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Wet Oxidation Behavior of Near-Stoichiometric SiC Fibres in the Simulated Aeroengine Circumstance 近化学计量SiC纤维在模拟航空发动机环境中的湿氧化行为
IF 3.1 Q2 Materials Science Pub Date : 2018-08-01 DOI: 10.1155/2018/4319354
Liangyu Li, K. Jian, Xianhe Mao, Yifei Wang
The precursor-derived and near-stoichiometric SiC fibres (KD-S) were exposed at 1000–1500°C for 1 h in the simulated aeroengine circumstance of PH2O:O2:Ar = 14:8:78 KPa with the gas rate of 200 ml/min. The results indicated that the oxidized KD-S fibres were covered by silica layer. The oxygen content, grain size of silica, and oxide layer thickness increased, whereas the tensile strength decreased with rising annealing temperature. KD-S fibres treated under simulated aeroengine circumstances showed larger SiO2 grain size, thicker silica layer, and better residual strength than those annealed in dry air. The steam could accelerate the oxidation on KD-S fibres by reducing the active energy. The influence of water vapour on the oxidation behavior of KD-S SiC fibres was investigated and discussed as well.
前体衍生和接近化学计量的SiC纤维(KD-S)在1000–1500°C下暴露1 h在PH2O:O2:Ar=14:8:78的模拟航空发动机环境中 KPa,气体流量为200 ml/分钟。结果表明,氧化后的KD-S纤维被二氧化硅层覆盖。随着退火温度的升高,氧含量、二氧化硅晶粒尺寸和氧化层厚度增加,而抗拉强度降低。在模拟航空发动机环境下处理的KD-S纤维显示出比在干燥空气中退火的纤维更大的SiO2晶粒尺寸、更厚的二氧化硅层和更好的残余强度。蒸汽可以通过降低活性能来加速KD-S纤维的氧化。研究和讨论了水蒸气对KD-S SiC纤维氧化行为的影响。
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引用次数: 0
Synergistic Effect of Carbamide and Sulfate Reducing Bacteria on Corrosion Behavior of Carbon Steel in Soil 尿素和硫酸盐还原菌对土壤中碳钢腐蚀行为的协同作用
IF 3.1 Q2 Materials Science Pub Date : 2018-08-01 DOI: 10.1155/2018/7491501
Ximing Li, Cheng Sun
Synergistic effect of carbamide and sulfate reducing bacteria (SRB) on corrosion behavior of carbon steel was studied in soils with moisture of 20% and 30%, by soil properties measurement, weight loss, polarization curve, and electrochemical impedance spectroscopy. The results show that carbamide decreased the soil redox potential and increased soil pH. In soil without SRB, carbamide made corrosion potential of Q235 steel much more positive and then inhibited corrosion. Meanwhile, in soil with SRB, 0.5 wt% carbamide restrained SRB growth and inhibited biocorrosion of Q235 steel. Corrosion rate of carbon steel decreased in soil with 30% moisture compared with that with 20% moisture.
通过土壤性质测定、失重、极化曲线和电化学阻抗谱等方法,研究了尿素和硫酸盐还原菌(SRB)在含水量为20%和30%的土壤中对碳钢腐蚀行为的协同作用。结果表明:尿素降低了土壤氧化还原电位,提高了土壤ph值;在未添加SRB的土壤中,尿素使Q235钢的腐蚀电位更正,从而抑制了腐蚀;同时,在含有SRB的土壤中,0.5 wt%的尿素抑制SRB的生长,抑制Q235钢的生物腐蚀。碳钢在含水率为30%的土壤中的腐蚀速率比在含水率为20%的土壤中的腐蚀速率降低。
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引用次数: 5
Corrigendum to “Application of a New Method in Identifying the Sludge Deposits from Refineries and Gas Plants: A Case of Laboratory-Based Study” 更正“一种新方法在识别炼油厂和天然气厂污泥沉积物中的应用:以实验室为基础的研究为例”
IF 3.1 Q2 Materials Science Pub Date : 2018-08-01 DOI: 10.1155/2018/8646104
H. Sitepu, Rasha A. Al-Ghamdi, S. R. Zaidi
In the article entitled “Application of a New Method in Identifying the Sludge Deposits from Refineries and Gas Plants: A Case of Laboratory-Based Study” [1], Rasha A. AlGhamdi was missing from the authors’ list. Rasha A. AlGhamdi performed the separation of the inorganic materials part (non-hydrocarbon) from the hydrocarbon part for the complex sample such as sludge deposit collected from theNG line, where the methylene chloride was insoluble. Rasha A. Al-Ghamdi also conducted the materials characterization of hydrocarbon parts using both the thermal gravimetric analysis and gas chromatography mass spectrometry techniques. Additionally, Rasha A. Al-Ghamdi interpreted the results, e.g., type of hydrocarbon (i.e., hydrocarbon type was diesel with the C10–C27) and the amount of inorganic compound, water, and hydrocarbon content (3 wt% of inorganic compound, 25wt% of water, and 72wt% of hydrocarbon content). The corrected authors’ list is shown above.
在题为“一种新方法在识别炼油厂和天然气厂污泥沉积物中的应用:一个基于实验室的研究案例”[1]的文章中,作者名单中缺少Rasha a.AlGhamdi。Rasha A.AlGhamdi对复杂样品(如从天然气管线收集的污泥沉积物)进行了无机材料部分(非烃)与烃部分的分离,其中二氯甲烷不溶。Rasha A.Al Ghamdi还使用热重量分析和气相色谱-质谱技术对碳氢化合物部件进行了材料表征。此外,Rasha A.Al Ghamdi解释了结果,例如,碳氢化合物的类型(即,碳氢化合物类型为C10–C27的柴油)以及无机化合物的量、水和碳氢化合物含量(无机化合物的3 wt%、水的25 wt%和碳氢化合物的72 wt%)。更正后的作者名单如上图所示。
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引用次数: 2
Experimental and Runge–Kutta Method Simulation to Investigate Corrosion Kinetics of Mild Steel in Sulfuric Acid Solutions 试验和龙格-库塔法模拟研究低碳钢在硫酸溶液中的腐蚀动力学
IF 3.1 Q2 Materials Science Pub Date : 2018-07-08 DOI: 10.1155/2018/9087101
I. Alwaan
The mild steel is extensively used in different industrial applications and the biggest problem in the application of mild steel is corrosion. In this work, the reaction kinetics of mild steel with sulfuric acid at different concentrations and at different temperatures were studied in combination with the experimental data and theoretical approach using the Runge–Kutta method. The results revealed that the rate of reaction constant for temperatures in the range of 30–50°C was changed from 2618 to 2793 L3/mol3.h, respectively. The order of reaction of mild steel was 4th order in all temperature ranges. The enthalpy, entropy, and Gibbs free energy of mild steel reaction at a temperature of 298 K were estimated. The activation energy (E/R) of the reaction was 4.829 K. It was concluded that the sulfuric acid reaction with mild steel occurred easily and the inhibitors should be used in these systems.
软钢广泛应用于不同的工业应用中,软钢应用中最大的问题是腐蚀。在这项工作中,结合实验数据和理论方法,使用Runge–Kutta方法研究了低碳钢在不同浓度和不同温度下与硫酸的反应动力学。结果表明,在30–50°C的温度范围内,反应常数的速率分别从2618变为2793 L3/mol3.h。在所有温度范围内,软钢的反应级数为4级。估算了298K温度下软钢反应的焓、熵和吉布斯自由能。反应的活化能(E/R)为4.829K。结果表明,硫酸与软钢的反应很容易发生,应在这些体系中使用抑制剂。
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引用次数: 4
Corrosion Behavior of Welded Joint of Q690 with CMT Twin Q690与CMT孪晶焊接接头的腐蚀行为
IF 3.1 Q2 Materials Science Pub Date : 2018-07-04 DOI: 10.1155/2018/2368717
Peng Liu, Shanguo Han, Y. Yi, Cuixia Yan
Low alloy steel of Q690 was welded with the method of CMT Twin. The corrosion behavior of welded joint had been investigated using scanning vibrating electrode technique (SVET) in 3.5% NaCl solution. The research results showed that the appearance of the troostite increased the hardness of the heat affected zone. Furthermore, the corrosion products of different microstructure were identical, and the white products (Fe(OH)2) of welded joint turned into products of rufous (Fe(OH)3). The quantitative information provided by SVET was discussed, and the corrosion degree was measured by some parameters. In comparison with other areas, the corrosion rates of the overheated zone and the base metal were higher. Then, the corrosion resistance of the weld zone with CMT Twin was greatly improved, when compared with that of the base metal. Therefore, Ni has significant influence on corrosion resistance of weld zone. In summary, it can be discovered that the corrosion rates of various zones were related to the welding heat input.
采用CMT双相焊法焊接低合金钢Q690。采用扫描振动电极技术(SVET)研究了焊接接头在3.5% NaCl溶液中的腐蚀行为。研究结果表明,矫形体的出现提高了热影响区的硬度。不同组织的腐蚀产物相同,焊接接头的白色产物(Fe(OH)2)转变为黄褐色产物(Fe(OH)3)。讨论了SVET提供的定量信息,并通过一些参数测量了腐蚀程度。与其他区域相比,过热区和母材的腐蚀速率更高。然后,与母材相比,CMT Twin焊区的耐蚀性大大提高。因此,Ni对焊缝区的耐蚀性有显著影响。综上所述,可以发现各区域的腐蚀速率与焊接热输入有关。
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引用次数: 2
Improvement of Corrosion Behavior of Nanostructured Ni Coating by Jet Electrodeposition and Laser Remelting 喷射电沉积和激光重熔改善纳米Ni涂层的腐蚀行为
IF 3.1 Q2 Materials Science Pub Date : 2018-07-02 DOI: 10.1155/2018/2786429
H. Fan, Yangpei Zhao, Shankui Wang
An effective method to improve corrosion resistance for the nickel coating on the stainless steel(1Cr18Ni9) is described. The nickel coating was predeposited on the 1Cr18Ni9 by using the jet electrodeposition technology. Then the laser remelting was conducted on the predeposited Ni coating in order to strengthen the coating’s microstructure and the interface between the substrate and the Ni coating. The experimental results revealed that, at current density of 40 A/dm2, the deposited coating had the optimal corrosion resistance because of refined grains and dense interior-structure. After laser remelting, the bonding state between the coating and substrate evolved to a new metallurgical combination from originally mechanical combination. The corrosion rate comparison indicated that Ni coating with compound process of jet electrodeposition and laser remelting had higher corrosion resistance compared with bare 1Cr18Ni9 as well as jet electrodeposited Ni coating.
介绍了一种提高不锈钢(1Cr18Ni9)镍镀层耐蚀性的有效方法。采用喷射电沉积技术在1Cr18Ni9上预沉积了镍涂层。然后对预沉积的Ni涂层进行激光重熔,以增强涂层的微观结构以及基体与Ni涂层之间的界面。实验结果表明,在40A/dm2的电流密度下,沉积的涂层由于晶粒细化和内部结构致密而具有最佳的耐腐蚀性。激光重熔后,涂层与基体的结合状态由原来的机械结合演变为新的冶金结合。腐蚀速率比较表明,喷射电沉积和激光重熔复合工艺的Ni涂层比裸露的1Cr18Ni9和喷射电沉积的Ni涂层具有更高的耐蚀性。
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引用次数: 1
Experimental and Theoretical Studies on the Corrosion Inhibition of Brass in Hydrochloric Acid by N-(4-((4-Benzhydryl Piperazin-1-yl) Methyl Carbamoyl) Phenyl) Furan-2-Carboxamide N-(4-((4-苄基哌嗪-1-基)甲基氨基)苯基)呋喃-2-甲酰胺对黄铜在盐酸中缓蚀作用的实验与理论研究
IF 3.1 Q2 Materials Science Pub Date : 2018-07-02 DOI: 10.1155/2018/9372804
N. Zulfareen, T. Venugopal, K. Kannan
The corrosion inhibition effect of N-(4-((4-Benzhydryl piperazin-1-yl) methyl Carbamoyl) Phenyl) Furan-2-Carboxamide (BFC) on brass in 1M HCl has been investigated using weight loss method, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV). The result reveals that BFC acts as a mixed type corrosion inhibitor with more pronounced effect on anodic domain and the inhibition efficiency of BFC increases with increase in temperature ranges from 30°C to 60°C. AC impedance implies thatRctvalue of BFC increases with increase in concentration. CV indicates that the addition of inhibitor controls the oxidation of the copper on the brass metal. The structural confirmation of BFC was carried out by the spectral studies like FT-IR,1H NMR,13C NMR, and the molecular weight was confirmed by LC-MS. Surface characterization of brass with BFC was analysed using scanning electron microscope (SEM). Quantum chemical parameter was used to calculate the electronic properties of BFC in order to confirm the correlation between the inhibitor effect and molecular structure of BFC. BFC has more negative charge on nitrogen and oxygen atom, which facilitates the adsorption of BFC on the surface of brass.
采用失重法、动电位极化法、电化学阻抗谱(EIS)和循环伏安法研究了N-(4-((4-苄基哌嗪-1-基)甲基氨基)苯基)呋喃-2-甲酰胺(BFC)在1M HCl中对黄铜的缓蚀作用。结果表明,BFC是一种混合型缓蚀剂,对阳极畴的缓蚀效果更为明显,在30°C至60°C的温度范围内,BFC的缓蚀效率随着温度的升高而提高。交流阻抗表明BFC的Rctv值随着浓度的增加而增加。CV表明,抑制剂的加入控制了铜在黄铜金属上的氧化。BFC的结构通过FT-IR、1H NMR、13C NMR等光谱研究进行了确证,分子量通过LC-MS进行了确证。用扫描电子显微镜(SEM)分析了BFC对黄铜表面的表征。利用量子化学参数计算了BFC的电子性质,以证实抑制剂效应与BFC分子结构之间的相关性。BFC在氮和氧原子上具有更多的负电荷,这有利于BFC在黄铜表面的吸附。
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引用次数: 19
Effect of Chloride Ion on Free Nitrite Ion in Cement 氯离子对水泥中游离亚硝酸盐离子的影响
IF 3.1 Q2 Materials Science Pub Date : 2018-07-02 DOI: 10.1155/2018/2940953
Xiangwei Xing, Junzhe Liu, Yanhua Dai, Mengna Yang, Yushun Li
This was an experiment in which chloride was externally permeated into cement paste. The influence of on the content and distribution of free-form in the cement paste was researched using the chemical quantitative analysis method. The action mechanism was investigated by the micro-means of X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that the physical competitive adsorption of with on C-S-H and the chemical substitution of to NO2-AFm caused more free-form in the cement paste. In the cement paste with chloride salt erosion, the concentration in the erosion surface was the lowest, and the concentration reached the highest value at 10mm from the erosion surface. The concentration decreased gradually with the depth from the erosion surface.
这是一个将氯化物从外部渗透到水泥浆中的实验。采用化学定量分析方法,研究了自由基对水泥浆体中自由基含量和分布的影响。利用X射线衍射(XRD)和扫描电子显微镜(SEM)对其作用机理进行了微观研究。结果表明,水对C-S-H的物理竞争吸附和对NO2-AFm的化学取代使水泥浆体更加自由。在氯盐侵蚀的水泥浆体中,侵蚀面浓度最低,在距离侵蚀面10mm处浓度最高。浓度随侵蚀面深度的增加而逐渐降低。
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引用次数: 4
Regression Analysis of Bond Parameters between Corroded Rebar and Concrete Based on Reported Test Data 基于试验数据的锈蚀钢筋与混凝土粘结参数回归分析
IF 3.1 Q2 Materials Science Pub Date : 2018-07-02 DOI: 10.1155/2018/5309243
H. J. Zhou, Y. F. Zhou, Y. Xu, Z. Y. Lin, F. Xing, L. Li
Reinforcement corrosion is a major cause of degradation in reinforced concrete structures. The fragile rust layer and cracking and spalling of the cover caused by splitting stress due to rust expansion can alter bond behaviors significantly. Despite extensive experimental tests, no stochastic model has yet incorporated randomness into the bond parameters model. This paper gathered published experimental data on the bond-slip parameters of pull-out specimens and beam-end specimens. Regression analysis was carried out to identify the best fit of bond strength and the corresponding slip value in the context of different corrosion levels from the recollected test results. An F-test confirmed the regression effect to be significant. Residual data were also analyzed and found to be well described by a normal distribution. Crack width data of the tested specimens were also collected. A regression analysis of the bond strength and maximum crack width was carried out given the comparative simplicity of measuring crack width versus rebar area loss. Results indicate that maximum crack width can also be used to predict bond strength degradation with similar variation magnitude.
钢筋腐蚀是钢筋混凝土结构退化的主要原因。由于锈蚀膨胀引起的劈裂应力导致的脆弱锈层和覆盖层的开裂和剥落会显著改变粘结性能。尽管进行了大量的实验测试,但还没有一个随机模型将随机性纳入债券参数模型。本文收集了已发表的拉拔试件和梁端试件粘结滑移参数的实验数据。进行回归分析,从收集的测试结果中确定不同腐蚀水平下粘结强度和相应滑移值的最佳拟合。F检验证实回归效果显著。还对残差数据进行了分析,发现正态分布可以很好地描述残差数据。还收集了试样的裂纹宽度数据。对粘结强度和最大裂缝宽度进行了回归分析,给出了测量裂缝宽度与钢筋面积损失的相对简单性。结果表明,最大裂纹宽度也可以用来预测具有相似变化幅度的粘结强度退化。
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引用次数: 4
Influence of Hot-Dip Galvanised Coating Morphology on the Adhesion of Organic Coatings Depending on the Zinc Bath Pb Content and the Postgalvanising Cooling Method 热镀锌层形态对有机涂层附着力的影响取决于锌浴铅含量和镀锌后冷却方法
IF 3.1 Q2 Materials Science Pub Date : 2018-07-02 DOI: 10.1155/2018/2102086
M. Nowicka-Nowak, M. Zubielewicz, H. Kania, P. Liberski, M. Sozańska
Hot-dip galvanised coatings used either alone or with an organic coating (duplex system) constitute an effective anticorrosion protection. Adhesion between the coating and the zinc substrate plays a vital role in the durability of the duplex system. Conditions of the galvanising process and alloying additives incorporated into the zinc bath influence mechanical and protective properties as well as thickness, structure, and surface morphology of the zinc coatings. The influence of the surface morphology of zinc coatings on the adhesion of organic coatings was studied. The tests were carried out on zinc coatings produced in baths with varying Pb content and by employing various cooling methods after the galvanising process. It was noted that a rapid cooling in water produces zinc coatings with a fine-grain structure, more suitable for paint application compared to the air-cooled ones, with a spangle.
热镀锌涂层单独使用或与有机涂层(双相体系)一起使用,都能形成有效的防腐保护。镀层与锌基体之间的附着力对双相体系的耐久性起着至关重要的作用。镀锌过程的条件和加入锌浴的合金添加剂影响锌涂层的机械和保护性能以及厚度、结构和表面形态。研究了锌镀层表面形貌对有机镀层附着力的影响。试验是在不同铅含量的镀液中生产的锌涂层上进行的,并在镀锌过程后采用各种冷却方法。人们注意到,在水中快速冷却会产生具有细颗粒结构的锌涂层,与风冷的锌涂层相比,它更适合油漆应用,具有闪亮的光泽。
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引用次数: 2
期刊
International Journal of Corrosion
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