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AUTHOR INDEX VOLUME 31 (2023) 作者索引》第 31 卷(2023 年)
Pub Date : 2023-12-01 DOI: 10.1142/s0129083523990012
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引用次数: 0
Elemental concentrations in green vegetables from the perspective of urolithiasis risk 从泌尿系统结石风险的角度看绿色蔬菜中的元素浓度
Pub Date : 2023-11-15 DOI: 10.1142/s0129083523500055
K. Sera, S. Goto, T. Hosokawa, Y. Saitoh, A. Terakawa, K. Ishii
Although green vegetables are valuable sources of essential elements, and are safe in that they lack harmful elements, they are high in oxalic acid, increasing the risk of urolithiasis. We performed elemental analyses on spinach (Spinacia oleracea L), Malabar nightshade (Basella alba), and water Morning Glory (Ipomoea aquatica), which contain large amounts of oxalic acid, and compared the data to those of Japanese mustard spinach (Brassica rapa var. perviridis), which is the second most commonly consumed green vegetable (after spinach) in Japan. We focused on concentrations of Ca, Mg, and Sr that suppress the formation of ureteral stones (calculi). The calcium concentration in spinach was [Formula: see text]g/g in leaves and [Formula: see text]g/g in stalks, and the level in Japanese mustard spinach were [Formula: see text]g/g in leaves and [Formula: see text]g/g in stalks. The overall Sr concentration in Japanese mustard spinach was thus 10-fold higher than in spinach, but the Mg concentration was lower than that in spinach. The concentrations of Ca and Sr in Malabar nightshade and water Morning Glory were 3- to 5-fold higher than in spinach. As the former vegetables are consumed much less often than spinach, the risk of urolithiasis is low. We explored how the concentrations of these elements changed after boiling.
虽然绿色蔬菜是人体必需元素的重要来源,而且因缺乏有害元素而安全,但它们却含有大量草酸,增加了罹患尿毒症的风险。我们对含有大量草酸的菠菜(Spinacia oleracea L)、马拉巴尔夜来香(Basella alba)和牵牛花(Ipomoea aquatica)进行了元素分析,并将数据与日本芥菜菠菜(Brassica rapa var.我们重点研究了能抑制输尿管结石(结石)形成的钙、镁和锶的浓度。菠菜叶中的钙浓度为[式中:见正文]克/克,茎中的钙浓度为[式中:见正文]克/克,日本芥菜菠菜叶中的钙浓度为[式中:见正文]克/克,茎中的钙浓度为[式中:见正文]克/克。因此,日本芥菜菠菜中的总体硒浓度是菠菜的 10 倍,但镁浓度低于菠菜。马拉巴尔夜来香和朝天椒中的钙和锶浓度比菠菜高 3 到 5 倍。由于前一种蔬菜的食用频率远低于菠菜,因此患尿路结石的风险较低。我们探讨了煮沸后这些元素浓度的变化情况。
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引用次数: 0
Elemental concentrations of seven types of green vegetables grown on small-scale farmlands in rural areas of Japan: Differences according to the type and place of production 日本农村地区小规模农田种植的七种绿色蔬菜的元素浓度:生产类型和生产地的差异
Pub Date : 2023-11-15 DOI: 10.1142/s0129083523500043
K. Sera, S. Goto, T. Hosokawa, Y. Saitoh, A. Terakawa, K. Ishii
We collected seven types of green vegetables produced in 11 areas of Japan and analyzed their elemental concentrations. Halogen analyses were performed with and without prior chemical treatment. The most popular type of spinach exhibited the highest concentrations of Mg, K, and Zn, and the lowest concentrations of alkaline earths (Ca and Sr) and halogens (Cl and Br). Japanese mustard spinach, the second most consumed type of spinach in Japan, exhibited the highest concentrations of P, S, Ca, Fe, and Br and adequate amounts of other essential elements. The other five green vegetables had unique elemental concentrations. In particular, radish had the highest concentrations of Ca, Na, and Cl and the lowest concentrations of Mg, P, Cu, and Zn. Leaves and stalks were separately analyzed. Fe, Cu, Zn, and Mn concentrations tended to be higher in leaves, and K, Na, and Rb concentrations were higher in stalks. Halogen (Cl and Br) concentrations in Japanese mustard spinach produced on farmland near the coast were remarkably high, suggesting an effect of sea salt. However, even in green vegetables produced near the coast, halogen uptake clearly differed by production area. The concentrations of Cl and Br in Japanese mustard spinach produced in two coastal areas were very high and were not removed by washing, but were mostly lost after boiling samples from Taneichi for 3[Formula: see text]min. In contrast, there was no difference in Na concentrations among vegetables produced in coastal and inland areas. The concentrations of essential elements such as Mg, Ca, and Fe were clearly higher in green vegetables from small- versus large-scale production areas, perhaps attributable to differences in the farming methods employed.
我们收集了日本 11 个地区生产的七种绿色蔬菜,并对其元素浓度进行了分析。卤素分析是在事先进行化学处理和未进行化学处理的情况下进行的。最受欢迎的菠菜中,镁、钾和锌的浓度最高,碱土(钙和锶)和卤素(氯和溴)的浓度最低。日本芥菜菠菜是日本消费量第二大的菠菜种类,其磷、硒、钙、铁和硼的含量最高,其他必需元素的含量也很充足。其他五种绿色蔬菜的元素浓度各不相同。其中,萝卜中 Ca、Na 和 Cl 的浓度最高,而 Mg、P、Cu 和 Zn 的浓度最低。叶片和茎秆分别进行了分析。叶片中的铁、铜、锌和锰浓度往往较高,而茎秆中的钾、纳和铷浓度较高。在靠近海岸的农田里生产的日本芥菜菠菜中,卤素(Cl 和 Br)的浓度明显较高,这表明受到了海盐的影响。不过,即使是在海岸附近生产的绿色蔬菜中,不同生产地区对卤素的吸收也明显不同。在两个沿海地区生产的日本芥菜菠菜中,Cl 和 Br 的浓度非常高,而且清洗后也无法去除,但在煮沸 3[公式:见正文]分钟后,来自金市的样本中的 Cl 和 Br 大部分都消失了。相比之下,沿海地区和内陆地区生产的蔬菜中 Na 的浓度没有差异。小规模生产地区的绿色蔬菜与大规模生产地区的绿色蔬菜相比,镁、钙和铁等必需元素的浓度明显较高,这可能与采用的耕作方法不同有关。
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引用次数: 0
Characterization analysis of particles emitted from aircraft using positive matrix factorization 用正矩阵分解法分析飞机发射粒子的特性
Pub Date : 2023-10-31 DOI: 10.1142/s0129083523500031
Katsumi Saitoh, Koyomi Nakazawa, Osamu Nagafuchi
In order to characterize particles emitted from aircraft, we analyzed the elemental composition information of particles collected from aircraft using positive matrix factorization (PMF). The factor profile and source contribution were deduced based on PMF analysis with five factors and 30 random starting points. Factor 1 contains particles derived from engine oil. Factor 2 contains particles originating from the friction between the runway surface and the tire. Factor 3 contains particles deposited on the runway surface, mainly composed of soil components. Factor 4 contains particles derived from the turbine blade. Factor 5 contains particles derived from plant combustion and particles scattered during landing. Engine reversers accounted for more than 85% of the element total value with factor 2, factor 4, and factor 5. The carbon disc brakes had different main factors depending on the sample. For the tire grooves, factor 2 and factor 3 accounted for the majority of the element total value. The PMF analysis revealed that the particles collected from aircraft contained elements with different modes of generation. In addition, it was found that particles derived from plant combustion, which are presumed to have little relevance to particles emitted from aircraft, were included in the particles collected from the engine reverser, carbon disc brakes, and tire grooves.
为了表征飞机发射的粒子,利用正矩阵分解(PMF)分析了飞机发射的粒子的元素组成信息。基于5个因子和30个随机起点的PMF分析,推导出因子分布和源贡献。因子1含有来自发动机油的颗粒。因子2包含来自跑道表面和轮胎之间摩擦的颗粒。因子3包含沉积在跑道表面的颗粒,主要由土壤成分组成。因子4包含来自涡轮叶片的颗粒。因子5含有植物燃烧产生的颗粒和着陆时散落的颗粒。发动机反转器在因子2、因子4、因子5中占元件总价值的85%以上。碳盘式制动器的主要因素因样品而异。对于轮胎沟槽,因子2和因子3占要素总价值的大部分。PMF分析显示,从飞机上收集的颗粒含有不同生成模式的元素。此外,研究还发现,从发动机逆转器、碳盘式制动器和轮胎凹槽收集的颗粒中包括来自植物燃烧的颗粒,这些颗粒被认为与飞机排放的颗粒无关。
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引用次数: 0
Effects of titanium fluoride on caries inhibition and elemental distribution in the tooth structure: Comparisons with sodium fluoride at the same fluoride concentration and pH values 氟化钛对龋抑制和元素在牙齿结构中的分布的影响:与氟化钠在相同氟浓度和pH值下的比较
Pub Date : 2023-10-31 DOI: 10.1142/s0129083523500018
K. Okuyama, K. Shintani, Y. Tamaki, Y. Matsuda, M. Sakurai, T. Saito, H. Yamamoto, K. Naito, H. Kanda, M. Hayashi, T. Satoh, N. Yamada, R. Yamagata, Y. Ishii
Titanium fluoride (TiF[Formula: see text] reduces mineral loss and lesion depth more effectively than sodium fluoride (NaF). However, the pH values of TiF 4 and NaF solutions are different. This study aimed to evaluate the effects of TiF 4 solution on the inhibition of demineralization and elemental distribution in root dentin in comparison with NaF solution at the same pH and fluoride concentrations. This study was conducted using 0.5% TiF 4 or 0.675% NaF solution adjusted to pH 5 or pH 7. Bovine dentin specimens of 200 [Formula: see text]m thickness were subjected to pH cycling (pH 4.5 and 7.0; 6 cycles/day; simulated oral conditions) for eight weeks to prepare artificial carious dentin. During this cycle, the specimens were soaked in each solution once a week for 5 min. The control group involved no fluoride application during the test period. After cycling, the demineralization depth was measured and the calcium, fluorine, and titanium distributions were analyzed and calculated using an in-air micro-proton-induced X-ray emission (PIXE)/proton-induced gamma emission (PIGE) system at TIARA. At pH 7, TiF 4 solution yielded a lower lesion depth than the NaF solution. The NaF solution at pH 7 showed lower fluorine concentration than that with the other fluoride solutions. Thus, TiF 4 is more effective in inhibiting demineralization than NaF in a solution adjusted to pH 7. Moreover, the presence of titanium may strengthen the tooth structure.
氟化钛(TiF[公式:见正文])比氟化钠(NaF)更有效地减少矿物质流失和损伤深度。然而,TiF 4和NaF溶液的pH值不同。本研究旨在评价TiF 4溶液与NaF溶液在相同pH和氟浓度下对牙根本质脱矿和元素分布的抑制作用。本研究使用0.5% TiF 4或0.675% NaF溶液调节至pH 5或pH 7。200 m厚度的牛牙本质标本进行pH循环(pH为4.5和7.0;6周期/天;模拟口腔状况)8周,准备人工龋齿。在此循环中,将标本在每种溶液中浸泡5分钟,每周一次。对照组在测试期间不使用氟化物。循环后,使用TIARA的空气中微质子诱导x射线发射(PIXE)/质子诱导伽马发射(PIGE)系统测量脱矿深度,分析和计算钙、氟和钛的分布。在pH为7时,TiF - 4溶液的损伤深度比NaF溶液小。pH为7时NaF溶液的氟浓度低于其他氟溶液。因此,在pH为7的溶液中,TiF 4比NaF更有效地抑制脱矿。此外,钛的存在可以加强牙齿的结构。
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引用次数: 0
Study on chemical forms of aluminum in tea leaves using micro-PIXE method 用微探针法研究茶叶中铝的化学形态
Pub Date : 2023-10-27 DOI: 10.1142/s012908352350002x
K. Yasuda, N. Yamada, R. Yamagata, Y. Ishii, N. Suzui, T. Satoh, N. Kawachi
Elemental analysis of the epidermis of tea leaves was performed using the micro-beam particle-induced X-ray emission (micro-PIXE) method. The ratios of the X-ray yields of silicon (Si), potassium (K), calcium (Ca), and manganese (Mn) to that of aluminum (Al) in the cell wall of epidermal cells of tea leaves were determined. The ratio of Si to Al X-ray yields agreed within a range of 11% in the four samples measured in this study. On the other hand, the ratio of the X-ray yields of K, Ca, and Mn to Al varied from 41% to 87%. This result suggests that Al forms compounds with Si in tea leaves.
采用微束粒子诱导x射线发射(micropixe)方法对茶叶表皮进行了元素分析。测定了茶叶表皮细胞细胞壁中硅(Si)、钾(K)、钙(Ca)、锰(Mn)与铝(Al)的x射线产率之比。在本研究中测量的四个样品中,硅与铝x射线产率的比例在11%的范围内一致。另一方面,K、Ca和Mn与Al的x射线产率之比从41%到87%不等。这一结果表明Al与Si在茶叶中形成化合物。
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引用次数: 0
Preface: Proceedings of the 36th Symposium on PIXE in Japan Nara, 26–27 November 2022 前言:2022年11月26日至27日在日本奈良举行的第36届pxie研讨会论文集
Pub Date : 2023-10-27 DOI: 10.1142/s0129083523020011
Kunikazu Ishii
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引用次数: 0
Long-term and season-specific changes in the concentrations of trace elements and sulfur in a human body over twelve years by means of quantitative analyses of beard samples collected every day — A case study 通过对每天收集的胡须样本进行定量分析,12年来人体微量元素和硫浓度的长期和季节特异性变化-个案研究
Pub Date : 2022-10-25 DOI: 10.1142/s0129083520500060
K. Sera, S. Goto, T. Hosokawa, Y. Saitoh, A. Terakawa, K. Ishii
In this paper, we measured more than 4200 beard samples collected from a single person every day over a 12-year period and analyzed them based on a standard-free method. It was found that the sulfur concentration remained almost constant from a long-term perspective but showed small periodic elevations. Silicone, phosphorus and rubidium showed significant periodic changes with a cycle of several years. While manganese, strontium and molybdenum seemed to show long-term changes, there were no significant differences due to their large standard deviations. Concerning seasonal changes, silicone and phosphorus showed decreasing trends in summer, albeit without significant differences. The bromine concentration showed clear seasonal variations, rising in winter and falling in summer, suggesting the possible influence of seasonal changes in the elemental components in the airborne particles that pass over to Japan from the Asian Continent. These findings confirmed that beard analyses are useful not only for evaluating changes in trace element concentrations in the human body but also for clarifying the main pathways of the intake of these elements.
在本文中,我们测量了在12年的时间里每天从一个人身上收集的4200多个胡须样本,并基于无标准方法对它们进行了分析。从长期的角度看,硫的浓度基本保持不变,但有小的周期性上升。硅酮、磷和铷表现出明显的周期性变化,周期为几年。虽然锰、锶和钼似乎表现出长期变化,但由于它们的标准偏差很大,没有显著差异。在季节变化方面,硅酮和磷在夏季呈下降趋势,但差异不显著。溴的浓度表现出明显的季节变化,冬季上升,夏季下降,这表明从亚洲大陆传入日本的空气颗粒中元素成分的季节变化可能产生了影响。这些发现证实,胡须分析不仅有助于评估人体微量元素浓度的变化,而且有助于阐明这些元素摄入的主要途径。
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引用次数: 0
Development of thallium bromide semiconductor detectors for particle-induced gamma-ray emission 用于粒子诱导伽马射线发射的溴化铊半导体探测器的研制
Pub Date : 2022-10-25 DOI: 10.1142/s0129083520500072
K. Hitomi, M. Nogami, A. Terakawa, K. Ishii
A thallium bromide (TlBr) gamma-ray detector was developed for particle-induced gamma-ray emission (PIGE) applications. The PIGE spectrum of a lithium fluoride (LiF) crystal was obtained for the first time using the TlBr detector. This detector was fabricated using a zone-purified crystal with dimensions of approximately [Formula: see text]. An energy resolution of 2.3% full-width at half maximum for 511 keV gamma rays was obtained from the detector at room temperature. The LiF crystal target was irradiated with a 20 MeV proton beam at the Aomori Prefecture Quantum Science Center. Full-energy peaks of 478 keV and 197 keV were successfully detected from lithium and fluorine, respectively, using the TlBr detector in the PIGE experiment.
研制了一种用于粒子诱导伽玛射线发射(PIGE)的溴化铊(TlBr)伽玛射线探测器。利用TlBr探测器首次获得了氟化锂晶体的PIGE光谱。该探测器是用区域纯化晶体制造的,其尺寸约为[公式:见文本]。在室温下,探测器对511 keV伽马射线的能量分辨率为2.3%。在青森县量子科学中心用20 MeV质子束照射liff晶体目标。在PIGE实验中,利用TlBr探测器成功地从锂和氟中分别探测到478 keV和197 keV的全能峰。
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引用次数: 0
Analysis of soil aggregates contaminated by 137Cs via particle size classification and X-ray diffraction 137Cs污染土壤团聚体的粒径分级和x射线衍射分析
Pub Date : 2022-10-25 DOI: 10.1142/s0129083520500084
H. Arai, K. Ishii
We subjected [Formula: see text]Cs-contaminated soil to stirring and particle classification to reduce the contaminated soil volume. [Formula: see text]Cs activity as a function of particle diameter changed drastically as the weight ratio of soil/water varied; 85% of all [Formula: see text]Cs was adsorbed to particles of minimum diameter after stirring. Soil argillites (smectites, vermiculites, and illites) adsorbed [Formula: see text]Cs. We used X-ray diffraction (XRD) analysis to measure the soil contents; the [Formula: see text]Cs distribution as a function of soil particle diameter mirrored the smectite levels revealed by the XRD peak intensities. Thus, smectic was the main absorbent of [Formula: see text]Cs.
我们对[公式:见文]cs污染土壤进行搅拌和颗粒分类,以减小污染土壤体积。[公式:见文]随着土/水重量比的变化,Cs活性随粒径的函数变化剧烈;85%的[公式:见文]Cs在搅拌后被吸附到最小直径的颗粒上。土壤粘土(蒙脱石、蛭石和伊利石)被吸附[公式:见原文]。采用x射线衍射(XRD)分析测定土壤含量;[公式:见文]Cs随土壤粒径的分布反映了XRD峰强度所揭示的蒙脱石水平。因此,smectic是[公式:见文]Cs的主要吸收剂。
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引用次数: 0
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International Journal of PIXE
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