In this paper, the composition of binary nonazeotropic working fluids is explored from the perspective of improving OTEC-ORC efficiency, and the turbine is designed to accommodate with the working fluid. It is found that the OTEC-ORC using a R152a/R32 mixture as the working fluid is significantly higher than the OTEC-ORC thermal efficiency and system efficiency of the pure NH3, and the optimal composition of the mixed working fluid R152a/R32 is determined to be 85 : 15 with the thermal efficiency and the system efficiency of 2.8% and 1.7%, respectively, improving by 35.7% and 151.2% compared to the NH3 ORC. According to the determined working fluid, a one-dimensional (1-D) design and CFD simulation analysis simulation are carried out on the turbine. The 1-D calculation results are in good agreement with the three-dimensional (3-D) results. At the design point, the turbine output is 83.84 kW, and the isentropic efficiency is 87.53%. At the off-design point, turbines have better off-design performance, indicating that the designed turbine also has good adaptability.
{"title":"Performance Improvement of OTEC-ORC and Turbine Based on Binary Zeotropic Working Fluid","authors":"Q. Ma, Jie-guang Huang, Zezhou Gao, Hui Lu, Hongfeng Luo, Jingru Li, Zhongye Wu, Xinrang Feng","doi":"10.1155/2023/8892450","DOIUrl":"https://doi.org/10.1155/2023/8892450","url":null,"abstract":"In this paper, the composition of binary nonazeotropic working fluids is explored from the perspective of improving OTEC-ORC efficiency, and the turbine is designed to accommodate with the working fluid. It is found that the OTEC-ORC using a R152a/R32 mixture as the working fluid is significantly higher than the OTEC-ORC thermal efficiency and system efficiency of the pure NH3, and the optimal composition of the mixed working fluid R152a/R32 is determined to be 85 : 15 with the thermal efficiency and the system efficiency of 2.8% and 1.7%, respectively, improving by 35.7% and 151.2% compared to the NH3 ORC. According to the determined working fluid, a one-dimensional (1-D) design and CFD simulation analysis simulation are carried out on the turbine. The 1-D calculation results are in good agreement with the three-dimensional (3-D) results. At the design point, the turbine output is 83.84 kW, and the isentropic efficiency is 87.53%. At the off-design point, turbines have better off-design performance, indicating that the designed turbine also has good adaptability.","PeriodicalId":13921,"journal":{"name":"International Journal of Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45941362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The textile industry is one of the biggest water consumption production areas and its waste is essential to cause ecological contamination as they deliver questionable color, weighty metal, and degradable natural and inorganic results whenever arranged without treatment. The natural treatment strategy is not broadly drilled because of its intricate method. In the adsorption method, for example, actuated carbon was limited by prudence of its significant expense and low adsorption limit. This study has completed the combination and portrayal of bagasse cellulose-based hydrogel for the expulsion of methylene blue color from textile industry wastewater. The study furnishes a major critical contributing option for biodegradable adsorption material by supplanting the conventional color evacuation method with a nonconventional one that showsthe attainability of horticultural waste for a union of the hydrogel as opposed to noninexhaustible petrochemical based and show the capability of involving hydrogel for the expulsion of harmful contamination from the textile industry. The hydrogel was combined utilizing free extreme polymerization that can utilize acrylic corrosive (AA) and citrus extract as cross-connecting specialists and monomers individually. FTIR, XRD, and conduct metric titration are the primary hardware utilized for the portrayal of the hydrogel. The cycle boundaries that can influence the color evacuation proficiency of hydrogel, for example, pH, contact time, and temperature have been examined. A focal composite plan by rotatable component is the technique used to browse reaction surface strategies to control the tests with the communication of cycle boundaries.
{"title":"Analysis of Bagasse Cellulose-Based Hydrogel for Methylene Blue Removal from Textile Industry Wastewater","authors":"Bayisa Dame Tesema, Tariku Ayala Chamada","doi":"10.1155/2023/2313874","DOIUrl":"https://doi.org/10.1155/2023/2313874","url":null,"abstract":"The textile industry is one of the biggest water consumption production areas and its waste is essential to cause ecological contamination as they deliver questionable color, weighty metal, and degradable natural and inorganic results whenever arranged without treatment. The natural treatment strategy is not broadly drilled because of its intricate method. In the adsorption method, for example, actuated carbon was limited by prudence of its significant expense and low adsorption limit. This study has completed the combination and portrayal of bagasse cellulose-based hydrogel for the expulsion of methylene blue color from textile industry wastewater. The study furnishes a major critical contributing option for biodegradable adsorption material by supplanting the conventional color evacuation method with a nonconventional one that showsthe attainability of horticultural waste for a union of the hydrogel as opposed to noninexhaustible petrochemical based and show the capability of involving hydrogel for the expulsion of harmful contamination from the textile industry. The hydrogel was combined utilizing free extreme polymerization that can utilize acrylic corrosive (AA) and citrus extract as cross-connecting specialists and monomers individually. FTIR, XRD, and conduct metric titration are the primary hardware utilized for the portrayal of the hydrogel. The cycle boundaries that can influence the color evacuation proficiency of hydrogel, for example, pH, contact time, and temperature have been examined. A focal composite plan by rotatable component is the technique used to browse reaction surface strategies to control the tests with the communication of cycle boundaries.","PeriodicalId":13921,"journal":{"name":"International Journal of Chemical Engineering","volume":"108 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136334575","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
H. A. González-Ponce, D. Mendoza-Castillo, A. Bonilla-Petriciolet, H. Reynel-Ávila, K. I. Camacho-Aguilar
High concentrations of fluoride (F−) in drinking water represent a public health threat, and consequently, effective and sustainable methods are required to improve the water quality, mainly in developing and low-income countries. This study focused on the thermodynamics of fluoride adsorption on bone char regenerated with NaOH for water defluoridation. A detailed analysis of the number of fluoride adsorption/desorption cycles, their impact on the performance and surface chemistry of bone char using different NaOH concentrations, and modeling of the adsorption mechanism using statistical physics theory was carried out. The results showed that 0.075 mol/L NaOH was effective in recuperating the defluoridation properties of bone char with a regeneration efficiency higher than 90% during five adsorption/desorption cycles. Bone char regeneration efficiency decreased up to 64% after ten adsorption/desorption cycles with a maximum fluoride adsorption capacity of 0.18 mmol/g. NaOH restored the bone char surface properties for ligand exchange of the fluoride anions via the hydroxyapatite functionalities contained in this adsorbent. It was calculated that around 0.25–0.46 mmol/g hydroxyapatite ligand exchange sites of regenerated bone char samples could be involved in the fluoride adsorption, which was also expected to be a mono-ligand mechanism. The reduction in defluoridation properties of bone char during the regeneration cycles was attributed to the decrease in the ligand exchange capacity as well as the deactivation and blocking of some functional groups of hydroxyapatite, which limited their participation in consecutive adsorption processes. This study contributes to the optimization of the recycling and reuse of bone char for fluoride removal from water to reduce the operating defluoridation costs, thus enhancing the application of this technology in low-income areas where fluorinated water represents a threat to public health.
{"title":"Regeneration Analysis of Bone Char Used in Water Defluoridation: Chemical Desorption Route, Surface Chemistry Analysis and Modeling","authors":"H. A. González-Ponce, D. Mendoza-Castillo, A. Bonilla-Petriciolet, H. Reynel-Ávila, K. I. Camacho-Aguilar","doi":"10.1155/2023/8378162","DOIUrl":"https://doi.org/10.1155/2023/8378162","url":null,"abstract":"High concentrations of fluoride (F−) in drinking water represent a public health threat, and consequently, effective and sustainable methods are required to improve the water quality, mainly in developing and low-income countries. This study focused on the thermodynamics of fluoride adsorption on bone char regenerated with NaOH for water defluoridation. A detailed analysis of the number of fluoride adsorption/desorption cycles, their impact on the performance and surface chemistry of bone char using different NaOH concentrations, and modeling of the adsorption mechanism using statistical physics theory was carried out. The results showed that 0.075 mol/L NaOH was effective in recuperating the defluoridation properties of bone char with a regeneration efficiency higher than 90% during five adsorption/desorption cycles. Bone char regeneration efficiency decreased up to 64% after ten adsorption/desorption cycles with a maximum fluoride adsorption capacity of 0.18 mmol/g. NaOH restored the bone char surface properties for ligand exchange of the fluoride anions via the hydroxyapatite functionalities contained in this adsorbent. It was calculated that around 0.25–0.46 mmol/g hydroxyapatite ligand exchange sites of regenerated bone char samples could be involved in the fluoride adsorption, which was also expected to be a mono-ligand mechanism. The reduction in defluoridation properties of bone char during the regeneration cycles was attributed to the decrease in the ligand exchange capacity as well as the deactivation and blocking of some functional groups of hydroxyapatite, which limited their participation in consecutive adsorption processes. This study contributes to the optimization of the recycling and reuse of bone char for fluoride removal from water to reduce the operating defluoridation costs, thus enhancing the application of this technology in low-income areas where fluorinated water represents a threat to public health.","PeriodicalId":13921,"journal":{"name":"International Journal of Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48415224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wei Xu, Yan Lei, Mengting Zhang, Xueping Liu, Lihua Hu, G. Xiao, Lijing Gao
Herein, a kind of three-dimensional hollow Mg-Ca-Al hydrotalcite-like compounds (HTLCs) microsphere was prepared by self-assembly of hydrotalcite-like nanosheets. Mg-Ca-Al HTLCs microsphere (MS) has large specific surface area and large pore size, and the modification of KF·2H2O increases numerous alkaline active sites on the surface of the catalyst. The prepared catalyst has excellent catalytic effect for the production of biodiesel by transesterification. Under the optimal conditions of the catalyst addition amount which accounts for 2% of the weight of oil, the biodiesel yield of the best catalyst is as high as 92% within 30 minutes. This article also provides a paradigm of a rational structural design for regulating the morphology of HTLCs.
{"title":"3D Hollow Mg-Ca-Al Hydrotalcite-Like Compounds Doped with KF for Catalytic Transesterification","authors":"Wei Xu, Yan Lei, Mengting Zhang, Xueping Liu, Lihua Hu, G. Xiao, Lijing Gao","doi":"10.1155/2023/9944183","DOIUrl":"https://doi.org/10.1155/2023/9944183","url":null,"abstract":"Herein, a kind of three-dimensional hollow Mg-Ca-Al hydrotalcite-like compounds (HTLCs) microsphere was prepared by self-assembly of hydrotalcite-like nanosheets. Mg-Ca-Al HTLCs microsphere (MS) has large specific surface area and large pore size, and the modification of KF·2H2O increases numerous alkaline active sites on the surface of the catalyst. The prepared catalyst has excellent catalytic effect for the production of biodiesel by transesterification. Under the optimal conditions of the catalyst addition amount which accounts for 2% of the weight of oil, the biodiesel yield of the best catalyst is as high as 92% within 30 minutes. This article also provides a paradigm of a rational structural design for regulating the morphology of HTLCs.","PeriodicalId":13921,"journal":{"name":"International Journal of Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44390129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In a biogas plant, the acetic acid concentration is a major component of the substrate as it determines the pH value, and this pH value correlates with the volume of biogas produced. Since it requires specialized laboratory equipment, the concentration of acetic acid in a biogas substrate cannot be measured on-line. The project aims to use NIR sensors and machine learning algorithms to estimate the acetic acid concentration in a biogas substrate based on the measured intensities of the substrate. As a result of this project, it was possible to determine whether the acetic acid concentration in a biogas substrate is higher or lower than 2 g/l using machine learning models.
{"title":"Estimation of Acetic Acid Concentration from Biogas Samples Using Machine Learning","authors":"Lingga Aksara Putra, B. Huber, M. Gaderer","doi":"10.1155/2023/2871769","DOIUrl":"https://doi.org/10.1155/2023/2871769","url":null,"abstract":"In a biogas plant, the acetic acid concentration is a major component of the substrate as it determines the pH value, and this pH value correlates with the volume of biogas produced. Since it requires specialized laboratory equipment, the concentration of acetic acid in a biogas substrate cannot be measured on-line. The project aims to use NIR sensors and machine learning algorithms to estimate the acetic acid concentration in a biogas substrate based on the measured intensities of the substrate. As a result of this project, it was possible to determine whether the acetic acid concentration in a biogas substrate is higher or lower than 2 g/l using machine learning models.","PeriodicalId":13921,"journal":{"name":"International Journal of Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46078896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tannery hair wastes are becoming a challenge for tanners regarding environmental pollution control and human health. In this study, an experiment had been designed to hydrolyse sheep hair in an alkaline medium, and the operational condition for the alkaline extraction of KH has been modeled and optimized. The structure, morphology, functional groups, particle size, and molecular mass of the KH extracts were evaluated experimentally by scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), particle size analysis, and SDS-PAGE analysis, respectively. FTIR analysis of the extract confirmed the presence of carboxylic, amide, and aldehyde functional groups and alkyl side chains of amino acids. The molecular weight of the extracted keratin ranges between 3–15 kDa, and X-ray diffraction (XRD) analysis showed an amorphous form of structure with two peaks at 2 theta of 9.36° and 21.16° due to α -helix and β - sheet structure in keratin. Response surface methodology (RSM) coupled with BOX-Behnken design was applied as a statistical tool to investigate the effect of extraction time, the concentration of the hydrolysing agent, and temperature on the response variable (yield of keratin protein). The concentration of the hydrolysing agent was found to be the most significant factor affecting the speed of extraction, but its gradual increase tends to affect the protein content of the extract. Optimum parameters of 0.5 N, 80°C, and 3.5 hr were obtained for the concentration of NaOH, temperature, and extraction time, respectively, with a maximum average protein yield of 91.5% and a percentage total nitrogen content of 14.6% using the Kjeldahl method and 86.57% using the biuret test method.
{"title":"Optimization of Keratin Hydrolysate Extraction from Tannery Sheep Hair Waste","authors":"Ashagrie Mengistu, K. Angassa, Israel Tessema","doi":"10.1155/2023/9293505","DOIUrl":"https://doi.org/10.1155/2023/9293505","url":null,"abstract":"Tannery hair wastes are becoming a challenge for tanners regarding environmental pollution control and human health. In this study, an experiment had been designed to hydrolyse sheep hair in an alkaline medium, and the operational condition for the alkaline extraction of KH has been modeled and optimized. The structure, morphology, functional groups, particle size, and molecular mass of the KH extracts were evaluated experimentally by scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), particle size analysis, and SDS-PAGE analysis, respectively. FTIR analysis of the extract confirmed the presence of carboxylic, amide, and aldehyde functional groups and alkyl side chains of amino acids. The molecular weight of the extracted keratin ranges between 3–15 kDa, and X-ray diffraction (XRD) analysis showed an amorphous form of structure with two peaks at 2 theta of 9.36° and 21.16° due to \u0000 \u0000 α\u0000 \u0000 -helix and \u0000 \u0000 β\u0000 \u0000 - sheet structure in keratin. Response surface methodology (RSM) coupled with BOX-Behnken design was applied as a statistical tool to investigate the effect of extraction time, the concentration of the hydrolysing agent, and temperature on the response variable (yield of keratin protein). The concentration of the hydrolysing agent was found to be the most significant factor affecting the speed of extraction, but its gradual increase tends to affect the protein content of the extract. Optimum parameters of 0.5 N, 80°C, and 3.5 hr were obtained for the concentration of NaOH, temperature, and extraction time, respectively, with a maximum average protein yield of 91.5% and a percentage total nitrogen content of 14.6% using the Kjeldahl method and 86.57% using the biuret test method.","PeriodicalId":13921,"journal":{"name":"International Journal of Chemical Engineering","volume":"1 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41312602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ionic liquids (ILs) are proposed as potential “green” solvents with remarkable properties. Deep eutectic solvents (DESs) are a new type of ILs with additional properties, such as higher biodegradability and a lower price. ILs and DESs are “green” absorbents for various gas separations, such as CO2/N2, CO2/H2/CO, H2S/CH4, and N2O/N2. Due to their large number, the screening of ILs is crucial. Although ILs with high absorption capacities were screened using gas solubility and selectivity, it is important to consider the energy and solvents used in the process. In this paper, the absorbent amount and the energy consumption were used for screening absorbents for various gas separation processes. The results reveal that physical IL [Bmim][DCA] and chemical IL [Eeim][Ac] are screened for CO2/N2 and CO2/H2/CO separation, physical IL [Omim][PF6] for H2S/CH4 separation, and physical IL [P66614][eFAP] for NO/N2 separation. The screened ILs offer some advantages over commercial absorbents in terms of lower energy consumption or amount.
{"title":"Screening of Pure ILs and DESs for CO2 Separation, N2O Separation, and H2S Separation Processes","authors":"Yin Zhang, Xuzhao Yang, Jingli Han, Junfeng Tian, Ting Zhang, Yakun Li, Jiangqiang Zhang, Yuxin Shi, Jingjing Zhang","doi":"10.1155/2023/8691957","DOIUrl":"https://doi.org/10.1155/2023/8691957","url":null,"abstract":"Ionic liquids (ILs) are proposed as potential “green” solvents with remarkable properties. Deep eutectic solvents (DESs) are a new type of ILs with additional properties, such as higher biodegradability and a lower price. ILs and DESs are “green” absorbents for various gas separations, such as CO2/N2, CO2/H2/CO, H2S/CH4, and N2O/N2. Due to their large number, the screening of ILs is crucial. Although ILs with high absorption capacities were screened using gas solubility and selectivity, it is important to consider the energy and solvents used in the process. In this paper, the absorbent amount and the energy consumption were used for screening absorbents for various gas separation processes. The results reveal that physical IL [Bmim][DCA] and chemical IL [Eeim][Ac] are screened for CO2/N2 and CO2/H2/CO separation, physical IL [Omim][PF6] for H2S/CH4 separation, and physical IL [P66614][eFAP] for NO/N2 separation. The screened ILs offer some advantages over commercial absorbents in terms of lower energy consumption or amount.","PeriodicalId":13921,"journal":{"name":"International Journal of Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44705876","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The behavior of droplets collision in a flash evaporation ambient widely exists in various fields. In this work, the deformation analysis and thermal analysis models were established under the condition of flash via a computational fluid dynamics (CFD) method. First, the effects of initial temperature and collision velocity on heat and mass transfer during evaporation were considered. Then, the morphology change of the liquid phase, the mass change, and their influencing factors during the droplet evaporation process were analyzed. A very good agreement is observed between the results of this paper and the published literature. The results show that the interaction between the initial collision velocity and the initial temperature affects the heat and mass transfer performance. The initial collision velocity influences the heat and mass transfer process of the evaporating droplet by affecting the deformation characteristics of the droplet. The collision velocity and the liquid temperature have a competitive relationship with the evaporation process. Under a low-initial temperature, the collision velocity played a leading role in the evaporation of the liquid phase and the mass transfer of steam.
{"title":"Simulation of Mass and Heat Transfer of Droplets Collision in a Flash Evaporation Pattern","authors":"Facheng Qiu, Xianming Zhang, Xinjie Chai, Yingying Dong, Xingjuan Xie, Zuohua Liu, Renlong Liu, Wensheng Li","doi":"10.1155/2023/3574285","DOIUrl":"https://doi.org/10.1155/2023/3574285","url":null,"abstract":"The behavior of droplets collision in a flash evaporation ambient widely exists in various fields. In this work, the deformation analysis and thermal analysis models were established under the condition of flash via a computational fluid dynamics (CFD) method. First, the effects of initial temperature and collision velocity on heat and mass transfer during evaporation were considered. Then, the morphology change of the liquid phase, the mass change, and their influencing factors during the droplet evaporation process were analyzed. A very good agreement is observed between the results of this paper and the published literature. The results show that the interaction between the initial collision velocity and the initial temperature affects the heat and mass transfer performance. The initial collision velocity influences the heat and mass transfer process of the evaporating droplet by affecting the deformation characteristics of the droplet. The collision velocity and the liquid temperature have a competitive relationship with the evaporation process. Under a low-initial temperature, the collision velocity played a leading role in the evaporation of the liquid phase and the mass transfer of steam.","PeriodicalId":13921,"journal":{"name":"International Journal of Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45344566","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
G. Aleid, A. Alshammari, Asma D. Alomari, Shehu Sa’ad Abdullahi, Rania Edrees Adam Mohammad, Rokhsana Mohammed Ismail Abdulrahman
A potential and developing green technology for producing renewable energy and treating wastewater is the microbial fuel cell (MFC). Despite several advancements, there are still several serious problems with this approach. In the present work, we addressed the problem of the organic substrate in MFC, which is necessary for the degradation of metal ions in conjunction with the production of energy. The utilization of fruit waste as a carbon source was strongly suggested in earlier research. Hence, the mango peel was used as a substrate in the current study. Within 25 days of operation, a 102-mV voltage was achieved in 13 days, while the degradation efficiency of Cr3+ was 69.21%, Co2+ was 72%, and Ni2+ was 70.11%. The procedure is carried out in the batch mode, and there is no continuous feeding of the organic substrate. In addition, a detailed explanation of the hypothesized mechanism for this investigation is provided, which focuses on the process of metal ion degradation. Lastly, future and concluding remarks are also enclosed.
{"title":"Degradation of Metal Ions with Electricity Generation by Using Fruit Waste as an Organic Substrate in the Microbial Fuel Cell","authors":"G. Aleid, A. Alshammari, Asma D. Alomari, Shehu Sa’ad Abdullahi, Rania Edrees Adam Mohammad, Rokhsana Mohammed Ismail Abdulrahman","doi":"10.1155/2023/1334279","DOIUrl":"https://doi.org/10.1155/2023/1334279","url":null,"abstract":"A potential and developing green technology for producing renewable energy and treating wastewater is the microbial fuel cell (MFC). Despite several advancements, there are still several serious problems with this approach. In the present work, we addressed the problem of the organic substrate in MFC, which is necessary for the degradation of metal ions in conjunction with the production of energy. The utilization of fruit waste as a carbon source was strongly suggested in earlier research. Hence, the mango peel was used as a substrate in the current study. Within 25 days of operation, a 102-mV voltage was achieved in 13 days, while the degradation efficiency of Cr3+ was 69.21%, Co2+ was 72%, and Ni2+ was 70.11%. The procedure is carried out in the batch mode, and there is no continuous feeding of the organic substrate. In addition, a detailed explanation of the hypothesized mechanism for this investigation is provided, which focuses on the process of metal ion degradation. Lastly, future and concluding remarks are also enclosed.","PeriodicalId":13921,"journal":{"name":"International Journal of Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46238836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Al-Samhan, J. Al-Fadhli, A. M. Al-Otaibi, R. Bouresli
Maximizing the production of high-value olefins from heavy crude oil is a crucial topic in the downstream refining industry. However, converting heavier fractions is a major challenge due to the small pore size of the zeolites. Therefore, this work aimed to develop extrudate zeolite catalysts posing adequate micromesoporous pore network and moderate acidity by combining microporous zeolite with the boehmite phase of alumina. These extruded zeolite-alumina catalysts are expected to allow sufficient diffusion of heavy fractions, thus leading to high cracking of heavy oil into valuable olefins. Different zeolite-alumina catalysts of varying alumina content ranging from 25 to 75% (AlZ-25, AlZ-50, and AlZ-75) were prepared in the laboratory to study the optimum zeolite-alumina ratios for maximum olefin production from heavy oil. The catalysts were characterized for their chemical and physical properties using nitrogen adsorption (N2 adsorption), X-ray diffraction (XRD), inductively coupled plasma (ICP) spectrometry, Fourier transform infrared (FT-IR) spectroscopy, and NH3 temperature programmed desorption (TPD). A gradual increase in the average pore diameter (APD) of the catalysts was observed due to the alumina ratio with a distinct range of acidity that is in the range of 125 to 375°C, and also the geometry of pores is not the same for all of the supports. Catalytic performance tests were conducted in a fixed-bed reactor at 450°C, 10 bar, and liquid hourly space velocity (LHSV) of 1 h−1. The results revealed that the prepared catalysts were thermally stable and effective in heavy oil conversion to olefins. Moreover, the selectivity of propylene was higher than that of ethylene (P/E) due to the modified textural and acidic properties of the catalysts. The results showed that the catalysts prepared with moderate acidity and adequate mesopores exhibited a considerable effect on the conversion of heavy crude oil into olefins. Hence, the acidity and mesoporosity of the catalysts play a vital role in determining the catalyst performance.
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