N. Deb, M. Alam, T. Rahman, M. Al-Khatib, M. Jami, M. F. Mansor
Palm oil mill effluent (POME) is one of the main agro-industrial wastewaters in Malaysia. Highly polluting POME is a serious threat to the environment. In recent years, the methods used to treat POME are inefficient and complex in terms of cost or environmental preservation. The main object of this research is to propose a single reactor system (SRS) obtained from POME wastewater discharge as a promising low-cost treatment and high-energy method for harvesting the fermentable sugar by applying acid–base–enzyme pretreatment and hydrolysis of POME by locally produced cellulase enzymes to enhance biofuel production. Several experiments were conducted to produce fermentable sugars through the statistical methods, including the characterization of POME, acid-base pretreatment, and enzymatic hydrolysis process for reducing sugar production. The one-factor-at-a-time (OFAT) results showed that the highest reducing sugar yield, 23.5 mg/mL of POME, was achieved by enzymatic hydrolysis in an SRS without having a separation and purification. Based on OFAT performance, optimization of two factors such as substrate concentration (total suspended solids, TSS %w/v) and enzyme loading (μmol/min) was carried out by applying face-centered central composite design (FCCCD) under the response surface methodology (RSM) to develop a second-order regression model. The optimum reducing sugar production was 26.6 mg/mL (53.14%) with the conditions of 5% w/v, TSS, and 80 μmol/min/mL of the enzyme dose. In addition, the results of this research can be further considered in biofuel production using other wastewaters to enhance biofuel production as well as wastewater treating functions and minimize the negative environmental impacts.
{"title":"Acid–Base Pretreatment and Enzymatic Hydrolysis of Palm Oil Mill Effluent in a Single Reactor System for Production of Fermentable Sugars","authors":"N. Deb, M. Alam, T. Rahman, M. Al-Khatib, M. Jami, M. F. Mansor","doi":"10.1155/2023/8711491","DOIUrl":"https://doi.org/10.1155/2023/8711491","url":null,"abstract":"Palm oil mill effluent (POME) is one of the main agro-industrial wastewaters in Malaysia. Highly polluting POME is a serious threat to the environment. In recent years, the methods used to treat POME are inefficient and complex in terms of cost or environmental preservation. The main object of this research is to propose a single reactor system (SRS) obtained from POME wastewater discharge as a promising low-cost treatment and high-energy method for harvesting the fermentable sugar by applying acid–base–enzyme pretreatment and hydrolysis of POME by locally produced cellulase enzymes to enhance biofuel production. Several experiments were conducted to produce fermentable sugars through the statistical methods, including the characterization of POME, acid-base pretreatment, and enzymatic hydrolysis process for reducing sugar production. The one-factor-at-a-time (OFAT) results showed that the highest reducing sugar yield, 23.5 mg/mL of POME, was achieved by enzymatic hydrolysis in an SRS without having a separation and purification. Based on OFAT performance, optimization of two factors such as substrate concentration (total suspended solids, TSS %w/v) and enzyme loading (μmol/min) was carried out by applying face-centered central composite design (FCCCD) under the response surface methodology (RSM) to develop a second-order regression model. The optimum reducing sugar production was 26.6 mg/mL (53.14%) with the conditions of 5% w/v, TSS, and 80 μmol/min/mL of the enzyme dose. In addition, the results of this research can be further considered in biofuel production using other wastewaters to enhance biofuel production as well as wastewater treating functions and minimize the negative environmental impacts.","PeriodicalId":14283,"journal":{"name":"International Journal of Polymer Science","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2023-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47308484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Manjunathan Alagarsamy, S. R. Barkunan, N. Jayapal, A. Murugan, P. Muralikrishnan, P. J. Ramulu
Due to their profusion, high durability, and rigidity, lesser weight and biodegradable nature nanocellulose (NC) is observed as the challenging tasks for the aspirants in making of the green composites. The continuous network of the cellulose nanoparticle connected through hydrogen bonding is happened mainly due to the reinforcing effect allocated to the mechanical reoccurrence phenomenon of the NC. When comparing with the nanocrystalline cellulose, the NC has significant convincing progress in the durability and rigidity, and the aspect ratio of the NC is higher than that of the NC crystal. The reinforcement effect of NC is the characteristic of the NC polymer interaction as well as the reinforcement effect eventualizing through stress transfer at the NC–polymer interface. Thus, the concentration of the reinforcement particle rises to the saturation level due to the frailty of the NC reinforcement constituent and due to surface compliance between the matrix and the filler. Due to its structural firmness and mechanical behaviors, the NC compounds are used in many industrial applications like tissue engineering, food packaging, and electronic applications. The stretchable electronic systems and instruments are awaiting the maximal attention due to its essential applications in certain domains, such as robotics artificial intelligence, brain control and machine interface, clinical devices, and health care electronic monitoring devices. In addition to that, when realizing the operational performance of electronic devices, the electronic instruments and systems must be physically expandable and flexible. The proposed study deems the technique of reinforcing the NC compounds as green agent in electronic applications, which has been associated with the composites of polymer matrix. The elongation could be achieved through the formulation of composition via elastomers. In addition, it is being focused on the illustration of functional soft development of materials that is inclusive of the conductive intrinsic polymers for the elongated electrodes and electrothermal conversion and vice versa, occupying the maximal area along with tactile sensing elements.
{"title":"Reinforcement of Nanocellulose as Green Agent in the Electronic Applications Associated with the Composites of Polymer Matrix","authors":"Manjunathan Alagarsamy, S. R. Barkunan, N. Jayapal, A. Murugan, P. Muralikrishnan, P. J. Ramulu","doi":"10.1155/2023/9645190","DOIUrl":"https://doi.org/10.1155/2023/9645190","url":null,"abstract":"Due to their profusion, high durability, and rigidity, lesser weight and biodegradable nature nanocellulose (NC) is observed as the challenging tasks for the aspirants in making of the green composites. The continuous network of the cellulose nanoparticle connected through hydrogen bonding is happened mainly due to the reinforcing effect allocated to the mechanical reoccurrence phenomenon of the NC. When comparing with the nanocrystalline cellulose, the NC has significant convincing progress in the durability and rigidity, and the aspect ratio of the NC is higher than that of the NC crystal. The reinforcement effect of NC is the characteristic of the NC polymer interaction as well as the reinforcement effect eventualizing through stress transfer at the NC–polymer interface. Thus, the concentration of the reinforcement particle rises to the saturation level due to the frailty of the NC reinforcement constituent and due to surface compliance between the matrix and the filler. Due to its structural firmness and mechanical behaviors, the NC compounds are used in many industrial applications like tissue engineering, food packaging, and electronic applications. The stretchable electronic systems and instruments are awaiting the maximal attention due to its essential applications in certain domains, such as robotics artificial intelligence, brain control and machine interface, clinical devices, and health care electronic monitoring devices. In addition to that, when realizing the operational performance of electronic devices, the electronic instruments and systems must be physically expandable and flexible. The proposed study deems the technique of reinforcing the NC compounds as green agent in electronic applications, which has been associated with the composites of polymer matrix. The elongation could be achieved through the formulation of composition via elastomers. In addition, it is being focused on the illustration of functional soft development of materials that is inclusive of the conductive intrinsic polymers for the elongated electrodes and electrothermal conversion and vice versa, occupying the maximal area along with tactile sensing elements.","PeriodicalId":14283,"journal":{"name":"International Journal of Polymer Science","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2023-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43372928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zerihun Feyissa, G. D. Edossa, Tariku Bayisa Bedasa, L. G. Inki
This research focused on preparing hydrogels with controlled drug release properties to control gastrointestinal tract bacterial infection. Chitosan (CS) and polyvinylpyrrolidone (PVP) were used as the base polymers, with the CS component crosslinked by glutaraldehyde for hydrogel preparation using the solution casting technique. The effect of varying glutaraldehyde content in the hydrogels was characterized by the extent of swelling in simulated physiological fluids of pH 1.2, 6.8, and 7.4; the development of porosity; and gel fraction. Functional groups and covalent and hydrogen bonds formed, thermal stability, phase structure, and morphology were characterized by Fourier-transform infrared spectroscopy, thermogravimetric analysis, X-ray diffraction, and scanning electron microscopy. The results show that the components in the hydrogels have good compatibility and formed honeycomb-like structures. In vitro studies confirmed that the hydrogels have good biodegradability at pH 7.4. Based on these properties, a CS/PVP hydrogel of the ratio of 60 : 40 crosslinked with 600 μL glutaraldehyde was selected for the in-situ loading of 200 mg of the drug metronidazole (MTZ). The hydrogel was characterized for cumulative drug release in the simulated physiological fluids and drug release kinetics using different models and for its antibacterial activity. The best-fit Korsmeyer–Peppas model suggests that MTZ release followed diffusion and swelling-controlled time-dependent non-Fickian transport related to hydrogel erosion. This hydrogel displays enhanced antimicrobial activity against Staphylococcus aureus, and Escherichia coli showed substantial inhibition zones indicating the produced CS/PVP hydrogels are promising candidates for controlled drug release applications.
{"title":"Fabrication of pH-Responsive Chitosan/Polyvinylpyrrolidone Hydrogels for Controlled Release of Metronidazole and Antibacterial Properties","authors":"Zerihun Feyissa, G. D. Edossa, Tariku Bayisa Bedasa, L. G. Inki","doi":"10.1155/2023/1205092","DOIUrl":"https://doi.org/10.1155/2023/1205092","url":null,"abstract":"This research focused on preparing hydrogels with controlled drug release properties to control gastrointestinal tract bacterial infection. Chitosan (CS) and polyvinylpyrrolidone (PVP) were used as the base polymers, with the CS component crosslinked by glutaraldehyde for hydrogel preparation using the solution casting technique. The effect of varying glutaraldehyde content in the hydrogels was characterized by the extent of swelling in simulated physiological fluids of pH 1.2, 6.8, and 7.4; the development of porosity; and gel fraction. Functional groups and covalent and hydrogen bonds formed, thermal stability, phase structure, and morphology were characterized by Fourier-transform infrared spectroscopy, thermogravimetric analysis, X-ray diffraction, and scanning electron microscopy. The results show that the components in the hydrogels have good compatibility and formed honeycomb-like structures. In vitro studies confirmed that the hydrogels have good biodegradability at pH 7.4. Based on these properties, a CS/PVP hydrogel of the ratio of 60 : 40 crosslinked with 600 μL glutaraldehyde was selected for the in-situ loading of 200 mg of the drug metronidazole (MTZ). The hydrogel was characterized for cumulative drug release in the simulated physiological fluids and drug release kinetics using different models and for its antibacterial activity. The best-fit Korsmeyer–Peppas model suggests that MTZ release followed diffusion and swelling-controlled time-dependent non-Fickian transport related to hydrogel erosion. This hydrogel displays enhanced antimicrobial activity against Staphylococcus aureus, and Escherichia coli showed substantial inhibition zones indicating the produced CS/PVP hydrogels are promising candidates for controlled drug release applications.","PeriodicalId":14283,"journal":{"name":"International Journal of Polymer Science","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2023-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46721312","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Modern chemical industries trend towards industrial ecology to achieve a circular economy, because of increasing environmental and economic awareness jointly. One of the most important of these industries is polyurethane, accompanied by more and more interest in using renewable polyols. The study focuses on synthesizing and characterizing polyurethane rigid foams formulated by replacing 40%, 60%, and 100% of a petrochemical polyol with a bio-polyol derived from used cooking oil, and introducing perlite and modified perlite nanoparticles into the bio-polyol. The products were evidenced by transmission electron microscopy (TEM), Fourier transform infrared (FTIR), nuclear magnetic resonance spectral analyses, thermogravimetric analysis (TGA), and scanning electron microscopy equipped with energy-dispersive spectroscopy. The results indicate that the hydroxide value and viscosity at 25°C of the bio-polyol were around 456 ± 30 mg KOH/g and 148 mPa s. Bio-polyol blends of 40% and 60% had no significant effect on the thermal properties of polyurethane systems. The lowest value of char yield was observed for the sample with a 100% bio-polyol content of 2.3%. The beneficial effects of both perlite and modified perlite particles on the 100% bio-polyol-based foam were observed as having an effective role in improving thermal stability and reconstructing cellular structure. The yield char increased to 13.2%, 14%, 14.7%, and 15% for the two filler contents 2.5% and 5%. However, the new bio-polyol has a fairly good value in industrial construction, and the perlite particles have enhanced and improved this value.
{"title":"Preparation and Characterization of Polyurethane Rigid Foam Nanocomposites from Used Cooking Oil and Perlite","authors":"Muntajab Sarim, M. M. Alavi Nikje, M. Dargahi","doi":"10.1155/2023/7185367","DOIUrl":"https://doi.org/10.1155/2023/7185367","url":null,"abstract":"Modern chemical industries trend towards industrial ecology to achieve a circular economy, because of increasing environmental and economic awareness jointly. One of the most important of these industries is polyurethane, accompanied by more and more interest in using renewable polyols. The study focuses on synthesizing and characterizing polyurethane rigid foams formulated by replacing 40%, 60%, and 100% of a petrochemical polyol with a bio-polyol derived from used cooking oil, and introducing perlite and modified perlite nanoparticles into the bio-polyol. The products were evidenced by transmission electron microscopy (TEM), Fourier transform infrared (FTIR), nuclear magnetic resonance spectral analyses, thermogravimetric analysis (TGA), and scanning electron microscopy equipped with energy-dispersive spectroscopy. The results indicate that the hydroxide value and viscosity at 25°C of the bio-polyol were around \u0000 \u0000 456\u0000 ±\u0000 30\u0000 \u0000 mg KOH/g and 148 mPa s. Bio-polyol blends of 40% and 60% had no significant effect on the thermal properties of polyurethane systems. The lowest value of char yield was observed for the sample with a 100% bio-polyol content of 2.3%. The beneficial effects of both perlite and modified perlite particles on the 100% bio-polyol-based foam were observed as having an effective role in improving thermal stability and reconstructing cellular structure. The yield char increased to 13.2%, 14%, 14.7%, and 15% for the two filler contents 2.5% and 5%. However, the new bio-polyol has a fairly good value in industrial construction, and the perlite particles have enhanced and improved this value.","PeriodicalId":14283,"journal":{"name":"International Journal of Polymer Science","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2023-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42131434","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
B. Mensah, B. Onwona-Agyeman, J. Efavi, Ralph Abakah Ofor, Mawufemor Zigah, J. Koranteng, Maxwell Karikari, Frank Nsaful, Daniel Akwei Addo
For the first time, acrylonitrile–butadiene rubber (NBR)–graphene oxide (GO) and reduced graphene oxide (rGO) composites were prepared without cure activators: zinc oxide/stearic acid (ZnO/SA) and studied. The vulcanization characteristics of the compounds were systematically studied at 160–190°C, with the aid of rheometer and differential scanning calorimetry (DSC) techniques. NBR revealed rapid curing time (t90) with greater cure rate index compared with NBR–GO/rGO composites for the rheometer measurement. This results were in correspondence with the activation energies Ea (kJ/mol) calculated by Ozawa and Kissinger models of vulcanization kinetics. NBR–rGO obtained reduced t90 and Ea (kJ/mol) than NBR–GO, perhaps due to lower oxygenated groups: epoxide (–C–O–C–), carboxyl (–O–C=O), and hydroxyl (–OH) present. Although, the composites delayed in curing, they significantly recorded high tensile properties with high reinforcing factors than NBR. The order of increasing mechanical properties: NBR < NBR–rGO < NBR–GO followed the same order of increasing crosslinking density. In terms of tensile strength, NBR–GO-1 obtained 62.5% and 18.2% increment than NBR and NBR–rGO-1, respectively. The findings from this study indicate that the absence of ZnO/SA in rubber compounds may slow down curing of rubber–GO/rGO composites and lower networks compared with those containing activators ZnO/SA. However, optimization of ZnO/SA and with desired functional groups on graphene and derivative graphene sheets (GDS) including other proposed factors may enhance the curing speed of rubber–GDS based systems, without compromising their mechanical integrity for advanced applications.
{"title":"Investigating the Effect of Curing Activators on the Cure Kinetics of Acrylonitrile–Butadiene Rubber Filled with Graphene Oxide and Reduced Graphene Oxides Nanocomposites","authors":"B. Mensah, B. Onwona-Agyeman, J. Efavi, Ralph Abakah Ofor, Mawufemor Zigah, J. Koranteng, Maxwell Karikari, Frank Nsaful, Daniel Akwei Addo","doi":"10.1155/2023/6387898","DOIUrl":"https://doi.org/10.1155/2023/6387898","url":null,"abstract":"For the first time, acrylonitrile–butadiene rubber (NBR)–graphene oxide (GO) and reduced graphene oxide (rGO) composites were prepared without cure activators: zinc oxide/stearic acid (ZnO/SA) and studied. The vulcanization characteristics of the compounds were systematically studied at 160–190°C, with the aid of rheometer and differential scanning calorimetry (DSC) techniques. NBR revealed rapid curing time (t90) with greater cure rate index compared with NBR–GO/rGO composites for the rheometer measurement. This results were in correspondence with the activation energies Ea (kJ/mol) calculated by Ozawa and Kissinger models of vulcanization kinetics. NBR–rGO obtained reduced t90 and Ea (kJ/mol) than NBR–GO, perhaps due to lower oxygenated groups: epoxide (–C–O–C–), carboxyl (–O–C=O), and hydroxyl (–OH) present. Although, the composites delayed in curing, they significantly recorded high tensile properties with high reinforcing factors than NBR. The order of increasing mechanical properties: NBR < NBR–rGO < NBR–GO followed the same order of increasing crosslinking density. In terms of tensile strength, NBR–GO-1 obtained 62.5% and 18.2% increment than NBR and NBR–rGO-1, respectively. The findings from this study indicate that the absence of ZnO/SA in rubber compounds may slow down curing of rubber–GO/rGO composites and lower networks compared with those containing activators ZnO/SA. However, optimization of ZnO/SA and with desired functional groups on graphene and derivative graphene sheets (GDS) including other proposed factors may enhance the curing speed of rubber–GDS based systems, without compromising their mechanical integrity for advanced applications.","PeriodicalId":14283,"journal":{"name":"International Journal of Polymer Science","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2023-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48617581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. V. Gurupranes, I. Rajendran, S. Gokulkumar, M. Aravindh, S. Sathish, Md. Elias Uddin
Various environmental concerns motivate scientists and researchers to look out for unique new materials in science and technology. In order to address the demand for polymeric materials with partial biodegradability, the usage of lignocellulosic fibre in the polymer matrix has risen. Lignocellulosic fibres are a cheap, easily renewable resource that is readily available in all regions. Cellulosic plant fibres also have a plethora of possibilities for use in polymer reinforcement because of their properties. Many researchers put their effort into developing a natural polymer with better mechanical properties and thermal stability using nanotechnology and the use of natural polymers to make its composites with lignocellulosic fibres. This study provides a review of the biodegradable composite market, processing methods, matrix-reinforcement phases, morphology, and characteristic improvements. In addition, it provides a concise summary of the findings of significant research on natural fibre polymer composites (NFRCs) that have been published. Indeed, a noticeably brief discussion is provided on the significant issues faced during composite extraction as well as the challenges encountered during the machining. Recent developments in the study of lignocellulosic fibre composites or NFRCs have demonstrated their enormous potential as structural elements in vehicles, aerospace structures, buildings, ballistics, soundproofing, and other structures.
{"title":"Preparation, Characteristics, and Application of Biopolymer Materials Reinforced with Lignocellulosic Fibres","authors":"S. V. Gurupranes, I. Rajendran, S. Gokulkumar, M. Aravindh, S. Sathish, Md. Elias Uddin","doi":"10.1155/2023/1738967","DOIUrl":"https://doi.org/10.1155/2023/1738967","url":null,"abstract":"Various environmental concerns motivate scientists and researchers to look out for unique new materials in science and technology. In order to address the demand for polymeric materials with partial biodegradability, the usage of lignocellulosic fibre in the polymer matrix has risen. Lignocellulosic fibres are a cheap, easily renewable resource that is readily available in all regions. Cellulosic plant fibres also have a plethora of possibilities for use in polymer reinforcement because of their properties. Many researchers put their effort into developing a natural polymer with better mechanical properties and thermal stability using nanotechnology and the use of natural polymers to make its composites with lignocellulosic fibres. This study provides a review of the biodegradable composite market, processing methods, matrix-reinforcement phases, morphology, and characteristic improvements. In addition, it provides a concise summary of the findings of significant research on natural fibre polymer composites (NFRCs) that have been published. Indeed, a noticeably brief discussion is provided on the significant issues faced during composite extraction as well as the challenges encountered during the machining. Recent developments in the study of lignocellulosic fibre composites or NFRCs have demonstrated their enormous potential as structural elements in vehicles, aerospace structures, buildings, ballistics, soundproofing, and other structures.","PeriodicalId":14283,"journal":{"name":"International Journal of Polymer Science","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48962056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Glass fiber-reinforced polypropylene (PP/GF) has been widely used due to its high stiffness, but for some applications that need low-module characteristics, PP/GF will have limitations due to its lower toughness, so it is necessary to develop glass fiber-modified polypropylene with good stiffness–toughness balance performance. In this study, two average length glass fibers (4.5 mm and 12 mm) and glass fiber powder, combined with β-nucleating agent, were used to investigate the effects on the crystallization and mechanical properties of polypropylene. The results show that compared with glass fiber, glass fiber powder cooperates with β-nucleating agent reinforced polypropylene composite showed good stiffness–toughness balance performance, and β-crystals were found in the composite measured by Differential Scanning Calorimetry (DSC), the presence of β-crystals can improve the toughness of the composite.
{"title":"The Influence of Glass Fiber/Glass Fiber Powder with β-Nucleating Agent on the Properties of Polypropylene","authors":"Peng Yan, Shaoran Kang, Lebo Ma","doi":"10.1155/2023/1240792","DOIUrl":"https://doi.org/10.1155/2023/1240792","url":null,"abstract":"Glass fiber-reinforced polypropylene (PP/GF) has been widely used due to its high stiffness, but for some applications that need low-module characteristics, PP/GF will have limitations due to its lower toughness, so it is necessary to develop glass fiber-modified polypropylene with good stiffness–toughness balance performance. In this study, two average length glass fibers (4.5 mm and 12 mm) and glass fiber powder, combined with β-nucleating agent, were used to investigate the effects on the crystallization and mechanical properties of polypropylene. The results show that compared with glass fiber, glass fiber powder cooperates with β-nucleating agent reinforced polypropylene composite showed good stiffness–toughness balance performance, and β-crystals were found in the composite measured by Differential Scanning Calorimetry (DSC), the presence of β-crystals can improve the toughness of the composite.","PeriodicalId":14283,"journal":{"name":"International Journal of Polymer Science","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2023-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47317386","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Limenew Abate Worku, R. K. Bachheti, Mesfin Getachew Tadesse, Archana Bachheti
This study examined the chemical composition, fiber morphology, and physical properties of Oxytenanthera abyssinica culm to assess its pulping potential. Technical Association of the Pulp and Paper Industry (TAPPI) and Franklin’s methods have been used for experiments. The statistical analysis showed that the chemical composition of O. abyssinica is influenced by the age of the plant. The amount of cellulose in the culm increases with age, while hand extractive content decreases with age. The average chemical content of the three years aged O. abyssinica was 49.26 ± 0.13 wt%, 21.31 ± 0.15 wt%, and 20.63 ± 0.12 wt% for cellulose, hemicellulose, and lignin contents, respectively. A significant difference exists between 1, 2, and 3-year aged plants ( P < 0.05 ) in cellulose, lignin, ash, and extractive content. The position of the culm also affects the fiber morphology of O. abyssinica. The fiber’s length, diameter, cell wall thickness, and lumen diameter increase from top to bottom, whereas the flexibility and slenderness ratio decrease. The average fiber morphology of O. abyssinica was flexibility ratio ( 0.72 ± 0.10 ), Runkel ratio ( 0.35 ± 0.10 ), slenderness ratio ( 109.98 ± 0.21 ), lumen diameter ( 15.63 ± 0.03 μm), cell wall thickness ( 2.74 ± 0.03 μm), fiber length ( 2.40 ± 0.10 mm), and fiber diameter ( 21.83 ± 0.09 μm). The above data showed that the mean value of the fiber length of the plant is greater than 1.5 mm, the Runkel ratio was less than 1, and the slenderness ratio was greater than 70 standard values. The result also showed that the average bulk density and the moisture content were 660 kg/m3 and 9.6%, respectively. Although O. abyssinica is widely grown in the study area, no comprehensive studies have been carried out on fiber morphology, chemical composition, and physical properties based on age and height. Thus, this research was carried out to study the plant’s fiber characteristics to assess its suitability for pulp and paper production. Based on the above data, the 3-year aged bottom part of O. abyssinica is recommended for more yield pulp and high-quality paper production than the first and second-year aged plant.
{"title":"Proximate Chemical Analysis and Effect of Age and Height of Oxytenanthera abyssinica on Fiber Morphology and Chemical Compositions for Pulp and Paper Production Potential","authors":"Limenew Abate Worku, R. K. Bachheti, Mesfin Getachew Tadesse, Archana Bachheti","doi":"10.1155/2023/5582854","DOIUrl":"https://doi.org/10.1155/2023/5582854","url":null,"abstract":"This study examined the chemical composition, fiber morphology, and physical properties of Oxytenanthera abyssinica culm to assess its pulping potential. Technical Association of the Pulp and Paper Industry (TAPPI) and Franklin’s methods have been used for experiments. The statistical analysis showed that the chemical composition of O. abyssinica is influenced by the age of the plant. The amount of cellulose in the culm increases with age, while hand extractive content decreases with age. The average chemical content of the three years aged O. abyssinica was \u0000 \u0000 49.26\u0000 ±\u0000 0.13\u0000 \u0000 wt%, \u0000 \u0000 21.31\u0000 ±\u0000 0.15\u0000 \u0000 wt%, and \u0000 \u0000 20.63\u0000 ±\u0000 0.12\u0000 \u0000 wt% for cellulose, hemicellulose, and lignin contents, respectively. A significant difference exists between 1, 2, and 3-year aged plants (\u0000 \u0000 P\u0000 <\u0000 0.05\u0000 \u0000 ) in cellulose, lignin, ash, and extractive content. The position of the culm also affects the fiber morphology of O. abyssinica. The fiber’s length, diameter, cell wall thickness, and lumen diameter increase from top to bottom, whereas the flexibility and slenderness ratio decrease. The average fiber morphology of O. abyssinica was flexibility ratio (\u0000 \u0000 0.72\u0000 ±\u0000 0.10\u0000 \u0000 ), Runkel ratio (\u0000 \u0000 0.35\u0000 ±\u0000 0.10\u0000 \u0000 ), slenderness ratio (\u0000 \u0000 109.98\u0000 ±\u0000 0.21\u0000 \u0000 ), lumen diameter (\u0000 \u0000 15.63\u0000 ±\u0000 0.03\u0000 \u0000 μm), cell wall thickness (\u0000 \u0000 2.74\u0000 ±\u0000 0.03\u0000 \u0000 μm), fiber length (\u0000 \u0000 2.40\u0000 ±\u0000 0.10\u0000 \u0000 mm), and fiber diameter (\u0000 \u0000 21.83\u0000 ±\u0000 0.09\u0000 \u0000 μm). The above data showed that the mean value of the fiber length of the plant is greater than 1.5 mm, the Runkel ratio was less than 1, and the slenderness ratio was greater than 70 standard values. The result also showed that the average bulk density and the moisture content were 660 kg/m3 and 9.6%, respectively. Although O. abyssinica is widely grown in the study area, no comprehensive studies have been carried out on fiber morphology, chemical composition, and physical properties based on age and height. Thus, this research was carried out to study the plant’s fiber characteristics to assess its suitability for pulp and paper production. Based on the above data, the 3-year aged bottom part of O. abyssinica is recommended for more yield pulp and high-quality paper production than the first and second-year aged plant.","PeriodicalId":14283,"journal":{"name":"International Journal of Polymer Science","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2023-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44732050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Electrospinning technology is famous for its simple preparation, and accurate and easy control of process parameters. It is widely used in ultrafine filtration membrane and biological tissue engineering support. Polycaprolactone (PCL) and poly(butylene succinate) (PBS) have good biocompatibility and are commonly used materials in electrospinning. In this study, the relationship between the electrospun sample, process parameters, and spinning solution of PCL/PBS blend system was systematically studied in an electrospinning experiment. The morphology characteristics, thermodynamic properties, and microstructure of the electrospun sample were screened by scanning electron microscopy, thermogravimetric analysis, differential scanning calorimetry, and X-ray diffraction. The optimum conditions of electrospinning with high practical value were obtained.
{"title":"Fabrication and Properties of Polycaprolactone/Poly(Butylene Succinate) Blends Based on Electrospinning","authors":"Lan Yu, Feng Wang, Shan Huang","doi":"10.1155/2023/9471371","DOIUrl":"https://doi.org/10.1155/2023/9471371","url":null,"abstract":"Electrospinning technology is famous for its simple preparation, and accurate and easy control of process parameters. It is widely used in ultrafine filtration membrane and biological tissue engineering support. Polycaprolactone (PCL) and poly(butylene succinate) (PBS) have good biocompatibility and are commonly used materials in electrospinning. In this study, the relationship between the electrospun sample, process parameters, and spinning solution of PCL/PBS blend system was systematically studied in an electrospinning experiment. The morphology characteristics, thermodynamic properties, and microstructure of the electrospun sample were screened by scanning electron microscopy, thermogravimetric analysis, differential scanning calorimetry, and X-ray diffraction. The optimum conditions of electrospinning with high practical value were obtained.","PeriodicalId":14283,"journal":{"name":"International Journal of Polymer Science","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2023-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48131821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
K. Mohan kumar, Venkatesh Naik, S. Waddar, N. Santhosh, Vijayananda Kaup, H. V. Harish
The present work deals with the characterization of mango seed shell fiber reinforced epoxy composites by using hand layup method by varying the volume composition of the mango seed shell from 0 vol. % to 60 vol. % (M-0 to M-60). The physical density test, tensile test, flexural test, and water absorption test were conducted as per the American Society for Testing and Materials (ASTM) standards. Results revealed that the tensile strength of M-20 (20 vol. %) is 43% more than a neat epoxy, while the flexural strength of M-50 (50 vol. %) is greater than 10.85% more than a neat epoxy. The water absorption test was conducted by immersing the samples in distilled water at room temperature, and the weight of the specimens was measured and recorded at every 24-hour time interval. For all composite samples, saturation in water absorption and thickness swelling were observed after 432 hours of water immersion. The moisture absorption increases with the inclusion of reinforcements as compared to the neat epoxy samples. However, for the M-50 composite, the water absorption decreases due to the uniform mixing and stronger bonding between the matrix and the reinforcements. The scanning electron microscope (SEM) images of the composite specimens also depicted the particulate fiber distribution and the presence of micro-voids in the epoxy matrix.
{"title":"Mechanical and Water Absorption Characterization of Mango Seed Shell/Epoxy Composite for Low Load Carrying Structures","authors":"K. Mohan kumar, Venkatesh Naik, S. Waddar, N. Santhosh, Vijayananda Kaup, H. V. Harish","doi":"10.1155/2023/9976409","DOIUrl":"https://doi.org/10.1155/2023/9976409","url":null,"abstract":"The present work deals with the characterization of mango seed shell fiber reinforced epoxy composites by using hand layup method by varying the volume composition of the mango seed shell from 0 vol. % to 60 vol. % (M-0 to M-60). The physical density test, tensile test, flexural test, and water absorption test were conducted as per the American Society for Testing and Materials (ASTM) standards. Results revealed that the tensile strength of M-20 (20 vol. %) is 43% more than a neat epoxy, while the flexural strength of M-50 (50 vol. %) is greater than 10.85% more than a neat epoxy. The water absorption test was conducted by immersing the samples in distilled water at room temperature, and the weight of the specimens was measured and recorded at every 24-hour time interval. For all composite samples, saturation in water absorption and thickness swelling were observed after 432 hours of water immersion. The moisture absorption increases with the inclusion of reinforcements as compared to the neat epoxy samples. However, for the M-50 composite, the water absorption decreases due to the uniform mixing and stronger bonding between the matrix and the reinforcements. The scanning electron microscope (SEM) images of the composite specimens also depicted the particulate fiber distribution and the presence of micro-voids in the epoxy matrix.","PeriodicalId":14283,"journal":{"name":"International Journal of Polymer Science","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2023-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45744487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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