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Design and manufacture of an additive manufacturing printer based on 3D melt electrospinning writing of polymer 基于聚合物三维熔融静电纺丝书写的增材制造打印机的设计与制造
IF 1.3 4区 工程技术 Q3 Engineering Pub Date : 2023-05-10 DOI: 10.1515/ipp-2023-4352
B. Akhoundi, V. Modanloo, A. Mashayekhi
Abstract Objectives Electrospinning is one of the most well-known approaches to producing polymer nanofibers from a polymer solution by applying a potential difference (voltage) between the spinner and the collector, which is used in various industries such as medicine and military. This method has some significant restrictions, like low process efficiency due to the evaporation of the solvent, remaining solvent on the fibers, which are sometimes toxic, and inability to control the geometry of the produced fibers. On the other hand, preparing some solvents used in the electrospinning of polymer solutions is costly. Polymer melt electrospinning writing is a replacement for this type of electrospinning, which can be mentioned in terms of economy, efficiency, and production of solvent-free fibers. Therefore, in this research, a melt polymer electrospinning device was designed and manufactured according to existing extrusion-based additive manufacturing (AM) devices (3D printer). Methods Changes in an extrusion-based 3D printer to convert it into a writing electrospinning device experimentally. Results PLA and PCL fibers with diameters ranging from 8 to 84 μm were produced. The effect of process variables on the produced fibers’ diameter was investigated: Applied potential difference between the nozzle and the substrate: As its increases, the fiber diameter decreases. Increasing temperature: As its increases, the fiber diameter decreases. Distance between the nozzle and the substrate: As its increases, the fiber diameter increases. Flow rate: As its increases, the fiber diameter increases. Conclusions By presenting a 3D printer-electrospinning device, it is possible to control the fiber’s diameter and the 3D geometry in the 3D printing-electrospinning process.
摘要目的静电纺丝是利用纺丝器和集电极之间的电位差(电压)从聚合物溶液中制备聚合物纳米纤维的一种最著名的方法,它被广泛应用于医学和军事等各个行业。这种方法有一些明显的限制,如由于溶剂蒸发导致的工艺效率低,纤维上残留的溶剂有时是有毒的,并且无法控制所生产纤维的几何形状。另一方面,制备一些用于聚合物溶液静电纺丝的溶剂是昂贵的。聚合物熔体静电纺丝书写是这种类型的静电纺丝的替代品,在经济、效率和生产无溶剂纤维方面都可以提到。因此,本研究在现有的基于挤压的增材制造(AM)设备(3D打印机)的基础上,设计并制造了熔融聚合物静电纺丝装置。方法对挤压式3D打印机进行改造,将其转化为书写式静电纺丝装置。结果制备出直径为8 ~ 84 μm的PLA和PCL纤维。研究了工艺变量对纤维直径的影响:喷嘴与基体之间的外加电位差:随着电位差的增大,纤维直径减小。温度升高:随着温度的升高,纤维直径减小。喷嘴与基材之间的距离:随着距离的增加,纤维直径也随之增加。流量:随着流量的增大,纤维直径增大。结论通过3D打印-静电纺丝装置,实现了3D打印-静电纺丝过程中纤维直径和三维几何形状的控制。
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引用次数: 1
The effect of extensional viscosity on the core structure of fiber orientation for injection-molded fiber composites 拉伸粘度对注射成型纤维复合材料纤维取向核心结构的影响
IF 1.3 4区 工程技术 Q3 Engineering Pub Date : 2023-05-09 DOI: 10.1515/ipp-2023-4368
H. Tseng
Abstract The famous informed isotropic (IISO) viscosity successfully dominates the broader core structure of fiber orientation distributions for injection-molded long fiber composites, due to the flow-fiber coupling effect of stretching deformation. Recently, the GNF-X (Generalized Newtonian Fluid eXtended) constitutive equation of weighted shear/extensional viscosity has been shown to possess the potential to demonstrate the extension-induced corner vortex in the entry flow of a polymer melt. Using GNF-X, three-dimensional injection-molding flow simulations of a center-gated disk are, therefore, performed for verifying the effect of extensional viscosity on the core structure of fiber orientation, namely, the extension-induced fiber orientation. The equivalent of GNF-X and IISO is demonstrated for predicting fiber orientation distribution, while their primary parameter relationship is particularly found herein. It is significant to visualize dramatic patterns of extensional rate occurring in the center-gated disk simulation.
摘要:由于拉伸变形的流-纤维耦合效应,著名的通知各向同性(IISO)粘度成功地主导了注射成型长纤维复合材料纤维取向分布的更广泛的芯结构。最近,GNF-X(广义牛顿流体扩展)加权剪切/拉伸黏度本构方程被证明具有表征聚合物熔体入口流动中拉伸引起的角涡的潜力。因此,利用GNF-X对中心门控圆盘进行了三维注射成型流动模拟,以验证拉伸粘度对纤维取向的芯结构,即拉伸诱导纤维取向的影响。证明了GNF-X和IISO的等效性,用于预测纤维取向分布,而它们的主要参数关系在这里特别发现。在中心门控盘的模拟中,可视化的伸展速率的戏剧性模式是有意义的。
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引用次数: 0
Modelling of roller conveyor for the simulation of rubber tire tread extrusion 对滚筒输送机进行建模,用于橡胶轮胎胎面挤压过程的仿真
IF 1.3 4区 工程技术 Q3 Engineering Pub Date : 2023-05-09 DOI: 10.1515/ipp-2023-4356
B. Debbaut
Abstract The extrusion of large or heavy technical rubber profiles is usually assisted by a conveying device. Such a device can be a conveyor belt or a series of rollers, and its use is necessary mainly for being able to achieve the process. Within the context of numerical simulation of extrusion flows, a conveying device brings additional downstream constraints to the flow governing equations. In the present paper, we propose a simple engineering approach for modelling a roller conveyor used in rubber tire tread extrusion, and we apply it to the extrusion simulation of a flat tire tread profile as typically encountered in the tire manufacturing industry.
大型或重型工业橡胶型材的挤压通常由输送装置辅助。这种装置可以是一条传送带,也可以是一系列滚筒,它的使用主要是为了能够实现所需要的工艺。在挤压流动数值模拟的背景下,输送装置给流动控制方程带来了额外的下游约束。在本文中,我们提出了一种简单的工程方法来建模用于橡胶轮胎胎面挤压的滚筒输送机,并将其应用于轮胎制造业中典型遇到的扁平轮胎胎面轮廓的挤压模拟。
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引用次数: 0
Reactive compatibilization of polypropylene grafted with maleic anhydride and styrene, prepared by a mechanochemical method, for a blend system of biodegradable poly(propylene carbonate)/polypropylene spunbond nonwoven slice 机械化学法制备的马来酸酐和苯乙烯接枝聚丙烯对可生物降解的聚碳酸亚丙酯/聚丙烯纺粘非织造切片共混体系的反应增容
IF 1.3 4区 工程技术 Q3 Engineering Pub Date : 2023-05-03 DOI: 10.1515/ipp-2023-4345
Zheng Tian, Yilu Zhang, N. Xu, Lisha Pan, Yuhong Feng
Abstract Poly(propylene carbonate) (PPC)/polypropylene (PP) spunbond nonwoven slice has gained more attention, owing to its excellent properties, such as biodegradability, flexibility, biocompatibility, and CO2 utilization. However, the applications of this green material are limited due to the poor thermodynamic incompatibility between PPC and PP. In this paper, PP grafted with maleic anhydride (MAH) and styrene (St) (PP-g-(MAH-co-St)), prepared by a mechanochemical method and having a grafting percentage GMAH = 1.40 %, was used as a compatibilizer to prepare a biodegradable PPC/compatibilizer/PP composite-spunbond nonwoven slice by melt-blending. The effects of compatibilizer content on the tensile strength, elongation at break, melt flow rate, thermal properties, and micro-morphology of PPC/PP-g-(MAH-co-St)/PP were systematically studied. Furthermore, the mechanism of compatibilization of PP-g-(MAH-co-St) in the PPC/PP spunbond nonwoven composite slice is discussed. The results indicated that this green PP-g-(MAH-co-St) exhibited a clear reactive compatibilization effect. Therefore, it can be considered as a good compatibilizer for the biodegradable PPC/PP spunbond nonwoven slice.
摘要聚碳酸亚丙酯(PPC)/聚丙烯(PP)纺粘非织造布切片因其优异的生物降解性、柔韧性、生物相容性和CO2利用率等性能而备受关注。然而,由于PPC和PP之间的热力学不相容性较差,这种绿色材料的应用受到限制。本文采用机械化学方法制备了马来酸酐(MAH)和苯乙烯(St)接枝的PP(PP-g-(MAH-co-St)),接枝率GMAH=1.40 %, 作为相容剂,通过熔融共混制备了可生物降解的PPC/相容剂/PP复合纺粘非织造切片。系统研究了相容剂含量对PPC/PP-g-(MAH-co-St)/PP的拉伸强度、断裂伸长率、熔体流动速率、热性能和微观形态的影响。探讨了PP-g-(MAH-co-St)在PPC/PP纺粘非织造布复合切片中的增容机理。结果表明,该绿色PP-g-(MAH-co-St)具有明显的反应增容作用。因此,它可以被认为是可生物降解的PPC/PP纺粘非织造切片的良好相容剂。
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引用次数: 0
Numerical analysis of a new mound-shaped extensional mixing element designed based on a sine curve in single-screw extrusion 单螺杆挤压中基于正弦曲线设计的新型土墩型拉伸混合单元的数值分析
IF 1.3 4区 工程技术 Q3 Engineering Pub Date : 2023-05-03 DOI: 10.1515/ipp-2022-4319
Hezhi He, Weijie Li, Zong‐ji Huang, Guidong Tian, Z. Zhu
Abstract The rapid development of polymer blends and nanocomposites has put forward new requirements for the mixing performance of extruders. In comparison with shear flow field, extensional flow field has been shown to have unique advantages in improving dispersive mixing performance and reducing energy consumption. However, building an extensional flow field in a conventional single-screw extruder remains challenging. In this work, a new mound-shaped extensional mixing element (M-EME) was designed based on the geometric characteristics of a sine curve. To investigate the effect of this M-EME on the mixing properties of a conventional single-screw extruder, a numerical simulation analysis of this M-EME was performed. The results showed that the proportion of the region with a mixing index greater than 0.55 in the M-EME was higher than 43 %, and that the highest mixing index of the M-EME reached around 0.9, confirming the dominance of the extensional flow field in the M-EME. Moreover, it was observed that the changes in amplitude and period of the sine function have no significant effect on the distribution of the mixing index. The findings from this work provide a viable way to generate extensional flow fields in conventional screw extruders.
高分子共混物和纳米复合材料的快速发展对挤出机的混炼性能提出了新的要求。与剪切流场相比,伸展流场在提高分散混合性能和降低能耗方面具有独特的优势。然而,在传统的单螺杆挤出机中建立拉伸流场仍然具有挑战性。本文根据正弦曲线的几何特性,设计了一种新型的土墩型外延混合单元。为了研究M-EME对常规单螺杆挤出机混合性能的影响,对M-EME进行了数值模拟分析。结果表明:M-EME中混合指数大于0.55的区域比例大于43 %,M-EME的最高混合指数达到0.9左右,证实了伸展流场在M-EME中占主导地位。此外,观察到正弦函数振幅和周期的变化对混合指数的分布没有显著影响。本文的研究结果为在常规螺杆挤出机中产生拉伸流场提供了一条可行的途径。
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引用次数: 0
Numerical investigation of pressure drop within isothermal capillary rheometry for viscous and viscoelastic fluids 粘性和粘弹性流体等温毛细管流变法压降的数值研究
IF 1.3 4区 工程技术 Q3 Engineering Pub Date : 2023-05-03 DOI: 10.1515/ipp-2022-4322
H. Tseng
Abstract In capillary rheometry of a polymer melt, the total pressure drop consists of three primary components: shear viscosity, extensional viscosity, and normal stress differences. Traditionally, viscoelastic constitutive equations have been used to produce accurate predictions regarding the pressure drop. It is difficult to investigate the primary components in past experimental measurements and numerical computations. The useful improvement of the classic White-Metzner viscoelastic constitutive equation coupled with the weighted shear/extension viscosity is performed in isothermal capillary flow simulations. It is significant to analyze the extension-induced pressure drop for a short die and the shear-induced pressure drop for a long die, along with a small contribution of normal stress differences.
在聚合物熔体的毛细管流变测量中,总压降由三个主要组成部分组成:剪切粘度、拉伸粘度和正应力差。传统上,粘弹性本构方程被用来对压降进行准确的预测。在过去的实验测量和数值计算中,很难对主要成分进行研究。在等温毛细管流动模拟中,对经典的White-Metzner粘弹性本构方程进行了有用的改进,并结合了加权剪切/拉伸黏度。分析短模拉伸引起的压降和长模剪切引起的压降具有重要意义,且正应力差的贡献很小。
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引用次数: 0
Frontmatter 头版头条
4区 工程技术 Q3 Engineering Pub Date : 2023-05-01 DOI: 10.1515/ipp-2023-frontmatter2
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引用次数: 0
Experimental investigation on mechanical and tribological characteristics of snake grass/sisal fiber reinforced hybrid composites 蛇草/剑麻纤维增强混杂复合材料力学与摩擦学特性试验研究
IF 1.3 4区 工程技术 Q3 Engineering Pub Date : 2023-04-18 DOI: 10.1515/ipp-2022-4301
S. Rajamanickam, Natarajan Ponnusamy, M. Mohanraj, Arockia Julias Arulraj
Abstract An experiential research on mechanical and tribological characteristics of snake grass and sisal fiber reinforced hybrid polymer (epoxy) composites was carried out and reported in this article. The snake grass and sisal fibers were initially treated with 5% sodium hydroxide (NaOH). Hybrid composite samples were fabricated using a compression moulding technique with a total fiber weight ratio of 30% and an epoxy resin weight ratio of 70%. The proportions of snake grass and sisal fibers in the hybrid composites were 70:30, 50:50, and 30:70. The fabricated hybrid composite samples were subjected to flexural, tensile, interlaminar shear strength, Shore D hardness, water absorption, and wear tests as per ASTM international standards, and the outcomes were compared with the results of snake grass and sisal mono fiber composites. The results disclosed that the 30:70 (SG:S) hybrid composite has higher mechanical characteristics than those of other hybrid and mono fiber composites. Also, the 30:70 hybrid sample performed at par with the sisal mono composite in wear and water absorption characteristics. Optical microscopy examination of alkali-treated natural hybrid and mono fiber composites displayed excellent results in terms of interfacial bonding between polymer and fiber.
摘要本文对蛇草和剑麻纤维增强混杂聚合物(环氧)复合材料的力学和摩擦学特性进行了实验研究。用5%氢氧化钠(NaOH)对蛇草和剑麻纤维进行初步处理。采用压缩成型技术制备了总纤维重量比为30%、环氧树脂重量比为70%的复合材料样品。混杂复合材料中蛇草纤维和剑麻纤维的比例分别为70:30、50:50和30:70。按照ASTM国际标准对制备的混杂复合材料试样进行了抗弯、拉伸、层间剪切强度、邵氏硬度、吸水率和磨损试验,并与蛇草和剑麻单纤维复合材料的试验结果进行了比较。结果表明:30:70 (SG:S)混杂复合材料的力学性能优于其他混杂复合材料和单纤维复合材料。此外,30:70混合样品在磨损和吸水特性方面与剑麻单复合材料相当。用光学显微镜检查碱处理的天然杂化和单纤维复合材料在聚合物和纤维之间的界面结合方面显示出优异的结果。
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引用次数: 0
Non-isothermal simulation of a corner vortex within entry flow for a viscoelastic fluid 粘弹性流体入口流内角涡的非等温模拟
IF 1.3 4区 工程技术 Q3 Engineering Pub Date : 2023-04-18 DOI: 10.1515/ipp-2022-4312
H. Tseng
Abstract A modified White-Metzner viscoelastic constitutive equation is incorporated into the state-of-the-art Three Dimensional Computational Fluid Dynamics (3D-CFD) framework for performing isothermal and non-isothermal entry flow simulations of a polymer melt. As a result, the corner vortex becomes smaller with increased isothermal temperature, namely, the so-called temperature-induced vortex reduction. In addition, the vortex grows with raising wall temperatures, whereas the vortex reduction is found under high inlet temperatures. Through the visualized flow patterns, it is significant to investigate the dramatic variations of vortex size in relation to fluid temperature, weighted viscosity and extension rate, as well as Weissenberg number and Trouton ratio.
摘要将一个改进的White-Metzner粘弹性本构方程纳入最先进的三维计算流体动力学(3D-CFD)框架中,用于对聚合物熔体进行等温和非等温入口流模拟。结果,角涡随着等温温度的升高而变小,即所谓的温度诱导涡减少。此外,涡流随着壁温的升高而增大,而在高入口温度下涡流减小。通过可视化的流型,研究涡流大小与流体温度、加权粘度和拉伸速率以及Weissenberg数和Trouton比的显著变化具有重要意义。
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引用次数: 1
Time series data for process monitoring in injection molding: a quantitative study of the benefits of a high sampling rate 注塑过程监控的时间序列数据:高采样率效益的定量研究
IF 1.3 4区 工程技术 Q3 Engineering Pub Date : 2023-04-14 DOI: 10.1515/ipp-2022-4258
Lucas Bogedale, Alexander Schrodt, H. Heim
Abstract Process monitoring systems are playing an increasingly important role in reducing production capacity losses in injection molding. Process monitoring and optimization systems are mostly based on processing data of injection molding machine control systems. These data consist of scalar data and time series. This paper introduces a novel approach to modelling injection molding processes using only time series data and evaluates the quantitative influences of varying sampling times on calculation of integral values and model quality. On the basis of the first experiment, it is shown that the sampling rates of these time series have a large influence on information which can be derived from this data (e.g. injection work). These findings provide an assessment of whether the effort is justified for the respective requirements on the accuracy of the injection work and other parameters derived from the time series. In the second experiment, a model is presented which uses only the injection flow and injection pressure profile as input and achieves high coefficients of determination for the prediction of the part weight, despite the absence of mold sensor data and scalar data. It is shown that higher sampling rates of time series results in higher prediction quality of these models. This improves the understanding of the data needed for high quality machine learning models of injection molding processes and enable users to estimate a lower bound for the sample rates of time series for their use cases.
摘要过程监控系统在减少注塑生产能力损失方面发挥着越来越重要的作用。工艺监控和优化系统大多基于注塑机控制系统的工艺数据。这些数据由标量数据和时间序列组成。本文介绍了一种仅使用时间序列数据对注塑过程建模的新方法,并评估了不同采样时间对积分值计算和模型质量的定量影响。在第一个实验的基础上,研究表明,这些时间序列的采样率对可以从这些数据中得出的信息(例如,注入功)有很大影响。这些发现提供了一个评估,即对于注射工作的准确性和从时间序列得出的其他参数的相应要求,该努力是否合理。在第二个实验中,提出了一个模型,该模型仅使用注射流量和注射压力轮廓作为输入,并且在没有模具传感器数据和标量数据的情况下,实现了用于预测零件重量的高确定系数。结果表明,时间序列的采样率越高,这些模型的预测质量就越高。这提高了对注塑工艺的高质量机器学习模型所需数据的理解,并使用户能够估计其用例的时间序列采样率的下限。
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引用次数: 0
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International Polymer Processing
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