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New insights on early diagenesis and palaeoenvironment of the Late Triassic bonebeds of India: evidence from rare earth element concentrations in fossil vertebrates 印度晚三叠世骨床早期成岩作用与古环境的新认识:来自脊椎动物化石中稀土元素浓度的证据
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2025-12-22 DOI: 10.1016/j.gr.2025.11.020
Aishee Sanyal, Sanghamitra Ray
This first comprehensive geochemical investigation of vertebrate fossils from India focuses on mass death assemblages recovered from four contemporaneous bonebeds in the Upper Triassic Tiki Formation, India. The study encompasses three extinct tetrapod taxonomic groups, namely the metoposaurids, phytosaurs and rhynchosaurs that co-existed, occupied different life habits and proliferated on the Tiki landscape. Geochemical signals including high crystallinity indices with low variability, similar patterns of Post-Archean Australian Shale-normalised mean rare earth element concentrations, considerable overlapping of convex hull polygons, and consistent enrichment in middle rare earth elements suggest similar early diagenetic palaeoenvironments for the four Tiki bonebeds. Such enrichment in middle rare earth elements is seen because of the presence of iron oxide within a terrestrial well-oxygenated fluvial setting that prevailed during fossilisation. The burial was a single-phase event, likely caused by a major flooding event, irrespective of whether the fossil accumulation was time-averaged, attritional or catastrophic. Differences in mean rare earth element concentrations in the taxonomic groups may have resulted from variation in their infiltration that was influenced by bone density which in-turn was influenced by contrasts in lifestyle. A positive europium anomaly in all specimens suggests localised reducing or anaerobic conditions resulting from autolytic degradation of the tissues at the time of early diagenesis. Studied specimens exhibited both positive and negative cerium anomalies that signify variations in the duration of subaerial exposure prior to burial, weathering stages and burial depth. The study helped in delineating the early diagenetic palaeoenvironments and reconstructing fossilisation pathways of the four Late Triassic bonebeds and highlights the significance of understanding geochemical signals in fossil bones.
这是对印度脊椎动物化石的第一次全面的地球化学调查,重点是在印度上三叠统提基组的四个同时期骨床中发现的大规模死亡组合。该研究涵盖了三个已灭绝的四足动物分类群,即中跖龙、植龙和舌龙,它们共存,有着不同的生活习惯,并在提基地貌上繁衍生息。高结晶度、低变异性的地球化学信号、后太古代澳大利亚页岩标准化平均稀土元素浓度的相似模式、凸壳多边形的大量重叠以及中稀土元素的一致富集表明,提基4个骨床具有相似的早期成岩古环境。这种中稀土元素的富集是由于在石化期间普遍存在的陆生含氧良好的河流环境中存在氧化铁。掩埋是一个单一阶段的事件,可能是由一次大的洪水事件引起的,无论化石堆积是时间平均的,是磨损的还是灾难性的。分类类群中平均稀土元素浓度的差异可能是由于其浸润的变化,而浸润的变化受骨密度的影响,而骨密度又受生活方式差异的影响。所有标本的阳性铕异常表明,早期成岩作用时组织的自溶降解导致局部减少或厌氧条件。所研究的标本显示出阳性和阴性的铈异常,这表明在埋藏前的地面暴露时间、风化阶段和埋藏深度的变化。该研究有助于圈定晚三叠世4个骨床的早成岩古环境和重建化石路径,并强调了理解化石骨中的地球化学信号的意义。
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引用次数: 0
Unravelling environmental drivers of blue carbon and primary productivity: Microphytobenthic biocoenosis in the mangrove sediments along the southwest coast of India 揭示蓝碳和初级生产力的环境驱动因素:印度西南海岸红树林沉积物中的微底栖植物群落
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2025-12-05 DOI: 10.1016/j.gr.2025.11.008
Niya Benny , Jittu Mathai , Lathika Cicily Thomas , P. Ajayakumar , T. Amaldev , K.B. Padmakumar
The microphytobenthic biocoenosis in the mangrove sediments along the southwest coast of India is intricately shaped by hydrographic and sediment characteristics. From December 2018 to February 2020, sediment and water samples were taken from five stations: KAN, KOL, KOC1, KOC2, and KOC3. During the investigation, 155 MPB species from 71 genera were discovered. The MPB community comprises diatoms, dinoflagellates, cyanobacteria, euglenophytes, charophytes, and chrysophytes. Major benthic diatoms present in the overall study were Navicula erifuga (179 cells cm−3), Diploneis suborbicularis (146 cells cm−3), Halamphora cymbifera (136 cells cm−3), Diploneis smithii (117 cells cm−3), Nitzschia sigma (109 cells cm−3), Amphora cymbamphora (93 cells cm−3), Achnanthes fimbriata (91 cells cm−3), Amphora proteus (74 cells cm−3), Gyrosigma balticum (71 cells cm−3) and Nitzschia lorenziana (71 cells cm−3). The C/N ratios indicated terrigenous organic matter in KOL, while the C/S ratios suggested oxidising conditions at all stations except KOC1, which was reducing. Principal component analysis revealed that MPB and diatom diversity were positively correlated to porewater salinity, sediment temperature, C/N ratio, porewater nitrate and phosphate, DO, silt%, and OC content. MPB, diatoms, dinoflagellates, cyanobacteria, and euglenophytes correlated positively with sand% and chlorophyll a. Conversely, rainfall intensity, porewater silicate, sediment pH, and clay% negatively influenced diversity. Seasonal variations in MPB along the southwest coast of India were more pronounced than spatial differences, with nutrient availability and sediment properties shaping community composition, highlighting key environmental drivers of blue carbon and primary productivity in mangrove sediments.
印度西南海岸红树林沉积物中的微底栖植物群落受水文和沉积物特征的复杂影响。2018年12月至2020年2月,在KAN、KOL、KOC1、KOC2和KOC3 5个站点采集了沉积物和水样。调查共发现71属155种。MPB群落包括硅藻、鞭毛藻、蓝藻、裸藻、绿藻和绿藻。在整个研究中,主要的底栖硅藻是Navicula erifuga(179个细胞厘米−3)、Diploneis suborbicularis(146个细胞厘米−3)、Halamphora cymbifera(136个细胞厘米−3)、Diploneis smithii(117个细胞厘米−3)、Nitzschia sigma(109个细胞厘米−3)、Amphora cymbamphora(93个细胞厘米−3)、Achnanthes fimbriata(91个细胞厘米−3)、Amphora proteus(74个细胞厘米−3)、Gyrosigma balticum(71个细胞厘米−3)和Nitzschia lorenziana(71个细胞厘米−3)。C/N表明KOL中存在陆源有机质,而C/S表明除KOC1外,其余站点均处于氧化状态。主成分分析表明,MPB和硅藻多样性与孔隙水盐度、沉积物温度、C/N比、孔隙水硝酸盐和磷酸盐、DO、淤泥%和OC含量呈正相关。MPB、硅藻、鞭毛藻、蓝藻和裸藻与沙%和叶绿素a呈正相关。相反,降雨强度、孔隙水硅酸盐、沉积物pH和粘土%对多样性呈负相关。印度西南海岸MPB的季节变化比空间差异更为明显,养分有效性和沉积物性质决定了群落组成,突出了红树林沉积物中蓝碳和初级生产力的关键环境驱动因素。
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引用次数: 0
Formation mechanism and global implications of the early Guadalupian phosphorite deposition along the eastern Palaeo-Tethys upwelling region (South China) 古特提斯东部上升流区早瓜达鲁普期磷矿沉积形成机制及其全球意义
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2025-12-13 DOI: 10.1016/j.gr.2025.11.009
Zhongqi Hu , Bolin Zhang , Xianguo Lang , Jian Cao , Suping Yao
The Guadalupian (Middle Permian) marks a critical interval of climatic–oceanographic transition during the waning of the Late Palaeozoic Ice Age (LPIA), accompanied by widespread phosphorite deposits in South China and North America. However, the linkage between palaeoenvironmental change and phosphorite formation remains poorly understood. Here we investigate the Kuhfeng Formation phosphorite deposition of the Lower Yangtze region in South China through integrated petrographic, mineralogical, geochronologic, and geochemical analyses. Our results suggest that phosphorite accumulated mainly in continental margin slope settings during the early Guadalupian (∼272.95 – 270.6 Ma), with phosphorus (P) hosted primarily in apatite. Left-sloping REE patterns, high Y/Ho values, and strong Al–P2O5 anti-correlation point to a dominantly marine source of phosphorus with limited volcanic input. Palaeoenvironmental proxies reveal warm-humid climates, strong upwelling, high productivity, suboxic-anoxic conditions, and elevated salinity during deposition. Based on an integrated tectonic–climatic–oceanic analysis, we propose an upwelling-driven high productivity mechanism under deglacial warming and intensified tectonism, controlling phosphorite formation. Following the deglaciation of the LPIA, enhanced upwelling and volcanic activity supplied abundant P, stimulating high primary productivity and abundant organic matter formation. This process promoted the deposition and decomposition of P–rich organic matter near the sediment–water interface, releasing large amounts of P into pore waters and finally facilitating phosphate precipitation. Comparison with contemporaneous phosphorite deposits in North America further suggests a global upwelling-driven mechanism for Guadalupian phosphorite formation.
瓜达鲁普期(中二叠世)标志着晚古生代冰期(LPIA)末期气候-海洋学转变的一个关键时期,伴随着华南和北美广泛的磷矿沉积。然而,古环境变化与磷矿形成之间的联系仍然知之甚少。本文通过岩石学、矿物学、地质年代学和地球化学综合分析,对华南下扬子地区库峰组磷矿沉积进行了研究。我们的研究结果表明,在瓜达鲁普期早期(~ 272.95 ~ 270.6 Ma),磷(P)主要赋存于磷灰石中,主要聚集在大陆边缘斜坡环境中。左倾斜的REE模式、高Y/Ho值和强的Al-P2O5反相关表明,磷主要来自海相,火山输入有限。古环境指标显示,沉积时期气候温暖湿润、上升流强、生产力高、缺氧条件和盐度升高。基于构造-气候-海洋的综合分析,提出了在融冰增温和构造活动加剧下,由上升流驱动的高产机制,控制着磷矿的形成。在冰期消退后,上升流和火山活动增强,提供了丰富的磷,促进了高初级生产力和丰富的有机质形成。这一过程促进了沉积物-水界面附近富P有机质的沉积和分解,将大量P释放到孔隙水中,最终促进了磷酸盐的沉淀。与北美同时期磷矿床的对比进一步表明,瓜达鲁普系磷矿形成具有全球性的上升流驱动机制。
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引用次数: 0
Mass extinction constrained and redirected flight evolution in Permopsocida 大灭绝限制和重定向了Permopsocida的飞行进化
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2026-01-01 DOI: 10.1016/j.gr.2025.12.009
Sheng Li , Feiyang Liang , Xiaoyue Yang , Chungkun Shih , Yunzhi Yao , Dong Ren , Ming Bai
Insect flight represents a key evolutionary innovation, yet the impact of mass extinctions on wing evolution remains unclear. We reconstruct wing shape evolution in Permopsocida (Carboniferous–Cretaceous) based on morphometric approaches. The present study reveals a tri-phasic pattern: pre-extinction expansion, end-Permian bottleneck and post-extinction redirection. Despite opportunities in the Mesozoic, structurally conservative features constrained aerodynamic innovation. During the Jurassic-Cretaceous period, wings elongated convergently as compensatory adaptations, not as functional breakthroughs. Morphological disparity recovery lagged behind and was decoupled from early angiosperm radiation but synchronized with gymnosperm diversity. These findings demonstrate how extinction-induced structural constraints redirected evolution through compensatory adaptation.
昆虫飞行代表了一项关键的进化创新,但大灭绝对翅膀进化的影响尚不清楚。基于形态计量学方法重建了石炭纪-白垩纪Permopsocida翼形演化。本研究揭示了灭绝前扩张-二叠纪末瓶颈-灭绝后重定向的三阶段格局。尽管中生代有机会,但结构保守的特征限制了空气动力学的创新。在侏罗纪-白垩纪时期,翅膀逐渐拉长是一种补偿性适应,而不是功能上的突破。形态差异恢复滞后于早期被子植物辐射,与裸子植物多样性同步。这些发现证明了灭绝引起的结构约束如何通过补偿性适应重新引导进化。
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引用次数: 0
Geological sedimentary records constraining Earth-Moon system evolution over the past 60 million years: Insights from Cyclostratigraphy 约束过去6000万年地月系统演化的地质沉积记录:来自旋回地层学的见解
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2026-01-05 DOI: 10.1016/j.gr.2026.01.001
Zhenwei Ge , Juye Shi , Quanyou Liu , Tailiang Fan , Zhiqian Gao , Huiyuan Xu , Ruyue Wang , Weihui Bi , Zhijun Jin
Over the past 60 million years, Earth has transitioned from a warmhouse to an icehouse climate. Understanding the variations in Earth-Moon orbital parameters during this interval is essential for understanding past tidal dissipation and predicting the future dynamical evolution of the Earth-Moon system. However, geological records that constrain the Earth-Moon system throughout the Cenozoic remain limited. Here, we analyzed high-resolution borehole gamma-ray logs from two wells (F154 and L242) in the Bohai Bay Basin (BBB), dated to approximately 41.25 Ma and 39.23 Ma, respectively. Using two independent astronomical methods, we reconstructed key orbital parameters, including the precession constant k, Earth-Moon distance (EMD) and length of day (LOD). The results showed that the precession constant k is 51.32 ± 0.22 arcsec/yr for well L242 and 51.33 ± 0.27 arcsec/yr for well F154. These geological k values are consistent with the Farhat model, correspond to the upper uncertainty range of the Waltham model, and significantly deviate from the Laskar model. Linear regression of the compiled geological k values indicates a long-term LOD increase rate of 1.39 ms/century over the past 60 million years. This rate is lower than the 2.13 ms/century predicted by Farhat model, likely due to enhanced hydrological and oceanic mass redistribution under extreme warming events in the early to middle Eocene. These findings provide new constraints on Cenozoic Earth-Moon dynamics and long-term variations in LOD throughout geological history.
在过去的6000万年里,地球从温室气候转变为冰窖气候。了解地月轨道参数在这段时间内的变化,对于理解过去的潮汐耗散和预测地月系统未来的动力学演化是至关重要的。然而,限制整个新生代地月系统的地质记录仍然有限。在这里,我们分析了渤海湾盆地(BBB)的两口井(F154和L242)的高分辨率井眼伽马射线测井曲线,分别约为41.25 Ma和39.23 Ma。利用两种独立的天文方法,我们重建了关键的轨道参数,包括岁差常数k、地月距离(EMD)和日长(LOD)。结果表明,L242井进动常数k为51.32±0.22 arcsec/yr, F154井进动常数k为51.33±0.27 arcsec/yr。这些地质k值与Farhat模型一致,对应于Waltham模型的上不确定范围,与Laskar模型偏差较大。对地质k值的线性回归表明,在过去6000万年中,LOD的长期增长速率为1.39 ms/世纪。这一速率低于Farhat模型预测的2.13 ms/世纪,可能是由于始新世早期至中期极端变暖事件下的水文和海洋质量再分配增强。这些发现为研究新生代地月动力学和LOD在地质历史上的长期变化提供了新的约束。
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引用次数: 0
The role of renewable energy transition in achieving carbon neutrality within the SDG framework: challenges, and prospects 可再生能源转型在可持续发展目标框架内实现碳中和中的作用:挑战与前景
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2025-12-22 DOI: 10.1016/j.gr.2025.11.022
Moslem Ansarinasab
The transition of economies to renewable energy is one of the most important and fundamental building blocks for achieving decarbonization, and both are increasingly important in achieving the United Nations Sustainable Development Goals. This article systematically reviewed 32 peer-reviewed scientific articles published between 2000 and 2025, following the PRISMA guidelines. Thematic linkage findings showed that the stronger the transition to sustainable energy, the faster the achievement of the Sustainable Development Goals, including SDG 7 (Affordable and Clean Energy), SDG 13 (Climate Action), and SDG 9 (Industry, Innovation, and Infrastructure). Co-authorship and co-citation analysis indicated that China, Bangladesh, and Pakistan were the leading countries in this direction. The keyword map also showed technological innovation, energy policy, and environmental sustainability as the focus of the studies. However, the findings showed that despite all the efforts made in this field, areas such as integrating social justice, poverty reduction and biodiversity protection in the energy transition remain neglected in studies. Therefore, a coherent global, transnational and targeted strategy seems necessary in this regard. Therefore, this study highlights three key insights in this regard: (1) The transition to renewable energy by accelerating decarbonization will facilitate access to affordable and clean energy as a sustainable development goal. (2) The more investments in the renewable energy transition are strengthened with complementary policies such as carbon pricing and technology transfer, the better the climate change outcomes will be. (3) Emphasis on green innovations in storage infrastructure and smart energy grids will lead to the development of green jobs and sustainable industrial growth.
经济向可再生能源转型是实现脱碳的最重要和最基本的组成部分之一,两者在实现联合国可持续发展目标方面日益重要。本文系统地回顾了2000年至2025年间发表的32篇同行评议的科学文章,遵循PRISMA指南。专题联系调查结果表明,向可持续能源的过渡越快,实现可持续发展目标的速度就越快,包括可持续发展目标7(负担得起的清洁能源)、可持续发展目标13(气候行动)和可持续发展目标9(工业、创新和基础设施)。共同作者和共被引分析表明,中国、孟加拉国和巴基斯坦是这一方向的主要国家。关键词地图还显示了技术创新、能源政策和环境可持续性是研究的重点。然而,研究结果表明,尽管在这一领域做出了所有努力,但在能源转型中整合社会正义、减贫和生物多样性保护等领域仍然被忽视。因此,在这方面似乎需要一项连贯的全球、跨国和目标明确的战略。因此,本研究强调了这方面的三个关键见解:(1)通过加速脱碳向可再生能源的过渡将促进获得负担得起的清洁能源,并将其作为可持续发展目标。(2)可再生能源转型投资力度越大,碳定价和技术转让等政策配套力度越大,应对气候变化效果越好。(3)重视储能基础设施和智能电网的绿色创新,将促进绿色就业的发展和产业的可持续增长。
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引用次数: 0
Seeking El Dorado: Iceland’s carbon dioxide removal service opportunities to meet global demand and a new lens on overnight transition cost 寻求黄金国:冰岛二氧化碳去除服务的机会,以满足全球需求,并对隔夜过渡成本的新视角
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2025-12-13 DOI: 10.1016/j.gr.2025.11.016
Dominik Keiner, Yousef Pourjamal, Siavash Khalili, Christian Breyer
Carbon dioxide removal is likely needed to reach the 1.5°C and a more ambitious 1.0°C target rebalancing the climate within planetary boundaries. Research on carbon dioxide removal is usually done either on global scale or for large regions. Dedicated energy system integration of a large-scale carbon dioxide removal industry sector into a national energy system is not yet state-of-the-art. This study closes this research gap for the case of Iceland, one of the most promising countries in the world to act as a carbon dioxide removal hub due to its geologically favourable conditions for in-situ mineralisation, and abundance of renewable energy sources including geothermal energy. Incorporating a novel method to represent the legacy transition cost in an overnight system transition model, several scenarios are applied varying the availability of geothermal energy and carbon dioxide removal service contribution to global demand for ambitious climate targets. The results indicate the requirement of alternative renewable energy sources beyond hydropower and geothermal energy, while large-scale carbon dioxide removal is possible. Renewable power generation capacities are required to significantly increase; onshore wind power, solar photovoltaics, and wave power are identified as additional pillars to supply the energy required. Instead of energy supply, the availability of workforce is identified as the main limitation, and 1 GtCO2/a seems a realistic upper bound for carbon dioxide removal in Iceland. The gross domestic product per capita could be doubled by 2070, turning Iceland into one of the richest countries in the world and the ‘El Dorado’ of carbon dioxide removal.
二氧化碳的去除可能需要达到1.5 °C和更雄心勃勃的1.0 °C目标,以在地球范围内重新平衡气候。二氧化碳去除的研究通常是在全球范围内或在大区域内进行的。将大规模二氧化碳去除工业部门纳入国家能源系统的专用能源系统还不是最先进的。这项研究填补了冰岛的研究空白,冰岛是世界上最有希望作为二氧化碳去除中心的国家之一,因为它的地质条件有利于原地矿化,并且拥有丰富的可再生能源,包括地热能。结合一种新的方法来表示隔夜系统转换模型中的遗留转换成本,应用了几种不同的场景,包括地热能的可用性和二氧化碳去除服务对实现雄心勃勃的气候目标的全球需求的贡献。结果表明,除了水电和地热能之外,还需要可替代的可再生能源,而大规模的二氧化碳去除是可能的。可再生能源发电能力需要大幅提高;陆上风力发电、太阳能光伏发电和波浪能被确定为提供所需能源的额外支柱。劳动力的可用性被确定为主要限制,而不是能源供应,1 GtCO2/a似乎是冰岛二氧化碳去除的现实上限。到2070年,人均国内生产总值(gdp)可能翻一番,使冰岛成为世界上最富有的国家之一,并成为二氧化碳减排的“黄金国”。
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引用次数: 0
Porous rock permeability quantification: A superpixel-driven graph neural network method for pore region analysis 多孔岩石渗透率量化:一种用于孔隙区域分析的超像素驱动图神经网络方法
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2025-12-13 DOI: 10.1016/j.gr.2025.11.014
Xinlin Zhao , Yuan Zhong , Ping Li
Rock permeability, as a significant parameter, plays a crucial role in research related to geological exploration, reservoir resource development, and the movement and distribution of subsurface fluids. Despite significant advancements in artificial intelligence technology for rock analysis in recent years, challenges remain in terms of prediction accuracy, computational complexity, and resource dependency. To address these issues, this paper proposes a superpixel-based graph neural network (SP-GNN) method to achieve rock permeability prediction. Specifically, the flow space of the rock medium is superpixelized to construct graph data. Based on the superpixel graph data, a graph neural network designed to learn multi-level cascading features is developed, while also implementing an algorithm to extract neighborhood spatial features that contain sequential relationships. A temporal pooling strategy is proposed to perform collaborative learning of the cascading features and neighborhood spatial features of graph data from a temporal perspective, in order to obtain hierarchical global features of dynamic nodes. Finally, the global features of the graph are input into the downstream tasks to achieve accurate prediction of permeability. Experimental results show that the SP-GNN significantly outperforms various existing benchmark schemes for permeability prediction across seven comprehensive performance metrics, demonstrating the ability to accurately and efficiently predict permeability for both mixed-type and single-type rocks; ablation experiments further validate the effectiveness of the proposed temporal pooling strategy.
岩石渗透率作为一个重要的参数,在地质勘探、储层资源开发、地下流体运动分布等研究中起着至关重要的作用。尽管近年来人工智能技术在岩石分析方面取得了重大进展,但在预测精度、计算复杂性和资源依赖性方面仍然存在挑战。针对这些问题,本文提出了一种基于超像素的图神经网络(SP-GNN)方法来实现岩石渗透率预测。具体来说,对岩石介质的流动空间进行超像素化处理以构建图形数据。基于超像素图数据,提出了一种学习多层次级联特征的图神经网络,并实现了包含序列关系的邻域空间特征提取算法。提出了一种时间池化策略,从时间角度对图数据的级联特征和邻域空间特征进行协同学习,以获得动态节点的层次化全局特征。最后,将图的全局特征输入到下游任务中,实现对渗透率的准确预测。实验结果表明,SP-GNN在7个综合性能指标上显著优于现有的各种渗透率预测基准方案,能够准确有效地预测混合类型和单一类型岩石的渗透率;消融实验进一步验证了时间池策略的有效性。
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引用次数: 0
Early Cretaceous Meso-Tethyan oceanic plateau built on an ultraslow-spreading oceanic lithosphere: Insights from Hf–Nd–Os isotopes and Pt-group elements of the Dongco ophiolite, central Tibet
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2025-12-13 DOI: 10.1016/j.gr.2025.11.012
Chen Ji , Kai-Jun Zhang
The Dongco ophiolite in central Tibet represents an ideal profile of a Meso-Tethyan oceanic plateau lithosphere. In this paper, we presented petrological, geochronological, geochemical, Hf–Nd–Os isotopic and Pt-group elemental data for its primary igneous units, in an attempt to constrain the architecture and building process of oceanic plateau. The oceanic plateau basalts erupted over the Middle Jurassic (∼167 Ma) normal mid-oceanic ridge basalt (N-MORB)-like oceanic lithosphere dominantly composed of ultramafic and mafic plutons (εNd(t) = 6.5–9.5; εHf(t) = 15–21), at the Early Cretaceous (∼125 Ma). The absence of MORB-type basalt in the Dongco ophiolite, as well as the presence of diabase dikes intruding the mantle peridotite and cumulate gabbro, indicates the base of the oceanic plateau formed under an ultraslow spreading setting. The plateau basalts have positive εNd(t) values (3.8–5.1), geochemically with distinct ocean-island basalt (OIB) affinity, and represent plume melts that were estimated to form at a depth over 160 km (1600 ℃ potential temperature). Wehrlites at the bottom of the OIBs, isotopically consistent with the OIBs, have highly siderophile element (HSE) compositions similar to Hawaii picrite and tholeiitic basalt with suprachondritic Os isotopic compositions (87Os/188Os = 0.1306–0.1329), signifying the plume melt cumulates based on modeling. The harzburgites are geochemically heterogeneous due to the plume melt–rock interaction. Type 1 harzburgites, mantle residues, have abyssal peridotite-like HSE compositions with subchondritic 187Os/188Os ratios (0.1182–0.1204) and ancient Re depletion model ages (1.0–1.3 Ga), indicating a complex depletion history. Type 2 harzburgites are characterized by fractionated Ir-group Pt group element compositions, higher subchondritic 187Os/188Os ratios (0.1211–0.1251) and younger Re depletion model ages (0.3–0.9 Ga), likely a percolation effect of plume melts with radiogenic Os isotopic compositions.
本文通过岩石学、年代学、地球化学、Hf-Nd-Os同位素、pt族元素等资料对其原生火成岩单元进行分析,试图对海洋高原的构造和形成过程进行约束。中侏罗统(~ 167 Ma)正常的洋中脊玄武岩(N-MORB)型洋岩石圈(εNd(t) = 6.5-9.5;εHf(t) = 15-21),早白垩世(~ 125 Ma)。东错蛇绿岩中没有morb型玄武岩,而辉绿岩脉侵入地幔橄榄岩和堆积辉长岩,表明该洋基高原是在超低扩张背景下形成的。高原玄武岩εNd(t)值为正(3.8 ~ 5.1),地球化学上具有明显的洋岛玄武岩(OIB)亲和性,代表在深度160 km(1600℃位温)以上形成的羽流熔体。岩石底部的威氏岩同位素特征与岩石一致,具有与夏威夷冰辉岩和拉斑玄武岩相似的高亲铁元素(HSE)组成,并具有超软粒质Os同位素组成(87Os/188Os = 0.1306-0.1329),表明模拟结果为羽流熔融堆积。由于羽流熔融-岩石相互作用,哈尔茨伯尔土具有地球化学不均匀性。1型哈尔茨伯尔岩为地幔残余物,具有深海橄榄岩样HSE组成,亚球粒状187Os/188Os比值(0.1182 ~ 0.1204),古Re枯竭模式年龄(1.0 ~ 1.3 Ga),具有复杂的枯竭历史。2型哈茨伯尔岩的特征是ir -组Pt -组元素组成分异,亚球粒型187Os/188Os比值较高(0.1211 ~ 0.1251),Re耗尽模型年龄较低(0.3 ~ 0.9 Ga),可能是放射性成因Os同位素组成的羽流熔体的渗透作用。
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引用次数: 0
Mantle eclogite evidence of subducted carbonate sediments in Earth’s deep carbon cycle 地球深部碳循环中俯冲碳酸盐沉积物的地幔榴辉岩证据
IF 7.2 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2025-12-13 DOI: 10.1016/j.gr.2025.11.015
Jing Sun , Ross N. Mitchell , Luc S. Doucet , Kouki Kitajima , Ranpeng Li , Jinglin Su , Qiqi Ou , Tanya Kalashnikova , Sergey I. Kostrovitsky
Mantle eclogite represents a rare and unique archive for understanding the dynamics and implications of subduction, but its origin is still debated especially for high-MgO eclogites. We report new chemical and Mg–O isotopic data on high-MgO mantle eclogites from the Obnazhennaya kimberlite, Siberia craton. Obnazhennaya high-MgO eclogites have lower bulk δ26Mg isotopes (-1.47– -0.36‰) and mantle-like garnet δ18O isotopes (+5.18–+6.39‰). A bulk mixing calculation among oceanic crust, carbonate sediment and kimberlite, and its effects on Mg isotopes and MgO content indicate that metasomatism can only increase the MgO content but not δ26Mg, and more than 50% dolostone by mass is needed, under conditions with no kimberlitic melt metasomatism, to account for both high-MgO contents, which is unrealistically high for natural settings. The ternary mixing model on both O–Mg isotopic compositions and MgO–Mg isotopic compositions suggest that subducted oceanic crusts modified by mantle metasomatism (e.g., kimberlite-like melt) as well as carbonate sediments involvement collectively provides the best explanation for such a high magnesian origin. This model is also compatible with global mantle eclogite observations, where there is also a clear chemical composition distinction between high- and low-MgO eclogites globally. In light of our new results and global compilation, we propose that mantle eclogites represent a spectrum of metasomatized subducted oceanic crust with variable amounts of the involvement of carbonate sediments, the latter of which represents a novel ingredient in the recipe for making previously enigmatic high-MgO eclogite xenoliths in kimberlites.
地幔榴辉岩是了解俯冲动力学和意义的一个罕见而独特的档案,但其起源仍然存在争议,特别是高镁榴辉岩。本文报道了西伯利亚克拉通Obnazhennaya金伯利岩中高mgo地幔榴辉岩的化学和Mg-O同位素新数据。Obnazhennaya高mgo榴辉岩具有较低的δ26Mg同位素(-1.47 ~ -0.36‰)和幔状石榴石δ18O同位素(+5.18 ~ +6.39‰)。海洋地壳、碳酸盐沉积物和金伯利岩的整体混合计算及其对Mg同位素和MgO含量的影响表明,交代作用只会增加MgO含量,而不会增加δ26Mg,并且在没有金伯利岩熔融交代的条件下,需要超过50%的白云岩质量才能解释这两个高MgO含量,这在自然环境中是不现实的。O-Mg同位素组成和MgO-Mg同位素组成的三重混合模型表明,俯冲洋壳经过地幔交代作用(如金伯利岩类熔体)和碳酸盐沉积物的共同作用,为这种高镁成因提供了最好的解释。该模型也与全球地幔榴辉岩观测相一致,在全球范围内,高、低镁榴辉岩的化学成分也有明显的区别。根据我们的新结果和全球汇编,我们提出地幔榴辉岩代表了交代俯冲海洋地壳的光谱,其中碳酸盐沉积物的参与程度不同,后者代表了金伯利岩中以前神秘的高mgo榴辉岩包体配方的新成分。
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引用次数: 0
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Gondwana Research
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