Pub Date : 2023-08-31DOI: 10.26418/indonesian.v6i2.63497
Afif Hidayatul Mustafid, Y. Maryani, Sri Agustina, Boima Situmeang
In our previous research, ethyl acetate extract of kesambi stem bark have the highest antibacterial activity against Escherichia coli compared with n-hexane and methanol extract. In our present study, we report the antibacterial activity of fractions from ethyl acetate extract against Escherichia coli. The method of fractionation used coloumn and thin lawyer chromatography. The Antibacterial activity uses Kirby Bauer methods. The characterization of active fractions used spectrometer infrared. The result showed fractions 6 and 7 have the highest antibacterial activity with inhibition zone 11.65 and 7.1 mm. The characterization of fractions 6 and 7 showed fungtional groups C=O, O-H, and C=C. The ethyl acetate fraction has the potential as antibacterial materials.
{"title":"POTENSI FRAKSI ETIL ASETAT KULIT BATANG KESAMBI SEBAGAI ANTIBAKTERI TERHADAP Escherichia coli THE POTENTIAL OF ETHYL ACETATE FRACTION OF KESAMBI STEM AS ANTIBACTERIAL AGAINST Escherichia coli","authors":"Afif Hidayatul Mustafid, Y. Maryani, Sri Agustina, Boima Situmeang","doi":"10.26418/indonesian.v6i2.63497","DOIUrl":"https://doi.org/10.26418/indonesian.v6i2.63497","url":null,"abstract":"In our previous research, ethyl acetate extract of kesambi stem bark have the highest antibacterial activity against Escherichia coli compared with n-hexane and methanol extract. In our present study, we report the antibacterial activity of fractions from ethyl acetate extract against Escherichia coli. The method of fractionation used coloumn and thin lawyer chromatography. The Antibacterial activity uses Kirby Bauer methods. The characterization of active fractions used spectrometer infrared. The result showed fractions 6 and 7 have the highest antibacterial activity with inhibition zone 11.65 and 7.1 mm. The characterization of fractions 6 and 7 showed fungtional groups C=O, O-H, and C=C. The ethyl acetate fraction has the potential as antibacterial materials.","PeriodicalId":13554,"journal":{"name":"Indonesian Journal of Pure and Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73256282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-31DOI: 10.26418/indonesian.v6i2.62731
Nur Ridha An Nisa, I. Syahbanu, Winda Rahmalia, N. Nurlina
Geopolymer synthesis was carried out using kaolin, for the adsorption of Pb (II) ions in solutions. Kaolin is used by Kaolin Capkala from Bengkayang Regency, West Kalimantan. This kaolin was first modified into metakaolin. The scaling up of geopolymers is carried out by making an activating solution, namely by mixing NaOH and Na2SiO3. The activating solution is mixed into metakaolin. The mass composition of each component in the geopolymer: metakaolin of 94,5 grams, Na2SiO3 of 57 grams, NaOH of 12 grams, and H2O of 30 grams. The formed geopolymers are tested for their adsorption ability against Pb(II) ions. The research results show the success of geopolymer formation as indicated by FTIR and XRD characterization results. Based on the FTIR results, several indications of successful geopolymer formation are seen in the shift and widening of the Si-O absorption peak at wave number 1109 cm-1 for kaolin to 1058 cm-1 for metakaolin and 1016 cm-1 for geopolymer; the appearance of O-C-O bond absorption in CO32- at 1362 cm-1 in geopolymer; and a shift in absorption of Al-O (Al (VI), wherein kaolin it is indicated by a wave number of 536 cm-1 while in metakaolin it is characterized by a wave number of 544 cm-1 and for geopolymer a wave number of 553 cm-1 indicates it. XRD diffractogram of the formation hump's appearance shows the amorphous characteristics of metakaolin and geopolymer at around 2θ 26o-35o. The application of geopolymer for Pb adsorption shows that Pb(II) can be adsorbed well in geopolymers with the maximum adsorption capacity of 2.77 mg/ g obtained at various concentrations of 40 ppm.
{"title":"SINTESIS GEOPOLIMER DENGAN BAHAN DASAR KAOLIN CAPKALA SEBAGAI ADSORBEN ION Pb(II) DALAM LARUTAN (SYNTHESIS OF GEOPOLYMERS WITH BASE MATERIALS KAOLIN CAPKALA AS ADSORBENT ION Pb(II) IN SOLUTION)","authors":"Nur Ridha An Nisa, I. Syahbanu, Winda Rahmalia, N. Nurlina","doi":"10.26418/indonesian.v6i2.62731","DOIUrl":"https://doi.org/10.26418/indonesian.v6i2.62731","url":null,"abstract":"Geopolymer synthesis was carried out using kaolin, for the adsorption of Pb (II) ions in solutions. Kaolin is used by Kaolin Capkala from Bengkayang Regency, West Kalimantan. This kaolin was first modified into metakaolin. The scaling up of geopolymers is carried out by making an activating solution, namely by mixing NaOH and Na2SiO3. The activating solution is mixed into metakaolin. The mass composition of each component in the geopolymer: metakaolin of 94,5 grams, Na2SiO3 of 57 grams, NaOH of 12 grams, and H2O of 30 grams. The formed geopolymers are tested for their adsorption ability against Pb(II) ions. The research results show the success of geopolymer formation as indicated by FTIR and XRD characterization results. Based on the FTIR results, several indications of successful geopolymer formation are seen in the shift and widening of the Si-O absorption peak at wave number 1109 cm-1 for kaolin to 1058 cm-1 for metakaolin and 1016 cm-1 for geopolymer; the appearance of O-C-O bond absorption in CO32- at 1362 cm-1 in geopolymer; and a shift in absorption of Al-O (Al (VI), wherein kaolin it is indicated by a wave number of 536 cm-1 while in metakaolin it is characterized by a wave number of 544 cm-1 and for geopolymer a wave number of 553 cm-1 indicates it. XRD diffractogram of the formation hump's appearance shows the amorphous characteristics of metakaolin and geopolymer at around 2θ 26o-35o. The application of geopolymer for Pb adsorption shows that Pb(II) can be adsorbed well in geopolymers with the maximum adsorption capacity of 2.77 mg/ g obtained at various concentrations of 40 ppm.","PeriodicalId":13554,"journal":{"name":"Indonesian Journal of Pure and Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81636693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sunscreen activity has been tested on simpur leaves (Dillenia indica Linn.) by determining the value of sun protection factor (SPF), erythema transmission percentage (%Te) and pigmentation transmission percentage (%Tp) of each methanol extract, n-hexane, dichloromethane fraction, and methanol fraction from simpur leaves. This test was carried out using a UV-Vis spectrophotometer (λ = 200-400 nm), a variation of sample concentration of 50; 75 and 100 ppm. The methanol fraction at a concentration of 100 ppm showed the highest SPF value of 4.630 ± 0.043 and the lowest %Te and %Tp values of 32.316 ± 0.297 and 52.699 ± 0.160, respectively. Isolation of flavonoids from the methanol fraction produced a relatively pure isolate (Rf = 0.901) with code G1 in the form of a yellowish-green solid/powder (1.5 mg). Characterization of isolate G1 using the FTIR spectrophotometer showed that there were vibrations of the alcohol O-H groups (3446.79 cm-1), aliphatic C-H (2958.80-2858.51 cm-1), C=C aromatic (1635.64 cm-1), C=C aromatic (1635.64 cm-1), C =O (1730.15 cm-1), C-O alcohol (1122.57 cm-1), and aliphatic C-H (1463.97-1382.96 cm-1). Based on a comparison of the spectra of isolate G1 with the spectra from the literature, isolate G1 was predicted as a flavonoid compound in the flavan or flavanol groups
通过测定辛帕叶中甲醇提取物、正己烷、二氯甲烷馏分和甲醇馏分的防晒系数(SPF)、红斑透射率(%Te)和色素透射率(%Tp)的值，对辛帕叶(Dillenia indica Linn.)的防晒活性进行了测试。本试验采用紫外可见分光光度计(λ = 200-400 nm)，样品浓度变化为50;75和100ppm。100 ppm甲醇馏分的SPF值最高，为4.630±0.043，%Te和%Tp值最低，分别为32.316±0.297和52.699±0.160。从甲醇馏分中分离得到相对纯净的黄酮类化合物(Rf = 0.901)，编码G1，为黄绿色固体/粉末(1.5 mg)。用FTIR分光光度计对G1分离物进行了表征，结果表明G1存在醇O- h基团(3446.79 cm-1)、脂肪族C- h (2958.80 ~ 2858.51 cm-1)、C=C芳(1635.64 cm-1)、C=C芳(1635.64 cm-1)、C= O (1730.15 cm-1)、C-O醇(1122.57 cm-1)、脂肪族C- h (1463.97 ~ 1382.96 cm-1)的振动。通过与文献的光谱比较，推测G1为黄酮类化合物，属于黄烷或黄烷醇基团
{"title":"AKTIVITAS TABIR SURYA FRAKSI METANOL DARI DAUN SIMPUR (Dillenia indica Linn.) DAN KARAKTERISASI SENYAWA ISOLATNYA","authors":"Salatiana Salatiana, Endah Sayekti, Gusrizal Gusrizal","doi":"10.26418/indonesian.v6i1.63085","DOIUrl":"https://doi.org/10.26418/indonesian.v6i1.63085","url":null,"abstract":"Sunscreen activity has been tested on simpur leaves (Dillenia indica Linn.) by determining the value of sun protection factor (SPF), erythema transmission percentage (%Te) and pigmentation transmission percentage (%Tp) of each methanol extract, n-hexane, dichloromethane fraction, and methanol fraction from simpur leaves. This test was carried out using a UV-Vis spectrophotometer (λ = 200-400 nm), a variation of sample concentration of 50; 75 and 100 ppm. The methanol fraction at a concentration of 100 ppm showed the highest SPF value of 4.630 ± 0.043 and the lowest %Te and %Tp values of 32.316 ± 0.297 and 52.699 ± 0.160, respectively. Isolation of flavonoids from the methanol fraction produced a relatively pure isolate (Rf = 0.901) with code G1 in the form of a yellowish-green solid/powder (1.5 mg). Characterization of isolate G1 using the FTIR spectrophotometer showed that there were vibrations of the alcohol O-H groups (3446.79 cm-1), aliphatic C-H (2958.80-2858.51 cm-1), C=C aromatic (1635.64 cm-1), C=C aromatic (1635.64 cm-1), C =O (1730.15 cm-1), C-O alcohol (1122.57 cm-1), and aliphatic C-H (1463.97-1382.96 cm-1). Based on a comparison of the spectra of isolate G1 with the spectra from the literature, isolate G1 was predicted as a flavonoid compound in the flavan or flavanol groups","PeriodicalId":13554,"journal":{"name":"Indonesian Journal of Pure and Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81793026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-04-30DOI: 10.26418/indonesian.v6i1.61936
Banan Fitriani, Harlia Harlia, A. Alimuddin
Areca catechu L. belongs to the Arecaceae which has been widely developed as a raw material for cosmetics industries. Areca nut contains many bioactive compounds, one of which is anti-inflammatory. In this study, the anti-inflammatory activity of betel nut extract was tested using the Red Blood Cell membrane stability method. The results of phytochemical screening showed that areca nut contains flavonoid compounds. Partitioning was carried out with n-hexane, dichloromethane solvents. Partition results obtained fraction of n-hexane 1.442 g with a yield of 5.546%; fraction of dichloromethane 5.831 g with a yield of 22.427%; fraction of ethyl acetate 0.470 g with a yield of 1.807%; and fraction of methanol was 3.432 g with a yield of 13.200%. The results of the anti-inflammatory activity test showed that the highest percent value of hemolysis inhibition was in the 100 g/mL concentration of methanol extract, which was 77.693% compared to the partitioned fractions such as the n-hexane fraction 10.215%; dichloromethane fraction 75.713%; ethyl acetate fraction 73.218% and methanol fraction 48.130%. This value can be said to be good if it approaches or exceeds the positive control of diclofenac sodium, which is 89.613%. The data from this study showed that methanol extract, fraction dichloromethane and fraction ethyl acetate had the best potential as an anti-inflammatory because the percentage of hemolysis was close to positive control
{"title":"AKTIVITAS ANTIINFLAMASI EKSTRAK BIJI PINANG (Areca catechu L.) MENGGUNAKAN METODE STABILITAS MEMBRAN RED BLOOD CELL (RBCs) (ANTI-INFLAMMATORY ACTIVITIES OF ARECA (Areca catechu L.) FRUIT SEED EXTRACTS USING RED BLOOD CELL (RBCs) MEMBRANE STABILITY METHOD)","authors":"Banan Fitriani, Harlia Harlia, A. Alimuddin","doi":"10.26418/indonesian.v6i1.61936","DOIUrl":"https://doi.org/10.26418/indonesian.v6i1.61936","url":null,"abstract":"Areca catechu L. belongs to the Arecaceae which has been widely developed as a raw material for cosmetics industries. Areca nut contains many bioactive compounds, one of which is anti-inflammatory. In this study, the anti-inflammatory activity of betel nut extract was tested using the Red Blood Cell membrane stability method. The results of phytochemical screening showed that areca nut contains flavonoid compounds. Partitioning was carried out with n-hexane, dichloromethane solvents. Partition results obtained fraction of n-hexane 1.442 g with a yield of 5.546%; fraction of dichloromethane 5.831 g with a yield of 22.427%; fraction of ethyl acetate 0.470 g with a yield of 1.807%; and fraction of methanol was 3.432 g with a yield of 13.200%. The results of the anti-inflammatory activity test showed that the highest percent value of hemolysis inhibition was in the 100 g/mL concentration of methanol extract, which was 77.693% compared to the partitioned fractions such as the n-hexane fraction 10.215%; dichloromethane fraction 75.713%; ethyl acetate fraction 73.218% and methanol fraction 48.130%. This value can be said to be good if it approaches or exceeds the positive control of diclofenac sodium, which is 89.613%. The data from this study showed that methanol extract, fraction dichloromethane and fraction ethyl acetate had the best potential as an anti-inflammatory because the percentage of hemolysis was close to positive control","PeriodicalId":13554,"journal":{"name":"Indonesian Journal of Pure and Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87755994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-04-30DOI: 10.26418/indonesian.v6i1.62725
Veren Fransiska, Intan Syahbanu, Adhitiyawarman Adhitiyawarman
Recycled High Density Polyethylene (HDPE) has been prepared for geomembrane construction material. The aim of this research was to study the effect of Butylated Hydroxytoluene (BHT) addition as an antioxidant on the characteristics of the resulting geomembrane. Fourier Transform Infra Red (FTIR) analysis was carried out to examine functional groups of recycled HDPE and prepared geomembranes. Mechanical properties, permeability and hydrophobicity of geomembrane were observed to determined optimum BHT addition. The results of FTIR analysis on recycled HDPE showed the presence of functional groups at wavelengths 2912 and 2847 cm-1 (C-H stretching); 1474 and 1467 cm-1 (CH2 bend); 721 cm-1 (CH2 Rock). After being formulated with other materials to obtain geomembranes, it was not found new peak indicating that the presence of BHT in geomembrane only physical interaction occurs. All of geomembranes had no permeability to water and reach 100% of hydrophobicity. The highest tensile test value was shown by geomembrane with 0,25 b/b% of BHT which about 21.235 MPa and 16.01 MPa for before and after soil burial test for four weeks, respectively. Perhaps might be due to the interaction between BHT at low concentrations which has lower polarity and HDPE which is nonpolar has better compatibility than at other concentrations
{"title":"THE EFFECT OF ADDITION BY BUTHYLATED HYDROXYTOLUENE (BHT) ON PHYSICAL PROPERTIES OF GEOMEMBRANE FROM RECYCLED HIGH DENSTY POLYETHYLENE (HFPE) PLASTIC WASTE","authors":"Veren Fransiska, Intan Syahbanu, Adhitiyawarman Adhitiyawarman","doi":"10.26418/indonesian.v6i1.62725","DOIUrl":"https://doi.org/10.26418/indonesian.v6i1.62725","url":null,"abstract":"Recycled High Density Polyethylene (HDPE) has been prepared for geomembrane construction material. The aim of this research was to study the effect of Butylated Hydroxytoluene (BHT) addition as an antioxidant on the characteristics of the resulting geomembrane. Fourier Transform Infra Red (FTIR) analysis was carried out to examine functional groups of recycled HDPE and prepared geomembranes. Mechanical properties, permeability and hydrophobicity of geomembrane were observed to determined optimum BHT addition. The results of FTIR analysis on recycled HDPE showed the presence of functional groups at wavelengths 2912 and 2847 cm-1 (C-H stretching); 1474 and 1467 cm-1 (CH2 bend); 721 cm-1 (CH2 Rock). After being formulated with other materials to obtain geomembranes, it was not found new peak indicating that the presence of BHT in geomembrane only physical interaction occurs. All of geomembranes had no permeability to water and reach 100% of hydrophobicity. The highest tensile test value was shown by geomembrane with 0,25 b/b% of BHT which about 21.235 MPa and 16.01 MPa for before and after soil burial test for four weeks, respectively. Perhaps might be due to the interaction between BHT at low concentrations which has lower polarity and HDPE which is nonpolar has better compatibility than at other concentrations","PeriodicalId":13554,"journal":{"name":"Indonesian Journal of Pure and Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81026319","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-04-30DOI: 10.26418/indonesian.v6i1.63202
Mardiana Rimba Utami, K. Riyani, T. Setyaningtyas
Industrial activities in modern times that are growing rapidly can cause environmental problems. This is due to the increasing amount of waste generated due to increased production. Untreated dye waste can inhibit sunlight penetration, photosynthesis activity, and the growth of aquatic biota. One of the dye wastes that is often found is methylene blue. Processing of methylene blue dye can use a practical adsorption method, easy to do at a low cost. This study showed the results of methylene blue adsorption using activated perlite nitric acid adsorbent. The best activity of perlite in adsorbing methylene blue is at pH 9 with a contact time of 180 minutes which results in a maximum adsorption capacity of 3,873 mg/g. The adsorption kinetics used followed a pseudo second order-model with consecutive k and q values of 0.0055 g/mg.min and 3.3102 mg/g, while the adsorption isotherms followed the Langmuir isotherm model with qmax and KL values of 3.873 mg/g and 0.5822 L/mg, respectively.
{"title":"THE USE OF NITRIC ACID AS A PERLITE ACTIVATOR IN ADSORBING METHYLENE BLUE","authors":"Mardiana Rimba Utami, K. Riyani, T. Setyaningtyas","doi":"10.26418/indonesian.v6i1.63202","DOIUrl":"https://doi.org/10.26418/indonesian.v6i1.63202","url":null,"abstract":"Industrial activities in modern times that are growing rapidly can cause environmental problems. This is due to the increasing amount of waste generated due to increased production. Untreated dye waste can inhibit sunlight penetration, photosynthesis activity, and the growth of aquatic biota. One of the dye wastes that is often found is methylene blue. Processing of methylene blue dye can use a practical adsorption method, easy to do at a low cost. This study showed the results of methylene blue adsorption using activated perlite nitric acid adsorbent. The best activity of perlite in adsorbing methylene blue is at pH 9 with a contact time of 180 minutes which results in a maximum adsorption capacity of 3,873 mg/g. The adsorption kinetics used followed a pseudo second order-model with consecutive k and q values of 0.0055 g/mg.min and 3.3102 mg/g, while the adsorption isotherms followed the Langmuir isotherm model with qmax and KL values of 3.873 mg/g and 0.5822 L/mg, respectively.","PeriodicalId":13554,"journal":{"name":"Indonesian Journal of Pure and Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91292560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-04-30DOI: 10.26418/indonesian.v6i1.63771
D. Notriawan, Febrika Laila, Eka Angasa, Gustria Ernis, Teja Dwi Sutanto, Reza Pertiwi, Ida Ayu Suci
This study aims to synthesize and characterize silver particles using Porang leaf extract (Amorphophallus muelleri Blume) and determine the selectivity of silver particles as mercury metal ion detectors. The study employed Porang leaf extract as a bioreductor and stabilizer, 0.01M AgNO3 solution as a precursor, and HgCl2 salt solution and PbCl2 salt solution as standard salt solutions to be tested for selectivity. The 2 g of Porang leaves used were cleaned, cut into pieces, allowed to stand at room temperature for three days, and mashed. Porang leaf powder was added with 50 mL of demineralized water and then heated for 15 minutes at a solution temperature of 80°C. The reaction of silver particle formation was carried out by adding Porang leaf extract and AgNO3 0.01M in variations of 1:3, 1:4, 1:5, 1:6, and 1:7, then irradiating under indirect sunlight for 15 minutes. The reaction results of a mixture of colloidal extract and AgNO3 solution showed a change in color to brownish-yellow. The color change indicated the formation of silver particles. The silver particles were then characterized with a UV-Vis spectrophotometer after 15 minutes of heating, 1 hour, and 5 hours at room temperature. The results obtained with colloidal silver particles can be synthesized with a bioreductor of Porang leaf extract (Amorphophallus muelleri Blume) with optimum variations of 1:3 and 1:4. The PSa results obtained in the mixture of silver particles formed were micro-nano-sized silver particles. The results of silver particles tested against metal ions showed that silver particles selectively detect Hg (II) metal ions in HgCl2 solutions compared to Pb (II) metal ions in PbCl2 solutions.
{"title":"BIOSINTESIS DAN KARAKTERISASI PARTIKEL PERAK EKSTRAK TANAMAN DAUN PORANG (Amorphophallus muelleri Blume) SEBAGAI PENDETEKSI ION LOGAM MERKURI","authors":"D. Notriawan, Febrika Laila, Eka Angasa, Gustria Ernis, Teja Dwi Sutanto, Reza Pertiwi, Ida Ayu Suci","doi":"10.26418/indonesian.v6i1.63771","DOIUrl":"https://doi.org/10.26418/indonesian.v6i1.63771","url":null,"abstract":"This study aims to synthesize and characterize silver particles using Porang leaf extract (Amorphophallus muelleri Blume) and determine the selectivity of silver particles as mercury metal ion detectors. The study employed Porang leaf extract as a bioreductor and stabilizer, 0.01M AgNO3 solution as a precursor, and HgCl2 salt solution and PbCl2 salt solution as standard salt solutions to be tested for selectivity. The 2 g of Porang leaves used were cleaned, cut into pieces, allowed to stand at room temperature for three days, and mashed. Porang leaf powder was added with 50 mL of demineralized water and then heated for 15 minutes at a solution temperature of 80°C. The reaction of silver particle formation was carried out by adding Porang leaf extract and AgNO3 0.01M in variations of 1:3, 1:4, 1:5, 1:6, and 1:7, then irradiating under indirect sunlight for 15 minutes. The reaction results of a mixture of colloidal extract and AgNO3 solution showed a change in color to brownish-yellow. The color change indicated the formation of silver particles. The silver particles were then characterized with a UV-Vis spectrophotometer after 15 minutes of heating, 1 hour, and 5 hours at room temperature. The results obtained with colloidal silver particles can be synthesized with a bioreductor of Porang leaf extract (Amorphophallus muelleri Blume) with optimum variations of 1:3 and 1:4. The PSa results obtained in the mixture of silver particles formed were micro-nano-sized silver particles. The results of silver particles tested against metal ions showed that silver particles selectively detect Hg (II) metal ions in HgCl2 solutions compared to Pb (II) metal ions in PbCl2 solutions.","PeriodicalId":13554,"journal":{"name":"Indonesian Journal of Pure and Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85396531","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The chemical structure of fatty acid compounds in plant parts other than seeds and fruit is still not widely known even though it has various benefits. One of the plants known to contain fatty acid compounds is Langsat. This research was conducted to characterize the structure of fatty acid compounds and the content of secondary metabolites in the roots of the langsat plant. The fatty acid characterization process was carried out by spectroscopy while the secondary metabolite content was analyzed by phytochemical screening test. Based on the spectrum of Proton Nuclear Magnetic Resonance (H-NMR) in acetone-d6 solvent at a frequency of 500 MHz, chemical shift data were obtained at 0.89 ppm (t, 3H), 1.33 ppm (m, 6H), 1.63 ppm (m, 2H), 2.33 ppm (t, 2H) and 8.14 ppm (s, 1H) and the results of phytochemical tests on the methanol extract of langsat root are known to contain alkaloids, terpenoids, flavonoids, phenolics, and saponins. Based on these data and compared with the literature, it is suspected that L1 isolates have similarities with the structure of compounds belonging to the fatty acid group.
{"title":"KARAKTERISASI SENYAWA ASAM LEMAK PADA AKAR TUMBUHAN LANGSAT (Lansium domesticum Correa) (CHARACTERIZATION OF FATTY ACID COMPOUNDS IN THE ROOT OF LANGSAT PLANT (Lansium domesticum Correa)","authors":"Azzizah Laila, Harlia Harlia, Rudyansyah Rudyansyah","doi":"10.26418/indonesian.v5i3.58016","DOIUrl":"https://doi.org/10.26418/indonesian.v5i3.58016","url":null,"abstract":"The chemical structure of fatty acid compounds in plant parts other than seeds and fruit is still not widely known even though it has various benefits. One of the plants known to contain fatty acid compounds is Langsat. This research was conducted to characterize the structure of fatty acid compounds and the content of secondary metabolites in the roots of the langsat plant. The fatty acid characterization process was carried out by spectroscopy while the secondary metabolite content was analyzed by phytochemical screening test. Based on the spectrum of Proton Nuclear Magnetic Resonance (H-NMR) in acetone-d6 solvent at a frequency of 500 MHz, chemical shift data were obtained at 0.89 ppm (t, 3H), 1.33 ppm (m, 6H), 1.63 ppm (m, 2H), 2.33 ppm (t, 2H) and 8.14 ppm (s, 1H) and the results of phytochemical tests on the methanol extract of langsat root are known to contain alkaloids, terpenoids, flavonoids, phenolics, and saponins. Based on these data and compared with the literature, it is suspected that L1 isolates have similarities with the structure of compounds belonging to the fatty acid group.","PeriodicalId":13554,"journal":{"name":"Indonesian Journal of Pure and Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73426454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-10-31DOI: 10.26418/indonesian.v5i3.59132
Risna Jupri, S. Fauziah, P. Taba
Molecularly Imprinted Polymer (MIP) is an intelligent synthetic material because it has the ability to selectively recognize target molecules. This study aims to synthesize, characterize and analyze the performance of MIP. MIP material was synthesized using di-(2-Ethylhexyl) phthalate (DEHP) as a template molecule, methyl methacrylate (MMA) monomer combined with ethylene glycol dimethacrylate (EGDMA) as a crosslinker by precipitation polymerization method. MIP materials were characterized by SEM-EDS instrument, FTIR spectrometer, SAA instrument, and UV-Vis spectrophotometer. The test variables for the adsorption ability of MIP material on DEHP compounds were time and concentration. The results showed that the synthesized MIP was in the form of a coarse white solid with a stiff texture. Characterization with the EDS instrument showed a decrease in the mass percent of C and percent of C atoms which indicated the formation of MIP_DEHP_MMA-co-EGDMA(TE) and the surface morphology characterized by the SEM instrument was composed of small grains that tend to be uniform and have pores. The bonds that affect the formation of polymers characterized by FTIR were –C=C, –C=O, and –CO. Characterization with the SAA instrument was 142,2770 m2/g, the total pore volume was 0,2616 cm3/g and the average pore radius was 7.3562 nm, indicating mesoporous material. The optimum time for adsorption of MIP_DEHP_MMA-co-EGDMA(TE) to DEHP was 120 minutes. MIP_DEHP_MMA-co-EGDMA(TE) followed the pseudo-second-order kinetics model and the adsorption obeyed the Freundlich adsorption isotherm
{"title":"SINTESIS DAN KARAKTERISASI MOLECULARLY IMPRINTED POLYMERS MENGGUNAKAN METIL METAKRILAT DAN ETILEN GLIKOL DIMETAKRILAT SEBAGAI ADSORBEN DI-(2-ETILHEKSIL) FTALAT (SYNTHESIS AND CHARACTERIZATION OF MOLECULARLY IMPRINTED POLYMERS USING METHYL METHACRYLATE AND ETHYLENE GLYCOL DIMETACRILATE AS ADSORBENT D","authors":"Risna Jupri, S. Fauziah, P. Taba","doi":"10.26418/indonesian.v5i3.59132","DOIUrl":"https://doi.org/10.26418/indonesian.v5i3.59132","url":null,"abstract":"Molecularly Imprinted Polymer (MIP) is an intelligent synthetic material because it has the ability to selectively recognize target molecules. This study aims to synthesize, characterize and analyze the performance of MIP. MIP material was synthesized using di-(2-Ethylhexyl) phthalate (DEHP) as a template molecule, methyl methacrylate (MMA) monomer combined with ethylene glycol dimethacrylate (EGDMA) as a crosslinker by precipitation polymerization method. MIP materials were characterized by SEM-EDS instrument, FTIR spectrometer, SAA instrument, and UV-Vis spectrophotometer. The test variables for the adsorption ability of MIP material on DEHP compounds were time and concentration. The results showed that the synthesized MIP was in the form of a coarse white solid with a stiff texture. Characterization with the EDS instrument showed a decrease in the mass percent of C and percent of C atoms which indicated the formation of MIP_DEHP_MMA-co-EGDMA(TE) and the surface morphology characterized by the SEM instrument was composed of small grains that tend to be uniform and have pores. The bonds that affect the formation of polymers characterized by FTIR were –C=C, –C=O, and –CO. Characterization with the SAA instrument was 142,2770 m2/g, the total pore volume was 0,2616 cm3/g and the average pore radius was 7.3562 nm, indicating mesoporous material. The optimum time for adsorption of MIP_DEHP_MMA-co-EGDMA(TE) to DEHP was 120 minutes. MIP_DEHP_MMA-co-EGDMA(TE) followed the pseudo-second-order kinetics model and the adsorption obeyed the Freundlich adsorption isotherm","PeriodicalId":13554,"journal":{"name":"Indonesian Journal of Pure and Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88556007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-10-31DOI: 10.26418/indonesian.v5i3.54948
Berta Juniarty Antomy, M. A. Wibowo, N. Wahyuni
Magnetic activated carbon (KAM) is used as an absorbent or adsorbent based on coconut shell which has been activated with sodium bicarbonate. The activated carbon is added to the iron composite which produces KAM. The iron composite content in the adsorbent has the ability to absorb and facilitate the separation process on the adsorbate. The purpose of this study was to determine the ability of the adsorbent to absorb the adsorbate, namely the pyrrole monomer compound. The adsorbent was characterized using the Fourier Transform Infra-Red (FTIR) instrument to determine the functional groups present. The adsorption capacity of iodine and methylene blue, adsorption isotherm, and adsorption kinetics were analysis. The adsorption isotherm was determined by varying the pyrrole concentration from the range of 30; 40; 50; 60 and 70 ppm. Determination of time variation was also carried out on adsorption kinetics with a range of 1; 1.5; 2; 2.5 and 3 hours. The FTIR spectrum produces Fe-O functional groups with an absorption peak of 556 cm-1, indicating the presence of a magnetic composite that has been attached to carbon. The adsorption capacity of iodine and methylene blue on magnetic activated carbon are 527 mg/g and 699 mg/g, respectively. The adsorption kinetics on KAM with the first-order model resulted in a value of R2=0.7736
{"title":"ADSORPSI SENYAWA MONOMER PIROL OLEH KARBON AKTIF MAGNETIK (ADSORPTION OF PYROL MONOMER COMPOUNDS BY MAGNETIC ACTIVE CARBON)","authors":"Berta Juniarty Antomy, M. A. Wibowo, N. Wahyuni","doi":"10.26418/indonesian.v5i3.54948","DOIUrl":"https://doi.org/10.26418/indonesian.v5i3.54948","url":null,"abstract":"Magnetic activated carbon (KAM) is used as an absorbent or adsorbent based on coconut shell which has been activated with sodium bicarbonate. The activated carbon is added to the iron composite which produces KAM. The iron composite content in the adsorbent has the ability to absorb and facilitate the separation process on the adsorbate. The purpose of this study was to determine the ability of the adsorbent to absorb the adsorbate, namely the pyrrole monomer compound. The adsorbent was characterized using the Fourier Transform Infra-Red (FTIR) instrument to determine the functional groups present. The adsorption capacity of iodine and methylene blue, adsorption isotherm, and adsorption kinetics were analysis. The adsorption isotherm was determined by varying the pyrrole concentration from the range of 30; 40; 50; 60 and 70 ppm. Determination of time variation was also carried out on adsorption kinetics with a range of 1; 1.5; 2; 2.5 and 3 hours. The FTIR spectrum produces Fe-O functional groups with an absorption peak of 556 cm-1, indicating the presence of a magnetic composite that has been attached to carbon. The adsorption capacity of iodine and methylene blue on magnetic activated carbon are 527 mg/g and 699 mg/g, respectively. The adsorption kinetics on KAM with the first-order model resulted in a value of R2=0.7736","PeriodicalId":13554,"journal":{"name":"Indonesian Journal of Pure and Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82224766","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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