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Passive Remediation of Acid Mine Drainage Using Ball-Milling Modified Indonesian Natural Bentonite: Laboratory Batch and Column Sorption of Manganese 球磨改性印尼天然膨润土对酸性矿山废水的被动修复:实验室批式和柱式锰吸附
Pub Date : 2018-10-10 DOI: 10.4236/gsc.2018.84020
Widyawanto Prastistho, W. Kurniawan, H. Hinode
Manganese (Mn) is an essential element for human body. However, elevated concentration of manganese causes severe problem and disease. Acid mine drainage (AMD), wastewater generated due to open-pit mining, commonly contains Mn with exceeded concentration. This study is to investigate the improvement of ball-milling modified Indonesian natural bentonite (INB) for manganese (Mn) removal from AMD and to increase the pH through batch and column sorption test as a passive treatment system approach. The batch sorption test result showed the maximum Mn adsorbed (Qm) on INB from the Langmuir model increased from 4.69 to 17.12 mg/g after milling. The column sorption test result also showed the amount of Mn adsorbed on INB until breakthrough time (qu) and until saturation time (q) increased after milling. The qu increased from 1.27 to 10.06 mg/g, and the q increased from 4.55 to 12.91 mg/g. The mass transfer zone (MTZ) became significantly shorter after milling from 0.22 to 0.07 cm. The Thomas model exhibited the equilibrium uptake of Mn (q0) increased after milling from 3.91 to 13.72 mg/g. In equilibrium condition, both unmilled and milled INB showed the pH increased from ≈3 to 8.
锰(Mn)是人体必需的元素。然而,锰浓度升高会导致严重的问题和疾病。露天开采产生的酸性矿山水(AMD)中,锰含量普遍超标。本研究旨在研究球磨改性印尼天然膨润土(INB)对AMD中锰(Mn)的去除效果,并通过间歇和柱式吸附试验提高pH值作为被动处理体系。批量吸附试验结果表明,磨矿后Langmuir模型INB的最大Mn吸附量(Qm)由4.69 mg/g增加到17.12 mg/g。柱吸附试验结果还表明,磨矿后,INB在突破时间(qu)和饱和时间(q)前的Mn吸附量均有所增加。qu从1.27 mg/g增加到10.06 mg/g, q从4.55 mg/g增加到12.91 mg/g。制粒后的传质区(MTZ)由0.22 cm显著缩短至0.07 cm。Thomas模型显示,磨粉后的平衡Mn (q0)吸收量从3.91 mg/g增加到13.72 mg/g。在平衡条件下,未磨和磨后的INB的pH均从≈3增加到8。
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引用次数: 2
A Mild and Efficient Method for the Synthesis of Acylals from Aromatic Aldehydes and Their Deprotections Catalyzed by Synthetic Phosphates under Solvent-Free Conditions 一种在无溶剂条件下由芳香醛合成酰基的温和高效方法及其在合成磷酸盐催化下的脱保护反应
Pub Date : 2018-10-09 DOI: 10.4236/gsc.2018.84023
F. Bazi, B. Mounir, M. Hamza, S. Sebti
An efficient and clean preparation of acylals from aromatic aldehydes in the presence of synthetic phosphates (flourapatite and hydroxyapatite doped with ZnCl2 and ZnBr2) and acetic anhydride was achieved easily in high yields (86% - 97%) at room temperature under solvent-free conditions. Deprotection of the resulting acylals has also been attained by using the same catalysts under microwave irradiation. This method consistently has advantage of excellent yields (82% - 96%) and a short reaction time (3 - 4 min).
在无溶剂的室温条件下,在合成磷酸盐(掺杂ZnCl2和ZnBr2的氟磷灰石和羟基磷灰石)和乙酸酐的存在下,以芳香醛为原料制备了高效、清洁的酰基化合物,收率高达86% ~ 97%。用相同的催化剂在微波照射下也实现了对所得酰基的脱保护。该方法具有收率高(82% ~ 96%)、反应时间短(3 ~ 4 min)等优点。
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引用次数: 1
Biochemical Methane Potential of Food Wastes from Akouedo Landfill, Côte d’Ivoire Akouedo垃圾填埋场食物垃圾的生化甲烷潜力,Côte科特迪瓦
Pub Date : 2018-08-24 DOI: 10.4236/GSC.2018.83019
Kouadio Marc Cyril, Kouakou Adjoumani Rodrigue, Kra Essi, Trokourey Albert, Akichi Agboue
The determination of biochemical methane potential (BMP) is very important for the valorization of food wastes. This study is focused on the evaluation of the theoretical methane production from chemical oxygen demand (COD) of some food wastes, coming out Akouedo landfill. Almost all of the considered samples exhibited methane theoretical yields equal to about 402.5 - 507.8 mLCH4/gVS. These results indicate the suitability of all the studied food wastes from Akouedo landfill to be converted into energy.
生物化学甲烷势(BMP)的测定对食物垃圾的价值评价具有重要意义。本研究主要对来自Akouedo垃圾填埋场的部分食物垃圾的化学需氧量(COD)产甲烷理论进行了评价。几乎所有样品的甲烷理论产率都在402.5 - 507.8 mLCH4/gVS之间。这些结果表明,所研究的Akouedo垃圾填埋场的食物垃圾都适合转化为能源。
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引用次数: 2
Synthesis and Characterisation of a Biolubricant from Cameroon Palm Kernel Seed Oil Using a Locally Produced Base Catalyst from Plantain Peelings 喀麦隆棕榈仁籽油生物润滑剂的合成与表征
Pub Date : 2018-08-02 DOI: 10.4236/GSC.2018.83018
M. Alang, M. Ndikontar, Y. Sani, P. Ndifon
Biolubricant was synthesized from Cameroon palm kernel oil (PKO) by double transesterification, producing methyl esters in the first stage which were then transesterified with trimethylolpropane (TMP) to give the PKO biolubricant in the presence of a base catalyst obtained from plantain peelings (municipal waste). The yields from both catalysts were significantly similar (48% for the locally produced and 51% for the conventional) showing that the locally produced catalyst could be valorized. The synthesized biolubricant was characterized by measuring its physical and chemical properties. The specific gravity of 1.2, ASTM color of 1.5, cloud point of 0°C, pour point of -9°C, viscosities at 40°C of 509.80 cSt and at 100°C of 30.80 cSt, viscosity index of 120, flash point greater than 210°C and a fire point greater than 220°C were obtained. This synthesized biolubricant was found to be comparable to commercial T-46 petroleum lubricant sample produced industrially from mineral sources. We have therefore used local materials to produce a biolubricant using a cheap base catalyst produced from municipal waste.
以喀麦隆棕榈仁油(PKO)为原料,采用双酯交换法合成生物润滑剂,第一阶段生成甲酯,然后与三甲基丙烷(TMP)进行酯交换,得到PKO生物润滑剂,催化剂来源于车前草皮(城市垃圾)。两种催化剂的产率非常相似(本地生产的为48%,传统的为51%),这表明本地生产的催化剂可以实现增值。对合成的生物润滑剂进行了理化性质的表征。比重为1.2,ASTM颜色为1.5,浊点为0°C,倾点为-9°C, 40°C时粘度为509.80 cSt, 100°C时粘度为30.80 cSt,粘度指数为120,闪点大于210°C,燃点大于220°C。这种合成的生物润滑剂被发现可与工业上从矿物来源生产的商业T-46石油润滑剂样品相媲美。因此,我们使用当地材料生产生物润滑剂,使用从城市垃圾中提取的廉价碱性催化剂。
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引用次数: 20
A Novel Process Using Ion Exchange Resins for the Coproduction of Ethyl and Butyl Acetates 离子交换树脂协同生产乙酸乙酯和乙酸丁酯的新工艺
Pub Date : 2018-07-31 DOI: 10.4236/GSC.2018.83016
Nydia Ileana Guzman Barrera, Cecile Bories, J. Peydecastaing, C. Sablayrolles, E. Vedrenne, C. Vaca-Garcia, S. Thiebaud-Roux
Before proposing an innovative process for the coproduction of ethyl and butyl acetates, the individual syntheses of ethyl acetate and butyl acetate by two different routes were first studied. These syntheses involved the reaction of ethanol or n-butanol with acetic acid or acetic anhydride in the presence of ion exchange resins: Amberlyst 15, Amberlyst 16, Amberlyst 36 and Dowex 50WX8. Kinetic and thermodynamic studies were performed with all resins. The lowest activation energy (Ea) value was obtained with Dowex 50WX8, which was identified as the best-performing resin, able to be reused at least in four runs without regeneration. The presence of water-azeotropes during the synthesis of ethyl acetate makes its purification difficult. A new strategy was adopted here, involving the use of ethanol and acetic anhydride as the starting material. In order to minimize acetic acid as co-product of this reaction, a novel two-step process for the coproduction of ethyl and butyl acetates was developed. The first step involves the production of ethyl acetate and its purification. Butyl acetate was produced in the second step: n-butanol was added to the mixture of acetic acid and the resin remaining after the first-step distillation. This process yields ethyl acetate and butyl acetate at high purity and shows an environmental benefit over the independent syntheses by green metrics calculation and life cycle assessment.
在提出联合生产乙酸乙酯和乙酸丁酯的创新工艺之前,首先研究了两种不同路线分别合成乙酸乙酯和乙酸丁酯的方法。这些合成涉及乙醇或正丁醇与乙酸或醋酸酐在离子交换树脂存在下的反应:Amberlyst 15, Amberlyst 16, Amberlyst 36和Dowex 50WX8。对所有树脂进行了动力学和热力学研究。Dowex 50WX8的活化能(Ea)值最低,被认为是性能最好的树脂,至少可以在4次运行中重复使用而不再生。在合成乙酸乙酯的过程中,水共沸物的存在使其纯化变得困难。采用了以乙醇和乙酸酐为原料的新工艺。为了最大限度地减少醋酸作为该反应的副产物,开发了一种新的两步联产乙酸乙酯和乙酸丁酯的新工艺。第一步包括乙酸乙酯的生产和纯化。第二步生产乙酸丁酯:将正丁醇加入到第一步蒸馏后剩余的乙酸和树脂的混合物中。通过绿色指标计算和生命周期评价,该工艺可获得高纯度的乙酸乙酯和乙酸丁酯,比独立合成具有更大的环境效益。
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引用次数: 1
Functional Organo-Nano Particles by RAFT Copolymerisation RAFT共聚的功能有机纳米颗粒
Pub Date : 2018-07-31 DOI: 10.4236/gsc.2018.83017
H. Langhals, Dominik Zgela, Arthur Haffner, C. Koschnick, K. Gottschling, C. Paulik
A significant impact of this work on the use of polymers is expected because the developed organo-nano particles (ONP) mixed into standard polymers will make them unique and traceable. The doping of polymers with non migrating ONP was demonstrated and applications for the recycling of plastics were discussed. Thus, perylene derivatives were linked to polymerisable vinyl groups and copolymerized under RAFT conditions (Reversible Addition Fragmentation chain Transfer) with styrene and methylmethacrylate, respectively, to obtain fluorescent ONP with sizes of 40 nm or even less and narrow distributions of molecular weight in most cases with polydispersities PD of 1.1 and lower.
预计这项工作将对聚合物的使用产生重大影响,因为开发的有机纳米颗粒(ONP)混合到标准聚合物中,将使它们独特且可追溯。介绍了不迁移ONP在聚合物中的掺杂,并讨论了其在塑料循环利用中的应用。因此,苝衍生物与可聚合的乙烯基连接,并在RAFT(可逆加成裂解链转移)条件下分别与苯乙烯和甲基丙烯酸甲酯共聚,得到了尺寸为40 nm甚至更小的荧光ONP,大多数情况下分子量分布较窄,多分散度PD为1.1及以下。
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引用次数: 0
Sodium-Modified Fluorapatite: A Mild and Efficient Reusable Catalyst for the Synthesis of α,α’-Bis(Substituted Benzylidene) Cycloalkanones under Conventional Heating and Microwave Irradiation 钠修饰氟磷灰石:一种温和高效的可重复使用催化剂,用于常规加热和微波辐射合成α,α′-双(取代苄基)环烷酮
Pub Date : 2018-05-02 DOI: 10.4236/GSC.2018.82011
B. Mounir, F. Bazi, Abddelfetah Mounir, H. Toufik, M. Zahouily
A versatile and environmentally friendly method for α,α’-bis(substituted ben-zylidene) cycloalkanones has been developed using a heterogeneous catalysis technology. We have synthesized a series of the α,α’-bis(substituted benzylidene) cycloalkanones, a biologically important class of compounds, via the cross aldol condensation between arylaldehydes and cycloketones using sodium-modified fluorapatite (Na/FAP) as a highly efficient solid catalyst under conventional heating in aqueous media and solventless conditions under microwave. Catalyst reuse, ease of separation of the pure product, and high yields are some of the unique features of this process. Shorter reaction times (4 - 7 min) and higher yields (80% - 94%) were achieved under microwave irradiation conditions.
采用多相催化技术,开发了一种合成α,α′-双(取代苄基)环烷酮的通用、环保的方法。以钠修饰氟磷灰石(Na/FAP)为高效固体催化剂,在水介质常规加热和微波无溶剂条件下,通过芳醛和环酮之间的交叉醛缩合反应,合成了一系列具有重要生物学意义的α,α′-二(取代苄基)环烷酮。催化剂的重复使用,易于分离的纯产品,和高收率是一些独特的特点,这一过程。在微波辐照条件下,反应时间较短(4 ~ 7 min),产率较高(80% ~ 94%)。
{"title":"Sodium-Modified Fluorapatite: A Mild and Efficient Reusable Catalyst for the Synthesis of α,α’-Bis(Substituted Benzylidene) Cycloalkanones under Conventional Heating and Microwave Irradiation","authors":"B. Mounir, F. Bazi, Abddelfetah Mounir, H. Toufik, M. Zahouily","doi":"10.4236/GSC.2018.82011","DOIUrl":"https://doi.org/10.4236/GSC.2018.82011","url":null,"abstract":"A versatile and environmentally friendly method for α,α’-bis(substituted ben-zylidene) cycloalkanones has been developed using a heterogeneous catalysis technology. We have synthesized a series of the α,α’-bis(substituted benzylidene) cycloalkanones, a biologically important class of compounds, via the cross aldol condensation between arylaldehydes and cycloketones using sodium-modified fluorapatite (Na/FAP) as a highly efficient solid catalyst under conventional heating in aqueous media and solventless conditions under microwave. Catalyst reuse, ease of separation of the pure product, and high yields are some of the unique features of this process. Shorter reaction times (4 - 7 min) and higher yields (80% - 94%) were achieved under microwave irradiation conditions.","PeriodicalId":12770,"journal":{"name":"Green and Sustainable Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72547625","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Henry Reaction between Benzaldehyde and Nitromethane over Solid Base Catalysts: A Green Protocol 苯甲醛和硝基甲烷在固体碱催化剂上的亨利反应:一个绿色方案
Pub Date : 2018-05-02 DOI: 10.4236/GSC.2018.82010
M. Abdellattif, H. M. Mohamed
The development of environmentally benign solid base catalysts instead of the soluble bases for C-C bond formation in organic reactions especially Henry reactions with nitroalkanes compounds is of intense research activity in the bulk and fine chemical chemistry in order to achieve the selectivity of the desired product and the reduction of the salts formed due to soluble bases neutralization. While using of LDHs catalysts in the synthesis of nitro alcohols is of great interest because LDHs (double layered hydroxides) is of unique properties and an excellent catalytic property. The nitroalcohols are obtained in a very good yield while using catalyst either by conventional at 90°C in liquid phase, microwave or sonoenergy without solvent methods, and the results yields are compared. A series of different nitro alcohols from (a - o) were prepared, the catalytic test reaction were carried out using benzaldehyde and their derivatives with nitromethane and their derivatives. A series of LDHs catalysts were prepared also and studying of the catalytic effect on the reactions was carried out. Properties of the compounds prepared were characterized by IR, MNR, and GC-MS.
在有机反应特别是硝基烷烃类化合物的Henry反应中,为实现所需产物的选择性和减少可溶性碱中和所形成的盐,开发环境友好型固体碱催化剂代替可溶性碱形成C-C键,在大宗化学和精细化学领域的研究十分活跃。而利用双层氢氧化物催化剂合成硝基醇则因其独特的性质和优异的催化性能而备受关注。在90°C液相、微波法和无溶剂声能法的催化作用下,以很好的收率得到了硝基醇,并对收率进行了比较。以(A - o)为原料制备了一系列不同的硝基醇,并以苯甲醛及其衍生物与硝基甲烷及其衍生物进行了催化反应试验。制备了一系列LDHs催化剂,并对其催化效果进行了研究。通过IR、MNR和GC-MS对所制化合物的性质进行了表征。
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引用次数: 3
Efficient Solvent- and Catalyst-Free Syntheses of Imine Derivatives Applying the Pressure Reduction Technique: Remarkable Change of the Reaction Rate with the Phase Transition 应用减压技术无溶剂无催化剂高效合成亚胺衍生物:反应速率随相变的显著变化
Pub Date : 2018-05-02 DOI: 10.4236/gsc.2018.82012
Shoko Suzuki, S. Sakaki, S. Ishizuka, T. Nishino, Hiroyuki Ito, R. Nonaka, M. Noike, T. Kodama, Hajime Nozaka, Tsuneyuki Sato, Hitoshi Agematsu, K. Maruyama, Shun Oyamada, T. Kuroishi, Kazuma Sasaki, Keisuke Yagawa, M. Yoshioka, Y. Yokoyama*
Because imines could be used as convenient starting materials in various fields, the development of an easy synthetic method of imine was strongly desired. In response to this demand, we thought that it would be an effective synthesis method if an aldehyde and an amine could be reacted to give an imine in good yield under solvent- and catalyst-free conditions. In fact, we tried the reaction of benzaldehyde with various amines under solvent- and catalyst-free conditions followed by removal of water that was produced in the reaction system by a vacuum pump, and desired imines could be obtained in good yields. Observation of this reaction using a nuclear magnetic resonance spectrometer revealed that the reaction rate was extremely fast at the initial stage but slowed over time. However, the reaction of benzaldehyde with aniline differed greatly, and the reaction rate dramatically improved in 47 - 48 minutes after the start of the reaction. At this time, we found that the reaction system underwent a phase transition from the liquid phase to the solid phase.
由于亚胺可以作为方便的起始原料用于许多领域,因此迫切需要开发一种简便的合成亚胺的方法。针对这一需求,我们认为在无溶剂和无催化剂的条件下,如果醛和胺能反应生成收率高的亚胺,将是一种有效的合成方法。事实上,我们在无溶剂和无催化剂的条件下尝试了苯甲醛与各种胺的反应,然后用真空泵除去反应系统中产生的水,得到了所需的亚胺,收率很高。用核磁共振谱仪观察该反应,发现反应速率在初始阶段非常快,但随着时间的推移而减慢。而苯甲醛与苯胺的反应差异较大,反应开始后47 ~ 48分钟,反应速率显著提高。此时,我们发现反应体系发生了由液相到固相的相变。
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引用次数: 5
Valorization of Solid Waste Recovery in an Institution of Higher Education 高等院校固体废物回收的价值评估
Pub Date : 2018-05-02 DOI: 10.4236/GSC.2018.82013
N. Munguia, Angela Diaz, L. Velazquez, R. Perez, J. Esquer, David S. Zepeda
One of the biggest challenges for organizations, cities and countries is waste management. Currently, 1.3 million tons of solid wastes are generated in the cities and by 2025 it is estimated that this volume will increase up to 2.2 billion tons. Considering this, it is clear that strategies for the reduction of waste generation are needed. In order to achieve this arduous and critic task changes in education, culture and public policy are required and one of the strategies that emerge as one of the most effective is the “zero waste” programs. This paper shows the foundation of a zero waste program based on previous and successful experiences in institutions of higher education. It presents the characterization and quantification of waste, as well as the valorization of it and potential environmental and economic benefits of the implementation of this kind of programs in higher education institutions. Results show that reduction and valorization of waste generation is possible in academic sectors while other outcomes emerge, such as the generation of human capital for the implementation of this kind of programs in different sectors of society and, in that way, contribute in the transition towards sustainable development.
对于组织、城市和国家来说,最大的挑战之一是废物管理。目前,城市产生的固体废物为130万吨,预计到2025年,这一数量将增加到22亿吨。考虑到这一点,显然需要减少废物产生的战略。为了完成这一艰巨而艰巨的任务,需要在教育、文化和公共政策方面进行变革,其中最有效的战略之一是“零浪费”计划。本文根据高等教育机构以往的成功经验,阐述了零浪费计划的基础。它介绍了废物的特征和量化,以及它的价值和在高等教育机构实施这类计划的潜在环境和经济效益。研究结果表明,在学术领域减少废物产生并使其增值是可能的,同时还出现了其他结果,例如在社会不同部门实施这类项目所需的人力资本的产生,从而有助于向可持续发展过渡。
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引用次数: 4
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Green and Sustainable Chemistry
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