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Effect of Zn Doping in CdS Thin Films on Structural, Morphological and Optical Characterization 锌掺杂对CdS薄膜结构、形态和光学特性的影响
Pub Date : 2017-07-01 DOI: 10.9790/4861-0904015053
B. S. Munde, L. Ravangave
In this particular experiment we employ Chemical Bath deposition Technique. Initially the bath parameters such as temperature, pH of the precursors, molarity of the solutions, deposition time were optimized for synthesis of CdS thin films. Using above optimized parameters, we prepare Cd1-xZnxS thin films for the study of effect of Zn concentration on various properties of the films. The structural, Morphological and optical characterization were investigated. The XRD spectra of the Cd1-xZnxS films exhibit the hexagonal crystal structure with preferential orientations at (100), (002), (101), (203), (102), (110), (200) and (004) planes. The planes (101), (002), (100) exhibited the wurtzite (hexagonal type) structure. XRD pattern shows increase in half width at full maximum with Zn content. SEM micrograph shows the porous fibrous network consisting of regularly arranged matrix over which regular shaped fine particles systematically distributed. The effect of Zn concentration in Cd1-xZnxS thin films clearly understood from the improvement in the microstructure of the surface morphology. The optical spectra show that absorption was found decreased with Zn content of the Cd1xZnxS.The absorption spectra shows the significant blue shifting of absorption edge (approximately from 450 – 325 nm). The optical transmittance was found maximum in the visible region (450 800 nm) and increased on increasing the Zn concentration. The x=0.2 composition having maximum transmittance 78% show the maximum 3.9 eV optical band gap which may be high enough for solar cell applications.
在这个特殊的实验中,我们采用了化学浴沉积技术。首先对制备CdS薄膜的温度、前驱体的pH、溶液的摩尔浓度、沉积时间等工艺参数进行了优化。利用上述优化参数制备了Cd1-xZnxS薄膜,研究了锌浓度对薄膜各项性能的影响。研究了其结构、形态和光学特性。Cd1-xZnxS薄膜在(100)、(002)、(101)、(203)、(102)、(110)、(200)和(004)平面呈优先取向的六方晶体结构。平面(101)、(002)、(100)呈现纤锌矿(六角形)结构。XRD谱图显示,随着Zn含量的增加,最大半宽增大。扫描电镜显示,多孔纤维网络由规则排列的基质组成,其上有规则形状的细颗粒系统分布。Zn浓度对Cd1-xZnxS薄膜表面形貌的影响从表面微观结构的改善可以清楚地理解。光谱结果表明,Cd1xZnxS的吸收随Zn含量的增加而降低。吸收光谱显示吸收边有明显的蓝移(大约在450 ~ 325 nm)。透过率在可见光区(450 ~ 800 nm)最大,随Zn浓度的增加而增加。x=0.2组合物的最大透过率为78%,显示出最大3.9 eV的光学带隙,这对于太阳能电池的应用可能足够高。
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引用次数: 2
Characterization and Evaluation of Activation Energy for Dc Conductivity of Polypyrrole/Nickel Zinc Iron Oxide Nanocomposites 聚吡咯/镍锌氧化铁纳米复合材料直流电导率的表征及活化能评价
Pub Date : 2017-07-01 DOI: 10.9790/4861-0904022936
V. S. Shanthala, S. Devi, M. Murugendrappa, H. Nagabhushana
Polymer nanocomposites of Polypyrrole and Nickel zinc iron oxide (NiZnFe2O4) are prepared by insitu polymerisation using Ammonium persulphate as oxidising agent. Various nanocomposites have been prepared by varying the level of additive material NiZnFe2O4. The formation of nanocomposites and changes in the structural and microstructural properties were investigated by using XRD, FTIR, and SEM analysis. The size of the particle was analysed by XRD using Scherrer equation and found to be in the range of 15nm 20nm. The lattice parameters were evaluated by W-H plots. DC conductivity has been measured in which activation energy (Ea) of the composites has been evaluated. Activation energies were evaluated from Arrhenius plots for all compositions. Results show that the incorporation of additive material increases the activation energy ‘Ea’ for the DC conductivity of the composites, compared to the base polymer. The increase in the activation energy ‘Ea’ is found to depend on the level of the additive in the composites. Significant increase (196%) in DC conductivity was observed for nanocomposite of 50 wt.%. Therefore such polymer nanocomposites find applications in microwave absorbers, sensors, electromagnetishielding etc.,
以过硫酸铵为氧化剂,采用原位聚合法制备了聚吡咯与镍锌氧化铁(NiZnFe2O4)聚合物纳米复合材料。通过改变NiZnFe2O4的添加量,制备了多种纳米复合材料。采用XRD、FTIR和SEM分析了纳米复合材料的形成、结构和微观结构性能的变化。采用Scherrer方程对颗粒进行XRD分析,粒径在15nm ~ 20nm之间。用W-H图评价晶格参数。测量了复合材料的直流电导率,并对其活化能(Ea)进行了评价。用阿伦尼乌斯图计算了所有组分的活化能。结果表明,与基体聚合物相比,添加剂材料的掺入提高了复合材料直流电导率的活化能Ea。发现活化能Ea的增加取决于复合材料中添加剂的含量。当纳米复合材料质量分数为50%时,直流电导率显著提高(196%)。因此,这种聚合物纳米复合材料在微波吸收器、传感器、电磁屏蔽等方面都有应用。
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引用次数: 6
Aberrations in Theories of Optical Aberrations 光学像差理论中的像差
Pub Date : 2017-07-01 DOI: 10.9790/4861-0904013743
P. Krishna, D. K. Sagar
Optical imaging systems find applications from medicine to military, nano chip to deep space. Their imaging efficiency is deteriorated by Aberrations. Aberration theory has very long history of development. Different types of aberrations, different notations of their description are available in the literature. Often a situation of ambiguity arises for an interdisciplinary scholar to understand them. This paper emphasizes the need of commonness and presents an effort to put them at one place.
光学成像系统的应用范围从医学到军事,从纳米芯片到深空。它们的成像效率因像差而下降。畸变理论有很长的发展历史。不同类型的像差,在文献中有不同的描述方法。跨学科学者在理解它们时往往会遇到模棱两可的情况。本文强调了共同性的必要性,并提出了将它们放在一起的努力。
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引用次数: 0
Synthesis and Optical properties of Eu3+ doped Sr2SiO4 Phosphor for Solid State lighting applications 固态照明用Eu3+掺杂Sr2SiO4荧光粉的合成及光学性能
Pub Date : 2017-07-01 DOI: 10.9790/4861-0904023741
B. ChaudhariDilip, Z. ZambarePradip, H. MahajanO.
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引用次数: 1
Structural and Elastic Studies of Strontium Doped Manganese Borate Glasses 掺锶硼酸锰玻璃的结构与弹性研究
Pub Date : 2017-07-01 DOI: 10.9790/4861-0904014449
P. Vasantharani, S. Vichitra
Ternary Strontium Borate glasses were prepared using the conventional meltquenching method. Longitudinal and shear velocities were measured at 4 MHz at room temperature by Pulse Echo technique. Density is measured using the Archimedes principle. Elastic properties, Debye Temperature and micro hardness have been investigated using the measured velocities and densities. Results indicate that these parameters increase as the composition of SrO increases in the manganese borate glasses.
采用常规熔淬法制备了三元硼酸锶玻璃。利用脉冲回波技术在室温下测量了4 MHz频率下的纵向和剪切速度。密度是用阿基米德原理测量的。使用测量的速度和密度研究了弹性性能、德拜温度和显微硬度。结果表明,这些参数随着硼酸锰玻璃中SrO成分的增加而增加。
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引用次数: 3
Dust-Acoustic Solitary Waves in a Magnetized Dusty Plasma With Ions Of Distinct Temperatures 尘埃-具有不同温度离子的磁化尘埃等离子体中的声学孤波
Pub Date : 2017-07-01 DOI: 10.9790/4861-0903036875
M. Anowar, I. Tasnim, M. Masud
A theoretical investigation has been made of obliquely propagating electrostatic solitary structures in a magnetized dusty plasma, composed of negatively charged dust, nonthermal ions of distinct temperatures, and Boltzmann distributed electrons. The properties of small but finite amplitude dust-acoustic solitary waves (DASWs) in this dusty plasma system are studied by deriving the Zakharov-Kuznetsov (ZK) equation. It has been inferred that the effects of obliqueness, external magnetic field, nonthermal ions of two distinct temperatures, and Boltzmann electrons cause modification of the characteristics (i.e., amplitude and width) of these solitary structures. The implications of our present investigation in understanding the basic features of nonlinear electrostatic perturbations observed in many space plasma systems and laboratory devices are briefly discussed.
对由带负电荷的尘埃、不同温度的非热离子和玻尔兹曼分布电子组成的磁化尘埃等离子体中斜传播的静电孤立结构进行了理论研究。通过推导Zakharov-Kuznetsov (ZK)方程,研究了尘埃等离子体系统中小而有限振幅的尘声孤立波(DASWs)的特性。据推测,倾角、外磁场、两种不同温度的非热离子和玻尔兹曼电子的影响会导致这些孤立结构的特性(即振幅和宽度)的改变。简要讨论了我们目前的研究对理解在许多空间等离子体系统和实验室装置中观察到的非线性静电扰动的基本特征的意义。
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引用次数: 0
Synthesis and Characterization of PVP capped Er and Cu codoped ZnS Nanoparticles PVP包盖Er和Cu共掺杂ZnS纳米粒子的合成与表征
Pub Date : 2017-06-01 DOI: 10.9790/4861-0903026266
S. Rajesh, K. Thyagarajan, G. Harish, V. Reddy
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引用次数: 0
Assessment of Spatial Resolution on SPECT using Image Processing 基于图像处理的SPECT空间分辨率评估
Pub Date : 2017-06-01 DOI: 10.9790/4861-0903025256
E. M. Ahmed, Suhaib Alameen, Y. Khairi, M. E. Gar-elnabi
: The main objective of this study to assess the spatial resolution of SPECT gamma camera using developed Algorithm via image processing procedure. Usually assessment done through visual inspection of phantom images i.e. visual perception trend; in this study, separate algorithm was developed using Interactive Data Language IDL software to quantify the resolution with Modulation Transfer Function (MTF). The data were collected from Departments of nuclear medicine in main hospitals in Khartoum – Sudan (RCIH & RICK) in period from 2015 to 2017; images of QC test were taken from SPECT gamma camera as DICOM format. The result showed that the resolution for minimum object used 4mm was 70% and increased with object size increased to reach 100% resolution for an object size of 10 mm i.e. 100% resolution corresponds to the coordinate of the MTF at 10% and frequency of 0.05cycle /mm. Inconclusion the developed algorithm can be used objectively and improved as required without looking for expertise from other country, as well it can be made to check the acceptance of the device performance regardless the built-in programs.
本研究的主要目的是利用开发的算法,通过图像处理程序来评估SPECT伽玛相机的空间分辨率。通常通过视觉检查幻像进行评估,即视觉感知趋势;本研究使用交互式数据语言IDL软件开发了单独的算法,利用调制传递函数(MTF)量化分辨率。数据收集于2015 - 2017年苏丹喀土穆主要医院(RCIH & RICK)核医学科;QC测试图像以DICOM格式取自SPECT伽玛相机。结果表明,最小目标尺寸为4mm时,分辨率为70%,随着目标尺寸的增大而增大,当目标尺寸为10mm时,分辨率达到100%,即100%的分辨率对应于MTF在10%频率为0.05cycle /mm时的坐标。综上所述,所开发的算法可以客观地使用,并根据需要进行改进,而不需要寻找其他国家的专业知识,也可以不考虑内置程序对设备性能进行验收。
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引用次数: 0
Time Dependence of Density Parameters for a Variable EoS Parameter in Brans-Dicke Framework Brans-Dicke框架中变量EoS参数密度参数的时间依赖性
Pub Date : 2017-06-01 DOI: 10.9790/4861-0903029096
S. Roy
The time dependence of the equation-of-state (EoS) parameter has been determined in the framework of the Brans-Dicke (BD) theory, using BD field equations and the wave equation for the scalar field, for a homogeneous, isotropic and spatially flat universe. This study is based on a model where a linear combination of BD field equations has been taken. The generalized expression of the EoS parameter is a function of the ratio of the constant coefficients used for this linear combination. Expressions of the densities of matter and dark energy and also the density parameters for matter and dark energy have been derived in terms of the EoS parameter. The value of the EoS parameter, at the present epoch, is found to depend, almost solely, on a constant that determines the time dependence of the scalar field. This parameter and the ratio of constant coefficients have been varied, to show graphically, the time dependence of the matter density and the density parameters for matter and dark energy. For certain combinations of these parameters, the matter density is found to decrease with time after initially rising to a peak value, indicating generation of matter, probably from dark energy, during an era in the past.
在Brans-Dicke (BD)理论的框架下,利用BD场方程和标量场的波动方程,确定了均匀、各向同性和空间平坦的宇宙中状态方程(EoS)参数的时间依赖性。本研究基于一个模型,该模型采用了双相场方程的线性组合。EoS参数的广义表达式是用于该线性组合的常系数之比的函数。用EoS参数导出了物质和暗能量的密度表达式以及物质和暗能量的密度参数。在当前历元,发现EoS参数的值几乎完全取决于一个常数,该常数决定标量场的时间依赖性。这个参数和常系数的比值已经改变,以图形显示物质密度和物质和暗能量的密度参数的时间依赖性。对于这些参数的某些组合,发现物质密度在最初上升到峰值后随着时间的推移而降低,这表明在过去的一个时代中物质的产生,可能来自暗能量。
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引用次数: 0
Physical and Spectroscopic Characterization of Chemically Deposited Cd1-xMnxs Thin Films 化学沉积Cd1-xMnxs薄膜的物理和光谱表征
Pub Date : 2017-06-01 DOI: 10.9790/4861-0903028589
B. S. Munde, S. RavangaveL.SRavangaveL.
Chemical bath deposition technique (CBD) was used for deposition of Cd1-xMnxs Thin Films. Initially bath parameters were optimized by physical observation of sustainable Deposition of CdS thin films. The deposited films have been characterized by using X-ray diferactometer, Scanning electron microscopy, EDAX and spectrophotometer. The film thickness was estimated using weight and difference method. Film thickness was found increased with increase in Mn concentration in CdS material. All the films show polycrystalline crystal structure. The observed diffraction patterns were well fitted with the standard JCPDS card data: 772306 of CdS and 76-2049 for MnS. Cd1-xMnxS thin films exhibit the hexagonal as well as cubic crystal structure. The micrograph shows that the films deposited cover the whole substrate with uniform surface morphology. The significant effect of Mn doping has been observed from SEM micrographs of the CdxMn1-xS thin film. Very small amount of Mn doping can show significant change in the microstructure of the SEM. The nanowire morphology was found changed into granular morphology. The absorption spectra show significant blue shifting for the composition x=0.8, having very low absorption. The optical transmittance was higher in the visible region (350 900 nm) and was found increased from 5 to 68 %. The optical band gap was found increased on Mn doping. The x=0.8 exhibit 3.58eV band gap. The maximum transmittance and higher band gap shows that Cd0.2Mn0.8S Composition can be used for solar cell applications.
采用化学浴沉积技术(CBD)制备了Cd1-xMnxs薄膜。通过持续沉积CdS薄膜的物理观察,初步优化了镀液参数。用x射线衍射仪、扫描电镜、电子能谱仪和分光光度计对沉积膜进行了表征。采用重量差法估计膜厚。薄膜厚度随锰浓度的增加而增加。所有薄膜均呈现多晶结构。观察到的衍射图与标准JCPDS卡数据吻合良好:cd为772306,MnS为76-2049。Cd1-xMnxS薄膜具有六方晶体结构和立方晶体结构。显微照片显示,沉积的薄膜覆盖了整个衬底,表面形貌均匀。从CdxMn1-xS薄膜的SEM显微照片中可以观察到Mn掺杂对CdxMn1-xS薄膜的显著影响。极少量的Mn掺杂会使SEM的微观结构发生显著变化。纳米线形态转变为颗粒形态。x=0.8的吸收光谱显示出明显的蓝移,吸收很低。在可见光区(350 900 nm)的透光率较高,从5%增加到68%。Mn掺杂后光学带隙增大。x=0.8的带隙为3.58eV。最大的透过率和较高的带隙表明Cd0.2Mn0.8S化合物可用于太阳能电池。
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引用次数: 1
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IOSR Journal of Applied Physics
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