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Dimensioning of an Anaerobic Digester for the Treatment of Chicken Manure and for the Production of Biogas: The Case Study of a Chicken Farm in Yaokokoroko (Côte d’Ivoire) 用于处理鸡粪和生产沼气的厌氧沼气池的尺寸:以yokokoroko的一个养鸡场为例(Cô科特迪瓦)
Pub Date : 2022-01-01 DOI: 10.4236/gsc.2022.124008
Kouakou Adjoumani Rodrigue, Ehouman Ahissan Donatien, Konan Affoué Tindo Sylvie, Teki Adjoba Marie-Emmanuelle, Kouadio Marc Cyril, A. Eric, Konan Gbangbo Remis
This study allowed us to highlight the level of pollution of a BAYA River water near several poultry farms and the sizing of an anaerobic digester that will be able to treat chicken manure from a poultry farm (BRIN FOUNDATION). To evaluate this pollution, the parameters such as ammonium ( 4 NH + ), Phosphate ( 34 PO − ), Biochemical Oxygen Demand (DBO 5 ) and Nitrate ( digester with a capacity of 10 m 3 .
这项研究使我们能够突出几个家禽养殖场附近的BAYA河水的污染水平,以及能够处理家禽养殖场鸡粪的厌氧沼气池的大小(BRIN基金会)。为了评价这一污染,采用了氨(4 NH +)、磷酸盐(34 PO−)、生化需氧量(DBO 5)和硝酸盐(容量为10 m3)等参数。
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引用次数: 1
Efficiency of Crude α-Cyclodextrin in Gold Recovery from Electronic Waste and Soil 粗α-环糊精在电子废弃物和土壤中回收金的效果
Pub Date : 2022-01-01 DOI: 10.4236/gsc.2022.123006
I. Karume, S. Tewolde, E. Tebandeke, Is’harq Z. T. Mukasa, Ruth Mbabazi
In this study, the metal coordination ability of alpha-cyclodextrin (α-CD) was employed to complex gold and thus isolate and extract it from different matrices of acid-digests of electronic waste and soil. The crude α-CD used was extracted from cassava and yam starch of the non-edible plant species using E. coli α-cyclodextrin glucanotransferase (α-CGTase), with yields ≥ 62%. The reaction was monitored progressively by ultraviolet-visible spectroscopy and checked with infrared spectroscopy (IR) for the presence of α-CD. The crude α-CD extract without need for purification was refluxed with gold contain-ing-electronic waste and soil predigested in a mixture of NaBr/HNO 3 for 4 - 7 days. Recoveries of up to 22.9% and 70.8% gold were achieved from electronic waste and soil, respectively using 0.1 M α-CD. This approach is cheap, ef-fective, and environmentally benign.
本研究利用α-环糊精(α-CD)的金属配位能力来络合金,从而从不同基质的电子废弃物和土壤酸消化物中分离提取金。采用大肠杆菌α-环糊精葡聚糖转移酶(α-CGTase)从木薯和山药的非食用植物淀粉中提取粗α-CD,产率≥62%。用紫外-可见光谱逐步监测反应,并用红外光谱(IR)检测α-CD的存在。将不需要提纯的α-CD粗提物与含金电子废弃物和在NaBr/ hno3混合物中预消化的土壤一起回流4 ~ 7天。在0.1 M α-CD条件下,从电子废弃物和土壤中金的回收率分别高达22.9%和70.8%。这种方法廉价、有效,而且对环境无害。
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引用次数: 1
Full Scale SBR Municipal Wastewater Treatment Facility Utilization of Simultaneous Nitrification/Denitrification Coupled with Traditional Nitrogen Removal to Meet Water Criterion 利用同步硝化/反硝化与传统脱氮相结合的全规模SBR城市污水处理设施达到水标准
Pub Date : 2022-01-01 DOI: 10.4236/gsc.2022.122004
Charles L Martin Jr., Clayton J. Clark II
Simultaneous nitrification denitrification (SND) is a well-established phenomenon in biological nutrient removal activated sludge systems. Study at a municipal wastewater treatment facility sought to determine nitrogen removal effectiveness within a full-scale sequential batch reactor (SBR) system utilizing SND in conjunction with traditional nitrogen removal. In addition to characterizing extent of SND, the research examined the ability of SND to meet state-based effluent water quality standards. At the selected facility, the average SND efficiency during a two-month sampling period was 52.8%, par-alleling results from similar SBR municipal wastewater systems. The observed SBR system had removal efficiencies > 99% for the influent to effluent 4 NH + -N concentrations. The SND process also resulted in average NO 3 -NO 2 -N concentration that was 82% lower than the theoretical concentration under comparable circumstances. Overall, nitrogen removal for this SBR system was >99% which typified results in other SND systems, but at a higher Total Nitrogen removal rate.
同步硝化反硝化(SND)是生物去除活性污泥系统中一个公认的现象。在城市污水处理设施中进行的一项研究,旨在确定利用SND与传统脱氮相结合的全尺寸顺序间歇反应器(SBR)系统的脱氮效果。除了表征SND的程度外,该研究还考察了SND满足国家污水水质标准的能力。在选定的设施中,在两个月的采样期间,SND的平均效率为52.8%,与类似的SBR市政污水系统的结果相当。SBR系统对进水至出水nh4 + -N的去除率> 99%。SND过程还导致no3 - no2 -N的平均浓度比可比条件下的理论浓度低82%。总体而言,该SBR系统的氮去除率>99%,与其他SND系统的结果相同,但总氮去除率更高。
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引用次数: 1
The Compatibility of Groups Used to Protect Phenolic Functionality during Oxone-Mediated Oxidative Esterification 在酮介导的氧化酯化过程中用于保护酚功能的基团的相容性
Pub Date : 2022-01-01 DOI: 10.4236/gsc.2022.124007
T. Mineno, Yukizi Suzuki, Tomoya Nobuta, Daiki Takano, Hisao Kansui
Protecting groups often play an essential role in organic synthesis, particularly for multi-step synthesis or natural product total synthesis. Various protecting groups areavailable to mask the vulnerable functionality; phenolic hydroxy groups are noteworthy examples, but their stability differs when protected. Herein, the compatibility of protective phenolic functionality was investigated with the implementation of indium (III) triflate-catalyzed oxidative esterification using Oxone in methanol. A wide range of protective moieties was selected and subjected to Oxone-mediated oxidative esterification. For example, sulfonates were found to be sufficiently stable and inert whereas acetals were susceptible to reaction conditions. The details of this investigation are pro-vided.
保护基团在有机合成中起着重要的作用,特别是在多步合成或天然产物全合成中。各种保护组可用于掩盖易受攻击的功能;酚羟基是值得注意的例子,但它们的稳定性在保护时不同。本文研究了保护酚醛官能团与三氟化铟催化氧化酯化反应的相容性。广泛的保护基团被选择并受到氧酮介导的氧化酯化反应。例如,磺酸盐被发现是足够稳定和惰性的,而缩醛则易受反应条件的影响。提供了这项调查的细节。
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引用次数: 1
Recovery of Biomass Incinerated as Struvite-K Precipitates Followed Aluminium Removal 除铝后生物质焚烧鸟粪石- k沉淀的回收
Pub Date : 2021-07-30 DOI: 10.4236/gsc.2021.113009
E. Hidayat, Hadi Imran A. Halem, Y. Mitoma, H. Harada
Phosphorus (P) and potassium (K) are non-renewable materials and widely in many industries such as agricultural sectors. On the other hand, the demand of P and K as fertilizers increases which following global population. The nutrient source of P and K which get from biomass waste i.e. incinerated of activated sludge and coffee husk biochar, respectively. The present study was conducted recovery of P and K as struvite-K (KMgPO4·6H2O) precipitates. The results showed that aluminium was released simultaneously with P from incinerated activated sludge with precipitate of Al:P of 1:1, K:P of 0.5, and Mg:P of 3. However, aluminium was inhibited to form struvite-K. Then, we examined cation removal especially for removed Al by dissolved 0.5 M HNO3 and the solution was mixed with KH2PO4 and MgCl2·6H2O as source of K and Mg, respectively. The results showed aluminium (Al) was removed with precipitate K:P of 0.5, and Mg:P of 0.8. This study was confirmed that recovery of biomass incinerated was successful as struvite-K and can be used as fertilizers.
磷(P)和钾(K)是不可再生材料,广泛应用于许多工业,如农业部门。另一方面,随着全球人口的增加,作为肥料的磷和钾的需求也在增加。磷和钾的营养源分别来自生物质废弃物,即焚烧后的活性污泥和咖啡壳生物炭。本研究以鸟粪石-K (KMgPO4·6H2O)沉淀的形式回收P和K。结果表明:在Al:P为1:1,K:P为0.5,Mg:P为3的条件下,焚烧活性污泥中铝与磷同时释放;然而,铝被抑制形成鸟粪石- k。然后,我们研究了溶解0.5 M HNO3,并分别以KH2PO4和MgCl2·6H2O为K和Mg源的溶液对阳离子的去除,特别是对去除Al的去除。结果表明,铝(Al)的去除率为沉淀K:P为0.5,Mg:P为0.8。本研究证实焚烧后的生物质可成功回收为鸟粪钾,可作为肥料使用。
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引用次数: 1
A Field Survey to Assess the Consumption of Nkang for Standardization and Valorization in the North-West Region of Cameroon 对喀麦隆西北地区Nkang的标准化和定价消费进行实地调查
Pub Date : 2021-07-30 DOI: 10.4236/gsc.2021.113010
Acha Anna Afek, D. Carly, N. E. Jong
In African communities, traditional beer drinking remains a unifying factor within its populations both socially, commercially, culturally, politically, in health and nutrition and for some ritual practices. In this research a field survey was carried out to investigate the consumption of corn beer and in particular Nkang in the North-West Region of Cameroon. The tools that were employed to carry out these investigations included face-to-face interviews and the use of properly designed questionnaires. Results from the survey showed that three types of maize-based beverages are drunk in the North-West Region of Cameroon, which are locally called Kwacha (whitish, most viscous and most turbid), Sha-ah (cream white, viscous and turbid) and Nkang (dark brown, least viscous and least turbid) in terms of colour, viscosity and turbidity. The percentage awareness of the existence of these beers from the sampled population gave the following values; 60.9% for Kwacha, 100% for Sha-ah and 89.1% for Nkang. Nonetheless, 54.5% of the 60.9% of those who were aware of the existence of kwacha had at least tasted it. Also 98.2% out of the 100% for Sha-ah and 85.5% out of 89.1% for Nkang had tasted them, too. Nkang was found to be the most preferred to Sha-ah then Kwacha in that order by the consumers since Nkang is very tasteful, least alcoholic, least turbid, least viscous, has the most attractive colour than the others, has a significant impact on the culture of some localities in this region and as well as it is natural and nutritious. However, Nkang as well as the other two has varying organoleptic properties, unsatisfactory conservation and short shelf-life. Hence are consumed within a short period of time from their production. Because of the low alcoholic content of Nkang, the beverage is consumed by both adults (most elderly), children, those who have health problems and it is mostly preferred by some Christians though not frequently seen in the markets. It was equally observed that the little quantity of Nkang found in the markets is of poor quality which keeps dropping everyday thus an indication of its risk becoming extinct. Therefore, if Nkang is clarified and its quality improved, the problems can be solved as even attested by the consumers who say they will buy at even a higher price if clarify. As well as those who want it for their cultural reasons do not want it to face out too.
在非洲社区,传统的啤酒饮用仍然是其人口在社会、商业、文化、政治、健康和营养以及一些仪式习俗方面的一个统一因素。在这项研究中,进行了实地调查,以调查玉米啤酒的消费情况,特别是喀麦隆西北地区的Nkang啤酒。进行这些调查所采用的工具包括面对面访谈和使用设计合理的问卷。调查结果显示,喀麦隆西北地区饮用三种玉米饮料,当地称其为Kwacha(白色,最粘稠和最浑浊),Sha-ah(奶油白色,粘稠和浑浊)和Nkang(深棕色,最粘稠和最浑浊),其颜色,粘度和浑浊度。从抽样人群中知道这些啤酒存在的百分比给出了以下值;Kwacha为60.9%,shaah为100%,Nkang为89.1%。尽管如此,在60.9%知道克瓦查存在的人中,有54.5%至少尝过它。在100%的“沙阿”中98.2%的人尝过,在89.1%的“恩康”中85.5%的人尝过。消费者发现Nkang比Sha-ah和Kwacha更受欢迎,因为Nkang非常有品味,酒精含量最低,浑浊度最低,粘稠度最低,颜色最吸引人,对该地区一些地方的文化有重大影响,而且它是天然和营养丰富的。然而,Nkang和其他两种具有不同的感官特性,保存不理想,保质期短。因此,它们在生产后的短时间内就被消耗掉了。由于Nkang的酒精含量很低,成年人(大多数是老年人)、儿童、有健康问题的人都饮用这种饮料,一些基督徒更喜欢这种饮料,尽管在市场上并不常见。人们还注意到,在市场上发现的少量Nkang质量很差,每天都在下降,因此表明它有灭绝的危险。因此,如果对Nkang进行澄清,提高其质量,就可以解决问题,甚至消费者也证明,如果澄清,他们会以更高的价格购买。而那些出于文化原因想要它的人也不希望它正面朝外。
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引用次数: 1
Bismuth (III) Chloride Catalyzed Multicomponent Synthesis of Substituted Hexahydroimidazo[1, 2-a]Pyridines 氯化铋催化多组分合成取代六氢咪唑[1,2 -a]吡啶
Pub Date : 2021-07-30 DOI: 10.4236/gsc.2021.113008
Noah Haskin, Richard A. Guingrich, Allison J. Schrader, Matthew R. Crosse, A. Dave, Eeshwaraiah Begari, R. Mohan
The synthesis of nitrogen containing heterocycles is of particular interest in the pharmaceutical industry due to the range of biological activities exhibited by such compounds. Their synthesis using multicomponent reactions saves steps and minimizes waste generation. The bismuth (III) chloride multicomponent synthesis of a series of hexahydroimidazo[1, 2-a]pyridines is reported. Bismuth (III) compounds are especially attractive from a green chemistry perspective because they are remarkably nontoxic, non-corrosive and relatively inexpensive. The reported method avoids chromatography and an aqueous waste stream to afford the products in a very mass efficient manner.
含氮杂环化合物的合成是制药工业特别感兴趣的,因为这种化合物具有广泛的生物活性。它们的合成使用多组分反应,节省了步骤,并最大限度地减少了废物的产生。报道了一系列六氢咪唑[1,2 -a]吡啶的氯化铋多组分合成。从绿色化学的角度来看,铋(III)化合物尤其具有吸引力,因为它们具有显著的无毒、无腐蚀性和相对便宜的特点。所报道的方法避免了色谱和水废物流,以非常有效的质量方式提供产品。
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引用次数: 1
Current trends in green sample preparation prior to liquid chromatographic bioanalysis 液相色谱生物分析前绿色样品制备的当前趋势
Pub Date : 2021-04-01 DOI: 10.1016/J.COGSC.2021.100499
V. Alampanos, V. Samanidou
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引用次数: 12
Evaluation of Plantain Biomass (Musa paradisiaca L.), as Feedstock for Bio-Ethanol Production 车前草生物质作为生物乙醇原料的评价
Pub Date : 2021-03-29 DOI: 10.4236/GSC.2021.112006
H. O. Ogunsuyi, Christiana Aanu Olawale
This study investigated the viability of post-harvested plantain biomass as a promising feedstock for the production of Bioethanol. The properties of the derived bio-ethanol were determined to examine its suitability as a promising and sustainable alternative to petroleum-based ethanol The research revealed that Plantain biomass is made up of Lignocellulosic contents such as extractive, Lignin, cellulose, hemicelluloses, ash and moisture in different proportions. The different parts of the biomass such as the flower, stem and leaves were hydrolyzed using H2SO4. Optimum hydrolysis conditions of 6%w/v acid concentration, 30 min contact time and 80°C working temperature were established for Plantain stem and flower. However, hydrolysis of Plantain leaves was at the best under the experimental conditions of acid concentration (10% w/v), contact time (120 min) and temperature (120°C). The highest yield of the bio-ethanol produced was obtained from Plantain stem biomass with a record of 8.04% followed by Plantain flower with a yield of 7.73% and 757% from Plantain leaves The hydrolyzate was fermented using Baker’s yeast (Saccharomyces cerevisiae) at a room temperature of 25°C and pH of 4.5 for 4 D. The structural determination of the derived bioethanol was conducted using FT-IR analysis and the fuel properties were found to be consistent with those of the conventional ethanol. The SEM analysis conducted on the post hydrolysed biomass confirmed the effectiveness of the hydrolysis scheme adopted as evident on the surface morphology of the biomass. This study confirmed the viability of Plantain biomass as promising feedstock for Bio-ethanol production under the established hydrolysis conditions.
本研究探讨了收获后车前草生物量作为生产生物乙醇的有前途的原料的可行性。研究表明,车前草生物质由不同比例的提取物、木质素、纤维素、半纤维素、灰分和水分等木质纤维素成分组成。利用H2SO4对花、茎、叶等生物质的不同部位进行水解。确定了车前草茎和花的最佳水解条件为6%w/v的酸浓度、30 min的接触时间和80℃的工作温度。而在酸浓度(10% w/v)、接触时间(120 min)和温度(120℃)的实验条件下,车前草叶的水解效果最好。获得最高产量生产的生物乙醇从车前草茎生物量创纪录的8.04%,其次是车前草花从车前草的叶子与收益率为7.73%和757%的水解产物利用面包酵母发酵(酿酒酵母)的室温25°C和pH值为4.5 4 d的结构确定衍生生物乙醇进行使用傅立叶变换红外光谱分析和燃料特性被发现是一致的与传统乙醇。对水解后的生物质进行的SEM分析证实了所采用的水解方案的有效性,从生物质的表面形貌上可以看出。本研究证实了车前草生物质在既定的水解条件下作为生物乙醇生产原料的可行性。
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引用次数: 0
Use of Cucurbita pepo Oil to Fight against the UV Action on the Skin 使用瓜籽油对抗紫外线对皮肤的作用
Pub Date : 2021-03-11 DOI: 10.4236/GSC.2021.112005
A. Nakavoua, Guy Crépin Enoua, Stéphanie Manhan-Iniangas, P. Chalard, G. Figuérédo
Skin aging is a process most often attributed to UV [1] and also to the use of creams and other cosmetic products low in antioxidant compounds [2]. Photochemically stable pepo Cucurbita oil can be used as an exogenous cosmetic supplement due to its high antioxidant content. Incorporated in an agar, media containing a synthetic melanin solution with added pumpkin oil are subjected to UV light, the aging thus modeled is followed by the measurement of photoresistance values correlated with chemical and spectrophotometric analyses. This study confirms that pumpkin oil is highly effective in protecting the skin, especially the most sensitive skins such as babies’ skin [3] by reinforcing the action of melanin and also that of albinos without melanin. Indeed its SPF (Significant Sun Protection Factor) index estimated during this work is very consistent, i.e. more than 22% of UVB (280 - 315 nm) radiations are suppressed.
皮肤老化是一个通常归因于紫外线的过程[1],也归因于使用低抗氧化化合物的面霜和其他化妆品[2]。光化学稳定的瓜油因其抗氧化剂含量高,可作为外源性化妆品补充剂。将加入南瓜油的合成黑色素溶液放入琼脂中,在紫外光下进行老化模拟,然后测量与化学和分光光度分析相关的光阻值。本研究证实,南瓜油具有非常有效的保护皮肤,特别是最敏感的皮肤,如婴儿皮肤[3],可以增强黑色素的作用,也可以增强无黑色素的白化皮肤的作用。事实上,在这项工作中估计的SPF(显著防晒系数)指数非常一致,即超过22%的UVB (280 - 315 nm)辐射被抑制。
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引用次数: 1
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Green and Sustainable Chemistry
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