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Exploration of the rules for the use of organic additives in the mortar of the Forbidden city 故宫灰浆中有机添加剂使用规则探讨
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.culher.2024.08.017
Kuanrong Zhai , Hui Zhu , Li Luo , Bingjian Zhang , Longguan Zhu , Qiong Zhang , Peng Zhao

The Forbidden City exemplifies the official architecture of the Ming (C.E. 1368–1644) and Qing (C.E. 1644–1911) dynasties in China. The buildings within the Forbidden City adhere to a specific construction system and hierarchy. This study examined the organic additives in eighty-three lime mortar samples collected from the Forbidden City. These mortar samples were categorised into two main groups: garden mortar and construction mortar. The construction mortar was further subdivided into masonry, rendering, tile roof, and pointing mortars. Classical chemical analysis was performed to identify organic residues in the samples, including glutinous rice, sugar, oil, blood, and protein. Additionally, ovalbumin, casein, collagen, and peach gum were detected using enzyme-linked immunosorbent assay (ELISA). The results confirmed historical records regarding to the use of organic additives in ancient mortars. Statistical analysis revealed that the organic additives added to different types of mortars were selected according to the location and function of the mortar. This evidence supports the validity of traditional Chinese composite mortar scientifically. Ancient Chinese artisans adhered to rules aimed at practicality and functional realisation when selecting organic additives.

紫禁城是中国明朝(公元 1368-1644 年)和清朝(公元 1644-1911 年)官方建筑的典范。故宫内的建筑遵循特定的建筑体系和等级制度。本研究检测了从故宫采集的 83 份石灰砂浆样本中的有机添加剂。这些砂浆样本被分为两大类:园林砂浆和建筑砂浆。建筑砂浆又细分为砌筑砂浆、渲染砂浆、瓦顶砂浆和尖顶砂浆。对样本进行了经典化学分析,以确定样本中的有机残留物,包括糯米、糖、油、血液和蛋白质。此外,还使用酶联免疫吸附法(ELISA)检测了卵清蛋白、酪蛋白、胶原蛋白和桃胶。结果证实了有关古代灰泥中使用有机添加剂的历史记录。统计分析显示,不同类型灰泥中添加的有机添加剂是根据灰泥的位置和功能选择的。这些证据从科学上支持了中国传统复合砂浆的有效性。中国古代工匠在选择有机添加剂时坚持以实用性和功能实现为目标的规则。
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引用次数: 0
Implementation of the diagnostic capabilities of the CMOS sensor in the NIR environment, using 1070 nm interference filter and a conventional IR-pass filters set 使用 1070 纳米干扰滤波器和传统红外滤波器组,在近红外环境中实现 CMOS 传感器的诊断功能
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.culher.2024.08.007
Paolo A.M. Triolo

NIR reflectography with silicon sensors (CMOS) is commonly acquired with 780 nm band-pass filters that allow the acquisition of clear images and high shutter speeds, while maintaining a low equipment cost. In this way, however, acquisition between 1000 nm and 1150nm-where the silicon sensor is still formally infrared sensitive-is in fact overhelmed by the stronger sensitivity in the infrared spectrum portion between 780 nm and 980 nm. Coupling a 1070 nm (± 5 nm) interferencial filter to an 87C nm IR pass filter (FHWH 850 nm) acquisitions in this portion of the NIR spectrum were carried out, witnessing a outstanding increase in visibility of underdrawings and pentimenti. A practical test of the effectiveness of the filters system mounted on the Nikon D800 IRUV was made, comparing the results with those obtained by the “Osiris” InGaAs detector by Opus Instruments. The comparison was performed on the “Deposition” (oil on panel) by Antonio Semino (1485–1555) in the collection of the Accademia Ligustica of Genoa, highlighting a significant qualitative proximity between the results obtained with the interference system and those with InGaAs detector, compared to the conventional acquisition with single IR long-pass filter.

In addition, the 1070nm+87C filter system was used to increase the recognition capability of azurite pigments. This procedure widens the possibilities of first-impact diagnostics by means of low-cost and market available imaging systems based on commercial CMOS IRUV cameras..

使用硅传感器(CMOS)进行近红外反射成像时,通常使用 780 纳米带通滤光片,这样可以获得清晰的图像和较高的快门速度,同时保持较低的设备成本。然而,这样一来,1000 纳米至 1150 纳米之间的采集(硅传感器在形式上仍具有红外敏感性)实际上被 780 纳米至 980 纳米之间红外光谱部分的较强敏感性所掩盖。将 1070 nm(± 5 nm)干涉滤光片与 87C nm 红外通滤光片(FHWH 850 nm)耦合后,对这部分近红外光谱进行了采集,发现底图和五角星的可见度显著提高。对安装在尼康 D800 IRUV 上的滤光片系统的有效性进行了实际测试,并将测试结果与 Opus Instruments 公司的 "Osiris "InGaAs 探测器获得的结果进行了比较。对比是在热那亚 Accademia Ligustica 收藏的 Antonio Semino(1485-1555 年)的 "Deposition"(板上油画)上进行的,与使用单个红外长通滤镜的传统采集方法相比,使用干涉系统和 InGaAs 检测器获得的结果在质量上有显著的接近性。这一方法拓宽了利用基于商用 CMOS IRUV 相机的低成本、市场上可买到的成像系统进行首次影响诊断的可能性。
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引用次数: 0
HUL values in practice: A character area designation model for the conservation of built heritage in less-developed regions HUL 价值观的实践:欠发达地区建筑遗产保护的特色区域指定模式
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-09-11 DOI: 10.1016/j.culher.2024.08.010
Erfaneh Ghanbari, Sahand Lotfi, Mahsa Sholeh

This study endeavors to confront the challenge of adhering to international guidelines for Historic Urban Landscape (HUL) values and heritage conservation in developing nations, specifically focusing on Iran. Conventional reliance on basic buffer zone methodologies for safeguarding national monuments often leads to the oversight and subsequent deterioration of valuable structures, resulting in irreversible decay. This research introduces an innovative GIS-based zoning methodology alongside a comprehensive framework for assessing heritage values to mitigate these deficiencies. Grounded in seminal texts such as the Venice Charter (1964), Washington Charter (1987), and Vienna Memorandum (2005), this study extends the HUL approach to establish a cost-effective yet robust practical foundation. Through the Lar Old City case study, the research systematically integrates the Analytical Hierarchy Process (AHP) and Inverse Distance Weighting (IDW) within GIS to evaluate heritage values and map character areas. This approach facilitates regular assessments and promotes sustainable management of built heritage, demonstrating efficiency in resource allocation. The framework aims to bolster conservation efforts by embedding HUL values and advocating for sustainable urban development consistent with contemporary planning principles. The findings underscore this approach's practical significance and applicability, offering a comprehensive framework to bridge gaps in heritage conservation practices and safeguard cultural heritage for future generations.

本研究致力于应对发展中国家(特别是伊朗)在城市历史景观(HUL)价值和遗产保 护方面遵守国际准则所面临的挑战。传统上依靠基本的缓冲区方法来保护国家古迹的做法往往会导致对有价值建筑的疏忽和随之而来的损坏,造成不可逆转的衰败。这项研究引入了一种基于地理信息系统的创新分区方法,以及一个评估遗产价值的综合框架,以减少这些缺陷。本研究以《威尼斯宪章》(1964 年)、《华盛顿宪章》(1987 年)和《维也纳备忘录》(2005 年)等开创性文献为基础,扩展了 HUL 方法,以建立一个具有成本效益且稳健的实用基础。通过拉尔老城案例研究,本研究系统地将层次分析法(AHP)和反距离加权法(IDW)整合到地理信息系统中,以评估遗产价值并绘制特色区域图。这种方法便于定期评估,促进了建筑遗产的可持续管理,提高了资源分配效率。该框架旨在通过植入 HUL 价值,倡导符合当代规划原则的可持续城市发展,从而加强保护工作。研究结果强调了这一方法的实际意义和适用性,为弥合遗产保护实践中的差距和为子孙后代保护文化遗产提供了一个全面的框架。
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引用次数: 0
Analysis of Eleonore Koch's artwork and powdered pigments from MAC-USP and Pinacoteca of São Paulo collections 分析埃莉奥诺尔-科赫的艺术作品和来自 MAC-USP 和圣保罗 Pinacoteca 收藏馆的粉末颜料
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-09-11 DOI: 10.1016/j.culher.2024.08.011
Vitória D. Sousa , Wanda G.P. Engel , Julia Schenatto , Márcia Barbosa , Márcia A. Rizzutto

Eleonore Koch is a German artist known for her paintings featuring arrangements of colors and ordinary objects. She spent a significant part of her life in Brazil, where she had the opportunity to interact with and learn from Alfredo Volpi, a colorist artist who introduced her to the tempera technique and the use of natural and mineral pigments, replacing oil-based industrial ones. A collection of powdered pigments she used during her lifetime was studied by spectroscopic analysis, forming an initial basis of knowledgement about Koch's pigments. In this paper, one painting from the Museum of Contemporary Art of the University of Sao Paulo (MAC-USP) collection was analyzed by spectroscopic (ED-XRF, Raman and FTIR) and imaging techniques. The painting palette was compared with some powdered pigments from the artist's collection. The pigments identified in the artwork are Chrome Oxide Green, Titanium White, Phthalocyanine Blue, Ivory or Bone Black and a yellowish/brown pigment rich in hematite. The findings indicate that most of the pigments found in Koch's artwork were also part of her personal collection.

Eleonore Koch 是一位德国艺术家,她的画作以色彩和普通物品的排列组合而闻名。在巴西,她有机会与色彩艺术家阿尔弗雷多-沃尔皮(Alfredo Volpi)交流并向其学习,后者向她介绍了蛋彩画技法和天然矿物颜料的使用,以取代油性工业颜料。通过光谱分析研究了她生前使用的一系列粉末颜料,为了解科赫的颜料奠定了初步基础。本文通过光谱(ED-XRF、拉曼和傅立叶变换红外光谱)和成像技术对圣保罗大学当代艺术博物馆(MAC-USP)收藏的一幅画作进行了分析。调色板与艺术家收藏的一些粉末状颜料进行了比较。艺术品中的颜料包括氧化铬绿、钛白、酞菁蓝、象牙黑或骨黑以及一种富含赤铁矿的黄褐色/棕色颜料。研究结果表明,在科赫的艺术作品中发现的大部分颜料也是她个人收藏的一部分。
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引用次数: 0
Evaluation of carbonated fossil bone consolidation by induction of calcium hydroxide nanoparticles in a Miocene Cheirogaster richardi specimen 通过诱导中新世 Cheirogaster richardi 标本中的氢氧化钙纳米颗粒,评估碳化化石骨的固结情况
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-09-09 DOI: 10.1016/j.culher.2024.08.006
Silvia Marín-Ortega , Manuel Ángel Iglesias-Campos , M. Àngels Calvo i Torras

In this research, calcium hydroxide nanoparticles, as a carbonate consolidation method, have been evaluated on carbonated fossil bone samples from decontextualized Cheirogaster richardi specimens’ fragments.

The main objective was to assess whether the treatment improved fossil bone surface cohesion and mechanical strength by creating a consolidated carbonate matrix in fossil substrate. Treatment penetration capacity and chemical compatibility without causing observable alterations in substrate porosity and external appearance were considered as significant questions to be assessed. Samples were analysed both before and after treatment using scanning electron microscopy, spectrophotometry, weight measurement control, water absorption assessment, conductivity and pH measurement, Vickers microindentation and tape testing. During analysis and evaluation, changes in fossil bone after treatment compared to its original condition have been taken into account.

Results point out that hardness and cohesion increased significantly after treatment, bonding together disaggregated particles via a calcium carbonate micrometric layer, with almost negligible changes in surface topography and colour. In addition, calcium hydroxide nanoparticles penetration depth was remarkable. Conductivity, pH and weight hardly changed and porosity reduction was observed without complete pore blockage. To sum up, the treatment was effective and suitable for carbonate fossil bones having a highly compatibility with carbonate fossil bones substrates.

在这项研究中,氢氧化钙纳米粒子作为一种碳酸盐固结方法,被用于评估来自去质化 Cheirogaster richardi 标本碎片的碳化骨化石样本。主要目的是评估这种处理方法是否能通过在化石基质中形成固结的碳酸盐基质来改善化石骨表面的内聚力和机械强度。处理的渗透能力和化学兼容性,同时不对基质的孔隙率和外观造成明显改变,被认为是需要评估的重要问题。使用扫描电子显微镜、分光光度法、重量测量控制、吸水性评估、电导率和 pH 值测量、维氏微压痕法和胶带测试对处理前后的样品进行了分析。结果表明,处理后硬度和内聚力显著增加,通过碳酸钙微米层将分散的颗粒粘合在一起,表面形貌和颜色的变化几乎可以忽略不计。此外,氢氧化钙纳米颗粒的渗透深度也非常显著。电导率、pH 值和重量几乎没有变化,孔隙率降低,但孔隙没有完全堵塞。总之,该处理方法是有效的,适用于碳酸盐化石骨骼,与碳酸盐化石骨骼基质高度兼容。
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引用次数: 0
Use of water - white spirit microemulsion to clean a white monochromatic painting by Gilda Azevedo 使用水-白酒微乳液清洗 Gilda Azevedo 创作的白色单色画
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-09-07 DOI: 10.1016/j.culher.2024.08.013
João Cura D'Ars de Figueiredo Junior, Márcia Georgina de Assis, Maria Alice Honório Sanna Castello Branco

Cleaning a painting is a process that requires knowledge of its materiality, integrity, and solvent systems. Aqueous solvent systems are a sustainable alternative, but their use must consider the potential harm that can arise in the process- such as swelling and leaching of layers underlying the dirt. Modern oil paintings made from the twentieth century onwards may be sensitive to aqueous solvents and suffer such damage. In this work, the cleaning of a white monochromatic oil painting by artist Gilda Azevedo was carried out with a microemulsified system of water in white-spirit using Tween 80 and ethanol as surfactant and cosurfactant, respectively. The microemulsified system and emulsions are the result of a ternary pseudodiagram where water, white-spirit, and surfactant/cosurfactant are carefully rationed. The emulsions obtained were characterized by measurements of conductivity and Dynamic Light Scattering. The artwork was examined by infrared absorption spectroscopy and X-ray fluorescence spectroscopy. Cleaning tests were firstly performed with emulsions and microemulsion and the removal of pigments was qualitatively analyzed by X-ray fluorescence spectroscopy. It was observed that the microemulsified system was an efficient cleaner while causing less removal of pigments compared to emulsified systems and, thus, chosen for cleaning. This cleaning efficiency was attributed to the use of water-white-spirit mixes capable of interacting with hydrophobic and hydrophilic substances in dirt. The lower pigment removal was ascribed to the dynamic percolation system and the nanometric size of the microemulsions.

清洗油画是一个需要了解其材质、完整性和溶剂系统的过程。水性溶剂系统是一种可持续的替代品,但在使用过程中必须考虑到可能产生的潜在危害,例如污垢下层的膨胀和浸出。二十世纪以来创作的现代油画可能对水性溶剂很敏感,会受到这种损害。在这项工作中,我们使用白灵水的微乳化体系来清洗艺术家吉尔达-阿泽维多(Gilda Azevedo)的一幅白色单色油画,并分别使用吐温 80 和乙醇作为表面活性剂和助表面活性剂。微乳化体系和乳液是水、白灵水和表面活性剂/共表面活性剂经过精心配比的三元假图表的结果。通过测量电导率和动态光散射,对获得的乳液进行了表征。通过红外吸收光谱和 X 射线荧光光谱对艺术品进行了检测。首先对乳液和微乳液进行了清洁测试,并通过 X 射线荧光光谱对颜料的去除情况进行了定性分析。结果表明,与乳化体系相比,微乳化体系是一种高效的清洁剂,但对颜料的去除率较低,因此被选为清洁剂。这种清洁效率归功于使用了能够与污垢中的疏水性和亲水性物质相互作用的水-白-精神混合物。颜料去除率较低的原因是动态渗滤系统和微乳剂的纳米尺寸。
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引用次数: 0
CO2 snow microblasting of submicron particles from cellulose-based cultural heritage objects: Comparison with traditional dry cleaning methods 纤维素文物亚微米颗粒的二氧化碳喷雪:与传统干洗方法的比较
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-09-06 DOI: 10.1016/j.culher.2024.08.008
Ludmila Mašková , Jiří Smolík , Petra Vávrová , Jitka Neoralová , Dana Novotná , Věra Jandová , Jakub Ondráček , Kateřina Kocová , Adéla Marešová , Mária Zedníková , Jaroslav Schwarz

Library collections are mostly made of porous cellulose-based materials such as papers and textiles. Submicron particles, representing up to 90% of particulate matter (PM) mass in libraries and archives, deposit on book surfaces and can also penetrate into small openings, including inter-fibre spaces. These particles can cause degradation of archival documents and therefore it is necessary to clean them. An alternative method of cleaning using the CO2 snow jet was tested and compared with six traditional mechanical dry cleaning techniques. Different types of papers and textiles (bookbinding cloths) commonly used in library collections were treated with the jet using a newly developed automatic system. Measurements included the assessment of particle removal efficiency and possible degradation of the cellulose materials. The method was verified using real archival documents. Results revealed that the jet was effective in removing submicron particles, including those embedded in the fibrous surface. The CO2 snow jet did not alter the surface properties of uncoated papers and textiles, whereas the degradation of coated samples was probably caused by surface temperature decrease after the CO2 snow application. In contrast, the mechanical dry cleaning methods were almost ineffective for the submicron PM. Moreover, the mechanical techniques alter the surface by leaving visible crumbs of the cleaning material, releasing fibers, and changing of fibers structure. The results indicate that CO2 snow jet cleaning using the automatic system is a suitable method for common types of papers and textiles with uncoated surfaces.

图书馆的藏书大多由纸张和纺织品等多孔纤维素材料制成。亚微米颗粒占图书馆和档案馆颗粒物质(PM)质量的 90%,它们沉积在书籍表面,也可渗透到小孔中,包括纤维间的空隙。这些微粒会导致档案文件降解,因此有必要对其进行清洁。我们测试了一种使用二氧化碳喷雪的替代清洁方法,并与六种传统的机械干洗技术进行了比较。使用新开发的自动系统,对图书馆藏品中常用的不同类型的纸张和纺织品(装订布)进行了喷射处理。测量包括评估颗粒去除效率和纤维素材料的可能降解。使用真实的档案文件对该方法进行了验证。结果显示,喷射器能有效去除亚微米级的颗粒,包括嵌入纤维表面的颗粒。二氧化碳雪水喷射不会改变未涂层纸张和纺织品的表面特性,而涂层样品的降解可能是由于二氧化碳雪水喷射后表面温度降低造成的。相比之下,机械干洗方法对亚微米可吸入颗粒物几乎无效。此外,机械技术会通过留下明显的清洁材料碎屑、释放纤维和改变纤维结构来改变表面。结果表明,使用自动系统进行二氧化碳雪花喷射清洁是一种适用于常见类型的未涂层纸张和纺织品的方法。
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引用次数: 0
ours Elsevier 爱思唯尔熊
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-09-01 DOI: 10.1016/S1296-2074(24)00190-0
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引用次数: 0
Intangible heritage restoration of damaged tomb murals through augmented reality technology: A case study of Zhao Yigong Tomb murals in Tang Dynasty of China 通过增强现实技术修复受损古墓壁画的非物质遗产:中国唐代赵翼公墓壁画案例研究
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-09-01 DOI: 10.1016/j.culher.2024.08.005
Sun Zheng

Tomb murals are a precious amalgamation of tangible and intangible heritage, encapsulating profound historical significance and aesthetic value. While tangible heritage often gains more attention than intangible heritage in cultural protection, it is still imperative to acknowledge that intangible heritage complements and substantiates the historical, cultural and artistic context. Tomb murals contain intangible heritage elements such as religious practices, customs and artistic techniques. Tomb murals from the Tang Dynasty of China showcase the cultural richness of both tangible and intangible heritage. Nevertheless, there are many challenges to the protection of Tang Dynasty tomb murals. In light of these challenges, the current study aims to protect the intangible heritage embodied in Tang Dynasty tomb murals through augmented reality technology. A Tang Dynasty tomb, the Zhao Yigong Tomb, has been selected as the research object. Seven murals from this tomb were restored using a process involving two-dimensional and three-dimensional modelling combined with augmented reality (AR) technology. Throughout the restoration process, the current study explores the impact of religious customs associated with the Zhao Yigong Tomb on mural contents and artistic techniques. The scenes depicted in these seven murals were integrated into an on-cloud AR platform to establish an effective process for protecting intangible heritage in tomb murals and stimulate further research, design and development. This study identifies the target audience as researchers, educators and college students interested in history, art and culture. To evaluate the current study, researchers and educators with relevant working backgrounds and college student participants with different backgrounds and interests were invited to test the AR application in the field, followed by one-to-one interviews for a usability assessment. The usability assessment shows that the AR application is widely accepted. In addition to adding information interactively, it helps the audience to improve their understanding of Tang Dynasty art and culture.

古墓壁画是物质遗产和非物质遗产的珍贵结合,具有深远的历史意义和美学价值。虽然在文化保护方面,物质遗产往往比非物质遗产更受关注,但仍然必须承认非物质遗产是对历史、文化和艺术背景的补充和证实。古墓壁画包含宗教习俗、风俗习惯和艺术技巧等非物质遗产元素。中国唐代的墓葬壁画展示了物质和非物质遗产的丰富文化内涵。然而,唐代墓葬壁画的保护工作面临诸多挑战。鉴于这些挑战,本研究旨在通过增强现实技术保护唐代墓葬壁画所体现的非物质遗产。本研究选择了唐代赵翼公墓作为研究对象。通过二维和三维建模结合增强现实(AR)技术,对该墓中的七幅壁画进行了修复。在整个修复过程中,本研究探讨了与赵一公墓相关的宗教习俗对壁画内容和艺术技巧的影响。这七幅壁画中描绘的场景被整合到云上 AR 平台中,以建立保护墓葬壁画中非物质遗产的有效流程,并促进进一步的研究、设计和开发。本研究将目标受众确定为对历史、艺术和文化感兴趣的研究人员、教育工作者和大学生。为了对本研究进行评估,我们邀请了具有相关工作背景的研究人员和教育工作者以及具有不同背景和兴趣的大学生参与实地测试 AR 应用程序,随后进行了一对一的可用性评估访谈。可用性评估结果表明,AR 应用程序被广泛接受。除了以互动方式增加信息外,它还有助于受众加深对唐代艺术和文化的了解。
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引用次数: 0
Multifunctional organic-inorganic hybrid coating for enhanced bronze corrosion protection 用于增强青铜腐蚀防护的多功能有机-无机杂化涂层
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-09-01 DOI: 10.1016/j.culher.2024.08.003
Wenling Wu , Xuan Zhang , Yinghao Chen , Juan Ji , Fang Zhang , Jiang Guo , Ting Zhao , Jianfeng Zhu , Hongjie Luo

Bronze relics with vital historical, artistic, and scientific value, are one of the significant symbolizations of human civilization. However, due to the long burial time and the change in storage conditions, an inevitable and thorny problem arises in preventing the ancient bronze relics from corrosion. Coatings have great potential for metal corrosion protection at present. This study prepared a multifunctional coating consisting of zinc oxide (ZnO), titanium dioxide (TiO2), and fluoroethylene vinyl ether (FEVE) polymer by an organic-inorganic hybrid, which was applied onto the surface of corroded bronze using a self-assembly method and spraying. The rough structure of composite coating resembling that of the mastoid structure found on lotus leaf, effectively prolongs the transmission path of corrosive ions while preventing bronze contact with the corrosive media. Additionally, this study mainly investigated the bronze anti-corrosion mechanism through an electrochemical analysis perspective. Electrochemical tests revealed the lower corrosion current density, and the positive corrosion potential of multifunctional FEVE@ZnO/TiO2 coating immersion in 3.5 wt% NaCl solution. The experimental results demonstrate that the synergistic effect of organic-inorganic significantly enhances corrosion resistance by retarding the corrosion process and providing active protection against corrosion. The multifunctional coating also exhibits exceptional self-cleaning properties and weatherability when without changing the bronze color and appearance. Consequently, this preparation strategy and research approach for constructing a multifunction coating has a great application prospect in the conservation of bronze relics and metal anti-corrosion.

青铜文物具有重要的历史、艺术和科学价值,是人类文明的重要标志之一。然而,由于埋藏时间长、保存条件多变等原因,古代青铜文物在防腐方面出现了不可避免的棘手问题。目前,涂料在金属防腐方面具有很大的潜力。本研究通过有机-无机杂化制备了一种由氧化锌(ZnO)、二氧化钛(TiO2)和氟乙烯-乙烯基醚(FEVE)聚合物组成的多功能涂层,并采用自组装法和喷涂法将其涂在被腐蚀的青铜器表面。复合涂层的粗糙结构类似于荷叶上的乳突结构,可有效延长腐蚀离子的传输路径,同时防止青铜与腐蚀介质接触。此外,本研究主要从电化学分析的角度研究了青铜的抗腐蚀机理。电化学测试表明,多功能 FEVE@ZnO/TiO2 涂层浸泡在 3.5 wt% 的 NaCl 溶液中,腐蚀电流密度较低,腐蚀电位为正。实验结果表明,有机-无机协同作用通过延缓腐蚀过程和提供积极的防腐蚀保护,显著增强了耐腐蚀性能。在不改变青铜颜色和外观的情况下,这种多功能涂层还具有优异的自清洁性能和耐候性。因此,这种多功能涂层的制备策略和研究方法在青铜文物保护和金属防腐方面具有广阔的应用前景。
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引用次数: 0
期刊
Journal of Cultural Heritage
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