首页 > 最新文献

International Journal of Spectroscopy最新文献

英文 中文
Design of Novel Metal Nanostructures for Broadband Solar Energy Conversion 用于宽带太阳能转换的新型金属纳米结构设计
Pub Date : 2015-02-03 DOI: 10.1155/2015/147423
K. A. Zhang, D. Ma, Ying-Chih Pu, Yat Li
Solar power holds great potential as an alternative energy source, but current photovoltaic cells have much room for improvement in cost and efficiency. Our objective was to develop metal nanostructures whose surface plasmon resonance (SPR) spectra closely match the solar spectrum to enhance light absorption and scattering. We employed the finite-difference time-domain simulation method to evaluate the effect of varying key parameters. A novel nanostructure with SPR absorption matching a region of the solar spectrum (300 to 1500 nm) that contains 90% of solar energy was successfully designed. This structure consists of a large gold-silica core-shell structure with smaller gold nanoparticles and nanorods on its surface. Such complex nanostructures are promising for broad and tunable absorption spectra. In addition, we investigated the SPR of silver nanoparticle arrays, which can achieve scattering close to the solar spectrum. We demonstrated an improvement in efficiency of over 30% with optimal nanoparticle radius and periods of 75 nm and 325 nm, respectively. In combination, our studies enable high-efficiency, tunable, and cost-effective enhancement of both light absorption and scattering, which has potential applications in solar energy conversion as well as biomedical imaging.
太阳能作为一种替代能源具有巨大的潜力,但目前的光伏电池在成本和效率上还有很大的提高空间。我们的目标是开发表面等离子体共振(SPR)光谱与太阳光谱密切匹配的金属纳米结构,以增强光的吸收和散射。我们采用时域有限差分仿真方法来评估不同关键参数的影响。成功设计了一种SPR吸收匹配太阳光谱(300 ~ 1500nm)区域的新型纳米结构,该区域包含90%的太阳能。该结构由一个大的金-硅核-壳结构组成,其表面有较小的金纳米颗粒和纳米棒。这种复杂的纳米结构有望获得广泛和可调的吸收光谱。此外,我们还研究了银纳米颗粒阵列的SPR,该阵列可以实现接近太阳光谱的散射。我们证明,当纳米颗粒半径和周期分别为75 nm和325 nm时,效率提高了30%以上。我们的研究使光吸收和散射的高效、可调和经济有效的增强成为可能,这在太阳能转换和生物医学成像方面具有潜在的应用。
{"title":"Design of Novel Metal Nanostructures for Broadband Solar Energy Conversion","authors":"K. A. Zhang, D. Ma, Ying-Chih Pu, Yat Li","doi":"10.1155/2015/147423","DOIUrl":"https://doi.org/10.1155/2015/147423","url":null,"abstract":"Solar power holds great potential as an alternative energy source, but current photovoltaic cells have much room for improvement in cost and efficiency. Our objective was to develop metal nanostructures whose surface plasmon resonance (SPR) spectra closely match the solar spectrum to enhance light absorption and scattering. We employed the finite-difference time-domain simulation method to evaluate the effect of varying key parameters. A novel nanostructure with SPR absorption matching a region of the solar spectrum (300 to 1500 nm) that contains 90% of solar energy was successfully designed. This structure consists of a large gold-silica core-shell structure with smaller gold nanoparticles and nanorods on its surface. Such complex nanostructures are promising for broad and tunable absorption spectra. In addition, we investigated the SPR of silver nanoparticle arrays, which can achieve scattering close to the solar spectrum. We demonstrated an improvement in efficiency of over 30% with optimal nanoparticle radius and periods of 75 nm and 325 nm, respectively. In combination, our studies enable high-efficiency, tunable, and cost-effective enhancement of both light absorption and scattering, which has potential applications in solar energy conversion as well as biomedical imaging.","PeriodicalId":14329,"journal":{"name":"International Journal of Spectroscopy","volume":"43 1","pages":"1-10"},"PeriodicalIF":0.0,"publicationDate":"2015-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82365937","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Moderate UVC Irradiation on Bovine Serum Albumin and Complex with Antimetabolite 5-Fluorouracil: Fluorescence Spectroscopic and Molecular Modelling Studies 中等紫外线照射对牛血清白蛋白及其与抗代谢物5-氟尿嘧啶复合物的影响:荧光光谱和分子模拟研究
Pub Date : 2015-01-31 DOI: 10.1155/2015/315764
Shanmugavel Chinnathambi, Shanmugavel Chinnathambi, S. Karthikeyan, D. Velmurugan, N. Hanagata, N. Hanagata, P. Aruna, S. Ganesan
The interaction of antimetabolite 5-fluorouracil (5FU) with bovine serum albumin (BSA) under UVC (253.7 nm) irradiation was investigated in the present study using UV-Vis spectroscopy, steady state/time resolved fluorescence spectroscopic techniques. The stability of protein was found to be very strong when BSA gets bind to 5FU and moreover it is compared with the free BSA under UVC irradiation. From the fluorescence spectroscopic study, the stability of the complex was found to acquire 2-fold stronger than free protein. From the molecular modelling studies, we came to know the hydrogen bonds between BSA and antimetabolite 5FU are strong, up to 70.4 J/m2 under UVC irradiation.
采用紫外可见光谱、稳态/时间分辨荧光光谱技术研究了抗代谢物5-氟尿嘧啶(5FU)与牛血清白蛋白(BSA)在UVC (253.7 nm)照射下的相互作用。发现BSA与5FU结合后蛋白的稳定性很强,并与UVC照射下的游离BSA进行了比较。通过荧光光谱研究,发现复合物的稳定性比游离蛋白强2倍。通过分子模拟研究,我们了解到BSA与抗代谢产物5FU之间的氢键很强,在UVC照射下氢键可达70.4 J/m2。
{"title":"Effect of Moderate UVC Irradiation on Bovine Serum Albumin and Complex with Antimetabolite 5-Fluorouracil: Fluorescence Spectroscopic and Molecular Modelling Studies","authors":"Shanmugavel Chinnathambi, Shanmugavel Chinnathambi, S. Karthikeyan, D. Velmurugan, N. Hanagata, N. Hanagata, P. Aruna, S. Ganesan","doi":"10.1155/2015/315764","DOIUrl":"https://doi.org/10.1155/2015/315764","url":null,"abstract":"The interaction of antimetabolite 5-fluorouracil (5FU) with bovine serum albumin (BSA) under UVC (253.7 nm) irradiation was investigated in the present study using UV-Vis spectroscopy, steady state/time resolved fluorescence spectroscopic techniques. The stability of protein was found to be very strong when BSA gets bind to 5FU and moreover it is compared with the free BSA under UVC irradiation. From the fluorescence spectroscopic study, the stability of the complex was found to acquire 2-fold stronger than free protein. From the molecular modelling studies, we came to know the hydrogen bonds between BSA and antimetabolite 5FU are strong, up to 70.4 J/m2 under UVC irradiation.","PeriodicalId":14329,"journal":{"name":"International Journal of Spectroscopy","volume":"71 1","pages":"1-12"},"PeriodicalIF":0.0,"publicationDate":"2015-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86236858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
Spectral Properties of Dyes with Interfragmental Charge Transfer: Solvatochromism and Solvatofluorochromism of 2-(3-Coumaroyl)-benzopyrylium Perchlorates 片段间电荷转移染料的光谱性质:2-(3-香豆醇基)-高氯酸苯并吡啶的溶剂变色和溶剂荧光变色
Pub Date : 2014-12-23 DOI: 10.1155/2014/508153
E. V. Sanin, A. I. Novikov, A. Roshal
The paper deals with the spectral properties of dyes with interfragmental charge transfer, in particular, derivatives of 2-(3-coumaroyl)benzopyrylium (CBP) perchlorates. The positions of long-wavelength absorption and emission bands, quantum yields, and lifetimes of fluorescence were measured, mostly in aprotic solvents. Regression analysis of the relationship between the spectral characteristics of CBP and the main solvent parameters (polarity, polarisability, nucleophilicity, and electrophilicity) was carried out. It was found that the characteristics of CBP depend mainly on two solvent parameters—polarity and/or nucleophilicity. An increase in these parameters results in a hypsochromic shift of absorption bands and a decrease of lifetimes and fluorescence intensity. The positions of the emission bands can demonstrate either hypsochromism or bathochromism, depending on the nature of the substituents. The solvatofluorochromic effects are not as strong as the solvatochromic ones. We believe that the spectral behaviour of CBP can be explained by cation depolarisation and by a decrease in the stability of nucleophilic complexes with solvent molecules that is associated with interfragmental charge transfer following excitation, relaxation, and radiative deactivation of the excited state.
本文研究了具有片段间电荷转移的染料的光谱性质,特别是高氯酸盐2-(3-香豆醇基)苯并吡啶(CBP)衍生物。主要在非质子溶剂中测量了长波吸收和发射带的位置、量子产率和荧光寿命。对CBP的光谱特征与主要溶剂参数(极性、极化性、亲核性和亲电性)之间的关系进行了回归分析。结果表明,CBP的性质主要取决于极性和亲核性两个溶剂参数。这些参数的增加导致吸收带的次色移和寿命和荧光强度的降低。根据取代基的性质,发射带的位置可以表现为浅显色或深显色。溶剂化致荧光效应不如溶剂化致荧光效应强。我们认为CBP的光谱行为可以用阳离子去极化和与溶剂分子的亲核配合物稳定性的降低来解释,这与激发态激发、弛豫和辐射失活后碎片间电荷转移有关。
{"title":"Spectral Properties of Dyes with Interfragmental Charge Transfer: Solvatochromism and Solvatofluorochromism of 2-(3-Coumaroyl)-benzopyrylium Perchlorates","authors":"E. V. Sanin, A. I. Novikov, A. Roshal","doi":"10.1155/2014/508153","DOIUrl":"https://doi.org/10.1155/2014/508153","url":null,"abstract":"The paper deals with the spectral properties of dyes with interfragmental charge transfer, in particular, derivatives of 2-(3-coumaroyl)benzopyrylium (CBP) perchlorates. The positions of long-wavelength absorption and emission bands, quantum yields, and lifetimes of fluorescence were measured, mostly in aprotic solvents. Regression analysis of the relationship between the spectral characteristics of CBP and the main solvent parameters (polarity, polarisability, nucleophilicity, and electrophilicity) was carried out. \u0000It was found that the characteristics of CBP depend mainly on two solvent parameters—polarity and/or nucleophilicity. An increase in these parameters results in a hypsochromic shift of absorption bands and a decrease of lifetimes and fluorescence intensity. The positions of the emission bands can demonstrate either hypsochromism or bathochromism, depending on the nature of the substituents. The solvatofluorochromic effects are not as strong as the solvatochromic ones. We believe that the spectral behaviour of CBP can be explained by cation depolarisation and by a decrease in the stability of nucleophilic complexes with solvent molecules that is associated with interfragmental charge transfer following excitation, relaxation, and radiative deactivation of the excited state.","PeriodicalId":14329,"journal":{"name":"International Journal of Spectroscopy","volume":"1 1","pages":"1-8"},"PeriodicalIF":0.0,"publicationDate":"2014-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90209829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Graphical Conversion between Compliance and Modulus, Permittivity and Electric Modulus, and Impedance and Admittance 柔度和模量、介电常数和电模量、阻抗和导纳之间的图形转换
Pub Date : 2014-11-25 DOI: 10.1155/2014/538206
M. Nakanishi
Spectrometries probing relaxation and retardation phenomena, such as dielectric, mechanical, and impedance spectroscopies, often require the analyses with both susceptibilities spectra and its reciprocals (e.g., complex permittivity and electric modulus, mechanical compliance and mechanical modulus, and impedance and admittance). In the present paper, the geometric relation between and is derived and the procedure to convert into on a Cole-Cole diagram is proposed. This method helps us to relate them intuitively and yields clearer understanding on their interrelations. Moreover, it opens the new route for the geometric approach to derive many mathematical properties of spectra. The relation between peak position of spectrum and that of spectrum and the shape of spectra are discussed on the basis of this method.
探测弛豫和延迟现象的光谱学,如介电、机械和阻抗光谱,通常需要同时分析磁化率光谱及其倒数(如复介电常数和电模量、机械顺应性和机械模量、阻抗和导纳)。本文推导了与的几何关系,并给出了转换成Cole-Cole图的方法。这种方法有助于我们直观地将它们联系起来,并对它们的相互关系有更清晰的理解。此外,它还为用几何方法推导光谱的许多数学性质开辟了新的途径。在此基础上讨论了谱峰位置与谱峰位置和谱峰形状之间的关系。
{"title":"Graphical Conversion between Compliance and Modulus, Permittivity and Electric Modulus, and Impedance and Admittance","authors":"M. Nakanishi","doi":"10.1155/2014/538206","DOIUrl":"https://doi.org/10.1155/2014/538206","url":null,"abstract":"Spectrometries probing relaxation and retardation phenomena, such as dielectric, mechanical, and impedance spectroscopies, often require the analyses with both susceptibilities spectra and its reciprocals (e.g., complex permittivity and electric modulus, mechanical compliance and mechanical modulus, and impedance and admittance). In the present paper, the geometric relation between and is derived and the procedure to convert into on a Cole-Cole diagram is proposed. This method helps us to relate them intuitively and yields clearer understanding on their interrelations. Moreover, it opens the new route for the geometric approach to derive many mathematical properties of spectra. The relation between peak position of spectrum and that of spectrum and the shape of spectra are discussed on the basis of this method.","PeriodicalId":14329,"journal":{"name":"International Journal of Spectroscopy","volume":"25 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2014-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79646958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Optical Path Length Calibration: A Standard Approach for Use in Absorption Cell-Based IR-Spectrometric Gas Analysis 光程长度校准:一种用于基于吸收池的红外光谱气体分析的标准方法
Pub Date : 2014-07-17 DOI: 10.1155/2014/132607
J. Nwaboh, O. Witzel, A. Pogány, O. Werhahn, V. Ebert
We employed a comparison method to determine the optical path length of gas cells which can be used in spectroscopic setup based on laser absorption spectroscopy or FTIR. The method is based on absorption spectroscopy itself. A reference gas cell, whose length is ap rioriknown and desirably traceable to the international system of units (SI), and a gas mixture are used to calibrate the path length of a cell under test. By comparing spectra derived from pressure-dependent measurements on the two cells, the path length of the gas cell under test is determined. The method relies neither on the knowledge of the gas concentration nor on the line strength parameter of the probed transition which is very rarely traceable to the SI and of which the uncertainty is often relatively large. The method is flexible such that any infrared light source and infrared active molecule with isolated lines can be used. We elaborate on the method, substantiate the method by reporting results of this calibration procedure applied to multipass and single pass gas cells of lengths from 0.38 m to 21 m, and compare this to other methods. The relative combined uncertainty of the path length results determined using the comparison method was found to be in the ±0.4% range.
我们采用比较的方法来确定气体电池的光程长度,该方法可用于基于激光吸收光谱或FTIR的光谱设置。该方法是基于吸收光谱本身。参考气体池,其长度是已知的,并期望可溯源到国际单位制(SI),气体混合物被用来校准被测电池的路径长度。通过比较从两个电池上的压力相关测量得到的光谱,确定了待测气体电池的路径长度。该方法既不依赖于气体浓度的知识,也不依赖于探测跃迁的线强度参数,这些参数很少可追溯到SI,并且其不确定性通常相对较大。该方法具有灵活性,可以使用任何红外光源和具有隔离线的红外活性分子。我们详细阐述了该方法,通过报告该校准程序应用于长度为0.38 m至21 m的多通和单通气池的结果来证实该方法,并将其与其他方法进行比较。对比法测定的路径长度结果的相对组合不确定度在±0.4%范围内。
{"title":"Optical Path Length Calibration: A Standard Approach for Use in Absorption Cell-Based IR-Spectrometric Gas Analysis","authors":"J. Nwaboh, O. Witzel, A. Pogány, O. Werhahn, V. Ebert","doi":"10.1155/2014/132607","DOIUrl":"https://doi.org/10.1155/2014/132607","url":null,"abstract":"We employed a comparison method to determine the optical path length of gas cells which can be used in spectroscopic setup based on laser absorption spectroscopy or FTIR. The method is based on absorption spectroscopy itself. A reference gas cell, whose length is ap rioriknown and desirably traceable to the international system of units (SI), and a gas mixture are used to calibrate the path length of a cell under test. By comparing spectra derived from pressure-dependent measurements on the two cells, the path length of the gas cell under test is determined. The method relies neither on the knowledge of the gas concentration nor on the line strength parameter of the probed transition which is very rarely traceable to the SI and of which the uncertainty is often relatively large. The method is flexible such that any infrared light source and infrared active molecule with isolated lines can be used. We elaborate on the method, substantiate the method by reporting results of this calibration procedure applied to multipass and single pass gas cells of lengths from 0.38 m to 21 m, and compare this to other methods. The relative combined uncertainty of the path length results determined using the comparison method was found to be in the ±0.4% range.","PeriodicalId":14329,"journal":{"name":"International Journal of Spectroscopy","volume":"19 1","pages":"1-9"},"PeriodicalIF":0.0,"publicationDate":"2014-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84450965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 13
Uniform versus Nonuniform Scaling of Normal Modes Predicted by Ab Initio Calculations: A Test on 2-(2,6-Dichlorophenyl)-N-(1,3-thiazol-2yl) Acetamide 用从头计算预测正态模式的均匀与非均匀标度:对2-(2,6-二氯苯基)- n -(1,3-噻唑-2基)乙酰胺的测试
Pub Date : 2014-07-10 DOI: 10.1155/2014/649268
A. K. Srivastava, A. K. Pandey, S. Pandey, P. Nayak, B. Narayana, B. Sarojini, N. Misra
A test on calculated vibrational modes of 2-(2,6-dichlorophenyl)-N-(1,3-thiazol-2yl) acetamide using ab initio density functional method has been performed. The calculated harmonic vibrational frequencies are scaled via two schemes, uniform, , and nonuniform, . Scaled vibrational modes are compared with experimental FTIR bands. A good correlation is shown between scaled frequencies with the correlation coefficient, . This clearly shows that both schemes efficiently reproduce observed spectrum. However, a close investigation of individual normal modes reveals that nonuniform scaling performs much better than uniform scaling especially in the high frequency region.
用从头算密度泛函法对2-(2,6-二氯苯基)- n -(1,3-噻唑-2基)乙酰胺的计算振动模态进行了测试。计算出的谐波振动频率通过均匀和非均匀两种格式进行缩放。将尺度振动模式与实验波段进行了比较。缩放后的频率与相关系数之间具有良好的相关性。这清楚地表明两种方案都能有效地再现观测到的光谱。然而,对单个正态模态的仔细研究表明,非均匀标度比均匀标度表现得更好,特别是在高频区域。
{"title":"Uniform versus Nonuniform Scaling of Normal Modes Predicted by Ab Initio Calculations: A Test on 2-(2,6-Dichlorophenyl)-N-(1,3-thiazol-2yl) Acetamide","authors":"A. K. Srivastava, A. K. Pandey, S. Pandey, P. Nayak, B. Narayana, B. Sarojini, N. Misra","doi":"10.1155/2014/649268","DOIUrl":"https://doi.org/10.1155/2014/649268","url":null,"abstract":"A test on calculated vibrational modes of 2-(2,6-dichlorophenyl)-N-(1,3-thiazol-2yl) acetamide using ab initio density functional method has been performed. The calculated harmonic vibrational frequencies are scaled via two schemes, uniform, , and nonuniform, . Scaled vibrational modes are compared with experimental FTIR bands. A good correlation is shown between scaled frequencies with the correlation coefficient, . This clearly shows that both schemes efficiently reproduce observed spectrum. However, a close investigation of individual normal modes reveals that nonuniform scaling performs much better than uniform scaling especially in the high frequency region.","PeriodicalId":14329,"journal":{"name":"International Journal of Spectroscopy","volume":"263 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2014-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75106849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Quantum Chemical and Spectroscopic Investigations of (Ethyl 4 hydroxy-3-((E)-(pyren-1-ylimino)methyl)benzoate) by DFT Method DFT法研究(4 -羟基-3-((E)-(芘-1-苯甲酸)甲基苯甲酸酯)的量子化学和光谱
Pub Date : 2014-07-09 DOI: 10.1155/2014/841593
Diwaker, A. Gupta
In the present work we have reported the optimized ground state geometry, harmonic vibrational frequencies, NMR chemical shifts, NBO analysis, and molecular electrostatic potential surface map of the title compound using DFT/B3LYP/6-311
本文利用DFT/B3LYP/6-311分析了该化合物的优化基态几何结构、谐波振动频率、核磁共振化学位移、NBO分析和分子静电势表面图
{"title":"Quantum Chemical and Spectroscopic Investigations of (Ethyl 4 hydroxy-3-((E)-(pyren-1-ylimino)methyl)benzoate) by DFT Method","authors":"Diwaker, A. Gupta","doi":"10.1155/2014/841593","DOIUrl":"https://doi.org/10.1155/2014/841593","url":null,"abstract":"In the present work we have reported the optimized ground state geometry, harmonic vibrational frequencies, NMR chemical shifts, NBO analysis, and molecular electrostatic potential surface map of the title compound using DFT/B3LYP/6-311","PeriodicalId":14329,"journal":{"name":"International Journal of Spectroscopy","volume":"33 1","pages":"1-15"},"PeriodicalIF":0.0,"publicationDate":"2014-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76551429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
New Kinetic Spectrophotometric Method for Determination of Fexofenadine Hydrochloride in Pharmaceutical Formulations 动力学分光光度法测定制剂中盐酸非索非那定的含量
Pub Date : 2014-06-29 DOI: 10.1155/2014/308087
S. Ashour, Mouhammed Khateeb
A simple and sensitive kinetic spectrophotometric method was developed for the determination of fexofenadine hydrochloride in bulk and pharmaceutical preparations. The method is based on a kinetic investigation of the oxidation reaction of fexofenadine using alkaline potassium permanganate as an oxidizing agent at room temperature. The reaction is followed spectrophotometrically by measuring the increase of absorbance owing to the formation of manganate ion at 610 nm. The initial rate and fixed time (at 15 min) methods are utilized for construction of calibration graphs. All the reaction conditions for the proposed method have been studied. The linearity range was found to be 2.5–50.0 μg mL−1 with detection limit of 0.055 μg mL−1 for both initial rate and fixed time methods. The proposed method was applied successfully for the determination of fexofenadine in pharmaceutical formulations; the percentage recoveries were 99.98–101.96%. The results obtained were compared statistically with those obtained by the official method and showed no significant differences regarding accuracy and precision.
建立了一种简便、灵敏的动力学分光光度法测定原料药和制剂中盐酸非索非那定的含量。以碱性高锰酸钾为氧化剂,对非索非那定在室温下的氧化反应进行了动力学研究。用分光光度法测定了锰离子在610 nm处形成的吸光度的增加。采用初始速率法和固定时间法(15分钟)构建标定图。研究了该方法的所有反应条件。初始速率法和固定时间法的线性范围为2.5 ~ 50.0 μ mL−1,检出限为0.055 μ mL−1。该方法成功地用于制剂中非索非那定的含量测定;加样回收率为99.98 ~ 101.96%。所得结果与官方方法进行了统计比较,在准确度和精密度上均无显著差异。
{"title":"New Kinetic Spectrophotometric Method for Determination of Fexofenadine Hydrochloride in Pharmaceutical Formulations","authors":"S. Ashour, Mouhammed Khateeb","doi":"10.1155/2014/308087","DOIUrl":"https://doi.org/10.1155/2014/308087","url":null,"abstract":"A simple and sensitive kinetic spectrophotometric method was developed for the determination of fexofenadine hydrochloride in bulk and pharmaceutical preparations. The method is based on a kinetic investigation of the oxidation reaction of fexofenadine using alkaline potassium permanganate as an oxidizing agent at room temperature. The reaction is followed spectrophotometrically by measuring the increase of absorbance owing to the formation of manganate ion at 610 nm. The initial rate and fixed time (at 15 min) methods are utilized for construction of calibration graphs. All the reaction conditions for the proposed method have been studied. The linearity range was found to be 2.5–50.0 μg mL−1 with detection limit of 0.055 μg mL−1 for both initial rate and fixed time methods. The proposed method was applied successfully for the determination of fexofenadine in pharmaceutical formulations; the percentage recoveries were 99.98–101.96%. The results obtained were compared statistically with those obtained by the official method and showed no significant differences regarding accuracy and precision.","PeriodicalId":14329,"journal":{"name":"International Journal of Spectroscopy","volume":"42 1","pages":"1-8"},"PeriodicalIF":0.0,"publicationDate":"2014-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85550526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Binding of the Bi (III) Complex of Naringin with β-Cyclodextrin/Calf Thymus DNA: Absorption and Fluorescence Characteristics 柚皮苷Bi (III)配合物与β-环糊精/小牛胸腺DNA的结合:吸收和荧光特性
Pub Date : 2014-06-05 DOI: 10.1155/2014/562160
Sameena Yousuf, I. V. Enoch
Naringin-Bi (III) complex (Narb) was prepared and analysed by UV-Visible absorption and fluorescence measurements. The inclusion complex of Narb with β-Cyclodextrin (β-CD) was characterized by the UV-Visible absorption, Infrared, scanning dlectron microscopic, and X-ray diffractometric techniques. The stoichiometry of the inclusion complex of Narb with β-CD was 1 : 1 with a binding constant of 5.18 × 102 mol−1 dm3. The interaction of Narb with Calf Thymus DNA (ctDNA) was investigated in the presence and the absence of β-CD. The binding constants for the interaction of Narb with ctDNA in the absence and the presence of β-CD were 1.29 × 105 mol−1 dm3 and 6.89 × 104 mol−1 dm3, respectively. The Stern-Volmer constants for the interaction of Narb with ctDNA in the absence and the presence of β-CD were 1.25 × 104 mol−1 dm3 and 5.10 × 103 mol−1 dm3, respectively. The lowering of the binding affinity and the were observed for the interaction of Narb with ctDNA in the presence of β-CD.
制备了柚皮苷-碧(III)配合物(Narb),并对其进行了紫外可见吸收和荧光分析。通过紫外可见吸收、红外、扫描电镜和x射线衍射等技术对Narb与β-环糊精(β-CD)的包合物进行了表征。Narb与β-CD包合物的化学计量比为1:1,结合常数为5.18 × 102 mol−1 dm3。在存在和不存在β-CD的情况下,研究了Narb与小牛胸腺DNA (ctDNA)的相互作用。在β-CD不存在和β-CD存在的情况下,Narb与ctDNA的结合常数分别为1.29 × 105 mol−1 dm3和6.89 × 104 mol−1 dm3。在β-CD不存在和β-CD存在的情况下,Narb与ctDNA相互作用的Stern-Volmer常数分别为1.25 × 104 mol−1 dm3和5.10 × 103 mol−1 dm3。在β-CD存在的情况下,Narb与ctDNA相互作用的结合亲和力降低。
{"title":"Binding of the Bi (III) Complex of Naringin with β-Cyclodextrin/Calf Thymus DNA: Absorption and Fluorescence Characteristics","authors":"Sameena Yousuf, I. V. Enoch","doi":"10.1155/2014/562160","DOIUrl":"https://doi.org/10.1155/2014/562160","url":null,"abstract":"Naringin-Bi (III) complex (Narb) was prepared and analysed by UV-Visible absorption and fluorescence measurements. The inclusion complex of Narb with β-Cyclodextrin (β-CD) was characterized by the UV-Visible absorption, Infrared, scanning dlectron microscopic, and X-ray diffractometric techniques. The stoichiometry of the inclusion complex of Narb with β-CD was 1 : 1 with a binding constant of 5.18 × 102 mol−1 dm3. The interaction of Narb with Calf Thymus DNA (ctDNA) was investigated in the presence and the absence of β-CD. The binding constants for the interaction of Narb with ctDNA in the absence and the presence of β-CD were 1.29 × 105 mol−1 dm3 and 6.89 × 104 mol−1 dm3, respectively. The Stern-Volmer constants for the interaction of Narb with ctDNA in the absence and the presence of β-CD were 1.25 × 104 mol−1 dm3 and 5.10 × 103 mol−1 dm3, respectively. The lowering of the binding affinity and the were observed for the interaction of Narb with ctDNA in the presence of β-CD.","PeriodicalId":14329,"journal":{"name":"International Journal of Spectroscopy","volume":"48 1","pages":"1-8"},"PeriodicalIF":0.0,"publicationDate":"2014-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79163582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Understanding and Control of High Temperature Oxidation Flaws of Low-Density Poly(ethylene) with Raman Spectroscopy 拉曼光谱对低密度聚乙烯高温氧化缺陷的认识与控制
Pub Date : 2014-06-05 DOI: 10.1155/2014/194563
M. Veitmann, R. Jumeau, P. Bourson, M. Ferriol, F. Lahure
Studies of high temperature oxidation of polyethylene are not much present in the literature though it can really be a problem especially in polymer production and processing. This study aims to detect oxidation flaws in polyethylene and to determine their impact on polymer structure and properties. Besides, we suggest a method via PLS-regression to determine the degree of flaws that can occur during polymer processing due to oxidation. Several kinds of oxidation flaws were reproduced in laboratory at 150°C in an oven operating in air and Raman spectroscopy analysis was performed on each sample. Using statistical tools as chemometrics on these spectra, we have built a Partial Least Square (PLS) model able to predict the oxidation degree of flaws. Interpretation of the model construction and further characterization tests show that oxidation can be followed with the evolution of the crystalline carbon group and of the created carbonyl functions. Finally we suggest possible mechanisms which can explain the high temperature oxidation process in LPDE, and we link them to the modification of the material properties.
聚乙烯高温氧化的研究在文献中并不多见,但它确实是一个问题,特别是在聚合物生产和加工中。本研究旨在检测聚乙烯中的氧化缺陷,并确定其对聚合物结构和性能的影响。此外,我们提出了一种通过pls回归的方法来确定由于氧化而在聚合物加工过程中可能发生的缺陷程度。在150°C的实验室空气烘箱中再现了几种氧化缺陷,并对每种样品进行了拉曼光谱分析。利用统计工具作为这些光谱的化学计量学,我们建立了一个能够预测缺陷氧化程度的偏最小二乘(PLS)模型。对模型构建的解释和进一步的表征测试表明,氧化可以随着结晶碳基团和生成的羰基功能的演化而发生。最后,我们提出了解释LPDE高温氧化过程的可能机制,并将其与材料性能的改变联系起来。
{"title":"Understanding and Control of High Temperature Oxidation Flaws of Low-Density Poly(ethylene) with Raman Spectroscopy","authors":"M. Veitmann, R. Jumeau, P. Bourson, M. Ferriol, F. Lahure","doi":"10.1155/2014/194563","DOIUrl":"https://doi.org/10.1155/2014/194563","url":null,"abstract":"Studies of high temperature oxidation of polyethylene are not much present in the literature though it can really be a problem especially in polymer production and processing. This study aims to detect oxidation flaws in polyethylene and to determine their impact on polymer structure and properties. Besides, we suggest a method via PLS-regression to determine the degree of flaws that can occur during polymer processing due to oxidation. Several kinds of oxidation flaws were reproduced in laboratory at 150°C in an oven operating in air and Raman spectroscopy analysis was performed on each sample. Using statistical tools as chemometrics on these spectra, we have built a Partial Least Square (PLS) model able to predict the oxidation degree of flaws. Interpretation of the model construction and further characterization tests show that oxidation can be followed with the evolution of the crystalline carbon group and of the created carbonyl functions. Finally we suggest possible mechanisms which can explain the high temperature oxidation process in LPDE, and we link them to the modification of the material properties.","PeriodicalId":14329,"journal":{"name":"International Journal of Spectroscopy","volume":"51 1","pages":"1-9"},"PeriodicalIF":0.0,"publicationDate":"2014-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89467569","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
期刊
International Journal of Spectroscopy
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1