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Effect of water vapour on the interface reaction between carbon brick and molten iron in blast furnace hearth 水蒸气对高炉炉底炭砖与铁水界面反应的影响
IF 2.1 3区 材料科学 Q2 Materials Science Pub Date : 2023-04-09 DOI: 10.1080/03019233.2023.2195745
Chen-kun Ji, Jian-liang Zhang, Zhong-ping Zou, Wang Cui, Niu Qun, Ke-xin Jiao, Zhong-yi Wang
ABSTRACT In the production process of blast furnace, the damage of cooler and tuyere sleeve and some operation problems often lead to ponding in the hearth. Steam will not only oxidize carbon bricks, but also lead to the falling off of solidification layer, which poses a great threat to the longevity of the hearth. By studying the influence of water vapour content change, the influence mechanism of water vapour on the interface between carbon brick and molten iron in blast furnace hearth is revealed. The results show that the entry of water vapour will isolate the molten iron and carbon brick, and oxidize in contact with the carbon brick, increase the ceramic phase, dissolve into the molten iron, destroy the carbon brick structure at the iron carbon interface, produce spalling, accelerate the destruction and falling off of the solidification layer, so as to reduce the service life of the blast furnace.
在高炉生产过程中,由于冷却器和风口套的损坏以及一些操作问题,经常导致炉膛积水。蒸汽不仅会氧化碳砖,还会导致凝固层脱落,对炉膛的使用寿命构成极大威胁。通过对水蒸气含量变化的影响研究,揭示了水蒸气对高炉炉底炭砖与铁水界面的影响机理。结果表明:水蒸气的进入会使铁液与碳砖分离,并与碳砖接触氧化,增加陶瓷相,溶解到铁液中,破坏铁碳界面处的碳砖结构,产生剥落,加速凝固层的破坏和脱落,从而降低高炉的使用寿命。
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引用次数: 1
Critical analysis of variable atmosphere gaseous reduction of iron oxides pellets 氧化铁球团变大气气体还原的临界分析
IF 2.1 3区 材料科学 Q2 Materials Science Pub Date : 2023-04-04 DOI: 10.1080/03019233.2023.2194732
P. Cavaliere, A. Perrone, D. Marsano
ABSTRACT The paper deals with the analyses of the direct reduction kinetics of industrial iron oxide pellets. Various types of pellets were reduced at different temperatures and pressure (700–1100°C and 1–6 bar) in various atmospheres with different contents of hydrogen and carbon monoxide. The reduction behaviour was described in terms of time to reduction, rate of reduction, and kinetics constant. For those pellets reduced in presence of carbon monoxide, also the carbon percentage in the reduced pellets was taken into account. All the obtained results were analysed through the employment of a commercial multi-objective optimisation tool (modeFrontier) in order to precisely define the weight that each single parameter has on the reduction behaviour of the pellets. The performed analyses allowed also to correlate the different processing parameters and the pellets properties in order to define the kinetics conditions as well as the factors limiting the reduction process.
本文对工业氧化铁球团的直接还原动力学进行了分析。在不同的温度和压力(700–1100°C和1–6 bar)下,在氢气和一氧化碳含量不同的不同环境中还原各种类型的球团。还原行为根据还原时间、还原速率和动力学常数进行了描述。对于那些在一氧化碳存在下还原的颗粒,还考虑了还原颗粒中的碳百分比。通过使用商业多目标优化工具(modeFrontier)对所有获得的结果进行分析,以精确定义每个单个参数对颗粒还原行为的影响。所进行的分析还允许将不同的工艺参数和球团性质关联起来,以确定动力学条件以及限制还原过程的因素。
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引用次数: 1
Study on the formation mechanism of clogging layer of rare earth microalloyed Q355 steel’s submerged entry nozzle and process optimization 稀土微合金化Q355钢水下入口喷嘴堵塞层形成机理及工艺优化研究
IF 2.1 3区 材料科学 Q2 Materials Science Pub Date : 2023-04-03 DOI: 10.1080/03019233.2023.2185738
Bo Zhao, Wei Wu, J. Zhi, Cheng-dong Su, Jiahua Zhang
ABSTRACT The formation mechanism of the clogging layer of the alumina-carbon submerged entry nozzle in the smelting process of rare earth Q355 steel was investigated in this paper. First, the inclusions in the molten steel were discovered to be primarily composed of CaAl2O4, MgO, CaS, and CeAlO3. The mass fraction of solid inclusions increases as the rare earth content increases, and the proportion of inclusions, primarily CaAl2O4, changes. Calcium titanate and cerium aluminate formation can be inhibited by high [Ca] content. XRD and scanning electron microscopy were then used to examine the phase composition and morphology of the inner and outer arcs of the clogging nodules. The clogging was found to be divided into three layers: the nozzle matrix, the reaction layer, and the steel layer. Finally, it is concluded that the dissolution of C element in refractory material is the cause of nozzle blockage, and the core cause of nozzle blockage is the deposition of Al2O3, CaAl2O4, and rare earth compounds. Meanwhile, solutions to nozzle blockage are provided from the perspectives of top slag optimization, the deoxidization process, the calcium treatment process, and protective pouring.
研究了稀土Q355钢冶炼过程中铝碳浸入式水口堵塞层的形成机理。首先,发现钢水中的夹杂物主要由CaAl2O4、MgO、CaS和CeAlO3组成。固体夹杂物的质量分数随着稀土含量的增加而增加,夹杂物(主要是CaAl2O4)的比例也发生了变化。钛酸钙和铝酸铈的形成可以通过高[Ca]含量来抑制。然后使用XRD和扫描电子显微镜检查堵塞结节的内弧和外弧的相组成和形态。发现堵塞分为三层:喷嘴基体、反应层和钢层。最后得出结论,C元素在耐火材料中的溶解是喷嘴堵塞的原因,喷嘴堵塞的核心原因是Al2O3、CaAl2O4和稀土化合物的沉积。同时,从顶渣优化、脱氧工艺、钙处理工艺、保护浇注等方面,提出了水口堵塞的解决方案。
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引用次数: 0
Effect of municipal sludge addition on the sinter process and sinter quality 城市污泥添加对烧结工艺及烧结矿质量的影响
IF 2.1 3区 材料科学 Q2 Materials Science Pub Date : 2023-03-31 DOI: 10.1080/03019233.2023.2192591
Xiao Ping, Feng Wang, Jianlei Pan, Haifeng Wang, Zhi-wei An
ABSTRACT In order to analyse the feasibility of sintering for municipal sludge treatment, a sintering pot was used for the experiment. The results showed that the main effects of sludge addition on the sintering process and sinter quality come from the changes in the heat addition and moisture content of the granulated sinter. The addition of sludge could improve the granulation efficiency of the sinter mixture and the particle size composition of the sinter. When the proportion of sludge was 7%, the addition of sludge completely replaced the water required for mixing, and the overall sintering index was the best. In this case, after reducing fuel consumption by 10%, except for the content of P, the sinter quality and the sintering index could met the requirements of steel production. Finally, the use of fuel and raw materials with high P content needed to be reduced with the addition of sludge.
摘要为了分析烧结处理城市污泥的可行性,采用烧结罐进行了实验研究。结果表明,污泥添加量对烧结过程和烧结质量的主要影响来自于颗粒状烧结矿的热添加量和含水率的变化。污泥的加入可以提高烧结混合料的造粒效率和烧结矿的粒度组成。当污泥掺量为7%时,污泥的加入完全取代了搅拌所需的水,整体烧结指标最好。在此情况下,降低10%的燃料消耗后,除P含量外,烧结质量和烧结指标均能满足钢铁生产的要求。最后,随着污泥的加入,需要减少高磷含量的燃料和原料的使用量。
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引用次数: 0
Analysis of macrosegregation during slab continuous casting using 3D-longitudinal 2D hybrid model 基于三维-纵向-二维混合模型的板坯连铸宏观偏析分析
IF 2.1 3区 材料科学 Q2 Materials Science Pub Date : 2023-03-30 DOI: 10.1080/03019233.2023.2190255
Yaoguang Li, Weiqiang Chen, Yan-hui Sun
ABSTRACT To improve the computational efficiency of simulating the macrosegregation process that occurs during continuous casting of steel slabs, a new hybrid method combining three-dimensional and longitudinal two-dimensional models was developed to consider the turbulent flow, heat transfer, solidification, and solute transport phenomena. The reasonability of the performed computational domain division was determined, and the model accuracy was verified experimentally. Using this approach, the solute distribution characteristics and central segregation during continuous casting were examined in detail. The obtained results revealed that recirculation flows in the turbulent flow region play a critical role in the distribution of solute elements near the slab surface. Owing to the redistribution of solute elements at the solid–liquid interface and the movement of the solid–liquid interface towards the slab centre during continuous casting, the solute elements in the slab centre are continuously enriched, ultimately resulting in central segregation.
为了提高模拟板坯连铸宏观偏析过程的计算效率,提出了一种结合三维和纵向二维模型的混合方法,考虑了湍流、传热、凝固和溶质输运等现象。确定了计算域划分的合理性,并通过实验验证了模型的准确性。利用该方法对连铸过程中溶质分布特征和中心偏析进行了详细的研究。结果表明,湍流区的再循环流动对板坯表面附近溶质元素的分布起着至关重要的作用。在连铸过程中,由于固液界面处溶质元素的重新分布以及固液界面向板坯中心的移动,导致板坯中心处溶质元素不断富集,最终导致中心偏析。
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引用次数: 1
Investigation on the mechanical and pitting corrosion behaviour of solution-treated 22% Cr lean duplex stainless steel with different Mn/N ratio 不同Mn/N比固溶处理22% Cr贫双相不锈钢的力学和点蚀行为研究
IF 2.1 3区 材料科学 Q2 Materials Science Pub Date : 2023-03-22 DOI: 10.1080/03019233.2023.2188522
Gaoling Xia, Shiyu Wu, Yinhui Yang, Xiaoyu Pan, Tao Yuan, Zihao Gao, Zhixin Gao
ABSTRACT Effect of Mn/N ratio on the microstructure evolution, mechanical and pitting corrosion properties of solution-treated 22% Cr lean duplex stainless steel (DSS) was investigated. As the Mn/N ratio decreased, tensile and yied strength, as well as elongation,increased due to the strengthening solid solution effect of more nitrogen addition, and two-phase equilibrium was obtained at 17.80 Mn/N ratio. The drop in the amount of Cr2N, more dislocation cell formation in ferrite and the increase of slip bands in austenite contributed to an increase in toughness with increasing Mn/N ratio from 3.28 to 17.80, whereas more σ precipitates and ferrite fraction resulted in a decrease of it at 54.14 Mn/N ratio. Moreover, higher pitting corrosion resistance was obtained for 17.80 Mn/N ratio DSS than that for 2205 DSS due to the thicker and more compact passive film formation, but higher Mn/N ratio of 54.14 decreased it with more loose MnO formation.
研究了Mn/N比对固溶处理22% Cr贫双相不锈钢(DSS)组织演变、力学性能和点蚀性能的影响。随着Mn/N比的降低,氮加入量的增加增强了固溶体效应,拉伸强度、屈服强度和伸长率均有所提高,在Mn/N比为17.80时达到两相平衡。当Mn/N比从3.28增加到17.80时,Cr2N含量的减少、铁素体中位错细胞的增多和奥氏体中滑移带的增多导致韧性增加,而当Mn/N比为54.14时,σ析出物和铁素体分数的增加导致韧性降低。此外,17.80 Mn/N比的DSS比2205 DSS具有更高的抗点蚀性能,这是由于钝化膜形成更厚、更致密,但当Mn/N比为54.14时,钝化膜形成更松散,降低了DSS的抗点蚀性能。
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引用次数: 0
Development of softening and melting testing conditions simulating blast furnace operation with hydrogen injection 模拟高炉喷氢操作软化熔融试验条件的开发
IF 2.1 3区 材料科学 Q2 Materials Science Pub Date : 2023-03-15 DOI: 10.1080/03019233.2023.2185735
N. Barrett, S. Mitra, H. Doostmohammadi, Damien O’dea, P. Zulli, S. Chew, T. Honeyands
ABSTRACT Softening and Melting (S&M) experiments have evolved alongside the blast furnace as a crucial tool for burden characterisation and optimisation. Modern blast furnaces derive a base load of hydrogen from various sources. However, with hydrogen-enrichment of the blast furnace being considered to mitigate emissions, new S&M test conditions are required. In this study, a 2-D axisymmetric CFD model is used to simulate the internal conditions of a modern blast furnace operation, and a future operation with tuyere level hydrogen injection. The model results are used to guide the development of novel S&M test conditions, inclusive of H2, H2O, CO, CO2 and N2. The maximum hydrogen concentration under hydrogen enrichment was 20%, with the hydrogenous fraction of the gas primarily replacing nitrogen. A particular focus was given to the importance of including water vapour in the inlet gas, andits impact on reactions occurring in the S&M test.
摘要软化和熔炼(S&M)实验与高炉一起发展,成为炉料表征和优化的重要工具。现代高炉从各种来源获得基本负荷的氢气。然而,考虑到高炉的氢气富集以减少排放,需要新的S&M测试条件。在本研究中,使用二维轴对称CFD模型来模拟现代高炉运行的内部条件,以及风口级氢气喷射的未来运行。模型结果用于指导新的S&M测试条件的开发,包括H2、H2O、CO、CO2和N2。氢气富集时的最大氢气浓度为20%,气体中的含氢部分主要取代氮气。特别强调了在进气中加入水蒸气的重要性,以及它对S&M试验中发生的反应的影响。
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引用次数: 1
Effect of cooling conditions on the size evolution of typical inclusions in the Al-Ti deoxidised steel 冷却条件对Al-Ti脱氧钢中典型夹杂物尺寸演变的影响
IF 2.1 3区 材料科学 Q2 Materials Science Pub Date : 2023-03-15 DOI: 10.1080/03019233.2023.2185736
Guocheng Wang, Tiepeng Song, Yuanyou Xiao, Jianfeng Wei, Pengliang Jin
ABSTRACT Confocal laser scanning microscopy was used to perform experiments with various cooling rates for the solidification of Al-Ti deoxidised steel. The effects of cooling rate on the morphology, size distribution of observed with typical inclusions, Al2O3, TiS, and Al2O3-TiS in the steel were investigated. The experimental results demonstrate that the inclusion morphology is significantly influenced by the cooling rate. With an increase in cooling rate, the number of inclusions smaller than 3 μm rises while the number of inclusions bigger than 3 μm continues to fall. The number density of the inclusions increases gradually with the increase of the cooling rate. The nucleation and growth of inclusion were calculated using a combination of kinetics and thermodynamics. It was found that the cooling rate has no influence on the precipitation temperature of inclusions but has slightly influence on the segregation of solute elements during solidification. TiS inclusions can precipitate at the end of solidification while Al2O3 inclusions can precipitate in the liquid phase based on the thermodynamic calculations. As the cooling rate rises, the size of the inclusions decreases gradually and the effect of cooling rate on inclusion decreases.
摘要利用共聚焦激光扫描显微镜对不同冷却速率的Al-Ti脱氧钢进行了凝固实验。研究了冷却速度对钢中典型夹杂物Al2O3、TiS和Al2O3-TiS的形态和尺寸分布的影响。实验结果表明,冷却速度对夹杂物形态有显著影响。随着冷却速度的增加,夹杂物的数量小于3 当夹杂物数量大于3时,μm增加 μm继续下降。夹杂物的数量密度随着冷却速度的增加而逐渐增加。采用动力学和热力学相结合的方法计算了夹杂物的形核和生长。研究发现,冷却速度对夹杂物的析出温度没有影响,但对凝固过程中溶质元素的偏析影响较小。基于热力学计算,TiS夹杂物可以在凝固结束时沉淀,而Al2O3夹杂物可以在液相中沉淀。随着冷却速率的升高,夹杂物的尺寸逐渐减小,冷却速率对夹杂物的影响减小。
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引用次数: 0
Modelling of continuous casting processes parameters on the shrinkage cavity formation in bearing steel blooms 连铸工艺参数对轴承型钢缩孔形成的影响
IF 2.1 3区 材料科学 Q2 Materials Science Pub Date : 2023-03-10 DOI: 10.1080/03019233.2023.2175511
Baozhen Yang, Hui Zhang, Ming-lin Wang
ABSTRACT Based on the thermal-mechanical coupling model, the distance from the critical position of the shrinkage cavity formation of the two bearing steel blooms to the meniscus is 22 and 19.78 m, respectively, and the critical center solid fraction is 0.7145 and 0.7033, respectively. Furthermore, the effects of superheat and casting speed on the critical value of shrinkage cavity formation are discussed. The results show that the two factors have a great influence on the critical position of shrinkage cavity formation in the former, but basically do not affect the critical solid fraction of shrinkage cavity formation. Finally, the industrial heavy reduction tests in different reduction intervals were carried out, and the results show that when the initial reduction position of the heavy reduction process is set before the critical solid fraction, it can not only eliminate the central shrinkage cavity of the bloom, but also improve the central segregation.
基于热-力耦合模型,两种轴承钢华缩洞形成的临界位置距半月板的距离分别为22和19.78 m,中心固相临界分数分别为0.7145和0.7033。讨论了过热度和浇注速度对缩孔形成临界值的影响。结果表明,两者对前者缩孔形成的临界位置影响较大,但对缩孔形成的临界固相分数基本没有影响。最后,进行了不同还原间隔的工业重还原试验,结果表明,将重还原过程的初始还原位置设置在临界固相分数之前,不仅可以消除毛坯的中心缩孔,还可以改善中心偏析。
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引用次数: 0
Homogeneous cooling control technology for high-strength low-alloy hot-rolled strip 高强度低合金热轧带钢均匀冷却控制技术
IF 2.1 3区 材料科学 Q2 Materials Science Pub Date : 2023-03-10 DOI: 10.1080/03019233.2023.2182037
Aigeng Fei, Zhiyi Zhao, R. Xue
ABSTRACT Heterogeneities of transverse temperature during laminar cooling of high-strength low-alloy hot-rolled strip can cause heterogeneous distribution of microstructure, mechanical property and internal stress. Edge masking is a control technology that can be used to improve laminar cooling heterogeneities. In this paper, different edge masking schemes were set up based on the transverse transformation characteristics of the strip. The results show that a slow cooling of 7.1 s during transformation could reduce the heterogeneity of grain size, internal stress and microhardness at the edge and middle of the strip. In addition, the relationship model between grain size and six variables such as transformation start temperature was established by PCA. It provided a new idea for the construction of a microstructure prediction model under nonlinear cooling.
高强度低合金热轧带钢层流冷却时横向温度的不均匀性会导致组织、力学性能和内应力的不均匀分布。边缘掩蔽是一种改善层流冷却非均匀性的控制技术。本文根据条带的横向变换特性,建立了不同的边缘掩蔽方案。结果表明:在相变过程中,慢速冷却7.1 s可以降低带材边缘和中部的晶粒尺寸、内应力和显微硬度的不均匀性;此外,利用主成分分析法建立了晶粒尺寸与转变起始温度等6个变量的关系模型。为建立非线性冷却条件下的微观结构预测模型提供了新的思路。
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引用次数: 0
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Ironmaking & Steelmaking
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