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The Effect of Chlorine Ion on Metal Corrosion Behavior under the Scratch Defect of Coating 涂层划伤缺陷下氯离子对金属腐蚀行为的影响
IF 3.1 Q2 Materials Science Pub Date : 2019-01-23 DOI: 10.1155/2019/7982893
Yanyu Cui, Yongxiang Qin, Dilinuer Dilimulati, Yujun Wang
The influence of chloride ion on the corrosion of metal under coating with scratch defects was researched by wire beam electrode (WBE) technology and electrochemical impedance spectroscopy (EIS) technology. The results showed that the current of metal surface could be characterized by the WBE technology. In the case of scratches on the coating, the location of the damage always showed an anodic current, and the cathodic reaction took place adjacent to the damaged location. The cathode area surrounded the defect and migrated to the far end over time. With the increase of Cl- concentration, the corrosion reaction speeded up, the rate of cathode migration also increased, and the speed of coating stripping did as well. Combined with electrochemical impedance spectroscopy, uniform laws were obtained.
采用线束电极(WBE)技术和电化学阻抗谱(EIS)技术研究了氯离子对带划痕缺陷涂层下金属腐蚀的影响。结果表明,WBE技术可以表征金属表面的电流。在涂层出现划痕的情况下,损伤部位始终呈现阳极电流,在损伤部位附近发生阴极反应。阴极区围绕缺陷并随时间迁移到远端。随着Cl-浓度的增加,腐蚀反应速度加快,阴极迁移速度加快,涂层剥离速度加快。结合电化学阻抗谱法,得到了均匀规律。
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引用次数: 14
Corrosion Study of Aluminum Alloy 3303 in Water-Ethylene Glycol Mixture: Effect of Inhibitors and Thermal Shocking 3303铝合金在水-乙二醇混合物中的腐蚀研究:缓蚀剂和热冲击的影响
IF 3.1 Q2 Materials Science Pub Date : 2019-01-10 DOI: 10.1155/2019/9020489
Mohammad Asadikiya, Y. Zhong, M. Ghorbani
Three types of corrosion inhibitors consisting of sodium diphosphate (Na2H2P2O7), sodium benzoate (NaC7H5O2), and sodium tetraborate (Na2B4O7) were evaluated to analyze their effectiveness to inhibit the aluminum alloy 3303 (UNS A93303) against corrosion, in water-ethylene glycol (C2H6O2) mixture. Potentiodynamic polarization tests were carried out to study the effect of each chemical. The temperature of solutions was 88°C and the aluminum samples were coupled with five other metals consisting of mild steel, stainless steel, brass, copper, and solder to include the effect of galvanic corrosion. The results showed that sodium diphosphate can effectively protect the aluminum alloy 3303 in comparison with two other chemicals. The effect of thermal shocking on the corrosivity of water-ethylene glycol solution was also investigated. It was indicated that the corrosivity of water-ethylene glycol solution increases because of thermal shocking, which oxidizes the aqueous ethylene glycol. The corrosion rate of aluminum alloy 3303 coupled with the five metals in thermal shocked water-ethylene glycol solution is 142 mpy, while it is 94 mpy in fresh water-ethylene glycol solution.
评价了由二磷酸钠(Na2H2P2O7)、苯甲酸钠(NaC7H5O2)和四硼酸钠(Na2B4O7)组成的三种缓蚀剂对铝合金3303(UNS A93303)在水-乙二醇(C2H6O2)混合物中的缓蚀效果。进行了电位动力学极化试验,以研究每种化学物质的影响。溶液温度为88°C,铝样品与其他五种金属结合,包括软钢、不锈钢、黄铜、铜和焊料,以包括电偶腐蚀的影响。结果表明,与其他两种化学物质相比,二磷酸钠能有效地保护3303铝合金。研究了热冲击对水-乙二醇溶液腐蚀性的影响。结果表明,乙二醇水溶液的腐蚀性是由于热冲击氧化乙二醇水而增加的。3303铝合金与五种金属在热冲击水乙二醇溶液中的腐蚀速率为142 mpy,而它是94 mpy在淡水乙二醇溶液中。
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引用次数: 13
Microstructure and Damping Capacity of ZK60 Alloy Sheets Fabricated by Twin Roll Casting and Hot Rolling Process 双辊铸造和热轧ZK60合金薄板的组织与阻尼性能
IF 3.1 Q2 Materials Science Pub Date : 2019-01-10 DOI: 10.1155/2019/2618737
Hongmei Chen, Xiaowen Li
ZK60 magnesium alloy sheets with 0.65 mm thickness were successfully fabricated by twin roll casting (TRC) and subsequent hot rolling process. Fine equiaxed grains were obtained after T6 treatment by the short-term TRC and hot rolling process, and the grain size for different reduction ratio per pass was similar. The studied sheets exhibited high strength and elongation, and the tensile strength, yield strengths, and elongation for the 10% and 30% reduction per pass were above 400 MPa, 300 MPa, and 17.0 %, respectively. The damping capacity values at low strain decreased with increasing the reduction ration per pass and the values at high strain were similar for the different reduction ration per pass. The lower reduction ratio per pass and the heat treatment between rolling passes can improve the mobility of dislocations, which indicated that this process was beneficial for improving damping capacity. Compared with higher reduction ratio per pass, the high tensile properties and damping capacity were obtained by 10% reduction per pass hot rolling process.
采用双辊铸造和后续热轧工艺成功制备了厚度为0.65 mm的ZK60镁合金板材。经T6短时间TRC和热轧工艺处理后得到细小的等轴晶粒,不同次径压下的晶粒尺寸相似。所研究的板材具有较高的强度和伸长率,每道次折减10%和30%时的抗拉强度、屈服强度和伸长率分别大于400 MPa、300 MPa和17.0%。低应变下的阻尼能力值随每道次压缩比的增大而减小,高应变下不同的每道次压缩比的阻尼能力值基本一致。较低的单道次压下率和轧制道次之间的热处理可以改善位错的迁移率,表明该工艺有利于提高阻尼能力。与较高的单道次压下率相比,单道次压下率为10%的热轧工艺获得了较高的拉伸性能和阻尼性能。
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引用次数: 3
Effect of Aging Treatment on Intergranular Corrosion Properties of Ultra-Low Iron 625 Alloy 时效处理对超低铁625合金晶间腐蚀性能的影响
IF 3.1 Q2 Materials Science Pub Date : 2019-01-02 DOI: 10.1155/2019/9506401
Zhi-yuan Zhu, Yi Sui, A. Dai, Yuan-fei Cai, Ling-Li Xu, Ze-xin Wang, Hong-Mei Chen, X. Shao, Wei Liu
The microstructures evolution of precipitations for an ultra-low iron Alloy 625 subjected to long term aging treatment at 750°C was investigated using scanning electron microscope (SEM) and X-ray diffraction (XRD). The intergranular corrosion behaviors of Alloy 625 were evaluated by using ASTM G28A. The result shows that the precipitated phase γ′′-Ni3Nb was mainly precipitated at the grain boundaries and twin boundaries. The number and volume fraction of γ′′ increased with the prolonging of aging time. The transformation of γ′′ to δ-Ni3Nb occurred after aging periods of 200 h. The corrosion resistance of Alloy 625 was significantly reduced during aging treatment. The decrease in intergranular corrosion resistance of Alloy 625 was attributed to the dissolution of precipitated phase and chromium depleted zone. The mass loss rate of Alloy 625 after aging treatment is related to the volume of precipitated phase and can be simulated by Johnson-Mehl-Avrami equation.
利用扫描电子显微镜(SEM)和X射线衍射(XRD)研究了超低铁合金625在750°C下长期时效处理后析出物的微观结构演变。采用ASTM G28A对625合金的晶间腐蚀行为进行了评价。结果表明,析出相γ′′-Ni3Nb主要在晶界和孪晶界析出。γ′′的数量和体积分数随着老化时间的延长而增加。时效200小时后,γ′′转变为δ-Ni3Nb。625合金的耐腐蚀性在时效处理过程中显著降低。625合金抗晶间腐蚀性能的降低归因于析出相和铬贫化区的溶解。625合金时效处理后的质量损失率与析出相的体积有关,可以用Johnson-Mehl-Avrami方程模拟。
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引用次数: 4
Prediction Method of Asphalt Pavement Performance and Corrosion Based on Grey System Theory 基于灰色系统理论的沥青路面性能与腐蚀预测方法
IF 3.1 Q2 Materials Science Pub Date : 2019-01-01 DOI: 10.1155/2019/2534794
Ding-bang Zhang, Xin Li, Yi Zhang, Hang Zhang
The Grey system theory is a new mathematical method to predict data changes in the poor data integrity. As a branch of Grey system theory, the GM (1, 1) model is widely used because only small sample data and simple calculations are needed in prediction of engineering project. It is a critical problem to effectively predict the performance and corrosion of asphalt pavement of highway construction due to the inadequacy of highway performance monitoring data. The smoothness, rut, and pavement skid resistance are three important indexes to evaluate the performance and corrosion of asphalt pavement. This paper has established the prediction model and derived prediction equation of asphalt pavement performance according to the GM (1, 1) model method and then listed the calculation equation of residual and the gray absolute correlation degree. Based on the experience of constructed Dalian-Guangzhou expressway in China, the vectors “a” and “b” in the prediction equation of smoothness, rut, and pavement skid resistance have been calculated by using the original monitoring data. The field monitoring data are compared with the predictive data for residual and the gray absolute correlation. The results reveal that the predicted data of the smoothness, rut, and skid resistance are mostly consistent with the monitoring data, the biggest residual of the above three indexes is smaller than 8.09%, and the gray absolute correlation degrees all exceed 0.9, which means the accuracy of the predicted equation is excellent. The calculation method based on GM (1, 1) model can effectively predict the changing performance index of asphalt pavement.
灰色系统理论是在数据完整性差的情况下预测数据变化的一种新的数学方法。GM(1,1)模型作为灰色系统理论的一个分支,在工程项目预测中由于样本数据少、计算简单而得到了广泛的应用。由于公路性能监测数据的不足,如何有效预测沥青路面的性能和腐蚀是公路建设中的一个关键问题。平整度、车辙和路面防滑性是评价沥青路面性能和腐蚀性能的三个重要指标。本文根据GM(1,1)模型法建立了沥青路面性能预测模型,推导了预测方程,并给出了残差和灰色绝对关联度的计算公式。根据国内已建成的大广高速公路的经验,利用原始监测数据,计算了平整度、车辙和路面防滑性预测方程中的向量a和b。将现场监测数据与预测数据进行残差和灰色绝对相关比较。结果表明,平整度、车辙、防滑性预测数据与监测数据基本一致,3项指标最大残差均小于8.09%,灰色绝对关联度均大于0.9,预测方程精度较好。基于GM(1,1)模型的计算方法能够有效预测沥青路面性能指标的变化。
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引用次数: 11
Prevention of Reinforcement Corrosion in Concrete by Sodium Lauryl Sulphate: Electrochemical and Gravimetric Investigations 十二烷基硫酸钠预防混凝土中钢筋腐蚀的电化学和重量分析研究
IF 3.1 Q2 Materials Science Pub Date : 2018-12-02 DOI: 10.1155/2018/9471694
Binsi M. Paulson, Thomas K. Joby, V. P. Raphael, K. S. Shaju
Prolonged corrosion inhibition response of sodium lauryl sulphate (SLS) on steel reinforcement in contaminated concrete was investigated by gravimetric method and electrochemical techniques such as potentiodynamic polarization and electrochemical impedance spectroscopy. Using half cell potential measurements probability of steel reinforcement corrosion was monitored for a period of 480 days. FT-IR spectroscopic analysis of the corroded products deposited on the steel reinforcement revealed the mechanism of corrosion inhibition. Modification in the surface morphology of steel specimens in the concrete was examined by optical microscopy. During the period of investigation (480 days), SLS showed appreciable corrosion inhibition efficiency on the steel reinforcement in concrete.
采用重量法和电化学技术,如动电位极化和电化学阻抗谱,研究了十二烷基硫酸钠(SLS)对污染混凝土中钢筋的长期缓蚀反应。使用半电池电位测量,对钢筋腐蚀的概率进行了为期480天的监测。对钢筋表面沉积的腐蚀产物进行FT-IR光谱分析,揭示了其缓蚀机理。通过光学显微镜检查了混凝土中钢试样表面形态的变化。在研究期间(480天),SLS对混凝土中的钢筋表现出明显的缓蚀效果。
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引用次数: 3
Effect of Stress Corrosion on Relaxation of Large Diameter BGFRP Bars 应力腐蚀对大直径BGFRP筋松弛的影响
IF 3.1 Q2 Materials Science Pub Date : 2018-12-02 DOI: 10.1155/2018/3418596
Guowei Li, Sidi Kabba Bakarr, Jingqiu Wang, Xue Liu, Cheng-yu Hong
Fibre reinforced polymer (FRP) rebars do not corrode like steel rebars when they are exposed to moisture such as water. Instead they have been shown to degrade when exposed to alkaline media and, in some cases, acids. It has especially demonstrated extensive deterioration when it has been simultaneously stressed and exposed to harsh environments. This combined effect has been termed as stress corrosion. The effect of stress corrosion on the stress relaxation of large sized prestressed basalt-glass fibre reinforced polymer (BGFRP) bars was analyzed by laboratory experiments. Two stressed bars were submerged in aqueous solutions of acid and alkaline in two separate plastic tanks under constant strain. Stress reduction values were observed over a period of about 7 months. Bars immersed in acid bath had an average stress relaxation of 9.2% and that in the alkali bath was observed to be about 13.4%. These results support earlier assertions that exposure of GFRP bars to alkali media is likely to be detrimental to the long-term durability of the reinforced structure.
纤维增强聚合物(FRP)钢筋在暴露于水分(如水)时不会像钢筋一样腐蚀。相反,当暴露在碱性介质中时,它们会降解,在某些情况下,还会降解酸。当它同时受到压力和暴露在恶劣环境中时,它尤其表现出广泛的退化。这种综合效应被称为应力腐蚀。通过室内试验,分析了应力腐蚀对大尺寸预应力玄武岩玻璃纤维增强聚合物(BGFRP)钢筋应力松弛的影响。在恒定应变下,将两个应力棒浸入两个单独的塑料罐中的酸性和碱性水溶液中。在大约7个月的时间内观察到应力降低值。浸泡在酸浴中的钢筋平均应力松弛率为9.2%,在碱浴中的平均应力弛豫率约为13.4%。这些结果支持了早期的断言,即GFRP钢筋暴露在碱介质中可能对钢筋结构的长期耐久性不利。
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引用次数: 3
Synergistic Inhibition of Mild Steel Corrosion in Seawater and Acidic Medium by Cathodic Protection and Monodora myristica Using Zinc Anode 阴极保护和肉豆蔻酸锌阳极协同抑制软钢在海水和酸性介质中的腐蚀
IF 3.1 Q2 Materials Science Pub Date : 2018-11-27 DOI: 10.1155/2018/5648907
I. Ukpong, O. Bamgboye, O. Soriyan
The synergistic inhibition of mild steel corrosion in seawater and 0.1M sulphuric acid by the cathodic protection and Monodora myristica was carried out through the weight loss and the linear polarization resistance (LPR) measurement. The results showed that in seawater, the synergism was not too effective for the protection of steel, whereas in 0.1M sulphuric acid, there was a great synergism between cathodic protection and the oil extracts of Monodora myristica, having an efficiency (IE%) of 102.89% at 15 mL of the oil extracts. For the linear polarization resistance (LPR), in most of the cases, there was a slight shift of the corrosion potential (Ecorr) and the open circuit potential (OPC) toward the positive as the volume of the oil extracts increased, thereby causing a change in the cathodic and the anodic Tafel slopes, which showed that the inhibitor is a mixed- type inhibitor. The corrosion current density (icorr) decreases as the volumes of the oil extract increase. Langmuir adsorption isotherm fitted best with an R2 of 1 unit, indicating a good agreement with the experimental data and with Langmuir adsorption isotherm.
通过失重和线极化电阻(LPR)测量,研究了阴极保护和肉豆蔻酸对低碳钢在海水和0.1M硫酸中腐蚀的协同抑制作用。结果表明,在海水中,阴极保护对钢铁的保护效果不太好,而在0.1M硫酸中,肉豆蔻的油提取物与阴极保护有很大的协同作用,在15mL的油提取物下,阴极保护的效率(IE%)为102.89%。对于线性极化电阻(LPR),在大多数情况下,随着油提取物体积的增加,腐蚀电位(Ecorr)和开路电位(OPC)略有向正偏移,从而导致阴极和阳极Tafel斜率的变化,这表明抑制剂是一种混合型缓蚀剂。腐蚀电流密度(icorr)随着油提取物体积的增加而降低。Langmuir吸附等温线在R2为1的情况下拟合得最好,表明与实验数据和Langmuir等温线吻合良好。
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引用次数: 6
Experimental Assessment of Rebar Corrosion in Concrete Slab Using Ground Penetrating Radar (GPR) 用探地雷达对混凝土板中钢筋腐蚀的实验评估
IF 3.1 Q2 Materials Science Pub Date : 2018-11-21 DOI: 10.1155/2018/5389829
A. Zaki, M. A. Megat Johari, Wan Muhd Aminuddin Wan Hussin, Y. Jusman
Corrosion of steel reinforcement is a major cause of structural damage that requires repair or replacement. Early detection of steel corrosion can limit the extent of necessary repairs or replacements and costs associated with the rehabilitation works. The ground penetrating radar (GPR) method has been found to be a useful method for evaluating reinforcement corrosion in existing concrete structures. In this paper, GPR was utilized to assess corrosion of steel reinforcement in a concrete slab. A technique for accelerating reinforcement bar corrosion using direct current (DC) power supply with 5% sodium chloride (NaCl) solution was used to induce corrosion to embedded reinforcement bars (rebars) in this concrete slab. A 2 GHz GPR was used to assess the corrosion of the rebars. The analysis of the results of the GPR data obtained shows that corrosion of the rebars could be effectively localized and assessed.
钢筋腐蚀是结构损坏的主要原因,需要修理或更换。钢腐蚀的早期检测可以限制必要的修理或更换的程度以及与修复工程相关的费用。探地雷达(GPR)方法已被证明是评估既有混凝土结构钢筋腐蚀的有效方法。本文采用探地雷达对混凝土板中钢筋的腐蚀进行了评估。采用直流电源加5%氯化钠溶液加速钢筋腐蚀技术,对混凝土板内预埋钢筋进行腐蚀诱导。采用2ghz探地雷达对钢筋的腐蚀进行了评估。通过对探地雷达数据的分析,可以有效地定位和评估钢筋的腐蚀情况。
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引用次数: 40
Study on the Electrochemical Performance of Sacrificial Anode Interfered by Alternating Current Voltage 交流电压干扰下牺牲阳极电化学性能的研究
IF 3.1 Q2 Materials Science Pub Date : 2018-11-05 DOI: 10.1155/2018/1523626
Qing-Miao Ding, Xiao Chu, Tao Shen, Xiaoxiao Yu
The effect of alternating current (AC) voltage of 0V, 1V, 3V, and 5V on magnesium alloy sacrificial anode electrochemical properties was studied by open circuit potential (OCP) analysis, electrochemical impedance spectroscopy (EIS), and polarization curve measurements. The results demonstrate that the AC voltage has a great effect on the magnesium alloy sacrificial anode. The corrosion control is anode control in the first two days with no AC interference. The stray current accelerates the transmission and diffusion of oxygen, so the corrosion rate under AC interference is higher than that with no AC interference. And the corrosion control becomes cathodic control under AC interference. The corrosion rate of the sacrificial anode is faster and faster as the AC interference voltage increases in the range of 0~5V, while the corrosion inclination is weakened.
通过开路电位(OCP)分析、电化学阻抗谱(EIS)和极化曲线测量,研究了0V、1V、3V和5V交流电压对镁合金牺牲阳极电化学性能的影响。结果表明,交流电压对镁合金牺牲阳极的性能有很大影响。腐蚀控制为前两天阳极控制,无交流干扰。杂散电流加速了氧的传输和扩散,因此在交流干扰下的腐蚀速率高于无交流干扰的腐蚀速率。在交流干扰下,腐蚀控制变为阴极控制。在0~5V范围内,随着交流干扰电压的升高,牺牲阳极的腐蚀速率越来越快,腐蚀倾斜度减弱。
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引用次数: 0
期刊
International Journal of Corrosion
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