Strength of vegetated coal-bearing soil is of great significance to evaluate the shallow stability of vegetated slopes in coal-bearing soil regions. This paper takes D-W cycles, dry density, water content, and vegetation root (VR) content as four factors and carries out the triaxial test for the orthogonal design of vegetated coal-bearing soil in southern China. The strength curves of vegetated coal-bearing soil under four factors were obtained. The Taguchi method was used to quantitatively analyse the effects of four factors. The microstructure of coal-bearing soil under D-W cycles and the theory of soil reinforcement by VR were discussed. The results indicated that D-W cycles had a significant effect on the cohesion and internal friction angle ( P < 0.05 ). The internal friction angle was little affected by the water content and VR content, which had considerable influence on the cohesion. The cohesion could be improved with less than 2% VR content. The cohesion was the largest for no D-W cycles, 10% water content, and 2% VR content. The links between mineral particles go from a stable layered structure to unsteadiness chain structure with the increase in the number of D-W cycles.
{"title":"Strength of Vegetated Coal-Bearing Soil under Dry-Wet Cycles: An Experimental Study","authors":"Gang Huang, Ming Zheng","doi":"10.1155/2021/6657160","DOIUrl":"https://doi.org/10.1155/2021/6657160","url":null,"abstract":"Strength of vegetated coal-bearing soil is of great significance to evaluate the shallow stability of vegetated slopes in coal-bearing soil regions. This paper takes D-W cycles, dry density, water content, and vegetation root (VR) content as four factors and carries out the triaxial test for the orthogonal design of vegetated coal-bearing soil in southern China. The strength curves of vegetated coal-bearing soil under four factors were obtained. The Taguchi method was used to quantitatively analyse the effects of four factors. The microstructure of coal-bearing soil under D-W cycles and the theory of soil reinforcement by VR were discussed. The results indicated that D-W cycles had a significant effect on the cohesion and internal friction angle (\u0000 \u0000 P\u0000 <\u0000 0.05\u0000 \u0000 ). The internal friction angle was little affected by the water content and VR content, which had considerable influence on the cohesion. The cohesion could be improved with less than 2% VR content. The cohesion was the largest for no D-W cycles, 10% water content, and 2% VR content. The links between mineral particles go from a stable layered structure to unsteadiness chain structure with the increase in the number of D-W cycles.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2021-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46130903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shobha Bhaskara, Sanaulla Pathapalya Fakrudeen, Tegene Desalegn, H. Murthy, V. Bheemaraju
The Schiff base compounds N,N ′ -bis(salicylidine)-4,4 ′ –diaminostilbene(SDS) and N,N ′ -bis(salicylidine)-4,4 ′ -diamino azobenzene(SDA) were synthesized, and their molecular structure was determined by FT-IR and 1H NMR. The corrosion inhibitions of Schiff base compounds on aluminum alloy 2024 in 1 M hydrochloric acid were evaluated by potentiodynamic polarization, impedance techniques, weight loss method, and scanning electron microscopic technique. The potentiodynamic polarization (PDP) studies revealed that SDS and SDA compounds acted predominantly as cathodic inhibitors. The electrochemical impedance spectroscopic (EIS) parameters confirmed the adsorption of SDS and SDA molecules over the surface of aluminum alloy 2024 alloy by forming an inhibitive layer. The weight loss studies showed that the inhibition efficiency of these compounds increases directly with concentration and decreases with an increase in solution temperature and immersion time. The thermodynamic parameters were calculated to investigate the mechanism of corrosion inhibition. The SDA was found to be more effective than SDS and followed the Langmuir adsorption isotherm model. The scanning electron microscopy (SEM) results revealed that the deterioration of the alloy surface is minimal in the presence of an inhibitor. Both Schiff base molecules exhibited superior corrosion inhibition for aluminum alloy 2024 alloy in HCl medium.
合成了席夫碱化合物N，N′-双（水杨基）-4，4′-二氨基二苯乙烯（SDS）和N，N’-双（水杨基）-4,4′-二胺基偶氮苯（SDA），并用FT-IR和1H NMR测定了它们的分子结构。Schiff碱化合物对2024 in 1铝合金的缓蚀作用 用动电位极化法、阻抗法、失重法和扫描电镜技术对M盐酸进行了评价。电位极化（PDP）研究表明，SDS和SDA化合物主要作为阴极抑制剂。电化学阻抗谱（EIS）参数证实了SDS和SDA分子通过形成抑制层而在2024铝合金表面吸附。失重研究表明，这些化合物的抑制效率直接随着浓度的增加而增加，并随着溶液温度和浸泡时间的增加而降低。通过计算热力学参数，探讨了缓蚀机理。SDA比SDS更有效，并遵循Langmuir吸附等温线模型。扫描电子显微镜（SEM）结果显示，在抑制剂存在的情况下，合金表面的劣化最小。两种希夫碱分子对2024铝合金在HCl介质中均表现出优异的缓蚀性能。
{"title":"Evaluation of Corrosion Inhibition Efficiency of Aluminum Alloy 2024 by Diaminostilbene and Azobenzene Schiff Bases in 1 M Hydrochloric Acid","authors":"Shobha Bhaskara, Sanaulla Pathapalya Fakrudeen, Tegene Desalegn, H. Murthy, V. Bheemaraju","doi":"10.1155/2021/5869915","DOIUrl":"https://doi.org/10.1155/2021/5869915","url":null,"abstract":"The Schiff base compounds N,N\u0000 \u0000 \u0000 \u0000 \u0000 ′\u0000 \u0000 \u0000 \u0000 -bis(salicylidine)-4,4\u0000 \u0000 \u0000 \u0000 \u0000 ′\u0000 \u0000 \u0000 \u0000 –diaminostilbene(SDS) and N,N\u0000 \u0000 \u0000 \u0000 \u0000 ′\u0000 \u0000 \u0000 \u0000 -bis(salicylidine)-4,4\u0000 \u0000 \u0000 \u0000 \u0000 ′\u0000 \u0000 \u0000 \u0000 -diamino azobenzene(SDA) were synthesized, and their molecular structure was determined by FT-IR and 1H NMR. The corrosion inhibitions of Schiff base compounds on aluminum alloy 2024 in 1 M hydrochloric acid were evaluated by potentiodynamic polarization, impedance techniques, weight loss method, and scanning electron microscopic technique. The potentiodynamic polarization (PDP) studies revealed that SDS and SDA compounds acted predominantly as cathodic inhibitors. The electrochemical impedance spectroscopic (EIS) parameters confirmed the adsorption of SDS and SDA molecules over the surface of aluminum alloy 2024 alloy by forming an inhibitive layer. The weight loss studies showed that the inhibition efficiency of these compounds increases directly with concentration and decreases with an increase in solution temperature and immersion time. The thermodynamic parameters were calculated to investigate the mechanism of corrosion inhibition. The SDA was found to be more effective than SDS and followed the Langmuir adsorption isotherm model. The scanning electron microscopy (SEM) results revealed that the deterioration of the alloy surface is minimal in the presence of an inhibitor. Both Schiff base molecules exhibited superior corrosion inhibition for aluminum alloy 2024 alloy in HCl medium.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":"1 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2021-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41445875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Qing-Miao Ding, Yongxiang Qin, Tao Shen, Yuning Gao
In this paper, the effect of alternating stray current (AC) density on the corrosion behavior of X80 steel under disbonded coating was studied by electrochemical methods, wire beam electrode (WBE) technology, and surface observation technology. The results showed that under the interference of different AC densities, the corrosion potential of X80 steel under disbonded coating underwent negative deviation, and the degree of negative deviation increased with the increase of AC density. The corrosion current density of X80 steel under disbonded coating with the action of 0~100 A/m2 AC density had few differences. While the corrosion current density of X80 steel with the action of 200~300 A/m2 AC density increased and the corrosion current density was higher than that under low AC density. The cathode area of the wire beam electrode under disbonded coating is mainly distributed outside and the edge of the gap between disbonded coating and X80 steel, while the anode area is mainly distributed inside the gap.
{"title":"Effect of Alternating Stray Current Density on Corrosion Behavior of X80 Steel under Disbonded Coating","authors":"Qing-Miao Ding, Yongxiang Qin, Tao Shen, Yuning Gao","doi":"10.1155/2021/8833346","DOIUrl":"https://doi.org/10.1155/2021/8833346","url":null,"abstract":"In this paper, the effect of alternating stray current (AC) density on the corrosion behavior of X80 steel under disbonded coating was studied by electrochemical methods, wire beam electrode (WBE) technology, and surface observation technology. The results showed that under the interference of different AC densities, the corrosion potential of X80 steel under disbonded coating underwent negative deviation, and the degree of negative deviation increased with the increase of AC density. The corrosion current density of X80 steel under disbonded coating with the action of 0~100 A/m2 AC density had few differences. While the corrosion current density of X80 steel with the action of 200~300 A/m2 AC density increased and the corrosion current density was higher than that under low AC density. The cathode area of the wire beam electrode under disbonded coating is mainly distributed outside and the edge of the gap between disbonded coating and X80 steel, while the anode area is mainly distributed inside the gap.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2021-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44959517","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Aimad Mazkour, S. El hajjaji, N. Labjar, E. Lotfi, M. El Mahi
The use of 5-azidomethyl-7-morpholinomethyl-8-hydroxyquinoline (AMH) as a corrosion inhibitor for AISI 321 stainless steel in 5.5 M polluted phosphoric acid was investigated using the hydrogen evolution technique, linear polarization curves, and impedance spectroscopy. Impedance measurements revealed that the dissolution of AISI 321 in 5.5 M polluted phosphoric acid was controlled by an activation mechanism, unchanged even with the addition of AMH at different concentrations. Polarization results showed that the inhibition ability was enhanced with increasing inhibitor concentration. AMH acted as a mixed-type inhibitor by random adsorption on the alloy surface, whatever the nature of the reaction that is taking place. The adsorption of AMH on the AISI 321 surface was also discussed via the Langmuir adsorption isotherm. The influence of elevating the solution temperature on the corrosion inhibition performance was studied. A quantum chemistry study with the DFT method was also conducted, which supplied a logical and exploitable theoretical explanation of the adsorption and the inhibition action of AMH on AISI 321.
{"title":"Investigation of Corrosion Protection of Austenitic Stainless Steel in 5.5 M Polluted Phosphoric Acid Using 5-Azidomethyl-7-morpholinomethyl-8-hydroxyquinoline as an Ecofriendly Inhibitor","authors":"Aimad Mazkour, S. El hajjaji, N. Labjar, E. Lotfi, M. El Mahi","doi":"10.1155/2021/6666811","DOIUrl":"https://doi.org/10.1155/2021/6666811","url":null,"abstract":"The use of 5-azidomethyl-7-morpholinomethyl-8-hydroxyquinoline (AMH) as a corrosion inhibitor for AISI 321 stainless steel in 5.5 M polluted phosphoric acid was investigated using the hydrogen evolution technique, linear polarization curves, and impedance spectroscopy. Impedance measurements revealed that the dissolution of AISI 321 in 5.5 M polluted phosphoric acid was controlled by an activation mechanism, unchanged even with the addition of AMH at different concentrations. Polarization results showed that the inhibition ability was enhanced with increasing inhibitor concentration. AMH acted as a mixed-type inhibitor by random adsorption on the alloy surface, whatever the nature of the reaction that is taking place. The adsorption of AMH on the AISI 321 surface was also discussed via the Langmuir adsorption isotherm. The influence of elevating the solution temperature on the corrosion inhibition performance was studied. A quantum chemistry study with the DFT method was also conducted, which supplied a logical and exploitable theoretical explanation of the adsorption and the inhibition action of AMH on AISI 321.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":"2021 1","pages":"1-15"},"PeriodicalIF":3.1,"publicationDate":"2021-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64763187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Epoxy polymer, an illustrious barrier corrosion protective coating, was reinforced with metakaolin clay, an eco-friendly inorganic filler to enhance the barrier corrosion protection properties in water and in acidic environment on galvanized steel plates. Various proportions 0, 1, 3, 5, and 7 wt.% of metakaolin fillers were mixed intrinsically with kadilux epoxy and characterized for thermal stability, water absorption according to ASTM G31, and acid immersion according to ASTM D-570 standards, respectively. The reinforced coatings minimized the pore size and density, lower water absorption, and better acid resistance properties especially at 7 wt.% of the fillers. The thermal stability of the films improved beyond 5 wt.% of filler composition.
{"title":"Barrier Corrosion Protection Properties of Metakaolin Clay-Kadilux Epoxy Coatings on Galvanized Steel","authors":"Fantaye Tasew, Ganesh Thothadri","doi":"10.1155/2021/1049021","DOIUrl":"https://doi.org/10.1155/2021/1049021","url":null,"abstract":"Epoxy polymer, an illustrious barrier corrosion protective coating, was reinforced with metakaolin clay, an eco-friendly inorganic filler to enhance the barrier corrosion protection properties in water and in acidic environment on galvanized steel plates. Various proportions 0, 1, 3, 5, and 7 wt.% of metakaolin fillers were mixed intrinsically with kadilux epoxy and characterized for thermal stability, water absorption according to ASTM G31, and acid immersion according to ASTM D-570 standards, respectively. The reinforced coatings minimized the pore size and density, lower water absorption, and better acid resistance properties especially at 7 wt.% of the fillers. The thermal stability of the films improved beyond 5 wt.% of filler composition.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2021-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43142185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cracks lead to a reduction of the bond between concrete and reinforcing steel rebars. A considerable decrease in the bond strength is more dangerous to a structural element’s safety than the loss of the cross-sectional steel reinforcement area. The purpose of this study is to evaluate the bond strength of corroded-damaged structures exposed to severely aggressive marine environments. Eighteen (18) cube specimens with dimensions of 200 mm x 200 mm were cast. They were reinforced with three (3) different diameters of deformed steel and were grouped as unconfined and confined. The specimen was accelerated under a simulated corrosive environment. The experiment results reveal that the bond strength of concrete and steel reinforcement is susceptible to corrosion levels. The degree of corrosion significantly affects the bond strength of concrete and steel. The bond strength and the average crack width have a strong correlation; a minimal amount of corrosion with a minimum crack width of 0.03 mm after cracking reduces the bond strength to an unacceptable level. Stirrups confinement has a significant influence on the bond strength; it provides an excellent means to counteract bond loss. The loss of bond directly affects the serviceability and ultimate strength of reinforced concrete structures. There is an exponential relationship between cement and steel reinforcement’s bond strength with the serviceability and residual strength of reinforced concrete structures.
{"title":"Bond Deterioration of Corroded-Damaged Reinforced Concrete Structures Exposed to Severe Aggressive Marine Environment","authors":"Cecielle N. Dacuan, Virgilio Y. Abellana","doi":"10.1155/2021/8847716","DOIUrl":"https://doi.org/10.1155/2021/8847716","url":null,"abstract":"Cracks lead to a reduction of the bond between concrete and reinforcing steel rebars. A considerable decrease in the bond strength is more dangerous to a structural element’s safety than the loss of the cross-sectional steel reinforcement area. The purpose of this study is to evaluate the bond strength of corroded-damaged structures exposed to severely aggressive marine environments. Eighteen (18) cube specimens with dimensions of \u0000 \u0000 200\u0000 \u0000 mm\u0000 \u0000 x\u0000 \u0000 200\u0000 \u0000 mm\u0000 \u0000 were cast. They were reinforced with three (3) different diameters of deformed steel and were grouped as unconfined and confined. The specimen was accelerated under a simulated corrosive environment. The experiment results reveal that the bond strength of concrete and steel reinforcement is susceptible to corrosion levels. The degree of corrosion significantly affects the bond strength of concrete and steel. The bond strength and the average crack width have a strong correlation; a minimal amount of corrosion with a minimum crack width of 0.03 mm after cracking reduces the bond strength to an unacceptable level. Stirrups confinement has a significant influence on the bond strength; it provides an excellent means to counteract bond loss. The loss of bond directly affects the serviceability and ultimate strength of reinforced concrete structures. There is an exponential relationship between cement and steel reinforcement’s bond strength with the serviceability and residual strength of reinforced concrete structures.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2021-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45787774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Despite extensive work on improving atmospheric corrosion resistance in metals, i.e., steel and alloy, the corrosion rate on the metallic surface is higher at some localized geographical area of the globe. Despite the visible successes in recent coating technology in curbing environmental conditions, it is proposed that the recent increase of atmospheric bioaerosols has a significant role in the dissolution of corrosion-resistant coating over a metallic surface. In this review, the science of atmospheric corrosion on metallic materials was reviewed in the light of the chemical and physical composition of atmospheric bioaerosols and aerosols. It was observed that aside from general conditions (i.e., alloying element level, surface roughness, surface treatment, and microclimate), the bioaerosols content is essential for future research in corrosion. It is recommended that further experimental research be carried out to corroborate the science of atmospheric bioaerosols to different forms of corrosion.
{"title":"Role of Atmospheric Aerosol Content on Atmospheric Corrosion of Metallic Materials","authors":"M. Emetere, S. Afolalu, L. Amusan, A. Mamudu","doi":"10.1155/2021/6637499","DOIUrl":"https://doi.org/10.1155/2021/6637499","url":null,"abstract":"Despite extensive work on improving atmospheric corrosion resistance in metals, i.e., steel and alloy, the corrosion rate on the metallic surface is higher at some localized geographical area of the globe. Despite the visible successes in recent coating technology in curbing environmental conditions, it is proposed that the recent increase of atmospheric bioaerosols has a significant role in the dissolution of corrosion-resistant coating over a metallic surface. In this review, the science of atmospheric corrosion on metallic materials was reviewed in the light of the chemical and physical composition of atmospheric bioaerosols and aerosols. It was observed that aside from general conditions (i.e., alloying element level, surface roughness, surface treatment, and microclimate), the bioaerosols content is essential for future research in corrosion. It is recommended that further experimental research be carried out to corroborate the science of atmospheric bioaerosols to different forms of corrosion.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2021-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42451899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Narayanan, G. G. Sozhamannan, K. Hemalatha, K. Velmurugan, V. Venkatachalapathy
The objective of this work is to evaluate the corrosion behaviour of nanographene oxide reinforced aluminium (Al/GO) metal matrix composites with different immersion time periods using the immersion corrosion technique. The Al/GO composites were fabricated by the ultrasonic gravitational stir casting process. The corrosions of Al/GO were evaluated using a scanning electron microscope. The experimental results revealed that the corrosion rate decreased and weight losses increased with increasing immersion time periods. The nonimmersed Al/GO composites exhibited higher microhardness values compared to the immersed Al/GO composites.
{"title":"Corrosion and Hardness Behaviour of Al/GO Nanocomposites Processed by the Ultrasonic Gravitational Stir Casting Method","authors":"S. Narayanan, G. G. Sozhamannan, K. Hemalatha, K. Velmurugan, V. Venkatachalapathy","doi":"10.1155/2021/6658186","DOIUrl":"https://doi.org/10.1155/2021/6658186","url":null,"abstract":"The objective of this work is to evaluate the corrosion behaviour of nanographene oxide reinforced aluminium (Al/GO) metal matrix composites with different immersion time periods using the immersion corrosion technique. The Al/GO composites were fabricated by the ultrasonic gravitational stir casting process. The corrosions of Al/GO were evaluated using a scanning electron microscope. The experimental results revealed that the corrosion rate decreased and weight losses increased with increasing immersion time periods. The nonimmersed Al/GO composites exhibited higher microhardness values compared to the immersed Al/GO composites.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2021-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45966682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Chadili, M. Rguiti, B. El Ibrahimi, R. Oukhrib, A. Jmiai, M. Beelkhaouda, L. Bammou, M. Hilali, L. Bazzi
According to the literature, the works on the inhibition of aluminum alloy corrosion using naturally occurring compounds are limited. For this, the inhibiting effect of oil mill liquid by-product (OMW) on the corrosion of 3003 aluminum alloy (AA3003) in molar hydrochloric acid solution was evaluated using electrochemical techniques. In parallel, a computational approach based on DFT/B3LYP and Monte Carlo methods was used to understand the inhibition process under electronic and atomic scales, respectively. The experimental results reveal that OMW has a good inhibiting effect on the corrosion of AA3003 alloy in the tested solution and acts as a cathodic inhibitor. The inhibitory efficiency increases by increasing OMW concentration to attain 89% at 6.0 ppm. The effect of temperature shows that the inhibition efficiency of OMW decreases with temperature rising. Nevertheless, a good prevention capacity of 83% is obtained at 338 K. Such interesting achieved protection property was attributed to the adsorption of OMW constituents onto the alloy surface via a mixed physichemisorption process. This process is found to obey the Langmuir adsorption isotherm. Furthermore, the activation thermodynamic parameters of the corrosion process of AA3003 alloy were also determined and discussed. The computational outcomes outlined the ability of the OMW components to interact favorably with the metal surface, hence the formation of a protective layer, which justified the observed inhibition behaviors. Conferring to the present study, OMW can be used as a good green corrosion inhibitor for AA3003 alloy in the acidic medium.
{"title":"Corrosion Inhibition of 3003 Aluminum Alloy in Molar Hydrochloric Acid Solution by Olive Oil Mill Liquid By-Product","authors":"M. Chadili, M. Rguiti, B. El Ibrahimi, R. Oukhrib, A. Jmiai, M. Beelkhaouda, L. Bammou, M. Hilali, L. Bazzi","doi":"10.1155/2021/6662395","DOIUrl":"https://doi.org/10.1155/2021/6662395","url":null,"abstract":"According to the literature, the works on the inhibition of aluminum alloy corrosion using naturally occurring compounds are limited. For this, the inhibiting effect of oil mill liquid by-product (OMW) on the corrosion of 3003 aluminum alloy (AA3003) in molar hydrochloric acid solution was evaluated using electrochemical techniques. In parallel, a computational approach based on DFT/B3LYP and Monte Carlo methods was used to understand the inhibition process under electronic and atomic scales, respectively. The experimental results reveal that OMW has a good inhibiting effect on the corrosion of AA3003 alloy in the tested solution and acts as a cathodic inhibitor. The inhibitory efficiency increases by increasing OMW concentration to attain 89% at 6.0 ppm. The effect of temperature shows that the inhibition efficiency of OMW decreases with temperature rising. Nevertheless, a good prevention capacity of 83% is obtained at 338 K. Such interesting achieved protection property was attributed to the adsorption of OMW constituents onto the alloy surface via a mixed physichemisorption process. This process is found to obey the Langmuir adsorption isotherm. Furthermore, the activation thermodynamic parameters of the corrosion process of AA3003 alloy were also determined and discussed. The computational outcomes outlined the ability of the OMW components to interact favorably with the metal surface, hence the formation of a protective layer, which justified the observed inhibition behaviors. Conferring to the present study, OMW can be used as a good green corrosion inhibitor for AA3003 alloy in the acidic medium.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2021-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43913908","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. A. Florez-Frias, V. Barba, R. López‐Sesenes, L. Landeros-Martínez, J. F. los Rios, M. Casales, J. González-Rodríguez
A tin-containing metallic complex derived from Curcuma longa, bis[1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dionato-κO,κO ′ ]bis(butyl), has been obtained and used as a green corrosion inhibitor for carbon steel in 0.5 M sulfuric acid by using weight loss, electrochemical techniques, and the Density Functional Theory. It was found that the obtained metallic complex greatly decreases the steel corrosion rate by adsorption according to a Frumkin model in a weak, physical type of adsorption. Inhibitor efficiency increased with its concentration, and it acted as a mixed type of inhibitor. Results were supported by quantum-chemical research in order to examine the relationship between structural and electronic properties and the inhibitor efficiency.
{"title":"Use of a Metallic Complex Derived from Curcuma Longa as Green Corrosion Inhibitor for Carbon Steel in Sulfuric Acid","authors":"E. A. Florez-Frias, V. Barba, R. López‐Sesenes, L. Landeros-Martínez, J. F. los Rios, M. Casales, J. González-Rodríguez","doi":"10.1155/2021/6695299","DOIUrl":"https://doi.org/10.1155/2021/6695299","url":null,"abstract":"A tin-containing metallic complex derived from Curcuma longa, bis[1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dionato-κO,κO\u0000 \u0000 \u0000 \u0000 \u0000 ′\u0000 \u0000 \u0000 \u0000 ]bis(butyl), has been obtained and used as a green corrosion inhibitor for carbon steel in 0.5 M sulfuric acid by using weight loss, electrochemical techniques, and the Density Functional Theory. It was found that the obtained metallic complex greatly decreases the steel corrosion rate by adsorption according to a Frumkin model in a weak, physical type of adsorption. Inhibitor efficiency increased with its concentration, and it acted as a mixed type of inhibitor. Results were supported by quantum-chemical research in order to examine the relationship between structural and electronic properties and the inhibitor efficiency.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2021-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43390503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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