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Hydrogeologic Heterogeneity Impacts on Fresh–Saltwater Interaction in Jeju Volcanic Island, Korea 韩国济州火山岛水文地质非均质性对淡水-盐水相互作用的影响
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-03-10 DOI: 10.1111/gwat.13472
Chang-Seong Koh, Eun-Hee Koh, Won-Bae Park, Min-Choel Kim

Jeju volcanic island of South Korea is characterized by hydrogeological heterogeneity, which has resulted in complex environments in a coastal aquifer system. The shape of the fresh-saltwater transition zone (FSTZ) and depth-dependent tidal influences on fresh-saltwater interaction in the eastern part of Jeju Island were examined by assessing geological logs from drilling cores, vertical profiles of specific conductance (SC) and temperature from geophysical logging, and performing time series analysis of groundwater level and multi-depth SC (collected from multiple sensors installed at various borehole depths). A sharp interface and step-like FSTZ were developed in the hyaloclastite and lava layers, respectively. The tidal influences on groundwater levels were highly associated with the distance from the coastline; however, SC data revealed different responses to tidal changes according to depth. Based on these data, we propose a conceptual hydrogeological model that incorporates different volcanic structures, including hyaloclastite and lava layers. Conduit flow through the highly permeable hyaloclastite layers led to the development of a sharp interface of FSTZ and disturbed the tidal signals on SC by acting as a preferential pathway for fast and abundant fresh groundwater discharge. Conversely, in the lava layers characterized by the successive formation of high- and low-permeability layers, boundary flows in the geological boundaries created a step-like FSTZ and showed a relatively high association between the tide and SC. This study highlights the crucial role of hydrogeological heterogeneity in determining the complex behaviors of fresh-saltwater interactions in the coastal aquifers of volcanic regions.

韩国济州岛火山岛具有水文地质非均质性的特点,导致其沿海含水层系统环境复杂。通过评估钻探岩心的地质记录、地球物理测井的比电导(SC)垂直剖面和温度,以及地下水水位和多深度SC(由安装在不同钻孔深度的多个传感器收集)的时间序列分析,研究了济州岛东部淡水-盐水过渡带(FSTZ)的形状和深度依赖潮汐对淡水-盐水相互作用的影响。透明晶岩层发育尖界面,熔岩层发育阶梯状FSTZ。潮汐对地下水位的影响与离海岸线的距离密切相关;然而,SC数据显示了不同深度对潮汐变化的不同响应。基于这些数据,我们提出了一个概念水文地质模型,其中包括不同的火山结构,包括透明碎屑岩和熔岩层。通过高渗透性透明晶岩层的导管流导致FSTZ形成一个尖锐的界面,并作为快速和丰富的新鲜地下水排放的优先通道,干扰了SC上的潮汐信号。相反,在以高、低渗层连续形成为特征的熔岩层中,地质边界的边界流动形成了阶梯状的FSTZ,显示出潮汐与SC之间相对较高的相关性。该研究强调了水文地质非均质性在决定火山地区沿海含水层淡水-盐水相互作用的复杂行为中的关键作用。
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引用次数: 0
Generating a Statistically Constrained Quaternary Model of a Buried Bedrock Valley Using FDEM 基于FDEM的隐伏基岩谷统计约束第四纪模型的建立
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-03-07 DOI: 10.1111/gwat.13478
C. Gorrie, C.M. Steelman, O. Conway-White, A. Smiarowski, E. Arnaud, B.L. Parker

An airborne electromagnetic (AEM) survey was conducted using the Resolve™ frequency-domain system over a buried bedrock valley near Elora, Ontario, Canada. A statistical bootstrapping approach was used to establish a relationship between the electrical resistivity from spatially interpolated one-dimensional AEM resistivity models and the lithostratigraphy of Quaternary sediments logged in continuously cored holes located within and adjacent to the buried bedrock valley. Three lithology types were classified using a bootstrapping approach: (i) clay, (ii) sandy to muddy diamicton with the presence of clasts, and (iii) sand/gravel. The statistically derived ranges in electrical resistivity from the model were used to generate a lithostratigraphic model of the Quaternary deposits along the valley axis. The resulting lithology model differentiated more electrically resistive coarse-grained sand and gravel from electrically conductive finer-grained clay-rich tills; but was not able to resolve interbedded layers associated with complex fluvial deposits. Modeled Quaternary deposit architecture and bedrock morphology along two transects orthogonal to the valley axis were consistent with co-located surface electrical resistivity tomography models and borehole natural gamma logs, indicating that the AEM method, when calibrated using high-quality continuous-core logs, can support quantitative conceptualizations of complex Quaternary architecture within and around a buried bedrock valley. Key limitations in this approach were the reduced vertical resolution of the AEM method and the inability to resolve thinly bedded layers (meter scale) identified in the core logs that may have a hydrogeologic influence. This study demonstrates the utility of combining airborne electrical methods with high-resolution geological logs through statistical analysis to constrain hydrostratigraphic architecture at scales relevant to municipal groundwater flow systems.

利用Resolve™频域系统对加拿大安大略省Elora附近的一个隐蔽基岩山谷进行了机载电磁(AEM)调查。采用统计自启动方法建立了空间插值一维AEM电阻率模型的电阻率与埋藏基岩谷内及附近连续取心孔中第四纪沉积物的岩石地层之间的关系。采用自举方法对三种岩性类型进行了分类:(i)粘土,(ii)含碎屑的砂质至泥质砾石,以及(iii)砂/砾石。利用该模型统计得到的电阻率范围,建立了沿山谷轴线第四纪沉积的岩石地层模型。由此建立的岩性模型将电阻性较强的粗粒砂和砾石与导电性较好的细粒富粘土土区分开来;但无法分辨与复杂河流沉积相关的互层。模拟的第四纪沉积结构和基岩形态沿与山谷轴线正交的两条样条与同一位置的地表电阻率层析成像模型和井内自然伽马测井相一致,表明AEM方法在使用高质量连续岩心测井进行校准时,可以支持对埋藏基岩山谷内部和周围复杂第四纪结构的定量概念。该方法的主要局限性是AEM方法的垂直分辨率较低,并且无法解析可能具有水文地质影响的岩心测井中确定的薄层(米级)。该研究表明,通过统计分析,将航空电气方法与高分辨率地质测井相结合,可以在与城市地下水流动系统相关的尺度上约束水文地层结构。
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引用次数: 0
Society News 社会新闻
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-03-03 DOI: 10.1111/gwat.13473
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引用次数: 0
ARCHI: A New R Package for Automated Imputation of Regionally Correlated Hydrologic Records ARCHI:用于区域相关水文记录自动估算的新 R 软件包。
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-02-28 DOI: 10.1111/gwat.13474
Zeno F. Levy, Robin L. Glas, Timothy J. Stagnitta, Neil Terry

Missing data in hydrological records can limit resource assessment, process understanding, and predictive modeling. Here, we present ARCHI (Automated Regional Correlation Analysis for Hydrologic Record Imputation), a new, open-source software package in R designed to aggregate, impute, cluster, and visualize regionally correlated hydrologic records. ARCHI imputes missing data in “target” records by linear regression using more complete “reference” records as predictors. Automated imputation is implemented using a novel, iterative algorithm that allows each site to be considered a target or reference for regression, growing the pool of complete references with each imputed record until viable gap-filling ceases. Users can limit artifacts from spurious correlations by specifying model-acceptance criteria and applying geospatial, correlation, and group-based filters to control reference selection. ARCHI provides additional functions for visualizing results, clustering records with similar correlation structures, evaluating holdout data, and interactive parameterization with an accessible and intuitive graphical user interface (GUI). This methods brief provides an overview of the ARCHI package, modeling guidelines, and benchmarking on two regional groundwater-level datasets from the Central Valley, CA and Long Island, NY. We evaluate ARCHI alongside widely used multivariate imputation software to highlight and contextualize its computational efficiency, imputation accuracy, and model transparency when applied to large, groundwater-level datasets.

水文记录中缺少的数据会限制资源评估、过程理解和预测建模。本文介绍了ARCHI (Automated Regional Correlation Analysis for Hydrologic Record Imputation),这是一个用R语言编写的新的开源软件包,用于聚合、Imputation、聚类和可视化区域相关水文记录。ARCHI使用更完整的“参考”记录作为预测因子,通过线性回归来推算“目标”记录中缺失的数据。自动输入使用一种新颖的迭代算法实现,该算法允许将每个站点视为回归的目标或参考,使用每个输入的记录增加完整的参考池,直到可行的空白填充停止。用户可以通过指定模型接受标准和应用地理空间、相关性和基于组的过滤器来控制参考选择,从而限制伪相关性产生的工件。ARCHI提供了其他功能,用于可视化结果、具有相似关联结构的聚类记录、评估保留数据以及使用可访问且直观的图形用户界面(GUI)进行交互式参数化。该方法简要介绍了ARCHI软件包、建模指南以及来自加利福尼亚州中央山谷和纽约州长岛的两个区域地下水位数据集的基准测试。我们将ARCHI与广泛使用的多元数据输入软件一起进行评估,以突出其计算效率、输入精度和模型透明度,并将其应用于大型地下水位数据集。
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引用次数: 0
From stoning to building: How to energize science meetings 从扔石头到建大楼:如何激励科学会议。
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-02-20 DOI: 10.1111/gwat.13471
Barbara J. Bickford
<p>Most groundwater professionals attend one or more regional or national conferences each year. At these meetings, we hope to move science forward by sharing research, exchanging ideas, and gaining allies in scientific pursuits with other scientists, practitioners, policymakers, funders, and the public.</p><p>But many science meetings fail to meet these aspirations. They overwhelm, confuse, and isolate participants. They prioritize the consumption of information over conversation, and that inhibits the collaborative scientific process.</p><p>Everyone can advance science by improving science meetings. Let's start with the presenters.</p><p>In 1985, Dr. Jay Lehr wrote an editorial in <i>Groundwater</i> entitled “Let there be stoning” (Lehr <span>1985</span>). In it, Dr. Lehr criticized scientists who subject their listeners to boring presentations. He accused them of being arrogant, thoughtless, insulting, and other derogatory adjectives.</p><p>Dr. Lehr's complaints are still valid. Many scientists give too much information or fail to provide enough narrative structure to help listeners understand the topic (Olson <span>2015</span>). The result? Boring presentations and confused listeners.</p><p>Now, I don't believe most scientists are purposely giving terrible presentations; perhaps they just don't know how to create truly engaging ones.</p><p>Fortunately, besides threats of public humiliation, Dr. Lehr offered timeless practical guidance, ranging from designing slides to enthusiastically connecting with the audience. I suggest that anyone planning to present at a professional conference read Lehr's editorial and take it to heart.</p><p>Conferences are meetings, and meetings are where people meet, or hope to. But the structure of traditional science meetings can inhibit meaningful connections. Food, name tags, and poster sessions can help people meet, but they are not enough.</p><p>As a result, instead of meeting new people and discussing science, we may create needed downtime for ourselves with our friends or phones.</p><p>I could throw stones at meeting planners for these structural shortcomings, but as one living in a proverbial glass house, it is more constructive to share ideas that work. At a recent 3-day science meeting, the sponsors and I prioritized connection and conversation in three ways:</p><p>First, to initiate connections immediately, we began Day 1 with two rounds of introductions around tables of eight, where participants shared their names, how they got there, what they wanted to happen, and what they had to offer (Segar <span>2009</span>, <span>2015</span>). Table leaders promoted conciseness by limiting each introduction to 90 s.</p><p>Our one-hour investment in personal introductions paid off. Everyone felt heard and connected. The resulting palpable energy and eagerness to talk lasted all 3 days. Around 30 of the 108 participants stayed for up to 2 h after the meeting ended, just to continue talking!</p><p>Even in large conf
大多数地下水专家每年参加一个或多个地区或国家会议。在这些会议上,我们希望通过与其他科学家、实践者、政策制定者、资助者和公众分享研究成果、交流思想,并在科学追求中获得盟友,推动科学向前发展。但是许多科学会议未能满足这些愿望。他们压垮、迷惑和孤立参与者。他们优先考虑信息的消费而不是对话,这阻碍了协作的科学过程。每个人都可以通过改进科学会议来推进科学。让我们从演讲者开始。1985年,杰伊·莱尔博士在《地下水》杂志上发表了一篇题为“让石头砸死吧”的社论(莱尔1985)。在这篇文章中,莱尔博士批评了那些让听众听无聊演讲的科学家。他指责他们傲慢、轻率、侮辱性和其他带有贬义的形容词。莱尔的抱怨仍然站得住脚。许多科学家提供了太多的信息,或者没有提供足够的叙事结构来帮助听众理解主题(Olson 2015)。结果呢?无聊的演讲和困惑的听众。现在,我不相信大多数科学家故意做糟糕的演讲;也许他们只是不知道如何创造真正吸引人的游戏。幸运的是,除了公开羞辱的威胁,从设计幻灯片到热情地与观众交流,莱尔博士提供了永恒的实用指导。我建议任何计划在专业会议上发言的人都应该读一读莱尔的社论,并牢记在心。会议就是会议,会议是人们见面或希望见面的地方。但传统科学会议的结构可能会抑制有意义的联系。食物、名牌和海报会议可以帮助人们见面,但这还不够。因此,我们可能会为自己和朋友或手机创造必要的停机时间,而不是结识新朋友和讨论科学。我可以因为这些结构性缺陷向会议策划者扔石头,但作为一个住在玻璃房子里的人,分享有用的想法更有建设性。在最近一次为期3天的科学会议上,我和发起人以三种方式优先考虑联系和对话:首先,为了立即建立联系,我们在第一天开始围绕8人的桌子进行两轮介绍,参与者分享他们的名字,他们是如何到达那里的,他们想要发生什么,以及他们能提供什么(Segar 2009, 2015)。表领导通过将每个介绍限制在90年代来促进简洁。我们在个人介绍上的一小时投资得到了回报。每个人都感到被倾听和联系在一起。由此产生的明显的精力和谈话的渴望持续了整整3天。108名参与者中,约有30人在会议结束后停留了2个小时,只是为了继续交谈!即使是在大型会议上,邀请人们简要介绍自己或说点什么,也更有可能让他们稍后提问。其次,为了鼓励每个人参与科学,我们将每个主题会议限制为三到四人发言,并规定发言时间限制为10分钟。问答环节结束后,与会人员在各自的桌子上讨论了相关的开放式问题。吸收简明的内容并进行讨论有助于人们记住他们所听到的内容,并刺激进一步的探索。在任何规模的会议上,两人一组或小组讨论相关问题的几分钟时间能让每个人同时参与进来,真正让整个房间充满活力。第三,为了促进有意义的对话,我们安排了长时间的休息和午餐时间,并在附近提供了非正式对话的空间。我们鼓励参与者共同努力,确定趋势和潜在的问题解决方案(图1)。在第三天,我们花了2小时的时间就参与者自己提出的主题进行公开讨论。他们喜欢这样!任何会议策划者都可以通过调整会议环境、优先考虑人际关系和鼓励生动的对话来促进科学的发展。说实话吧。我们中的一些人更多的是信息的消费者而不是贡献者,还有一些人是内向和害羞的。但是科学传播是一条双向的道路。我们需要放下手机,认真倾听演讲者,提出好奇的问题,自我介绍,参加小组活动。这可能不容易,但值得。熟能生巧。我们在科学领域交流和集会的方式正在发生变化。莱尔博士的建议可以帮助我们清理无聊和令人困惑的演讲。在计划和参与科学会议的方式上进行深思熟虑的改变,可以培养对话,从而产生真正的合作科学。少扔石头,多建立联系!作者声明无利益冲突。
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引用次数: 0
A New Groundwater Energy Transport Model for the MODFLOW Hydrologic Simulator MODFLOW水文模拟器的地下水能量输运新模型。
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-02-14 DOI: 10.1111/gwat.13470
Eric D. Morway, Alden M. Provost, Christian D. Langevin, Joseph D. Hughes, Martijn J. Russcher, Chieh-Ying Chen, Yu-Feng F. Lin

Heat transport in the subsurface is an important aspect of research related to the effects of a warming climate on ecological services (i.e., cold-water refugia); the development of geothermal resources for energy banking schemes (i.e., aquifer thermal energy storage [ATES]); and the effects of temperature on other aspects of groundwater quality, such as nutrient cycling. Historically, simulation of heat transport using the MODFLOW groundwater simulator and related codes was performed by scaling the input parameters of a solute-transport model to emulate heat transport. However, that approach required additional pre- and post-processing of input and output and could not account for the variation in effective thermal storage and transport properties during transient, unsaturated flow, for example. True heat-transport capabilities in the context of MODFLOW were first introduced in a variant called USG-Transport. More recently, a new groundwater energy-transport (GWE) model type has been added to MODFLOW 6, the core version of the MODFLOW hydrologic simulator. GWE supports the simulation of heat transport on structured or unstructured grids as well as within and between features of advanced packages that represent streams, lakes, multi-aquifer wells, and the unsaturated zone. GWE is integrated within MODFLOW 6 and is accessible through the FloPy Python package and the MODFLOW 6 application programming interface (API). An example simulation demonstrates conduction between grid cells through both the water and the solid aquifer material, including thermal bleeding from saturated overburden cells into a groundwater flow field.

地下热传输是研究气候变暖对生态服务(即冷水避难所)影响的一个重要方面;开发地热资源用于能源银行计划(即含水层热能储存[ATES]);以及温度对地下水质量其他方面的影响,比如养分循环。过去,使用MODFLOW地下水模拟器和相关代码进行热输运模拟是通过缩放溶质输运模型的输入参数来模拟热输运。然而,这种方法需要对输入和输出进行额外的预处理和后处理,并且无法解释例如在瞬态、不饱和流动期间有效储热和输运特性的变化。MODFLOW中真正的热传输能力最初是在USG-Transport中引入的。最近,MODFLOW水文模拟器的核心版本MODFLOW 6中增加了一种新的地下水能量输送(GWE)模型类型。GWE支持结构化或非结构化网格上的热传输模拟,以及代表溪流、湖泊、多含水层井和不饱和带的高级包内和包之间的热传输模拟。GWE集成在MODFLOW 6中,可通过FloPy Python包和MODFLOW 6应用程序编程接口(API)访问。一个模拟实例演示了网格单元之间通过水和固体含水层材料的传导,包括从饱和覆盖层单元到地下水流场的热渗流。
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引用次数: 0
Sustainable Irrigation: A Shift From Conventional to Solar Tube-Wells 可持续灌溉:从传统到太阳能管井的转变。
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-02-11 DOI: 10.1111/gwat.13469
Asim Khan, Israr Ahmed, Syed Mohammad Khair

This study examines the factors influencing the adoption of solar tube well technology for groundwater extraction in the agriculture sector, focusing on the Balochistan region of Pakistan. Water scarcity is a major challenge in this region due to declining groundwater level and unreliable power supplies. The study uses a binary logit regression model to analyze the factors that determine the adoption of solar tube wells by farmers. The study took into account variables such as age, education level of household head and access to credit, farmers' perception of groundwater depletion, number of hours of tube well operation, and cost of adopting solar technology. The results indicate that education level and experience positively influence farmers' ability to use solar tube wells. Education provides farmers with the knowledge to understand modern farming methods and the benefits of solar technology. In addition, the cost-effectiveness and increased operating hours of solar tube wells contribute significantly to their adoption. Farmers' concerns about greater groundwater depletion also influenced their decisions, with those seeing groundwater decline more likely to adopt solar technology. The results also suggest that policies that promote access to credit and reduce the initial cost of solar tube well adoption can further encourage farmer's adoption decision.

本研究以巴基斯坦俾路支地区为重点,探讨了影响农业部门采用太阳能管井技术抽取地下水的因素。由于地下水位下降和电力供应不可靠,缺水是该地区面临的主要挑战。本研究采用二元对数回归模型来分析决定农民采用太阳能管井的因素。研究考虑了年龄、户主的教育水平和获得信贷的机会、农民对地下水枯竭的看法、管井运行小时数和采用太阳能技术的成本等变量。结果表明,教育水平和经验对农民使用太阳能管井的能力有积极影响。教育为农民提供了了解现代耕作方法和太阳能技术益处的知识。此外,太阳能管井的成本效益和工作时间的增加也大大促进了太阳能管井的采用。农民对地下水日益枯竭的担忧也影响了他们的决定,那些看到地下水减少的农民更有可能采用太阳能技术。研究结果还表明,促进获得信贷和降低采用太阳能管井初始成本的政策可以进一步鼓励农民做出采用太阳能技术的决定。
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引用次数: 0
R.W. Gillham and the Role of Capillary Fringe Processes in Shallow Aquifer Behavior R.W. Gillham 和毛细边缘过程在浅层含水层行为中的作用。
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-02-05 DOI: 10.1111/gwat.13468
John Vogan, Steve Shikaze, Kristian Doerken
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引用次数: 0
Impact of Long Well Screens on Monitoring of the Freshwater-Saltwater Transition Zone 长井筛管对淡水-咸水过渡区监测的影响
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-01-24 DOI: 10.1111/gwat.13465
Frédérik Croteau, Cécile Coulon, John Molson, Jean-Michel Lemieux

Deep monitoring wells with long screens crossing the transition zone between freshwater and saltwater are often used in coastal areas to characterize fresh groundwater resources and the depth of saline groundwater. However, past studies have demonstrated that long-screen wells can lead to biased observations of the transition zone, since vertical flow within the borehole can modify the shape and elevation of the transition zone in and around the borehole compared to undisturbed conditions without a well. Here, field observations and variable-density numerical flow simulations are used to evaluate, under natural flow conditions, how the installation of long-screen wells can provide time-varying biased observations of the freshwater-saltwater transition zone, and how various aquifer and well parameters affect the magnitude of these biases. Results show that long-screen wells can lead to a more dispersed interface, an upward displacement of the transition zone of between 5 and 10 m, and a salinity decrease in the saltwater portion of the well on the order of 10 to 15 g/L. The perturbations take up to 5 years to fully develop and stabilize. The degree of displacement depends on the screen diameter, screen length, aquifer anisotropy, and hydraulic conductivity, whereas the displacement is independent of the distance of the well from the coast. This analysis provides insight into which well and aquifer characteristics increase the risk of obtaining biased observations in long-screen wells, and provides orders of magnitude for these biases.

在沿海地区经常使用跨越淡水和咸水过渡带的长屏深监测井来表征淡水地下水资源和咸水地下水的深度。然而,过去的研究表明,长筛管井可能导致对过渡区的观测偏差,因为与没有井的情况相比,井内的垂直流动可以改变井内和井周围过渡区的形状和高度。本文通过现场观测和变密度数值流动模拟来评估在自然流动条件下,长筛井的安装如何提供淡水-咸水过渡区随时间变化的偏差观测,以及不同含水层和井参数如何影响这些偏差的大小。结果表明,长筛井可使界面更加分散,过渡区位移向上移动5 ~ 10 m,井中盐水部分矿化度降低10 ~ 15 g/L。这些扰动需要长达5年的时间才能完全发展和稳定下来。驱替程度取决于筛管直径、筛管长度、含水层各向异性和水力导电性,而驱替程度与井距海岸的距离无关。该分析提供了在长筛管井中,哪些井和含水层特征增加了获得偏差观测的风险,并提供了这些偏差的数量级。
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引用次数: 0
Dissolved Inorganic Carbon Evolution of Sediment Porewater in the Huixian Wetland, Southwest China 汇县湿地沉积物孔隙水的溶解无机碳演化
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-01-17 DOI: 10.1111/gwat.13466
Jing Li, Xiaodong Pan, Huanxiong Chen, Congming Huang, Ruirui Cheng

Wetlands, as crucial terrestrial carbon reservoirs, have recently suffered severe degradation due to intense human activities. Lacustrine sediments serve as vital indicators for understanding wetland environmental changes. In the current paper, porewater samples were extracted from lacustrine sediment in three boreholes with a depth of ~75 cm in the Huixian karst wetland, southwest China, to study the chemical and dissolved inorganic carbon (DIC) evolution under anthropogenic influence. Two boreholes are situated beneath the Mudong Lake, while the other one is in the degraded wetland area. The results show that porewater in the central region of Mudong Lake is natural HCO3–Ca type water and recharged by karst groundwater as evidenced by depleted 2H -18O isotopes. Methanogenesis prevails in this area, suggested by positive δ13C values ranging from 4.29‰ to 7.05‰. However, shallow porewater at the western edge of Mudong Lake and porewater in the degraded wetland exhibit significantly higher concentrations of NO3 and SO42−, resulting from the agricultural input and recharged groundwater influenced by oxidation of pyrite. These processes lead to a decrease in methane production and generate DIC through degradation of organic fertilizer and carbonate weathering by sulfuric acid, thereby significantly altering porewater δ13C values. Two types of DIC mixing processes were observed based on the increasing δ13C values with depth, which can be attributed to the unique karst groundwater subsystems. This work highlights the potential impact of human-induced porewater chemical variations on the fate of DIC, particularly in karst wetland environments.

湿地作为重要的陆地碳库,近年来由于强烈的人类活动而遭受严重退化。湖泊沉积物是了解湿地环境变化的重要指标。本文以中国西南部惠县喀斯特湿地为研究对象,在3个深度约75 cm的钻孔中提取湖泊沉积物孔隙水样品,研究了人为影响下湖泊沉积物中化学和溶解无机碳(DIC)的演化。两个钻孔位于木洞湖底,另一个位于退化湿地区。结果表明:木洞湖中部孔隙水为天然HCO3-Ca型水,由岩溶地下水补给,2H -18O同位素耗竭。正δ13C值为4.29‰~ 7.05‰,表明该区产甲烷作用明显。而木洞湖西缘浅层孔隙水和退化湿地孔隙水NO3 -和SO4 -浓度显著升高,这是由于农业投入和补给地下水受黄铁矿氧化作用的影响所致。这些过程导致甲烷产量减少,并通过有机肥的降解和碳酸盐岩的硫酸风化作用生成DIC,从而显著改变孔隙水δ13C值。δ13C值随深度增加,可观测到两种类型的DIC混合过程,这可归因于独特的岩溶地下水子系统。这项工作强调了人类引起的孔隙水化学变化对DIC命运的潜在影响,特别是在喀斯特湿地环境中。
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引用次数: 0
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Groundwater
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