Yan-bo Chen, Yong Deng, Ran Liu, Li-da Chen, Xingfeng Guo
Abstract In order to improve the alkali metals discharge capacity of slag, the gas-slag balance method was used to carry out the slag alkali metals discharge experiments, the effect of slag composition on alkali metals discharge performance of slag was studied, some suggestions were put forward to optimize the alkali metals discharge performance of slag and the extreme value model was established. The results show that the alkali metals discharge ratio of slag decreased with the increase in the binary basicity and mass fraction of TiO2, and increased with the increase in the mass fraction of MgO, Al2O3 and MnO. The change in slag composition led to the change in the solubility of alkali metal oxides in liquid slag, decomposition of alkali metal silicates, structure of the slag in liquid state and viscosity of the slag, and then affected the alkali metals discharge performance of slag. The ability of slag to absorb alkali metals was certain under the condition of fixed composition. With the help of slag alkali metals discharge extreme value model, whether the current slag meets the needs of blast furnace alkali metals discharge could be evaluated. The alkali metals discharge capacity of slag could be improved by optimizing the alkali metals discharge performance of slag combined with experiments and actual production.
{"title":"Optimization of alkali metals discharge performance of blast furnace slag and its extreme value model","authors":"Yan-bo Chen, Yong Deng, Ran Liu, Li-da Chen, Xingfeng Guo","doi":"10.1515/htmp-2022-0013","DOIUrl":"https://doi.org/10.1515/htmp-2022-0013","url":null,"abstract":"Abstract In order to improve the alkali metals discharge capacity of slag, the gas-slag balance method was used to carry out the slag alkali metals discharge experiments, the effect of slag composition on alkali metals discharge performance of slag was studied, some suggestions were put forward to optimize the alkali metals discharge performance of slag and the extreme value model was established. The results show that the alkali metals discharge ratio of slag decreased with the increase in the binary basicity and mass fraction of TiO2, and increased with the increase in the mass fraction of MgO, Al2O3 and MnO. The change in slag composition led to the change in the solubility of alkali metal oxides in liquid slag, decomposition of alkali metal silicates, structure of the slag in liquid state and viscosity of the slag, and then affected the alkali metals discharge performance of slag. The ability of slag to absorb alkali metals was certain under the condition of fixed composition. With the help of slag alkali metals discharge extreme value model, whether the current slag meets the needs of blast furnace alkali metals discharge could be evaluated. The alkali metals discharge capacity of slag could be improved by optimizing the alkali metals discharge performance of slag combined with experiments and actual production.","PeriodicalId":12966,"journal":{"name":"High Temperature Materials and Processes","volume":"41 1","pages":"306 - 314"},"PeriodicalIF":1.5,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44813879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract This study shows the application of microwave sintering (MS) on preparing NbC–10Ni and NbC–12Ni cermets, as well as the effect of its microstructure, phase formation, and mechanical properties. Results indicated that NbC–Ni cermets with a fine and uniform structure can be obtained by MS in a relatively short time. And the sintering temperature greatly influenced the microstructure and mechanical properties of NbC–Ni cermets, whereas the effect of dwell time is relatively small. With the increase of the sintering temperature, the microstructure of NbC–Ni cermets experienced sintering densification and grain growth. The strength and toughness increased first and then decreased, and the hardness increased with the increase of sintering temperature. According to the comprehensive mechanical properties, the optimized sintering process is 1,390°C and the dwell time is 15 min. At this time, no new phase formed, but the diffraction peak of the Ni phase shifted. Through analysis, it is found that the improvement mechanisms for comprehensive mechanical properties of NbC–Ni cermets mainly include grain refinement, crack deflection and bridging, and energy absorption of the ductile phase of Ni.
{"title":"Microstructure and mechanical properties of NbC–Ni cermets prepared by microwave sintering","authors":"Si-wen Tang, Hao Zhang, Zhifu Yang, Qian Liu, Zhengyong Lv, Congsen Ouyang, X. Qiu","doi":"10.1515/htmp-2022-0049","DOIUrl":"https://doi.org/10.1515/htmp-2022-0049","url":null,"abstract":"Abstract This study shows the application of microwave sintering (MS) on preparing NbC–10Ni and NbC–12Ni cermets, as well as the effect of its microstructure, phase formation, and mechanical properties. Results indicated that NbC–Ni cermets with a fine and uniform structure can be obtained by MS in a relatively short time. And the sintering temperature greatly influenced the microstructure and mechanical properties of NbC–Ni cermets, whereas the effect of dwell time is relatively small. With the increase of the sintering temperature, the microstructure of NbC–Ni cermets experienced sintering densification and grain growth. The strength and toughness increased first and then decreased, and the hardness increased with the increase of sintering temperature. According to the comprehensive mechanical properties, the optimized sintering process is 1,390°C and the dwell time is 15 min. At this time, no new phase formed, but the diffraction peak of the Ni phase shifted. Through analysis, it is found that the improvement mechanisms for comprehensive mechanical properties of NbC–Ni cermets mainly include grain refinement, crack deflection and bridging, and energy absorption of the ductile phase of Ni.","PeriodicalId":12966,"journal":{"name":"High Temperature Materials and Processes","volume":"41 1","pages":"482 - 492"},"PeriodicalIF":1.5,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45975945","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Liang Shi, D. Huo, Yanhua Lei, Shaopeng Qu, Xueting Chang, Y. Yin
Abstract The tribocorrosion performance of low-temperature steels is vital for use in hostile environments. This study aims to investigate the tribocorrosion behavior of FH36 low-temperature steel with two distinct microstructures of tempered martensite (TM) and tempered sorbite (TS), respectively. Also, the coefficient of friction, surface morphologies, electrochemical properties, and corrosion features of the two steels were investigated. The results showed that the TM and TS steel exhibited outstanding impact toughness values of 239 and 306 J at −60°C, respectively. The friction coefficient and the electrochemical impedance in the TM steel were lower than those of the TS steel, while the scratch was deeper and narrower in the TM steel. Both the microstructure and the electrochemical corrosion affect the wear resistance of the low-temperature steels during the tribocorrosion process. The friction can accelerate the adsorption of Cl− ions that enrich the pits near the scratches, and the pitting of the TM steel was severe.
{"title":"Effect of microstructure on tribocorrosion of FH36 low-temperature steels","authors":"Liang Shi, D. Huo, Yanhua Lei, Shaopeng Qu, Xueting Chang, Y. Yin","doi":"10.1515/htmp-2022-0034","DOIUrl":"https://doi.org/10.1515/htmp-2022-0034","url":null,"abstract":"Abstract The tribocorrosion performance of low-temperature steels is vital for use in hostile environments. This study aims to investigate the tribocorrosion behavior of FH36 low-temperature steel with two distinct microstructures of tempered martensite (TM) and tempered sorbite (TS), respectively. Also, the coefficient of friction, surface morphologies, electrochemical properties, and corrosion features of the two steels were investigated. The results showed that the TM and TS steel exhibited outstanding impact toughness values of 239 and 306 J at −60°C, respectively. The friction coefficient and the electrochemical impedance in the TM steel were lower than those of the TS steel, while the scratch was deeper and narrower in the TM steel. Both the microstructure and the electrochemical corrosion affect the wear resistance of the low-temperature steels during the tribocorrosion process. The friction can accelerate the adsorption of Cl− ions that enrich the pits near the scratches, and the pitting of the TM steel was severe.","PeriodicalId":12966,"journal":{"name":"High Temperature Materials and Processes","volume":"41 1","pages":"328 - 342"},"PeriodicalIF":1.5,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46678220","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract To comprehensively utilize Fe and P in oolitic hematite ore, an innovative method was proposed to enhance P enrichment in the reduced iron during the reduction process. The reduced iron was then converted to low-P-containing molten iron and high-P-containing slag in the presence of CaO–SiO2–FeO–Al2O3 slag. In this study, the P content of the final iron after 0–1,800 s dephosphorization was investigated at different slag composition conditions, and the dephosphorization kinetics of the reduced iron was analyzed. The results showed that the P content of the final iron sample decreased rapidly within 600 s of dephosphorization and became almost constant with increasing dephosphorization time to 1,800 s. The basicity, FeO content, and Al2O3 content also affected the dephosphorization rate of the reduced iron. The apparent dephosphorization rate constant ranged from 1.141 × 10−3 to 2.363 × 10−3 g·(cm2·s)−1, and the overall mass transfer coefficient ranged from 2.47 × 10−3 to 3.38 × 10−3 cm·s−1. The rate-controlling step of the dephosphorization process was the mass transfer of P in both the slag and iron phases. The findings of this study provide a theoretical basis for the utilization of refractory oolitic hematite ore.
{"title":"Dephosphorization kinetics of high-P-containing reduced iron produced from oolitic hematite ore","authors":"Liwei Liu, Guofeng Li, Yanfeng Li, Libing Zhao","doi":"10.1515/htmp-2022-0017","DOIUrl":"https://doi.org/10.1515/htmp-2022-0017","url":null,"abstract":"Abstract To comprehensively utilize Fe and P in oolitic hematite ore, an innovative method was proposed to enhance P enrichment in the reduced iron during the reduction process. The reduced iron was then converted to low-P-containing molten iron and high-P-containing slag in the presence of CaO–SiO2–FeO–Al2O3 slag. In this study, the P content of the final iron after 0–1,800 s dephosphorization was investigated at different slag composition conditions, and the dephosphorization kinetics of the reduced iron was analyzed. The results showed that the P content of the final iron sample decreased rapidly within 600 s of dephosphorization and became almost constant with increasing dephosphorization time to 1,800 s. The basicity, FeO content, and Al2O3 content also affected the dephosphorization rate of the reduced iron. The apparent dephosphorization rate constant ranged from 1.141 × 10−3 to 2.363 × 10−3 g·(cm2·s)−1, and the overall mass transfer coefficient ranged from 2.47 × 10−3 to 3.38 × 10−3 cm·s−1. The rate-controlling step of the dephosphorization process was the mass transfer of P in both the slag and iron phases. The findings of this study provide a theoretical basis for the utilization of refractory oolitic hematite ore.","PeriodicalId":12966,"journal":{"name":"High Temperature Materials and Processes","volume":"41 1","pages":"48 - 56"},"PeriodicalIF":1.5,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47007034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Aiming at the problems of poor sensitivity and low accuracy of traditional combustible gas explosion hazard identification methods, the discrete probability model was introduced to design a multicomponent combustible gas explosion hazard identification method. Fem3 model is selected to analyze the diffusion mode of multicomponent combustible gas, and the calculation formula of diffusion velocity is obtained. The explosion limit of multicomponent combustible gas was observed by means of test, and the upper limit of explosion concentration of multicomponent combustible gas was obtained. According to the characteristics of explosion, a multicomponent combustible gas explosion hazard identification device is designed. The discrete probability model is used to identify the explosion hazard of multicomponent combustible gas. Experimental results show that the proposed method greatly improves the recognition sensitivity and accuracy, which fully shows that the proposed method has a better detection effect.
{"title":"Discrete probability model-based method for recognition of multicomponent combustible gas explosion hazard sources","authors":"Wenhua Ye, Yang Feng, Yangming Chen","doi":"10.1515/htmp-2021-0052","DOIUrl":"https://doi.org/10.1515/htmp-2021-0052","url":null,"abstract":"Abstract Aiming at the problems of poor sensitivity and low accuracy of traditional combustible gas explosion hazard identification methods, the discrete probability model was introduced to design a multicomponent combustible gas explosion hazard identification method. Fem3 model is selected to analyze the diffusion mode of multicomponent combustible gas, and the calculation formula of diffusion velocity is obtained. The explosion limit of multicomponent combustible gas was observed by means of test, and the upper limit of explosion concentration of multicomponent combustible gas was obtained. According to the characteristics of explosion, a multicomponent combustible gas explosion hazard identification device is designed. The discrete probability model is used to identify the explosion hazard of multicomponent combustible gas. Experimental results show that the proposed method greatly improves the recognition sensitivity and accuracy, which fully shows that the proposed method has a better detection effect.","PeriodicalId":12966,"journal":{"name":"High Temperature Materials and Processes","volume":"41 1","pages":"16 - 30"},"PeriodicalIF":1.5,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43896751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. He, Lu Lin, Ya-qin Liu, Meng-Yao Feng, Zhongxiao Hou, Wei Wu
Abstract With the development of the duplex converter process, the amount of dephosphorization furnace slag is increasing, and it has relatively low basicity. It has been indicated that the recovery of valuable elements from dephosphorization slag by carbothermic reduction has great environmental and economic benefits due to its high content of P, Fe, and Mn. In this work, the experimental slag was reduced by carbon powder in a resistance furnace at 1,550°C. The results show that 76.82% of P, 99.60% of Fe, and 11.82% of Mn in the slag are recycled at basicity 1.0, and the recovery ratios of P, Fe, and Mn are 34.58, 78.89, and 13.85% at basicity 2.0, respectively. The ferrophosphorus obtained from the reduction of the dephosphorization furnace slag can be used as a raw material for steel-making alloy, and the residual steel slag can be used as cement and other building materials. This work provides a reference for recycling and resource utilization of dephosphorization furnace slag.
{"title":"Experimental study on the preparation of ferrophosphorus alloy using dephosphorization furnace slag by carbothermic reduction","authors":"S. He, Lu Lin, Ya-qin Liu, Meng-Yao Feng, Zhongxiao Hou, Wei Wu","doi":"10.1515/htmp-2022-0236","DOIUrl":"https://doi.org/10.1515/htmp-2022-0236","url":null,"abstract":"Abstract With the development of the duplex converter process, the amount of dephosphorization furnace slag is increasing, and it has relatively low basicity. It has been indicated that the recovery of valuable elements from dephosphorization slag by carbothermic reduction has great environmental and economic benefits due to its high content of P, Fe, and Mn. In this work, the experimental slag was reduced by carbon powder in a resistance furnace at 1,550°C. The results show that 76.82% of P, 99.60% of Fe, and 11.82% of Mn in the slag are recycled at basicity 1.0, and the recovery ratios of P, Fe, and Mn are 34.58, 78.89, and 13.85% at basicity 2.0, respectively. The ferrophosphorus obtained from the reduction of the dephosphorization furnace slag can be used as a raw material for steel-making alloy, and the residual steel slag can be used as cement and other building materials. This work provides a reference for recycling and resource utilization of dephosphorization furnace slag.","PeriodicalId":12966,"journal":{"name":"High Temperature Materials and Processes","volume":"41 1","pages":"578 - 588"},"PeriodicalIF":1.5,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46876052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-01DOI: 10.1615/hightempmatproc.2022043681
N. Cherenda, N. Bibik, V. Astashynski, A. Kuzmitski
{"title":"Modification of hypereutectic Al-Si alloy surface layer structure by Nb alloying under high temperature plasma impact","authors":"N. Cherenda, N. Bibik, V. Astashynski, A. Kuzmitski","doi":"10.1615/hightempmatproc.2022043681","DOIUrl":"https://doi.org/10.1615/hightempmatproc.2022043681","url":null,"abstract":"","PeriodicalId":12966,"journal":{"name":"High Temperature Materials and Processes","volume":"32 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79426727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-01DOI: 10.1615/hightempmatproc.2022043589
E. Kolesnikova, V. Uglov, A. Drapezo, A. Kuleshov, Rusalsky Dmitry
{"title":"Study of temperature coefficient of resistance of n-InSb films on i-GaAs (100) substrate and temperature sensors based on them","authors":"E. Kolesnikova, V. Uglov, A. Drapezo, A. Kuleshov, Rusalsky Dmitry","doi":"10.1615/hightempmatproc.2022043589","DOIUrl":"https://doi.org/10.1615/hightempmatproc.2022043589","url":null,"abstract":"","PeriodicalId":12966,"journal":{"name":"High Temperature Materials and Processes","volume":"56 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90311329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-01DOI: 10.1615/hightempmatproc.2022044420
V. Uglov, N. Stepanjuk, S. Zlotski
{"title":"Irradiation resistance estimation method by crystal lattice distortions fast calculation for Ni, CoCrFeNi and CoCrFeMnNi FCC-alloys","authors":"V. Uglov, N. Stepanjuk, S. Zlotski","doi":"10.1615/hightempmatproc.2022044420","DOIUrl":"https://doi.org/10.1615/hightempmatproc.2022044420","url":null,"abstract":"","PeriodicalId":12966,"journal":{"name":"High Temperature Materials and Processes","volume":"123 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89053071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-01DOI: 10.1615/hightempmatproc.2022044226
I. Popov, D. Y. Коnstantinov, Y. Zhukova, A. Chorny
{"title":"THERMAL CONDUCTIVITY AND SPECIFIC HEAT OF CARBON-PLASTIC POLYMER COMPOSITE MATERIALS","authors":"I. Popov, D. Y. Коnstantinov, Y. Zhukova, A. Chorny","doi":"10.1615/hightempmatproc.2022044226","DOIUrl":"https://doi.org/10.1615/hightempmatproc.2022044226","url":null,"abstract":"","PeriodicalId":12966,"journal":{"name":"High Temperature Materials and Processes","volume":"85 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73270992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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