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Influence of Mineral Admixtures on Corrosion Inhibition Effect of Nitrites 矿物掺合料对亚硝酸盐缓蚀效果的影响
IF 3.1 Q4 ELECTROCHEMISTRY Pub Date : 2018-09-18 DOI: 10.1155/2018/2537634
Mengna Yang, Junzhe Liu, Hui Wang, Yushun Li, Yanhua Dai, Xiangwei Xing
Chemical quantitative analysis of effective anticorrosion component and micro-analysis of hydration products of fly ash and slag on the influence of the nitrites corrosion inhibition was studied by the free nitrite ion concentration and X-ray diffraction pattern. The free nitrite ion concentration was used to describe the corrosion inhibition effect of nitrites. And the X-ray diffraction patterns were used to analyze the adsorption properties. The research results show that fly ash and slag were beneficial for improving the corrosion inhibition effect of nitrites. Cement-based materials with slag at low content presented high free nitrite ion concentration, but the addition of low content of fly ash harmed the corrosion inhibition effect of nitrites. The specimens incorporated with both fly ash and slag can reach the highest free nitrite ion concentration when the compounding proportion was 1:1. It was concluded that the extent of mineral admixtures of the corrosion inhibition effect of nitrites was affected by its type and content.
通过游离亚硝酸根离子浓度和X射线衍射图,研究了粉煤灰和矿渣有效防腐成分的化学定量分析和水化产物的微观分析对亚硝酸盐缓蚀作用的影响。用游离亚硝酸根离子浓度来描述亚硝酸盐的缓蚀作用。并利用X射线衍射图谱对吸附性能进行了分析。研究结果表明,粉煤灰和矿渣有利于提高亚硝酸盐的缓蚀效果。低掺量矿渣的水泥基材料具有较高的游离亚硝酸根离子浓度,但低掺量粉煤灰的加入损害了亚硝酸盐的缓蚀作用。当配合比为1:1时,掺入粉煤灰和矿渣的试样可以达到最高的游离亚硝酸根浓度。结果表明,矿物掺合料对亚硝酸盐的缓蚀作用程度受其种类和含量的影响。
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引用次数: 0
Corrosion of Materials after Advanced Surface Processing, Joining, and Welding 高级表面处理、连接和焊接后材料的腐蚀
IF 3.1 Q4 ELECTROCHEMISTRY Pub Date : 2018-09-02 DOI: 10.1155/2018/3569282
Xizhang Chen, Arvind Singh, S. Konovalov, J. Hirsch, Kai Wang
1College of Mechanical and Electrical Engineering, Wenzhou University, Wenzhou, China 2Department of Mechanical Engineering, Kumaraguru College of Technology (KCT), Tamil Nadu, India 3Department of Metals Technology and Aviation Materials, Samara National Research University, Samara, Russia 4Hydro Aluminium Deutschland GmbH, Bonn, Germany 5Department of Mechatronics Engineering, Foshan University, Foshan City, China
1中国温州温州温州大学机电工程学院2印度泰米尔纳德邦库马拉古鲁理工学院机械工程系3俄罗斯萨马拉萨马拉国立研究大学金属技术与航空材料系4德国波恩海德鲁铝业公司5佛山大学机电工程系,中国佛山市
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引用次数: 11
Evaluation of the Corrosion Inhibiting Capacity of Silica/Polypyrrole-Oxalate Nanocomposite in Epoxy Coatings 二氧化硅/聚吡咯-草酸盐纳米复合材料在环氧涂料中的缓蚀性能评价
IF 3.1 Q4 ELECTROCHEMISTRY Pub Date : 2018-09-02 DOI: 10.1155/2018/6395803
V. H. Vu, T. Dinh, N. T. Pham, T. Nguyen, P. Nguyen, H. To
Silica/Polypyrrole nanocomposites (SiO2/PPy) incorporating oxalate as counter anion (SiO2/PPyOx) were chemically polymerized in the solution with the presence of pyrrole, silica, and sodium oxalate. Nanocomposites SiO2/PPyOx at different concentrations of oxalate anion were characterized with FTIR, XRD, EDX, TGA, and TEM. The corrosion protective properties for carbon steel of nanocomposites in epoxy coating were studied by electrochemical techniques including electrochemical impedance spectroscopy (EIS) and open circuit potential (OCP). FTIR results of nanocomposites show a slightly red-shift in terms of wavelength compared with the case of PPy and SiO2 spectra. It may be due to a better conjugation and interactions between PPy and SiO2 in nanocomposite structure. TEM image indicated that nanocomposites have spherical morphologies with diameters between 100 and 150 nm. The EIS results showed that |Z| modulus values of epoxy coatings containing SiO2/PPyOx composites reached about 109.7 Ω.cm2, always higher than that of epoxy coating. These results are also confirmed by OCP results. It proves that the presence of oxalate anion can enhance the resistance against corrosion and it has been shown that the content of counter anion strongly affects the anticorrosion ability.
以草酸盐为反阴离子的二氧化硅/聚吡咯纳米复合材料(SiO2/PPyOx)在吡咯、二氧化硅和草酸钠存在的溶液中进行化学聚合。采用FTIR、XRD、EDX、TGA和TEM对不同浓度草酸阴离子下SiO2/PPyOx纳米复合材料进行了表征。采用电化学阻抗谱(EIS)和开路电位(OCP)等电化学技术研究了环氧涂层纳米复合材料对碳钢的防腐性能。纳米复合材料的FTIR结果与PPy和SiO2光谱相比,在波长上有轻微的红移。这可能是由于PPy和SiO2在纳米复合结构中具有更好的共轭和相互作用。TEM图像显示,纳米复合材料具有直径在100 ~ 150 nm之间的球形形貌。EIS结果表明,含有SiO2/PPyOx复合材料的环氧涂料的|Z|模量值约为109.7 Ω。Cm2,始终高于环氧涂料。这些结果也得到了OCP结果的证实。结果表明,草酸盐阴离子的存在可以增强材料的抗腐蚀能力,而反阴离子的含量对材料的抗腐蚀能力有很大的影响。
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引用次数: 5
Characterization of Sludge Deposits from Refineries and Gas Plants: Prerequisite Results Requirements to Facilitate Chemical Cleaning of the Particular Equipment 炼油厂和天然气厂污泥沉积物的表征:促进特定设备化学清洗的先决条件结果要求
IF 3.1 Q4 ELECTROCHEMISTRY Pub Date : 2018-09-02 DOI: 10.1155/2018/4121506
Rasha A. Al-Ghamdi, H. Sitepu
In this paper, the method developed by the authors to separate the inorganic materials from the hydrocarbon of the sludge deposits, which is fast and can accurately identify very small quantities of inorganic materials, has been extended to characterize the 12 types of sludge samples collected from (a) a regeneration overhead acid gas condenser, (b) water draw-off pump’s suction strainer in a gas plant, and (c) condenser, inside vessels of inlet head, and head coiler tube equipment at gas plants. The results revealed that the major phases are (a) iron sulfide corrosion products with the hydrocarbon type of mixture of diesel and lube oil for a condenser and (b) carbonate scale in the form of calcium carbonate with the hydrocarbon type of lubricant oil for sludge deposits from a suction strainer for pumps, and drilling mud in the form of barium sulfate with no organic hydrocarbon or polymer for sludge samples from a water recycling pump. Moreover, the major phases for inorganic materials built up in a condenser, inside the vessel’s inlet head, and the head coiler tube revealed that iron oxide corrosion products are found in the steam drum, and iron sulfate corrosion products are built up in the condenser. The presence of dissolved oxygen in the boiler feed water is indicated by a high wt% of iron oxide corrosion product in the form of magnetite (Fe3O4), which appeared in the inorganic materials built up in the condenser steam drum. Knowing accurately which phases and their wt% were involved in the inorganic materials can guide the field engineers to facilitate efficient cleaning of the equipment by drawing up the right procedures and taking preventive action to stop the generation of those particular sludge deposits.
在本文中,作者开发的从污泥沉积物的碳氢化合物中分离无机材料的方法快速且可以准确识别极少量的无机材料,已扩展到对从(a)再生塔顶酸性气体冷凝器收集的12种类型的污泥样品进行表征,(b)天然气厂的抽水泵吸滤器,以及(c)天然气工厂的冷凝器、入口封头容器内部以及封头盘管设备。结果表明,主要相是(a)冷凝器用柴油和润滑油的烃类混合物的硫化铁腐蚀产物和(b)碳酸钙形式的碳酸盐垢,以及不含有机烃或聚合物的硫酸钡形式的钻井泥浆,用于来自水循环泵的污泥样品。此外,冷凝器、容器入口封头内和封头卷取管内无机材料的主要相表明,在汽包中发现了氧化铁腐蚀产物,在冷凝器中形成了硫酸铁腐蚀产物。锅炉给水中溶解氧的存在表现为磁铁矿(Fe3O4)形式的氧化铁腐蚀产物的高wt%,其出现在冷凝器汽包中形成的无机材料中。准确了解无机材料中涉及的相及其wt%,可以指导现场工程师通过制定正确的程序和采取预防措施来阻止这些特定污泥沉积物的产生,从而促进设备的有效清洁。
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引用次数: 4
Corrosion of Reinforced Concrete Structures Submerged by the 2004 Tsunami in West Aceh, Indonesia 2004年印尼西亚齐海啸淹没的钢筋混凝土结构腐蚀
IF 3.1 Q4 ELECTROCHEMISTRY Pub Date : 2018-08-07 DOI: 10.1155/2018/4318434
H. Susanto, S. Huzni, S. Fonna
The earthquake and tsunami of 26 December 2004 caused the infrastructure in Aceh’s West Coast region to be submerged by seawater and to require the rehabilitation and reconstruction. The infrastructure that was submerged in the tsunami might experience a decrease in strength due to corrosion attack and would unexpectedly collapse if an earthquake occurs even on a small scale. This study was conducted to examine the corrosion risk level of the infrastructures in Aceh’s West Coast region, Indonesia, which submerged by the 2004 tsunami. Three locations were chosen for the study, i.e., Suak Ribee, Ujong Kalak, and Padang Seurahet. The assessments were carried out in 2014 and 2015. Three to four columns in each of the buildings were selected for the assessment. The half-cell potential technique method which refers to ASTM C876 was used to obtain and analyze the assessment data. The results of the assessment show that the electrical potentials on the surface of concrete for the buildings which submerged by the tsunami were range between -100 and -450 mV (vs. Cu/CuSO4) and categorized into low to high corrosion risk level. Meanwhile, the electrical potentials for new buildings range between (-100) and (-350) mV which indicated low to medium corrosion risk. Hence, the corrosion actively occurred in the areas having medium to high corrosion risk. Also, it was found that the corrosion risk level for the building tends to increase by increasing time. Therefore, the prevention and/or rehabilitation is necessary for stopping the corrosion, and so the premature failure of the building might be avoided.
2004年12月26日的地震和海啸导致亚齐西海岸地区的基础设施被海水淹没,需要恢复和重建。被海啸淹没的基础设施可能会因腐蚀而强度下降,如果发生小规模地震,也会意外倒塌。这项研究是为了检查2004年海啸淹没的印尼亚齐西海岸地区基础设施的腐蚀风险水平。选择了三个地点进行研究,即Suak Ribee、Ujong Kalak和Padang Seurahet。评估于2014年和2015年进行。每栋建筑都选择了三到四根柱子进行评估。采用参考ASTM C876的半电池电位技术方法来获得和分析评估数据。评估结果表明,被海啸淹没的建筑物混凝土表面的电位范围在-100至-450 mV(相对于Cu/CuSO4)之间,属于低至高腐蚀风险等级。同时,新建筑的电位范围在(-100)到(-350)mV之间,这表明腐蚀风险为低到中等。因此,腐蚀活动发生在具有中等至高腐蚀风险的区域。此外,研究发现,随着时间的推移,建筑物的腐蚀风险水平往往会增加。因此,预防和/或修复对于阻止腐蚀是必要的,因此可以避免建筑物的过早失效。
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引用次数: 7
Embankment Filling Loads on an Assembled Concrete Culvert beneath High Embankment 高路堤下组合式混凝土涵洞的路堤填土荷载
IF 3.1 Q4 ELECTROCHEMISTRY Pub Date : 2018-08-01 DOI: 10.1155/2018/9870673
Q. Ma, Chaogang Huang, Heng-lin Xiao, Zhi Chen
A culvert with prefabricated and assembled structural components is introduced to speed up the progress of highway construction in China. In order to clear the behavior of the prefabricated and assembled slab culvert, the center line section and the shoulder section of the embankment are selected for field tests. In the tests, the distribution and the growth of the earth pressures on the top slab and the lateral walls and the displacements and the deformations of the top slab and lateral walls are investigated, thereafter, the tested earth pressures are linearly fitted, and the formulas of fitting lines are obtained. The results show that the deflections of the lateral walls and of the cover slab are very small, and the variation of distribution and growth of the earth pressures presents significantly nonlinear characters, which is totally different from the linear earth pressure theory proposed by the current Chinese code. The vertical pressure is much smaller in the middle part of the top slab than that on both ends, and it is much larger than the linear theory results. The distribution curve of the lateral earth pressures on the lateral walls is approximately “3” in shape, and the maximum earth pressure locates at the junction of the cap and the lateral wall. The formula of the fitted line obtained from the primary stage pressure can be employed to estimate the earth pressure of embankment completion. The results of the field tests can provide references for the calculations of the components and the strength in the junctions of the assembled culverts.
为了加快我国公路建设的步伐,介绍了一种预制拼装结构涵洞。为了明确预制和组装盖板涵的性能,选择路堤的中心线段和路肩段进行现场试验。在试验中,研究了顶板和侧墙土压力的分布和增长,以及顶板和侧壁的位移和变形,然后对试验土压力进行了线性拟合,得到了拟合线的公式。结果表明,边墙和盖板的挠度很小,土压力的分布和增长变化具有明显的非线性特征,这与现行规范提出的线性土压力理论完全不同。顶板中部的竖向压力远小于两端的竖向压力,且远大于线性理论结果。侧墙上的侧向土压力分布曲线形状约为“3”,最大土压力位于承台与侧墙的交界处。根据一级压力得到的拟合线公式可用于估算路堤完工的土压力。现场试验结果可为组装涵洞连接处的构件和强度计算提供参考。
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引用次数: 3
Study on the Electrochemical Performance of Sacrificial Anode Interfered by DC Stray Current 直流杂散电流干扰下牺牲阳极电化学性能的研究
IF 3.1 Q4 ELECTROCHEMISTRY Pub Date : 2018-08-01 DOI: 10.1155/2018/4728692
Qing-Miao Ding, Tao Shen, Yanyu Cui, Juan Xue
The influence of sacrificial anode electrochemical properties interfered by direct stray current (DC) of 0 V, 1 V, 3 V, and 5 V, with different chloride ion concentration and temperature, was studied by open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), and polarization curves. The specific performance was as follows: as the DC interference voltage increased from 0 V to 5 V, the degree of positive migration of the sacrificial anode open circuit potential increased. The effect of temperature in DC interference voltage environment on sacrificial anode corrosion was not great, but the low temperature of 10°C could slow down the sacrificial anode corrosion and maintain good work efficiency. With the increase of the ambient temperature, the degree of corrosion of the sacrificial anode was deepened. As the chloride ion concentration in DC interference voltage environment increased from 0% to 0.3%, the degree of positive migration of the sacrificial anode open circuit potential increased. The higher the chloride ion concentration was, the greater the impact on the performance of the sacrificial anode was.
通过开路电位(OCP)、电化学阻抗谱(EIS)和极化曲线,研究了不同氯离子浓度和温度下,0 V、1 V、3 V和5 V直流杂散电流对牺牲阳极电化学性能的影响。具体性能如下:当直流干扰电压从0V增加到5V时,牺牲阳极开路电位的正迁移程度增加。直流干扰电压环境中的温度对牺牲阳极腐蚀的影响不大,但10°C的低温可以减缓牺牲阳极的腐蚀,并保持良好的工作效率。随着环境温度的升高,牺牲阳极的腐蚀程度加深。随着直流干扰电压环境中氯离子浓度从0%增加到0.3%,牺牲阳极开路电位的正迁移程度增加。氯离子浓度越高,对牺牲阳极性能的影响越大。
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引用次数: 0
Wet Oxidation Behavior of Near-Stoichiometric SiC Fibres in the Simulated Aeroengine Circumstance 近化学计量SiC纤维在模拟航空发动机环境中的湿氧化行为
IF 3.1 Q4 ELECTROCHEMISTRY Pub Date : 2018-08-01 DOI: 10.1155/2018/4319354
Liangyu Li, K. Jian, Xianhe Mao, Yifei Wang
The precursor-derived and near-stoichiometric SiC fibres (KD-S) were exposed at 1000–1500°C for 1 h in the simulated aeroengine circumstance of PH2O:O2:Ar = 14:8:78 KPa with the gas rate of 200 ml/min. The results indicated that the oxidized KD-S fibres were covered by silica layer. The oxygen content, grain size of silica, and oxide layer thickness increased, whereas the tensile strength decreased with rising annealing temperature. KD-S fibres treated under simulated aeroengine circumstances showed larger SiO2 grain size, thicker silica layer, and better residual strength than those annealed in dry air. The steam could accelerate the oxidation on KD-S fibres by reducing the active energy. The influence of water vapour on the oxidation behavior of KD-S SiC fibres was investigated and discussed as well.
前体衍生和接近化学计量的SiC纤维(KD-S)在1000–1500°C下暴露1 h在PH2O:O2:Ar=14:8:78的模拟航空发动机环境中 KPa,气体流量为200 ml/分钟。结果表明,氧化后的KD-S纤维被二氧化硅层覆盖。随着退火温度的升高,氧含量、二氧化硅晶粒尺寸和氧化层厚度增加,而抗拉强度降低。在模拟航空发动机环境下处理的KD-S纤维显示出比在干燥空气中退火的纤维更大的SiO2晶粒尺寸、更厚的二氧化硅层和更好的残余强度。蒸汽可以通过降低活性能来加速KD-S纤维的氧化。研究和讨论了水蒸气对KD-S SiC纤维氧化行为的影响。
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引用次数: 0
Corrigendum to “Application of a New Method in Identifying the Sludge Deposits from Refineries and Gas Plants: A Case of Laboratory-Based Study” 更正“一种新方法在识别炼油厂和天然气厂污泥沉积物中的应用:以实验室为基础的研究为例”
IF 3.1 Q4 ELECTROCHEMISTRY Pub Date : 2018-08-01 DOI: 10.1155/2018/8646104
H. Sitepu, Rasha A. Al-Ghamdi, S. R. Zaidi
In the article entitled “Application of a New Method in Identifying the Sludge Deposits from Refineries and Gas Plants: A Case of Laboratory-Based Study” [1], Rasha A. AlGhamdi was missing from the authors’ list. Rasha A. AlGhamdi performed the separation of the inorganic materials part (non-hydrocarbon) from the hydrocarbon part for the complex sample such as sludge deposit collected from theNG line, where the methylene chloride was insoluble. Rasha A. Al-Ghamdi also conducted the materials characterization of hydrocarbon parts using both the thermal gravimetric analysis and gas chromatography mass spectrometry techniques. Additionally, Rasha A. Al-Ghamdi interpreted the results, e.g., type of hydrocarbon (i.e., hydrocarbon type was diesel with the C10–C27) and the amount of inorganic compound, water, and hydrocarbon content (3 wt% of inorganic compound, 25wt% of water, and 72wt% of hydrocarbon content). The corrected authors’ list is shown above.
在题为“一种新方法在识别炼油厂和天然气厂污泥沉积物中的应用:一个基于实验室的研究案例”[1]的文章中,作者名单中缺少Rasha a.AlGhamdi。Rasha A.AlGhamdi对复杂样品(如从天然气管线收集的污泥沉积物)进行了无机材料部分(非烃)与烃部分的分离,其中二氯甲烷不溶。Rasha A.Al Ghamdi还使用热重量分析和气相色谱-质谱技术对碳氢化合物部件进行了材料表征。此外,Rasha A.Al Ghamdi解释了结果,例如,碳氢化合物的类型(即,碳氢化合物类型为C10–C27的柴油)以及无机化合物的量、水和碳氢化合物含量(无机化合物的3 wt%、水的25 wt%和碳氢化合物的72 wt%)。更正后的作者名单如上图所示。
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引用次数: 2
Synergistic Effect of Carbamide and Sulfate Reducing Bacteria on Corrosion Behavior of Carbon Steel in Soil 尿素和硫酸盐还原菌对土壤中碳钢腐蚀行为的协同作用
IF 3.1 Q4 ELECTROCHEMISTRY Pub Date : 2018-08-01 DOI: 10.1155/2018/7491501
Ximing Li, Cheng Sun
Synergistic effect of carbamide and sulfate reducing bacteria (SRB) on corrosion behavior of carbon steel was studied in soils with moisture of 20% and 30%, by soil properties measurement, weight loss, polarization curve, and electrochemical impedance spectroscopy. The results show that carbamide decreased the soil redox potential and increased soil pH. In soil without SRB, carbamide made corrosion potential of Q235 steel much more positive and then inhibited corrosion. Meanwhile, in soil with SRB, 0.5 wt% carbamide restrained SRB growth and inhibited biocorrosion of Q235 steel. Corrosion rate of carbon steel decreased in soil with 30% moisture compared with that with 20% moisture.
通过土壤性质测定、失重、极化曲线和电化学阻抗谱等方法,研究了尿素和硫酸盐还原菌(SRB)在含水量为20%和30%的土壤中对碳钢腐蚀行为的协同作用。结果表明:尿素降低了土壤氧化还原电位,提高了土壤ph值;在未添加SRB的土壤中,尿素使Q235钢的腐蚀电位更正,从而抑制了腐蚀;同时,在含有SRB的土壤中,0.5 wt%的尿素抑制SRB的生长,抑制Q235钢的生物腐蚀。碳钢在含水率为30%的土壤中的腐蚀速率比在含水率为20%的土壤中的腐蚀速率降低。
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引用次数: 5
期刊
International Journal of Corrosion
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