Pub Date : 2024-10-02DOI: 10.1016/j.gr.2024.09.006
Emő Márton , János Haas , Gábor Imre , Máté Velki , László Fodor
Mesozoic paleomagnetic data from the Transdanubian Range Unit (TRU) of the Pannonian Basin has been revised and updated to enable its paleogeographic evolution within SE Europe to be evaluated. After a 30° declination correction, the TRU data are fully consistent with those for Adria which has an almost identical stratigraphic history. This enabled a revised Apparent Polar Wander Path (APWP) to be constructed for the combined data. Comparing this with the corresponding African and European APWP shows that Adria separated from Europe around 190 Ma, then moved independently southwards between 170–120 Ma (a 30° clockwise rotation changing to counter-clockwise around 155–145 Ma). After 155 Ma, there was a northward movement that brought Adria close to the stable European margin by 115 Ma. This latter may have been with or independently of Africa. After 100 Ma, Africa and Adria moved in coordination until the end of the Cretaceous. This sequence of events correlated well with geologically established tectonic events. These include the major extensional phases in the Alpine Tethys during the southward shift and large clockwise rotation (170–155/145 Ma). This was followed by ophiolite obduction in the Neotethys (West and East Vardar) around 155–145 Ma as a result of the dramatic reversal in the displacement of Adria. Finally, around 115 Ma, the TRU was emplaced over Austroalpine units as a thick nappe associated with the general uplift in the Adriatic realm.
对潘诺尼亚盆地外多瑙河山脉单元(TRU)的中生代古地磁数据进行了修订和更新,以便对其在欧洲东南部的古地理演变进行评估。经过 30° 偏角校正后,TRU 的数据与地层历史几乎完全相同的阿德里亚的数据完全一致。这样,就可以为合并数据构建一个修正的表观极地漫游路径(APWP)。将其与相应的非洲和欧洲 APWP 相比较,可以发现阿德里亚在 190 Ma 左右与欧洲分离,然后在 170-120 Ma 之间独立向南移动(顺时针旋转 30° 在 155-145 Ma 左右变为逆时针旋转)。155Ma之后,阿德里亚发生了北移,到115Ma时接近稳定的欧洲边缘。后者可能与非洲一起或独立于非洲之外。100Ma之后,非洲和阿德里亚协调移动,直到白垩纪末。这一系列事件与地质构造事件密切相关。这些事件包括阿尔卑斯特提斯山在南移和大顺时针旋转(170-155/145 Ma)期间的主要扩展阶段。随后,由于阿德里亚位移的急剧逆转,新特提斯(西瓦尔达尔和东瓦尔达尔)在 155-145 Ma 左右发生了蛇绿岩俯冲。最后,在公元前115年左右,TRU作为与亚得里亚海地区总体隆起相关的厚岩层,隆起于奥陶纪单位之上。
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Pub Date : 2024-10-02DOI: 10.1016/j.gr.2024.09.014
Jack E. Stirling , Anthony I.S. Kemp , Malcolm T. McCulloch , Steven W. Denyszyn
Cordilleran granitic batholiths represent significant episodes of crustal growth and differentiation, and commonly display lateral isotopic and chemical variations. Establishing the tectono-magmatic processes responsible for generating this compositional asymmetry is important for understanding crustal evolutionary processes throughout the Phanerozoic. The Bega Batholith, an example of a ‘Cordilleran style’ granite batholith, is the largest I-type Siluro-Devonian granite complex in the Lachlan Fold Belt (LFB) of southeastern Australia and comprises seven granite supersuites that display systematic lateral isotopic and chemical asymmetry. From west to east towards the present-day continental margin, an increase in the content of Na2O, Sr, Al2O3, and P2O5, with concomitant decreases in CaO, Sc, Rb, and V are observed. In the same direction, whole-rock initial 87Sr/86Sr decreases from 0.7098 to 0.7039, εNd values increase from −8.3 to +4.4, and δ18O decreases from 10.2 ‰ to 7.9 ‰. Depleted-mantle model ages also decrease from ca. 1800 Ma in the west to 600 Ma in the east. Here, we address whether these chemical and isotopic variations were generated by interaction between two distinct components (mantle-derived magmas and supracrustal sources) or were alternatively produced by partial melting of infracrustal source rocks formed sequentially by much earlier episodes of crustal underplating. Combined whole-rock Nd-Sr-O isotopic and geochemical analyses indicate that several I-type supersuites exhibit chemical and isotopic correlations consistent with two-component magma mixing. This new evidence challenges the long-held view that I-type granites derive exclusively from the melting of infracrustal sources, and that granite terranes represent wholesale crustal reworking rather than new crustal growth. Our results show that the compositional zoning within the Bega Batholith is multifaceted. Firstly, the presence of two discrete mantle sources endows chemically and isotopically distinct eastern and western segments in the batholith. Secondly, within these compositionally distinct regions the lateral compositional changes across supersuites derives from mixing between mantle-derived and supracrustal sources. Finally, progressive extension within a developing back-arc environment regulates the ratio of crust-mantle contributions and compositional architecture of each I-type supersuite.
科迪勒拉花岗岩浴成岩代表了地壳生长和分化的重要阶段,通常表现出横向同位素和化学变化。确定产生这种成分不对称的构造-岩浆过程对于了解整个新生代的地壳演化过程非常重要。贝加浴成岩是 "科迪勒拉风格 "花岗岩浴成岩的典范,是澳大利亚东南部拉克兰褶皱带(LFB)中最大的 I 型西鲁-德文花岗岩群,由七个花岗岩超基岩组成,显示出系统的横向同位素和化学不对称。从西向东走向今天的大陆边缘,观察到 Na2O、Sr、Al2O3 和 P2O5 的含量增加,CaO、Sc、Rb 和 V 的含量同时减少。在同一方向上,全岩初始 87Sr/86Sr 值从 0.7098 降至 0.7039,εNd 值从 -8.3 升至 +4.4,δ18O 值从 10.2 ‰ 降至 7.9 ‰。贫幔模型年龄也从西部的约 1800 Ma 下降到东部的 600 Ma。在此,我们探讨了这些化学和同位素变化是由两种不同成分(地幔岩浆和上地壳源)之间的相互作用产生的,还是由更早的地壳下沉事件连续形成的地壳下源岩的部分熔融产生的。综合全岩 Nd-Sr-O 同位素和地球化学分析表明,几个 I 型超岩体显示出与双组分岩浆混合相一致的化学和同位素相关性。这一新证据挑战了长期以来的观点,即 I 型花岗岩完全来自于地壳下源的熔融,花岗岩岩体代表了地壳的整体再加工,而不是新的地壳生长。我们的研究结果表明,贝加浴成岩内部的成分分带是多方面的。首先,由于存在两个不同的地幔源,浴成岩的东西两段在化学和同位素上截然不同。其次,在这些成分截然不同的区域内,不同超岩体之间的横向成分变化源于地幔源与超岩体源之间的混合。最后,在发展中的后弧环境中的逐渐延伸调节了地壳-地幔贡献的比例和每个I型超岩体的成分结构。
{"title":"Chemical and isotopic investigation of the I-type Bega Batholith, southeastern Australia: Implications for batholith compositional zoning and crustal evolution in accretionary orogens","authors":"Jack E. Stirling , Anthony I.S. Kemp , Malcolm T. McCulloch , Steven W. Denyszyn","doi":"10.1016/j.gr.2024.09.014","DOIUrl":"10.1016/j.gr.2024.09.014","url":null,"abstract":"<div><div>Cordilleran granitic batholiths represent significant episodes of crustal growth and differentiation, and commonly display lateral isotopic and chemical variations. Establishing the tectono-magmatic processes responsible for generating this compositional asymmetry is important for understanding crustal evolutionary processes throughout the Phanerozoic. The Bega Batholith, an example of a ‘Cordilleran style’ granite batholith, is the largest I-type Siluro-Devonian granite complex in the Lachlan Fold Belt (LFB) of southeastern Australia and comprises seven granite supersuites that display systematic lateral isotopic and chemical asymmetry. From west to east towards the present-day continental margin, an increase in the content of Na<sub>2</sub>O, Sr, Al<sub>2</sub>O<sub>3</sub>, and P<sub>2</sub>O<sub>5</sub>, with concomitant decreases in CaO, Sc, Rb, and V are observed. In the same direction, whole-rock initial <sup>87</sup>Sr/<sup>86</sup>Sr decreases from 0.7098 to 0.7039, ε<sub>Nd</sub> values increase from −8.3 to +4.4, and δ<sup>18</sup>O decreases from 10.2 ‰ to 7.9 ‰. Depleted-mantle model ages also decrease from ca. 1800 Ma in the west to 600 Ma in the east. Here, we address whether these chemical and isotopic variations were generated by interaction between two distinct components (mantle-derived magmas and supracrustal sources) or were alternatively produced by partial melting of infracrustal source rocks formed sequentially by much earlier episodes of crustal underplating. Combined whole-rock Nd-Sr-O isotopic and geochemical analyses indicate that several I-type supersuites exhibit chemical and isotopic correlations consistent with two-component magma mixing. This new evidence challenges the long-held view that I-type granites derive exclusively from the melting of infracrustal sources, and that granite terranes represent wholesale crustal reworking rather than new crustal growth. Our results show that the compositional zoning within the Bega Batholith is multifaceted. Firstly, the presence of two discrete mantle sources endows chemically and isotopically distinct eastern and western segments in the batholith. Secondly, within these compositionally distinct regions the lateral compositional changes across supersuites derives from mixing between mantle-derived and supracrustal sources. Finally, progressive extension within a developing back-arc environment regulates the ratio of crust-mantle contributions and compositional architecture of each I-type supersuite.</div></div>","PeriodicalId":12761,"journal":{"name":"Gondwana Research","volume":"137 ","pages":"Pages 79-98"},"PeriodicalIF":7.2,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142424202","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Karst bauxites mark episodic exhumation of carbonate platforms, thus providing key information for basin analysis and paleoclimate processes at the regional to continental scale. Most karst bauxite deposits of SE France lie between Jurassic platform carbonates in the footwall and Upper Cretaceous marine to continental sediments in the hanging wall. These deposits delineate a stratigraphic gap coeval with the Durance extensional tectonics, which led to the separation of the Vocontian and South Provence Basins, and shaped the junction between the Alpine Tethys and the Pyrenean Rift.
Our new mineralogical and geochemical data show that SE France karst bauxites were affected by in-situ weathering and alteration in conjunction to sedimentary reworking. Statistical analysis of geochemical data indicates that bauxite deposits have a similar chemical footprint, likely pointing to a common and long-lasting bauxitization process. New U-Pb zircon data from the Provence deposits confirm that the source material for the SE France bauxites is to be primarily found in the Hercynian basement. The data suggest the presence of an additional exotic zircon source deriving either from Avalonia and/or Baltica. The comparison of the new U-Pb zircon data with those on coeval bauxites evidences a marked difference between the SE France and the Sardinian deposits. This difference indicates diversification in the detritus provenance of the two areas since the Lower Cretaceous, setting the bauxites of SE France and Sardinia in lateral continuity with the bauxites occurring on the two opposite margins of the Pyrenean Rift, and supporting the development of these deposits on the shoulders of the rift-related basin formed at the eastern termination of the Pyrenean Rift.
{"title":"The mid-Cretaceous bauxites of SE France: Geochemistry, U-Pb zircon dating and their implications for the paleogeography at the junction between Alpine Tethys and Pyrenean Rift","authors":"Nicola Mondillo , Cyril Chelle-Michou , Francesco Putzolu , Giuseppina Balassone , Angela Mormone , Licia Santoro , Salvatore Cretella , Gennaro Scognamiglio , Marcella Tarallo , Stefano Tavani","doi":"10.1016/j.gr.2024.09.012","DOIUrl":"10.1016/j.gr.2024.09.012","url":null,"abstract":"<div><div>Karst bauxites mark episodic exhumation of carbonate platforms, thus providing key information for basin analysis and paleoclimate processes at the regional to continental scale. Most karst bauxite deposits of SE France lie between Jurassic platform carbonates in the footwall and Upper Cretaceous marine to continental sediments in the hanging wall. These deposits delineate a stratigraphic gap coeval with the Durance extensional tectonics, which led to the separation of the Vocontian and South Provence Basins, and shaped the junction between the Alpine Tethys and the Pyrenean Rift.</div><div>Our new mineralogical and geochemical data show that SE France karst bauxites were affected by in-situ weathering and alteration in conjunction to sedimentary reworking. Statistical analysis of geochemical data indicates that bauxite deposits have a similar chemical footprint, likely pointing to a common and long-lasting bauxitization process. New U-Pb zircon data from the Provence deposits confirm that the source material for the SE France bauxites is to be primarily found in the Hercynian basement. The data suggest the presence of an additional exotic zircon source deriving either from Avalonia and/or Baltica. The comparison of the new U-Pb zircon data with those on coeval bauxites evidences a marked difference between the SE France and the Sardinian deposits. This difference indicates diversification in the detritus provenance of the two areas since the Lower Cretaceous, setting the bauxites of SE France and Sardinia in lateral continuity with the bauxites occurring on the two opposite margins of the Pyrenean Rift, and supporting the development of these deposits on the shoulders of the rift-related basin formed at the eastern termination of the Pyrenean Rift.</div></div>","PeriodicalId":12761,"journal":{"name":"Gondwana Research","volume":"137 ","pages":"Pages 145-170"},"PeriodicalIF":7.2,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142424305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-01DOI: 10.1016/j.gr.2024.09.013
Xubin Wang , Lin Dong , Yiwu Wang , Zhijun Jin
Carbonate authigenesis, the in situ precipitation of carbonate minerals within the sediment porewaters, is a key pathway for carbonate deposition and plays a crucial role in global biogeochemical cycles. Heterotrophic microorganisms are essential in regulating authigenic carbonate formation, primarily through the consumption of organic matter. Although bacterial manganese reduction is known to influence the formation of rhodochrosite and dolomite, its role in limestone deposition is unclear. Here, we present a systematic investigation of mixed calcareous siliciclastic rocks from a Paleogene freshwater lake to identify the formation of authigenic carbonate, decode the role of microbial Mn reduction, and understand the microbial response to ancient lacustrine environmental changes. The positive correlation between carbonate fraction in bulk samples (Carb%) and Mn content in carbonate minerals (Mncarb) suggests that carbonate precipitation is stimulated by Mn2+ enrichment. The dissimilarity between Mncarb and Fecarb, along with the synergic variations of Mncarb and diagenetic indicators, support an authigenic rather than a hydrogenetic origin for the carbonates. Using a one-dimensional diffusion–advection-reaction model, we quantify the impact of Mn reduction on promoting carbonate precipitation. Furthermore, correlations between Pcarb and other values–positive with the chemical index alteration (CIA), negative with Mncarb, and none with TOC–suggest that nitrogen availability, regulated by continental weathering, is likely the primary factor limiting both the primary productivity and the bacterial reduction intensity at the study site. Overall, this study uncovers the role of microbial Mn reduction in stimulating authigenic carbonate precipitation, and reveals the modulation mechanism of Mn-reducing microorganisms in an ancient lake. These findings shed new light on the authigenic limestone formation mechanisms and provide a new perspective on interpreting the authigenic impacts on carbonate chemistry.
{"title":"Recognizing microbial manganese reduction in lacustrine carbonate and its linkage to terrestrial biogeochemical processes","authors":"Xubin Wang , Lin Dong , Yiwu Wang , Zhijun Jin","doi":"10.1016/j.gr.2024.09.013","DOIUrl":"10.1016/j.gr.2024.09.013","url":null,"abstract":"<div><div>Carbonate authigenesis, the in situ precipitation of carbonate minerals within the sediment porewaters, is a key pathway for carbonate deposition and plays a crucial role in global biogeochemical cycles. Heterotrophic microorganisms are essential in regulating authigenic carbonate formation, primarily through the consumption of organic matter. Although bacterial manganese reduction is known to influence the formation of rhodochrosite and dolomite, its role in limestone deposition is unclear. Here, we present a systematic investigation of mixed calcareous siliciclastic rocks from a Paleogene freshwater lake to identify the formation of authigenic carbonate, decode the role of microbial Mn reduction, and understand the microbial response to ancient lacustrine environmental changes. The positive correlation between carbonate fraction in bulk samples (Carb%) and Mn content in carbonate minerals (Mn<sub>carb</sub>) suggests that carbonate precipitation is stimulated by Mn<sup>2+</sup> enrichment. The dissimilarity between Mn<sub>carb</sub> and Fe<sub>carb</sub>, along with the synergic variations of Mn<sub>carb</sub> and diagenetic indicators, support an authigenic rather than a hydrogenetic origin for the carbonates. Using a one-dimensional diffusion–advection-reaction model, we quantify the impact of Mn reduction on promoting carbonate precipitation. Furthermore, correlations between P<sub>carb</sub> and other values–positive with the chemical index alteration (CIA), negative with Mn<sub>carb</sub>, and none with TOC–suggest that nitrogen availability, regulated by continental weathering, is likely the primary factor limiting both the primary productivity and the bacterial reduction intensity at the study site. Overall, this study uncovers the role of microbial Mn reduction in stimulating authigenic carbonate precipitation, and reveals the modulation mechanism of Mn-reducing microorganisms in an ancient lake. These findings shed new light on the authigenic limestone formation mechanisms and provide a new perspective on interpreting the authigenic impacts on carbonate chemistry.</div></div>","PeriodicalId":12761,"journal":{"name":"Gondwana Research","volume":"137 ","pages":"Pages 36-55"},"PeriodicalIF":7.2,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142424200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-30DOI: 10.1016/j.gr.2024.09.007
Rodrigo Temp Müller
Investigations regarding the early evolutionary history of bird-line archosaurs have undergone significant advancements in recent years. However, controversies remain, especially regarding the phylogenetic position of “silesaurids”. Whereas some hypotheses place these archosaurs as the sister-group to dinosaurs, others suggest that “silesaurids” are early ornithischian dinosaurs. Despite the phylogenetic disputes, “silesaurids” are a crucial group for comprehending the origins and early evolution of dinosaurs. In the present study, a new “silesaurid” from the Middle-Upper Triassic of Southern Brazil is described. Gondwanax paraisensis gen. et sp. nov. comes from the Dinodontosaurus Assemblage Zone of the Santa Maria Formation (Ladinian-Carnian boundary), representing one of the oldest “silesaurids” worldwide. Furthermore, Gondwanax paraisensis gen. et sp. nov is the oldest “silesaurid” with three sacral vertebrae, a feature usually observed in more derived forms. In addition, distinct from any other Triassic Pan-Aves, the new taxon bears an incipient fourth trochanter of the femur. This unique combination of features indicates a high diversity of locomotor strategies among early pan-avians. The co-occurrence of Gondwanax paraisensis gen. et sp. nov. and Gamatavus antiquus in the same Assemblage Zone represents the oldest evidence of sympatry among “silesaurids” in South America. Indeed, the unique combination of sacral and hindlimb features may suggest distinct behaviors for these species, potentially leading to niche differentiation within the same ecosystems.
近年来,有关鸟纲古龙早期进化史的研究取得了重大进展。然而,争议依然存在,尤其是关于 "硅龙类 "的系统发育地位。一些假说认为这些古龙是恐龙的姊妹群,而另一些假说则认为 "鸟龙 "是早期的鸟臀目恐龙。尽管在系统发育上存在争议,但 "硅龙类 "是了解恐龙起源和早期演化的一个重要类群。本研究描述了巴西南部中-上三叠世的一种新的 "硅龙类"。Gondwanax paraisensis gen. et sp. nov.来自圣玛丽亚地层(拉迪尼安-卡尼亚边界)的恐龙集合区,是世界上最古老的 "硅龙类 "之一。此外,新发现的 Gondwanax paraisensis gen.此外,与其他三叠纪泛有蹄类动物不同的是,这一新类群具有初生的第四股转子。这种独特的特征组合表明早期泛鸟类的运动策略具有高度的多样性。Gondwanax paraisensis gen. et sp. nov.和 Gamatavus antiquus同时出现在同一集合区,是南美洲 "硅龙类 "共生的最古老证据。事实上,骶骨和后肢特征的独特组合可能暗示了这些物种的不同行为,有可能导致它们在同一生态系统中的生态位分化。
{"title":"A new “silesaurid” from the oldest dinosauromorph-bearing beds of South America provides insights into the early evolution of bird-line archosaurs","authors":"Rodrigo Temp Müller","doi":"10.1016/j.gr.2024.09.007","DOIUrl":"10.1016/j.gr.2024.09.007","url":null,"abstract":"<div><div>Investigations regarding the early evolutionary history of bird-line archosaurs have undergone significant advancements in recent years. However, controversies remain, especially regarding the phylogenetic position of “silesaurids”. Whereas some hypotheses place these archosaurs as the sister-group to dinosaurs, others suggest that “silesaurids” are early ornithischian dinosaurs. Despite the phylogenetic disputes, “silesaurids” are a crucial group for comprehending the origins and early evolution of dinosaurs. In the present study, a new “silesaurid” from the Middle-Upper Triassic of Southern Brazil is described. <em>Gondwanax paraisensis</em> gen. et sp. nov. comes from the <em>Dinodontosaurus</em> Assemblage Zone of the Santa Maria Formation (Ladinian-Carnian boundary), representing one of the oldest “silesaurids” worldwide. Furthermore, <em>Gondwanax paraisensis</em> gen. et sp. nov is the oldest “silesaurid” with three sacral vertebrae, a feature usually observed in more derived forms. In addition, distinct from any other Triassic Pan-Aves, the new taxon bears an incipient fourth trochanter of the femur. This unique combination of features indicates a high diversity of locomotor strategies among early pan-avians. The co-occurrence of <em>Gondwanax paraisensis</em> gen. et sp. nov. and <em>Gamatavus antiquus</em> in the same Assemblage Zone represents the oldest evidence of sympatry among “silesaurids” in South America. Indeed, the unique combination of sacral and hindlimb features may suggest distinct behaviors for these species, potentially leading to niche differentiation within the same ecosystems.</div></div>","PeriodicalId":12761,"journal":{"name":"Gondwana Research","volume":"137 ","pages":"Pages 13-28"},"PeriodicalIF":7.2,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142424198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-29DOI: 10.1016/j.gr.2024.09.008
Mu Liu , Wei Yuan , Chaogang Fang , Xun Wang , Ning Tan , Mingyu Zhao , Xiangli Wang , Thomas J. Algeo , Peng Sun , Xinbin Feng , Daizhao Chen
The Darriwilian (Middle Ordovician) is marked by a striking peak of the Great Ordovician Biodiversification Event (GOBE) followed by an abrupt ∼50 % decline in invertebrate species. Understanding the ultimate driving mechanism behind this biotic turnover and its correlation with those proximate climatic-oceanic changes that directly result in elevated biotic mortality have garnered considerable attention. One hypothesis posits that oceanic redox evolution actively influenced biodiversification, and progressive expansion of marine anoxia caused the termination of this biotic event. In this study, we present sedimentological and geochemical profiles for three outcrops of different lithofacies across the Middle-Upper Ordovician transition, ranging from carbonate platform to deep-water slope-basinal facies of the Tarim and South China cratons. Mercury isotopes reveal that recurrent and spatially dynamic photic-zone euxinia (PZE) occurred in the slope-basinal facies while being absent in platform facies. Mass balance model results suggest that ∼23 % of local atmospheric Hg was sequestered in marine sediments due to elevated dissolved H2S in surface waters. This finding suggests that destabilized oceanic redox conditions developed during climatic cooling, particularly shoaling and upwelling of deep-marine euxinic waters into the photic zone, coupled with global carbon-cycle disturbances, resulted in biodiversity decline following the peak of the GOBE.
{"title":"Mercury isotope evidence for Middle Ordovician photic-zone euxinia: Implications for termination of the Great Ordovician biodiversification event","authors":"Mu Liu , Wei Yuan , Chaogang Fang , Xun Wang , Ning Tan , Mingyu Zhao , Xiangli Wang , Thomas J. Algeo , Peng Sun , Xinbin Feng , Daizhao Chen","doi":"10.1016/j.gr.2024.09.008","DOIUrl":"10.1016/j.gr.2024.09.008","url":null,"abstract":"<div><div>The Darriwilian (Middle Ordovician) is marked by a striking peak of the Great Ordovician Biodiversification Event (GOBE) followed by an abrupt ∼50 % decline in invertebrate species. Understanding the ultimate driving mechanism behind this biotic turnover and its correlation with those proximate climatic-oceanic changes that directly result in elevated biotic mortality have garnered considerable attention. One hypothesis posits that oceanic redox evolution actively influenced biodiversification, and progressive expansion of marine anoxia caused the termination of this biotic event. In this study, we present sedimentological and geochemical profiles for three outcrops of different lithofacies across the Middle-Upper Ordovician transition, ranging from carbonate platform to deep-water slope-basinal facies of the Tarim and South China cratons. Mercury isotopes reveal that recurrent and spatially dynamic photic-zone euxinia (PZE) occurred in the slope-basinal facies while being absent in platform facies. Mass balance model results suggest that ∼23 % of local atmospheric Hg was sequestered in marine sediments due to elevated dissolved H<sub>2</sub>S in surface waters. This finding suggests that destabilized oceanic redox conditions developed during climatic cooling, particularly shoaling and upwelling of deep-marine euxinic waters into the photic zone, coupled with global carbon-cycle disturbances, resulted in biodiversity decline following the peak of the GOBE.</div></div>","PeriodicalId":12761,"journal":{"name":"Gondwana Research","volume":"137 ","pages":"Pages 131-144"},"PeriodicalIF":7.2,"publicationDate":"2024-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142424207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-29DOI: 10.1016/j.gr.2024.09.009
Olev Vinn , Karma Nanglu , Mark A. Wilson , Mare Isakar , Ursula Toom
The Ediacaran taxon Conotubus hemiannulatus has been discovered in the Terreneuvian blue clays of Estonia. Alongside Conotubus, Gaojiashania-like tubes are also found in these clays. These tubes are fully compressed and pyritized. The well-developed peristomes of Conotubus might have provided stability if the living worm was partially buried in the soft sea floor, suggesting that Conotubus was a sessile suspension feeder. The presence of the archaic Conotubus hemiannulatus in the Fortunian of Estonia indicates that the tube morphology of some cloudinids did not change between the Ediacaran and the Terreneuvian. The existence of these old-fashioned cloudinids in the Terreneuvian suggests either that the early Cambrian ecosystem in Baltica was not significantly different from that of the Ediacaran, or that cloudinids with organic tubes were more resilient to ecological changes than previously thought. Most Terreneuvian faunas originate from lower latitudes, whereas Baltica, during the Terreneuvian, was located at middle-high latitudes and experienced a cold climate. We hypothesize that the cold climate zone ecosystem was more archaic in the Fortunian than the tropical ecosystem, providing a final refuge for the Ediacaran non-mineralized tubicolous organisms. The increased competition pressure from diverse modern animals in the tropics could have driven Ediacaran-type non-mineralized tubicolous organisms to seek refuge in the colder regions of the ocean, where the competition from more advanced animals was less intense.
{"title":"Ediacaran-type non-mineralized tube-dwelling organisms persisted into the early Cambrian (Terreneuvian) in Baltica","authors":"Olev Vinn , Karma Nanglu , Mark A. Wilson , Mare Isakar , Ursula Toom","doi":"10.1016/j.gr.2024.09.009","DOIUrl":"10.1016/j.gr.2024.09.009","url":null,"abstract":"<div><div>The Ediacaran taxon <em>Conotubus hemiannulatus</em> has been discovered in the Terreneuvian blue clays of Estonia. Alongside <em>Conotubus</em>, <em>Gaojiashania</em>-like tubes are also found in these clays. These tubes are fully compressed and pyritized. The well-developed peristomes of <em>Conotubus</em> might have provided stability if the living worm was partially buried in the soft sea floor, suggesting that <em>Conotubus</em> was a sessile suspension feeder. The presence of the archaic <em>Conotubus hemiannulatus</em> in the Fortunian of Estonia indicates that the tube morphology of some cloudinids did not change between the Ediacaran and the Terreneuvian. The existence of these old-fashioned cloudinids in the Terreneuvian suggests either that the early Cambrian ecosystem in Baltica was not significantly different from that of the Ediacaran, or that cloudinids with organic tubes were more resilient to ecological changes than previously thought. Most Terreneuvian faunas originate from lower latitudes, whereas Baltica, during the Terreneuvian, was located at middle-high latitudes and experienced a cold climate. We hypothesize that the cold climate zone ecosystem was more archaic in the Fortunian than the tropical ecosystem, providing a final refuge for the Ediacaran non-mineralized tubicolous organisms. The increased competition pressure from diverse modern animals in the tropics could have driven Ediacaran-type non-mineralized tubicolous organisms to seek refuge in the colder regions of the ocean, where the competition from more advanced animals was less intense.</div></div>","PeriodicalId":12761,"journal":{"name":"Gondwana Research","volume":"137 ","pages":"Pages 29-35"},"PeriodicalIF":7.2,"publicationDate":"2024-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142424199","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-26DOI: 10.1016/j.gr.2024.09.004
Ana Mantilla-Dulcey , Paul Goyes-Peñafiel , Rosana Báez-Rodríguez , Sait Khurama
Mineral prospectivity mapping is crucial for identifying areas with economically valuable minerals. Therefore, several methods based on machine learning have been applied to predict the likelihood of mineral occurrences, especially deep learning (DL), which provides a flexible and precise approach to the use of continuous data. It allows the approximation of predictive variables with probability values related to new ore targets. However, in the early stages of mineral exploration, DL-based methods face a challenge related to class and sampling imbalance due to scarce mineral deposits, resulting in a lack of enough samples to train, limiting the model’s predictive ability. This work proposed a detailed and systematic framework to address imbalanced data issues with prior geological transfer learning and a weighted loss function. We exploited the abundant pixel information of input variables to develop a pretext geological classification and a feature data extraction task as an initializer for the trainable variables of the neural network. The proposed workflow was tested in a porphyry-rich Yukon (Canada) region and overperformed other state-of-the-art classification algorithms such as random forest, support vector machines, and logistic regression. Moreover, our results were contrasted against different geological reports, where our mineral prospectivity map was coherent with regional and local potential assessments of porphyry-type mineral occurrences. The quantitative metrics with a validation dataset suggested that the proposed method can effectively predict mineral prospective areas in different imbalanced data scenarios.
{"title":"Porphyry-type mineral prospectivity mapping with imbalanced data via prior geological transfer learning","authors":"Ana Mantilla-Dulcey , Paul Goyes-Peñafiel , Rosana Báez-Rodríguez , Sait Khurama","doi":"10.1016/j.gr.2024.09.004","DOIUrl":"10.1016/j.gr.2024.09.004","url":null,"abstract":"<div><div>Mineral prospectivity mapping is crucial for identifying areas with economically valuable minerals. Therefore, several methods based on machine learning have been applied to predict the likelihood of mineral occurrences, especially deep learning (DL), which provides a flexible and precise approach to the use of continuous data. It allows the approximation of predictive variables with probability values related to new ore targets. However, in the early stages of mineral exploration, DL-based methods face a challenge related to class and sampling imbalance due to scarce mineral deposits, resulting in a lack of enough samples to train, limiting the model’s predictive ability. This work proposed a detailed and systematic framework to address imbalanced data issues with prior geological transfer learning and a weighted loss function. We exploited the abundant pixel information of input variables to develop a pretext geological classification and a feature data extraction task as an initializer for the trainable variables of the neural network. The proposed workflow was tested in a porphyry-rich Yukon (Canada) region and overperformed other state-of-the-art classification algorithms such as random forest, support vector machines, and logistic regression. Moreover, our results were contrasted against different geological reports, where our mineral prospectivity map was coherent with regional and local potential assessments of porphyry-type mineral occurrences. The quantitative metrics with a validation dataset suggested that the proposed method can effectively predict mineral prospective areas in different imbalanced data scenarios.</div></div>","PeriodicalId":12761,"journal":{"name":"Gondwana Research","volume":"136 ","pages":"Pages 236-250"},"PeriodicalIF":7.2,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142425311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-26DOI: 10.1016/j.gr.2024.09.005
Thomas De Keyser , Wolfgang Ruebsam , Moujahed Al-Husseini , Sandra Crespo de Cabrera , Ghaida Al-Sahlan
The Early and Middle Jurassic Marrat Formation in Kuwait was deposited along the southwestern margin of the Neo-Tethys Ocean. The formation has been extensively cored and sampled in deep wells by Kuwait Oil Company for sedimentological and biostratigraphic analyses. Based on mainly long-ranging benthic species, the Middle Marrat Member is assigned in published articles to the Toarcian Stage. The formation has also been sampled for stable carbon and oxygen isotopic analyses in 19 wells across a depositional profile extending from sabkha to intrashelf basin. Stable carbon isotope analyses from these wells (∼2000 samples) reveal the signature of the negative Pliensbachian-Toarcian carbon-isotope excursion (Pl-T-CIE) in the uppermost part of the Lower Marrat Member. The younger early Toarcian carbon-isotope excursion (T-CIE) is recognized in the lower part of the Middle Marrat Member. A composite δ13Ccarb curve spanning the Middle Marrat Member is constructed by combining overlapping δ13C segments from six wells guided by correlations of regional sequence boundaries and gamma-ray logs. Cyclostratigraphic analyses of gamma-ray logs in these six wells reveal a periodic signal formed by multiples of the 0.405-Ma long-eccentricity cycle. This result suggests the Middle Marrat Member in Kuwait may represent the complete Toarcian Stage consisting of depositional sequences controlled by sea-level cycles with durations ranging between 0.8 and 1.6 Ma. Correlations of the Toarcian succession between Kuwait, Saudi Arabia and Oman are hampered by imprecise biostratigraphic control. This limitation is bypassed by correlating the T-CIE in Kuwait to published δ13C records in the Marrat Formation in central Saudi Arabia and the Mafraq Formation in Wadi Sahtan in Oman. The correlations indicate that whereas the Toarcian Stage is apparently complete in Kuwait, most of the middle and upper Toarcian and the Aalenian are absent in Oman and Saudi Arabia.
{"title":"Carbon-isotope stratigraphy of the Toarcian in Kuwait","authors":"Thomas De Keyser , Wolfgang Ruebsam , Moujahed Al-Husseini , Sandra Crespo de Cabrera , Ghaida Al-Sahlan","doi":"10.1016/j.gr.2024.09.005","DOIUrl":"10.1016/j.gr.2024.09.005","url":null,"abstract":"<div><div>The Early and Middle Jurassic Marrat Formation in Kuwait was deposited along the southwestern margin of the Neo-Tethys Ocean. The formation has been extensively cored and sampled in deep wells by Kuwait Oil Company for sedimentological and biostratigraphic analyses. Based on mainly long-ranging benthic species, the Middle Marrat Member is assigned in published articles to the Toarcian Stage. The formation has also been sampled for stable carbon and oxygen isotopic analyses in 19 wells across a depositional profile extending from sabkha to intrashelf basin. Stable carbon isotope analyses from these wells (∼2000 samples) reveal the signature of the negative Pliensbachian-Toarcian carbon-isotope excursion (Pl-T-CIE) in the uppermost part of the Lower Marrat Member. The younger early Toarcian carbon-isotope excursion (T-CIE) is recognized in the lower part of the Middle Marrat Member. A composite δ<sup>13</sup>C<sub>carb</sub> curve spanning the Middle Marrat Member is constructed by combining overlapping δ<sup>13</sup>C segments from six wells guided by correlations of regional sequence boundaries and gamma-ray logs. Cyclostratigraphic analyses of gamma-ray logs in these six wells reveal a periodic signal formed by multiples of the 0.405-Ma long-eccentricity cycle. This result suggests the Middle Marrat Member in Kuwait may represent the complete Toarcian Stage consisting of depositional sequences controlled by sea-level cycles with durations ranging between 0.8 and 1.6 Ma. Correlations of the Toarcian succession between Kuwait, Saudi Arabia and Oman are hampered by imprecise biostratigraphic control. This limitation is bypassed by correlating the T-CIE in Kuwait to published δ<sup>13</sup>C records in the Marrat Formation in central Saudi Arabia and the Mafraq Formation in Wadi Sahtan in Oman. The correlations indicate that whereas the Toarcian Stage is apparently complete in Kuwait, most of the middle and upper Toarcian and the Aalenian are absent in Oman and Saudi Arabia.</div></div>","PeriodicalId":12761,"journal":{"name":"Gondwana Research","volume":"137 ","pages":"Pages 209-226"},"PeriodicalIF":7.2,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142424306","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-26DOI: 10.1016/j.gr.2024.09.003
Xiaoqian Liu , Javier Cifuentes-Faura , Shikuan Zhao , Long Wang , Jian Yao
Artificial intelligence (AI), as a new technology, not only revolutionizes economic development, but also provides an opportunity for environment governance. Extant studies primarily explore the environmental performance of AI from a macro perspective, while evidence on how AI technology applications affect firms’ energy-saving behavior is scarce. Employing Python technology to recognize AI-related keywords in the annual reports of listed enterprises and adopting data on corporate energy consumption from 2011 to 2020, we explore the impact of AI on corporate energy consumption intensity (CECI) and its mechanisms. We observe that AI technology applications reduce CECI. After a range of robustness tests, the conclusions are still solid. The mechanism analysis reveals that AI cuts CECI through spurring firm green innovation, stimulating firms to introduce new equipment, and reducing firms’ internal management costs. Heterogeneity analysis reveals that this negative impact is more prominent for SOEs and private enterprises’ energy intensity; we also find that this effect is more pronounced for high-tech industry enterprises and high-polluting enterprises. Our findings provide micro evidence for policymakers to reduce corporate energy intensity and realize energy conservation and emission abatement targets.
{"title":"Impact of artificial intelligence technology applications on corporate energy consumption intensity","authors":"Xiaoqian Liu , Javier Cifuentes-Faura , Shikuan Zhao , Long Wang , Jian Yao","doi":"10.1016/j.gr.2024.09.003","DOIUrl":"10.1016/j.gr.2024.09.003","url":null,"abstract":"<div><div>Artificial intelligence (AI), as a new technology, not only revolutionizes economic development, but also provides an opportunity for environment governance. Extant studies primarily explore the environmental performance of AI from a macro perspective, while evidence on how AI technology applications affect firms’ energy-saving behavior is scarce. Employing Python technology to recognize AI-related keywords in the annual reports of listed enterprises and adopting data on corporate energy consumption from 2011 to 2020, we explore the impact of AI on corporate energy consumption intensity (CECI) and its mechanisms. We observe that AI technology applications reduce CECI. After a range of robustness tests, the conclusions are still solid. The mechanism analysis reveals that AI cuts CECI through spurring firm green innovation, stimulating firms to introduce new equipment, and reducing firms’ internal management costs. Heterogeneity analysis reveals that this negative impact is more prominent for SOEs and private enterprises’ energy intensity; we also find that this effect is more pronounced for high-tech industry enterprises and high-polluting enterprises. Our findings provide micro evidence for policymakers to reduce corporate energy intensity and realize energy conservation and emission abatement targets.</div></div>","PeriodicalId":12761,"journal":{"name":"Gondwana Research","volume":"138 ","pages":"Pages 89-103"},"PeriodicalIF":7.2,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142658921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}