The mild steel is extensively used in different industrial applications and the biggest problem in the application of mild steel is corrosion. In this work, the reaction kinetics of mild steel with sulfuric acid at different concentrations and at different temperatures were studied in combination with the experimental data and theoretical approach using the Runge–Kutta method. The results revealed that the rate of reaction constant for temperatures in the range of 30–50°C was changed from 2618 to 2793 L3/mol3.h, respectively. The order of reaction of mild steel was 4th order in all temperature ranges. The enthalpy, entropy, and Gibbs free energy of mild steel reaction at a temperature of 298 K were estimated. The activation energy (E/R) of the reaction was 4.829 K. It was concluded that the sulfuric acid reaction with mild steel occurred easily and the inhibitors should be used in these systems.
{"title":"Experimental and Runge–Kutta Method Simulation to Investigate Corrosion Kinetics of Mild Steel in Sulfuric Acid Solutions","authors":"I. Alwaan","doi":"10.1155/2018/9087101","DOIUrl":"https://doi.org/10.1155/2018/9087101","url":null,"abstract":"The mild steel is extensively used in different industrial applications and the biggest problem in the application of mild steel is corrosion. In this work, the reaction kinetics of mild steel with sulfuric acid at different concentrations and at different temperatures were studied in combination with the experimental data and theoretical approach using the Runge–Kutta method. The results revealed that the rate of reaction constant for temperatures in the range of 30–50°C was changed from 2618 to 2793 L3/mol3.h, respectively. The order of reaction of mild steel was 4th order in all temperature ranges. The enthalpy, entropy, and Gibbs free energy of mild steel reaction at a temperature of 298 K were estimated. The activation energy (E/R) of the reaction was 4.829 K. It was concluded that the sulfuric acid reaction with mild steel occurred easily and the inhibitors should be used in these systems.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2018-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2018/9087101","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46272185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Low alloy steel of Q690 was welded with the method of CMT Twin. The corrosion behavior of welded joint had been investigated using scanning vibrating electrode technique (SVET) in 3.5% NaCl solution. The research results showed that the appearance of the troostite increased the hardness of the heat affected zone. Furthermore, the corrosion products of different microstructure were identical, and the white products (Fe(OH)2) of welded joint turned into products of rufous (Fe(OH)3). The quantitative information provided by SVET was discussed, and the corrosion degree was measured by some parameters. In comparison with other areas, the corrosion rates of the overheated zone and the base metal were higher. Then, the corrosion resistance of the weld zone with CMT Twin was greatly improved, when compared with that of the base metal. Therefore, Ni has significant influence on corrosion resistance of weld zone. In summary, it can be discovered that the corrosion rates of various zones were related to the welding heat input.
{"title":"Corrosion Behavior of Welded Joint of Q690 with CMT Twin","authors":"Peng Liu, Shanguo Han, Y. Yi, Cuixia Yan","doi":"10.1155/2018/2368717","DOIUrl":"https://doi.org/10.1155/2018/2368717","url":null,"abstract":"Low alloy steel of Q690 was welded with the method of CMT Twin. The corrosion behavior of welded joint had been investigated using scanning vibrating electrode technique (SVET) in 3.5% NaCl solution. The research results showed that the appearance of the troostite increased the hardness of the heat affected zone. Furthermore, the corrosion products of different microstructure were identical, and the white products (Fe(OH)2) of welded joint turned into products of rufous (Fe(OH)3). The quantitative information provided by SVET was discussed, and the corrosion degree was measured by some parameters. In comparison with other areas, the corrosion rates of the overheated zone and the base metal were higher. Then, the corrosion resistance of the weld zone with CMT Twin was greatly improved, when compared with that of the base metal. Therefore, Ni has significant influence on corrosion resistance of weld zone. In summary, it can be discovered that the corrosion rates of various zones were related to the welding heat input.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2018-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2018/2368717","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45779845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
An effective method to improve corrosion resistance for the nickel coating on the stainless steel(1Cr18Ni9) is described. The nickel coating was predeposited on the 1Cr18Ni9 by using the jet electrodeposition technology. Then the laser remelting was conducted on the predeposited Ni coating in order to strengthen the coating’s microstructure and the interface between the substrate and the Ni coating. The experimental results revealed that, at current density of 40 A/dm2, the deposited coating had the optimal corrosion resistance because of refined grains and dense interior-structure. After laser remelting, the bonding state between the coating and substrate evolved to a new metallurgical combination from originally mechanical combination. The corrosion rate comparison indicated that Ni coating with compound process of jet electrodeposition and laser remelting had higher corrosion resistance compared with bare 1Cr18Ni9 as well as jet electrodeposited Ni coating.
{"title":"Improvement of Corrosion Behavior of Nanostructured Ni Coating by Jet Electrodeposition and Laser Remelting","authors":"H. Fan, Yangpei Zhao, Shankui Wang","doi":"10.1155/2018/2786429","DOIUrl":"https://doi.org/10.1155/2018/2786429","url":null,"abstract":"An effective method to improve corrosion resistance for the nickel coating on the stainless steel(1Cr18Ni9) is described. The nickel coating was predeposited on the 1Cr18Ni9 by using the jet electrodeposition technology. Then the laser remelting was conducted on the predeposited Ni coating in order to strengthen the coating’s microstructure and the interface between the substrate and the Ni coating. The experimental results revealed that, at current density of 40 A/dm2, the deposited coating had the optimal corrosion resistance because of refined grains and dense interior-structure. After laser remelting, the bonding state between the coating and substrate evolved to a new metallurgical combination from originally mechanical combination. The corrosion rate comparison indicated that Ni coating with compound process of jet electrodeposition and laser remelting had higher corrosion resistance compared with bare 1Cr18Ni9 as well as jet electrodeposited Ni coating.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2018-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2018/2786429","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44526606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The corrosion inhibition effect of N-(4-((4-Benzhydryl piperazin-1-yl) methyl Carbamoyl) Phenyl) Furan-2-Carboxamide (BFC) on brass in 1M HCl has been investigated using weight loss method, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV). The result reveals that BFC acts as a mixed type corrosion inhibitor with more pronounced effect on anodic domain and the inhibition efficiency of BFC increases with increase in temperature ranges from 30°C to 60°C. AC impedance implies thatRctvalue of BFC increases with increase in concentration. CV indicates that the addition of inhibitor controls the oxidation of the copper on the brass metal. The structural confirmation of BFC was carried out by the spectral studies like FT-IR,1H NMR,13C NMR, and the molecular weight was confirmed by LC-MS. Surface characterization of brass with BFC was analysed using scanning electron microscope (SEM). Quantum chemical parameter was used to calculate the electronic properties of BFC in order to confirm the correlation between the inhibitor effect and molecular structure of BFC. BFC has more negative charge on nitrogen and oxygen atom, which facilitates the adsorption of BFC on the surface of brass.
{"title":"Experimental and Theoretical Studies on the Corrosion Inhibition of Brass in Hydrochloric Acid by N-(4-((4-Benzhydryl Piperazin-1-yl) Methyl Carbamoyl) Phenyl) Furan-2-Carboxamide","authors":"N. Zulfareen, T. Venugopal, K. Kannan","doi":"10.1155/2018/9372804","DOIUrl":"https://doi.org/10.1155/2018/9372804","url":null,"abstract":"The corrosion inhibition effect of N-(4-((4-Benzhydryl piperazin-1-yl) methyl Carbamoyl) Phenyl) Furan-2-Carboxamide (BFC) on brass in 1M HCl has been investigated using weight loss method, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV). The result reveals that BFC acts as a mixed type corrosion inhibitor with more pronounced effect on anodic domain and the inhibition efficiency of BFC increases with increase in temperature ranges from 30°C to 60°C. AC impedance implies thatRctvalue of BFC increases with increase in concentration. CV indicates that the addition of inhibitor controls the oxidation of the copper on the brass metal. The structural confirmation of BFC was carried out by the spectral studies like FT-IR,1H NMR,13C NMR, and the molecular weight was confirmed by LC-MS. Surface characterization of brass with BFC was analysed using scanning electron microscope (SEM). Quantum chemical parameter was used to calculate the electronic properties of BFC in order to confirm the correlation between the inhibitor effect and molecular structure of BFC. BFC has more negative charge on nitrogen and oxygen atom, which facilitates the adsorption of BFC on the surface of brass.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2018-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2018/9372804","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46072137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiangwei Xing, Junzhe Liu, Yanhua Dai, Mengna Yang, Yushun Li
This was an experiment in which chloride was externally permeated into cement paste. The influence of on the content and distribution of free-form in the cement paste was researched using the chemical quantitative analysis method. The action mechanism was investigated by the micro-means of X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that the physical competitive adsorption of with on C-S-H and the chemical substitution of to NO2-AFm caused more free-form in the cement paste. In the cement paste with chloride salt erosion, the concentration in the erosion surface was the lowest, and the concentration reached the highest value at 10mm from the erosion surface. The concentration decreased gradually with the depth from the erosion surface.
{"title":"Effect of Chloride Ion on Free Nitrite Ion in Cement","authors":"Xiangwei Xing, Junzhe Liu, Yanhua Dai, Mengna Yang, Yushun Li","doi":"10.1155/2018/2940953","DOIUrl":"https://doi.org/10.1155/2018/2940953","url":null,"abstract":"This was an experiment in which chloride was externally permeated into cement paste. The influence of on the content and distribution of free-form in the cement paste was researched using the chemical quantitative analysis method. The action mechanism was investigated by the micro-means of X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that the physical competitive adsorption of with on C-S-H and the chemical substitution of to NO2-AFm caused more free-form in the cement paste. In the cement paste with chloride salt erosion, the concentration in the erosion surface was the lowest, and the concentration reached the highest value at 10mm from the erosion surface. The concentration decreased gradually with the depth from the erosion surface.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":"2018 1","pages":"1-6"},"PeriodicalIF":3.1,"publicationDate":"2018-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2018/2940953","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43156171","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
H. J. Zhou, Y. F. Zhou, Y. Xu, Z. Y. Lin, F. Xing, L. Li
Reinforcement corrosion is a major cause of degradation in reinforced concrete structures. The fragile rust layer and cracking and spalling of the cover caused by splitting stress due to rust expansion can alter bond behaviors significantly. Despite extensive experimental tests, no stochastic model has yet incorporated randomness into the bond parameters model. This paper gathered published experimental data on the bond-slip parameters of pull-out specimens and beam-end specimens. Regression analysis was carried out to identify the best fit of bond strength and the corresponding slip value in the context of different corrosion levels from the recollected test results. An F-test confirmed the regression effect to be significant. Residual data were also analyzed and found to be well described by a normal distribution. Crack width data of the tested specimens were also collected. A regression analysis of the bond strength and maximum crack width was carried out given the comparative simplicity of measuring crack width versus rebar area loss. Results indicate that maximum crack width can also be used to predict bond strength degradation with similar variation magnitude.
{"title":"Regression Analysis of Bond Parameters between Corroded Rebar and Concrete Based on Reported Test Data","authors":"H. J. Zhou, Y. F. Zhou, Y. Xu, Z. Y. Lin, F. Xing, L. Li","doi":"10.1155/2018/5309243","DOIUrl":"https://doi.org/10.1155/2018/5309243","url":null,"abstract":"Reinforcement corrosion is a major cause of degradation in reinforced concrete structures. The fragile rust layer and cracking and spalling of the cover caused by splitting stress due to rust expansion can alter bond behaviors significantly. Despite extensive experimental tests, no stochastic model has yet incorporated randomness into the bond parameters model. This paper gathered published experimental data on the bond-slip parameters of pull-out specimens and beam-end specimens. Regression analysis was carried out to identify the best fit of bond strength and the corresponding slip value in the context of different corrosion levels from the recollected test results. An F-test confirmed the regression effect to be significant. Residual data were also analyzed and found to be well described by a normal distribution. Crack width data of the tested specimens were also collected. A regression analysis of the bond strength and maximum crack width was carried out given the comparative simplicity of measuring crack width versus rebar area loss. Results indicate that maximum crack width can also be used to predict bond strength degradation with similar variation magnitude.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2018-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2018/5309243","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42112485","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Nowicka-Nowak, M. Zubielewicz, H. Kania, P. Liberski, M. Sozańska
Hot-dip galvanised coatings used either alone or with an organic coating (duplex system) constitute an effective anticorrosion protection. Adhesion between the coating and the zinc substrate plays a vital role in the durability of the duplex system. Conditions of the galvanising process and alloying additives incorporated into the zinc bath influence mechanical and protective properties as well as thickness, structure, and surface morphology of the zinc coatings. The influence of the surface morphology of zinc coatings on the adhesion of organic coatings was studied. The tests were carried out on zinc coatings produced in baths with varying Pb content and by employing various cooling methods after the galvanising process. It was noted that a rapid cooling in water produces zinc coatings with a fine-grain structure, more suitable for paint application compared to the air-cooled ones, with a spangle.
{"title":"Influence of Hot-Dip Galvanised Coating Morphology on the Adhesion of Organic Coatings Depending on the Zinc Bath Pb Content and the Postgalvanising Cooling Method","authors":"M. Nowicka-Nowak, M. Zubielewicz, H. Kania, P. Liberski, M. Sozańska","doi":"10.1155/2018/2102086","DOIUrl":"https://doi.org/10.1155/2018/2102086","url":null,"abstract":"Hot-dip galvanised coatings used either alone or with an organic coating (duplex system) constitute an effective anticorrosion protection. Adhesion between the coating and the zinc substrate plays a vital role in the durability of the duplex system. Conditions of the galvanising process and alloying additives incorporated into the zinc bath influence mechanical and protective properties as well as thickness, structure, and surface morphology of the zinc coatings. The influence of the surface morphology of zinc coatings on the adhesion of organic coatings was studied. The tests were carried out on zinc coatings produced in baths with varying Pb content and by employing various cooling methods after the galvanising process. It was noted that a rapid cooling in water produces zinc coatings with a fine-grain structure, more suitable for paint application compared to the air-cooled ones, with a spangle.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2018-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2018/2102086","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46573983","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zinc phosphate (ZnP) baths are widely used for increasing corrosion resistance and surface preparation for painting. Studies on exploiting these baths in the reinforced concrete (RC) are still in the early stages. This is probably due to the shortcomings, such as the alkaline instability and high porosity of the obtained coatings. Use of natural pozzolan (NP) as cement replacement is growing rapidly due to its economic, ecological, and technical benefits. The combined effect of using ZnP baths and NP-based cement on the resistance of concrete against damage caused by corrosion has been investigated. Four phosphating baths were prepared: ZnP, ZnP-Ni, ZnP-Cu, and ZnP-Mn. Steel specimens were phosphated at 55-60°C for 15 min. Concrete specimens were produced with four different levels of NP: 0% (control), 10 %, 20%, and 30%. The investigation was carried out using RC specimens where a constant anodic potential was impressed after 28 and 90 days of concrete curing. The electrochemical behavior of the coated steel has further been evaluated in chloride contaminated Ca(OH)2 saturated solution (CH-Cl) using the open circuit potential (OCP), the potentiodynamic polarization, and the polarization resistance with time. The bond strength between the coated steel and concrete has been evaluated by the pull-out test. Test results showed that concrete containing NP at higher replacement levels and steel specimens treated in bication baths exhibited corrosion initiation times several times longer than the control concrete with uncoated steel. In addition, the best corrosion performance was noted in the steel specimen treated in the ZnP-Cu bath. Its corrosion density was about twentyfold lower with respect to the bare steel, and its inhibition efficiency exceeded 95% in (CH-Cl) solution. In addition, its polarization resistance was about fifteenfold lower with respect to the bare steel. SEM, EDX, and XRD techniques have been employed, as well.
{"title":"Inhibition Effect of Natural Pozzolan and Zinc Phosphate Baths on Reinforcing Steel Corrosion","authors":"A. Al-swaidani","doi":"10.1155/2018/9078253","DOIUrl":"https://doi.org/10.1155/2018/9078253","url":null,"abstract":"Zinc phosphate (ZnP) baths are widely used for increasing corrosion resistance and surface preparation for painting. Studies on exploiting these baths in the reinforced concrete (RC) are still in the early stages. This is probably due to the shortcomings, such as the alkaline instability and high porosity of the obtained coatings. Use of natural pozzolan (NP) as cement replacement is growing rapidly due to its economic, ecological, and technical benefits. The combined effect of using ZnP baths and NP-based cement on the resistance of concrete against damage caused by corrosion has been investigated. Four phosphating baths were prepared: ZnP, ZnP-Ni, ZnP-Cu, and ZnP-Mn. Steel specimens were phosphated at 55-60°C for 15 min. Concrete specimens were produced with four different levels of NP: 0% (control), 10 %, 20%, and 30%. The investigation was carried out using RC specimens where a constant anodic potential was impressed after 28 and 90 days of concrete curing. The electrochemical behavior of the coated steel has further been evaluated in chloride contaminated Ca(OH)2 saturated solution (CH-Cl) using the open circuit potential (OCP), the potentiodynamic polarization, and the polarization resistance with time. The bond strength between the coated steel and concrete has been evaluated by the pull-out test. Test results showed that concrete containing NP at higher replacement levels and steel specimens treated in bication baths exhibited corrosion initiation times several times longer than the control concrete with uncoated steel. In addition, the best corrosion performance was noted in the steel specimen treated in the ZnP-Cu bath. Its corrosion density was about twentyfold lower with respect to the bare steel, and its inhibition efficiency exceeded 95% in (CH-Cl) solution. In addition, its polarization resistance was about fifteenfold lower with respect to the bare steel. SEM, EDX, and XRD techniques have been employed, as well.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":"1 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2018-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2018/9078253","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41379561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jundi Geng, Junzhe Liu, Jiali Yan, M. Ba, Z. He, Yushun Li
The microstructures of steel bars were studied by X-ray photoelectron spectroscopy (XPS), and the mechanism of corrosion of steel bars under the corrosion factors was elucidated. The results show that the passivation film and corrosive surface of the steel surface in the solution of the chloride-containing salt were coarser and the surface state was denser. The main corrosion products are FeOOH and FeO. The surface of the steel immersed in the simulated carbonized solution had loose pores. The main components are FeOOH, Fe3O4, and Fe2O3. The surface of the steel bar has a large amount of yellowish brown corrosion products in the simulated carbonization and chloride salt. The surface of the corrosion products was stripped and the main components are FeOOH, Fe3O4, and FeCl3, where the content of FeOOH is as high as 60%. The peak value of iron is gradually increased from the simulated chloride salt solution to the carbonized solution to the combined effect of carbonation and chloride salt; the iron oxide content is increased and corrosion of steel is obviously serious.
{"title":"Chemical Composition of Corrosion Products of Rebar Caused by Carbonation and Chloride","authors":"Jundi Geng, Junzhe Liu, Jiali Yan, M. Ba, Z. He, Yushun Li","doi":"10.1155/2018/7479383","DOIUrl":"https://doi.org/10.1155/2018/7479383","url":null,"abstract":"The microstructures of steel bars were studied by X-ray photoelectron spectroscopy (XPS), and the mechanism of corrosion of steel bars under the corrosion factors was elucidated. The results show that the passivation film and corrosive surface of the steel surface in the solution of the chloride-containing salt were coarser and the surface state was denser. The main corrosion products are FeOOH and FeO. The surface of the steel immersed in the simulated carbonized solution had loose pores. The main components are FeOOH, Fe3O4, and Fe2O3. The surface of the steel bar has a large amount of yellowish brown corrosion products in the simulated carbonization and chloride salt. The surface of the corrosion products was stripped and the main components are FeOOH, Fe3O4, and FeCl3, where the content of FeOOH is as high as 60%. The peak value of iron is gradually increased from the simulated chloride salt solution to the carbonized solution to the combined effect of carbonation and chloride salt; the iron oxide content is increased and corrosion of steel is obviously serious.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2018-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2018/7479383","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46075839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kai Wang, Qinghua Lu, Zexin Jiang, Y. Yi, Jianglong Yi, B. Niu, Jinjun Ma, Huiping Hu
We modified the content of rare-earth elements (REE) in the flux-cored wire used to produce welds of high-strength low-alloy (HSLA) steel. The effect of REE addition on the microstructure as well as on the mechanical and electrochemical properties of the welded metal (WM) was investigated. REE-modified welded metals show very different responses during electrochemical impedance spectroscopy and the potentiodynamic polarization tests. The results indicate that the addition of REE of 0.3 wt.% facilitates a more uniform microstructure and improves both mechanical properties and corrosion resistance in welded metals.
{"title":"Effect of Rare-Earth Elements on the Corrosion Resistance of Flux-Cored Arc-Welded Metal with 10CrNi3MoV Steel","authors":"Kai Wang, Qinghua Lu, Zexin Jiang, Y. Yi, Jianglong Yi, B. Niu, Jinjun Ma, Huiping Hu","doi":"10.1155/2018/4071352","DOIUrl":"https://doi.org/10.1155/2018/4071352","url":null,"abstract":"We modified the content of rare-earth elements (REE) in the flux-cored wire used to produce welds of high-strength low-alloy (HSLA) steel. The effect of REE addition on the microstructure as well as on the mechanical and electrochemical properties of the welded metal (WM) was investigated. REE-modified welded metals show very different responses during electrochemical impedance spectroscopy and the potentiodynamic polarization tests. The results indicate that the addition of REE of 0.3 wt.% facilitates a more uniform microstructure and improves both mechanical properties and corrosion resistance in welded metals.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2018-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2018/4071352","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49406523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：