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Modeling the Influence of Coastal Site Characteristics on PFAS in Situ Remediation 模拟海岸带场地特征对PFAS原位修复的影响。
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-12-11 DOI: 10.1111/gwat.13456
Grant R. Carey, Anthony Danko, Anh Le-Tuan Pham, Keir Soderberg, Beth Hoagland, Brent Sleep

The potential performance of a hypothetical colloidal-activated carbon (CAC) in situ remedy for perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) in groundwater in coastal zones was evaluated using estimated hydrogeologic and geochemical parameters for a coastal site in the United States. With these parameters, a reactive transport model (ISR-MT3DMS) was used to assess the effects of tidal fluctuations and near-shore geochemistry on CAC performance. The average near-shore ionic strength of 84 mM at the site was conservatively estimated to result in an increase in the adsorption of PFOA to CAC by about 50% relative to non-coastal sites with ionic strength <10 mM. The modeling also confirmed the hypothesis that tidally induced groundwater flow reversals near the shore would result in the accumulation of PFOA at the downgradient edge of the CAC zone. Slow desorption of PFOA from this downgradient CAC boundary may sustain downgradient plume concentrations above a strict cleanup criterion (e.g., USEPA MCL of 0.004 μg/L), for decades; however, there was still a large PFOA mass flux reduction (>99.9%) achieved after several decades at the shore. CAC longevity was substantially greater for PFOS with a similar source concentration; however, the higher PFOS distribution coefficient (Kd) in soil downgradient from the CAC zone resulted in substantially longer flushing times. It is recommended that short-term remedial action objectives for CAC remedies at coastal sites be based on mass flux reduction targets over a period of several decades, given the demonstrated challenges in trying to achieve very low cleanup criteria downgradient of a CAC zone in the short term.

利用美国一个沿海地点的估计水文地质和地球化学参数,评估了一种假设的胶体活性炭(CAC)对沿海地区地下水中全氟辛酸(PFOA)和全氟辛烷磺酸(PFOS)的原位补救方法的潜在性能。利用这些参数,采用反应输运模型(ISR-MT3DMS)评估潮汐波动和近岸地球化学对CAC性能的影响。据保守估计,该地点的平均近岸离子强度为84 mM,在岸上几十年后,与非沿海地点(离子强度为99.9%)相比,PFOA对CAC的吸附增加了约50%。源浓度相似的全氟辛烷磺酸的CAC寿命要长得多;然而,在CAC区向下梯度的土壤中,PFOS分布系数(Kd)越高,冲刷时间就越长。鉴于试图在短期内达到极低的沉降率清除标准所面临的挑战,建议沿海场址的沉降率补救措施的短期补救行动目标应以几十年期间减少质量通量的目标为基础。
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引用次数: 0
The Federal Role in Addressing Groundwater Depletion 联邦政府在解决地下水枯竭问题中的作用。
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-12-04 DOI: 10.1111/gwat.13454
William M. Alley, Sharon B. Megdal, Thomas Harter
<p>Groundwater depletion has been brought to the public's attention lately, beginning with a series of high-profile articles in the <i>New York Times</i>. The articles infer the need for greater federal involvement and control over the nation's groundwater. Separately, the President's Council of Advisors on Science and Technology (PCAST) formed a working group and solicited input on “America's Groundwater Challenges.” The PCAST request suggested federal actions were needed. However, many responses raised questions and concerns about the nature and scope of such actions (PCAST <span>2024a</span>).</p><p>While safeguarding groundwater is a global challenge, the most effective solutions are found at the local or regional aquifer system level. Groundwater occurs in aquifers that are highly variable in size, geology, climate, overlying land use, water quality, and water uses. The response times of groundwater systems to pumping, connections to surface water, recharge characteristics, and environmental functions also vary widely. Each groundwater system requires individual attention.</p><p>Most critically, effective groundwater management and governance require meaningful and continuing engagement of numerous local stakeholders in the decision-making process. People's diverse values about the environment, property rights, livelihood, individual and community economic gains, and current and intergenerational equity come into play, as do diverse perspectives and passions on how to balance the often-competing demands around groundwater use and protection. Communication and facilitation among stakeholders, decisionmakers, scientists, technical experts, and groundwater users play critical roles in structuring informed and productive conversations.</p><p>Consideration of these key attributes is central to achieving sustainable groundwater management. It is also important to recognize that States and Tribes have authority over the allocation and administration of rights to the use of groundwater within their borders. States and Tribes also administer groundwater quality rules, as well as federal water-quality standards if they have achieved federal delegation. As indicated by several responses to the PCAST query, any effort to impose federal oversight on groundwater pumping would face fierce opposition from states, agricultural groups, and others.</p><p>Indeed, PCAST in their final recommendations acknowledged that the federal government does not manage groundwater (PCAST <span>2024b</span>). The question becomes what is the role of the federal government among a host of partners, including state, federal, tribal, regional, and local entities; nonprofits and community-based organizations; university and private researchers; water districts; industry; and landowners?</p><p>Among the multiple ways the federal government can help are financial assistance for managed aquifer recharge, research and support for new technology for desalination, treatment, and water
最近,从《纽约时报》上一系列引人注目的文章开始,地下水枯竭问题引起了公众的注意。文章推断联邦政府有必要加强对国家地下水的干预和控制。另外,总统科学技术顾问委员会(PCAST)成立了一个工作组,就“美国的地下水挑战”征求意见。PCAST的请求表明,联邦政府需要采取行动。然而,许多回应对此类行动的性质和范围提出了质疑和担忧(PCAST 2024a)。虽然保护地下水是一项全球性挑战,但最有效的解决办法是在地方或区域含水层系统层面找到的。地下水发生在含水层中,这些含水层在大小、地质、气候、上覆土地利用、水质和用水方面变化很大。地下水系统对抽水、与地表水的连接、补给特性和环境功能的响应时间也有很大差异。每个地下水系统都需要单独关注。最关键的是,有效的地下水管理和治理需要众多地方利益相关者在决策过程中有意义和持续的参与。人们在环境、产权、生计、个人和社区经济收益、当代人和代际人之间的公平等方面的不同价值观,以及在如何平衡地下水使用和保护等经常相互竞争的需求方面的不同观点和激情,都在发挥作用。利益相关者、决策者、科学家、技术专家和地下水用户之间的沟通和促进在组织知情和富有成效的对话方面发挥着关键作用。考虑到这些关键属性对于实现可持续地下水管理至关重要。同样重要的是要认识到,国家和部落有权分配和管理在其境内使用地下水的权利。各州和部落也管理地下水质量规则,以及联邦水质标准,如果他们获得联邦授权的话。正如对PCAST质询的几个回应所表明的那样,任何对地下水开采施加联邦监管的努力都将面临各州、农业团体和其他方面的强烈反对。事实上,PCAST在他们的最终建议中承认联邦政府没有管理地下水(PCAST 2024b)。问题变成了联邦政府在众多合作伙伴(包括州、联邦、部落、地区和地方实体)中的角色是什么;非营利组织和社区组织;大学和私人研究人员;水地区;产业;和地主吗?联邦政府可以通过多种方式提供帮助,包括为管理含水层补给提供财政援助,研究和支持淡化、处理和水再利用或减少用水需求的新技术,支持私人井主和服务不足的社区,公共教育和宣传,改善主要含水层系统的特征,扩大对全国地下水状况和趋势的监测,包括地下水水位和质量。地面沉降、海水入侵以及与地表水和地下水依赖生态系统的相互作用。此外,可以鼓励以减少地下水透支和强调利益相关者之间合作为重点的项目,为相关的农业、能源、环境和城市/工业项目提供资金。在美国地质调查局和各州联合运营的国家地下水监测网络(NGWMN)的基础上,需要加强监测系统和数据传输,以便更好地了解农业、能源、环境和饮用水用户面临的威胁和机遇。需要一项联邦政府参与的倡议,与各州密切合作,以加强监测和数据提供系统。为学术、公共和私人机构(包括非政府组织)以及部落提供资金和资源也是必要的,以建立包括教育(Ferre 2024)和研究机会在内的专业能力,以应对未来管理地下水资源的挑战。所有这些可能性的基础是提高“地下水能见度”的挑战(Alley et al. 2016)。《纽约时报》和PCAST提供的能见度为在尊重国家和部落角色的同时采取有意义的步骤解决地下水枯竭问题提供了机会。
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引用次数: 0
Mapping the Hydrogeological Structure of a Small Danish Island Using Transient Electromagnetic Methods 利用瞬态电磁方法绘制丹麦小岛的水文地质结构图。
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-09 DOI: 10.1111/gwat.13452
Paul McLachlan, Mathias Ø. Vang, Jesper B. Pedersen, Rune Kraghede, Anders V. Christiansen

Small island communities often rely on groundwater as their primary source of fresh water. However, the limited land area and high proportion of coastal zones pose unique challenges to groundwater management. A detailed understanding of the subsurface structure can provide valuable insights into aquifer structure, groundwater vulnerability, saltwater intrusion, and the location of water resources. These insights can guide groundwater management strategies, for example, pollution regulation, promotion of sustainable agriculture, establishment of coastal buffer zones, and re-naturalization of land cover. Ordinarily, structural characterization relies on geological mapping and boreholes, however, such approaches can have insufficient spatial resolution to aid groundwater management. In this study, transient electromagnetic (TEM) methods are used to map the subsurface of a small, 13.2 km2, Danish Island. The approach successfully identified two previously unknown paleochannels, where the interface between Quaternary aquifer units and an underlying Paleogene Clay aquiclude had maximum depths of 100 and 160 m below sea level. Before this, the interface was assumed to be 15 to 25 m below sea level: therefore, these paleochannels present substantial potential groundwater resources. Resolving geological heterogeneity within the Quaternary deposits was less successful and future work will focus on addressing these limitations. Nonetheless, in several locations, evidence of saltwater intrusion was observed within the Quaternary units. This work demonstrates how TEM mapping can identify water resources, define aquifer boundaries, and aid water management decisions. Such approaches could be applied in other areas, particularly small islands, where similar groundwater challenges exist.

小岛屿社区通常依赖地下水作为淡水的主要来源。然而,有限的土地面积和高比例的沿海地区给地下水管理带来了独特的挑战。详细了解地下结构可以为含水层结构、地下水脆弱性、盐水入侵和水资源位置提供有价值的信息。这些见解可以指导地下水管理策略,例如污染监管、促进可持续农业、建立沿海缓冲区和恢复土地植被。通常情况下,结构表征依赖于地质绘图和钻孔,但这种方法的空间分辨率可能不足以帮助地下水管理。本研究采用瞬态电磁(TEM)方法绘制了一个面积为 13.2 平方公里的丹麦小岛的地下结构图。该方法成功确定了两条之前未知的古河道,其中第四纪含水层单元与下层古新统粘土含水层之间的界面最大深度为海平面以下 100 米和 160 米。在此之前,该界面被假定为海平面以下 15 至 25 米:因此,这些古河道蕴藏着巨大的潜在地下水资源。解决第四纪沉积物内部地质异质性的工作不太成功,今后的工作将重点解决这些限制因素。不过,在一些地方,第四纪单元内观察到了盐水入侵的证据。这项工作展示了 TEM 测绘如何识别水资源、确定含水层边界以及帮助水资源管理决策。这种方法可应用于存在类似地下水挑战的其他地区,特别是小岛屿。
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引用次数: 0
Jupyter Notebooks for Parameter Estimation, Uncertainty Analysis, and Optimization with PEST++ 使用 PEST+ 进行参数估计、不确定性分析和优化的 Jupyter 笔记本。
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-05 DOI: 10.1111/gwat.13447
Chanse Ford, Wonsook Ha, Katherine Markovich, Johanna Zwinger
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引用次数: 0
The Three Ages of Water: Prehistoric Past, Imperiled Present, and a Hope for the Future 水的三个时代:史前的过去,危险的现在,以及对未来的希望
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-05 DOI: 10.1111/gwat.13453
Alan E. Fryar
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引用次数: 0
Interpreting Step-Drawdown Pumping Test Undergoing Confined-Unconfined Conversion with Well Loss 解释正在进行封闭-非封闭转换(井损)的阶梯式降压抽水试验。
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-04 DOI: 10.1111/gwat.13450
Lu Zhang, Hua Zhao, Ling Wang, Jianmei Liu, Qi Zhu, Na Li, Zhang Wen, Yizhao Wang, Dian Wang

The step-drawdown pumping test often experiences a transition from confined to unconfined conditions due to the continuously increasing pumping rate. However, the current well hydraulics model has not accurately interpreted this phenomenon. In this study, we developed an analytical solution to address the confined-unconfined conversion in step-drawdown pumping tests based on Girinskii's potential and superposition theory. Additionally, a field step-drawdown pumping test featuring confined-unconfined conversion was conducted to apply the proposed analytical solution. The particle swarm optimization algorithm was employed to simultaneously estimate multiple parameters. The results demonstrate that the newly proposed solution provides a better fit to the observed drawdown in the pumping well compared to previous models. The hydrogeological parameters (K, S), well loss coefficient (B), and critical time for confined-unconfined conversion (tc) were estimated to be K = 7.15 m/d, S = 6.65 × 10−5, B = 7.48 × 10−6, and tc = 1152 min, respectively. Neglecting the confined-unconfined conversion in step-drawdown pumping tests leads to underestimation of drawdown inside the pumping well due to an overestimation of the aquifer thickness. After the conversion from confined to unconfined conditions, the estimated well loss coefficient decreased by 88% compared to its pre-conversion value. This highlights the necessity of adjusting the well loss coefficient in the step-drawdown pumping test model to account for confined-unconfined conversion. In summary, this study introduces a new method for interpreting parameters in step-drawdown pumping tests and provides field validation for its effectiveness.

由于抽水速率不断增加,阶梯式抽水试验经常会经历从封闭条件到非封闭条件的过渡。然而,目前的油井水力学模型并不能准确解释这一现象。在本研究中,我们根据吉林斯基电位和叠加理论,开发了一种分析方法来解决阶梯式下抽测试中的致密-非致密转换问题。此外,为了应用所提出的分析解决方案,我们还进行了以封闭-非封闭转换为特征的现场步降抽水试验。采用粒子群优化算法同时估算多个参数。结果表明,与之前的模型相比,新提出的解决方案能更好地拟合抽水井中观测到的抽水情况。据估算,水文地质参数(K、S)、井损系数(B)和封闭-非封闭转换临界时间(tc)分别为 K = 7.15 m/d、S = 6.65 × 10-5、B = 7.48 × 10-6、tc = 1152 min。在阶梯式降水抽水试验中忽略承压-非承压转换,会因高估含水层厚度而低估抽水井内的降水量。从封闭条件转换为非封闭条件后,估计的水井损失系数比转换前的值降低了 88%。这突出表明,有必要调整梯级降水抽水试验模型中的水井损失系数,以考虑承压-非承压转换。总之,本研究介绍了一种解释阶梯式降水抽水试验参数的新方法,并对其有效性进行了实地验证。
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引用次数: 0
Remembering the Big Picture 牢记大局
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-27 DOI: 10.1111/gwat.13451
Kenneth R. Bradbury
<p>As a practicing hydrogeologist, I have assisted many people and communities who have problem wells or water shortages. But when I recently experienced my own water shortage, I realized how much we in developed countries depend on and take for granted that the water will just be there, and will be fit to drink, when we turn on the tap. In late May of this year, thunderstorms and a few tornados rumbled across the midwestern United States, including our home in southern Wisconsin. My wife and I live in a rural area and are accustomed to thunderstorms in the spring. We are also used to occasional electric power outages, which happen three or four times a year and usually last from 15 min to an hour. So, we weren't especially surprised or worried when our lights went out during the storm. Suddenly, our home was silent except for the rain on the windows—no TV, no radio, no internet, no refrigerator, no lights—and no water, because we depend on our domestic well and pump. Our system usually holds enough water and pressure for a couple of toilet flushes and face washes, but that's it. When the blackout lasts 1 to 2 h, no problem. But when it lasts for 24, then 48, then 60 h, as it did this time, we realize how much we take our well, and our water, for granted. We had no water stockpiled. Fortunately, I was able to drive to a convenience store and purchase a few gallons of “pure spring water” to get us through the requisite drinking, face washing, and tooth brushing, but flushing the toilets was a more complicated matter. Our older home has standard toilets, which require about 7 gal per flush (unlike the newer low-flow toilets). I found myself lugging buckets of water up a hill from a nearby stream (and 7 gal weighs around 58 pounds) for flushing toilets and watering our neighbors' horses.</p><p>Obviously, my power outage was just a minor inconvenience compared to the problems of billions of people faced with real disasters and perpetual water shortages. Based on research by Mekonnen and Hoekstra (<span>2016</span>), UNICEF reports that “…four billion people—almost two thirds of the world's population—experience severe water scarcity for at least one month each year, and over two billion people live in countries where water supply is inadequate (https://www.unicef.org/wash/water-scarcity).” This experience made me contemplate the scope of groundwater science and wonder if we are emphasizing the right things in our work and ignoring the big picture while we focus on the small stuff.</p><p><i>Groundwater's</i> publisher, Wiley, lists the top four issue categories addressed by papers in the journal during the past year as, (1) groundwater flow models; (2) groundwater/aquifer recharge; (3) flow/solute transport simulation; and (4) groundwater solute composition and concentrations. These are all important and interesting topics but may not directly address one of the fundamental issues of our time—global water supply and sustainability, the topic of a rece
作为一名执业水文地质学家,我曾帮助过许多水井有问题或缺水的人和社区。但是,当我最近亲身经历缺水问题时,我才意识到,我们发达国家的人们是多么依赖并理所当然地认为,当我们打开水龙头时,水就在那里,就可以饮用。今年 5 月下旬,雷暴和几场龙卷风在美国中西部地区隆隆作响,包括我们在威斯康星州南部的家。我和妻子住在农村地区,对春季的雷暴习以为常。我们也习惯了偶尔的停电,这种情况每年会发生三四次,通常持续 15 分钟到一个小时不等。因此,当我们的电灯在暴风雨中熄灭时,我们并没有感到特别惊讶或担心。突然间,除了雨水打在窗户上,家里一片寂静--没有电视、收音机、互联网、冰箱、电灯,也没有水,因为我们依靠的是家用水井和水泵。我们的系统通常有足够的水量和水压来冲洗几次厕所和洗脸,但仅此而已。当停电持续 1 到 2 小时时,没有问题。但当停电持续 24 小时、48 小时、60 小时,就像这次停电一样,我们才意识到我们是多么想当然地使用我们的水井和水。我们没有储备水。幸运的是,我开车到便利店买了几加仑的 "纯净泉水",可以满足我们喝水、洗脸和刷牙的需要。我们的老房子使用的是标准马桶,每次冲水大约需要 7 加仑(与新型低流量马桶不同)。我发现自己要从附近的小溪里拖着水桶上山(7 加仑重约 58 磅),用于冲厕所和给邻居的马匹浇水。显然,与面临真正灾难和长期缺水的数十亿人相比,我的停电只是一个小小的不便。根据 Mekonnen 和 Hoekstra(2016 年)的研究,联合国儿童基金会报告称:"......40 亿人--几乎占世界人口的三分之二--每年至少有一个月经历严重缺水,超过 20 亿人生活在供水不足的国家(https://www.unicef.org/wash/water-scarcity)"。这次经历让我思考地下水科学的范围,并怀疑我们是否在工作中强调了正确的事情,而忽略了大局,只关注小事。《地下水》的出版商 Wiley 列出了去年该期刊论文涉及的四大问题类别:(1) 地下水流模型;(2) 地下水/含水层补给;(3) 流量/溶质输运模拟;以及 (4) 地下水溶质成分和浓度。几年前,我有幸在津巴布韦度过了一段时间,观察到当地村民(通常是妇女或儿童)为满足日常需要而用手或头取水所付出的努力(图 1)。我访问过一个村庄,那里最近由某个国际友好组织安装了一口水井。遗憾的是,由于水泵出了故障,又没有维修零件,这口井一直闲置着。相反,我看到妇女和儿童步行近一英里到当地的河流取水。我怀疑这些人是否担心全氟辛烷磺酸、硝酸盐或其他微量化学物质;他们的目标只是获得足够的水以度过一天--这就是他们的大局观。地下水》杂志刊登了大量关于地下水科学的优秀文章,但我们需要记住,世界上有很多人都在为获得足够的水而绝望。贫困地区农村家庭所需的少量水不会影响全球的可持续发展。这些人并不真正需要新的科学进步或全球性问题的解决方案;他们需要的是在当地实施可靠、稳健的地下水利用方法。地下水》欢迎有关如何实现这一目标的文章和/或评论。
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引用次数: 0
Exploring Freshwater Beneath the Ocean Floor 探索海底淡水
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-24 DOI: 10.1111/gwat.13446
Jeeban Panthi, Rachel Spinti
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引用次数: 0
Integrating ERT and SP Techniques for Characterizing Aquifers and Surface-Groundwater Interactions 整合 ERT 和 SP 技术,确定含水层和地表-地下水相互作用的特征。
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-24 DOI: 10.1111/gwat.13444
Md Lal Mamud, Robert M. Holt, Craig J. Hickey, Andrew M. O'Reilly, Leti T. Wodajo, Parsa Bakhtiari Rad, Md Abdus Samad

This study enhances the understanding of riverbank filtration and improves management of the Mississippi River valley alluvial (MRVA) aquifer during a managed aquifer recharge (MAR) pilot project at Shellmound, MS. Using high-resolution electrical resistivity tomography (ERT) and self-potential (SP) geophysical methods, we characterized the heterogeneous MRVA aquifer and monitored groundwater flow near a pumping well. ERT was used to provide detailed spatial characterization, filling gaps left by airborne electromagnetic (AEM) data and soil boring logs, while SP techniques were used to monitor groundwater flow, predict drawdown trends, and investigate surface-groundwater interactions. Results showed that SP signals were influenced by groundwater flow, river infiltration, and water mixing due to pumping disturbance of natural geochemical stratification, with significant river interaction observed after 1 h of pumping. The integration of ERT and SP methods revealed lithologic heterogeneity, explaining greater drawdowns on the northern side of the well and increased flow from the riverside. This comprehensive approach offers valuable insights into aquifer management and sustainability.

这项研究加深了人们对河岸过滤的了解,并改善了密西西比河流域冲积(MRVA)含水层在密西西比州贝壳丘(Shellmound)管理性含水层补给(MAR)试点项目期间的管理。利用高分辨率电阻率层析成像 (ERT) 和自电位 (SP) 地球物理方法,我们确定了异质 MRVA 含水层的特征,并监测了抽水井附近的地下水流。ERT 用于提供详细的空间特征,填补机载电磁(AEM)数据和土壤钻孔记录留下的空白,而 SP 技术则用于监测地下水流、预测缩减趋势以及研究地表水与地下水之间的相互作用。结果表明,由于抽水干扰了自然地球化学分层,SP 信号受到地下水流、河流入渗和水体混合的影响,抽水 1 小时后观察到明显的河流相互作用。ERT和SP方法的整合揭示了岩性的异质性,解释了水井北侧水位下降较多和河水流量增加的原因。这种综合方法为含水层管理和可持续性提供了宝贵的见解。
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引用次数: 0
The Artesian Wells of Batavia, Dutch East-Indies 1872 to 1878 1872 至 1878 年荷属东印度群岛巴达维亚的自流井。
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-22 DOI: 10.1111/gwat.13449
Paul Whincup, Arjen van Schaijk
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引用次数: 0
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Groundwater
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