early animal evolution remains a highly debated topic. Recent research suggests that, rather than absolute atmospheric O2 threshold levels, the main factor controlling early animal distribution was long-term local marine redox conditions. To explore this hypothesis, we present trace element data along with Sr, Cr, and Cd isotopes in carbonate rocks from the late Ediacaran Corumbá Group, Brazil, obtained from drill cores of the GRIND-ECT project. This multiproxy approach is designed to constrain basin water circulation, redox conditions, and bioproductivity levels from ca. 565 to 540 Ma, ultimately aiming to reconstruct the paleoceanographic scenario in which early animal colonization occurred in the Corumbá Basin. Redox-sensitive metal abundances indicate a contrasting redox scenario, with predominant anoxia in the Bocaina Formation and expanded oxia in the overlying Tamengo Formation. This interpretation is further reinforced by Cr isotopes, whereby δ53Cr passes from low values in the range of Bulk Silicate Earth to positively fractionated values upsection. Two negative δ53Cr excursions in the Tamengo Formation are interpreted as anoxic intervals. 87Sr/86Sr values decrease from 0.7100 in the Bocaina Formation to late Ediacaran values around 0.7085 in the Tamengo Formation. These radiogenic values in the Bocaina Formation are attributed to post-depositional diagenesis of Sr-depleted dolostones. Lastly, variable δ114Cd in the Bocaina Formation indicate contrasting productivity levels during highstand and flooding periods. The two anoxic intervals in the Tamengo Formation exhibit anomalous negative δ114Cd values, which may be linked to widespread eutrophication. Our study, combined with compilations of redox and fossil data, reveals that the Corumbá Basin evolved from a predominantly anoxic setting dominated by microfossils in the Bocaina Formation, to a connected marine setting in the Tamengo Formation. This later phase featured a deeper redoxcline and was dominated by fossils of biomineralizing animals, representing a near-optimal environment for early animal benthic colonization.
海洋氧合与早期动物进化之间的关系仍然是一个备受争议的话题。最近的研究表明,控制早期动物分布的主要因素不是绝对的大气O2阈值水平,而是长期的当地海洋氧化还原条件。为了探索这一假设,我们提供了巴西埃迪卡拉纪晚期corumb群碳酸盐岩中Sr、Cr和Cd同位素的微量元素数据,这些数据来自GRIND-ECT项目的岩心。这种多代理方法旨在限制大约565至540 Ma的盆地水循环、氧化还原条件和生物生产力水平,最终旨在重建早期动物殖民发生在corumb盆地的古海洋学情景。氧化还原敏感金属丰度表明了一个截然不同的氧化还原情景,在Bocaina组中主要是缺氧,而在其上的Tamengo组中则是缺氧扩展。Cr同位素进一步加强了这一解释,即δ53Cr从块状硅酸盐土范围内的低值过渡到上部的正分馏值。Tamengo组两次δ53Cr负偏移被解释为缺氧层段。87Sr/86Sr值从Bocaina组的0.7100下降到Tamengo组的0.7085左右。波坎纳组的这些放射性成因价值归因于贫锶白云岩的沉积后成岩作用。最后,Bocaina组δ114Cd的变化表明了高水位和淹水时期的生产力水平差异。Tamengo组两个缺氧层段δ114Cd值异常,可能与富营养化有关。我们的研究结合氧化还原和化石资料的汇编,揭示了corumb盆地从以微化石为主的Bocaina组缺氧环境演变到Tamengo组连接的海相环境。这一后期阶段具有较深的氧化还原层,主要是生物矿化动物的化石,代表了早期底栖动物定居的近乎最佳环境。
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引用次数: 0
Seasonal variation and distribution of microplastics in surface water and sediments of Coimbatore Lakes, India 印度哥印拜陀湖表层水和沉积物中微塑料的季节变化和分布
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-23 DOI: 10.1016/j.gr.2025.12.013
Davis Kaimalayil Ephsy, Selvaraju Raja
This study quantified the abundance, distribution, and characteristics of microplastics in surface water and sediments from five lakes in the Coimbatore District: Kumaraswamy Lake, Ukkadam Lake, Kuruchi Lake, Singanallur Lake, and Sulur Lake. The highest microplastic abundance was found in the surface water of Kuruchi Lake (14.08 ± 0.63 particles/L) at site S5 during the monsoon, and in the surface sediments of Kumaraswamy Lake (13.33 ± 0.33 particles/g) at site S6 during summer. Spatial distribution patterns indicated that lakes receiving urban runoff, domestic wastewater inflow, and inputs from fishing and recreational activities exhibited higher microplastic concentrations. Seasonal variations showed elevated microplastic abundance in summer sediments and monsoon surface water samples. Microplastics were identified using Attenuated total reflectance- Fourier Transform Infrared Spectroscopy (ATR-FTIR) and Differential Scanning Calorimetry (DSC)), revealing Linear low-density polyethylene (LLDPE), High-density polyethylene (HDPE), Polyethylene terephthalate (PET), and Polypropylene (PP). These microplastic occurred in white, transparent, black, blue, yellow, and pink colors and appeared as films, fragments, thin pieces, and fibres. Characteristic DSC melting peaks were observed 200 °C for PET, 167.98 °C for PP, 126.70 °C for LLDPE, and 130.02 °C for HDPE. The lake’s pollution load index is categorized as risk level 1, indicating a low level of microplastic pollution. The presence and distribution of these microplastics suggest potential ecological risks to freshwater organisms and possible implications for human health.
本研究量化了哥印拜陀地区Kumaraswamy湖、Ukkadam湖、Kuruchi湖、Singanallur湖和Sulur湖五个湖泊地表水和沉积物中微塑料的丰度、分布和特征。季风期库鲁奇湖表层水(14.08±0.63颗粒/L)和夏季库马拉斯瓦米湖表层沉积物(13.33±0.33颗粒/g)的微塑料丰度最高。空间分布格局表明,城市径流、生活污水流入以及渔业和娱乐活动输入的湖泊呈现出较高的微塑料浓度。夏季沉积物和季风地表水样品的微塑料丰度随季节变化而升高。利用衰减全反射-傅里叶变换红外光谱(ATR-FTIR)和差示扫描量热法(DSC)对微塑料进行了鉴定,发现了线性低密度聚乙烯(LLDPE)、高密度聚乙烯(HDPE)、聚对苯二甲酸乙二醇酯(PET)和聚丙烯(PP)。这些微塑料有白色、透明、黑色、蓝色、黄色和粉红色,以薄膜、碎片、薄片和纤维的形式出现。PET的DSC熔化峰为200°C, PP为167.98°C, LLDPE为126.70°C, HDPE为130.02°C。该湖的污染负荷指数为风险1级,表明微塑料污染水平较低。这些微塑料的存在和分布表明对淡水生物存在潜在的生态风险,并可能对人类健康产生影响。
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引用次数: 0
Optimal spatial scale selection for maximizing regional ecological management benefits 区域生态治理效益最大化的空间尺度优化选择
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-27 DOI: 10.1016/j.gr.2025.12.018
Jing Shi , Dawei Zhang , Hui Xu , Aokang Xu
The trade-off/synergy relationship among landscape elements exhibit pronounced spatial scale dependence and it profoundly affects the scientific rationality and practical effectiveness of regional ecological management decisions by altering the mechanisms of interactions among ecosystem services. While existing studies have made progress in characterizing multi-scale differences, there is still a lack of research on determining the optimal scale of management to maximize ecological benefits. Therefore, this study constructed a framework for analyzing scale effect resolution and optimal scale identification by integrating wavelet analysis, spatial autocorrelation and semi-variational functions. At the same time, by combining the XGBoost-SHAP model to interpret environmental factors exhibiting trade-off/synergy spatial heterogeneity, we proposed an optimal management scale optimization strategy based on comprehensive error minimization and took the interactive relationships among production, liveling, and ecological land use function (LUF) within the Heihe River Basin as the empirical subject. The research findings are as follows: 1) Spatial scale expansion strengthens the overall synergy between LUFs (by 0.07–0.24) but weakens the trade-off intensity within some grid cells; 2) The optimal ecological management scale in the study area was determined through semi-variogram optimal fitting to be 7 km, at which distance the trade-off/synergy fitting degree among all LUFs was optimal (with the highest r2 reaching 0.959); 3) Both natural and socio-economic factors influence the trade-off/synergy among land-use functions, and the trade-off areas are mainly located in the densely populated central oasis areas (accounting for up to 13.93% of the watershed). This study proposed an integrated spatial governance system comprising core conservation, transitional regulation, and collaborative development. Building upon this, we contended that mitigating land use function trade-off primarily requires differentiated management strategies, including optimizing land use structures (avoiding excessive expansion of construction land), controlling population density, and preventing excessive concentration of economic scale (GDP). This study provides methodological support for resolving the multi-scale ecological management decision and sustainable development dilemma.
景观要素间的权衡/协同关系表现出明显的空间尺度依赖性,并通过改变生态系统服务之间相互作用的机制,深刻影响区域生态管理决策的科学合理性和实践有效性。虽然已有研究在多尺度差异表征方面取得了一定进展,但在确定生态效益最大化的最优管理尺度方面仍缺乏研究。因此,本研究将小波分析、空间自相关和半变分函数相结合,构建了尺度效应解析和最优尺度识别的分析框架。同时,结合XGBoost-SHAP模型对表现出权衡/协同空间异质性的环境因子进行解释,提出了基于综合误差最小化的最优管理规模优化策略,并以黑河流域生产、生活与生态土地利用功能(LUF)的交互关系为实证对象。研究结果表明:1)空间尺度扩展增强了区域间整体协同效应(增强幅度为0.07 ~ 0.24),但减弱了部分网格单元内部的权衡强度;2)通过半变异函数优化拟合确定研究区最优生态治理尺度为7 km,在该距离上各生态治理尺度的权衡/协同拟合程度最优(r2最高可达0.959);③自然因素和社会经济因素都影响着土地利用功能之间的权衡/协同,权衡区主要分布在人口密集的中部绿洲区(占流域面积的13.93%)。研究提出了一个由核心保护、过渡调控和协同发展组成的综合空间治理体系。在此基础上,我们认为缓解土地利用功能权衡主要需要采取差别化管理策略,包括优化土地利用结构(避免建设用地过度扩张)、控制人口密度和防止经济规模(GDP)过度集中。本研究为解决多尺度生态管理决策和可持续发展困境提供了方法论支持。
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引用次数: 0
Microplastics and PAH contamination in the Eastern Arabian Sea: A synergistic environmental hazard 东阿拉伯海的微塑料和多环芳烃污染:一种协同环境危害
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-23 DOI: 10.1016/j.gr.2025.12.019
Priyansha Gupta , Mahua Saha , Chayanika Rathore , V. Suneel , Jacob de Boer , Anita Garg
How significant is the role of microplastics (MPs) in transporting toxic chemicals such as polycyclic aromatic hydrocarbons (PAHs) in marine ecosystems, particularly along India’s vulnerable coastlines? Despite growing recognition of MPs as persistent pollutants and effective sorbents for hydrophobic compounds, limited evidence exists on their contaminant-loading potential in the Eastern Arabian Sea (EAS), a region subjected to intense anthropogenic stressors. This study quantifies PAHs associated with both pellets and fragments from 14 beaches in Maharashtra, Goa, and Karnataka along the EAS using column chromatography followed by Gas-chromatography mass spectroscopy techniques. The concentrations of ∑16PAHs in pellets were 1.9–29,500 ng/g (Goa), 0.6–22,900 ng/g (Mumbai), and 0.8–21,400 ng/g (Karnataka). For the fragments the ∑16PAHs ranged from 2 to 2,100 ng/g (Karnataka), followed by 1–1,500 ng/g (Goa) to 12–230 (Mumbai). 4–6 ring-PAHs dominated and the diagnostic ratios indicated combination of processes such as pyrolytic, petroleum spills, and combustion activities. The study also investigated which type of MPs, pellets or fragments, exhibited higher PAH concentrations, and explored the factors responsible. Pellets consistently exhibited higher PAH loads, likely due to their smaller size, greater surface area, and prolonged environmental exposure. The ecological risk associated with PAH-contaminated MPs showed that ∑PAH was higher than TEL (Threshold effect level) and ERL (Effects range low), indicating a probable occasional biological impact. On the other hand, lower ∑PAH level than PEL (Probable effect level) and ERM (Effects ranged median) suggest no significant adverse effects on marine or human ecosystems at the evaluated locations. By highlighting the ecological risks of PAH-contaminated MPs and their role as pollutant vectors, this study raises urgent questions: how far can these invisible threats disperse, and what are their long-term implications for coastal ecosystems and public health?
微塑料(MPs)在海洋生态系统中运输有毒化学物质,如多环芳烃(PAHs),特别是在印度脆弱的海岸线上,所起的作用有多重要?尽管越来越多的人认识到MPs是持久性污染物和疏水性化合物的有效吸附剂,但关于它们在东阿拉伯海(EAS)的污染物负荷潜力的证据有限,这是一个受到强烈人为压力的地区。本研究使用柱层析和气相色谱质谱技术对马哈拉施特拉邦、果阿邦和卡纳塔克邦沿EAS的14个海滩的颗粒和碎片中与多环芳烃相关的多环芳烃进行了量化。颗粒中∑16PAHs浓度分别为:果阿邦1.9 ~ 29500 ng/g、孟买0.6 ~ 22900 ng/g、卡纳塔克邦0.8 ~ 21400 ng/g。这些碎片的∑16PAHs含量在2 ~ 2100 ng/g(卡纳塔克邦)之间,其次是1 ~ 1500 ng/g(果阿邦)到12 ~ 230 ng/g(孟买)。4-6环多环芳烃占主导地位,诊断比率表明热解、石油泄漏和燃烧活动等过程的组合。该研究还调查了哪种类型的MPs,颗粒或碎片,表现出更高的多环芳烃浓度,并探讨了相关因素。颗粒始终表现出较高的多环芳烃负荷,可能是由于其较小的尺寸,较大的表面积和长时间的环境暴露。多环芳烃污染MPs的生态风险∑PAH高于TEL(阈值效应水平)和ERL(效应范围低),表明可能存在偶发性生物影响。另一方面,∑PAH水平低于PEL(可能影响水平)和ERM(影响范围中值),表明在评价地点对海洋和人类生态系统没有显著的不利影响。通过强调多环芳烃污染的MPs的生态风险及其作为污染物载体的作用,本研究提出了一些紧迫的问题:这些看不见的威胁能传播多远,它们对沿海生态系统和公众健康的长期影响是什么?
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引用次数: 0
The oldest rock in the Eurasian continent was reworked from Hadean protocrust 欧亚大陆最古老的岩石是由冥古宙的原地壳改造而成的
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-01-23 DOI: 10.1016/j.gr.2025.12.016
Xiao-Fei Qiu , Da Wang , Xi-Run Tong , Shi-Wen Xie , Nian-Wen Wu , Fei Liu , Yu-Sheng Wan
The oldest rocks provide direct constraints on the nature of the first crust on Earth and the earliest magmatic process, which is significant for understanding the physical and chemical properties of our planet’s early stage. On the modern Earth, Hadean to Eoarchean crustal rocks have been identified in less than ten areas worldwide. Due to relatively poor preservation of early Archean rocks, major controversies exist on the tectonic mechanisms responsible for the formation of the continent during the early Earth. Therefore, identification of new Eoarchean or even Hadean crustal exposures would provide key information for understanding the formation and evolution of early continental crust and its geodynamic driver in the early Earth. Here, we report the new identification of Eoarchean trondhjemitic gneisses in the Muzidian Gneiss Complex (MGC) in the northern margin of Yangtze Craton. Zircon SHRIMP U-Pb ages of 3855 ± 7 Ma and 3851 ± 6 Ma suggest this trondhjemite unit in the MGC is the oldest known igneous rock in Eurasia. Zircon Hf isotopic compositions indicate that the MGC gneisses were formed from reworking of pre-existing Hadean crust older than 4.1 Ga. These newly recognized rocks in the MGC mark an important, Hadean crust derived, ancient gneiss complex, which is isotopically comparable to the Acasta Gneiss Complex in the currently established global Eoarchean geological record. Our findings indicate that at least some of the earliest crustal rocks might have originated from an early-differentiated, incompatible element-enriched protocrust in the Hadean.
最古老的岩石提供了对地球上第一个地壳的性质和最早的岩浆过程的直接限制,这对理解我们星球早期的物理和化学性质具有重要意义。在现代地球上,冥古宙到太古宙的地壳岩石在全世界不到十个地区被发现。由于太古宙早期岩石保存相对较差,对早期大陆形成的构造机制存在较大争议。因此,确定新的太古宙甚至冥古宙地壳暴露将为了解早期大陆地壳的形成演化及其地球动力学驱动因素提供关键信息。本文报道了扬子克拉通北缘木子店片麻岩杂岩(MGC)中古太古代长闪质片麻岩的新发现。锆石SHRIMP U-Pb年龄分别为3855±7 Ma和3851±6 Ma,表明该闪长岩单元是欧亚大陆已知最古老的火成岩。锆石Hf同位素组成表明,MGC片麻岩是由早于4.1 Ga的冥古宙地壳改造形成的。这些新发现的MGC岩石标志着一个重要的冥古宙地壳衍生的古老片麻岩杂岩,其同位素特征与目前建立的全球太古宙地质记录中的阿卡斯塔片麻岩杂岩相当。我们的发现表明,至少有一些最早的地壳岩石可能起源于冥古宙早期分化的、不相容的、富含元素的原地壳。
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引用次数: 0
Heavy metals in food: mechanisms of toxicity and migration through various routes in different foods 食物中的重金属:在不同食物中通过各种途径的毒性和迁移机制
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-06-01 Epub Date: 2026-02-05 DOI: 10.1016/j.gr.2025.12.021
Md Faruque Ahmad , Fakhruddin Ali Ahmad , Md. Zeyaullah , Farkad Bantun , Ahmad O. Babalghith , Mazen M. Ghaith , Yousef Zahrani , Hytham Hummad , Boshra Mozaffar , Mohammad Firoz Alam , Abdullah Y. Otayf
Heavy metals consist of a variety of elements, including lead, mercury, cadmium, arsenic, and chromium, among others. Industrial operations, packaging, mining, agricultural practices, and waste discharges are all examples of anthropogenic activities that contribute to the production of persistent environmental pollutants. These pollutants originate from natural causes, such as volcanic eruptions and rock weathering, as well as from anthropogenic activity. These metals infiltrate ecosystems, contaminating water, soil, and air, subsequently entering the food chain through consumption by animals and plants. The primary dietary sources of heavy metal exposure consist of contaminated vegetables, fruits, cereals, fish, and shellfish. Metals accumulate in these foods, and posing substantial risks to human health. Heavy metals present in foods produce toxicities through various mechanisms that include generation of reactive oxygen species (ROS), disruption of cellular processes, oxidative stress, protein and enzyme inactivation, and DNA damage and genomic instability, leading to organ impairment, cancer, reproductive disorders, cardiac disorders, and endocrine disruption. Study highlighting the serious need for regulation, monitoring, and remediation approaches to minimise the threat of heavy metals across the world.
重金属由多种元素组成,包括铅、汞、镉、砷和铬等。工业作业、包装、采矿、农业实践和废物排放都是导致产生持久性环境污染物的人为活动的例子。这些污染物来自自然原因,如火山爆发和岩石风化,以及人为活动。这些金属渗入生态系统,污染水、土壤和空气,随后通过动物和植物的消费进入食物链。重金属暴露的主要饮食来源包括受污染的蔬菜、水果、谷物、鱼类和贝类。金属在这些食物中积累,对人体健康构成重大风险。食物中的重金属通过各种机制产生毒性,包括活性氧(ROS)的产生、细胞过程的破坏、氧化应激、蛋白质和酶的失活、DNA损伤和基因组不稳定,导致器官损伤、癌症、生殖障碍、心脏疾病和内分泌紊乱。研究强调,迫切需要监管、监测和补救方法,以尽量减少世界各地重金属的威胁。
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