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Heated press welding: analysis of the parameters influencing the mechanical strength of hybrid PA66/PA12 thermoplastic and S235 steel sheet joints 热压焊接:影响PA66/PA12热塑性与S235钢板混合接头机械强度的参数分析
4区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-12 DOI: 10.1080/00218464.2023.2280782
Thomas Fkyerat, Romain Creac’Hcadec, Franck Le Poulain, Clément Guéret
ABSTRACTThis study aims to optimize and characterize hot pressed polyamide/steel hybrid joints as a potential solution for reducing energy costs in public transport through structural lightweighting. The mechanical performance of these joints is compared to traditional bonding methods, specifically investigating two types of joints: PA66/steel and PA12/steel. A design of experiments approach is employed to explore the influence of process parameters, with a particular focus on the cooling rate and heating temperature as key factors. By determining the optimal process parameters, the study emphasizes the importance of reaching the polymer pyrolysis point and achieving the fastest cooling rate to achieve optimal results. The findings reveal that these hybrid joints exhibit comparable average shear strength values to bonded joints, showcasing their potential as effective joining methods. In conclusion, future developments in hybrid polymer/metal joining processes utilizing thermal methods should prioritize rapid and uniform heating at the polymer/metal interface to initiate pyrolysis selectively at the polymer surface for bond formation. Subsequent rapid cooling is essential to cease pyrolysis and prevent polymer degradation within its volume. These insights are crucial for successful implementation of such processes in various industrial applications.KEYWORDS: Hybrid polymer/metal jointhot press weldingTAST test AcknowledgmentsThe authors are in debt to the machining operators of the Brest IUT for providing us the metal and thermoplastic specimen.Disclosure statementNo potential conflict of interest was reported by the author (s).Additional informationFundingThis action benefited from the support of Région Bretagne (ARED) and Brest Métropole Océane.
摘要本研究旨在优化和表征热压聚酰胺/钢混合接头,通过结构轻量化来降低公共交通的能源成本。将这些接头的力学性能与传统的粘合方法进行了比较,具体研究了两种类型的接头:PA66/钢和PA12/钢。采用实验设计的方法探讨工艺参数的影响,特别关注冷却速度和加热温度作为关键因素。通过确定最优工艺参数,强调达到聚合物热解点和达到最快冷却速度对达到最优效果的重要性。研究结果表明,这些混合接头具有与粘结接头相当的平均抗剪强度值,显示了它们作为有效连接方法的潜力。综上所述,利用热方法开发聚合物/金属杂化连接工艺的未来发展应优先考虑在聚合物/金属界面快速均匀加热,从而在聚合物表面选择性地启动热解以形成键。随后的快速冷却对于停止热解和防止聚合物在其体积内降解是必不可少的。这些见解对于在各种工业应用中成功实施此类过程至关重要。关键词:混合聚合物/金属接头压焊;tast测试;致谢致谢作者感谢布雷斯特IUT的加工操作员为我们提供了金属和热塑性试样。披露声明作者未报告潜在的利益冲突。补充信息经费本行动得到了布雷斯特·布列塔尼和布雷斯特·布列塔尼的支持。
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引用次数: 0
Effect of exposure to UV-C rays on fire retardancy and adherence of curable polymer resins for application in disinfection chambers UV-C照射对消毒室用可固化聚合物树脂阻燃性和粘附性的影响
4区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-10 DOI: 10.1080/00218464.2023.2281594
Mateusz Koziol, Jakub Smoleń, Piotr Olesik, Bogusław Mendala, Tomasz Pawlik, Wiktoria Wilczyńska
ABSTRACTThis article discusses the effect of UV-C radiation on two types of cured polymer resins, epoxy and polyester, intended for use in disinfection chambers. The exposure of the samples to UV-C rays lasted 168 h. Our evaluation covered two aspects: the effect of UV-C rays on the flammability and flame retardancy of the resins, and the effect of UV-C rays on the adhesion of the resins to the steel substrate. It was found that the applied halogen and halogen-free organophosphate agents can be used for the tested resins under UV-C conditions (e.g. disinfection chambers), and no negative impact of UV-C radiation on the performance of these flame retardants was found. The use of the tested types of resins in the form of thin coatings on a steel substrate is feasible in disinfection chambers under UV-C radiation conditions, as the obtained results indicate that the radiation did not affect the adhesion of the coating. The visible effect of UV-C radiation on both the tested resins was discoloration, giving yellow and brown colors. Our results suggest that further studies, probably involving longer UV-C exposure, would be advisable.KEYWORDS: UV-C radiationfire retardancycoat adhesionunsaturated polyester resinepoxy resindisinfection chamber AcknowledgmentsThe study was financed by the Department of Materials Technology at the Silesian University of Technology, within the frame of the statutory research grant No. 11/030/BK_23/1127 (BK-220/RM3/2023). The authors want to thank Marta Gwiaździńska and Izabela Polańska for technical support during the testing procedures.Disclosure statementNo potential conflict of interest was reported by the author(s).Author contributionsM.K.: Conceptualization, Formal analysis, Investigation, Methodology, Project administration, Supervision, Validation, Writing – original draft, Writing – review & editing; J.S.: Data curation, Investigation, Visualization; P.O.: Data curation, Investigation; B.M.: Formal analysis, Funding acquisition, Methodology, Resources, Supervision, Writing – review & editing; T.P.: Formal analysis, Investigation, Methodology, Writing – review & editing; W.W.: Investigation, Methodology, VisualizationAdditional informationFundingAuthors confirm that there are no relevant financial or non-financial competing interests to report.
摘要本文讨论了UV-C辐射对两种用于消毒室的固化聚合物树脂环氧树脂和聚酯树脂的影响。样品暴露在UV-C射线下的时间为168 h。我们的评估包括两个方面:UV-C射线对树脂的可燃性和阻燃性的影响,以及UV-C射线对树脂与钢基体粘附性的影响。结果表明,在UV-C条件下(如消毒室),所使用的卤素和无卤有机磷酸酯剂均可用于所测试的树脂,且未发现UV-C辐射对阻燃剂性能的负面影响。在UV-C辐射条件下的消毒室中,在钢基材上以薄涂层的形式使用所测试的类型的树脂是可行的,因为所获得的结果表明辐射不影响涂层的附着力。UV-C辐射对两种测试树脂的可见影响是变色,呈现黄色和棕色。我们的结果表明,进一步的研究,可能涉及更长时间的UV-C暴露,将是可取的。本研究由西里西亚理工大学材料技术系在法定研究拨款No. 11/030/BK_23/1127 (BK-220/RM3/2023)框架内资助。作者要感谢Marta Gwiaździńska和Izabela Polańska在测试过程中的技术支持。披露声明作者未报告潜在的利益冲突。作者贡献:概念化、形式分析、调查、方法论、项目管理、监督、验证、写作-原稿、写作-审稿编辑;j.s.:数据管理、调查、可视化;p.o.:数据管理,调查;硕士:形式分析,资金获取,方法论,资源,监督,写作-审查和编辑;T.P:形式分析,调查,方法论,写作-审查和编辑;w.w.:调查、方法、可视化附加信息资金来源作者确认没有相关的财务或非财务竞争利益需要报告。
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引用次数: 0
Adhesion property of municipal solid waste incinerator bottom ash and limestone with asphalt based on surface energy theory 基于表面能理论的城市生活垃圾焚烧炉底灰与石灰石与沥青的粘附性能研究
4区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-08 DOI: 10.1080/00218464.2023.2280657
Yongjie Ding, Wei Wei, Danni Li, Jiaojiao Wang, Yuxin Shi, Zijun Mei
ABSTRACTThe aim of this paper is to investigate the adhesion of municipal solid waste incinerator bottom ash (MSWIBA) and limestone to asphalt using the principles of surface energy theory. MSWIBA asphalt mixes are known for their satisfactory water stability, with adhesion being a crucial factor, as demonstrated in previous freeze-thaw splitting tests. Contact angles of ground MSWIBA and limestone were measured using a capillary rise test, eliminating the influence of material surface structure. Subsequently, adhesion work and spalling work were calculated to correlate with water-induced damage. The results showed that the sequence of adhesion work was fine MSWIBA > limestone > coarse MSWIBA, while the sequence of spalling work was coarse MSWIBA > limestone > fine MSWIBA. The adhesion of MSWIBA asphalt mixes was evaluated using the water boiling test image method to validate the findings of surface energy theory. In both asphalt tests, the spalling rate followed this sequence: coarse MSWIBA > limestone > fine MSWIBA. The Adhesion index ER ranked as follows: ER Fine MSWIBA > ER limestone > ER coarse MSWIBA. These results suggest that the water stability of MSWIBA asphalt mixes is influenced by the surface energy of the components. Consequently, indices derived from surface energy theory can be applied in formulating and predicting the properties of MSWIBA asphalt mixes.KEYWORDS: Asphalt mixturemunicipal solid waste incinerator bottom ashsurface free energyadhesion workspalling work AcknowledgmentsThe research was financially supported by the National Natural Science Foundation of China (52008069) and Beijing Postdoctoral Research Foundation(2022-zz-054). The views in the paper only reflect those from the authors and may not necessarily reflect the views from the sponsors.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThe research was financially supported by the National Natural Science Foundation of China (52008069) and Beijing Postdoctoral Research Foundation (2022-zz-054). The views in the paper only reflect those from the authors and may not necessarily reflect the views from the sponsors.
摘要本文运用表面能理论研究了城市生活垃圾焚烧炉底灰和石灰石对沥青的附着力。MSWIBA沥青混合料以其令人满意的水稳定性而闻名,正如之前的冻融劈裂试验所证明的那样,附着力是一个关键因素。采用毛细上升法测量了地面MSWIBA与石灰石的接触角,消除了材料表面结构的影响。随后,计算了附着功和剥落功与水致损伤的关系。结果表明:黏附效果为细粒MSWIBA >灰岩>粗粒MSWIBA,剥落效果为粗粒MSWIBA >灰岩>细粒MSWIBA。采用沸水试验图像法对MSWIBA沥青混合料的附着力进行了评价,验证了表面能理论的结论。两种沥青试验的剥落率顺序为:粗粒MSWIBA >石灰石>细粒MSWIBA。粘附指数ER的大小为:ER细粒MSWIBA > ER石灰石> ER粗粒MSWIBA。这些结果表明,MSWIBA沥青混合料的水稳定性受到组分表面能的影响。因此,由表面能理论导出的指标可用于MSWIBA沥青混合料的配方和性能预测。关键词:沥青混合料;城市固体垃圾焚烧炉底灰;表面自由能;论文中的观点仅反映作者的观点,不一定反映主办方的观点。披露声明作者未报告潜在的利益冲突。本研究由国家自然科学基金(52008069)和北京市博士后科研基金(2022-zz-054)资助。论文中的观点仅反映作者的观点,不一定反映主办方的观点。
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引用次数: 0
Preparation of isocyanate microcapsules by complex coacervation and its application in plywood 复合凝聚法制备异氰酸酯微胶囊及其在胶合板中的应用
4区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.1080/00218464.2023.2277299
Yangbao Ma, Tao Wang, Xiaohui Chang, Ao Liu, Xiaona Meng, Changhui Liu, Yanhua Zhang
ABSTRACTAt present, the use of isocyanate adhesives mostly requires the assistance of solvents, which can cause adverse environmental pollution and health effects. The aqueous isocyanate avoids the shortcomings of the solvent, but shortens the working life of the isocyanate. Isocyanate microcapsules can avoid these shortcomings, and can also solidify isocyanate to improve the efficiency of isocyanate use. In this study, microencapsulation technology was used to protect the highly reactive -NCO group, improve the stability of isocyanate, and prolong the working life of isocyanate in water-based wood adhesives. That is, isocyanate microcapsules with gum Arabic/gelatin as shell and isocyanate as core were prepared in oil-in-water emulsion by complex coacervation. In addition, the preparation process was optimized by changing the parameters. Then, the prepared isocyanate microcapsules were characterized and analyzed by Fourier transform infrared spectrometer, Scanning electron microscope, Particle size analyzer, etc. Finally, plywood was prepared by using the prepared isocyanate microcapsules in the wood adhesive. The results showed that, the particle size of isocyanate microcapsules was controllable, and the content of active groups and core in the prepared isocyanate microcapsules can reach a high level. The isocyanate microcapsules extend the working life of isocyanates from about 30 mins to 5 hours, and significantly improve the stability of isocyanates. The bonding strength of the prepared plywood meets the requirements of (Class I plywood) with only 20% -NCO addition.KEYWORDS: Isocyanate microcapsulescomplex coacervationplywoodworking life AcknowledgmentThis work was supported by the Educational Commission of Henan Province of China (No. 23A430038) and the National Forestry and Grassland Administration Key Laboratory of Plant Fiber Functional Materials (2022KFJJ12). Special thanks to the support of Doctoral Cultivation Fund Project of Henan University of Engineering (No. D2022003).Disclosure statementNo potential conflict of interest was reported by the author(s).Authorship contribution statementYangbao Ma, Changhui Liu and Yanhua Zhang conceived and designed the experiments; Yangbao Ma, Xiaohui Chang, Ao Liu, Xiaona Meng performed the experiments; Yangbao Ma, Changhui Liu, Tao Wang and Yanhua Zhang analyzed the data; Yangbao Ma contributed reagents/materials/analysis tools; Yangbao Ma and Changhui Liu wrote the paper. All authors read and approved the manuscripts.Additional informationFundingThe work was supported by the National Natural Science Foundation of China [32071692]; National Forestry and Grassland Administration Key Laboratory of Plant Fiber Functional Materials [2022KFJJ12]; Educational Commission of Henan Province of China [23A430038].
摘要目前异氰酸酯胶粘剂的使用大多需要溶剂的辅助,会造成不良的环境污染和健康影响。含水异氰酸酯避免了溶剂的缺点,但缩短了异氰酸酯的使用寿命。异氰酸酯微胶囊可以避免这些缺点,还可以固化异氰酸酯,提高异氰酸酯的使用效率。本研究采用微胶囊化技术保护高活性的-NCO基团,提高异氰酸酯的稳定性,延长异氰酸酯在水性木材胶粘剂中的使用寿命。即以阿拉伯胶/明胶为壳,异氰酸酯为芯,在油包水乳液中复合凝聚法制备异氰酸酯微胶囊。另外,通过改变工艺参数对制备工艺进行了优化。然后利用傅里叶变换红外光谱仪、扫描电镜、粒度分析仪等对制备的异氰酸酯微胶囊进行表征和分析。最后,将制备的异氰酸酯微胶囊掺入木材胶粘剂中制备胶合板。结果表明,制备的异氰酸酯微胶囊粒径可控,活性基团和核心含量达到较高水平。异氰酸酯微胶囊将异氰酸酯的使用寿命从30分钟左右延长到5小时,并显著提高了异氰酸酯的稳定性。制备的胶合板粘结强度满足(I类胶合板)要求,仅添加20%的-NCO。本文得到河南省教委(No. 23A430038)和国家林业和草原局植物纤维功能材料重点实验室(No. 2022KFJJ12)的资助。特别感谢河南工程大学博士点培养基金项目(No. 811@166.com)的支持。D2022003)。披露声明作者未报告潜在的利益冲突。作者贡献声明:马阳宝、刘长辉、张艳华构思设计实验;马阳宝,常晓辉,刘傲,孟小娜进行了实验;马阳宝、刘长辉、王涛、张艳华分析了数据;马阳宝贡献的试剂/材料/分析工具;论文作者是马阳宝和刘长辉。所有作者都阅读并批准了稿件。基金资助:国家自然科学基金项目[32071692];国家林业和草原局植物纤维功能材料重点实验室[2022KFJJ12];河南省教育委员会[23A430038]。
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引用次数: 0
Comparative analysis of primers and alternative polypropylene pre-treatment techniques 底漆与聚丙烯预处理技术的比较分析
4区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.1080/00218464.2023.2276110
Henryk Szramowski, Marek Piotr Krzemiński
ABSTRACTThe test polypropylene substrates obtained from the original plastic car parts for Škoda Superb were subjected to 10 pre-treatment techniques: solvent cleaning (isopropanol, xylene), mechanical abrasion, immersion in a chromic acid mixture, flame activation, atmospheric and low-pressure plasma treatment, corona discharges and the application of two different primers (also called adhesion promoters). One of the primers, based on chlorinated polypropylene, was commercially available, while the other was prepared in our laboratory using polypropylene grafted with maleic anhydride. The test substrates were characterized using contact angle measurement for designation of surface free energy, Atomic Force Microscope (AFM) for roughness analysis, Scanning Electron Microscopy (SEM) for surface topography, and Energy Dispersive X-ray Spectrometry (EDX) for surface oxygen and contamination analysis. The suitability of the surface preparation methods in the industry was evaluated through peel strength tests (adhesive bonding process) and cross-cut tests (painting process). Not all tested methods were effective in increasing adhesion, especially in the adhesive bonding process, and even fewer in the painting process. However, some of them were suitable for both applications. The use of primers was found to be crucial.KEYWORDS: Plasticspolypropyleneadhesionsurface pre-treatmentadhesion promotersprimers AcknowledgmentsThe authors thank: Łukasiewicz Research Network - Institute for Engineering of Polymer Materials and Dyes for conducting plasma and corona discharge trials; Maflow Plastics Poland for receiving polypropylene samples and adhesive tapes.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.
摘要:从Škoda Superb原塑料汽车零件中获得的聚丙烯基材进行了10项预处理技术:溶剂清洗(异丙醇、二甲苯)、机械磨损、铬酸混合物浸泡、火焰活化、常压和低压等离子体处理、电晕放电和两种不同的底漆(也称为附着力促进剂)的应用。其中一种引物是基于氯化聚丙烯的市售引物,而另一种引物是在我们实验室用聚丙烯接枝马来酸酐制备的。使用接触角测量表征表面自由能,原子力显微镜(AFM)进行粗糙度分析,扫描电子显微镜(SEM)进行表面形貌分析,能量色散x射线光谱(EDX)进行表面氧和污染分析。通过剥离强度试验(胶粘接工艺)和横切试验(涂漆工艺)对工业表面制备方法的适用性进行了评价。并不是所有的测试方法都能有效地增加附着力,特别是在胶粘接过程中,在涂装过程中就更少了。然而,其中一些适用于这两种应用程序。引物的使用被认为是至关重要的。关键词:塑料聚丙烯粘接表面预处理粘接促进剂喷剂感谢:Łukasiewicz研究网络-高分子材料与染料工程研究所进行等离子体和电晕放电试验;Maflow塑料波兰接收聚丙烯样品和胶带。披露声明作者未报告潜在的利益冲突。本研究没有从公共、商业或非营利部门的资助机构获得任何特定的资助。
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引用次数: 0
Experimental investigation and molecular simulation on the chemical bonding between laser-treated titanium alloy amorphous surface and epoxy adhesive 激光处理钛合金非晶态表面与环氧胶粘剂化学键合的实验研究与分子模拟
4区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.1080/00218464.2023.2277298
Shuangshuang Li, Jianping Lin, Junying Min
ABSTRACTLaser surface modification is employed to enhance the interfacial bonding performance of metal-adhesive structures, and chemical bonding plays a crucial role in achieving strong interfacial adhesion. Understanding the mechanism of interfacial chemical bonding between laser-treated metal surface and adhesive at the molecular/atomic scale is key to further optimizing the interfacial bonding performance. In this study, the morphology and chemical composition of laser-induced amorphous titanium oxide on titanium alloy surfaces, as well as its enhanced effect on interfacial bonding performance, were characterized using scanning electron microscopy, energy dispersive spectroscopy, and single lap-shear testing.Through X – ray photoelectron spectroscopy analysis, experimental evidence is provided for the formation of Ti-O-C chemical bonds between the amorphous titanium oxide and adhesive. Transmission electron microscopy observations and molecular dynamics simulations reveal that the strong non-bonding intereactions between amorphous titanium oxide and adhesive enables the adhesive molecules to fully infiltrate the amorphous titanium oxide, providing more sites for chemical bond formation. Density functional theory calculations demonstrate that Ti-O-C chemical bonds tend to form between the dissociated hydroxyl group of the adhesive and titanium oxide, facilitated by a relatively low reaction barrier. This chemical bonding promote the formation of a strong bonding structure at the adhesive interface.KEYWORDS: Chemical bondinglaser ablationamorphous titanium oxideadhesive bondedmolecular simulation AcknowledgmentsThis work was supported by the International Exchange Program for Graduate Students, Tongji University (2023020021).The authors acknowledge the Adaptive Bonding Interface Behavior of Typical Automotive Sheet Metals with Coating project for providing financial support. Additionally, the authors extend their thanks to the School of Materials Science and Engineering, Tongji University for providing Materials Studio software which was used to perform computational work presented in this paper.Disclosure statementThe authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.Author contributionsShuangshuang Li: Validation, Visualization, Writing-original draft; Jianping Lin: Supervision, Conceptualization, Formal analysis, Writing – review & editing; Junying Min: Resources; Funding acquisition.Additional informationFundingThis work was supported by the International Exchange Program for Graduate Students [2023020021].
摘要激光表面改性是提高金属-粘接结构界面粘接性能的重要手段,而化学键合是提高金属-粘接结构界面粘接性能的关键。在分子/原子尺度上了解激光处理金属表面与胶粘剂之间的界面化学键合机理是进一步优化界面键合性能的关键。本研究采用扫描电镜、能量色散光谱、单搭剪测试等方法,表征了激光诱导钛合金表面非晶态氧化钛的形貌、化学成分及其对界面结合性能的增强作用。通过X射线光电子能谱分析,为无定形氧化钛与胶粘剂之间形成Ti-O-C化学键提供了实验证据。透射电镜观察和分子动力学模拟表明,非晶态氧化钛与胶粘剂之间的强非键相互作用使得胶粘剂分子能够充分渗透到非晶态氧化钛中,为化学键的形成提供了更多的位点。密度泛函理论计算表明,相对较低的反应势垒有助于在黏合剂的解离羟基与氧化钛之间形成Ti-O-C化学键。这种化学键合促进了在粘接界面处形成牢固的键合结构。关键词:化学键合;激光烧蚀;非晶态氧化钛;作者承认典型汽车钣金与涂装项目的自适应粘接界面行为提供了资金支持。此外,作者还对同济大学材料科学与工程学院提供的Materials Studio软件表示感谢,该软件用于完成本文的计算工作。披露声明作者声明,他们没有已知的竞争经济利益或个人关系,可能会影响本文所报道的工作。李双爽:验证、可视化、撰写原稿;林建平:监督、构思、形式分析、写作—审稿编辑;闵俊英:资源;融资收购。本研究由研究生国际交流项目[2023020021]资助。
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引用次数: 0
Optimization of chitosan adhesive properties by means of genipin crosslinking 吉尼平交联法优化壳聚糖粘接性能
4区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-10-19 DOI: 10.1080/00218464.2023.2270416
Jeanne Silvestre, Hélène de Baynast, Philippe Michaud, Cédric Delattre
ABSTRACTChitosan is a polysaccharide resulting from chitin deacetylation. It has demonstrated interesting characteristics in the field of adhesion but loses most of its adhesive resistance in moist environment. A chemical crosslinking of chitosan with genipin has been implemented to improve its adhesive properties in the presence of water. The study of crosslinking kinetics using rheology revealed its dependency on crosslinking rate and chitosan concentration. The capacity of the chitosan-genipin systems for water absorption has been quantified as their Free Swelling Capacity. The cross-linkage of chitosan by genipin (1% w/w) decreased significantly its ability for water absorption. Finally, the adhesive strength of several chitosans be they supplemented or not with genipin and/or glycerol used as plasticizer have been performed on Thick Adherent Shear Test samples of beech wood according to standard EN 204:2016 and EN 205:2016. The chitosan adhesive formulation containing genipin and glycerol exhibits the better adhesive properties on wood and presents higher water resistance compared to the native chitosan formulation.KEYWORDS: Adhesivechitosanwoodgenipincross-linkage Disclosure statementNo potential conflict of interest was reported by the authors.Data availability statementThe data presented in this study are available on request from the corresponding author.Additional informationFundingThis work was supported by the Région AuRA(France), Pack Ambition Recherche ChitoGlue project n°DRV_SIP_2020-043_Chitoglue.
壳聚糖是由几丁质脱乙酰化而成的多糖。它在粘接领域表现出了有趣的特性,但在潮湿环境中失去了大部分的粘接阻力。为了提高壳聚糖在水环境下的粘接性能,研究了壳聚糖与皂荚素的化学交联。用流变学方法研究了交联动力学,揭示了交联速率和壳聚糖浓度对交联动力学的影响。壳聚糖-基尼素体系的吸水能力被量化为它们的自由溶胀能力。壳聚糖与genipin (1% w/w)交联显著降低壳聚糖的吸水能力。最后,根据EN 204:2016和EN 205:2016标准,对几种壳聚糖进行了粘合强度测试,无论是否添加了genipin和/或甘油作为增塑剂。与天然壳聚糖配方相比,含有皂荚素和甘油的壳聚糖胶粘剂配方对木材具有更好的粘接性能和更高的耐水性。关键词:胶粘剂、粘多糖、木质素、交叉连锁披露声明作者未报告潜在利益冲突。数据可用性声明本研究中提供的数据可向通讯作者索取。本研究由r gion AuRA(France)、Pack Ambition Recherche chitog胶水项目(n°drv_sip_2020 -043 _chitog胶水)资助。
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引用次数: 0
A high-throughput technique to evaluate the probability distribution of strength of adhesively bonded joints after moisture absorption 一种评估粘接接头吸湿后强度概率分布的高通量技术
4区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-10-19 DOI: 10.1080/00218464.2023.2271399
Chao Kang, Ming Ji, Yu Sekiguchi, Masanobu Naito, Chiaki Sato
The reliability of adhesive bond strength influences the applicability of structural adhesives in industries. The statistical probability distribution of the strength of adhesive joints is an essential indicator when designing and choosing adhesives. In this study, we experimentally studied the probability distribution of the strength of adhesive joints. The strength data were collected using a novel high-throughput technique consisting of a sample preparation method and shear testing device. Numerous cylindrical butt shear-joint specimens were prepared by mechanical machining and tested using a self-developed shear testing device. The effect of moisture absorption by the adhesive was specifically considered. The probability distribution of the shear strength of the epoxy adhesive joints was characterized using five probability distribution functions: Normal, Lognormal, Exponential, Weibull, and Gamma. Quantile – quantile plots were employed to determine the suitability of each distribution function. The results suggested that the Weibull and Normal distributions were best suited for describing the probability distribution of the strength of the epoxy adhesive joints. The Weibull distribution is particularly suitable for brittle epoxy adhesives. Moisture absorption reduced both the mean and variance of the shear strength, which might be attributed to the plasticization of the adhesives. The high-throughput method proposed in this study significantly improved the efficiency of testing adhesive joints. It not only contributes to the study of the strength distributions of adhesive joints but also helps to shorten the research and development cycle of new adhesives by facilitating rapid strength evaluation.
胶粘剂结合强度的可靠性影响着结构胶粘剂在工业上的适用性。粘接接头强度的统计概率分布是设计和选择胶粘剂的重要指标。在本研究中,我们实验研究了粘接接头强度的概率分布。采用一种新型的高通量技术收集强度数据,该技术由样品制备方法和剪切测试装置组成。采用机械加工方法制备了大量圆柱对接剪切接头试件,并利用自行研制的剪切试验装置进行了试验。具体考虑了胶粘剂吸湿的影响。采用正态、对数正态、指数、威布尔和伽玛5种概率分布函数表征环氧胶合接头抗剪强度的概率分布。分位数-分位数图用于确定每个分布函数的适用性。结果表明,威布尔分布和正态分布最适合描述环氧胶合接头强度的概率分布。威布尔分布特别适用于脆性环氧胶粘剂。吸湿降低了抗剪强度的平均值和方差,这可能与胶粘剂的塑化有关。本研究提出的高通量方法显著提高了粘合接头的检测效率。它不仅有助于研究胶粘剂接头的强度分布,而且有助于通过快速评估强度来缩短新型胶粘剂的研发周期。
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引用次数: 0
An experimental investigation of static and fatigue behavior of various adhesive single lap joints under bending loads subjected to hygrothermal and thermal conditions 在湿热和热条件下,对不同粘结单搭接接头在弯曲载荷下的静态和疲劳性能进行了实验研究
4区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-10-18 DOI: 10.1080/00218464.2023.2270431
Li-Cai Zhao, Sajjad Karimi, Liang Xu
ABSTRACTThe objective of this study is to investigate the impact of hygrothermal and thermal aging on adhesive bonding joints of similar and dissimilar specimens. The research focuses on the single lap joint (SLJ) configuration using Aluminum/Aluminum and CFRP/CFRP for similar bonding and Aluminum/CFRP for dissimilar bonding. Understanding the behavior of such joints over time and eventual failure can enhance their durability, reliability, and safety in structures. The study submerged SLJ specimens in tap water at a temperature of 53°C for 20 days to assess hygrothermal aging and kept another group of joints in an oven set at the same temperature for thermal aging. The research evaluated the strength of samples that underwent no aging, hygrothermal and thermal aging, tested through three-point bending tests. Various load levels were tested utilizing a recently designed fixture, including 70%, 60%, and 50% of the static load level. Results showed the highest joint strength in Aluminum/Aluminum SLJs and reduced strength following thermal and hygrothermal aging. The failure patterns and number of cycles leading to failure also varied with load percent and aging. Ultimately, the study aimed to evaluate and contrast the strength of samples that underwent different aging processes.KEYWORDS: Jointstatic and fatigue strengthhygrothermal and thermal conditionsbending load AcknowledgementThis research has been jointly supported by The China's Liaoning Province 'Xing Liao Talents Plan' Youth Top-notch Talent Funding Project under Grant No.XLYC2007146 and Science and Technology Research Plan of China Railway 19th Bureau Co.,Ltd under Grant No.2021-B03.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingChina’s Liaoning Province “Xing Liao Talents Plan” Youth Top-notch Talent Funding Project (No.XLYC2007146).
摘要本研究的目的是研究湿热老化和热老化对相似和不同试样粘接接头的影响。重点研究了铝/铝、CFRP/CFRP相似键合、铝/CFRP不同键合的单搭接结构。了解这些节点随着时间的推移和最终失效的行为可以提高它们在结构中的耐久性、可靠性和安全性。研究将SLJ试件置于53℃的自来水中浸泡20天,进行湿热老化试验,并将另一组接头置于相同温度的烤箱中进行热老化试验。该研究评估了未老化、湿热老化和热老化样品的强度,并通过三点弯曲试验进行了测试。使用最近设计的夹具测试了各种负载水平,包括70%,60%和50%的静态负载水平。结果表明:铝/铝slj接头强度最高,热、湿热时效后接头强度降低;失效模式和导致失效的循环次数也随载荷百分比和老化而变化。最终,该研究旨在评估和对比经历不同老化过程的样品的强度。关键词:关节静力与疲劳强度湿热与热条件弯曲载荷。中铁十九局有限公司科技研究计划(批准号2021- b03)。披露声明作者未报告潜在的利益冲突。中国辽宁省“兴辽英才计划”青年拔尖人才资助项目(No.XLYC2007146)。
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引用次数: 0
Influence of printing material moisture on part adhesion in fused filament fabrication 3D printing 熔融长丝制造3D打印中打印材料水分对零件附着力的影响
4区 材料科学 Q2 ENGINEERING, CHEMICAL Pub Date : 2023-10-12 DOI: 10.1080/00218464.2023.2268531
D. Laumann, D. Spiehl, E. Dörsam
ABSTRACTFused filament fabrication plays an increasingly important role in modern manufacturing. Despite this, issues like deformations caused by thermal shrinkage are still common. These process failures, called warping, can easily be avoided by ensuring sufficient adhesion of the printed part to the build surface during the manufacturing process. Nevertheless, only a few is known about the factors which have an impact on the adhesion between a part to be printed and the build surface. Although the content of moisture in the used polymer plays an important role in every established processing method, its influence on adhesion is still unknown for fused filament fabrication. This publication investigates the influence of moisture in the printing material for the examples of build surfaces made from Pertinax and borosilicate glass and printing materials such as polylactide acid, polyvinyl alcohol and polyamide. These printing materials were characterized by thermogravimetric analyses and differential scanning calorimetry. Following adhesion tests showed that the moisture content of the printing material can alter the adhesion between the printed part and the build surface up to 68%. It was also shown that there is an optimum moisture content at which maximum adhesion is reached.KEYWORDS: Additive manufacturingmaterial extrusionbuild surface adhesion AcknowledgmentsWe would like to thank the working group of Macromolecular and Paper Chemistry of Markus Biesalski and especially Sunna Möhle-Saul for access to DSC and TGA measurements and consultation regarding setup and interpretation.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by the Federal Ministry for Economic Affairs and Climate Action within the Central Innovation Programme for small and medium-sized enterprises (SMEs) under Grant 16KN084521.
摘要熔融长丝制造在现代制造业中发挥着越来越重要的作用。尽管如此,热收缩引起的变形等问题仍然很常见。这些过程失败,称为翘曲,可以很容易地避免在制造过程中,通过确保印刷部分足够的粘附到构建表面。然而,对于影响待打印部件与构建表面之间粘附性的因素,我们所知甚少。虽然所使用的聚合物中的水分含量在每一种既定的加工方法中都起着重要的作用,但它对熔融长丝制造的粘附性的影响仍然未知。本出版物调查了印刷材料中水分的影响,例如由比蒂诺和硼硅酸盐玻璃制成的建筑表面以及印刷材料,如聚乳酸,聚乙烯醇和聚酰胺。用热重分析和差示扫描量热法对这些印刷材料进行了表征。随后的附着力测试表明,打印材料的水分含量可以改变打印部件与构建表面之间的附着力高达68%。结果还表明,有一个最佳的水分含量,达到最大的附着力。致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢披露声明作者未报告潜在的利益冲突。这项工作得到了联邦经济事务和气候行动部在中小型企业中央创新计划(sme)下的资助,资助号为16KN084521。
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引用次数: 0
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Journal of Adhesion
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