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Characterisation of Luffa cylindrica Fibre from Cameroon for Use in Composites: Effect of Alkaline Treatment 喀麦隆用于复合材料的圆柱丝瓜纤维的特性:碱性处理的效果
IF 3.3 4区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-05-31 DOI: 10.1155/2024/8108120
Jean Aimé Mono, Assona Appolince Rachelle, Claude Takoumbe, Odette Thérèse Adegono Assiene, Prince Hermann Pokem Nguimjeu, Fabrice Ella Belinga
The study of <i>Luffa cylindrica</i> is seen as an alternative solution for the development of green materials. However, a lack of knowledge about some of their characteristics can slow down these applications. The present study focuses on the characterisation of the fibre derived from the <i>Luffa cylindrica</i> sponge. In this study, the fibre was extracted using a manual technique, followed by a treatment cycle with 5%, 7.5%, and 10% NaOH at a temperature of 28°C for 60 min. The results obtained show the lightness of the fibre through its low density (0.233-0.419 g·cm<sup>-3</sup>), and a hydrophilic nature of the fibre is observed through its water absorption capacity (106.86-180.53%), its relative humidity (9.86-15.33%), and its capacity to diffuse water (<span><svg height="11.9413pt" style="vertical-align:-0.3499002pt" version="1.1" viewbox="-0.0498162 -11.5914 32.221 11.9413" width="32.221pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"></path></g><g transform="matrix(.013,0,0,-0.013,6.24,0)"></path></g><g transform="matrix(.013,0,0,-0.013,9.204,0)"></path></g><g transform="matrix(.013,0,0,-0.013,15.444,0)"></path></g><g transform="matrix(.013,0,0,-0.013,24.59,0)"></path></g></svg><span></span><svg height="11.9413pt" style="vertical-align:-0.3499002pt" version="1.1" viewbox="35.076183799999995 -11.5914 27.712 11.9413" width="27.712pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,35.126,0)"></path></g><g transform="matrix(.013,0,0,-0.013,41.366,0)"><use xlink:href="#g113-49"></use></g><g transform="matrix(.0091,0,0,-0.0091,47.653,-5.741)"></path></g><g transform="matrix(.0091,0,0,-0.0091,53.213,-5.741)"></path></g><g transform="matrix(.0091,0,0,-0.0091,57.645,-5.741)"></path></g></svg></span> m<sup>2</sup>·s<sup>-1</sup> to <span><svg height="11.9413pt" style="vertical-align:-0.3499002pt" version="1.1" viewbox="-0.0498162 -11.5914 32.221 11.9413" width="32.221pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"></path></g><g transform="matrix(.013,0,0,-0.013,6.24,0)"><use xlink:href="#g113-47"></use></g><g transform="matrix(.013,0,0,-0.013,9.204,0)"></path></g><g transform="matrix(.013,0,0,-0.013,15.444,0)"><use xlink:href="#g113-50"></use></g><g transform="matrix(.013,0,0,-0.013,24.59,0)"><use xlink:href="#g117-42"></use></g></svg><span></span><svg height="11.9413pt" style="vertical-align:-0.3499002pt" version="1.1" viewbox="35.076183799999995 -11.5914 27.712 11.9413" width="27.712pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,35.126,0)"><use xlink:href="#g113-50"></use></g><g transform="matrix(.013,0,0,-0.013,41.366,0)"><use xlink:href="#g113-49"></use></g><g transform="matrix(.0091,0,0,-0.0091,47.653,-5.741)"><use xlink:href="#g54-33"></use></g><g trans
对圆筒形丝瓜的研究被视为开发绿色材料的另一种解决方案。然而,对其某些特性的缺乏了解可能会延缓其应用。本研究的重点是分析从圆柱丝瓜海绵中提取的纤维的特性。在这项研究中,采用手工技术提取纤维,然后在 28°C 的温度下用 5%、7.5% 和 10%的 NaOH 进行 60 分钟的循环处理。研究结果表明,这种纤维密度低(0.233-0.419 g-cm-3),重量轻;吸水能力(106.86-180.53%)、相对湿度(9.86-15.33%)和水扩散能力(m2-s-1 至 m2-s-1)与其他植物纤维接近,因此具有亲水性,可用于绝缘和轻质材料。它的直径(418.61-554.42 μm)和线性质量(34-58 g-km-1)都很高,与纺织工业中用于生产纱线的其他纤维形成鲜明对比。其力学结果,即断裂应力(9.744-27.45 兆帕)、杨氏模量(307.56-582.41 兆帕)和断裂伸长率(3.45%-8.11%),与用作聚合物基复合材料增强材料的其他植物纤维接近,可应用于汽车、绝缘、家具和建筑行业。圆筒形丝瓜纤维也有同样的应用前景。用 5%NaOH 处理的纤维可有效改善原纤维的性能。
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引用次数: 0
Fracture Resistance of Endodontically Treated Teeth Restored Using Multifiber Posts Compared with Single Fiber Posts 使用多纤维桩与单纤维桩修复的牙髓治疗牙的抗折性比较
IF 3.3 4区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-05-10 DOI: 10.1155/2024/3203383
Alhanoof Aldegheishem, Reem Barakat, Nour A. L. Huda Alrefaei, Ghaida Alhussain, Kolood Alkoblan, Ebtisam M. Al-Madi
<i>Purpose</i>. The aim of this in vitro study was to evaluate the fracture resistance and type of failure of two adhesive fiber post systems used to restore endodontically treated teeth. <i>Material and Methods</i>. Twenty-seven extracted premolars were selected and divided into three groups (<span><svg height="8.55521pt" style="vertical-align:-0.2063904pt" version="1.1" viewbox="-0.0498162 -8.34882 17.789 8.55521" width="17.789pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"></path></g><g transform="matrix(.013,0,0,-0.013,10.158,0)"></path></g></svg><span></span><span><svg height="8.55521pt" style="vertical-align:-0.2063904pt" version="1.1" viewbox="21.3711838 -8.34882 6.416 8.55521" width="6.416pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,21.421,0)"></path></g></svg>):</span></span> a control group restored with direct composite core (group 1), teeth restored with single fiberglass posts (group 2), and teeth were restored with multifiber posts (Biolight Plus System) (group 3). Fracture resistance was measured by applying axial compressive loads parallel to the longitudinal axis of the tooth until failure. Data was analyzed with one-way ANOVA followed by post hoc Turkey tests. <i>Results</i>. The results showed that the mean forces to failure of the control group (0.068 kN) were significantly lower than those restored with either fiberglass post systems (<span><svg height="11.7782pt" style="vertical-align:-3.42938pt" version="1.1" viewbox="-0.0498162 -8.34882 18.973 11.7782" width="18.973pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"></path></g><g transform="matrix(.013,0,0,-0.013,11.342,0)"><use xlink:href="#g117-34"></use></g></svg><span></span><span><svg height="11.7782pt" style="vertical-align:-3.42938pt" version="1.1" viewbox="22.555183800000002 -8.34882 28.184 11.7782" width="28.184pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,22.605,0)"></path></g><g transform="matrix(.013,0,0,-0.013,28.845,0)"></path></g><g transform="matrix(.013,0,0,-0.013,31.809,0)"><use xlink:href="#g113-49"></use></g><g transform="matrix(.013,0,0,-0.013,38.049,0)"></path></g><g transform="matrix(.013,0,0,-0.013,44.289,0)"></path></g></svg>).</span></span> There was no significant difference between the multifiber and the single fiberglass post system in terms of resistance to fracture (<span><svg height="11.7782pt" style="vertical-align:-3.42938pt" version="1.1" viewbox="-0.0498162 -8.34882 18.973 11.7782" width="18.973pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><use xlink:href="#g113-113"></use></g><g transform="matrix(.013,0,0,-0.013,11.342,0)"><use xlink:href="#g117-34"></use></g></svg><s
研究目的本体外研究旨在评估两种用于修复牙髓治疗牙的粘接纤维桩系统的抗折性和失效类型。材料和方法。选取 27 颗拔出的前臼齿,将其分为三组():用直接复合材料核心修复的对照组(第 1 组)、用单一玻璃纤维桩修复的牙齿(第 2 组)和用多纤维桩(Biolight Plus 系统)修复的牙齿(第 3 组)。抗折性是通过施加平行于牙齿纵轴的轴向压缩荷载直至破坏来测量的。采用单因素方差分析对数据进行分析,然后进行事后火鸡试验。结果显示结果显示,对照组的平均破坏力(0.068 kN)明显低于使用玻璃纤维桩系统()修复的牙齿。在抗折力方面,多纤维和单玻璃纤维桩系统没有明显差异()。虽然与对照组和玻璃纤维桩组相比,Biolight Plus 组(77.7%)有更多的牙齿折断(CEJ 以上),但在统计学上并不显著()。结论在本研究的局限性范围内,就抗折性而言,使用多纤维桩系统进行牙髓治疗修复足以替代单一玻璃纤维桩系统。
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引用次数: 0
Experimental Investigation on the 3D Printing of Nylon Reinforced by Carbon Fiber through Fused Filament Fabrication Process, Effects of Extruder Temperature, and Printing Speed 通过熔融长丝制造工艺对碳纤维增强尼龙进行三维打印的实验研究,以及挤出机温度和打印速度的影响
IF 3.3 4区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-05-10 DOI: 10.1155/2024/1234797
Mahmoud Moradi, Zeinab Malekshahi Beiranvand, Nahid Salimi, Saleh Meiabadi, Jonathan Lawrance
This study investigated how the extruder temperature, printing speed, and specimen geometry interact during a tensile test of continuous carbon fiber-reinforced nylon matrix composites produced by the fused deposition modelling (FDM) process. The investigation utilized statistical techniques. For this purpose, tensile examinations were done on manufactured samples using a testing apparatus. The study’s objective is to identify the most efficient specimen geometry for tensile testing result optimization and to maximize the 3D printing process’s capability for producing complex, freeform patterns in these composites. In this study, the input parameters required for the response surface methodology (RSM) were varying extruder temperature (240-255°C) and printing speed (60-80 mm/s), and experimental responses included modulus, elongation at break, and weight. The findings of the regression analysis showed output responses are influenced by both input variables. The results showed that the strength of the samples was significantly influenced by the input parameters. To draw the surface and residual plots, the software of design expert software was used. The interaction between the two input variables suggests raising the extruder temperature and decreasing printing speed, which leads to printing heavier samples. Inversely, the diversity between the forecasted and real responses for the optimal specimens is less than 10% which is assumed to be acceptable for the design of experiments (DOE). The analysis took into account the lower and upper ranges of the input variable with the goal of enhancing both the most modulus and fracture elongation while simultaneously degrading the weight of the specimens. To achieve this objective, the extruder temperature and printing speed are between 240 and 250°C and 65 and 75 mm/s, respectively.
本研究探讨了在对采用熔融沉积模塑(FDM)工艺生产的连续碳纤维增强尼龙基复合材料进行拉伸测试时,挤出机温度、印刷速度和试样几何形状如何相互作用。调查采用了统计技术。为此,使用测试仪器对制造的样品进行了拉伸试验。研究的目的是确定最有效的试样几何形状,以优化拉伸测试结果,并最大限度地提高 3D 打印工艺在这些复合材料中制作复杂、自由形态图案的能力。在本研究中,响应面方法(RSM)所需的输入参数是不同的挤出机温度(240-255°C)和打印速度(60-80 mm/s),实验响应包括模量、断裂伸长率和重量。回归分析结果表明,输出响应受两个输入变量的影响。结果表明,样品的强度受输入参数的影响很大。绘制曲面图和残差图时使用了 design expert 软件。两个输入变量之间的相互作用表明,提高挤出机温度和降低打印速度会导致打印出更重的样品。相反,最佳试样的预测反应和实际反应之间的差异小于 10%,这对于实验设计(DOE)来说是可以接受的。分析考虑了输入变量的上限和下限范围,目的是提高最大模量和断裂伸长率,同时减轻试样重量。为实现这一目标,挤出机温度和印刷速度分别为 240 至 250°C 和 65 至 75 mm/s。
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引用次数: 0
Comparison of the Film Properties of Lemon and Sour Cherry Seed Essential Oil-Added Glycerol and/or Sorbitol-Plasticized Corn, Potato, Rice, Tapioca, and Wheat Starch-Based Edible Films 添加甘油和/或山梨醇的柠檬和酸樱桃籽精油塑化玉米、马铃薯、大米、木薯和小麦淀粉基食用薄膜的薄膜特性比较
IF 3.3 4区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-04-30 DOI: 10.1155/2024/9112555
Merve Basut Kazak, Nurcan Tugrul
In this study, lemon, and sour cherry seed essential oil-added glycerol and/or sorbitol-plasticized corn, potato, rice, tapioca, and wheat starch-based edible films were produced using the casting method. Starch, essential oil type and glycerol and/or sorbitol effects on the thickness, moisture content, water solubility, swelling index, and water vapor transmission rate of the films have been studied. The interaction of the film components was evaluated by Fourier transform infrared spectroscopy. It was seen that wheat starch-based control films give the lowest thickness value (0.010 mm). Wheat starch-based control films (15.50%), sour cherry seed essential oil-added corn starch (17.80%), and lemon essential oil-added rice starch-based composite films (17.70%) have high moisture content. The lowest solubility values were obtained from wheat starch control (22%) and sour cherry seed essential oil-added corn starch composite (16.40%) films. The highest swelling index values were obtained from wheat starch-based control (210.90-289.0%), sour cherry seed essential oil-added tapioca starch (388.80%), and lemon essential oil-added potato starch-based (433.20%) composite films. Rice starch-based control films have the lowest water vapor transmission rate (<span><svg height="11.9413pt" style="vertical-align:-0.3499002pt" version="1.1" viewbox="-0.0498162 -11.5914 32.221 11.9413" width="32.221pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"></path></g><g transform="matrix(.013,0,0,-0.013,6.24,0)"></path></g><g transform="matrix(.013,0,0,-0.013,9.204,0)"><use xlink:href="#g113-52"></use></g><g transform="matrix(.013,0,0,-0.013,15.444,0)"></path></g><g transform="matrix(.013,0,0,-0.013,24.59,0)"></path></g></svg><span></span><svg height="11.9413pt" style="vertical-align:-0.3499002pt" version="1.1" viewbox="35.076183799999995 -11.5914 68.719 11.9413" width="68.719pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,35.126,0)"></path></g><g transform="matrix(.013,0,0,-0.013,41.366,0)"><use xlink:href="#g113-49"></use></g><g transform="matrix(.0091,0,0,-0.0091,47.653,-5.741)"></path></g><g transform="matrix(.0091,0,0,-0.0091,53.213,-5.741)"></path></g><g transform="matrix(.013,0,0,-0.013,61.086,0)"></path></g><g transform="matrix(.013,0,0,-0.013,71.623,0)"></path></g><g transform="matrix(.013,0,0,-0.013,77.863,0)"><use xlink:href="#g113-47"></use></g><g transform="matrix(.013,0,0,-0.013,80.827,0)"></path></g><g transform="matrix(.013,0,0,-0.013,87.069,0)"><use xlink:href="#g113-49"></use></g><g transform="matrix(.013,0,0,-0.013,96.214,0)"><use xlink:href="#g117-42"></use></g></svg><span></span><span><svg height="11.9413pt" style="vertical-align:-0.3499002pt" version="1.1" viewbox="106.70118380000001 -11.5914 23.399 11.9413" width="23.399pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g
本研究采用浇铸法生产了柠檬和酸樱桃籽精油添加甘油和/或山梨醇塑化的玉米、马铃薯、大米、木薯和小麦淀粉基食用薄膜。研究了淀粉、精油类型以及甘油和/或山梨醇对薄膜厚度、含水量、水溶性、膨胀指数和水蒸气透过率的影响。傅里叶变换红外光谱法评估了薄膜成分之间的相互作用。结果表明,小麦淀粉基对照薄膜的厚度值最低(0.010 毫米)。小麦淀粉基对照薄膜(15.50%)、酸樱桃籽精油添加玉米淀粉(17.80%)和柠檬精油添加大米淀粉基复合薄膜(17.70%)的水分含量较高。小麦淀粉对照(22%)和酸樱桃籽精油添加玉米淀粉的复合薄膜(16.40%)的溶解度值最低。膨胀指数值最高的是小麦淀粉基对照组(210.90-289.0%)、酸樱桃籽精油添加木薯淀粉(388.80%)和柠檬精油添加马铃薯淀粉基(433.20%)复合薄膜。大米淀粉基对照薄膜的水蒸气透过率最低()。可食用复合薄膜的傅立叶变换红外光谱证明,薄膜成分之间不存在化学作用,并保持了各自的结构。本研究与以往研究的主要区别在于首次在食用薄膜生产中使用了酸樱桃籽精油,并比较了玉米、马铃薯、大米、木薯和小麦淀粉基食用薄膜与甘油或山梨醇塑化后的薄膜特性。
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引用次数: 0
Thermal and Mechanical Performance of 3-Phase Polymer Composite Panels for Structural Applications 用于结构应用的三相聚合物复合板的热性能和机械性能
IF 3.3 4区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-04-03 DOI: 10.1155/2024/8822860
Muhammad Zubair Jilani, Zulfiqar Ahmad Rehan, Zuhaib Ahmad, Madeha Jabbar, Yasir Nawab, Khubab Shaker
The objective of this study is to establish a conceptual framework for fiber-reinforced polymer composite (FRPC) panels designed for structural purposes through the incorporation of a third phase (fillers). The present investigation was aimed to design and fabricate 3-phase polymer composite panels that offer enhanced thermal insulation and strength while maintaining low material and labor expenses. Two types of fibrous reinforcements (jute fabric and glass fabric) of different origins were used as reinforcement; polypropylene (PP) was used as the matrix, and microcrystalline cellulose (MCC) was used as particle reinforcement material. The composite materials were fabricated with different MCC concentrations (0, 2 wt%, and 4 wt%), using a hot compression molding technique. It was found that MCC helped to enhance the mechanical performance of the composite panels, while the thermal conductivity showed a slight reduction due to lower concentrations of MCC used. For polypropylene/glass (PPG) composites, thermal conductivity was reduced from 0.214 to 0.193 W/m·K by the addition of 4% MCC fillers. Similarly, for polypropylene/jute (PPJ) composites, it was reduced from 0.14 to 0.126 W/m·K by 4% MCC fillers. The Charpy impact strength of both PPG and PPJ composites was enhanced by the addition of fillers, and the effect was more significant in the case of PPG (increased from 24.83 to 43.98 kJ/m2 for 4% fillers). Cost analysis of the composite panels was also done, showing PPJ panels to be slightly cheaper as compared to PPG. The findings indicate that the developed composite panels have the potential to serve as partitioning as well as the outer shield of the building due to their effective thermal and mechanical properties.
本研究的目的是为纤维增强聚合物复合材料(FRPC)板建立一个概念框架,通过加入第三阶段(填料)来实现结构目的。本研究旨在设计和制造三相聚合物复合板,在保持低材料和劳动力成本的同时,提高隔热性能和强度。我们使用了两种不同产地的纤维增强材料(黄麻织物和玻璃纤维织物)作为增强材料;聚丙烯(PP)作为基体,微晶纤维素(MCC)作为颗粒增强材料。采用热压成型技术,以不同的 MCC 浓度(0、2 wt% 和 4 wt%)制造复合材料。研究发现,MCC 有助于提高复合材料板的机械性能,而由于使用的 MCC 浓度较低,导热性能略有下降。对于聚丙烯/玻璃(PPG)复合材料,添加 4% 的 MCC 填料后,热导率从 0.214 W/m-K 降至 0.193 W/m-K。同样,对于聚丙烯/黄麻(PPJ)复合材料,添加 4% 的 MCC 填料后,导热系数从 0.14 W/m-K 降至 0.126 W/m-K。添加填料后,PPG 和 PPJ 复合材料的夏比冲击强度都有所提高,其中 PPG 的影响更为显著(添加 4% 的填料后,冲击强度从 24.83 kJ/m2 提高到 43.98 kJ/m2)。此外,还对复合板进行了成本分析,结果显示 PPJ 板的成本比 PPG 板稍低。研究结果表明,所开发的复合板具有有效的热性能和机械性能,因此有潜力用作建筑物的隔墙和外护板。
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引用次数: 0
Silver Nanoparticles Decorated in In Situ Reduced Graphene Oxide Nanohybrids Improved Properties in Poly(vinylidene fluoride)/Poly(methyl methacrylate) Blends 原位还原氧化石墨烯纳米杂质中的银纳米粒子改善了聚偏氟乙烯/聚甲基丙烯酸甲酯共混物的性能
IF 3.3 4区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-03-23 DOI: 10.1155/2024/1156880
Afifeh Khorramshokouh, Hesam Ramezani, Mehdi Sahami, Mehdi Sharif, Behzad Vaferi
In this paper, reduced graphene oxide decorated with silver nanoparticle (rGO-Ag) nanohybrids were prepared using an environmentally friendly approach and incorporated as reinforcement in poly(vinylidene fluoride)-poly(methyl methacrylate) blends via a melt mixing process. The microstructure of rGO-Ag nanohybrids and its effect on the microstructure, mechanical, thermal, and electrical properties of the PVDF/PMM/rGO-Ag was studied using Fourier transform infrared (FTIR), Raman spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), tensile, thermogravimetric analysis (TGA), and impedance spectroscopy methods. FTIR and TEM analysis confirmed that rGO-Ag successfully synthesized and Ag nanoparticles are located on the rGO surface. The tensile analysis demonstrated that incorporating 1 wt.% of rGO-Ag in PVDF/PMMA blend increases Young’s modulus and strength of nanocomposite up to 31% and 35%, respectively. The Halpin-Tsai model was also used for PVDF/PMMA/rGO-Ag nanocomposites, and the results confirmed that this model works well to predict the tensile modulus. Impedance spectroscopy analysis showed that the presence of rGO-Ag nanohybrids in PVDF/PMMA blend effectively enhanced the conductivity of PVDF/PMMA blend. TGA results demonstrated that the presence of rGO-Ag nanohybrids enhanced the thermal stability of nanocomposites and increased the degradation temperature of PVDF/PMMA/rGO-Ag nanocomposites in the range of 20°C compared to PVDF/PMMA blend.
本文采用一种环境友好型方法制备了银纳米粒子装饰的还原氧化石墨烯纳米杂化物(rGO-Ag),并通过熔融混合工艺将其作为增强材料加入到聚(偏氟乙烯)-聚(甲基丙烯酸甲酯)共混物中。采用傅立叶变换红外(FTIR)、拉曼光谱、X 射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、拉伸、热重分析(TGA)和阻抗光谱等方法研究了 rGO-Ag 纳米杂化物的微观结构及其对 PVDF/PMM/rGO-Ag 的微观结构、机械、热和电特性的影响。傅立叶变换红外光谱和透射电子显微镜分析证实 rGO-Ag 成功合成,且 Ag 纳米颗粒位于 rGO 表面。拉伸分析表明,在 PVDF/PMMA 混合物中加入 1 wt.% 的 rGO-Ag 可使纳米复合材料的杨氏模量和强度分别提高 31% 和 35%。Halpin-Tsai 模型也被用于 PVDF/PMMA/rGO-Ag 纳米复合材料,结果证实该模型能很好地预测拉伸模量。阻抗光谱分析表明,在 PVDF/PMMA 共混物中加入 rGO-Ag 纳米杂化物可有效提高 PVDF/PMMA 共混物的导电性。热重分析结果表明,rGO-Ag 纳米杂化物的存在增强了纳米复合材料的热稳定性,与 PVDF/PMMA 混合物相比,PVDF/PMMA/rGO-Ag 纳米复合材料在 20°C 范围内的降解温度有所提高。
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引用次数: 0
Evaluation of Monomer Releasing from Dentin Replacement Materials 牙本质替代材料释放单体的评估
IF 3.3 4区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-03-12 DOI: 10.1155/2024/9350118
Nurgül Çetin Tuncer, Sevde Gül Batmaz, Sergen Özdemir, Çağatay Barutçugil, Ayşe Dündar, Kardelen Yıldırım
The aim of this study is to determine and quantify the monomer elution from four different resin-based composite dentin replacement materials for 3 months using HPLC. Four different composite dentin replacement materials were used in the present study: EverX (EVX), X-tra base (XTB), SDR (SDR), and GrandioSO Heavy Flow (GHF). Fifteen samples from each material were prepared ( mm). After preparation, each specimen was immersed in a 10 ml 75% ethanol/distilled water solution for three different periods: 1 h, 24 h, and 3 months (). After the immersion period, 0.5 ml of solutions were taken from each bottle and analyzed using HPLC. At the end of the 3-month immersion period, the elution of monomers was determined mostly from SDR, GHF, EVX, and XTB, respectively. TEGDMA, the most released monomer of all groups, was released from all samples after 1 h, 24 h, and 3 months. The amount of monomer released in all composite groups at the end of the 3-month immersion period was significantly higher than the monomer amounts released after the 1-hour immersion period. The monomers were eluted from the composite dentin replacement materials during all immersion periods, and the amount of eluted monomers was increased with time.
本研究的目的是使用高效液相色谱法测定和量化四种不同树脂基复合牙本质替代材料 3 个月的单体洗脱情况。本研究使用了四种不同的复合牙本质替代材料:EverX (EVX)、X-tra base (XTB)、SDR (SDR) 和 GrandioSO Heavy Flow (GHF)。每种材料都制备了 15 个样品(毫米)。制备完成后,将每个试样浸泡在 10 毫升 75% 的乙醇/蒸馏水溶液中,浸泡时间分别为 1 小时、24 小时和 3 个月()。浸泡期结束后,从每个瓶子中提取 0.5 毫升溶液,使用高效液相色谱法进行分析。在 3 个月的浸泡期结束时,分别测定了 SDR、GHF、EVX 和 XTB 的单体洗脱情况。TEGDMA 是所有组别中释放量最大的单体,在 1 小时、24 小时和 3 个月后从所有样品中释放出来。所有复合材料组在 3 个月浸泡期结束时释放的单体量都明显高于 1 小时浸泡期后释放的单体量。在所有浸泡期中,单体都从复合牙本质替代材料中洗脱出来,而且洗脱出来的单体量随着时间的推移而增加。
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引用次数: 0
Antiacne Gel Containing Aloe vera and Clindamycin Phosphate: Design, Characterization, and Optimization Using Response Surface Methodology 含芦荟和克林霉素磷酸酯的祛痘凝胶:利用响应面方法进行设计、表征和优化
IF 3.3 4区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-03-07 DOI: 10.1155/2024/3353141
Tayyaba Rana, Muhammad Zaman, Mahtab Ahmed Khan, Abdul Qayyum Khan, Muhammad Jamshaid, Nehal Ahmed Talaat Nouh, Fatma M. El-Demerdash, Mohamed Kamel, Mohamed M. Abdel-Daim, Ghadeer M. Albadrani, Sumiyya Javaid, Zainab Naeem
Clindamycin phosphate is a topical antibiotic agent used to treat acne vulgaris, while Aloe vera has both antimicrobial and anti-inflammatory properties. The current study is aimed at formulating an antiacne gel with antioxidant and antimicrobial effects. The antiacne gels were prepared by using polymer HPMC K15M by cold dispersion method. Unveiling the intricacies of gel design, our research harnessed the power of Design Expert 11 to optimize critical parameters—viscosity, spreadability, and permeability. In vitro characterization tests, including pH, spreadability, viscosity, permeability, antimicrobial activity, antioxidant activity, and stability of the gels, were performed. The results of in vitro characterization tests showed that the gels had a mint-like odor, a pH of 6.8, and a spreadability of 21.5 g cm/sec. The gels had a viscosity of 34.2 Pa s and drug content ranging within 90%-110%, as per USP standards. Notably, in vitro permeation assays reveal an exceptional 86% drug release, showcasing the efficacy of our formulation. The uniqueness of our study lies not only in the robust optimization process but also in the multifaceted characterization. Our gel emerges as a promising candidate, exhibiting not only desired antimicrobial and antioxidant properties against acne vulgaris but also demonstrating stability under varied conditions. As we advance toward in vivo studies, our research paves the way for a nuanced understanding of the safety and efficacy of this distinctive antiacne gel.
克林霉素磷酸酯是一种用于治疗寻常痤疮的外用抗生素,而芦荟则具有抗菌和消炎特性。本研究旨在配制一种具有抗氧化和抗菌功效的抗痘凝胶。该抗痘凝胶采用聚合物 HPMC K15M,通过冷分散法制备而成。我们的研究揭示了凝胶设计的复杂性,利用 Design Expert 11 的强大功能优化了关键参数--粘度、铺展性和渗透性。我们还进行了体外表征测试,包括凝胶的 pH 值、铺展性、粘度、渗透性、抗菌活性、抗氧化活性和稳定性。体外表征测试结果表明,凝胶具有类似薄荷的气味,pH 值为 6.8,铺展性为 21.5 克厘米/秒。根据美国药典标准,凝胶的粘度为 34.2 帕秒,药物含量在 90%-110% 之间。值得注意的是,体外渗透试验显示药物释放率高达 86%,这充分展示了我们配方的功效。我们研究的独特之处不仅在于稳健的优化过程,还在于多方面的表征。我们的凝胶是一种很有前途的候选产品,不仅具有针对寻常痤疮的理想抗菌和抗氧化特性,而且在各种条件下都表现出稳定性。随着体内研究的推进,我们的研究为深入了解这种独特的抗痘凝胶的安全性和有效性铺平了道路。
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引用次数: 0
Determination of Dynamic Mechanical Properties on Addition of Carbon Black-Nanosilica Hybrid Fillers in NR-SBR Blends with Special Reference to Power Transmission Belt Applications 确定在 NR-SBR 共混物中添加炭黑-纳米二氧化硅混合填料时的动态力学性能,特别是在动力传动带应用中的效果
IF 3.3 4区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-02-23 DOI: 10.1155/2024/3101938
Thuruthil Raju Aswathy, Seshadri Mohan, Thangavel Kalaivendhan, A. Mohammed Adhil
Next to tyres, power transmission belts are one of the most complicated rubber products which is having a constant increase for demand in the market. Due to this high demand along with the requirement to meet certain special operating conditions, it is necessary to improve the belt properties continuously. In the last few decades, nanotechnology evolved as a suitable method for enhancing the properties of various rubber products without impacting the environment. Nanofillers which are having unique morphology along with excellent properties help to reduce the dependency in petroleum products and in turn make the products more sustainable. Even though, studies related to the usage of nanotechnology in the power transmission belt division are very limited. So, in this study, the effect of nanosilica on the dynamic mechanical properties of the natural rubber- (NR-) styrene butadiene rubber (SBR) blends is thoroughly studied with special reference to power transmission belt applications. The developed composites were analysed to ensure the rheological, mechanical, and morphological properties in comparison with the controlled samples. The nanosilica-based belt properties were analysed in reference with regular carbon black-filled belts, and a 15% improvement in belt life was obtained for newly developed belts.
传动带是仅次于轮胎的最复杂的橡胶产品之一,市场需求量不断增加。由于需求量大,而且需要满足某些特殊的操作条件,因此有必要不断改进传动带的性能。在过去的几十年中,纳米技术逐渐发展成为在不影响环境的情况下提高各种橡胶产品性能的合适方法。纳米填料具有独特的形态和优异的性能,有助于减少对石油产品的依赖,从而使产品更具可持续性。尽管如此,有关纳米技术在传动带领域应用的研究还非常有限。因此,本研究深入研究了纳米二氧化硅对天然橡胶-丁苯橡胶(SBR)混合物动态机械性能的影响,并特别参考了动力传动带的应用。与对照样品相比,对所开发的复合材料进行了流变学、机械和形态学性能分析。与普通碳黑填充皮带相比,对基于纳米二氧化硅的皮带性能进行了分析,结果表明新开发的皮带寿命提高了 15%。
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引用次数: 0
Biopolymer Composite Materials in Oil and Gas Sector 石油和天然气领域的生物聚合物复合材料
IF 3.3 4区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-02-21 DOI: 10.1155/2024/8584879
Jibrilla Abdulrahman, Williams S. Ebhota, Pavel Y. Tabakov
In the oil and gas industry, the demand for alternative materials is rising due to corrosion and the desire to reduce costs through weight reduction. Polymer composites are gaining attention for their corrosion resistance, favourable strength-to-weight ratio, and cost-effectiveness. The biopolymer composite is projected to have an output worth $4.95 billion between 2021 and 2025 and growth at a 5.38% compound annual growth rate. This review focuses on exploring the potential of natural fibres as reinforcement for biofibre polymer composite pipes in oil and gas, highlighting their ecofriendliness, biodegradability, and cost-efficiency. The paper assesses biopolymer composite pipes’ development, challenges, and applications, particularly those using continuous basalt and banana fibres. While basalt fibre has found field applications, banana fibre-reinforced polymer composites are still in the early research stages. Despite significant oil and gas industry players already endorsing polymer composites, further research is needed for biopolymer composites to address challenges like compatibility, environmental impact, standardisation, long-term durability, production processes, and regulatory acceptance. Advancing biocomposite research and exploring new research opportunities are essential for engineering advancements and advanced materials.
在石油和天然气行业,由于腐蚀和希望通过减轻重量来降低成本,对替代材料的需求不断增加。聚合物复合材料因其耐腐蚀性、良好的强度重量比和成本效益而备受关注。预计 2021 年至 2025 年,生物聚合物复合材料的产值将达到 49.5 亿美元,复合年增长率为 5.38%。本综述重点探讨了天然纤维作为生物纤维聚合物复合管道增强材料在石油和天然气领域的应用潜力,强调了天然纤维的生态友好性、生物降解性和成本效益。论文评估了生物聚合物复合管道的开发、挑战和应用,特别是使用连续玄武岩纤维和香蕉纤维的管道。玄武岩纤维已在实地应用,而香蕉纤维增强聚合物复合材料仍处于早期研究阶段。尽管石油和天然气行业的重要企业已经认可聚合物复合材料,但生物聚合物复合材料仍需进一步研究,以应对兼容性、环境影响、标准化、长期耐久性、生产工艺和监管认可度等挑战。推进生物复合材料研究和探索新的研究机会对于工程技术进步和先进材料至关重要。
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International Journal of Polymer Science
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