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Study on the thermal stability and smoke suppressant effect of polyurethane foam modified by ammonium lignosulfonate 木质素磺酸铵改性聚氨酯泡沫的热稳定性及抑烟效果研究
IF 1.3 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-08-18 DOI: 10.1515/ipp-2023-4378
Xu Zhang, Dehe Yuan, Simiao Sun, Zhi Wang, Hua Xie, Zhanpeng Su
Abstract The modified polyurethane foam (PUF) with ammonium lignosulfonate was prepared by one-step water foaming method. The effects of ammonium lignosulfonate on its thermal stability and smoke suppression were investigated by thermogravimetric analysis, pyrolysis kinetics analysis, smoke density (Ds) and smoke toxicity analysis. The results showed that the addition of 15 % ammonium lignosulfonate (PUFA15) had the lowest mass loss of PUFs and the highest integral programmed decomposition temperature (870.8 °C). Its activation energy was the highest according to the Flynn-Wall-Ozawa method (110.1 kJ/mol), Kissinger method (181.1 kJ/mol), Starnk method (106.3 kJ/mol) and Coats-Redfern method (149.7 kJ/mol). In addition, PUFA15 had the lowest Ds (34.43) and the highest transmittance (66.74). This indicated that PUFA15 had good thermal stability and smoke suppression properties. The research results had a reference value for exploring the production of environmentally friendly PUF by biomass modification.
摘要采用一步水发泡法制备了木质素磺酸铵改性聚氨酯泡沫。通过热重分析、热解动力学分析、烟气密度(Ds)和烟气毒性分析,研究了木质素磺酸铵对其热稳定性和抑烟性能的影响。结果表明,添加15 % 木质素磺酸铵(PUFA15)具有最低的PUFs质量损失和最高的积分程序分解温度(870.8 °C)。根据Flynn Wall Ozawa方法,其活化能最高(110.1 kJ/mol),Kissinger法(181.1 kJ/mol),Starnk法(106.3 kJ/mol)和Coats-Redfern法(149.7 kJ/mol)。此外,PUFA15的Ds最低(34.43),透射率最高(66.74)。这表明PUFA15具有良好的热稳定性和抑烟性能。研究结果对探索生物质改性生产环保PUF具有参考价值。
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引用次数: 1
Chicken feather protein for the thermal stability and combustion performance of rigid polyurethane foam 鸡毛蛋白对硬质聚氨酯泡沫塑料热稳定性和燃烧性能的影响
IF 1.3 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-07-18 DOI: 10.1515/ipp-2023-4364
Xu Zhang, Simiao Sun, Dehe Yuan, Zhi Wang, Hua Xie, Zhanpeng Su
Abstract Rigid polyurethane foams (RPUFs) were synthesized with chicken feather protein using the “one-step method” of all-water foaming. Thermogravimetry, pyrolysis kinetics analysis, Cone calorimetry and smoke density (Ds) were used to investigate the effects of chicken feather protein on thermal stability and combustion performance of RPUFs. The results showed that the modified RPUFs with 2.5 wt% chicken feather protein (RPUF-CF1) had the lowest mass loss, the highest integrated program pyrolysis temperature, the highest activation energy, the lowest Ds (13.3), the highest light transmittance (79.3 %), the lowest heat release rate (22.0 kW/m2 and 30.6 kW/m2) and total heat release (2.4 MJ/m2 and 2.8 MJ/m2), which indicated that RPUF-CF1 had better thermal stability and combustion performance. The current research results provide a useful reference for the preparation of RPUFs with good thermal stability by bio-based modification.
摘要以鸡毛蛋白为原料,采用全水发泡的“一步法”合成了硬质聚氨酯泡沫塑料。采用热重法、热解动力学分析、锥形量热法和烟密度法研究了鸡毛蛋白对RPUFs热稳定性和燃烧性能的影响。结果表明,用2.5 wt%鸡毛蛋白(RPUF-CF1)具有最低的质量损失、最高的综合程序热解温度、最高的活化能、最低的Ds(13.3)、最高的透光率(79.3 %), 最低放热率(22.0 kW/m2和30.6 kW/m2)和总热量释放(2.4 MJ/m2和2.8 MJ/m2),表明RPUF-CF1具有较好的热稳定性和燃烧性能。目前的研究结果为通过生物基改性制备具有良好热稳定性的RPUFs提供了有益的参考。
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引用次数: 1
Polyvinylidene fluoride/maghnite nanocomposites: fabrication and study of structural, thermal and mechanical properties 聚偏氟乙烯/磁铁矿纳米复合材料:结构、热性能和机械性能的制备和研究
IF 1.3 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-07-11 DOI: 10.1515/ipp-2022-4302
Zoulikha Khiati, L. Mrah
Abstract An in-depth study of polyvinylidene fluoride (PVDF) based nanocomposite systems will be the focus of this research. This polymer being hydrophobic and apolar, it will be unlikely to generate strong interactions with clay leaves called organophilic maghnite. The challenge of this study will therefore be to manage the load/polymer interfaces by using montmorillonite with specific surface treatments by adding a surfactant Cetyltrimethylammonium bromide. Therefore, a significant improvement in mechanical and thermal properties was observed. The properties of PVDFNC nanocomposites were evaluated using various physico-chemical techniques (XRD, FTIR, TGA, DSC, TEM, SEM). The results of the structural and thermal measurements carried out on these products reveal that the structural concept of the surfactant influences both the morphological profile, the thermal and mechanical properties of the nanocomposites obtained. Accelerated crystallization is observed in PVDNC nanocomposites as an effective nucleation agent, the crystals formed are predominantly β shaped and have a small number of polar α crystals. Measurements by X-ray diffraction, as well as transmission and scanning electron microscopy indicated that modified maghnite was perfectly distributed 3 % by weight in the polyvinylidene fluoride matrix. The mechanical properties of the nanocomposites were evaluated according to the filler material used and the polyvinylidene fluoride matrix.
摘要对聚偏氟乙烯(PVDF)基纳米复合材料体系的深入研究将是本研究的重点。这种聚合物具有疏水性和非极性,不太可能与被称为亲有机镁石的粘土叶产生强烈的相互作用。因此,本研究的挑战将是通过使用蒙脱石来管理负载/聚合物界面,通过添加表面活性剂十六烷基三甲基溴化铵进行特定的表面处理。因此,观察到机械和热性能的显著改善。采用XRD、FTIR、TGA、DSC、TEM、SEM等物理化学方法对PVDFNC纳米复合材料的性能进行了评价。对这些产品进行的结构和热测量结果表明,表面活性剂的结构概念影响所获得的纳米复合材料的形态、热性能和机械性能。在PVDNC纳米复合材料中观察到加速结晶作为一种有效的成核剂,形成的晶体主要是β形的,并具有少量极性α晶体。通过X射线衍射、透射和扫描电子显微镜的测量表明,改性的镁石分布完美。3 % 在聚偏二氟乙烯基质中按重量计。根据所用的填料和聚偏二氟乙烯基体对纳米复合材料的力学性能进行了评价。
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引用次数: 0
Free vibration behaviour and some mechanical properties of micro particle reinforced epoxy composites 微粒增强环氧树脂复合材料的自由振动行为及某些力学性能
IF 1.3 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-07-11 DOI: 10.1515/ipp-2023-4379
Meltem Ürer, Aydin Demir
Abstract The epoxy composite specimens of certain sizes were produced by adding graphite, silicon carbide and boron carbide microparticles separately at the rates of 5, 10 and 15 wt% to the epoxy resin. Free vibrations of these composite samples were investigated experimentally in a simple supported vibration test setup. Frequency spectrums were obtained by modal analysis method in this experimental setup. The damping ratios were calculated using the half power bandwidth method. The mechanical properties of these composite specimens were also determined by applying the tensile test. By controlling the obtained vibration values theoretically, the effects of microparticle contributions to these specimens at certain rates on natural frequency and damping properties were investigated in detail. The maximum reduction in natural frequency was observed at 5 wt% of each reinforcement. Only the first natural frequency of the 15 wt% boron carbide reinforced epoxy composite was slightly increased. The damping ratio was increased at 10 wt% graphite added and 5 wt% boron carbide added epoxy composites compared to pure epoxy, but decreased in other composite specimens.
摘要在环氧树脂中分别以5、10和15wt%的比例添加石墨、碳化硅和碳化硼微粒,制备了一定尺寸的环氧复合材料试样。在一个简单的支撑振动测试装置中,对这些复合材料样品的自由振动进行了实验研究。在该实验装置中,通过模态分析方法获得了频谱。阻尼比采用半功率带宽法计算。还通过拉伸试验测定了这些复合材料试样的力学性能。通过从理论上控制获得的振动值,详细研究了微粒在一定速率下对这些试样的贡献对固有频率和阻尼性能的影响。在每种增强物的5wt%处观察到固有频率的最大降低。只有15wt%碳化硼增强环氧树脂复合材料的第一固有频率略有增加。与纯环氧树脂相比,添加10wt%石墨和5wt%碳化硼的环氧复合材料的阻尼比增加,但在其他复合材料试样中阻尼比降低。
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引用次数: 0
Mechanical and tribological properties of snake grass fibers reinforced epoxy composites: effect of Java plum seed filler weight fraction 蛇草纤维增强环氧复合材料的力学和摩擦学性能:爪哇梅子填料重量分数的影响
IF 1.3 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-07-07 DOI: 10.1515/ipp-2023-4376
Ponnusamy Natarajan, Ponnusamy Rajasekaran, M. Mohanraj, Shanmugam Devi
Abstract Natural fiber composite materials are able to compete with common synthetic materials in situations where the strength-to-weight ratio is important. In this study, we aim to analyze the mechanical, tribological, and surface morphology of composites fabricated from randomly oriented snake grass natural fiber with java plum seed filler. Different weight ratios of fiber to seed filler are chosen: 30:0, 28:2, 26:4, 24:6, 22:8, and 20:10. A 70 % epoxy resin was kept constant in all compositions. The fabricated hybrid composite samples were subjected to tensile, flexural, shear, Shore D hardness, water absorption, and wear tests as per ASTM standards, and the results were compared with those of snake grass mono fiber composites. The 20:10 composite has the maximum tensile strength, impact resistance, flexural strength, hardness, water absorption, and wear resistance compared to other composites. The fiber/matrix adhesion was explored using a scanning electron microscope (SEM). The 20:10 composite shows predominant mechanical and tribological characteristics, making it easier to utilize in structural and automotive applications.
摘要天然纤维复合材料在强度重量比要求较高的场合能够与普通合成材料相竞争。在本研究中,我们的目的是分析随机取向蛇草天然纤维与爪哇梅子填料制成的复合材料的力学、摩擦学和表面形貌。选择不同重量比例的纤维与种子填料:30:0,28:2,26:4,24:6,22:8,20:10。70% %的环氧树脂在所有组成中保持恒定。按照ASTM标准对制备的混杂复合材料试样进行拉伸、弯曲、剪切、邵氏硬度、吸水率和磨损试验,并与蛇草单纤维复合材料进行对比。20:10复合材料与其他复合材料相比,具有最大的拉伸强度,抗冲击性,抗弯强度,硬度,吸水性和耐磨性。利用扫描电子显微镜(SEM)研究了纤维/基质的粘附性。20:10的复合材料表现出突出的机械和摩擦学特性,使其更容易在结构和汽车应用中使用。
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引用次数: 1
Mechanical characterization of randomly oriented short Sansevieria Trifasciata natural fibre composites 随机定向短三叶草天然纤维复合材料的力学性能
IF 1.3 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-07-04 DOI: 10.1515/ipp-2023-4377
Fantin Irudaya Raj, Appadurai M, Lurthu Pushparaj, Chithambara Thanu
Abstract The present work investigates the mechanical characteristics of randomly oriented short Sansevieria Trifasciata Fibre Polyester (STFP) composites. The STFP composites are fabricated using compression moulding methods with varying fibre weight percentages (5 %–50 %) and fibre lengths (5 mm–50 mm). It has been observed that the impact, flexural, and tensile strength of STFPs improve as the length of the fibre increases, up to a maximum of 40 mm. After that, these properties start to decrease as the length of the fibre further increases. Further, the analysis revealed that STFPs exhibited an increase in properties when the fibre weight percentage was less than 40 %, followed by a decrease in properties as the fibre percentage increased beyond that point. The impact strength of STFP is around 8.2 J/cm2. Similarly, the STFP has a flexural modulus and strength of about 3.4 GPa and 82.6 MPa, respectively. Lastly, the tensile strength of STFP is around 78.26 MPa, the elongation at break is between 6.25 % and 9.36 %, and the Young’s modulus is 11.8 GPa. The matrix and fibre interaction were examined by Scanning Electron Microscopy (SEM). Furthermore, Thermogravimetric (TGA) and Differential Scanning Calorimeter (DSC) analyses are carried out. From these analyses, the thermal stability of STFP is 200 °C and its activation energy is 65.48 kJ/mol. After a thorough comparison with other well-known natural fibres, the proposed properties of STFP demonstrate its superiority as a practical and effective natural fibre composite.
摘要本工作研究了随机取向的短Sansevieria Trifasita纤维聚酯(STFP)复合材料的力学特性。STFP复合材料采用不同纤维重量百分比(5%-50%)和纤维长度(5 毫米-50 mm)。已经观察到,STFP的冲击、弯曲和拉伸强度随着纤维长度的增加而提高,最高可达40 此后,随着纤维长度的进一步增加,这些性能开始降低。此外,分析表明,当纤维重量百分比小于40时,STFP的性能有所提高 %, 随后随着纤维百分比增加超过该点,性能下降。STFP的冲击强度约为8.2 J/cm2。类似地,STFP具有约3.4的弯曲模量和强度 GPa和82.6 MPa。最后,STFP的抗拉强度约为78.26 MPa,断裂伸长率在6.25之间 % 和9.36 %, 杨氏模量为11.8 GPa。用扫描电子显微镜(SEM)研究了基体与纤维的相互作用。此外,还进行了热重分析(TGA)和差示扫描量热仪(DSC)分析。根据这些分析,STFP的热稳定性为200 °C,其活化能为65.48 kJ/mol。在与其他众所周知的天然纤维进行彻底比较后,STFP的性能证明了其作为一种实用有效的天然纤维复合材料的优越性。
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引用次数: 0
Experimental analysis of localized hybridization by means of adding woven polyester strip 添加聚酯编织带进行局部杂交的实验分析
IF 1.3 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-07-04 DOI: 10.1515/ipp-2023-4339
M. Chithambara Thanu, Appadurai M, E. Fantin Irudaya Raj, T. Lurthu Pushparaj
Abstract Natural fiber-reinforced composites must be hybridized with synthetic fibers to enhance their mechanical strength. They are appropriate for structural applications after hybridizing with more than 40 % of synthetic fibers. The hybrid composite becomes a partly biodegradable material due to the blend of natural fibers. The localized hybridization approach has been used to minimize the quantity of synthetic fiber used in hybridization. The region around the drilled hole of a composite has been identified as stress concentrated region. In that stress-concentrated region, a polyester strip of different widths is deployed to reinforce it to reduce the delamination occurrence. The present work deals with Jute Fiber reinforced unsaturated polyester resin with local hybridization of woven polyester made up of Perma Core T-18 polyester fiber strands. The interfacial shear and tensile strengths are evaluated for the proposed composite. The results revealed that the yield strength of the proposed composite increased from 18.32 MPa to 29.62 MPa due to local hybridization. The increment of 69.24 % in yield strength is more significant for structural applications.
摘要天然纤维增强复合材料必须与合成纤维杂交以提高其机械强度。它们适合与40多种杂交后的结构应用 % 合成纤维。由于天然纤维的混合,混合复合材料成为一种部分可生物降解的材料。局部杂交方法已被用于最小化杂交中使用的合成纤维的量。复合材料钻孔周围的区域已被确定为应力集中区域。在该应力集中区域,部署不同宽度的聚酯带对其进行加固,以减少分层的发生。本文研究了由Perma Core T-18聚酯纤维股组成的编织聚酯的局部杂交黄麻纤维增强不饱和聚酯树脂。对所提出的复合材料的界面剪切强度和拉伸强度进行了评估。结果表明,所提出的复合材料的屈服强度从18.32提高到 MPa至29.62 MPa。增量69.24 % 屈服强度的变化对于结构应用更为重要。
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引用次数: 0
A comparative study on the mechanical properties of African teff and snake grass fiber-reinforced hybrid composites: effect of bio castor seed shell/glass/SiC fillers 非洲聚四氟乙烯和蛇草纤维增强混杂复合材料力学性能的比较研究——生物蓖麻籽壳/玻璃/SiC填料的影响
IF 1.3 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-07-03 DOI: 10.1515/ipp-2023-4343
K. Manickaraj, R. Ramamoorthi, S. Sathish, A. Johnson Santhosh
Abstract The environmental awareness and sustainable nature of plant-based fibers have forced material researchers and automakers to use natural fibers instead of petroleum-based fibers for various industrial applications. The need for environmentally and biodegradable fibers has created a demand in the transportation industry. In this study, bio castor seed shell (C), glass fiber (G), and SiC (SC) fillers in a constant weight fraction (10 %) were reinforced separately with varying weight fractions (5–25 %) of African teff and snake grass fibers to improve the mechanical properties of the hybrid composites. Both African teff and snake grass fibers were subjected to alkaline treatment to remove amorphous elements such as hemicellulose, lignin, and wax, resulting in high surface roughness. The hybrid composites were fabricated by the compression molding technique and their mechanical properties were characterized as per ASTM standards. The fractured surface of the treated fiber was examined by scanning electron microscopy. From the results, it was found that SC10SG20AT showed maximum mechanical properties compared to C10SG20AT and G10SG20AT due to higher load-bearing capacity of SiC filler. Therefore, SC10SG20AT can be recommended for lightweight applications.
植物基纤维的环保意识和可持续性迫使材料研究人员和汽车制造商在各种工业应用中使用天然纤维代替石油基纤维。对环保和可生物降解纤维的需求在运输行业产生了需求。在本研究中,生物蓖麻籽壳(C)、玻璃纤维(G)和SiC (SC)填充剂分别加入不同质量分数(5-25 %)的非洲teff和蛇草纤维,以提高混杂复合材料的力学性能。非洲苔草和蛇草纤维都经过碱性处理,以去除半纤维素、木质素和蜡等无定形元素,从而获得高表面粗糙度。采用压缩成型技术制备了复合材料,并按ASTM标准对其力学性能进行了表征。用扫描电镜观察了处理后纤维的断裂表面。结果表明,SC10SG20AT比C10SG20AT和G10SG20AT表现出最大的力学性能,这是由于SiC填料的承载能力更高。因此,SC10SG20AT可以推荐用于轻量级应用。
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引用次数: 1
Mechanical strength enhancement of natural fibre composites via localized hybridization with stitch reinforcement 通过局部杂交和缝合增强增强天然纤维复合材料的机械强度
IF 1.3 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-07-03 DOI: 10.1515/ipp-2023-4371
Chithambara Thanu, Fantin Irudaya Raj, Appadurai M, Lurthu Pushparaj
Abstract Stress concentration is an unavoidable phenomenon during the fabrication of composite structures. This research focuses on reducing stress concentration. Circular holes made on the composite structural member induce stress-concentrated regions. These stress-concentrated regions around the circular hole (considered as a weak section) were strengthened by adding synthetic fibre (local hybridization) in the form of fibre stitches (locked loop stitch). Through conducting a single fibre pull-out test, the present study analysed the impact of incorporating synthetic fibres in stitch form and the enhancement of Interfacial Shear Strength (IFSS). The load acting on the broken warp fibres is distributed to the broken weft fibres when the number of concentric stitches increases. The increment of concentric stitches resulted in the increase of IFSS due to localized hybridization. The tensile test results also show a significant improvement with 110 Nmm axial fastening force, from 6.749 MPa (for the natural fibre composite) to 76.91 MPa (for locally hybridized with eight concentric stitches). A simple bolted lap joint with local hybridization around the hole has been evaluated for different clamp-up forces. The best combinations of the clamp-up force and the extent of hybridization have been identified. SEM images illustrate the reduced voids and the reduced fibre pull-out due to the local hybridization around delamination-prone areas.
摘要应力集中是复合材料结构制造过程中不可避免的现象。这项研究的重点是减少应力集中。复合材料结构构件上的圆孔会引起应力集中区域。圆孔周围的这些应力集中区域(被认为是薄弱部分)通过添加纤维缝线(锁定环缝线)形式的合成纤维(局部杂交)来加强。通过单纤维拉拔试验,本研究分析了以缝合形式加入合成纤维对界面剪切强度(IFSS)的影响。当同心针数增加时,作用在断裂的经向纤维上的载荷分布到断裂的纬向纤维上。由于局部杂交,同心缝线的增加导致IFSS的增加。拉伸试验结果还显示,110 Nmm轴向紧固力,从6.749开始 MPa(用于天然纤维复合材料)至76.91 MPa(用于具有八个同心缝线的局部杂交)。对于不同的夹紧力,对孔周围具有局部杂交的简单螺栓搭接接头进行了评估。已经确定了夹紧力和杂交程度的最佳组合。SEM图像显示了由于易分层区域周围的局部杂交而减少的空隙和减少的纤维拉出。
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引用次数: 0
Frontmatter 头版头条
4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-07-01 DOI: 10.1515/ipp-2023-frontmatter3
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引用次数: 0
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International Polymer Processing
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