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PENGEMBANGAN POTENSI INDIGOFERA DENGAN PROSES KOMBINASI FERMENTASI AEROB-ANAEROB SEBAGAI ZAT WARNA ALAMI BATIK 开发不作为作为蜡染天然物质的空气-再氧发酵混合物
Pub Date : 2019-01-25 DOI: 10.33536/JCPE.V3I2.255
Azafilmi Hakiim, D. A. Sari, Vita Efelina
Teknik pewarnaan kain batik dapat dilakukan dengan zat warna sintetik atau zat warna alam (ZWA). Keberadaan banyaknya permintaan konsumen, mampu menggerser keberadaan zat warna alam. Keunggulan zat warna sintetik antara lain memberikan keuntungan ekonomi, efisiensi waktu dan warna yang dihasilkan beragam. Kelemahan penggunaan zat warna sintetik adalah dampak lingkungan yang dihasilkan. Kandungan bahan sintetik sukar diuraikan sehingga perlu diupayakan kembali penggunaan ZWA . Salah satunya berasal dari tanaman perdu yaitu indigofera tinctoria. Tujuan penelitian ini adalah sejauh mana pengaruh konsentrasi daun indigofera pada beda perlakuan proses fermentasi (aerob dan anaerob) dan perlakuan penggunaan fiksasi terhadap daya tahan pencucian, daya tawahan luntur dan daya tahan sinar matahari.Bahan baku sampel yaitu kain katun dan sutera yang dicelup dengan ZWA fermentasi indigofera pada konsentrasi daun indigo 1kg/5L dan 1kg/10L, kemudian dilanjutkan dengan pencelupan fiksasi/non fiksasi sebagai variable bebas dan variable terikat adalah uji daya tahan. Hasil uji ketahanan daya tahan pencucian, daya tahan luntur dan daya tahan sinar mtahari menunjukkan bahwa penggunaan konsentrasi memiliki kategori nilai yang tidak jauh berbeda. Sedangkan pada variable perlakuan fiksasi/non fiksasi diperoleh kategori nilai terbaik rata-rata pada perlakuan fermetasi aerob
蜡染布的染色技术可以用合成染料或天然染料(ZWA)来完成。消费者需求的存在,自然色彩的存在。合成染料的好处包括经济效益、时间效率和各种颜色的产生。合成色素的使用弱点是环境的结果。合成材料的含量很难破译,因此有必要重新使用ZWA。其中一种来自金雀花植物involfera tinctoria。本研究的目的是,不高压叶的浓度如何影响发酵过程(aerob和anaerob)的影响,以及对洗涤耐久性、手工艺下降和阳光耐久性的固化使用。在靛蓝1公斤/5L和1kg/10公斤/10公斤/10升的叶子上进行未经发酵的棉质发酵,然后以可变自由和可变结合的可变浸没成固态/非固态为耐力测试。洗涤耐久性、耐久性降低和磁共振成像性能测试的结果表明,浓度的使用并没有太大的不同类别。而在异化的固定/非固定治疗中,空气中发酵治疗的平均得分类别为最高
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引用次数: 0
Corrosion Failure Analysis of Elbow in LPG Desulfurization Unit LPG脱硫装置弯头腐蚀失效分析
Pub Date : 2019-01-01 DOI: 10.35248/2157-7048.19.10.395
Jianwen Z, Guoqing S, Chuansheng W
The elbow plays a crucial role in changing the flow direction of the medium in pipeline system and is one of the most commonly used pipeline components in the oil and gas transportation. This paper focuses on the corrosive failure mechanism of the elbow of regeneration tower of LPG desulfurization unit in a refinery. Aiming at the failure elbow, based on the macro and micro perspectives, the physical laws of the inner layer of the elbow, including the distribution of corrosion holes and wall thickness, are summarized and analyzed. The further characterization methods were used to study the corrosion mechanism, including mechanical properties, metallographic examination, X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) and energy spectrum analysis (EDS). Taking the thief hole as center, the elbow was divided into 4 rows. It is found that the maximum diameter was 21.1 mm while the minimum was 7.76 mm, and the vast majority of holes were 16 ~ 19 mm. The average size of the middle section was larger, meanwhile, possessed most holes over 19 mm. The corrosion thickness first increased then decreased along the flow direction and reached the maximum in completely destroyed area of the 1st and 2nd row. The corrosion thickness increased gradually along the flow direction of the 3rd and 4th row. Erosion corrosion is the main cause of elbow failure. Fluid erosion plays a dominant role in the failure process while electrochemical corrosion plays a dominant role in the formation of corrosion holes. Besides, the presence of heat-stable salts (HSS) also aggravates the corrosion of elbow.
弯头在管道系统中起着改变介质流动方向的关键作用,是油气输送中最常用的管道部件之一。对某炼油厂LPG脱硫装置再生塔弯管腐蚀失效机理进行了研究。针对失效弯头,从宏观和微观两个角度,总结和分析了弯头内层的物理规律,包括腐蚀孔分布和壁厚。采用力学性能、金相检验、x射线衍射分析(XRD)、扫描电镜(SEM)和能谱分析(EDS)等进一步表征方法研究了腐蚀机理。以贼洞为中心,将肘部分成4排。结果表明,孔的最大直径为21.1 mm,最小直径为7.76 mm,绝大多数孔的直径为16 ~ 19 mm。中间截面的平均尺寸较大,孔洞大于19 mm的居多。腐蚀厚度沿流动方向先增大后减小,在第1排和第2排完全破坏区达到最大值。腐蚀厚度沿第3排和第4排流动方向逐渐增大。冲蚀腐蚀是弯管失效的主要原因。流体侵蚀在破坏过程中起主导作用,电化学腐蚀在腐蚀孔的形成中起主导作用。此外,热稳定盐(HSS)的存在也加剧了弯头的腐蚀。
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引用次数: 0
The Acid and Radiation Stability of Some Commercial Ion Exchangers 一些商业离子交换剂的酸稳定性和辐射稳定性
Pub Date : 2019-01-01 DOI: 10.35248/2157-7048.19.10.394
B. G., E. H., Emmott Jd
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引用次数: 0
A Numerical Model for Bubble Column Reactors: Prediction of the Fractional Gas Holdup by the Implementation of the Drift-Flux Model 气泡塔反应器的数值模型:用漂移通量模型预测分数气含率
Pub Date : 2019-01-01 DOI: 10.35248/2157-7048.19.10.396
A. Bahramian, S. Elyasi
Comprehensive knowledge of hydrodynamics inside a reactor is crucial for the design and scale-up of bubble columns. Fractional gas holdup (αg) is an important parameter that should be obtained for the design of bubble column reactors. The estimation of this parameter depends mainly on experimental procedures. Drift-flux theory is one of the most practical and accurate models for calculating the gas holdup. Although many researchers have studied bubble column reactors, because of the limits of the experimental setting, there are few studies that have operated over a wide range of superficial gas velocities. In this work, a transient 3-D numerical simulation of upward air-water flow in the bubble column was performed over a wide range of superficial gas velocities (0.025-0.4 m/s) using the Eulerian-Eulerian model. The effect of the superficial gas velocity on the flow pattern was simulated, and two-phase flow regimes were classified into homogeneous, transition and heterogeneous regimes. Considering the importance of the drift-flux model, the values of the distribution parameter and the drift velocity were computed according to their definitions using the cross-sectional gas holdup and velocity profiles obtained via computational flow dynamic simulation. The results were verified against the experimental data, and a correlation is proposed for predicting the gas holdup.
反应器内流体力学的全面知识对于气泡塔的设计和放大是至关重要的。分数气含率(αg)是汽泡塔反应器设计的一个重要参数。该参数的估计主要取决于实验程序。漂移通量理论是计算气含率最实用、最精确的模型之一。尽管许多研究人员已经研究过气泡塔反应器,但由于实验设置的限制,很少有研究在大范围的表面气速范围内进行操作。在这项工作中,使用欧拉-欧拉模型对气泡柱中向上的空气-水流动进行了大范围的表面气体速度(0.025-0.4 m/s)的瞬态三维数值模拟。模拟了表面气速对两相流型的影响,并将两相流型划分为均匀型、过渡型和非均匀型。考虑到漂移通量模型的重要性,利用计算流动动力学模拟得到的横截面气含率和速度剖面,根据其定义计算了分布参数和漂移速度的取值。用实验数据对结果进行了验证,并提出了预测含气率的相关性。
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引用次数: 1
Ionic Liquid-Based Process Development for Cobalt Recovery from Aqueous Streams 基于离子液体的水相钴回收工艺开发
Pub Date : 2019-01-01 DOI: 10.35248/2157-7048.19.10.397
E. Othman, A. V. D. Ham, H. Miedema, S. Kersten
Using the ionic liquid [P8888 +][Oleate-], liquid-liquid extraction has been studied to recover Co2+ from water. Extractionregeneration experiments were followed during five consecutive cycles with Na2CO3(aq) as regeneration solution. Over 99% of Co2+ was extracted and using 0.7-1 M Na2CO3(aq) the extracted Co2+ was recovered for 99% in the form of CoCO3(s). Co2+ transfer shifted from ion-pair extraction in the first cycle to ion-exchange in the successive cycles. Thus, the measurement of a single extraction–regeneration cycle is not sufficient to perceive conclusive information about the steady-state conditions of the process. In the context of the feasibility of the technology, four key aspects are addressed: extraction efficiency, recovery of the IL, loss of the IL, and the end product. Synopsis Cobalt extraction from aqueous using ionic liquid [P8888 +][oleate-] and cobalt recovery applying Na2CO3 solution as an efficient and sustainable regeneration strategy since it provides interesting end product for market with high regeneration efficiency.
采用离子液体[P8888 +][油酸盐-],研究了液-液萃取法回收水中Co2+。以Na2CO3(aq)为再生液,连续5次进行萃取再生实验。在0.7 ~ 1 M Na2CO3(aq)条件下,Co2+以CoCO3(s)的形式回收率达到99%以上。Co2+的转移由第一个循环的离子对萃取转变为后续循环的离子交换。因此,单个提取-再生循环的测量不足以感知有关该过程稳态条件的结论性信息。在该技术可行性的背景下,解决了四个关键方面:提取效率,IL的回收,IL的损失和最终产品。离子液体[P8888 +][油酸盐-]从水中提取钴,使用Na2CO3溶液回收钴是一种高效和可持续的再生策略,因为它以高再生效率为市场提供了有趣的最终产品。
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引用次数: 2
Synthesis and Evaluation of Properties of a Novel Cationic Waterborne Polyurethane Finishing Agent 一种新型阳离子水性聚氨酯整理剂的合成及性能评价
Pub Date : 2019-01-01 DOI: 10.35248/2157-7048.19.10.398
K. Ismoilov, W. Akram, S. Chauhan, Khilola Ergasheva, R. Artikboeva, Zulaykho Islomova, H. Quan
There is a cationic group that makes sure waterborne polyurethane self-emulsify on the main or side chain of cationic waterborne polyurethane (CWPU), which brings excellent function to cationic polyurethane, simultaneously it reduces water resistance. In this research, the good stability of CWPU was prepared as well as the water resistance and softness of cationic waterborne polyurethane film was improved. Elasticity, extensibility, weight gain rate, contact angle, TG, and structure of polyurethane had been tested and evaluated. Also, emulsion stabilities of polyurethane were tested, including storage stability, high-temperature stability, freeze-thaw stability, electrolyte stability, acid stability, and dilution stability; In addition to that, particle size and its distribution were tested. The test showed that the emulsion stability of polyester polyurethane illustrated a good result, while the mechanical property, water resistance, and water repellency were poor. Moreover, mechanical property and water resistance of polyether polyurethane film were good, but high-temperature stability, acid and alkali resistant, and water repellency of emulsion showed poor. For the synthesis of polyurethane, mixed soft segments of polyester (PE2348) and polyether (ZC330) were used, when mass ratio of (PE2348) to (ZC330) is not less than 1, that helped to improve the emulsion stabilities, increased contact angle, decreased particle size. But the water-resistance of film weakened when mass ratios of PE2348 to ZC330 were increased and the mechanical property was poorer. TG showed that thermal stability became poor. The introduction of hydrophilic chain extender (N120) can reduce the water resistance and water repellency of polyurethane. When the mass fraction of N-methyl diethanolamine (MDEA) was about 6% to 7%, the smallest particle size was 61 nm, and the water repellency was larger. The increase of MDEA content would reduce the water-resistance of the film. Finally the effect of hydrophilic chain extender on waterborne polyurethane was studied.
在阳离子型水性聚氨酯(CWPU)的主链或侧链上存在保证水性聚氨酯自乳化的阳离子基团,使阳离子型聚氨酯具有优异的性能,同时降低了水性聚氨酯的耐水性。本研究制备了具有良好稳定性的CWPU,提高了阳离子水性聚氨酯膜的耐水性和柔软性。对聚氨酯的弹性、延伸性、增重率、接触角、TG和结构进行了测试和评价。对聚氨酯的乳液稳定性进行了测试,包括贮存稳定性、高温稳定性、冻融稳定性、电解质稳定性、酸稳定性和稀释稳定性;此外,还测试了颗粒大小及其分布。试验表明,聚酯聚氨酯的乳液稳定性较好,但力学性能、耐水性和拒水性较差。聚醚聚氨酯薄膜的力学性能和耐水性较好,但乳液的高温稳定性、耐酸碱性和拒水性较差。在合成聚氨酯时,采用聚酯(PE2348)和聚醚(ZC330)的混合软段,当(PE2348)与(ZC330)的质量比不小于1时,有助于提高乳液稳定性,增加接触角,减小粒径。但随着PE2348与ZC330质量比的增加,膜的耐水性减弱,力学性能变差。热重分析表明热稳定性变差。引入亲水扩链剂N120可以降低聚氨酯的耐水性和拒水性。当n -甲基二乙醇胺(MDEA)的质量分数为6% ~ 7%时,最小粒径为61 nm,防水性较大。MDEA含量的增加会降低膜的耐水性。最后研究了亲水扩链剂对水性聚氨酯的影响。
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引用次数: 6
High performance phosphite ligands containing various numbers of structural units for n-regioselective hydroformylation of olefins 含有不同数量结构单元的高性能亚磷酸酯配体用于烯烃的n-区域选择性氢甲酰化
Pub Date : 2018-11-13 DOI: 10.4172/2157-7048-C2-015
Baoxin Zhang, D. Selent, Armin Börner
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引用次数: 0
Experimental study on diffusion combustion of high-speed hydrogen round microjets. Part I: Attach flame in subsonic flow 高速氢圆微射流扩散燃烧实验研究。第一部分:在亚音速流动中附加火焰
Pub Date : 2018-11-13 DOI: 10.4172/2157-7048-C2-013
pSukon Phanichphantp
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引用次数: 0
On the features of estimating the coefficient of inhomogeneity of a loose mixture during the operation of a gravitational device 论重力装置运行过程中松散混合物非均匀性系数估计的特点
Pub Date : 2018-10-15 DOI: 10.4172/2157-7048-C3-018
pAnna Kapranova, Ivan Verlokap
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引用次数: 2
PEMBUATAN PUPUK ORGANIK CAIR DARI LIMBAH BIOGAS 从沼气废物中提取液体有机肥
Pub Date : 2018-07-05 DOI: 10.33536/JCPE.V3I1.193
Sentiyaki Sentiyaki, Andi Rina Ayu Astuti, Imam Fathurahman, Setyawati Yani, Mandasini Mandasini, N. Nurjannah, Zakir Sabara
Pencemaran udara yang berasal dari emisi gas hasil pembakaran (ghp), termasuk karbon monoksida semakin meningkat sejalan dengan meningkatnya jumlah kendaraan bermotor. Daun trembesi memiliki potensi untuk menyerap polutan CO. Penelitian ini bertujuan untuk menghasilkan desain alat penyerap CO dari ektrak daun trembesi dan mengetauhi daya kerja alat tersebut terhadap emisi CO. Penelitian dilakukan dengan membuat alat yang berisi adsorben daun trembesi dalam beberapa lapisan dengan ketebalan yang berbeda, yaitu lapis 1, lapis 2 dan lapis 3. Selanjutnya dilakukan pengujian alat pada tipe karburator dan tipe injeksi dengan menggunakan alat Analisa Gas Buang (AGS-688). Hasil penelitian ini menunjukkan desain terbaik pada lapis 3 dengan daya serap emisi CO sebesar 17,69% untuk tipe karburator dan 28,13% untuk tipe injeksi.
燃烧产生的气体排放所产生的空气污染,包括一氧化碳,随着汽车数量的增加而增加。trembesi叶子有潜力来吸收污染物CO。本研究旨在产生ektrak trembesi叶子吸收CO的工具的设计和对CO排放mengetauhi功率器件工作。通过制造工具的研究中包含adsorben trembesi叶几层不同的厚度,1层、2层和3层。然后用排气分析器(AGS-688)对化油器类型和注入类型进行工具测试。研究结果显示,三层的设计中,化油器类型为17.69%,注入类型为28%。
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引用次数: 4
期刊
Journal of Chemical Engineering & Process Technology
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