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Impact of the Proposed Euro 7 Regulations on Exhaust Aftertreatment System Design 欧7法规对尾气后处理系统设计的影响
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651323x16805977899699
Chris Morgan, J. Goodwin
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引用次数: 0
Desulfurizing Fuels Using Alcohol-Based DESs Using ECODS Method 用ECODS法对醇基DESs进行燃料脱硫
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651324x16964075320630
Nisha Saini, Pooja Yadav, Kuldeep Singh, Prasenjit Ghosh, Rajkumar Singh
A special awareness has been given worldwide to clean the polluted environment. The environment is polluted mainly by greenhouse gases, emissions from transportation fuels, etc. Among them, sulfur compounds emitted from the emission of transported fuels significantly impact environmental pollution. It requires the removal of these sulfur compounds from transportation fuels. Refineries use the hydrodesulfurization (HDS) process to reduce these sulfur compounds from fuels. However, the HDS process requires high hydrogen pressure and temperature, making it cost-effective. An alternative to the HDS process is oxidative desulfurization via solvent extraction, which requires low-temperature operating conditions. In this regard, deep eutectic solvents (DESs) are attractive for researchers to desulfurize transportation fuels via solvent extraction due to their low-cost synthesis method. In our study, DESs were synthesized using phenylacetic acid and salicylic acid as hydrogen bond acceptors (HBAs) and tetraethylene glycol as hydrogen bond donor (HBD) in the mole ratio of 1:2. DESs were characterized by using FTIR spectra. Physico-chemical properties of DESs, such as density, viscosity, and refractive Index, were also measured. The synthesized DESs were performed to extract organosulfur compounds from model fuel and actual diesel. An oxidation study was carried out for model fuel and diesel, followed by solvent extraction using these synthesized DESs. The extraction efficiency for PAA/TTEG(1:2) and SAA/TTEG(1:2) was achieved as 50.16% and 38.89% for model fuel at a temperature of 30oC using a solvent to feed ratio of 1.0 while for diesel, it was 38% and 37%. However, it increased to 77%, 68%, and 54%, 73%, respectively, for PAA/TTEG(1:2) and SAA/TTEG(1:2) when the feedstocks were oxidized. These results showed better extraction performance of DES PAA/TTEG(1:2) than that of SAA/TTEG(1:2) at low-temperature 30oC using extractive combined oxidative desulfurization (ECODS). Hence, the DES synthesized using SAA and TTEG in the mole ratio of 1:2 works better as an extraction solvent for removing the organic sulfur compounds from fuels at low temperatures.
全世界都有一种特别的意识来清洁被污染的环境。环境污染主要是由温室气体、交通燃料排放等造成的。其中,运输燃料排放产生的含硫化合物对环境污染影响较大。它要求从运输燃料中去除这些含硫化合物。炼油厂使用加氢脱硫(HDS)工艺从燃料中减少这些含硫化合物。然而,HDS工艺需要高氢气压力和温度,这使得它具有成本效益。HDS法的另一种替代方法是通过溶剂萃取进行氧化脱硫,这需要低温操作条件。在这方面,深共晶溶剂(DESs)因其低成本的合成方法而受到研究人员的青睐,可以通过溶剂萃取法对运输燃料进行脱硫。本研究以苯基乙酸和水杨酸为氢键受体(HBAs),四乙二醇为氢键供体(HBD),摩尔比为1:2合成了DESs。用FTIR光谱对des进行了表征。测定了DESs的物理化学性质,如密度、粘度和折射率。利用合成的DESs从模型燃料和实际柴油中提取有机硫化合物。对模型燃料和柴油进行了氧化研究,然后用合成的DESs进行了溶剂萃取。在温度为30℃、料液比为1.0的条件下,模型燃料对PAA/TTEG(1:2)和SAA/TTEG(1:2)的萃取效率分别为50.16%和38.89%,对柴油的萃取效率分别为38%和37%。PAA/TTEG(1:2)和SAA/TTEG(1:2)经氧化处理后,分别提高到77%、68%和54%、73%。结果表明,在低温30℃条件下,采用萃取剂联合氧化脱硫法(ECODS), DES PAA/TTEG(1:2)的萃取性能优于SAA/TTEG(1:2)。因此,以SAA和TTEG的摩尔比为1:2合成的DES作为低温脱除燃料中有机硫化合物的萃取溶剂效果较好。
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引用次数: 0
Properties of Additively Manufactured Platinum-Rhodium Alloys 增材制备铂铑合金的性能
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651323x16787270178522
T. Becker, T. Gries
Bushings made of platinum-rhodium alloys are a key component in glass fibre production. While bushings have grown in size and functionality since their introduction in the early 20th century, manufacturing constraints still limit their full potential. Both in terms of design and quality, traditional manufacturing methods such as milling, drilling and welding limit the potential of precious metal bushings. The technical feasibility of the use of additive manufacturing for the production of bushings is greatly dependent on the material properties. For the purpose of this work, an additively manufactured alloy consisting of 90 wt% platinum and 10 wt% rhodium (PtRh10) is investigated with regard to density, electrical resistivity, creep performance and the contact angle of E-glass on the PtRh10 samples.
由铂铑合金制成的衬套是玻璃纤维生产中的关键部件。虽然自20世纪初推出以来,衬套在尺寸和功能上都有所增长,但制造方面的限制仍然限制了它们的全部潜力。无论是在设计方面还是在质量方面,传统的制造方法,如铣削、钻孔和焊接,都限制了贵金属衬套的潜力。使用增材制造生产衬套的技术可行性在很大程度上取决于材料性能。为了这项工作的目的,研究了一种由90wt %铂和10wt %铑组成的增材制造合金(PtRh10)的密度、电阻率、蠕变性能和e -玻璃在PtRh10样品上的接触角。
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引用次数: 0
Utilization of Insect Gut as a Biosource for the Development of Future Biotransformation Processes 利用昆虫肠道作为生物资源促进未来生物转化过程的发展
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651323x16732719244908
Ayse Nur Akgedik, Gizem Oder, Cansu Erdem, Beyza Tutku Bıcakci, O. Bayraktar
Sustainability has been one of the main issues in the world in recent years. The decrease of resources in the world, along with the growing world population, and the resulting environmental waste, present a fairly significant problem. As an alternative solution to this problem, insects are put forward as an ideal resource. Due to the enzymes and microorganisms in their intestinal microbiota, the biotransformation processes of insects are capable of converting wastes, organic materials, and residues into valuable products that can be used for various industrial applications such as pharmaceuticals, cosmetics, functional food, etc. Some species of insects are in an advantageous position because of the simplicity of their life cycle and the ease of their production and feeding on organic materials to make them valuable products. Considering the sustainability perspective, utilization of the microorganisms or enzymes isolated from these microorganisms available in the microbiota of insects may allow novel insect-based biotransformation processes that promise a more sustainable world and novel green technologies.
可持续性是近年来世界上的主要问题之一。随着世界人口的增长,世界资源的减少,以及由此产生的环境浪费,提出了一个相当严重的问题。作为解决这一问题的另一种方法,昆虫被认为是一种理想的资源。由于昆虫肠道菌群中的酶和微生物,昆虫的生物转化过程能够将废物、有机物质和残留物转化为有价值的产品,可用于各种工业应用,如制药、化妆品、功能食品等。某些种类的昆虫处于有利地位,因为它们的生命周期简单,易于生产,并以有机材料为食,使其成为有价值的产品。考虑到可持续性的角度,利用昆虫微生物群中可获得的微生物或从这些微生物中分离出的酶可能会允许新的基于昆虫的生物转化过程,从而承诺更可持续的世界和新的绿色技术。
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引用次数: 0
“Practical Guidelines for the Chemical Industry: Operation, Processes, and Sustainability in Modern Facilities” 化学工业实用指南:现代设施的操作、过程和可持续性
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651323x16838888587238
Mahmud Juned
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引用次数: 0
In the Lab: The Use of Recovered Metal Complexes in Catalysis 在实验室中:回收金属配合物在催化中的应用
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651323x16838977749347
J. Matthey
Research in the group led by James Wilton‐Ely focuses on catalysis, imaging and sensing. All of this work involves d- and f-elements and is underpinned by the group’s wide-ranging expertise in synthesis. Collaborations with researchers in engineering, medicine and bioimaging allow these discoveries to be used to address major healthcare and sustainability challenges. Professor Wilton-Ely is the author of more than 100 publications and was the recipient of the 2021 Sir Geoffrey Wilkinson Award from the Royal Society of Chemistry for his work on metal-based carbon monoxide sensing. He has a strong interest in sustainability, having directed the MRes Green Chemistry course at Imperial College for over 12 years (2010–2022). He has published on the use of recovered metals in catalysis (1–5), the catalytic transformation of biomass to platform chemicals (6–11) and magnetically-recoverable nanoscale catalysts (12, 13). Elemental sustainability is a pressing concern for all researchers using precious metals and this has led Wilton-Ely to work with colleagues to explore the potential for using gold (3) and palladium (4, 5) complexes recovered from end-of-life products in catalysis.
由James Wilton‐Ely领导的研究小组专注于催化、成像和传感。所有这些工作都涉及d和f元素,并以该小组在合成方面的广泛专业知识为基础。与工程、医学和生物成像领域的研究人员合作,使这些发现能够用于解决主要的医疗保健和可持续性挑战。Wilton-Ely教授是100多篇出版物的作者,并因其在金属基一氧化碳传感方面的工作而获得了皇家化学学会颁发的2021年杰弗里·威尔金森爵士奖。他对可持续发展有着浓厚的兴趣,曾在帝国理工学院指导MRes绿色化学课程超过12年(2010-2022)。他发表了关于回收金属在催化中的应用(1-5),生物质催化转化为平台化学品(6-11)和磁性可回收纳米级催化剂(12,13)。元素的可持续性对所有使用贵金属的研究人员来说都是一个紧迫的问题,这使得Wilton-Ely和同事们一起探索利用从报废产品中回收的金(3)和钯(4,5)配合物进行催化的潜力。
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引用次数: 0
Synthesis and Characterization of Biochar Activated Carbon for Oil Spills Removal 生物炭活性炭去除溢油的合成与表征
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651324x17000531781388
Badar Mohammed Al-Nairi, D. Sri Maha Vishnu, A. Sri Hari Kumar, Mustafa Al Salmi, Sausan Al Yaqoobi, Mohammed Abdulhakim Al-Saadi, Ahmed Al-Harrasi
Activated carbon (AC) is an effective material for its various environmental and industrial applications. The characteristics and performance of AC is a result of interaction between source and method of preparation. In the current work, AC has been prepared from date seed wastes using microwave heating under nitrogen using basic (i.e., KOH) / acidic (i.e., H2SO4) chemical activating agents. The AC was characterised using XRD, SEM-EDX, TEM and TGA/DSC. XRD patterns of the AC in both the cases exhibited 3 peaks corresponding to the crystalline graphite form of carbon. SEM images of the freshly prepared carbons showed that the samples contained particles of various sizes including both nanoparticles as well as mm-range particles. DSC analysis showed that the samples exhibited endothermic reaction in low temperature ranges until 300 ◦C and exothermic reaction above this temperature. SEM analysis of the AC, separated into three different size ranges, showed significant etching of the surface of the carbon to yield porous structures. The AC produced using H2SO4 showed better adsorption capacity (9.2 g/g) when compared to that produced using KOH (7.7 g/g). We conclude that the AC prepared from dates seeds can find potential application in water purification and oil spill clean-up.
活性炭(AC)是一种有效的环保材料和工业材料。活性炭的特性和性能是原料和制备方法相互作用的结果。本研究采用碱性(如KOH) /酸性(如H2SO4)化学活化剂,在氮气条件下微波加热,以枣子渣为原料制备AC。采用XRD、SEM-EDX、TEM、TGA/DSC等手段对活性炭进行了表征。两种情况下AC的XRD谱图均显示出3个峰,对应于碳的结晶石墨形式。新制备的碳的SEM图像表明,样品中含有各种大小的颗粒,包括纳米颗粒和毫米范围的颗粒。DSC分析表明,样品在低温至300℃范围内表现出吸热反应,在此温度以上表现出放热反应。活性炭分为三个不同的尺寸范围,SEM分析表明碳表面有明显的蚀刻产生多孔结构。H2SO4制备的活性炭吸附量为9.2 g/g, KOH制备的活性炭吸附量为7.7 g/g。因此,从枣籽中制备的AC在水净化和溢油清理方面具有潜在的应用前景。
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引用次数: 0
Quantitative Thermal Imaging 定量热成像
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651323x16685950005819
R. Simpson, J. McMillan, M. Hayes, Wesley Bond, V. Panicker, S. Korniliou, G. Machin
Quantitative thermal imaging, the measurement of temperature by use of thermal imaging devices, is reviewed here from a metrological perspective with a focus on measurement confidence and system application to fields such as condition monitoring and healthcare diagnostics. Thermal imaging has seen greatly increased application for the measurement of temperature following dramatic improvements in practicality and price. Selected thermal imaging systems are reviewed here by providing some example measurements outputs from devices, highlighting their outcomes on measurement confidence and impact on practical use, such as in condition monitoring and healthcare diagnostics.
定量热成像,通过使用热成像设备测量温度,这里从计量的角度进行了回顾,重点是测量可信度和系统应用领域,如状态监测和医疗保健诊断。随着实用性和价格的显著提高,热成像在温度测量方面的应用大大增加。本文通过提供设备的一些示例测量输出来回顾选定的热成像系统,强调其测量结果的可信度和对实际使用的影响,例如在状态监测和医疗保健诊断中。
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引用次数: 0
Guest Editorial: Emissions Standards Delivering Cleaner Air on the Road to Net Zero 嘉宾评论:排放标准在实现零排放的道路上提供更清洁的空气
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651323x16790500384938
J. Goodwin
Clean air. It should be a basic right for everyone, yet the World Health Organization estimates that in 2019, ambient air pollution in cities and rural areas caused 4.2 million premature deaths worldwide (1). Heart disease, stroke and pulmonary disease are the key causes of premature deaths related to poor air quality and this burden falls largely on people living in low- to middle-income countries.
清洁空气。这应该是每个人的一项基本权利,但世界卫生组织估计,2019年,城市和农村地区的环境空气污染导致全球420万人过早死亡(1)。心脏病、中风和肺部疾病是与空气质量差有关的过早死亡的主要原因,这一负担主要落在中低收入国家的人们身上。
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引用次数: 0
Knowledge Structure of New Energy Vehicle Policy Research: Mapping Analysis and Future Research Agenda 新能源汽车政策研究的知识结构:映射分析与未来研究议程
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651324x16873481731553
Ruqia Shaikh, A. Qazi, Xiaoli Wang, D. Kassi
Globally, transport is responsible for 23% of energy-related carbon dioxide emissions, and 80% of these emissions are attributable to road transport. Significant transformations - including extensive electrification of the sector - are necessary to achieve the climate change goals. To understand the new energy vehicle (NEV) policy research, we explore the status, knowledge base, and research frontiers of NEV policy research by studying 355 papers collected from the Web of Science Core Collection database. We map NEV policy research trends and knowledge structure development using knowledge domain technology and bibliometric techniques. The knowledge base analysis shows that (1) NEV policy formation and evaluation, (2) policy incentives and consumer adoption, and (3) consumer preferences towards NEV adoption are all essential knowledge foundations in NEV policy research and development. The efficiency of NEV policy, cost-effectiveness of alternative fuel vehicles (AFVs), consumer preferences for NEV adoption, hydrogen energy and fuel cell vehicles, climate policy and CO2 emissions are five main lines of research in NEV policy studies. With the highest publications from Tsinghua University, China is the most active country in NEV policy research. Energy Policy, Sustainability, and Journal of Cleaner Production are the core journals, and energy and fuels and environmental sciences are the core disciplines of NEV policy research. The findings of this analysis help policymakers and researchers to navigate the literature on NEV, provide a clear map of existing works, identify the gaps and recommend promising avenues for future studies.
在全球范围内,交通运输占能源相关二氧化碳排放量的23%,其中80%来自公路运输。要实现气候变化目标,必须进行重大变革,包括该行业的广泛电气化。为了解新能源汽车政策研究,本研究通过对Web of Science Core Collection数据库中355篇论文的研究,探讨新能源汽车政策研究的现状、知识基础和研究前沿。利用知识域技术和文献计量学技术,绘制了新能源汽车政策研究趋势和知识结构发展趋势。知识库分析表明:(1)新能源汽车政策形成与评价;(2)政策激励与消费者采用;(3)消费者对新能源汽车采用的偏好都是新能源汽车政策研究与制定的重要知识基础。新能源汽车政策的效率、替代燃料汽车(afv)的成本效益、消费者对新能源汽车采用的偏好、氢能源和燃料电池汽车、气候政策和二氧化碳排放是新能源汽车政策研究的五大主线。中国是新能源政策研究最活跃的国家,清华大学的论文数量最多。《能源政策》、《可持续发展》和《清洁生产学报》是新能源汽车政策研究的核心期刊,能源与燃料、环境科学是新能源汽车政策研究的核心学科。这一分析的发现有助于决策者和研究人员浏览有关新能源汽车的文献,为现有工作提供清晰的地图,确定差距并为未来的研究推荐有希望的途径。
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引用次数: 0
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Johnson Matthey Technology Review
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