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GG20-GCI Brake Drum: The Effect of Mn/S on Machinability and Tensile Behavior GG20-GCI 制动鼓:Mn/S 对机械加工性能和拉伸行为的影响
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-09 DOI: 10.1007/s40962-024-01355-z
Hanie Ghanbari, Mostafa Ketabchi, Esmaeil Damavandi

This study aims to assess the influence of the Mn to S ratios on the machinability and tensile behavior of GG20-gray cast iron brake drums. The effect of various Mn and S contents on microstructural characteristics such as type, size, and aspect ratio of graphite particles, interlamellar spacing of pearlite, and the distribution factor, size, and volume fraction of MnS were investigated. The microstructural results showed that a decrease in the Mn/S ratio to 5.1 and a decrease in the Ti/S ratio to under 0.11 promote the lengthy A-type graphite formation. Meanwhile, with the %Mn × %S value of about 0.08, the best uniform distribution of MnS inclusions has been obtained (about 55% of MnS inclusions are near A-type graphite flakes in the P1 specimen with %Mn × %S about 0.08 and Mn/S value of 5.1). Good machining in terms of less wear of the cutting tool and easier fragmentation of the chip in the sample with Mn/S value of 1.5 (0.65% Mn and 0.128% Sulfur) due to having more MnS inclusions, as well as a larger grain size graphite and its high aspect ratio have been obtained. The minimum tensile strength has been calculated to be 193MPa in the specimen with Mn/S value of 3.5 (0.55% manganese and 0.156% sulfur) due to the effects of higher sulfur content on changing the morphology of graphite to a higher aspect ratio. Meanwhile, at the same content of Mn (almost 0.55 wt%), further reduction of sulfur results in promoting E and D types of graphite in the microstructure.

Graphic Abstract

本研究旨在评估 Mn 与 S 的比率对 GG20 灰口铸铁制动鼓的可加工性和拉伸性能的影响。研究了不同 Mn 和 S 含量对微观结构特征的影响,如石墨颗粒的类型、尺寸和长宽比,珠光体的层间间距,以及 MnS 的分布因子、尺寸和体积分数。微观结构结果表明,Mn/S 比降至 5.1 和 Ti/S 比降至 0.11 以下会促进 A 型石墨的形成。同时,当 Mn × S%值约为 0.08 时,MnS夹杂物的分布均匀度最佳(在 Mn × S%值约为 0.08 和 Mn/S 值为 5.1 的 P1 试样中,约 55% 的 MnS 夹杂物靠近 A 型石墨片)。在 Mn/S 值为 1.5(锰含量为 0.65%,硫含量为 0.128%)的试样中,由于含有更多的 MnS 杂质,以及石墨晶粒尺寸更大、长宽比更高,因此切削工具的磨损更小,切屑更容易破碎,从而获得了良好的加工效果。在 Mn/S 值为 3.5(锰含量为 0.55%,硫含量为 0.156%)的试样中,计算得出的最小抗拉强度为 193MPa。同时,在相同的锰含量(近 0.55 wt%)下,进一步降低硫含量可促进微观结构中 E 型和 D 型石墨的形成。
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引用次数: 0
Mechanical and Wear Behavior of Al-Si5Cu3/ZrB2 In-Situ Reinforced Metal Matrix Composite Al-Si5Cu3/ZrB2 原位增强金属基复合材料的力学和磨损行为
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-07 DOI: 10.1007/s40962-024-01349-x
J. Jenix Rino, A. S. Vivekananda, N. Thangapandian, Balasivanandha Prabu Shanmugavel

In this study, the in-situ ZrB2/Al-Si5Cu3 aluminum alloy composites were fabricated through the salt-melt reaction route with different weight fractions of ZrB2 reinforcements, i.e., 2.5%, 5%, and 7.5%. The composites were tested for their density, hardness, tensile strength, flexural strength, impact strength, and wear properties. The influence of reinforcement on the properties was studied concerning the wt.% of reinforcement. The increase in density of composites compared to the matrix material confirms the formation of the in-situ reinforcement phase. The microstructure showed a desirable distribution of reinforced particles over the matrix at all weight fractions of the reinforcements in the composites. The ZrB2 particles formed in the matrix have particle sizes in the range from 255 nm to 955 nm and the grain size has been reduced from 242 microns to 110 microns as the result of particle-induced solidification. The hardness of the composites containing ZrB2 reinforcements of 2.5, 5, and 7.5 wt.% showed improvement by 8%, 17.5%, and 34% respectively compared to the parent alloy. There is an improvement in the tensile strength and elongation for the wt.% of ZrB2 up to 5 wt.%, from 115 MPa to 183 MPa, after which, there was a drop in the tensile strength. The detailed analysis of tensile fractography shows that the agglomerated ZrB2 reinforced particles at higher weight fractions lead to a decrease in strength. The results of flexural strength also affirm the strength of 5 wt.% ZrB2/Al-Si5Cu3 increased from the matrix material’s flexural strength of 337 MPa to 672 MPa. The wear study shows that the composite with 7.5 wt.% ZrB2 possesses a higher wear resistance. However, the impact strength did not show any differences in the weight % of reinforcement.

在本研究中,通过盐熔反应路线制造了原位 ZrB2/Al-Si5Cu3 铝合金复合材料,其中添加了不同重量分数的 ZrB2 增强材料,即 2.5%、5% 和 7.5%。对复合材料的密度、硬度、拉伸强度、弯曲强度、冲击强度和磨损性能进行了测试。研究了增强材料的重量百分比对性能的影响。与基体材料相比,复合材料密度的增加证实了原位增强相的形成。微观结构显示,在复合材料中所有重量百分比的增强材料中,增强颗粒在基体上都有理想的分布。在基体中形成的 ZrB2 颗粒的粒径范围在 255 纳米到 955 纳米之间,由于颗粒诱导凝固,晶粒大小从 242 微米减小到 110 微米。与母合金相比,含有 2.5、5 和 7.5 重量百分比 ZrB2 增强材料的复合材料的硬度分别提高了 8%、17.5% 和 34%。ZrB2 的重量百分比在 5 重量百分比以下时,拉伸强度和伸长率有所提高,从 115 兆帕提高到 183 兆帕,之后拉伸强度有所下降。拉伸断裂图的详细分析表明,重量分数越高,ZrB2 增强颗粒的团聚会导致强度下降。抗折强度结果也证实,5 重量百分比 ZrB2/Al-Si5Cu3 的抗折强度从基体材料的 337 兆帕增加到 672 兆帕。磨损研究表明,含 7.5 wt.% ZrB2 的复合材料具有更高的耐磨性。不过,冲击强度并未因增强材料的重量百分比而出现任何差异。
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引用次数: 0
Nano-Al2O3 Particle Incorporated in Al Matrix Composite by Vortex-Free High-Speed Stir Casting 通过无涡流高速搅拌铸造在铝基复合材料中加入纳米 Al2O3 粒子
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-07 DOI: 10.1007/s40962-024-01345-1
Yinan Lu, Yunhui Du, Weiyi Zhang, Hongzhen Tan, Nan Zhang, Yi Luo, Peng Zhang

Vortex-free high-speed stir casting (VFHSC) methodology can achieve uniform dispersion of particles in melt without air entrapment for fabricating particle reinforced composites, and it has been proved to be feasible for preparing micron-composites by this methodology. In this work, in order to study deeply on particles in nano-size magnitude in composites by this methodology, the preparation of 1.5 vol.% Nano-Al2O3p/Al–Cu–Mg–Si composite is also investigated. The proper stirring parameters for ideal particle dispersion are determined to prepare the materials. Porosity of the composite can be limited to 0.147 % under the VFHSC methodology. The composition and microstructure of ingots, including the incorporation of Al2O3 particles as well as the morphology of precipitated phases, are examined by OM, XRD, SEM, TEM, HRTEM and EDS. The nano-particles are incorporated ideally in the matrix with restricted aggregation and sedimentation, and the well-bounded Al2O3–Al interface possesses semi-coherent interface. Moreover, the VFHSC 1.5 vol.% Nano-Al2O3p/Al–Cu–Mg–Si composite exhibits obvious strengthening, limited ductility reduction, higher hardness as well as better wear resistance than those of matrix, validating the efficacy of the VFHSC methodology on fabricating 1.5 vol.% Nano-Al2O3p/Al–Cu–Mg–Si composite. The work proves that incorporating nano-particles in Al matrix by VFHSC methodology is feasible and efficient. The work presented in this paper proposes a viable approach for the fabrication of nanocomposites using the stir casting method, thereby offering valuable insights for further research on stir casting technology.

无涡流高速搅拌铸造(VFHSC)方法可实现颗粒在熔体中的均匀分散,不会夹带空气,用于制造颗粒增强复合材料,而且该方法已被证明可用于制备微米复合材料。在本研究中,为了深入研究该方法在复合材料中的纳米级颗粒,还研究了 1.5 vol.% 纳米 Al2O3p/Al-Cu-Mg-Si 复合材料的制备。在制备材料时,确定了理想颗粒分散的适当搅拌参数。在 VFHSC 方法下,复合材料的孔隙率可限制在 0.147%。通过 OM、XRD、SEM、TEM、HRTEM 和 EDS 检查了铸锭的成分和微观结构,包括 Al2O3 颗粒的加入以及沉淀相的形态。纳米颗粒在基体中的结合非常理想,聚集和沉积受到限制,Al2O3-Al 界面具有良好的半相干界面。此外,与基体相比,VFHSC 1.5 Vol.% 纳米 Al2O3p/Al-Cu-Mg-Si 复合材料表现出明显的增强性、有限的延展性降低、更高的硬度和更好的耐磨性,验证了 VFHSC 方法在制造 1.5 Vol.% 纳米 Al2O3p/Al-Cu-Mg-Si 复合材料上的有效性。这项工作证明,通过 VFHSC 方法在铝基体中加入纳米颗粒是可行且高效的。本文介绍的工作为利用搅拌铸造法制造纳米复合材料提出了一种可行的方法,从而为进一步研究搅拌铸造技术提供了宝贵的见解。
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引用次数: 0
SiC and MWCNT Blending Actions on Functional Performance of Hybrid AA2024 Alloy Nanocomposite Via Two Step Stir Cast Route 通过两步搅拌铸造工艺掺入 SiC 和 MWCNT 对混合 AA2024 合金纳米复合材料功能性能的影响
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-07 DOI: 10.1007/s40962-024-01351-3
M. Aruna, S. Kaliappan, D. V. V. S. B. Reddy Saragada, R. Venkatesh, V. Vijayan, Manzoore Elahi M. Soudagar, V. Mohanavel, Ismail Hossain, A. H. Seikh

The hybrid aluminium alloy matrix composites are adopted in high-strength-to-weight ratio applications with technical benefits, including high strength, good hardness, better stability, and improved thermal stability. This research is enhancing microstructural and mechanical functional behaviours of the hybrid aluminium alloy (AA2024) nanocomposites by the blending actions of nano silicon carbides (SiC) particles and multi-walled carbon nanotube (MWCNT) via a two-step stir cast route. The contribution effect of SiC and MWCNT blending actions on metallography, physical/mechanical qualities, and resistance to corrosion individualities of hybrid AA2024 nanocomposites are studied by the procedure of the American Society for Testing and Materials (ASTM) and compared to monolithic cast AA2024 alloy characteristics. The hybrid AA2024 nanocomposite blended with SiC and MWCNT (weight percentages of 5 and 8%) exposed the specific tailored benefits like homogenous scattered reinforcements resulting in a lower percentage value of porosity (≤ 1%), excellent ultimate tensile strength of 330 MPa with acceptable elongation range of 10%, enhanced indentation resistance capabilities of 128 HV, specific toughness of 15.2 J/mm2, and enhanced corrosion performance.

混合铝合金基复合材料具有高强度、高硬度、高稳定性和高热稳定性等技术优势,被广泛应用于高强度-重量比应用领域。本研究通过两步搅拌铸造工艺,在纳米碳化硅(SiC)颗粒和多壁碳纳米管(MWCNT)的混合作用下,增强混合铝合金(AA2024)纳米复合材料的微观结构和机械功能行为。根据美国材料与试验协会(ASTM)的程序,研究了碳化硅和多壁碳纳米管混合作用对混合 AA2024 纳米复合材料的金相、物理/机械质量和抗腐蚀特性的贡献效应,并与整体铸造的 AA2024 合金特性进行了比较。混合了 SiC 和 MWCNT(重量百分比分别为 5%和 8%)的混合 AA2024 纳米复合材料具有特定的定制优势,如均匀分散的增强体导致较低的孔隙率百分比值(≤ 1%)、330 兆帕的优异极限拉伸强度(可接受的伸长率范围为 10%)、128 HV 的更强抗压痕能力、15.2 J/mm2 的比韧性以及更强的耐腐蚀性能。
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引用次数: 0
An Assessment of South African Chromite Sand Crushing Ratio 南非铬铁矿砂破碎率评估
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-06 DOI: 10.1007/s40962-024-01337-1
Jonathan Kabadjundi Kabasele, Kasongo Didier Nyembwe

Mechanical reclamation is the de facto method of sand recycling in most foundries used to limit sand dumping and adhere to environmental regulations. The latter metal casting imperatives align with the United Nations Sustainable Development Goals of Responsible Production (Goal 12 - Ensure sustainable consumption and production patterns.). The crushing ratio, which essentially assesses the propensity of the sand to produce fine particles during moulding operations, is a critical property to predict the effectiveness of the mechanical reclamation process. This study assesses the crushing ratio of South African chromite sand. Five samples from the top worldwide producers were evaluated and compared. Rod milling was used to simulate mechanical reclamation. After testing, it was found that this crushing ratio varies between 1.68 and 1.93 after 9 minutes. Good statistical linear correlations were established between the crushing ratio of samples with Cr/Fe ratio, chromite content, and grain size. The investigation contributes to additional knowledge of chromite sand for foundry applications.

机械回收是大多数铸造厂事实上的砂回收方法,用于限制砂倾倒和遵守环保法规。后一种金属铸造要求与联合国负责任生产的可持续发展目标(目标 12 - 确保可持续消费和生产模式)相一致。破碎率主要评估砂在造型过程中产生细小颗粒的倾向,是预测机械再生工艺有效性的关键属性。本研究对南非铬铁矿砂的破碎比进行了评估。对来自全球顶级生产商的五个样本进行了评估和比较。使用棒磨机模拟机械回收。经过测试发现,9 分钟后的破碎比在 1.68 和 1.93 之间。样品的破碎率与铬/铁比率、铬铁矿含量和粒度之间建立了良好的统计线性关系。这项调查有助于进一步了解铸造用铬铁矿砂。
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引用次数: 0
Methodology to Remove or Scale Back the Solution Treatment in the Thermal Processing of the 319-Type Alloy Without Changing Material Properties 在不改变材料特性的情况下,在 319 型合金的热加工过程中去除或缩减固溶处理的方法
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-03 DOI: 10.1007/s40962-024-01326-4
Robert Mackay, Glenn Byczynski

The 319-type alloy is one of the more widely used casting alloys for propulsion applications in the automotive space (i.e., E-motor housings for battery electric vehicles (BEV) and engine blocks for internal combustion engines (ICE)). For these 319-type applications that require the highest material properties and dimensional stability, a T7 (solution and quench followed by an artificial over-age) is used. The authors will demonstrate an innovative approach to investigate if the solution treatment stage can be scaled back significantly with adjustments in artificial age parameters, while achieving the same material properties and dimensional stability had a full solution treatment been used. The impact of achieving the objective of reducing the solution treatment stage would be the lower energy cost, eliminating or reducing the bottleneck (and/or increase capacity without capital investment) of the solution furnace, and finally reduce the CO2 footprint of the overall heat treat process, all of which are critical for the future of the North American automotive casting manufacturing.

319 型合金是在汽车领域推进应用(即电池电动汽车 (BEV) 的电动机壳体和内燃机 (ICE) 的发动机组)中使用较为广泛的铸造合金之一。这些 319 型应用需要最高的材料性能和尺寸稳定性,因此采用了 T7(固溶和淬火,然后人工过时效)工艺。作者将展示一种创新方法,研究是否可以通过调整人工时效参数来大幅缩减固溶处理阶段,同时达到与采用完全固溶处理相同的材料特性和尺寸稳定性。实现减少固溶处理阶段的目标将降低能源成本,消除或减少固溶炉的瓶颈(和/或提高产能而无需资本投资),并最终减少整个热处理过程的二氧化碳排放量,所有这些对于北美汽车铸件制造业的未来都至关重要。
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引用次数: 0
Predictive Analysis of Water Wettability and Corrosion Resistance of Secondary AlSi10MnMg(Fe) Alloy Manufactured by Vacuum-Assisted High Pressure Die Casting 真空辅助高压压铸二次铝硅锰铁合金水润湿性和耐腐蚀性的预测分析
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-03 DOI: 10.1007/s40962-024-01327-3
Amir Kordijazi, Swaroop K. Behera, Arthur Jamet, Ana Isabel Fernández-Calvo, Pradeep Rohatgi

In the present study, a predictive analysis was performed to investigate the effect of droplet size, section size and type of the primary and secondary AlSi10MnMg alloys manufactured by vacuum-assisted high pressure die casting on wettability of the cast samples with water, since wettability influences corrosion resistance. Additionally, corrosion resistance of samples was studied using a linear polarization experiment. Contact angle (CA) measurements were performed on the specimens using a goniometer. An Artificial Neural Network was then developed to predict the contact angle values as a function of the predictor variables. The developed model was able to predict unseen CA values with excellent accuracy with the Pearson correlation coefficient of 0.96 between the predicted and observed CA. The modeling results show that the type of alloy (primary or secondary) is the most significant factor affecting CA, where almost 80% of CA variation is the result of changing the type of alloy. Confocal microscopy images demonstrate that this is attributed to the change in the heterogeneity of the surface, which affects contact angle values. The corrosion studies reveal that corrosion resistance is dependent on the type of alloy and surface roughness. The primary alloy possesses more corrosion resistance than the secondary alloy. This is due to the larger fraction of intermetallic compounds in the microstructure of the secondary alloy, which serve as galvanic sites in the corrosion reaction accelerating corrosion rate. Moreover, the non-uniformity induced by larger surface roughness is detrimental to the corrosion resistance of the samples. These results indicate that the data-driven approach used in this research is very promising not only to predict the performance, but also to optimize and design high-performance corrosion resistant surfaces of cast aluminum alloys.

由于润湿性会影响耐腐蚀性,因此本研究进行了预测分析,以研究通过真空辅助高压压铸制造的一级和二级 AlSi10MnMg 合金的液滴尺寸、截面尺寸和类型对铸样与水的润湿性的影响。此外,还利用线性极化实验研究了样品的耐腐蚀性。使用测角仪对试样进行了接触角(CA)测量。然后开发了一个人工神经网络来预测作为预测变量函数的接触角值。所开发的模型能够非常准确地预测未见的接触角值,预测值与观测值之间的皮尔逊相关系数为 0.96。建模结果表明,合金类型(一次合金或二次合金)是影响 CA 的最重要因素,几乎 80% 的 CA 变化都是由改变合金类型造成的。共聚焦显微镜图像表明,这是由于表面异质性的变化影响了接触角值。腐蚀研究表明,耐腐蚀性取决于合金类型和表面粗糙度。初级合金比次级合金具有更强的耐腐蚀性。这是因为二次合金的微观结构中金属间化合物的比例较大,在腐蚀反应中可作为电偶位点,从而加快腐蚀速度。此外,较大的表面粗糙度引起的不均匀性也不利于样品的耐腐蚀性。这些结果表明,本研究采用的数据驱动方法不仅在预测性能方面大有可为,而且在优化和设计铸铝合金的高性能耐腐蚀表面方面也大有可为。
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引用次数: 0
Strength Evolution and Fracture Feature of Carbon Fiber-Reinforced Silica Sol Shell for Investment Casting 熔模铸造用碳纤维增强硅溶胶壳的强度演变和断裂特性
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-03 DOI: 10.1007/s40962-024-01343-3
Zhiran Zhang, Chang Liu, Zhijun Chen, Zhongxing Tian, Xiangdong Liu

The high-strength and thin-walled shells are extremely beneficial for not only rapid solidification of metal castings but also excellent for shell removal, its low residual strength and low solid waste discharge. In this work, short carbon fibers as reinforcement were induced into the shells. The strength of specimens and their fracture behavior at ambient temperature or high temperature in loading were investigated using scanning electron microscopy (SEM) and thermogravimetric-differential scanning calorimetry technique (TG-DSC). The results show that the bending strength of the shell progressively rises initially and then decreases rapidly with increasing content of fiber with a constant length. In particular, the shell reinforced with 0.42 wt% carbon fibers of length of 2.0 mm reaches a peak of green strength of 4.68 MPa and a peak of hot strength 16.06 MPa, respectively, approximately 89.47 and 61.20% higher than that of the unreinforced. Moreover, the peak of the fired strength of shell specimens containing 0.51 wt% fibers of length of 3.0 mm reaches 7.48 MPa, increasing by 61.20% in comparison with the unreinforced. However, the high-temperature self-weight deformation of the shell does not reveal positive correlation or monotonically increasing with the amount of fiber. Furthermore, the results revealed that the fracture types and failure patterns of fibers in shells were mostly related to fiber-fracture, pull-out and/or debonding during loading. These research results are beneficial to further improve this technology and promote the practical application to greatly reduce the generation and discharge of waste shells in the production of investment castings in the future.

高强度薄壁型壳不仅对金属铸件的快速凝固极为有利,而且在型壳去除方面也非常出色,其残余强度低,固体废物排放量少。在这项工作中,我们在型壳中加入了短碳纤维作为增强材料。使用扫描电子显微镜(SEM)和热重-差示扫描量热技术(TG-DSC)对试样的强度及其在常温或高温加载下的断裂行为进行了研究。结果表明,在长度不变的情况下,随着纤维含量的增加,壳体的抗弯强度最初会逐渐升高,然后迅速降低。其中,使用 0.42 wt%、长度为 2.0 mm 的碳纤维增强的壳体的绿色强度峰值为 4.68 MPa,热强度峰值为 16.06 MPa,分别比未增强的壳体高出约 89.47% 和 61.20%。此外,含有 0.51 wt%、长度为 3.0 mm 的纤维的壳体试样的烧成强度峰值达到 7.48 MPa,比未增强的提高了 61.20%。然而,壳体的高温自重变形并不与纤维量呈正相关或单调增加。此外,研究结果表明,壳体中纤维的断裂类型和失效模式主要与加载过程中的纤维断裂、拉出和/或脱粘有关。这些研究成果有利于进一步改进该技术,促进实际应用,从而在今后的熔模铸造生产中大大减少废型壳的产生和排放。
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引用次数: 0
Effect of Wall Thickness on Properties of Multilayer Composite Plaster Mold for Investment Casting 壁厚对用于熔模铸造的多层复合石膏模具性能的影响
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-03 DOI: 10.1007/s40962-024-01350-4
Yan Lu, Kai Lü, Yanfen Li, Zongxue Li

In order to research whether the properties of a thin-walled plaster mold meets the production requirements in investment casting, this paper investigates a novel preparation technology for an adhesion-layer composite plaster mold. Based on a solid plaster mold, a single adhesion layer was applied to the outer surface for preparing the composite mold. An adhesion layer was deposited using silica sol as an adhesive, while refractory materials served as sand particles. Effects of specimen wall thickness on the strength, permeability, and thermal conductivity of composite mold were investigated. The results reveal positive correlation between wall thickness of the composite mold and its strength properties. Permeability and thermal conductivity, on the other hand, decrease with increasing wall thickness. Notably, at wall thickness of 3.5/4 compared to original specimen, significant improvements are observed. Specifically, compared to original solid mold, green specimens exhibit an increase of 4.64% and 7.80% in flexural and tensile strength, respectively. For fired specimens, the increases are even more remarkable, reaching 28.87% for flexural strength and 28.71% for tensile strength. Moreover, the increment of permeability and thermal conductivity with fired specimens was 169.33% and 9.45%, respectively. The monoclinic ZrO2 (m-ZrO2) characteristic peak appeared in the Raman spectra of the composite mold. It is shown that Zr4+ plays an important role in the accumulation of anion groups with the gypsum system, and then improves the macroscopic strength of mold. The obvious physical interface is observed between the plaster matrix and adhesive layer. It is noteworthy that the gypsum matrix and adhesion layer demonstrate varying abilities to resist structural damage, with a macroscopic fracture of gypsum matrix being more likely to occur prior to adhesion layer. Composite plaster mold exhibits a symmetrical and stable crystal structure and has better fracture deformation resistance compared to a solid mold. Fracture of the mold can be attributed to three types of failure: fiber failure, delamination failure, and damage between fibers and the matrix. These failure types are major factors influencing macro fracture of composite molds.

为了研究薄壁石膏模具的性能是否符合熔模铸造的生产要求,本文研究了一种新型粘合层复合石膏模具的制备技术。在实心石膏模具的基础上,在外层表面涂上一层粘合剂,以制备复合模具。粘合层以硅溶胶为粘合剂,耐火材料为砂粒。研究了试样壁厚对复合材料模具强度、渗透性和导热性的影响。结果表明,复合材料模具的壁厚与其强度特性呈正相关。而渗透性和导热性则随着壁厚的增加而降低。值得注意的是,在壁厚为 3.5/4 时,与原始试样相比,复合材料的性能有了显著改善。具体来说,与原始实心模具相比,绿色试样的抗弯强度和抗拉强度分别提高了 4.64% 和 7.80%。焙烧试样的增幅更为显著,抗弯强度和抗拉强度分别提高了 28.87% 和 28.71%。此外,烧结试样的渗透率和导热率分别增加了 169.33% 和 9.45%。复合材料模具的拉曼光谱中出现了单斜 ZrO2(m-ZrO2)特征峰。这表明,Zr4+ 在阴离子基团与石膏体系的积累过程中发挥了重要作用,进而提高了模具的宏观强度。在石膏基体和粘合剂层之间观察到明显的物理界面。值得注意的是,石膏基体和粘合层抵抗结构破坏的能力各不相同,石膏基体的宏观断裂更有可能发生在粘合层之前。复合石膏模具有对称和稳定的晶体结构,与实心石膏模相比,具有更好的抗断裂变形能力。模具的断裂可归因于三种类型的失效:纤维失效、分层失效以及纤维与基体之间的损坏。这些失效类型是影响复合材料模具宏观断裂的主要因素。
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引用次数: 0
Low CRI, High CSR Coke Trials 低 CRI、高 CSR 焦炭试验
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-02 DOI: 10.1007/s40962-024-01332-6
Stephen Hay, Bruce T. Blatzer

To improve coke performance in the cupola, the authors discovered that coke used in blast furnaces [low coke reactivity index (CRI), high coke strength after reaction (CSR)] exhibits higher strength than foundry coke and may provide better performance due to larger coke pieces reaching the melt zone. Coke strength and sizing are extremely important in a cupola because the coke must reach the melt zone intact, stay in the melt zone long enough to replenish the coke bed, provide heat for melting and carbon pickup to the liquid iron. This research evaluates the cupola performance difference between cokes of high and low CRI. In addition, efforts were made to identify differences in characteristics of these cokes.

为了提高冲天炉中焦炭的性能,作者发现高炉中使用的焦炭[焦炭反应指数(CRI)低,反应后焦炭强度(CSR)高]比铸造焦炭的强度更高,而且由于到达熔化区的焦炭块更大,因此性能可能更好。冲天炉中焦炭的强度和尺寸极为重要,因为焦炭必须完整地到达熔化区,在熔化区停留足够长的时间以补充焦炭床,为熔化提供热量,并为铁液提供碳。本研究评估了高 CRI 和低 CRI 焦炭冲天炉性能的差异。此外,还努力确定这些焦炭的特性差异。
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International Journal of Metalcasting
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