Ibrahim Hamed, M. M. Osman, O. H. Abdelraheem, M. Nessim, Maryam Galal El mahgary
The efficiency of three new synthesized Gemini surfactants (namely, A312, A314, and A316) of the type 4,4-[1,4phenylenebis(azanylylidene)bis(N,N-dimethyl-N-alkylaminium] bromide is evaluated as corrosion inhibitors for carbon steel API 5L X52 grade in 1M HCl. The relation between the experimental inhibition efficiency and theoretical chemical parameters obtained by computational calculation in order to predict the behavior of the organic compounds as corrosion inhibitors was instigated. The chemical structures were elucidated using1HNMR spectra. Inhibition performance was investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and weight loss tests. The polarization curves show that applied surfactants act as mixed type inhibitors. Nyquist plots showed the semicircle capacitive loop with different surfactants and concentrations. The inhibition efficiency orders are A312 > A314 > A316 with the highest efficiency of 94.87% for A312. Adsorption of inhibitors on API X52 steel surface was found to obey Langmuir isotherm. Theoretical evaluation of the inhibitory effect was performed by computational quantum chemical calculations. The molecule structural parameters (EHOMO), (ELUMO), energy gap (ΔE), and the dipole moment (μ) were determined. The results of experimental inhibition efficiency and theoretical calculated quantum parameters were subjected to correlation analysis.
{"title":"Inhibition of API 5L X52 Pipeline Steel Corrosion in Acidic Medium by Gemini Surfactants: Electrochemical Evaluation and Computational Study","authors":"Ibrahim Hamed, M. M. Osman, O. H. Abdelraheem, M. Nessim, Maryam Galal El mahgary","doi":"10.1155/2019/4857181","DOIUrl":"https://doi.org/10.1155/2019/4857181","url":null,"abstract":"The efficiency of three new synthesized Gemini surfactants (namely, A312, A314, and A316) of the type 4,4-[1,4phenylenebis(azanylylidene)bis(N,N-dimethyl-N-alkylaminium] bromide is evaluated as corrosion inhibitors for carbon steel API 5L X52 grade in 1M HCl. The relation between the experimental inhibition efficiency and theoretical chemical parameters obtained by computational calculation in order to predict the behavior of the organic compounds as corrosion inhibitors was instigated. The chemical structures were elucidated using1HNMR spectra. Inhibition performance was investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and weight loss tests. The polarization curves show that applied surfactants act as mixed type inhibitors. Nyquist plots showed the semicircle capacitive loop with different surfactants and concentrations. The inhibition efficiency orders are A312 > A314 > A316 with the highest efficiency of 94.87% for A312. Adsorption of inhibitors on API X52 steel surface was found to obey Langmuir isotherm. Theoretical evaluation of the inhibitory effect was performed by computational quantum chemical calculations. The molecule structural parameters (EHOMO), (ELUMO), energy gap (ΔE), and the dipole moment (μ) were determined. The results of experimental inhibition efficiency and theoretical calculated quantum parameters were subjected to correlation analysis.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2019-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2019/4857181","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48255911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
As an effective ground-reinforcing system, rockbolts have been widely used in underground excavations. Corrosion of rockbolts has been one of the most reasons for rockbolts system failure. In this paper, the chemical composition and pH values of the groundwater in Sanshandao Gold mine are first tested. Corrosion of the slotted rockbolts used in roadways of the mine is analysed. The corrosion rate of rockbolts is evaluated based on experimental results from similar corrosive conditions. A time-dependent analytical model on anchoring force degradation caused by corrosion of the rockbolt is developed. Furthermore, the effects of corrosion rate and geometric parameters of the slotted rockbolts on anchoring force degradation are discussed. Suggestions on rockbolts support design in corrosive conditions are given. It has been found that, with the corrosion time increasing, the anchoring force between the rock and the rockbolt gradually decreases. The larger the corrosion rate is, the faster the anchoring force decreases. For long-term service roadways under corrosive conditions, a slotted rockbolt with a smaller radius and thicker wall can enhance the anchoring force.
{"title":"Corrosive Environment Assessment and Corrosion-Induced Rockbolt Failure Analysis in a Costal Underground Mine","authors":"Q. Guo, Jiliang Pan, Min Wang, M. Cai, Xun Xi","doi":"10.1155/2019/2105842","DOIUrl":"https://doi.org/10.1155/2019/2105842","url":null,"abstract":"As an effective ground-reinforcing system, rockbolts have been widely used in underground excavations. Corrosion of rockbolts has been one of the most reasons for rockbolts system failure. In this paper, the chemical composition and pH values of the groundwater in Sanshandao Gold mine are first tested. Corrosion of the slotted rockbolts used in roadways of the mine is analysed. The corrosion rate of rockbolts is evaluated based on experimental results from similar corrosive conditions. A time-dependent analytical model on anchoring force degradation caused by corrosion of the rockbolt is developed. Furthermore, the effects of corrosion rate and geometric parameters of the slotted rockbolts on anchoring force degradation are discussed. Suggestions on rockbolts support design in corrosive conditions are given. It has been found that, with the corrosion time increasing, the anchoring force between the rock and the rockbolt gradually decreases. The larger the corrosion rate is, the faster the anchoring force decreases. For long-term service roadways under corrosive conditions, a slotted rockbolt with a smaller radius and thicker wall can enhance the anchoring force.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2019-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2019/2105842","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45894461","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The ecofriendly poly(butylene succinate) extended with 1,6-diisocynatohexane composted with L-histidine (PBSLH) polymer composite was synthesized by condensation polymerization. The polymer composite was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), and scanning electron microscope (SEM-EDX). The inhibition action of the polymer composite was investigated by conventional weight loss, potentiodynamic polarization, variable amplitude micro (VASP), and electrochemical impedance spectroscopy (EIS). The maximum corrosion inhibition efficiency of 78 % was obtained at concentration level of 600 ppm. The results revealed PBSLH as a mixed type corrosion inhibitor. The thermodynamic and kinetic parameters also revealed adsorption of PBSLH on to mild surface as exothermic and the adsorption was conformed to Langmuir model. The morphology of mild steel coupons was investigated by SEM and atomic force microscope (AFM) and the results showed PBSLH to have inhibited corrosion on mild steel in 1 M HCL.
采用缩聚法制备了l -组氨酸(PBSLH)聚合物复合材料- 1,6-二异辛己烷延伸聚丁二酸丁二烯复合材料。采用傅里叶变换红外(FTIR)、x射线衍射(XRD)和扫描电镜(SEM-EDX)对聚合物复合材料进行了表征。采用常规失重法、动电位极化法、变振幅微谱法(VASP)和电化学阻抗谱法(EIS)研究了聚合物复合材料的缓蚀作用。在浓度为600 ppm时，缓蚀效率最高，达到78%。结果表明，PBSLH是一种混合型缓蚀剂。热力学和动力学参数也表明PBSLH在温和表面的吸附为放热吸附，符合Langmuir吸附模型。用SEM和原子力显微镜(AFM)研究了低碳钢片的形貌，结果表明PBSLH在1 M HCL中对低碳钢具有抑制腐蚀的作用。
{"title":"Corrosion Inhibition of Mild Steel by Poly(butylene succinate)-L-histidine Extended with 1,6-diisocynatohexane Polymer Composite in 1 M HCl","authors":"M. G. Tsoeunyane, M. Makhatha, O. Arotiba","doi":"10.1155/2019/7406409","DOIUrl":"https://doi.org/10.1155/2019/7406409","url":null,"abstract":"The ecofriendly poly(butylene succinate) extended with 1,6-diisocynatohexane composted with L-histidine (PBSLH) polymer composite was synthesized by condensation polymerization. The polymer composite was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), and scanning electron microscope (SEM-EDX). The inhibition action of the polymer composite was investigated by conventional weight loss, potentiodynamic polarization, variable amplitude micro (VASP), and electrochemical impedance spectroscopy (EIS). The maximum corrosion inhibition efficiency of 78 % was obtained at concentration level of 600 ppm. The results revealed PBSLH as a mixed type corrosion inhibitor. The thermodynamic and kinetic parameters also revealed adsorption of PBSLH on to mild surface as exothermic and the adsorption was conformed to Langmuir model. The morphology of mild steel coupons was investigated by SEM and atomic force microscope (AFM) and the results showed PBSLH to have inhibited corrosion on mild steel in 1 M HCL.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2019-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2019/7406409","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43744304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
H. Al-Mazeedi, A. Al-Farhan, N. Tanoli, L. Abraham
Galvanic corrosion of carbon steel (CS) coupled to four different alloys, namely, 316 SS, 321 SS, Incoloy 825, and 2205 SS, was studied in deaerated 3.5% ammonium bisulfide solution (ABS) at 60°C by electrochemical techniques under stagnant condition. The electrochemical work included the measurements of the potential of separate alloys as well as the measurements of galvanic potential and galvanic current as a function of time and Evans (polarization) diagrams of coupled metals. The impact of galvanic coupling on the anodic and cathodic reaction rates was determined. It was found that the CS suffered galvanic corrosion when it was coupled to all of the selected alloys but at different rates; so, it is recommended to avoid the galvanic coupling of CS with any of the noble alloys in stagnant deaerated 3.5% ABS at 60°C. Results indicated that the best alloy to be used with the CS in stagnant deaerated 3.5% ABS solution at 60°C is SS 2205 since the galvanic couple has the lowest CR with a less negative Ecorr value, indicating that CS corrodes at a lower rate when it is coupled to SS2205 in this environment.
采用电化学技术研究了碳钢(CS)与316 SS、321 SS、incoly 825和2205 SS 4种不同合金在60℃脱氧3.5%二硫化铵溶液(ABS)中的电偶腐蚀。电化学工作包括测量单独合金的电势，以及测量偶联金属的电势和电流随时间的函数和埃文斯(极化)图。测定了电偶联对阳极和阴极反应速率的影响。结果表明，当CS与所选合金耦合时，CS均受到电偶腐蚀，但腐蚀速率不同;因此，在60℃的滞气脱氧3.5% ABS中，建议避免CS与任何贵金属合金的电偶。结果表明，在60°C的停滞无氧3.5% ABS溶液中，与CS一起使用的最佳合金是SS2205，因为电偶的CR最低，Ecorr负值较小，表明CS在该环境中与SS2205耦合时腐蚀速率较低。
{"title":"A Study of Galvanic Corrosion in Stagnant Ammonium Bisulfide Solution","authors":"H. Al-Mazeedi, A. Al-Farhan, N. Tanoli, L. Abraham","doi":"10.1155/2019/1325169","DOIUrl":"https://doi.org/10.1155/2019/1325169","url":null,"abstract":"Galvanic corrosion of carbon steel (CS) coupled to four different alloys, namely, 316 SS, 321 SS, Incoloy 825, and 2205 SS, was studied in deaerated 3.5% ammonium bisulfide solution (ABS) at 60°C by electrochemical techniques under stagnant condition. The electrochemical work included the measurements of the potential of separate alloys as well as the measurements of galvanic potential and galvanic current as a function of time and Evans (polarization) diagrams of coupled metals. The impact of galvanic coupling on the anodic and cathodic reaction rates was determined. It was found that the CS suffered galvanic corrosion when it was coupled to all of the selected alloys but at different rates; so, it is recommended to avoid the galvanic coupling of CS with any of the noble alloys in stagnant deaerated 3.5% ABS at 60°C. Results indicated that the best alloy to be used with the CS in stagnant deaerated 3.5% ABS solution at 60°C is SS 2205 since the galvanic couple has the lowest CR with a less negative Ecorr value, indicating that CS corrodes at a lower rate when it is coupled to SS2205 in this environment.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2019-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2019/1325169","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46341543","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. Basuki, Dedi Chandra Nababan, F. Muhammad, A. Korda, D. Prajitno
A series of experiments have been conducted to study the resistance of isothermal oxidation in 69.5Fe-14Ni-9Al-7.5Cr (% wt) alloys with some temperature variations of 800, 900, and 1000°C and each temperature is tested for 1, 10, 50, and 150 hours. Based on the analysis conducted on the test results, it is known that the higher the oxidation temperature, the faster the oxidation rate. As for the duration of oxidation, the longer the testing time is, the smaller the weight change per unit sample area is, indicated by a sloping graph. The oxide products found in this study were Fe2O3, Fe3O4, α-Al2O3, NiO, Cr2O3, and NiCr2O4. The rate of oxidation of this alloy at each temperature follows a logarithmic equation indicating that the oxide layer formed is very thin and can protect the metal surface well. The oxidation rate constants at temperatures of 800, 900, and 1000°C are 5.15E-05, 5.57E-05, and 6.74E-05 gr.cm−2, respectively.
{"title":"Isothermal Oxidation Behaviour of 69.5Fe-14Ni-9Al-7.5Cr Alloy at High Temperatures","authors":"E. Basuki, Dedi Chandra Nababan, F. Muhammad, A. Korda, D. Prajitno","doi":"10.1155/2019/8517648","DOIUrl":"https://doi.org/10.1155/2019/8517648","url":null,"abstract":"A series of experiments have been conducted to study the resistance of isothermal oxidation in 69.5Fe-14Ni-9Al-7.5Cr (% wt) alloys with some temperature variations of 800, 900, and 1000°C and each temperature is tested for 1, 10, 50, and 150 hours. Based on the analysis conducted on the test results, it is known that the higher the oxidation temperature, the faster the oxidation rate. As for the duration of oxidation, the longer the testing time is, the smaller the weight change per unit sample area is, indicated by a sloping graph. The oxide products found in this study were Fe2O3, Fe3O4, α-Al2O3, NiO, Cr2O3, and NiCr2O4. The rate of oxidation of this alloy at each temperature follows a logarithmic equation indicating that the oxide layer formed is very thin and can protect the metal surface well. The oxidation rate constants at temperatures of 800, 900, and 1000°C are 5.15E-05, 5.57E-05, and 6.74E-05 gr.cm−2, respectively.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":"1 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2019-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2019/8517648","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41660178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Rocha, Rafael dos Santos Pereira, M. C. L. de Oliveira, R. A. Antunes
The relationship between the surface chemistry and the corrosion resistance of electrochemically nitrided AISI 304 stainless steel samples has been investigated. The nitriding treatment was carried out in HNO3 0.1 M and HNO3 0.1 M + KNO3 0.5 M at room temperature. Samples were subjected to the nitriding procedure for 30 minutes under a cathodic potential of -0.7 VAg/AgCl. The chemical composition of the nitrided layers was assessed by X-ray photoelectron spectroscopy (XPS). Depth profiles of the main elements present in the nitrided layers were also obtained by XPS by etching them with argon ions. The corrosion behavior of the nitrided samples was evaluated by potentiodynamic polarization. The results showed that the nitrided layers consisted of a mixture of chromium nitrides, chromium oxides, iron oxides/oxyhydroxides, and nickel oxide. The best corrosion resistance was obtained by electrochemical nitriding in the HNO3 0.1 M + KNO3 0.5 M solution. This result could be correlated with the composition and thickness of the nitrided layer.
{"title":"Investigation on the Relationship between the Surface Chemistry and the Corrosion Resistance of Electrochemically Nitrided AISI 304 Stainless Steel","authors":"J. Rocha, Rafael dos Santos Pereira, M. C. L. de Oliveira, R. A. Antunes","doi":"10.1155/2019/7023283","DOIUrl":"https://doi.org/10.1155/2019/7023283","url":null,"abstract":"The relationship between the surface chemistry and the corrosion resistance of electrochemically nitrided AISI 304 stainless steel samples has been investigated. The nitriding treatment was carried out in HNO3 0.1 M and HNO3 0.1 M + KNO3 0.5 M at room temperature. Samples were subjected to the nitriding procedure for 30 minutes under a cathodic potential of -0.7 VAg/AgCl. The chemical composition of the nitrided layers was assessed by X-ray photoelectron spectroscopy (XPS). Depth profiles of the main elements present in the nitrided layers were also obtained by XPS by etching them with argon ions. The corrosion behavior of the nitrided samples was evaluated by potentiodynamic polarization. The results showed that the nitrided layers consisted of a mixture of chromium nitrides, chromium oxides, iron oxides/oxyhydroxides, and nickel oxide. The best corrosion resistance was obtained by electrochemical nitriding in the HNO3 0.1 M + KNO3 0.5 M solution. This result could be correlated with the composition and thickness of the nitrided layer.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2019-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2019/7023283","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49394885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Stress corrosion cracking behavior of 4340 steel in oxygen-containing or chloride containing aqueous solution was researched, the tensile experiment results indicated 100°C deaerated distilled water, the rupture of 4340 steel mainly belongs to ductile fracture, the addition of oxygen or chloride would increase the SCC tendency of 4340 steel and transformed the rupture mechanism from ductile fracture to brittle rupture, the existence of oxygen or chloride would decreaseKISCCof 4340 steel in 100°C aqueous solution slightly, the simultaneous action of oxygen and chloride existed, and the simultaneous action would further increase the SCC tendency of 4340 steel in aqueous solution.
{"title":"Corrosion Failure of AISI4340 Steel in Oxygen-Containing Aqueous Chloride Solution","authors":"Ping-Zhu Zhang, Yafei Shi, H. Zhao, Fu-xiang Zhang, Guoqiang Zhang, Sixian Rao","doi":"10.1155/2019/5318290","DOIUrl":"https://doi.org/10.1155/2019/5318290","url":null,"abstract":"Stress corrosion cracking behavior of 4340 steel in oxygen-containing or chloride containing aqueous solution was researched, the tensile experiment results indicated 100°C deaerated distilled water, the rupture of 4340 steel mainly belongs to ductile fracture, the addition of oxygen or chloride would increase the SCC tendency of 4340 steel and transformed the rupture mechanism from ductile fracture to brittle rupture, the existence of oxygen or chloride would decreaseKISCCof 4340 steel in 100°C aqueous solution slightly, the simultaneous action of oxygen and chloride existed, and the simultaneous action would further increase the SCC tendency of 4340 steel in aqueous solution.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2019-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2019/5318290","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44229457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yanyu Cui, Yongxiang Qin, Dilinuer Dilimulati, Yujun Wang
The influence of chloride ion on the corrosion of metal under coating with scratch defects was researched by wire beam electrode (WBE) technology and electrochemical impedance spectroscopy (EIS) technology. The results showed that the current of metal surface could be characterized by the WBE technology. In the case of scratches on the coating, the location of the damage always showed an anodic current, and the cathodic reaction took place adjacent to the damaged location. The cathode area surrounded the defect and migrated to the far end over time. With the increase of Cl- concentration, the corrosion reaction speeded up, the rate of cathode migration also increased, and the speed of coating stripping did as well. Combined with electrochemical impedance spectroscopy, uniform laws were obtained.
{"title":"The Effect of Chlorine Ion on Metal Corrosion Behavior under the Scratch Defect of Coating","authors":"Yanyu Cui, Yongxiang Qin, Dilinuer Dilimulati, Yujun Wang","doi":"10.1155/2019/7982893","DOIUrl":"https://doi.org/10.1155/2019/7982893","url":null,"abstract":"The influence of chloride ion on the corrosion of metal under coating with scratch defects was researched by wire beam electrode (WBE) technology and electrochemical impedance spectroscopy (EIS) technology. The results showed that the current of metal surface could be characterized by the WBE technology. In the case of scratches on the coating, the location of the damage always showed an anodic current, and the cathodic reaction took place adjacent to the damaged location. The cathode area surrounded the defect and migrated to the far end over time. With the increase of Cl- concentration, the corrosion reaction speeded up, the rate of cathode migration also increased, and the speed of coating stripping did as well. Combined with electrochemical impedance spectroscopy, uniform laws were obtained.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2019-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2019/7982893","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43022740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Three types of corrosion inhibitors consisting of sodium diphosphate (Na2H2P2O7), sodium benzoate (NaC7H5O2), and sodium tetraborate (Na2B4O7) were evaluated to analyze their effectiveness to inhibit the aluminum alloy 3303 (UNS A93303) against corrosion, in water-ethylene glycol (C2H6O2) mixture. Potentiodynamic polarization tests were carried out to study the effect of each chemical. The temperature of solutions was 88°C and the aluminum samples were coupled with five other metals consisting of mild steel, stainless steel, brass, copper, and solder to include the effect of galvanic corrosion. The results showed that sodium diphosphate can effectively protect the aluminum alloy 3303 in comparison with two other chemicals. The effect of thermal shocking on the corrosivity of water-ethylene glycol solution was also investigated. It was indicated that the corrosivity of water-ethylene glycol solution increases because of thermal shocking, which oxidizes the aqueous ethylene glycol. The corrosion rate of aluminum alloy 3303 coupled with the five metals in thermal shocked water-ethylene glycol solution is 142 mpy, while it is 94 mpy in fresh water-ethylene glycol solution.
{"title":"Corrosion Study of Aluminum Alloy 3303 in Water-Ethylene Glycol Mixture: Effect of Inhibitors and Thermal Shocking","authors":"Mohammad Asadikiya, Y. Zhong, M. Ghorbani","doi":"10.1155/2019/9020489","DOIUrl":"https://doi.org/10.1155/2019/9020489","url":null,"abstract":"Three types of corrosion inhibitors consisting of sodium diphosphate (Na2H2P2O7), sodium benzoate (NaC7H5O2), and sodium tetraborate (Na2B4O7) were evaluated to analyze their effectiveness to inhibit the aluminum alloy 3303 (UNS A93303) against corrosion, in water-ethylene glycol (C2H6O2) mixture. Potentiodynamic polarization tests were carried out to study the effect of each chemical. The temperature of solutions was 88°C and the aluminum samples were coupled with five other metals consisting of mild steel, stainless steel, brass, copper, and solder to include the effect of galvanic corrosion. The results showed that sodium diphosphate can effectively protect the aluminum alloy 3303 in comparison with two other chemicals. The effect of thermal shocking on the corrosivity of water-ethylene glycol solution was also investigated. It was indicated that the corrosivity of water-ethylene glycol solution increases because of thermal shocking, which oxidizes the aqueous ethylene glycol. The corrosion rate of aluminum alloy 3303 coupled with the five metals in thermal shocked water-ethylene glycol solution is 142 mpy, while it is 94 mpy in fresh water-ethylene glycol solution.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2019-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2019/9020489","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46464511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ZK60 magnesium alloy sheets with 0.65 mm thickness were successfully fabricated by twin roll casting (TRC) and subsequent hot rolling process. Fine equiaxed grains were obtained after T6 treatment by the short-term TRC and hot rolling process, and the grain size for different reduction ratio per pass was similar. The studied sheets exhibited high strength and elongation, and the tensile strength, yield strengths, and elongation for the 10% and 30% reduction per pass were above 400 MPa, 300 MPa, and 17.0 %, respectively. The damping capacity values at low strain decreased with increasing the reduction ration per pass and the values at high strain were similar for the different reduction ration per pass. The lower reduction ratio per pass and the heat treatment between rolling passes can improve the mobility of dislocations, which indicated that this process was beneficial for improving damping capacity. Compared with higher reduction ratio per pass, the high tensile properties and damping capacity were obtained by 10% reduction per pass hot rolling process.
{"title":"Microstructure and Damping Capacity of ZK60 Alloy Sheets Fabricated by Twin Roll Casting and Hot Rolling Process","authors":"Hongmei Chen, Xiaowen Li","doi":"10.1155/2019/2618737","DOIUrl":"https://doi.org/10.1155/2019/2618737","url":null,"abstract":"ZK60 magnesium alloy sheets with 0.65 mm thickness were successfully fabricated by twin roll casting (TRC) and subsequent hot rolling process. Fine equiaxed grains were obtained after T6 treatment by the short-term TRC and hot rolling process, and the grain size for different reduction ratio per pass was similar. The studied sheets exhibited high strength and elongation, and the tensile strength, yield strengths, and elongation for the 10% and 30% reduction per pass were above 400 MPa, 300 MPa, and 17.0 %, respectively. The damping capacity values at low strain decreased with increasing the reduction ration per pass and the values at high strain were similar for the different reduction ration per pass. The lower reduction ratio per pass and the heat treatment between rolling passes can improve the mobility of dislocations, which indicated that this process was beneficial for improving damping capacity. Compared with higher reduction ratio per pass, the high tensile properties and damping capacity were obtained by 10% reduction per pass hot rolling process.","PeriodicalId":13893,"journal":{"name":"International Journal of Corrosion","volume":" ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2019-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2019/2618737","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45591749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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