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Extension of a Zero-Dimensional Mixing-Controlled Combustion Model for the Development of a NOx–Free System Based on the Oxy-Combustion Concept 基于全氧燃烧概念的无nox系统开发的零维混合控制燃烧模型的扩展
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651324x16963284171824
José R. Serrano, J. Javier López, Jaime Martín, Gabriela Bracho
Oxy-combustion is a promising concept to achieve an extremely clean combustion, independently of the fuel type, because, on the one hand, it is a NOx-free combustion and, on the other hand, the CO2 produced during combustion can be easily captured once the water vapor is removed from the exhaust gases stream, consequently allowing also carbon neutral operation. An existing 0D, mixing-controlled combustion model, developed for a standard diesel combustion scenario, has been adapted to the oxy-fuel combustion scenario. Initially, the model over-predicted the heat release at the end of the combustion process. The main model adaptation was to modify the relationship between the average YO2 and the effective YO2 (i.e. the one of the charge actually entrained by the spray), to be consistent with the significant increase in compression ratio needed in the oxy-fuel context. As a result, a model able to correctly predict the combustion behaviour at any operating condition has been obtained, which finally represents a very suitable tool to assist in the concept development.
氧燃烧是一个很有前途的概念,可以实现非常清洁的燃烧,与燃料类型无关,因为一方面,它是一种无nox的燃烧,另一方面,燃烧过程中产生的二氧化碳可以很容易地捕获,一旦水蒸气从废气流中除去,因此也允许碳中和操作。现有的0D混合控制燃烧模型是为标准柴油燃烧场景开发的,已经适应了全氧燃料燃烧场景。最初,该模型过度预测了燃烧过程结束时的热量释放。主要的模型调整是修改平均YO2和有效YO2(即喷雾实际携带的电荷之一)之间的关系,以与纯氧燃料环境中所需的压缩比的显着增加保持一致。因此,一个能够正确预测在任何工况下燃烧行为的模型已经获得,这最终代表了一个非常合适的工具来协助概念的发展。
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引用次数: 0
Hydrogen Use in a Dual-Fuel Compression-Ignition Engine with Alternative Biofuels 氢在双燃料压缩点火发动机与替代生物燃料中的应用
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651324x16963489202714
José Rodríguez-Fernández, Ángel Ramos, Víctor M. Domínguez, Blanca Giménez, Miriam Reyes, Juan J. Hernández
Recent progress has been made towards decarbonization of transport, which accounts for one quarter of the global carbon dioxide emissions. For the short-medium term, new EU and national energy and climate plans agree on a strategy based on the combination of increasing shares of electric vehicles with the promotion of sustainable fuels, especially if produced from residual feedstock and routes with low or zero net carbon emission. Hydrogen stands out among these fuels for its unique properties. This work analyses the potential of using hydrogen in a dual-fuel, compression-ignition engine running with three diesel-like fuels (conventional fossil diesel, advanced biodiesel and hydrotreated vegetable oil-HVO) and different hydrogen energy substitution ratios. The results were confronted with conventional diesel operation, revealing that dual-fuel combustion with hydrogen demands higher EGR rates and more advance combustion, leading to a remarked reduction of NOx emission at the expense of a penalty in energy consumption due mainly to unburnt hydrogen and wall heat losses. Unreacted hydrogen was ameliorated at high load. At low load, the use of biodiesel dual combustion permitted higher hydrogen substitution ratios and higher efficiencies than diesel and HVO.
最近在交通运输脱碳方面取得了进展,交通运输占全球二氧化碳排放量的四分之一。在中短期内,新的欧盟和国家能源和气候计划达成了一项战略,该战略基于增加电动汽车的份额与促进可持续燃料的结合,特别是如果由剩余原料和低或零净碳排放的路线生产。氢以其独特的性质在这些燃料中脱颖而出。本研究分析了在使用三种类柴油燃料(传统化石柴油、先进生物柴油和加氢处理植物油)和不同氢能替代比的双燃料压缩点火发动机中使用氢的潜力。研究结果与传统柴油工况进行了对比,结果表明,氢双燃料燃烧需要更高的EGR率和更早的燃烧,从而显著减少了氮氧化物排放,但代价是能源消耗的损失,主要是由于未燃烧的氢和壁面热损失。未反应氢在高负荷下得到改善。在低负荷情况下,生物柴油双燃烧比柴油和HVO具有更高的氢替代率和效率。
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引用次数: 0
A Review of the Sources, Environmental Behaviors, and Human Health of Atmospheric Microplastics 大气中微塑料的来源、环境行为和人体健康研究进展
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651324x16964141254874
Bowen Zhang, Rencheng Zhu, Yunjing Wang
The article places emphasis on the latest advancements in this field, particularly focusing on indoor and outdoor microplastic (MP) pollution, including their emission, behavior, and potential health hazards. Gaining an in-depth understanding of these factors is crucial for devising effective strategies to mitigate the impact of microplastics (MPs) on human health and the environment. Indoor MP abundance is generally higher than outdoor levels, with textiles serving as a primary source of indoor airborne MPs. Traffic-derived MP particles, MP fibers in residential areas, agricultural plastic mulch, marine MPs, and landfill sites appear to be contributors to outdoor atmospheric MP pollution. Factors such as wind direction, wind speed, precipitation, and snowfall, along with the physical characteristics and secondary suspension of MPs, collectively influence their behavior, distribution, and fate. Inhalation and ingestion constitute the main exposure pathways for airborne MPs, potentially leading to health issues like respiratory inflammation. Therefore, gaining a deeper insight into the behavior and impact mechanisms of atmospheric MPs aids in formulating effective risk management strategies to safeguard human health and maintain environmental sustainability.
本文重点介绍了该领域的最新进展,特别是室内和室外微塑料(MP)污染,包括其排放,行为和潜在的健康危害。深入了解这些因素对于制定有效战略以减轻微塑料对人类健康和环境的影响至关重要。室内MP丰度通常高于室外水平,纺织品是室内空气中MP的主要来源。交通产生的多聚氰胺颗粒、居民区的多聚氰胺纤维、农用塑料地膜、海洋多聚氰胺和垃圾填埋场似乎是造成室外大气多聚氰胺污染的原因。风向、风速、降水和降雪量等因素,以及MPs的物理特性和次生悬浮,共同影响着它们的行为、分布和命运。吸入和摄入是空气中多磺酸盐的主要暴露途径,可能导致呼吸道炎症等健康问题。因此,深入了解大气MPs的行为和影响机制有助于制定有效的风险管理策略,以保障人类健康和保持环境的可持续性。
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引用次数: 0
Mechanochemistry: A Green and Fast Method to Prepare A New Generation of Metal Supported Catalysts 机械化学:一种绿色快速制备新一代金属负载催化剂的方法
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651323x16933888986996
Maila Danielis, Sara Colussi, Núria J. Divins, Lluís Soler, Alessandro Trovarelli, Jordi Llorca
In this review, we report on recent advances in the use of mechanochemistry to synthesize new catalytic materials. We report recent results obtained by our groups where a rational design of the milling parameters led to the synthesis of advanced materials with novel properties such as unconventional arrangements of metals on the surface of oxide support materials, highly dispersed metals or the stabilization of species in particular oxidation states. These properties resulted in superior catalytic performances of the mechanochemically-synthesized catalysts compared to their counterparts prepared by traditional impregnation methods. To illustrate these advances, we review the progress made in two important fields of catalysis where noble metals are used: (i) emission-control catalysis using Pd-based materials, and (ii) the development of photocatalysts to produce hydrogen based on Au and Pd materials.
本文综述了机械化学在合成新型催化材料方面的最新进展。我们报告了我们小组最近获得的结果,其中合理设计的铣削参数导致合成具有新特性的先进材料,例如氧化物支撑材料表面的非常规金属排列,高度分散的金属或特定氧化状态下物种的稳定。这些特性使得机械化学合成的催化剂的催化性能优于传统浸渍法制备的催化剂。为了说明这些进展,我们回顾了贵金属在催化的两个重要领域的进展:(i)使用钯基材料的排放控制催化,以及(ii)基于金和钯材料的光催化剂的发展。
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引用次数: 1
X-Ray Computed Tomography for Failure Mechanism Characterisation within Layered Pouch Cells: Part II 层状袋状细胞内失效机制特征的x射线计算机断层扫描:第二部分
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651323x16686891950941
Drasti Patel, H. Reid, Sarah Ball, D. Brett, P. Shearing
In Part I (1), the failure response of a 1 Ah layered pouch cell with a commercially available nickel manganese cobalt (NMC) cathode and graphite anode at 100% state of charge (SOC) (4.2 V) was investigated for two failure mechanisms: thermal and mechanical. The architectural changes to the whole-cell and deformations of the electrode layers are analysed after failure for both mechanisms. A methodology for post-mortem cell disassembly and sample preparation is proposed and demonstrated to effectively analyse the changes to the electrode surfaces, bulk microstructures and particle morphologies. Furthermore, insights into critical architectural weak points in LIB pouch cells, electrode behaviours and particle cracking are provided using invasive and non-invasive X-ray computed tomography techniques. The findings in this work demonstrate methods by which LIB failure can be investigated and assessed.
在第一部分(1)中,研究了在100%荷电状态(4.2 V)下,采用镍锰钴(NMC)阴极和石墨阳极的1 Ah层状袋状电池在热、机械两种失效机制下的失效响应。分析了两种机构失效后整个细胞的结构变化和电极层的变形。提出并演示了一种用于死后细胞拆卸和样品制备的方法,以有效分析电极表面,体微结构和颗粒形态的变化。此外,利用侵入性和非侵入性x射线计算机断层扫描技术,深入了解LIB袋状细胞的关键结构弱点、电极行为和颗粒开裂。这项工作的发现证明了可以调查和评估LIB故障的方法。
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引用次数: 0
Guest Editorial: The Continuing Importance of Platinum Group Metals 嘉宾评论:铂族金属的持续重要性
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651323x16850003560865
Emma Schofield
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引用次数: 0
Potential of Hydrogen Internal Combustion Engine for the Decarbonized Passenger Vehicle 氢内燃机在脱碳乘用车中的潜力
4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651324x16965074891718
Seung Woo Lee, Hong-kil Baek, Kyeonghyeon Lee
CO2 regulations are becoming very stringent due to the goal of reducing greenhouse gases and achieving carbon neutrality. It has already become a common situation that electric vehicles are emerging as eco-friendly power systems rather than vehicles equipped with conventional internal combustion engines, and their share in the market is increasing. However, even with an internal combustion engine, CO2 can be drastically reduced if a carbon-free fuel such as hydrogen is used. Raw NOx emissions can be overcome to a certain level through ultra-lean burn operation, but in order to balance the amount of hydrogen and air in the limited space of combustion chamber, a drop in the engine's maximum output should be accepted. Hyundai Motor Company also previously developed an engine using hydrogen fuel, but was unable to progress to mass production. Since then, hybrid technology has become popular, and with the development of hydrogen injection devices, an era has arrived where the possibility of mass production can be increased. and for this reason, various studies on internal combustion engines using hydrogen fuel based on existing SI engines or CI engines are rapidly increasing recently. In this study, a hydrogen fuel engine was designed and manufactured based on the mass produced gasoline spark ignition engine. CO2 level was confirmed from initial performance evaluation, and it is found that raw NOx levels and maximum power were in a trade-off relationship with each other under same air-charging system application. In addition, the method to improve maximum engine torque was verified while maintaining the raw NOx level, and the maximum engine power improvement level was confirmed when raw NOx emissions were allowed to increase. Thereby it was shown that the potential of the carbon-neutral internal combustion engine.
由于减少温室气体和实现碳中和的目标,二氧化碳法规变得非常严格。电动汽车已经成为代替传统内燃机汽车的环保动力系统,其市场占有率正在增加。然而,即使使用内燃机,如果使用氢等无碳燃料,二氧化碳也可以大幅减少。通过超稀薄燃烧操作,可以将NOx的原始排放克服到一定程度,但为了平衡燃烧室有限空间内氢气和空气的数量,应该接受发动机最大输出的下降。现代汽车也曾开发过氢燃料发动机,但未能大规模生产。从那时起,混合动力技术开始流行,随着氢注入装置的发展,大规模生产可能性增加的时代已经到来。因此,最近在现有SI发动机或CI发动机的基础上,对氢燃料内燃机的各种研究正在迅速增加。在量产汽油火花点火发动机的基础上,设计制造了氢燃料发动机。从初始性能评估中确定了CO2水平,发现在相同的充气系统应用下,原始NOx水平和最大功率之间存在权衡关系。此外,验证了在保持NOx原始排放水平的情况下提高发动机最大扭矩的方法,以及在允许NOx原始排放增加的情况下,确定了发动机最大功率提高水平。由此可见,碳中性内燃机的潜力。
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引用次数: 0
Guest Editorial: Facility Process Safety and Control 嘉宾评论:设施过程安全与控制
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651323x16679225966590
J. Pearce
Temperature is a fundamental quantity relevant to almost all spheres of human endeavour. It is measured and controlled in a very wide range of applications, for example in combustion (engines, heating), heat treatment of high value components, healthcare (fever screening), meteorology and climate monitoring. Measurement and control of industrial process temperature in particular is key to maximising product quality, optimising energy efficiency, reducing waste and minimising carbon dioxide and other harmful emissions. It is also essential for ensuring safety; an accurate measure of temperature minimises the risk of operating outside the required process envelope (for example in nuclear power generation). There are several settings in which recent innovations have brought about significant improvements in thermometry, and these are described in this themed issue. Also discussed in this issue is the assessment and optimisation of safety in lithium-ion batteries, which is also a very important topic given the ubiquity of those devices, and testing for corrosion in chemical process plants, again a widespread issue of great relevance to many practitioners.
温度是一个基本的量,几乎关系到人类活动的所有领域。它在非常广泛的应用中进行测量和控制,例如燃烧(发动机,加热),高价值组件的热处理,医疗保健(发烧筛查),气象和气候监测。特别是工业过程温度的测量和控制是最大限度地提高产品质量,优化能源效率,减少浪费和减少二氧化碳和其他有害排放的关键。这对确保安全也是必不可少的;精确的温度测量可以最大限度地降低在要求的过程范围之外运行的风险(例如在核能发电中)。在一些环境中,最近的创新带来了测温方面的重大改进,这些都将在本主题问题中进行描述。本问题还讨论了锂离子电池的安全性评估和优化,这也是一个非常重要的话题,因为这些设备无处不在,以及化学加工厂的腐蚀测试,这也是一个与许多从业者密切相关的广泛问题。
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引用次数: 0
“PGM Market Report May 2023” 《2023年5月PGM市场报告》
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651323x16856083453770
A. Cowley
Johnson Matthey’s annual review of the platinum group metal (pgm) markets was published on 15th May 2023, providing an outlook for pgm supply and demand for 2023. The report contains a comprehensive review of developments in the automotive market, covering production and powertrain trends and their implications for pgm use as well as an update on future emissions legislation. It also features an in-depth discussion of the ruthenium and iridium markets in view of increasing interest in the use of these metals in the net zero transition.
庄信万丰于2023年5月15日发布了对铂族金属(pgm)市场的年度回顾,提供了2023年铂族金属供需前景。该报告全面回顾了汽车市场的发展,涵盖了生产和动力系统趋势及其对pgm使用的影响,以及未来排放立法的最新进展。报告还深入讨论了钌和铱市场,因为人们对在净零过渡中使用这些金属越来越感兴趣。
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引用次数: 4
Porous Metallic Implants from Additive Manufacturing to Biocorrosion: A Review 从增材制造到生物腐蚀的多孔金属植入物:综述
IF 2.3 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2023-01-01 DOI: 10.1595/205651324x16826780236175
Salwa El Baakili, Patrick Munyensanga, Meriame Bricha, K. El Mabrouk
The improved bulk and surface function of manufactured implants has advanced implantation procedures, leading to a decline in surgical risks. Most of the current techniques discussed in the literature are related to additive manufacturing (AM) of lightweight implants based on reliable, precise, flexible scaffolds and capable of mimicking bone properties while incorporating multi-physics features. Furthermore, these techniques have evolved in the production of a variety of biocompatible materials. AM has progressed beyond prototype to full-scale manufacturing of metals, polymers, and ceramic products. However, metallic implants often fail in vivo due to biocorrosion and deterioration, limiting implant longevity. This study reviewed current trends and approaches to enhancing the surface corrosion resistance of porous metallic implants and the effect of interfacial films on biological activity. The art of porous metallic implants manufactured by additive manufacturing and their biocorrosion behavior are discussed. This review also evaluates future trends and perspectives in additively manufactured synthetic orthopedic implants porous with enhanced surface morphology.
人造植入物的体积和表面功能的改进使得植入过程更加先进,从而降低了手术风险。目前文献中讨论的大多数技术都与增材制造(AM)轻量级植入物有关,这些植入物基于可靠、精确、灵活的支架,能够模仿骨骼特性,同时结合多物理场特征。此外,这些技术已经发展到生产各种生物相容性材料。增材制造已经从原型发展到金属、聚合物和陶瓷产品的全面制造。然而,由于生物腐蚀和变质,金属种植体经常在体内失效,限制了种植体的使用寿命。本文综述了提高多孔金属植入物表面耐腐蚀性能的研究现状和方法,以及界面膜对生物活性的影响。讨论了增材制造多孔金属植入物的工艺及其生物腐蚀性能。本综述还评估了增材制造多孔表面形态增强的合成骨科植入物的未来趋势和前景。
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引用次数: 0
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Johnson Matthey Technology Review
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