Journal of chemical technology and biotechnology最新文献

{"title":"Engineered hybrid iron-cobalt metal oxide nanoparticles for effective adsorption of malachite green dye","authors":"Nasira Hussain,&nbsp;Shanza Shafaat,&nbsp;Ambreen Sarfraz,&nbsp;Muhammad Usman,&nbsp;Muhammad Saqib Khan,&nbsp;Asad Muhammad Khan,&nbsp;Rafaqat Ali Khan,&nbsp;Bilal Ahmad Zafar Amin,&nbsp;Muhammad Bilal,&nbsp;Ahson Jabbar Shaikh","doi":"10.1002/jctb.7737","DOIUrl":"10.1002/jctb.7737","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>Hybrid iron and cobalt metal oxide nanoparticles are well known; however, are not optimized in terms of size and stability. We engineered these hybrid nanoparticles using the co-precipitation method and characterized them by various techniques, which are then used for the effective adsorption and removal of malachite green (MG) dye.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>The ideal conditions for synthesis are determined to be 50:50 ratio of Fe₂O₃ and CoO, pH of 11, temperature range of 40 °C–60 °C, and reactant addition time of 20 min. These hybrid nanoadsorbents effectively eliminated MG dye from aqueous solutions. Factors such as initial MG dye concentration, pH of the medium, contact time, temperature, and nanoadsorbent dose were optimized for the MG removal to achieve a maximum removal efficiency of 96.9%. Non-linear fitting of data indicates that both Langmuir and Freundlich models provided the best fit, suggesting the presence of both monolayer and multilayer adsorption of MG on hybrid nanoparticles. The kinetics of MG dye removal are better controlled by the intraparticle diffusion (IPD) phenomenon. The adsorption of MG onto the hybrid nanoparticles was confirmed to be endothermic, with negative ΔG and positive ΔH values. The optimized synthetic conditions also positively impacted the hybrid nanoparticles which enhanced the adsorption and exhibited ferromagnetic behavior as compared to the superparamagnetic behavior reported in the literature, making them significantly important for dye removal applications.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>These findings demonstrate the potential of optimized hybrid nanoparticles as effective nanoadsorbents for dye removal applications, with implications for further applications in photocatalysis and sensing. © 2024 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"99 12","pages":"2553-2568"},"PeriodicalIF":2.8,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142192156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Rapid precipitation of vanadium from solution using melamine as precipitant with high efficiency","authors":"Bo Wang,&nbsp;Qiaowen Yang,&nbsp;Ting Li,&nbsp;Sifan Cui,&nbsp;Pengqiang Feng,&nbsp;Xuan Hou","doi":"10.1002/jctb.7738","DOIUrl":"10.1002/jctb.7738","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>Selective catalytic reduction (SCR) can effectively remove NO_<i>x</i> from flue gas in a coal-fired power plant. As the core of SCR technology, the catalyst has a limited lifespan. The process of reducing acid leaching and roasting water leaching can efficiently extract vanadium and tungsten from spent SCR catalyst. For vanadium recovery in solution, the traditional vanadium precipitation process by NH₄Cl has the disadvantages of consuming high precipitant dosage and producing large amounts of waste water.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>This study focused on the vanadium precipitation process using a solution containing vanadium obtained from adopting some steps to handle the spent SCR catalyst. First, melamine was screened out as the vanadium precipitant. Then, the vanadium precipitation conditions were optimized as follows: solution pH value of 1.0, <i>n</i>(C₃H₆N₆)/<i>n</i>(V) = 0.8, 110 °C and 30 min. Under the best precipitation conditions, the vanadium precipitation efficiency of melamine can reach 99.32%. Finally, the mechanisms of vanadium precipitation by NH₄Cl and melamine were discussed, respectively.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>The results showed that the vanadium precipitation process by NH₄Cl followed the chemical reactions between NH₄⁺ and vanadium ions, while the vanadium precipitation process by melamine followed the redox and complexation reactions which essentially belonged to the types of chemical adsorption. The vanadium precipitation product was roasted at 550 °C for 2 h to obtain the vanadium product. The main component of the vanadium product was V₂O₅, with a purity of 93.27 wt%. The total recovery efficiency of vanadium from spent SCR catalyst was 78.24%. © 2024 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"99 12","pages":"2569-2581"},"PeriodicalIF":2.8,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142224721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Zinc-based metal–organic frameworks for encapsulation and sustained release of ciprofloxacin for excellent antibacterial activities","authors":"Abdul Rauf,&nbsp;Mohsin Javed,&nbsp;Muhammad Jahangir,&nbsp;Mehdi Hassan,&nbsp;Anam Tariq,&nbsp;Wajahat Ali,&nbsp;Ali Bahadur,&nbsp;Shahid Iqbal,&nbsp;Sajid Mahmood,&nbsp;Khalid M Alotaibi,&nbsp;Matar Alshalwi","doi":"10.1002/jctb.7736","DOIUrl":"10.1002/jctb.7736","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>In terms of crystalline nanoporous materials, metal–organic frameworks (MOFs) are relatively new. They are self-assembling structures made of organic ligands that serve as linkers between metal centers and metal ions that function as coordination centers. Due to MOFs' high porosity, absence of nonaccessible bulk volume, vast surface areas and variety of pore sizes and topologies, drug delivery via them is becoming more and more common.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>Zn-MOF and Zn-MOF@drug were produced using a solvothermal approach in this study and characterized using a variety of methods, including Fourier transform infrared spectroscopy, powder X-ray diffraction and scanning electron microscopy. Utilizing the zone of inhibition and minimum inhibitory concentration approaches, Zn-MOF and Zn-MOF@drug were evaluated for their antibacterial capability against <i>Escherichia coli</i> and <i>Bacillus subtilis</i>, two types of bacteria.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>The antibacterial potential of Zn-MOF@drug was greater than that of the metal salt, commercially available ZnO, Zn-MOF and ligand alone. The mechanism of antibacterial activity of Zn-MOF@drug was also discussed. © 2024 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"99 12","pages":"2545-2552"},"PeriodicalIF":2.8,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142192157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Adsorption of vanadium using a new anionic Schiff Base adsorbent and its application to vanadium separation from boiler ash","authors":"Mohamed Abdalla","doi":"10.1002/jctb.7733","DOIUrl":"10.1002/jctb.7733","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> Background</h3>\u0000 \u0000 <p>This study reports the preparation of 2-hydroxy-3-(4-(((2-((2-(((<i>E</i>)-4-(2-hydroxy-3-(trimethylammonio)propoxy)-3-methoxybenzylidene)amino)ethyl)amino)ethyl)imino)methyl)-2-methoxyphenoxy)-<i>N</i>,<i>N</i>,<i>N</i>-trimethylpropan-1-aminium (HYM/QA). The adsorbent was employed to extract and concentrate vanadium from its solutions and boiler ash samples.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Results</h3>\u0000 \u0000 <p>The impact of initial dosage, pH, reaction time and temperature on the sorption behavior of V(V) was examined. Under optimal conditions (pH 5, 0.08 g dose, 45 min at room temperature), a sorption capacity of 392.25 mg g⁻¹ was achieved. The uptake of V(V) on HYM/QA was effectively reversed using 1 mol L⁻¹ NaOH, regenerating the material. After six cycles of sorption and elution, the sorption capability remained at 91.4% of its initial value. The efficiency and selectivity of HYM/QA toward V⁵⁺ ions were assessed using the separation factor parameter, revealing limited interference from heavy metals such as Mn²⁺, Cr³⁺, Pb²⁺, Si⁴⁺, Al³⁺, NO₃²⁻, HCO₃⁻ and Zn²⁺. The uptake process of HYM/QA for V(V) conformed to the Langmuir and Dubinin–Radushkevich isotherm models and the pseudo-second-order kinetic model. HYM/QA was characterized by infrared, Brunauer–Emmett–Teller surface area, ¹H NMR, ¹³C NMR and gas chromatography–mass spectrometry analyses, confirming successful preparation. Thermodynamic assessments suggested that the sorption process is endothermic, spontaneous and becoming more favorable with rising temperature.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Conclusion</h3>\u0000 \u0000 <p>The optimized conditions were used to adsorb vanadium from boiler ash samples, and the obtained vanadium pentaoxide was analyzed and confirmed using various tools, demonstrating the material's effectiveness for vanadium extraction. © 2024 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"99 11","pages":"2434-2453"},"PeriodicalIF":2.8,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142192161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ibuprofen removal by modified natural zeolite: characterization, modeling, and adsorption mechanisms","authors":"Anna Carla Ribeiro,&nbsp;Wardleison Martins Moreira,&nbsp;Bruna Bruguer Ferri,&nbsp;Débora dos Federici Santos,&nbsp;Mara Heloisa Neves Olsen Scaliante,&nbsp;Elizabeth de da Costa Neves Fernandes Almeida Duarte,&nbsp;Rosângela Bergamasco","doi":"10.1002/jctb.7729","DOIUrl":"10.1002/jctb.7729","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>Developing robust technologies to remove emerging pollutants from water is urgent since conventional treatments are not technically prepared to remove them. This paper investigated the ibuprofen (IBU) adsorption capacity onto natural zeolite (NZ) and hydrothermally modified zeolite in an acidic medium followed by impregnation with the cationic surfactant cetyltrimethylammonium bromide (CTAB) (MZ_HT-CTAB). The materials characterization included scanning electron microscopy (SEM), X-ray diffraction (XRD), atomic absorption spectroscopy (AAS), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA/DTG), N₂ adsorption/desorption isotherm (BET), Zeta Potential (ZP), and Point of Zero Charge (pH_PZC). The adsorptive capacity studies were carried out by varying the pH solution, a kinetic study at three concentrations (25, 50, and 100 mg L⁻¹), and the contaminant concentration influence (5–100 mg L⁻¹).</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>The results showed that the MZ_HT-CTAB obtained both the highest removal efficiency (~ 37%) and the highest adsorption capacity (~ 14 mg g⁻¹) at pH 5.0. The Pseudo Second-Order (PSO) model, which showed the best fit to the experimental data, is significant as it indicates the reliability of our results. The maximum adsorption capacity for the concentration of 100 mg L⁻¹ was 11.93 mg g⁻¹. According to Giles's classification, the isotherm was classified as S-3 type, indicating the competition between the adsorbate and water molecules for the active sites on the adsorbent surface.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>The adsorption studies demonstrate that the novel adsorbent (MZ_HT-CTAB) is highly effective in removing IBU, presenting a significant removal capacity and feasibility. This promising result contributes to the ongoing search for alternative materials for water treatment. © 2024 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"99 11","pages":"2407-2419"},"PeriodicalIF":2.8,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142192159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ferrate(VI) green oxidant: electrochemical generation, self-decomposition, and application for reactive red 195 azo dye treatment","authors":"Thi Van Anh Nguyen,&nbsp;Thi Thanh Thuy Mai,&nbsp;Thi Binh Phan,&nbsp;Huu Quang Tran,&nbsp;Minh Quy Bui","doi":"10.1002/jctb.7734","DOIUrl":"10.1002/jctb.7734","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>Ferrate(VI), an environmentally friendly oxidant, has recently emerged as one of the most promising chemicals for water and wastewater treatment due to its versatile application as an oxidant, coagulant, and disinfectant. In this paper, the factors affecting the electrosynthesis process of ferrate using ductile iron anode were studied. Besides, the obtained ferrate was used to remove reactive red 195 (RR195).</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>The optimal ferrate electrochemical synthesis conditions were determined, including 14 mol L⁻¹ NaOH electrolyte solution, a current density of 40 mA cm⁻², and electrolysis time of approximately 5–6 h. Furthermore, the kinetics of the ferrate's self-decomposition reaction was also studied at different temperatures. The decomposition process of ferrate in a 14 mol L⁻¹ NaOH environment followed second-order kinetics, with reaction rate constants of 4.70 × 10⁻⁹, 7.31 × 10⁻⁸, 1.95 × 10⁻⁷, and 4.70 × 10⁻⁷ (L mol⁻¹ s⁻¹) at temperatures of 4, 10, 20, and 30 °C, respectively. RR195 treatment efficiency by ferrate reached 96.3% in a short time of 3 min at pH 3 with a ferrate/RR195 molar ratio of 30/1.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>This study identified the optimal conditions for the electrochemical synthesis of ferrate using a ductile iron anode. Ferrate was stable at a low temperature of 4 °C, so unused ferrate needs to be stored at low temperatures to avoid decomposition of ferrate. The ferrate green oxidant demonstrated high efficiency in the treatment of RR195 in a short time. © 2024 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"99 11","pages":"2454-2463"},"PeriodicalIF":2.8,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142192158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Textile waste pretreatment for anaerobic digestion: a review and technology feasibility study","authors":"Naveenrajah Tharmarajah,&nbsp;Kaveh Shahbaz,&nbsp;Saeid Baroutian","doi":"10.1002/jctb.7728","DOIUrl":"10.1002/jctb.7728","url":null,"abstract":"<p>The increasing volume of textile waste in landfills and incineration poses severe environmental challenges. Waste valorisation of textile waste via anaerobic digestion (AD) is preferable, as it offers economic and environmental benefits, but it is hindered by textile complexity, necessitating effective pretreatment technologies to improve biogas production. This study aims to evaluate various pretreatment technologies for biogas production from textile fibres via AD. A weighted-scoring analysis (WSA) assessed pretreatment methods based on technical, economic, environmental and operational criteria. Hydrothermal pretreatment emerged as the most technically effective method, scoring 140 owing to its substantial methane enhancement. Economically, shredding was the most viable option, scoring 125, as a consequence of low capital and O&amp;M cost. Environmentally, hydrothermal and deep eutectic solvent (DES) pretreatments were top performers with 100 points owing to low environmental impact and positive heat reactions. In a case study conducted in the Auckland region, the potential environmental impact (PEI) obtained from hydrothermal and DES were 169 and 92 per year, respectively, resulting in minimal environmental impact. Operationally, ultrasonic and biological pretreatments scored highest owing to their ease of operation, and minimal health and safety requirements. Overall, hydrothermal pretreatment achieved the highest WSA score of 340, reflecting its balanced performance across all criteria. Hydrothermal pretreatment is the most promising technology for enhancing biogas production from textile waste. Its technical efficiency, economic feasibility and environmental benefits regarding the WSA score make it suitable for upscaling and providing a viable solution for managing textile waste in the AD plant. © 2024 The Author(s). <i>Journal of Chemical Technology and Biotechnology</i> published by John Wiley &amp; Sons Ltd on behalf of Society of Chemical Industry (SCI).</p>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"99 11","pages":"2213-2227"},"PeriodicalIF":2.8,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jctb.7728","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142192160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploring enhanced syngas production via the catalytic performance of metal-doped X-Ni/CeO2 (X = Zr, La, Sr) in the dry reforming of methane","authors":"Wan Nabilah Manan,&nbsp;Wan Nor Roslam Wan Isahak,&nbsp;Zahira Yaakob,&nbsp;Salma Samidin,&nbsp;Khairul Naim Ahmad,&nbsp;Mohd Nor Latif,&nbsp;Ali Faris Aldoghachi,&nbsp;Yun Hin Taufiq-Yap","doi":"10.1002/jctb.7732","DOIUrl":"https://doi.org/10.1002/jctb.7732","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> Background</h3>\u0000 \u0000 <p>The quest to manufacture large amounts of syngas to bridge fossil fuels and the renewable energy ecosystem stimulates the creation of efficient and stable heterogeneous catalysts. The NiCeO₂ catalysts, synthesized via ultrasonic-assisted citric acid complexation, are highly efficient for the dry reforming of methane (DRM) reaction. Different promoter metals (Zr, La and Sr) were tested for catalytic performance and syngas production. A range of analyses, including X-ray diffraction (XRD), N₂ physisorption, H₂ temperature-programmed reduction, CO₂ temperature-programmed desorption, field emission scanning electron microscopy (FESEM), transmission electron microscopy and X-ray photoelectron spectroscopy, were employed to characterize the physicochemical properties of the catalysts.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Results</h3>\u0000 \u0000 <p>XRD results indicated the formation of NiO, CeO₂, solid solution ceria–zirconia, perovskite LaNiO₃ and SrNiO₃ crystalline phases. FESEM results showed the promoted catalysts (Zr, La, Sr) produce large pores to facilitate reactant diffusion, with zirconia specifically creating a spiderweb morphology. At 800 °C, the CH₄ and CO₂ conversions follow the sequence of NiCeO₂ catalyst (CH₄ = 54%, CO₂ = 45%) &lt; Sr/NiCeO₂ (CH₄ = 60%, CO₂ = 67%) &lt; La/NiCeO₂ (CH₄ = 85%, CO₂ = 84%) &lt; Zr/NiCeO₂ (CH₄ = 95%, CO₂ = 87%). The integration of promoters in DRM catalysts has notably improved carbon formation resistance, as evidenced by the following ranking: Zr/NiCeO₂ (5.1 wt%) &lt; commercial catalyst (6.0 wt%) &lt; La/NiCeO₂ (7.85 wt%) &lt; Sr/NiCeO₂ (10.9 wt%) &lt; NiCeO₂ (11.3 wt%).</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Conclusion</h3>\u0000 \u0000 <p>This study demonstrates that incorporating promoters, particularly Zr, in NiCeO₂ significantly enhances resistance to carbon formation. It offers valuable insights into selecting metal catalyst promoters for excellent catalytic performance in DRM. © 2024 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"99 11","pages":"2420-2433"},"PeriodicalIF":2.8,"publicationDate":"2024-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142430199","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Construction of magnetic bimetallic oxide-decorated attapulgite-based adsorbents for arsenic ion adsorption","authors":"Bo Yu,&nbsp;Xiaoning Li,&nbsp;Jiao Ma,&nbsp;Han Yan,&nbsp;Ke Lian,&nbsp;Pengfei Shen","doi":"10.1002/jctb.7727","DOIUrl":"10.1002/jctb.7727","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>Arsenic contamination can exert severe detrimental effects on the ecological environment and human health. It can cause acute or chronic poisoning, resulting in cell distortion or cancer when humans come into contact with or consume arsenic-containing water. Adsorption technology is one of the effective methods for arsenic removal. In this study, using attapulgite (ATP) as a support for bimetallic iron–manganese oxides, a series of adsorbents (Fe-Mn/ATP) with different manganese-to-iron molar ratios were prepared via the coprecipitation method. Scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy mapping, X-ray diffraction and zeta potential measurements were used to analyze the structure and properties of Fe-Mn/ATP. In addition, the adsorption performance of the material for arsenic ions was investigated by static adsorption and dynamic adsorption experiments.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>A novel Fe-Mn/ATP adsorbent was prepared using ATP as the raw material and manganese-to-iron molar ratio was 1:3 by coprecipitation at 60 °C for 1 h. The adsorption efficiency of arsenic ions was optimal at an Fe-Mn/ATP dosage of 2 g L⁻¹, pH 4 and a contact time of 10 min, reaching a maximum adsorption capacity of 38.27 mg g⁻¹ at room temperature. The adsorption process followed the pseudo-second-order kinetic model and the Langmuir isotherm adsorption model, indicating that arsenic ion adsorption by Fe-Mn/ATP was mainly monolayer chemical adsorption. Furthermore, Fe-Mn/ATP showed a removal rate for arsenic ions of over 80% after four cycles of regeneration, revealing a great potential for practical application.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>This study offers a promising Fe-Mn/ATP adsorbent for removal of arsenic ions from wastewater. © 2024 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"99 11","pages":"2395-2406"},"PeriodicalIF":2.8,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141925017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Production of magnetic photocatalysts from TiO2, Fe(NO3)3 and sucrose and their application for the degradation of model organic contaminants","authors":"Leydiane de Oliveira Pereira,&nbsp;Iara do Rosario Guimarães,&nbsp;Luana Pereira Zampiere,&nbsp;Isabela Sales Marques,&nbsp;Stéfany Gonçalves de Moura,&nbsp;Aline Aparecida Caetano,&nbsp;Fabiano Magalhães","doi":"10.1002/jctb.7725","DOIUrl":"10.1002/jctb.7725","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>Photocatalysis is an efficient method for the removal of organic contaminants in wastewater. In this study, different magnetic photocatalysts for the degradation of organic compounds were prepared.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>Ti/C/Fe photocatalysts were prepared by supporting TiO₂ (20, 40 and 60% w/w) on a carbon/iron oxide (C/Fe) magnetic carrier. Characterization via Raman spectroscopy, X-ray diffractometry, thermal analysis, X-ray fluorescence, scanning electron microscopy and energy-dispersive X-ray spectroscopy/elemental mapping and magnetic property analysis by vibrating-sample magnetometry confirmed the presence of TiO₂, Fe₃O₄, Fe₃C and char in the photocatalysts as well as their magnetic properties. The results of specific surface area analysis showed that the C/Fe support had a surface area of 183 m² g⁻¹ and that this area decreased with an increasing amount of supported TiO₂, reaching up to 129 m² g⁻¹. Diffuse reflectance spectroscopy characterization revealed that the bandgap values obtained for the photocatalysts (Ti/C/Fe) were lower than 3.2 eV. The prepared photocatalysts showed high efficiency in degrading the contaminants Remazol Black (RB5) (99%), paracetamol (77%) and phenol (90%). Recovery and reuse experiments using RB5 showed that after the fourth reaction, the photocatalytic efficiency was reduced by 50%, and the recovery reached up to 70%. Sedimentation kinetics showed that while only 6% of the TiO₂ was deposited, up to 89% of the photocatalysts were deposited.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSIONS</h3>\u0000 \u0000 <p>These results indicate that the photocatalysts showed excellent photocatalytic efficiency for different contaminants and can be easily and quickly separated from the reaction medium by magnetic separation. © 2024 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"99 11","pages":"2366-2380"},"PeriodicalIF":2.8,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141929240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}