The rare metal lithium (Li), a strategic critical resource, plays a vital role in low-carbon energy technologies, including mobile electronics and nuclear industries. In China, clay-type Li resources, particularly those associated with bauxite sequences in northern China, have gained significant attention due to their widespread distribution and potential role as Li reserves. In our study, three types of clay mineral samples, namely chlorite (Chl), illite (Ilt), and kaolinite (Kln), were collected from bauxite units in North China. The Chl sample (5926.22 μg/g) contained considerably higher Li content than Ilt (622.04 μg/g) and Kln (741.76 μg/g), indicating that chlorite is the primary carrier mineral for Li. The cation exchange experiment revealed that Li was mainly hosted in the lattices of clay minerals (chlorite, illite, and kaolinite). Subsequently, the original samples were subjected to sedimentation–separation treatment to obtain higher-purity clay mineral samples. These samples were fully characterized via spectroscopic techniques to investigate the occurrence sites of Li. Li was predominantly hosted in Chl (cookeite, 9876.64 μg/g), with minor amounts in Ilt (625.36 μg/g) and Kln (747.19 μg/g). Although Li in cookeite was mainly located in the interlayer hydroxide sheets, it occupied the octahedral sheets in illite and kaolinite. Additionally, Li played a crucial role in balancing the negative charges that resulted from the substitution of Si by Al in the tetrahedral sheets, highlighting the structural significance of Li in these clay minerals. These findings enhance the understanding of Li occurrence states in clay minerals and offer valuable information for the utilization of bauxite-associated type Li resources.
扫码关注我们
求助内容:
应助结果提醒方式:
